Process Of Treating Scrap Or Waste Product Containing Solid Organic Polymer To Recover A Solid Polymer Therefrom Patents (Class 521/40)
  • Publication number: 20110071230
    Abstract: Methods of reclaiming plastic from plastic medical waste containers containing medical waste and manufacturing recycled medical devices are described. Recycled medical devices made from plastic medical waste containers containing medical waste are also described.
    Type: Application
    Filed: September 18, 2009
    Publication date: March 24, 2011
    Applicant: Becton, Dickinson and Company
    Inventor: Richard Ji
  • Patent number: 7910688
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: October 22, 2008
    Date of Patent: March 22, 2011
    Assignee: Evonik Stockhausen Inc.
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 7902264
    Abstract: A composition comprising a polytrimethylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) contains at least one residue derived from the polyethylene terephthalate component. Methods for making such copolymers and articles made from such copolymers.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: March 8, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Michael Determan, Dhaval Shah
  • Patent number: 7902263
    Abstract: The invention relates to a process for making modified polybutylene terephthalate random copolymers from a polyethylene terephthalate component. In one embodiment, the invention relates to a two step process in which a 1,4-butane diol component reacts with a polyethylene terephthalate component under conditions that depolymerize the polyethylene terephthalate component into a molten mixture and the molten mixture is placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers.
    Type: Grant
    Filed: January 24, 2007
    Date of Patent: March 8, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Kristen Cohoon, Sandeep Dhawan, Robert Russell Gallucci, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Patent number: 7902262
    Abstract: The present invention relates to the recycling of waste electrical and electronic equipment (WEEE). Preferably, the present invention relates to the substantial recycling of all material forming the WEEE, thus providing substantially zero landfill. In yet another form, the invention relates to an additive and/or method of providing an additive. In still another form, the invention relates to recycling ink, toner, and/or PU foam from imaging consumables, forming part of the WEEE. In another form, the invention relates to the recycling of plastic materials containing flame retardants, including the recycling of plastics materials, such as plastics materials containing brominated flame retardants generally based on styrenics (e.g. PS, HIPS, ABS, PPO/PS, PPE/PS, ABS/PC) and polyamides (Nylon 6, nylon 6,6, nylon 12) and other engineering plastics such as polyacetal, polycarbonate, PET, PBT, liquid crystal polymers.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: March 8, 2011
    Assignee: Close the Loop Technologies Pty Ltd.
    Inventors: William Terence Armstrong, Stephen Michael Morriss, Glen Wilkie, John Scheirs
  • Patent number: 7897651
    Abstract: A method for rapidly depolymerizing a polyester and an unsaturated polyester by irradiating the polyester with microwaves in the presence of an alkylene glycol in which a titanium oxide fine powder having a bulk density of not more than 0.3 g/cm3 has been dispersed. Another embodiment comprises irradiating a polyester or an unsaturated polyester with microwaves in the presence of a monohydric alcohol or polyhydric alcohol containing an alkali metal and/or an alkaline earth metal. As a result, raw materials of a polyester, an unsaturated polyester or a polyurethane, such as an alkylene glycol and an unsaturated dibasic acid, can be recovered efficiently.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: March 1, 2011
    Inventor: Kazutoshi Ikenaga
  • Publication number: 20110046248
    Abstract: In a method and equipment for conditioning low-metal scrap high in plastics, which contains at least partially scrap high in plastics from shredder processes, especially of scrap vehicles, the method includes: splitting up ferromagnetic components from the scrap that is high in plastics; separating a first raw sand fraction from the scrap high in plastics that has been reduced in metals; reducing in size the fraction high in plastics that remains after the isolation of the first raw sand fraction; separating a second raw sand fraction after reducing in size the remaining fraction high in plastics; and splitting up the remaining fraction, that is high in plastics, into a light fraction and a heavy fraction. The equipment has the appropriate device for carrying out the individual method steps.
