At Least One Polymer Is Derived From A -n=c=x Reactant Wherein X Is A Chalcogen Atom Or Wherein The Polymer-forming System Contains The Same Type Of Reactant Patents (Class 521/137)
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Publication number: 20110263728Abstract: A recycled latex foam material is prepared by mixing polyurethane with recycled waste latex grains to cause a polymerization reaction and then feeding the polymerized recycled waste latex foam grains and polyurethane mixture into a mold for molding into a finished product. The method of the invention is environmentally friendly and practical for making latex foam pads of different hardnesses and densities for different application purposes by using different grain sizes of recycled waste latex grains with polyurethane. The finished product has comfort wearing, breathing, anti-slip, anti-bacterial and cost-saving characteristics.Type: ApplicationFiled: January 28, 2011Publication date: October 27, 2011Applicant: SIX-VICTOR LTD.Inventor: Heng-Tai CHANG
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Publication number: 20110257284Abstract: The present invention describes a process for producing flame-retardant polyurethane foams. The process of the invention includes the use of hyperbranched, nitrogen-containing polymers for providing flame retardancy to polyurethane foams. The amounts used of the hyperbranched compounds are preferably from 5 to 20% by weight, based on the polyol component. The N content of preferred nitrogen-containing compounds is at least 2% by weight. The N content of the polyurethane foams of the invention is from 1 to 8% by weight from the hyperbranched polymer. Compounds in particular used are hyper-branched polyureas, hyperbranched polyamides, and in particular hyperbranched polylysines, hyperbranched polyisocyanurates, and hyperbranched polyesteramides. An advantage of the use of the compounds of the invention is that the polyurethane foams can be rendered flame-retardant without the use of, or by using markedly reduced amounts of, halogen-containing flame retardants.Type: ApplicationFiled: April 12, 2011Publication date: October 20, 2011Applicant: BASF SEInventors: Bernd BRUCHMANN, Daniel SCHONFELDER, Jens FERBITZ, Andrea EISENHARDT, Maxim PERETOLCHIN
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Patent number: 8030366Abstract: The invention relates to the use of polyethers containing urethane or urea groups as foam stabilizers, obtained by reacting at least one isocyanate with (a) at least one hydrophilic polyether which statistically carries at least one OH and/or NH2 and/or NH function and (b) at least one hydrophobic polyether which statistically carries at least one OH and/or NH2 and/or NH function and optionally (c) further compounds which carry at least one OH and/or NH2 and/or NH function and/or other isocyanate-reactive groups, such as carboxyl or epoxide functions, with the proviso that at least one isocyanate is ?difunctional.Type: GrantFiled: September 6, 2007Date of Patent: October 4, 2011Assignee: Evonik Goldschmidt GmbHInventors: Michael Ferenz, Christian Eilbracht, Jutta Esselborn, Sascha Herrwerth, Gabriele Platte
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Publication number: 20110224320Abstract: New branched or star-branched styrene polymeric, telomeric, and monomeric product distributions, their preparation, their use as raw materials for bromination to produce flame retardants, the flame retardants themselves, and their use as flame retardants in various polymeric substrates are described.Type: ApplicationFiled: November 30, 2009Publication date: September 15, 2011Applicant: ALBEMARLE CORPORATIONInventors: William J. Layman, JR., Charles H. Kolich, Arthur G. Mack, Jonathan P. McCarney, Govindarajulu Kumar, Junzuo Wang, Jorge Morice, Zhongxin Ge, Bo Liu, Ravindra R. Joshi, Hoover B. Chew, Douglas W. Luther, Kimberly M. White
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Publication number: 20110224321Abstract: The present invention provides a triblock copolymer and a viscoelastic biostable foam comprising the same.Type: ApplicationFiled: March 15, 2011Publication date: September 15, 2011Applicant: Vysera Biomedical LimitedInventors: Niall Behan, Ashutosh Kumar
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Patent number: 8017664Abstract: The invention relates to a process for the batch or semi-batch preparation of a polymer polyol, which process involves (1) preparing a seed by polymerizing in a base polyol at least one ethylenically unsaturated monomer in the presence of a polymerization initiator and macromer, and in the presence of from 0.5 to 50% wt of polymer polyol heel, based on amount of polymer present in the heel compared with total amount of polymer formed, (2) adding additional ethylenically unsaturated monomer to the seed obtained in step (1) and optionally additional polyol, and (3) polymerizing the mixture obtained in step (2).Type: GrantFiled: May 14, 2003Date of Patent: September 13, 2011Assignee: Shell Oil CompanyInventors: Bob Heinis, Willem Karzijn, Martien Krijger, Martinus Johannes Maria Lelieveld
