Abstract: Disclosed is a method for making polystyrene foam which utilizes one or more atmospheric gases, particularly CO2, as the blowing agent in combination with a polymer processing aid (PPA), typically an ester that is relatively non-volatile at the extrusion temperature range. The blowing agent and the PPA may both be introduced into the molten thermoplastic polystyrene resin or the PPA may be incorporated in the solid source polystyrene resins. The resulting foam will be substantially free of residual blowing agent and dimensionally stable at ambient temperatures.

Abstract: The present invention provides a composition of which viscosity does not cause the problem of use at high temperature in the mounting process of electronic device. The present invention relates to a composition for electronic device comprising (a) a (meth)acrylic compound and (c) a particle having a functional group having metal scavenging functionality.

Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, activated carbon, and water are provided. The activated carbon acts as both a water absorbent and carrier for the water. The activated carbon is able to control and increase cell size even in the presence of carbon dioxide, HFCs, and/or infrared attenuating agents. Additionally, the activated carbon permits a desired amount of water to be introduced into the polymer melt. By controlling the amount of activated carbon and its water content during an extrusion process, a broad range of cell sizes can be obtained in the extruded product. In exemplary embodiments, the activated carbon is added to a primacy extruder and water is directly injected into a secondary extruder. Alternatively, the activated carbon is compounded with a polymer resin, pre-hydrated by conditioning or steam impregnation, and added to a primary or secondary extruder.

Abstract: The invention relates to elastic expanded polymer foams and also a process for producing expanded polymer foams by sintering a mixture comprising foam particles P1 and P2 composed of different thermoplastic polymers or polymer blends, wherein the foam particles P1 are obtained by prefoaming expandable, thermoplastic polymer particles comprising A) from 45 to 97.9 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin having a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin having a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a styrene-butadiene or styrene-isoprene block copolymer, C2) from 0.0 to 10 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, E) from 0 to 5 percent by weight of a nucleating agent, where the sum of A) to E) is 100% by weight.

Abstract: A method for forming a filter in a fluid flow path in a microfluidic device is provided. The method includes introducing a photopolymerization reaction solution into the microfluidic device; and performing polymerization of photopolymerization reaction solution to form a filter in the fluid flow path in a microfluidic device.

Abstract: An organic-inorganic composite molded product formed by molding a composite material of an organic resin and inorganic fine particles is provided, and in this molded product, the average primary particle diameter of the inorganic fine particles is 1 to 30 nm, the concentration of the inorganic fine particles is 25 to 50 percent by volume, and the porosity is 20 to 55 percent by volume. Accordingly, an organic-inorganic composite molded product having a small content of the inorganic fine particles and a significantly low average coefficient of linear expansion of 20*10?6 to ?110*10?6/degree Celsius can be manufactured.

Abstract: A blowing agent blend for making thermoplastic polymer foams includes methyl formate. The blowing agent blend can further comprise at least one co-blowing agent. The co-blowing agent is either a physical co-blowing agent (e.g. an inorganic agent, a hydrocarbon, a halogenated hydrocarbon, a hydrocarbon with polar, functional group(s), water or any combination thereof), or a chemical co-blowing agent, or combinations thereof. The thermoplastic polymer foam can be an alkenyl aromatic polymer foam, e.g. a polystyrene foam. The blowing agent blend includes methyl formate and one or more co-blowing agents. The methyl formate-based blowing agent blends produce dimensionally stable foams that have improved resistance to flame spread. A process for the preparation of such foams is also provided.

Abstract: Disclosed are compositions useful in a wide variety of applications, including heat transfer fluids which possess a highly desirable and unexpectedly superior combination of properties, and heat transfer systems and methods based on these fluids. The preferred heat transfer fluid comprises from about 1 to about 40 percent, on a weight basis, of carbon dioxide (CO2) and from about 99 to about 60 percent, on a weight basis, of a compound having the Formula I XCFzR3-z (I), where X is a C2 or a C3 unsaturated, substituted or unsubstituted, alkyl radical, each R is independently Cl, F, Br, I or H, and z is 1 to 3. A preferred compound of Formula I is tetrafluoropropene, particularly 1,1,1,3-tetrafluoropropene and/or 1,1,1,3-tetrafluoropropene.