    Type: Application
    Filed: March 18, 2008
    Publication date: February 24, 2011
    Inventors: Bram den Dunnen, Michael Knust, Heiner Guschall
  • Patent number: 7893120
    Abstract: A pulverized thermoplastic resin product such as a pulverized thermoplastic product containing a black pigment, a mixture of a pulverized thermoplastic product containing a colored pigment and a pulverized thermoplastic product containing a colored pigment, or a pulverized thermoplastic product containing two or more different colored pigments can be converted into colored reclaimed resin particles by a method comprising the steps of mixing the pulverized resin product with a white pigment and a black pigment, melting the resulting mixture, and converting the molten mixture into solid particles. The colored reclaimed resin products can be utilized in various field.
    Type: Grant
    Filed: February 4, 2008
    Date of Patent: February 22, 2011
    Assignee: UBE Industries, Ltd.
    Inventors: Yoshiki Suzuki, Tatsushi Ako, Yukimasa Tanaka, Saburou Hinenoya, Yasuo Kita
  • Patent number: 7893122
    Abstract: The present invention relates to a process for chemical recycling of PET waste that comprises, among other stages, a saponification reaction stage, wherein PET waste particles are reacted with stoichiometric or excessive amounts of a strong base metal in an alcoholic reaction media, the reaction being brought to the boiling temperature of the alcoholic reaction media, preferably at atmospheric pressure, thereby obtaining as reaction products a salt of terephthalic acid with the base metal and ethylene glycol, the latter being incorporated to the alcoholic reaction media. From this reaction it is possible to afford ethylene glycol, terephthalic acid and salts thereof, which are products with a high commercial value.
    Type: Grant
    Filed: January 27, 2004
    Date of Patent: February 22, 2011
    Inventors: Arturo Guadalupe Fregoso-Infante, Roxana Vega-Rangel, Maricruz Figueroa-Gomez-Crespo
  • Patent number: 7893195
    Abstract: Method for recovering a polymer from a liquid medium (1) substantially containing the polymer and a solvent for the latter, wherein: (a) this liquid medium (1) is injected into a reactor (2) containing a stirred substantially monophase liquid mixture comprising a major fraction by weight of a non-solvent and a minor fraction by weight of a solvent, the mixture having a composition and temperature such that the polymer precipitates therefrom progressively; (b) the polymer is recovered in the form of particles in suspension (5) in a liquid rich in non-solvent; (c) the polymer particles (9) are separated from the liquid.
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: February 22, 2011
    Assignee: SOLVAY (Societe Anonyme)
    Inventors: Eric Fassiau, Bernard Vandenhende, Jean-Raphael Caille, Jean-Christophe Lepers
  • Publication number: 20110034570
    Abstract: The present invention provides, e.g., methods to recycle and/or reduce plastic, non-plastic, or a combination thereof, from a waste stream. The methods of the present invention include contacting the plastic waste with infrared (IR) energy at one or more frequencies and at one or more intensities, over a period of time effective to heat plastic present in the plastic waste.
    Type: Application
    Filed: September 20, 2010
    Publication date: February 10, 2011
    Inventors: Peter Anthony Smith, Adam J. Koffler, Philip Mark Smith
  • Patent number: 7884140
    Abstract: Techniques for creating recycled plastic materials from waste plastic materials are described. A recycled plastic material contains at least a primary polymer, a secondary polymer, and residual additives. Predetermined properties of the recycled plastic material can be controlled by selecting the types of waste plastic materials used in the recycling feed, determining the types and amounts of recycled plastic material recovered from a separation process and blending the recycled plastic material with other materials.
    Type: Grant
    Filed: April 14, 2003
    Date of Patent: February 8, 2011
    Assignee: MBA Polymers, Inc.