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Publication number: 20110218258Abstract: The invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein a mixture of bi) from 25 to 70% by weight, based on the weight of the components bi), bii), biii) and biv), of a hydroxyl-comprising natural oil or fat or a reaction product of a hydroxyl-comprising natural oil or fat with alkylene oxides, bii) from 3 to 30% by weight, based on the weight of the components bi), bii), biii) and biv), of at least one polyether alcohol which has a hydroxyl number of from 100 to 800 mg KOH/g and a functionality of from 3 to 5 and is selected from the group consisting of polyether alcohols prepared by addition of alkylene oxides onto an amine, biii) 20-50% by weight, based on the weight of the components bi), bii), biii) and biv), of at least one polyether alcohol which has a hydroxyl number of from 10 to 80 mg KOH/g and a functionality of from 2 to 5 andType: ApplicationFiled: October 19, 2009Publication date: September 8, 2011Applicant: BASF SEInventors: Ansgar Frericks, Heinz-Dieter Lutter, Edmund Stadler, Heinz-Juergen Schroeder, Kirsten Simon, Andre Meyer, Franck Pomeris
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Publication number: 20110201712Abstract: Low density, flame-retardant polyurethane foams are prepared by reaction of a polyisocyanate with a branched organopolysiloxane prepared by reaction of a reactive hydrogen-functional organopolysiloxane with a polyisocyanate followed by reaction with an amine. Water is preferably used as a blowing agent in a one shot process.Type: ApplicationFiled: December 8, 2009Publication date: August 18, 2011Applicant: Wacker Chemie AGInventor: Jens Cremer
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Publication number: 20110201711Abstract: A bone defect filler for implantation in a bone defect of a patient includes a particulate polymer distributed within a polymeric binder. The particulate polymer includes a plurality of particles, which may have substantially the same material composition as the polymeric binder. The particles of the particulate polymer may be formed in a variety of shapes and/or sizes to provide the bone defect filler with improved pore interconnectivity, material expansion and contamination characteristics, while maintaining sufficient mechanical strength and handling characteristics for bone repair applications. The bone defect filler also provides the flexibility to be molded or shaped in situ to fill the bone defect.Type: ApplicationFiled: February 18, 2010Publication date: August 18, 2011Applicant: Doctors Research Group, Inc.Inventors: Richard J. Deslauriers, Eric Kolb, John Boxberger
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Publication number: 20110196329Abstract: Polyurethane gel foams are proposed as is their use in modern wound treatment. In particular, wound dressings comprise polyurethane gel foams for treating moderately to severely exuding wounds. The polyurethane gel foams are thereby produced from an isocyanate component A having a functionality f of fB?3, a polymeric polyol component B having a functionality f of fB?6, and a polysaccharide C, comprising at least one uronic acid or a salt thereof, wherein the ratio of the number of isocyanates groups of the isocyananate component A to the total number of hydroxyl groups, carboxy groups and carboxylate groups in the polymeric polyol component B and the polysaccharide C corresponds to the ratio 1:2 to 1:30.Type: ApplicationFiled: October 21, 2009Publication date: August 11, 2011Inventors: Axel Eckstein, Christian Schneider
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Publication number: 20110190405Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, a polystyrene/polyethylene oxide copolymer, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the blowing agent includes at least one hydrofluorocarbon blowing agent. The maleic anhydride-styrene copolymer grafted with polyethylene oxide provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid.Type: ApplicationFiled: January 29, 2010Publication date: August 4, 2011Inventors: Yadollah Delaviz, Raymond M. Breindel, Mitchell Z. Weekley, John F. Budinscak
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Publication number: 20110190406Abstract: Polyurethane foams are prepared from polyester polyols obtained by reaction of diols with a mixture of diacids derived from a mixture of dinitrile compounds obtained as by-products in the manufacture of adiponitrile by hydrocyanation of butadiene.Type: ApplicationFiled: January 22, 2009Publication date: August 4, 2011Inventors: Jean-Claude Masteau, Edson Leme Rodrigues
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Patent number: 7985468Abstract: An earpiece of flexible foam construction which incorporates recycled pulverized polyurethane foam (RPPF). RPPF constituting 5% to 30% of the improved foam has been found to be useful. The novel and unique nature of RPPF allows for the replacement of a higher cost component with a lower cost component while maintaining or improving physical properties, such as sound attenuation, sound control, comfort and fit.Type: GrantFiled: July 30, 2008Date of Patent: July 26, 2011Assignee: Sperian Hearing Protection, LLCInventors: Stephen D. Gilder, Jim Tiemens, Larry Sanders