Abstract: Crosslinked flame retardant thermoplastic elastomer gels are provided. The crosslinked flame retardant thermoplastic elastomer gels comprise a char catalyst, a char former, a maleic anhydride-modified styrene ethylene/butylene styrene polymer, and a softener oil. Methods are provided of making crosslinked flame retardant thermoplastic elastomer gels.

Abstract: Disclosed is a polymer foam with density in the range from 5 to 120 kg/m3 composed of a polymer component including at least one styrene polymer and from 0.1 to 5 parts by weight of a flame retardant mixture including at least one phosphorus compound of the formula PR1R2R3. A process for producing the polymer is also disclosed.

Abstract: The invention relates to a body, particularly a molded body made of polystyrene, particularly polystyrene particle foam or polystyrene hard foam, wherein the polystyrene, particularly the polystyrene particle foam or the polystyrene hard foam, comprises petroleum coke, particularly petroleum coke particles.

Abstract: A method of producing a foam product subjects a body of expanded closed-cell foam, in particular expanded polystyrene particle foam, to a non-melting heat treatment at a temperature above the glass transition temperature of the plastic used to form the foam, in particular polystyrene. The volume of the foam product is reduced by the heat treatment compared with the initial state prior to the heat treatment by a value from a range between a lower limit of 50% and an upper limit of 97%.

Abstract: The extensional viscosity of a styrenic resin is enhanced by increasing the Z+1 average molecular weight (Mz+1) of the resin. In one embodiment, an enhanced extensional viscosity resin is provided that has an Mz+1 molecular weight of at least approximately 745,000 and an extensional viscosity having a minimum value of approximately 360,000 Pascal-seconds (Pa-sec).

Abstract: A fiber comprises a composition including a poly(phenylene ether). The poly(phenylene ether) has less than or equal to 240 parts per million by weight of hydroxyl groups associated with ethylene bridge groups and less than or equal to 800 parts per million by weight of hydroxyl groups associated with rearranged backbone groups, both amounts based on the weight of the poly(phenylene ether). A method of spinning a fiber from the poly(phenylene ether) is disclosed. The fiber can be spun at a low denier.

Abstract: A blowing agent blend for making thermoplastic polymer foams includes methyl formate. The blowing agent blend can further comprise at least one co-blowing agent. The co-blowing agent is either a physical co-blowing agent (e.g. an inorganic agent, a hydrocarbon, a halogenated hydrocarbon, a hydrocarbon with polar, functional group(s), water or any combination thereof), or a chemical co-blowing agent, or combinations thereof. The thermoplastic polymer foam can be an alkenyl aromatic polymer foam, e.g. a polystyrene foam. The blowing agent blend includes methyl formate and one or more co-blowing agents. The methyl formate-based blowing agent blends produce dimensionally stable foams that have improved resistance to flame spread. A process for the preparation of such foams is also provided.

Abstract: The invention provides a new process for patterning TPE membranes for use in the design and fabrication of 3D microfluidic devices. The process involves patterning a TPE material without permitting the highest features of the mold to come into contact with the counter-plate, whereby adhesion between the TPE and the mold or counter-plate during demolding results directly in removal of the excess layer from the TPE membrane to produce well formed micrometric-sized open-through holes in the TPE membrane. The process permits rapid, reliable and efficient patterning of densely packed and arbitrarily placed micrometric open-through holes and channels of high aspect-ratio and any shape or wall profile in thin TPE membranes.

Abstract: The present invention relates to a monolithic organic copolymer prepared by copolymerization of at least one monomer of the group consisting of styrene, (C1-C3)alkylstyrene, (meth)acrylic acid and esters thereof with a crosslinker in the presence of a macroporogen and a microporogen, wherein a) the sum of said at least one monomer of the group and the crosslinker is 10-20%, preferably 10-15%, by volume of the reaction mixture, with the rest being essentially macroporogen and microporogen, and the degree of said copolymerization is at least 70%, preferably at least 90%, more preferably at least 99%, or b) the sum of said at least one monomer of the group and the crosslinker is 30-50%, preferably 35-45%, by volume of the reaction mixture, with the rest being essentially macroporogen and microporogen, and the degree of said copolymerization is in the range of 25-60%, preferably 35-50%.