    Inventors: Brian L. Riise, Laurence E. Allen, III, Ron C. Rau, Michael B. Biddle
  • Patent number: 7868052
    Abstract: A recovered disc of a structure in which plural disc substrates are bonded together with an adhesive, is to be recycled. To this end, there is provided a recycling method for a recovered disc wherein a recovered disc, containing a material of at least one coating film, out of a reflective film, a recording film, a protective film and an ink film, deposited on a disc substrate in addition to an adhesive used for bonding a plurality of the disc substrates together, is used as a starting material for preparing a flame retardant resin composition or resin molded product.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: January 11, 2011
    Assignee: Sony Corporation
    Inventor: Yasuhito Inagaki
  • Patent number: 7855237
    Abstract: The method for the manufacture of foamed or foamable polymer particles employs a mixture of a polymer melt and a recycled polymer melt produced from recycled, propellant-containing polymer particles. The associated plant for the manufacture of the foamed or foamable polymer particles is provided with an apparatus for the processing of recycled, propellant-containing polymer particles.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: December 21, 2010
    Assignee: Sulzer Chemtech AG
    Inventor: Philip Nising
  • Patent number: 7855238
    Abstract: A molding composition comprising (a) from 5 to 90 wt % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) at least one residue derived from the polyethylene terephthalate component, and (b) from 5 to 40 wt % of a polyalkylene terephthalate component; wherein the modified polybutylene terephthalate random copolymer, the polyalkylene terephthalate component, and optionally, at least one additive, have a combined weight % of 100 wt %. Methods for making the composition and articles made from the composition.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: December 21, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Kristen Cohoon, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Publication number: 20100317752
    Abstract: A delinking composition in the form of a combined solid dose comprising: (i) one or more elastomer delinking accelerators selected from the group consisting of zinc salts of thiocarbamates and zinc salts of dialkyl dithiophosphates; and (ii) one or more elastomer delinking accelerators selected from the group consisting of 2-mercaptobenzothiazole or derivatives thereof, thiurams, guanidines, 4,4?-dithiomorpholine and sulpenamides; and (iii) at least one elastomer delinking activator.
    Type: Application
    Filed: August 21, 2006
    Publication date: December 16, 2010
    Applicant: ELASTOMER TECHNOLOGIES LTD
    Inventor: Tan Sri Dr. Balachandra Chakkinggal Sekhar
  • Patent number: 7851514
    Abstract: The invention provides a process for producing a recycled resin, which includes: a first step of decomposing a resin composition containing a thermosetting resin in a supercritical or subcritical solvent having a monomer constituting the thermosetting resin or a derivative thereof as an essential component and a second step of adding a polyfunctional compound thereto to process; a recycled resin or a processed and recovered matter obtained according to the process for producing; a recycled resin composition formed from a recycled resin and/or a processed and recovered matter of the resin composition; and a method for recycling a resin composition, which reuses said recycled resin and/or said processed and recovered matter of a resin composition as a raw material of a recycled resin composition.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: December 14, 2010
    Assignee: Sumitomo Bakelite Company, Ltd.
    Inventors: Junya Goto, Masaki Ishikawa, Kazunori Shimoyachi
  • Publication number: 20100311849
    Abstract: A process is provided for making a reactive-block-copolymer chain extender and for using the chain extender to couple polymer chains together for increasing the average molecular weight of the polymer chains. The chain extender can be reacted with polymeric materials that have functional groups and low molecular weight to couple polymer chains together and increase the average molecular weight, thereby increasing intrinsic viscosity and improving properties of the polymeric material. The chain extender is particularly useful for recycling polyethylene terephthalate (PET) and other polymers with functional groups and is also useful as a surface modifier and as a compatibilizer for polymeric materials that do not have reactive functional groups, such as polyethylene, polypropylene and polystyrene.
    Type: Application
    Filed: May 27, 2010
    Publication date: December 9, 2010
    Applicant: CID Centro de Investigacion y Desarrollo Tecnologico SA de CV
    Inventors: Alfonso González Montiel, Leticia Flores Santos, Pablo Esparza Hernández
  • Patent number: 7846985
    Abstract: Methods and systems for processing waste materials and for manufacturing composite materials are disclosed herein. According to some embodiments, the heterogeneous waste includes a plastic component and a non-plastic component, and the non-plastic component includes a plurality of pieces of waste. The heterogeneous waste is heated to melt at least a portion of said plastic component and reducing a volume of said heterogeneous waste, and then mixed (e.g. by rotating a mixing chamber or by stirring) until at least some said pieces are each encapsulated by the melted plastic component. Upon cooling, the mixture optionally sets into a composite material. The presently disclosed invention does not require pre-sorting of the heterogeneous waste and is operative to process “as is” waste. Optionally, the waste is pre-sorted.