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Patent number: 7977397Abstract: The present invention relates to compositions comprising blends of alkenyl aromatic polymers such as styrenic polymers (i.e. PS and HIPS) and bio-based or biodegradable polymers (i.e. PLA, PGA, PHA, PBS, PCL) compatibilized with styrene-based copolymers (i.e. styrene-ethylene-butylene-styrene (SEBS) block copolymers, maleated SEBS, styrene-maleic anhydride (SMA) copolymer, styrene-methyl methacrylate (SMMA) copolymer) or a mixture of two or more styrene-based copolymers such as SEBS and SMA. These novel compositions can be extruded and thermoformed to produce very low density food service and consumer foam articles such as plates, hinged lid containers, trays, bowls, and egg cartons with good mechanical properties.Type: GrantFiled: March 14, 2008Date of Patent: July 12, 2011Assignee: Pactiv CorporationInventors: Yunwa Wilson Cheung, David V. Dobreski, Richard Turner, Mark Wheeler, Y. Paul Handa
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Publication number: 20110166244Abstract: The flexible, resilient polyurethane foam is prepared by reacting at least one polyisocyanate with one or more liquid compounds which have at least two isocyanate reactive groups and at least one of which contain one or more solid polymers stably dispersed therein in an amount of 2.5 to 35 parts per 100 parts of said liquid isocyanate reactive groups containing compounds. The wet compression set of the flexible polyurethane foam could be considerably reduced by including in said liquid isocyanate reactive groups containing compounds, per 100 parts thereof, (I) 50 to 80 parts of one or more polyoxyalkylene polyols having an oxyethylene unit content of at least 40 wt. %, a hydroxyl number of between 20 and 100, and a nominal functionality of 2 to 4; and (II) 20 to 50 parts of one or more further polyoxyalkylene polyols containing no oxyethylene units or having an oxyethylene unit content lower than 40 wt. %, and having a hydroxyl number of between 20 and 100 and a nominal functionality of 2 to 4.Type: ApplicationFiled: September 24, 2009Publication date: July 7, 2011Applicant: RECTICELInventors: Rudi Mortelmans, Koen Raman
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Patent number: 7947756Abstract: Process for making a slabstock, visco-elastic, flexible, polyurethane foam which process comprises reacting a polyisocyanate and a polyol at an index of 60-95 and using a blowing agent, wherein 5-50 and preferably 10-40% by weight of the polyol used is castor oil. The foams and a polyol composition are claimed as well.Type: GrantFiled: June 12, 2007Date of Patent: May 24, 2011Assignee: Huntsman International LLCInventors: Kris Andries, Johan Antoine Stefaan Macken
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Patent number: 7947755Abstract: The invention provides a polyurethane foam manufactured from a polyisocyanate and a polycarbonate polyol. Moreover, the invention provides a method of manufacturing the polyurethane foam manufactured from a polyisocyanate and a polycarbonate polyol, comprising mixing the polyisocyanate and polycarbonate polyol together and foaming same.Type: GrantFiled: February 25, 2009Date of Patent: May 24, 2011Assignee: Yukigaya Chemical Industry Co., Ltd.Inventors: Keisuke Nakamura, Masaaki Takagi
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Publication number: 20110034576Abstract: Preparation and use of polyurethane foams with the use of foam stabilizers of the general formula (I)Type: ApplicationFiled: December 15, 2008Publication date: February 10, 2011Inventors: Frauke Henning, Wilfried Knott, Oliver Thum, Carsten Schiller, Martin Glos, Annegret Terheiden
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Publication number: 20110034575Abstract: The invention relates to a polyether polyol composition for the preparation of polyurethane foams, comprising: (a) a polyether polyol having a hydroxyl functionality of 2, an OH number within a range of from 50 to 65 mg of KOH/g and a proportion of primary hydroxyl groups within a range of from 40 to 80%, based on the total number of primary and secondary hydroxyl groups, having a PO content of from 45 to 55% by weight and an EO content of from 40 to 55% by weight; (b) a dispersion of a polymer in a polyether polyol, wherein the OH number of the dispersion is within a range of from 10 to 30 mg of KOH/g and the polyether polyol has a hydroxyl functionality of 3, a proportion of primary hydroxyl groups within a range of from 70 to 90%, based on the total number of primary and secondary hydroxyl groups, a PO content of from 70 to 90% by weight and an EO content of from 10 to 30% by weight; (c) a polyether polyol having a hydroxyl functionality of 3, an OH number within a range of from 220 to 290 mg of KOH/g aType: ApplicationFiled: December 9, 2008Publication date: February 10, 2011Applicant: Bayer MaterialScience AGInventors: Sebastien Triouleyre, Sven Meyer-Ahrens, Alice Mosbach-Rosenberger