Abstract: There is described a new disordered nanoporous crystalline form of syndiotactic polystyrene, characterized by a specific X-ray diffractrogram, the process for its preparation and various articles comprising this form of s-PS. This disordered nanoporous crystalline form exhibits empty crystalline cavities of nanometric sizes, and in this case performs the function of absorbing molecules with low molecular mass and is useful in particular as functionally active packaging for plant products.

Abstract: The present application relates to novel monodisperse, gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is a radical —(CH2)q—COOR3, R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2, q is an integer from 1 to 5 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.

Abstract: The present application relates to novel gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is —CH2—S—CH2COOR3 or —CH2—S—C1-C4-alkyl or —CH2—S—CH2CH(NH2)COOR3 or —CH2—S—CH2—CH(OH)—CH2(OH) or or derivatives thereof or —C?S(NH2), R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.

Abstract: The present invention relates to the preparation and use of a blowing agent in the form of of nanoparticles of an inorganic carbonate, and an acid. The acid is capable of being liquefied by heating to be reactive with the carbonate to release carbon dioxide that is useful as a blowing agent in all types of organic foams. The blowing agent, optionally pelletized in a suitable polymer carrier, is useful as a heat-activated blowing agent additive in polymer compositions.

Abstract: This invention relates to foam insulating products, particularly extruded polystyrene foam, with increasing the cell orientation and reducing cell anisotropic ratio, as well as the process method for making the products thereof for improving the insulating properties and for reducing the manufacturing cost of the foam products. Alternatively, foam insulating products having increased cell compressive strength may be made by decreasing the cell orientation and increasing the cell anisotropic ratio.

Abstract: Disclosed is a process of fabricating a cast foam product, an intermediate foam product, and a cast foam product. The process includes positioning an expandable component and alloying particles within a die and injecting steam into the die and expanding the expandable component to form an expanded component. The expandable component includes one or more of polystyrene and polymethylmethacrylate. The intermediate foam product includes the alloying particles, the expandable component, and the steam. The cast foam product includes a distribution of the alloying particles and the expanded component, with the alloying particles being physically bound by the expanded component.

Abstract: Despite the excellent properties associated with Magnesium OxyChloride (Sorel) based cements and Magnesium OxySulfate based cements, water and corrosion resistance has been limiting factors for achieving greater commercial applications. Such issues can be addressed by incorporating various alkali metal phosphates, such as Magnesium mono- or dihydrogen phosphate (MgHPO4 or MgH2PO4) with alkali metal fatty acids; such as Magnesium Stearate; and metal or alkali metal sulfates such as Aluminum Sulfate or Magnesium Sulfate. Water resistance is further enhanced by either pre-carbonating the mix water or the liquid magnesium chloride phase of the cements, or by adding a carbonate into the powder phase. Accelerated cure of this system has also been obtained by using various inorganic metal oxides. Additionally, improved corrosion resistance is achieved through the use of certain phosphates, zeolites, nitrites and other novel additives.

Abstract: Disclosed herein is a method of preparing a fused aerogel-polymer composite in which aerogel and an organic polymer is mixed in a dry state to adsorb polymer particles on the surface of the aerogel and are then subjected to thermal treatment, thus forming a polymer coating on the aerogel. The fused aerogel-polymer composite can be used for thermal insulation in a variety of applications. The fused aerogel-polymer composite exhibits high thermal insulation properties and superior physical strength and processability while still maintaining the properties of an aerogel that does not have a polymer coated on its surface.

Abstract: Biocomposite compositions and compositions, which include dried distillers solubles, and which can be used in making biocomposite compositions are described. Methods for preparing the compositions are also described.

Abstract: The present invention relates to an acrylamide-based mesoporous polymer and its preparation method, where the acrylamide-based mesoporous polymer is fabricated by a simple preparation method to have uniform minute pores controllable in pore size and thereby applicable to a wide variety of fields. The acrylamide-based mesoporous polymer includes at least one of a defined repeating unit and contains a plurality of pores having a diameter of 2.0 to 10.0 nm in the solid state.

Abstract: The present invention relates to a porous electrospun fiber with uniform minute pores and very large surface area, and thus porous electrospun fiber can be preferably applicable to various uses that need mesoporous materials, and a method of preparing the same. The porous electrospun fiber comprises an acrylamide-based polymer.