    Type: Grant
    Filed: September 28, 2005
    Date of Patent: December 7, 2010
    Assignee: Yuval Tamir
    Inventors: Amit Azulay, Yuval Tamir
  • Patent number: 7846225
    Abstract: The present invention provides a process which utilizes biodiesel and other high boiling esters containing short alkyl groups to produce liquid fuels from fluff. The fluff is added to a solvent having a predetermined cycle starting solvent volume. An energy source is introduced into the solvent for a predetermined time at a predetermined temperature and pressure to form a product. The energy source is removed and the product is cooled to a predetermined temperature to produce the fuel. The invention also encompasses the fuel formed by the process described.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: December 7, 2010
    Assignee: Recarbon Corp.
    Inventors: Howard Gonchar, Roman Bielski, Donald Keiper, Ken Battle
  • Patent number: 7846984
    Abstract: If an ultraviolet curing resin is colored by contamination by another substance, there have been issues regarding increased cost and the environmental burden of treating the waste solution due to an inability to recycle the resin as it is. The ultraviolet curing resin that is in a colored, uncured state is decolored in the present invention by irradiation of light having a wavelength in the vicinity of the maximum absorption wavelength of the coloring material, and then recycled. As a result, it is possible to reduce costs and contribute to the protection of the environment.
    Type: Grant
    Filed: April 11, 2005
    Date of Patent: December 7, 2010
    Assignee: Panasonic Corporation
    Inventors: Yukako Doi, Toshiyuki Aoyama
  • Patent number: 7846986
    Abstract: Process for recovering at least one polymer in solution in a solvent by precipitation by means of a non-solvent introduced gradually into the solution to form the precipitation medium, whereby: in the course of the introduction of the non-solvent into the precipitation medium, there is first a phase separation (into a continuous phase rich in solvent, in which the polymer is dissolved, and into a disperse phase, consisting of droplets rich in non-solvent) and then there is a phase inversion (the continuous phase then becoming the phase rich in non-solvent, and the disperse phase becoming the phase rich in solvent containing the dissolved polymer) the non-solvent is initially introduced into the precipitation medium in liquid form only and in a quantity (Q?) which is not zero but is less than the quantity (Q) required to bring about the phase inversion, and is subsequently introduced into the precipitation medium at least partly in vapour form.
    Type: Grant
    Filed: July 14, 2004
    Date of Patent: December 7, 2010
    Assignee: Solvay S.A.
    Inventors: Eric Fassiau, Denis Geets
  • Patent number: 7842106
    Abstract: The present invention provides an economic process which utilizes biodiesel and other high boiling esters containing short alkyl groups to produce liquid fuels from polymeric materials such as, for example, used tires. In a first embodiment, polymeric material is dissolved/suspended/dispersed in biodiesel upon heating to form a product containing between about 10% and about 35% by weight of polymeric material. At least some of the biodiesel is recovered and reused to dissolve/suspend/disperse additional polymeric material to form additional product. After a predetermined number of cycles, the accumulated product is used as a fuel. In a second embodiment, polymeric material is dissolved/suspended/dispersed upon heating in biodiesel to form a mixture containing between about 30% and about 90% by weight of the polymeric material to be used as heavy fuel oil to be burned as is or bulk refined. The present invention also encompasses the fuel formed by the processes described.
    Type: Grant
    Filed: July 30, 2007
    Date of Patent: November 30, 2010
    Assignee: Recarbon Corp.
    Inventors: Howard Gonchar, Roman Bielski, Ken Battle, Donald Keiper
  • Patent number: 7820728
    Abstract: The present invention pertains to carpet and methods of making and recycling carpet. In one aspect, the carpet includes: a primary backing which has a face and a back surface; a plurality of fibers attached to the primary backing and extending from the face of the primary backing and exposed at the back surface of the primary backing; an adhesive composition backing; and an optional secondary backing adjacent to the adhesive backing. The method of making carpet includes extrusion coating the adhesive composition onto the back surface of a primary backing to form the adhesive composition backing. The method of recycling carpet can recover one or more polymeric carpet components.