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Publication number: 20110023333Abstract: The present invention relates to a composite comprising an elastic polyurethane molding with compact surface and with cellular core and rubber, capable of production via introduction of a reaction mixture, obtainable via mixing of (a) organic polyisocyanates with (b) at least one compound having at least two reactive hydrogen atoms, (c) chain extenders and/or crosslinking agents, (d) blowing agents, (e) catalysts, (f) hyperbranched polymers, and (g) if appropriate, other auxiliaries and/or additives, into a mold, comprising rubber, and also to a process for production of these composite materials, and to the use of these composite materials as shoe soles.Type: ApplicationFiled: September 17, 2007Publication date: February 3, 2011Inventors: Markus Schutte, Udo Wendel, Bernd Bruchmann, Daniel Schonfelder, Sibylle Schops, Nils Mohmeyer
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Publication number: 20100298453Abstract: Embodiments of the present disclosure can include polyurethane or polyisocyanurate board stock foam having a biobased content of 7% or greater as measured by ASTM D6866. In addition, embodiments of the present disclosure relate to the use of renewable material for producing aromatic polyesters polyols and/or resins to generate foam products having biobased content.Type: ApplicationFiled: January 26, 2010Publication date: November 25, 2010Applicant: INVISTA NORTH AMERICA S.A R.L.Inventors: CARINA ARAULLO MCADAMS, Eugen Gnedin, Leon J. Garcia
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Publication number: 20100292357Abstract: The invention relates to a process for the targeted reorganization of polydimethylsiloxanes over sulphonic acid-containing cation exchange resins which have water contents of 8 to 25% by weight, and polydimethylsiloxanes thus prepared and the use thereof.Type: ApplicationFiled: September 22, 2008Publication date: November 18, 2010Applicant: EVONIK GOLDSCHMIDT GMBHInventors: Wilfried Knott, Martin Glos, Norbert Nilewski
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Patent number: 7825166Abstract: To provide a flexible polyurethane foam having good vibration characteristics and suitable particularly for a seat for an automobile. A flexible polyurethane foam obtained by reacting a high molecular weight polyoxyalkylene polyol or a polymer-dispersed polyol containing fine polymer particles in the high molecular weight polyoxyalkylene polyol, with a polyisocyanate compound, in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that an amino-modified silicone (F) having a silicon atom and a nitrogen atom in its molecule is used in an amount of from 0.00001 to 1 part by mass per 100 parts by mass of all active hydrogen compounds.Type: GrantFiled: November 26, 2007Date of Patent: November 2, 2010Assignee: Asahi Glass Company, LimitedInventors: Takayuki Sasaki, Takashi Ito, Yoshinori Toyota, Naohiro Kumagai
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Publication number: 20100261804Abstract: Disclosed is a polyol composition containing an aromatic polyester polyol having a hydroxyl number of 300-500 mgKOH/g and an average number of functional groups of 2.0-2.5, a medium-chain polyether polyol having a hydroxyl number of 100-250 mgKOH/g and an average number of functional groups of 2.0-4.0 and composed of a polyoxypropylene unit, and a long-chain polyether polyol having a hydroxyl number of 15-40 mgKOH/g, an average number of functional groups of 2.0-4.0 and an oxyethylene content of not more than 14% by weight and mainly composed of a polyoxypropylene unit.Type: ApplicationFiled: November 6, 2008Publication date: October 14, 2010Inventors: Kenji Yamanaka, Masayoshi Idomoto, Kouji Fukui, Masashi Obata, Katsumi Inaoka, Masaaki Shibata
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Patent number: 7795322Abstract: A prepolymer having an NCO content of less than 10%, based on the reaction of (a) diisocyanate with (b) polyether alcohol, the (b) polyether alcohol comprising (b1) and (b2) and/or (b3) with the following meanings for (b1), (b2) and (b3): (b1) polytetrahydrofuran having a molecular weight of from 1800 to 2100 g/mol and (b2) polyether alcohol having a molecular weight of from 500 to 7000 g/mol, based on ethylene oxide and/or propylene oxide, and/or (b3) polytetrahydrofuran having a molecular weight of from 800 to 1200 g/mol.Type: GrantFiled: March 8, 2006Date of Patent: September 14, 2010Assignee: BASF AktiengesellschaftInventors: Elke Marten, Elke Weigelt, Anand G. Huprikar, Michael Strauβ
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Patent number: 7776934Abstract: Foamable one-part polyurethane compositions contain a high functionality quasi-prepolymer and a hydrated salt. The foamable compositions are capable of expanding to 1000% or more of their original volume to form a low density, stable foam. The compositions are particularly useful as foam-in-place thermal or sound insulation materials, especially in vehicle applications.Type: GrantFiled: February 13, 2007Date of Patent: August 17, 2010Assignee: Dow Global Technologies Inc.Inventors: Huzeir Lekovic, Ali El-Khatib