Abstract: Synthesis of polystyrene and/or other thermoplastic polymers or polymer blends which, for example, contain activated carbon and/or bamboo carbon carrying a co-blowing agent such as water and/or at least one of 1-dimensional, 2-dimensional, and 3-dimensional nano/micro-materials in suspension polymerization without using the inverse emulsion process. CO2 or other blowing agent based foaming processes such as extrusion, batch foaming, and injection molding may then be carried out to produce polymer foams that have low density, high-R value, bimodal structures, good mechanical properties, and high fire retardance.

Abstract: The invention provides a universal linker capable of synthesizing nucleic acid having a hydroxy group at the 3? terminal, a universal support carrying the linker, and a synthesis method of nucleic acid using the universal support.

Abstract: The invention provides a heat transfer composition comprising trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)), fluoroethane (R-161) and a third component selected from difluoromethane (R-32) and/or 1,1-difluoroethane (R-152a).

Abstract: The invention provides a heat transfer composition comprising: (i) trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)); (ii) a second component selected from difluoromethane (R-32), propene (R-1270)propane (R290) and mixtures thereof; (iii) a third component selected from pentafluoroethane (R-125), 1,1,1,2-tetrafluoroethane (R-134a), and mixtures thereof; and optionally (iv) a fourth component selected from fluoroethane (R-161), 1,1-difluoroethane (R-152a) and mixtures thereof.

Abstract: The invention provides a heat transfer composition consisting essentially of from about 60 to about 85% by weight of trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)) and from about 15 to about 40% by weight of fluoroethane (R-161). The invention also provides a heat transfer composition comprising R-1234ze(E), R-161 and 1,1,1,2-tetrafluoroethane (R-134a).

Abstract: Modified polystyrene-based resin particles comprising polyacrylic acid ester-based resin microparticles having an average particle diameter in the range of from 30 to 1,000 nm being dispersed in polystyrene-based resin particles, such that the polyacrylic acid ester-based resin microparticles are present (1) in the area ratio of from 0.1 to 15% in a surface area, which includes areas up to 20 ?m from the surface of each resin particle, and (2) present in the area ratio of from 11 to 50% in the inner area, which includes the area between the center of each resin particle and an point 30% of the radius from the center of each particle.

Abstract: The present invention relates to a method for producing a porous resin particle containing an aromatic vinyl compound-aromatic divinyl compound copolymer having a hydroxyl group, the method including: dissolving a monomer mixture containing an aromatic vinyl compound, an aromatic divinyl compound and a (meth)acrylic acid ester having one hydroxyl group within the molecule thereof, and a polymerization initiator in an organic solvent to obtain a solution containing the monomer mixture and the polymerization initiator; suspending the solution in water in the presence of a dispersion stabilizer; and performing a suspension copolymerization. The method of the invention is capable of easily producing a porous resin particle containing an aromatic vinyl compound-aromatic divinyl compound copolymer having a hydroxyl group, that is used as a support for solid phase synthesis and enables efficient nucleic acid synthesis.

Abstract: Compositions containing polymers and one or more heat labile and/or incompatible components adsorbed on carrier materials are provided. The heat labile components include materials that are inactivated, that volatilize, decompose, or undergo a chemical reaction or transformation at the polymer's processing temperatures (heat labile biocides). Incompatible components are materials that generally react or form gels or precipitates upon mixing. The carrier materials generally include inorganic or organic porous materials capable of remaining solid during processing temperatures. Methods for preparing the polymer compositions are provided.

Abstract: Prepare an extruded polymeric foam by extruding a foamable polymer composition through a foaming die and allowing the foamable polymer composition to expand into a polymer foam as it travels through and is constrained in its thickness dimension by at least two constraining sections, the first having opposing essentially parallel forming plates and the second constraining section having forming plates spaced further apart than the first constraining section.

Abstract: The present invention relates to a porous polymer and a synthetic method thereof. The porous polymer has the following general formula: wherein, the positions marked with the numeral 1-10 are C, CH, N, or CH with its H being substituted by methyl, ethyl, amido, carboxyl, methoxyl, hydroxyl, or ester group; the positions marked with letter a or b are C, N+, or B?.

Abstract: A substantially non-elastic incompressible composition, which substantially does not quickly self-level under standard operating conditions, includes: a suspending agent which reacts substantially as a solid when subjected to forces below a critical force, and which becomes substantially flowable when subjected to forces above said critical force; ceramic microparticulates dispersed within the suspending agent; flexible-walled microparticulates dispersed within the suspending agent; and celled macroparticulates dispersed within the suspending agent. The composition provides an incident energy absorbing property. The incident energy may include sound energy, and the microparticulates and macroparticulates may convert some of the sound energy into heat, or may diffract the sound energy.