    Type: Grant
    Filed: November 13, 2007
    Date of Patent: October 26, 2010
    Assignee: Columbia Insurance Company
    Inventors: Jeffrey Wright, Kellie Ballew
  • Publication number: 20100268192
    Abstract: Medical tubing (T), such as a guidewire, a stent, a catheter or a hollow needle, made of a kinked rigid-rod polyarylene exhibiting a outstanding characteristics including high torqueability, high pushability and high flexibility and which can be easily thin-wall extruded under especially harsh conditions.
    Type: Application
    Filed: April 21, 2010
    Publication date: October 21, 2010
    Applicant: SOLVAY ADVANCED POLYMERS, L.L.C.
    Inventors: Mohammad Jamal EL-HIBRI, Brian BALENO, Nikica MALJKOVIC, Bianca Sadicoff SHEMPER, Jean-Baptiste BONNADIER, Daniel J. IRELAND, Henri N. J. MASSILLON
  • Patent number: 7812061
    Abstract: A method for manufacturing a recycled polycarbonate raw material for a flame retardant resin composition from discarded and/or recovered optical discs using a polycarbonate resin as a substrate material, and includes (a) a step to identify if 2,2-bis(4-hydroxyphenyl)propane as a divalent phenol of the polycarbonate resin raw material is polymerized as the sole raw material in the polycarbonate resin as the substrate material of the discarded and/or recovered optical discs and (b) a step to remove impurities by a chemical treatment by separating only the discarded and/or recovered optical discs, wherein the polycarbonate resin is identified as polymerized by using 2,2-bis(4-hydroxyphenyl)propane as the sole raw material.
    Type: Grant
    Filed: May 10, 2007
    Date of Patent: October 12, 2010
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Toshio Isozaki
  • Patent number: 7807117
    Abstract: The present invention addresses a problem with conventional techniques for recycling electrical equipment that have a hardened epoxy resin and electroconductive material where a catalyst is degraded to an extent that it can no longer be reused when water is present in a dissolving system. Moisture, when present in the dissolving system for treating electrical equipment including electroconductive material of aluminum, may react with aluminum to produce an aluminate compound which is transformed into aluminum oxide (alumina) under heating, which, in turn, may cause abnormal temperature rise to melt aluminum. This may be accompanied by formation of hydrogen which can cause danger of explosion. The present invention manages moisture content in a dissolving system by drying an object to be treated with a catalyst and a solvent prior to the dissolving treatment.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: October 5, 2010
    Assignee: Hitachi Industrial Equipment Systems Co., Ltd.
    Inventors: Kohei Sato, Tomohiro Kaizu
  • Patent number: 7807728
    Abstract: Disclosed is a method for recycling a recovered polycondensation polymer which comprises a process wherein a recovered polycondensation polymer is supplied in a molten state to a polymerizer having a porous plate, and then after ejecting the polycondensation polymer through pores of the porous plate, the polymerization degree of the polycondensation polymer is increased under a reduced pressure or in a reduced inert gas atmosphere while dropping the polycondensation polymer along a supporting body.
    Type: Grant
    Filed: December 19, 2005
    Date of Patent: October 5, 2010
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Hiroshi Yokoyama, Muneaki Aminaka, Ken Someya
  • Patent number: 7807727
    Abstract: The invention relates to a method for selectively separating mixed synthetic organic materials such as filled or non-filled polymers and/or copolymers that are wastes, particularly used, for recycling in order to upgrade them. These synthetic organic materials result from the destruction by crushing of automobiles and durable consumer goods that have reached the end of their serviceable lives. Said selective separation method acts by separating these materials with regard to a density threshold selected in a dense medium consisting of separating fluid liquid suspensions composed of powdery particles dispersed in an aqueous phase. These suspensions are stabilized by using a dynamic stabilizing means at a density threshold value selected for causing the selective separation of a determined fraction from the mixture of the used materials to be separated.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: October 5, 2010
    Assignee: Galloo Plastics
    Inventors: Hugues De Feraudy, Henri Seinera
  • Publication number: 20100249253
    Abstract: Method for the recycling of polyvinyl butyral based on the obtaining of recycled polyvinyl butyral (PVB) from laminated glass which is then shattered and the polyvinyl butyral (PVB) is separated. The sheet obtained is cut into pieces, then proceeding to a surface cleaning process eliminating the dirt and foreign matter, which comprises: a first polyvinyl butyral (PVB) purification stage by way of a chemical treatment by means of a reagent; a subsequent final chemical treatment stage supplementary to the first stage by means of a reagent, the purification treatment being carried out on the polyvinyl butyral (PVB) in solid state and obtaining totally purified polyvinyl butyral read to be used again in the manufacture of laminated glass.