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Publication number: 20100204353Abstract: Isocyanate reactive materials of natural origin having an average isocyanate reactive functionality of less than about 1.5 can be used to enhance polyurethane foams. For instance, use of such materials often results in more open foams than is obtained in the same formulation without the materials. The materials also help maximize the level of renewable resource materials used in foams, especially with viscoelastic foams. The invention includes a polyol composition comprising at least one natural oil isocyanate reactive material having an average isocyanate reactive functionality of less than 1.5 in an amount greater than that naturally present in any natural oil polyol in the composition. While it is preferred to include at least one natural oil polyol in the polyol composition, doing so is optional.Type: ApplicationFiled: September 4, 2008Publication date: August 12, 2010Applicant: Dow Global Technologies Inc.Inventor: Francois M. Casati
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Publication number: 20100190880Abstract: The present invention relates to a process for the production of a polyurethane molding having a density of 150 to 350 g/L, in which a) polyisocyanate prepolymers, obtainable from a polyisocyanate component (a-1), polyol (a-2), comprising polypropylene oxide, and chain extender (a-3), b) polyetherpolyols having a functionality greater than 2.0, c) polymer polyetherpolyols, d) chain extender, e) catalysts, f) blowing agent, comprising water, and, if appropriate, g) other assistants and/or additives are mixed with a reaction mixture and cured in a mold to give the polyurethane molding. The present invention furthermore relates to polyurethane moldings obtainable by a process according to the invention and to shoe soles comprising polyurethane moldings according to the invention.Type: ApplicationFiled: September 29, 2008Publication date: July 29, 2010Applicant: BASF SE.Inventors: Andre Kamm, Markus Schuette, Holger Haschke, Tony Spitilli
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Publication number: 20100190879Abstract: Compositions according to the invention comprise water, a polyurethane or poly(meth)acrylate having perfluoroalkyl groups and a special siloxane. The treatment of fiber materials, in particular of nonwovens made of polypropylene, leads to articles which have oil-, water- and alcohol-repellency properties and can be used in the medical sector.Type: ApplicationFiled: September 11, 2008Publication date: July 29, 2010Applicant: Huntsman Textile Effects (Germany) GmbHInventors: Simpert Ludemann, Rule Niederstadt, Jurgen Riedmann, Daniel Wilson
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Patent number: 7759403Abstract: To provide a flexible polyurethane foam having good vibration characteristics and suitable particularly for a seat for an automobile. A flexible polyurethane foam obtainable by reacting a polyol composition with a polyisocyanate compound in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that the polyol composition comprises a high molecular weight polyoxyalkylene polyol (A1) and a polymer-dispersed polyol (A2) containing fine polymer particles in the high molecular weight polyoxyalkylene polyol (A1), and at least part of the fine polymer particles contained in the polymer-dispersed polyol (A2) are fine polymer particles having silicon atoms.Type: GrantFiled: November 26, 2007Date of Patent: July 20, 2010Assignee: Asahi Glass Company, LimitedInventors: Takayuki Sasaki, Takashi Ito, Chitoshi Suzuki, Tomohiro Hayashi
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Patent number: 7750058Abstract: The present invention is directed to a process for preparing water-blown rigid polyurethane foams having at least an 80% closed-cell content which involves reacting a) at least one polyol mixture which is composed of (i) at least one polymer polyol; (ii) at least one polyol having a hydroxyl value within the range of from about 200 to about 800; and (iii) optionally, at least one polyol having a hydroxyl value within the range of from about 25 to about 115; with b) at least one polymeric isocyanate and/or a prepolymer thereof; in the presence of c) optionally, at least one catalyst; d) water; and e) optionally, at least one additive or auxiliary agent. The present invention is also directed to the closed-cell water blown rigid polyurethane foams produced by the process of the present invention. The invention is further directed to a polyurethane-foam forming mixture which is used to produce the water-blown rigid polyurethane foams of the present invention.Type: GrantFiled: September 30, 2008Date of Patent: July 6, 2010Assignee: Bayer MaterialScience LLCInventors: Karl W. Haider, Neil H. Nodelman, John P. Forsythe, Brian R. Suddaby