Abstract: There is provided a shoe sole component that has properties such as strength and cushioning property that are suppressed from being changed even under a wide temperature range from severe cold at ?10° C. or lower to high temperature conditions exceeding 30° C. A shoe sole component includes a cross-linked foam of a resin composition, the resin composition containing a thermoplastic polyolefin resin, in which tan ? (?20° C. to 40° C.) at a frequency of 10 Hz measured according to JIS K 7244-4 is 0.01 to 0.5, and tan ? (?20° C.)/tan ? (40° C.) at a frequency of 10 Hz is 0.7 to 1.3.

Abstract: The invention provides a heat transfer composition comprising R-1234ze (E), R-32 and 1,1,1,2-tetrafluoroethane (R-134a).

Abstract: A foam composition is provided. An exemplary foam composition comprises a polymer of styrene, ethylene, and butylene. The exemplary foam composition further comprises additional agents that enhance the foam composition's stability during industrial laundering and usage. As characterized by a peak tangent ? value around 19 degrees Celsius and a specific gravity below 0.16 g/cc, the foam composition is impact-resistant, lightweight, and resistant to shrinkage. Examples of the foam composition may be incorporated into garments as part of impact-resistant athletic attire.

Abstract: An ester of a sugar and a brominated fatty acid is a useful FR additive for combustible polymers. The brominated FR additives unexpectedly are stable at the extrusion temperatures, and provide excellent flame retardancy to the combustible polymers.

Abstract: Alterations utilizing nanoparticles. Certain embodiments of the invention are methods of delivering a substance to a target using a delivery-aid which includes nanoparticles. Those nanoparticles may be nanocarbon particles. Other embodiments are methods of delivering nanoparticles to a target involving placing a mask between a source of ballistic delivery of nanoparticles and the target. Other embodiments include irradiating a target to cause localized heating of the region of the target in which the nanodiamonds or OLC particles are present. Other embodiments utilize nanoparticles to make cells competent for genetic transformation. This abstract is not to be considered limiting, since other embodiments may deviate from the features described in this abstract.

Abstract: An embodiment of the present invention relates to a composite material including a hydrophobic porous organic polymer bead. An embodiment further relates to a method of obtaining the composite material as well as the use thereof.

Abstract: Disclosed herein are a biomass composite composition and a foaming method thereof. The biomass composite composition includes (a) polyester alloy containing biodegradable polyester and petrochemical plastic, (b) reinforcing agent, (c) foaming agent, (d) compatibilizer, (e) lubricant, and (f) impact modifier. The biomass composite composition of the present invention is biodegradable and of heat resistance and melt strength suitable for manufacture of foam products.

Abstract: Various uses of fluoroalkenes, including tetrafluoropropenes, particularly (HFO-1234) in a variety of applications, including as blowing agents are disclosed.

Abstract: A porous polymer, poly-9,9?-spirobifluorene and its derivatives for storage of H2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO2/steam oxidation and supercritical water treatment.

Abstract: Disclosed are bowing agent compositions, foamable compositions, foams, foaming methods and/or foamed articles comprising one or more C2 to C6 fluoroalkenes, more preferably one or more C3 to C5 fluoroalkenes, and even more preferably one or more compounds having Formula I as follows: XCFzR3-z??(I) where X is a C1, C2, C3, C4, or C5 unsaturated, substituted or unsubstituted radical, each R is independently Cl, F, Br, I or H, and z is 1 to 3, it generally being preferred that the fluoroalkene of the present invention has at least four (4) halogen substituents, at least three of which are F and even more preferably none of which are Br.

Abstract: A thermoplastic elastomer (TPE) compound is disclosed which has very low hardness by virtue of the use of a combination of porous styrene block copolymer thermoplastic elastomer of a molecular weight greater than 200,000 and plasticizer oil of a molecular weight less than 400 present in an amount between 85 and 91 weight percent. Super-soft extruded or molded plastic articles can be formed from pellets of the compound, with a resulting Shore OOO Hardness of between 45 and 60. Molded articles can be prepared using hot melt adhesive dispensing units.