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Publication number: 20100160470Abstract: A flexible polyurethane foam having a density of <100 kg/m3 comprises a reaction product of a polyisocyanate composition and an isocyanate-reactive composition. The polyisocyanate composition comprises a polymeric MDI component and a monomeric MDI component comprising 2,4?-MDI that is present in the monomeric MDI in an amount >35 parts by weight of the 2,4?-MDI based on 100 parts by weight of the monomeric MDI. The isocyanate-reactive composition comprises a primary hydroxyl-terminated graft polyether polyol and a second polyol different from the primary hydroxyl-terminated graft polyether polyol. The primary hydroxyl-terminated graft polyether polyol comprises a carrier polyol and particles of co-polymerized styrene and acrylonitrile. The carrier polyol has a weight average molecular weight of ?3,500 g/mol.Type: ApplicationFiled: December 23, 2008Publication date: June 24, 2010Inventors: Theodore M. Smiecinski, Steven E. Wujcik
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Publication number: 20100160469Abstract: This invention relates to polymer polyols comprising the free-radical polymerization product of a base polyol, at least one ethylenically unsaturated monomer, and, optionally, a preformed stabilizer, in the presence of at least one free-radical polymerization initiator and at least one chain transfer agent, in which the base polyol is a natural oil. A process for preparing these polymer polyols is also described. The present invention also relates to a polyurethane foam prepared from these polymer polyols and to a process for the preparation of these polyurethane foams.Type: ApplicationFiled: December 23, 2008Publication date: June 24, 2010Inventors: Rick L. Adkins, Stanley L. Hager, Brian L. Neal, Jack R. Reese, Jiong England, Micah N. Moore
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Publication number: 20100151226Abstract: A textile having at least one adherent polyurethane backing, the backing being prepared from a polyurethane forming composition which comprises: (A) a polyisocyanate and (B) a mixture of a hydroxylated vegetable oil having a functionality of 1-4 and a blowing agent.Type: ApplicationFiled: May 26, 2006Publication date: June 17, 2010Inventors: Larry E. Mashburn, Thomas Edward Patterson, William H. Harrison
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Publication number: 20100113635Abstract: A polyurethane foam composition includes a polyol, a polyisocyanate, a catalyst, a foam stabilizer, a blowing agent and a fluorinated carbonate wherein the fluorinated carbonate is a compound represented by Formula 1: a compound represented by Formula 2: or a mixture thereof. Also disclosed is a polyurethane foam derived from the composition.Type: ApplicationFiled: August 24, 2009Publication date: May 6, 2010Applicant: SAMSUNG ELECTRONICS CO., LTDInventors: Sung Woo HWANG, Myung Dong CHO, Sang Ho PARK, Kwang Hee KIM
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Patent number: 7687548Abstract: Process for preparing a moulded elastomeric polyurethane material having an overall density of 200-1000 kg/m3, preferably of 200-500 kg/m3, and a compression load at 40% deflection of at least 25 kPa by reacting in a closed mould an isocyanate terminated prepolymer, having an NCO-value of 5-15% by weight and which is the reaction product of a polyisocyanate and a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 500-5000 and an oxyethylene content of 50-90% by weight, and water. The elastomer obtained is claimed as well.Type: GrantFiled: December 17, 2004Date of Patent: March 30, 2010Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Johan Indesteege
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Publication number: 20100068487Abstract: Formulation for cellular, foamed-polymer product based on polyvinyl chloride, comprising: a polyvinyl chloride homopolymer having a K-value of from 60 to 85 and a pH value of the aqueous extract ranging of from 8 to 12; at least one isocyanate selected from isomers and homologues of diphenylmethane-4,4?-diisocyanate and modified diphenylmethane-4,4-diisocyanate s and mixtures thereof; at least one anhydride selected from the group of succinic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, methyl-tetrahydrophthalic anhydride, 4-methyl-hexahydrophthalic anhydride, cyclohexane-1,2-dicarboxylic anhydride, methyl-endomethylene tetrahydrophthalic anhydride, dodecenyl succinic anhydride, trimellitic anhydride and mixtures thereof; at least a surfactant; at least a foaming agent.Type: ApplicationFiled: June 5, 2007Publication date: March 18, 2010Inventors: Leone Lauri, Sam Shehyee Ang, Jan Jerry Christian Stigsson, Raffaela Bressan
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Patent number: 7678840Abstract: This invention relates to reactive systems for the production of cavity filling polyurethane foams for NVH (noise vibration and harshness) application areas in which the system exhibits reduced isocyanate emissions. These foams comprises a polyisocyanate comprising a polymethylene poly(phenylisocyanate).Type: GrantFiled: November 28, 2006Date of Patent: March 16, 2010Assignee: Bayer MaterialScience LLCInventors: Jack W. Jenny, David A. Radovich
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Patent number: 7674853Abstract: Process for preparing a polyol comprising particulate material in dispersed form by reacting an MDI-based polyisocyanate and a polyol having an equivalent weight of up to 400 in a relative amount such that the number of NCO-groups is 70-100% of the number of OH-groups in said polyol having an equivalent weight of up to 400, the reaction being carried out in a polyol having an equivalent weight of 500 or more. The polyols are claimed as well.Type: GrantFiled: April 11, 2007Date of Patent: March 9, 2010Assignee: Huntsman International LLCInventors: Verhelst Gabriel Albert, Yu Jianming
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Publication number: 20100056659Abstract: This invention relates to fire-resistant, flexible, molded, medium density polyurethane foams. These foams typically have a density of from 10 to 30 pcf. The foams are the reaction product of a) at least one polyester polyol, b) at least one highly branched polyether polyol, c) at least one chain extender, d) a polymethylene poly(phenyl isocyanate), an isocyanate group containing prepolymer based on a polymethylene poly(phenyl isocyanate), or mixtures thereof, e) a solid flame retardant and f) water. This invention also relates to a process for preparing these polyurethane foams in open molds.Type: ApplicationFiled: August 29, 2008Publication date: March 4, 2010Inventors: James W. Rosthauser, Theodore S. Frick, Michael T. Wellman
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Patent number: 7670501Abstract: Microcellular polyurethane flexible foams having densities no greater than 0.3 g/cc which are suitable for use as lightweight shoe sole components are produced with carbon dioxide in an amount such that the polyurethane-forming mixture has a free rise density of from about 0.03 to about 0.3 g/cc. At least a portion of that carbon dioxide is dissolved as a gas into one or both of the reaction components. The amount of dissolved carbon dioxide must be such that the froth density of the isocyanate and/or isocyanate-reactive component(s) in which the carbon dioxide is dissolved will be from about 0.1 to about 0.8 g/cc. Additional carbon dioxide may be formed by the reaction of water and isocyanate during the polyurethane-forming reaction but the total amount of CO2 present should be controlled to ensure that the polyurethane-forming mixture has a free rise density of from about 0.03 to 0.3 g/cc.Type: GrantFiled: May 27, 2005Date of Patent: March 2, 2010Assignee: Bayer MaterialScience LLCInventors: Usama E. Younes, David M. Baily, Charles R. Carpenter
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Publication number: 20100036008Abstract: The present invention relates to a highly elastic flexible polyurethane foam obtainable by mixing a) polyisocyanate with b) at least one relatively high molecular weight compound having at least two reactive hydrogen atoms, c) hyperbranched polyester c1) of the AxBy type, where x is at least 1.1 and y is at least 2.1, and/or hyperbranched poly-carbonate c2), d) if appropriate, low molecular weight chain extender and/or crosslinker, e) catalyst, f) blowing agent and g) if appropriate other additives. The present invention further relates to a process for producing such a flexible polyurethane foam and the use of the flexible polyurethane foam of the invention for producing furniture, mattresses, orthopedic products, car seats and other upholstery in the automobile sector.Type: ApplicationFiled: December 6, 2007Publication date: February 11, 2010Applicant: BASF SEInventors: Bernd Bruchmann, Daniel Schoenfelder, Andrea Eisenhardt, Markus Schuette
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Publication number: 20100021513Abstract: The invention relates to a cellular substance, the method of preparation and uses thereof, in particular as an absorbent substance, and in particular for the manufacture of sponges and other products for household use. The cellular substance of the invention comprises a mixture of fibers of a hydrophilic polymer, and at least one elastomer, and has a cellular structure formed by cells whose size is between 0.2 ?m and 10 mm, at least 1% of the cells, by volume as compared to the total cell volume, having a size of between 0.2 ?m and 10 ?m. The invention has application, particularly, in the area of absorbent products.Type: ApplicationFiled: August 28, 2007Publication date: January 28, 2010Applicant: HUTCHINSONInventors: Nicolas Garois, Philippe Sonntag, Natacha Carniol
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Publication number: 20090313764Abstract: The present invention relates to springs made from compositions comprising rubber, foam formulated therewith and resulting bedding products such as foam mattress or toppers as well as other cushioning elements in a bedding or a seating product.Type: ApplicationFiled: June 22, 2007Publication date: December 24, 2009Applicant: Latexco NVInventor: Erik Deporte
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Patent number: 7625954Abstract: The invention relates to a process for producing flexible polyurethane foams, in particular molded flexible polyurethane foams, by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein at least one polyether alcohol bi) which has been prepared by means of a DMC catalyst and has a hydroxyl number in the range from 15 to 35 mg KOH/g, and ethylene oxide content in the range from 5 to 18% by weight, based on the total weight of the polyether alcohol and an end block of ethylene oxide and propylene oxide having an ethylene oxide content of from 25 to 75% by weight, based on the amount of alkylene oxide in the end block, is used as compound b) having at least two hydrogen atoms which are reactive toward isocyanate groups.Type: GrantFiled: September 20, 2005Date of Patent: December 1, 2009Assignee: BASF AktiengesellschaftInventors: Kathrin Harre, Raimund Ruppel, Berend Eling
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Publication number: 20090270523Abstract: The present invention relates to polyurethane foam-forming composition containing polysilsesquioxanes that provide high resilience flexible polyurethane molded foams having improved foam dimensional stability.Type: ApplicationFiled: April 23, 2008Publication date: October 29, 2009Inventors: Bright Dai, Lijun Feng, Paul Austin
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Patent number: 7601761Abstract: The present invention provides a rigid polyurethane foam made from the reaction product, at an isocyanate index of from about 90 to about 400, of a polyisocyanate, and a polyol component containing about 20 to about 80 wt. %, based on the weight of the polyol component, of a double metal cyanide (DMC)-catalyzed polyether polyol having a number average molecular weight of greater than about 1000 Daltons (Da), about 80 to about 20 wt. %, based on the weight of the polyol component, of a sucrose-based polyol having a functionality of from about 2.5 to about 6 and a molecular weight of from about 350 to less than about 1,000, and about 0 to about 40 wt. %, based on the weight of the polyol component, of a low molecular weight organic compound having a number average molecular weight of less than about 600 Da, in the presence of water, polyvinylchloride (PVC) particles having a diameter of from about 0.Type: GrantFiled: February 26, 2007Date of Patent: October 13, 2009Assignee: Bayer MaterialScience LLCInventors: Jan L. Clatty, Timothy R. Whelan, Susanne Whelan, legal representative, Michael T. Wellman, John W. Liddle, Marie W. Urick
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Patent number: 7601762Abstract: The present invention provides a rigid polyurethane foam comprising the reaction product, at an isocyanate index of from about 90 to about 400, of a polyisocyanate and a polyol component comprising, about 20 wt. % to about 80 wt. %, based on the weight of the polyol component, of a double metal cyanide (DMC)-catalyzed polyether polyol having a number average molecular weight of greater than about 1,000 Daltons (Da), about 80 wt. % to about 20 wt. %, based on the weight of the polyol component, of a sucrose-based polyol having a functionality of from about 2.5 to about 6 and a number average molecular weight of from about 350 Da to less than about 1,000 Da, and about 0 wt. % to about 40 wt. %, based on the weight of the polyol component, of a low molecular weight organic compound having a number average molecular weight of less than about 600 Da in the presence of water, polyvinylchloride (PVC) particles having a diameter of from about 0.Type: GrantFiled: July 27, 2007Date of Patent: October 13, 2009Assignee: Bayer MaterialScience LLCInventors: Jan L. Clatty, Michael T. Wellman, Michael A. Masciantonio
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Publication number: 20090247657Abstract: A polyurethane-modified polyisocyanurate (PU-PIR) foam exhibiting improved thermal stability is provided. The foam has incorporated therein a high molecular weight ammonium polyphosphate (APP). APP is employed as a partial or complete substitute for flame retardants conventionally employed in PU-PIR foams. The foams of the invention exhibit excellent and improved thermal stability characteristics as compared to foams to which no APP has been added.Type: ApplicationFiled: April 1, 2008Publication date: October 1, 2009Applicant: Stepan CompanyInventors: Warren A. Kaplan, Angelo R. Gabbianelli, David J. Norberg
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Publication number: 20090248172Abstract: The invention relates to a membrane comprising a biocompatible block copolymer and has a porous structure with regularly distributed pores. A method for preparing said membranes is also provided.Type: ApplicationFiled: May 30, 2007Publication date: October 1, 2009Applicant: EIDGENOSSISCHE TECHNISCHE HOCHSCHULE ZURICHInventor: Peter Neuenschwander