    Type: Application
    Filed: March 27, 2008
    Publication date: September 30, 2010
    Inventors: Claudio Fernandez Acevedo, Luis Martínez De Morentín Osaba, Edurne Osés Arteta, Germán Medina Herrera, Maria Antonia Fernández Fernández
  • Patent number: 7803848
    Abstract: The invention relates to a method for selectively separating synthetic organic materials such as polymers and/or reinforced or non-reinforced copolymers in the form of wastes, in particular domestic wastes recyclable in order to be reused. Said synthetic organic materials are recuperated from broken used cars and obsolete consumer durable products. The inventive method for selective separation consists in separating materials which have an identical density threshold value and are selected from a dense medium comprising separate liquid fluid suspensions which consist of powdery disperses particles in an aqueous phase and are stabilized with respect to the density threshold value selected in such a way that a selective separation of a determined fraction of the mixture of separable used material is initiated.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: September 28, 2010
    Assignee: Galloo Plastics
    Inventors: Hugues De Feraudy, Henri Seinera
  • Patent number: 7799837
    Abstract: There are provided a bottle which has a laminate structure including a glycolic acid polymer layer showing good gas-barrier property in addition to a principal resin layer and is yet provided with excellent recyclability, and also an efficient method of recycling the bottle. More specifically, a bottle having a laminate structure including at least one layer of glycolic acid polymer in addition to a principal resin layer, is obtained. After breaking the bottle, the broken pieces are washed with alkaline water, water or acidic water to remove the glycolic acid polymer layer, thereby recovering the principal resin.
    Type: Grant
    Filed: September 16, 2008
    Date of Patent: September 21, 2010
    Assignee: Kureha Corporation
    Inventors: Kazuyuki Yamane, Ryo Kato, Hiroyuki Sato
  • Patent number: 7799835
    Abstract: The present invention provides, e.g., methods to recycle and/or reduce plastic, non-plastic, or a combination thereof, from a waste stream. The methods of the present invention include contacting the plastic waste with infrared (IR) energy at one or more frequencies and at one or more intensities, over a period of time effective to heat plastic present in the plastic waste.
    Type: Grant
    Filed: March 4, 2004
    Date of Patent: September 21, 2010
    Assignee: Next-Tec, Ltd.
    Inventors: Peter Anthony Smith, Adam J. Koffler, Philip Mark Smith
  • Patent number: 7799836
    Abstract: The invention relates to a process for making modified polybutylene terephthalate random copolymers from a polyethylene terephthalate component. The invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butanediol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from the process.
    Type: Grant
    Filed: January 24, 2007
    Date of Patent: September 21, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Kristen Cohoon, Sandeep Dhawan, Robert Russell Gallucci, Ganesh Kannan, Kenneth Frederick Miller, Deepak Ramaraju, Gomatam Raghavan Ravi, Dhaval Shah
  • Patent number: 7799838
    Abstract: A composition comprising: (1) from 50 to 99 wt % of a modified, random copolyetherester containing: (i) a modified, random polybutylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and combinations thereof; and that contains at least one residue derived from the polyethylene terephthalate component; and (ii) a polyalkylene oxide copolymer block that is derived from a polyethylene terephthalate component and polyalkylene oxide glycol, and contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component; and (2) from 1 to 50 wt % of a polyester; wherein the copolyetherester, the polyester, and optionally any additives, are present in a total amount of 100 wt %.
    Type: Grant
    Filed: July 23, 2007
    Date of Patent: September 21, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Peter H. Vollenberg, Dhaval Shah, Kenneth F. Miller
  • Patent number: 7795319
    Abstract: A process for making a carbonous residue from scrap tires is disclosed. Tires are digested in an oil product. Steel and glass fibers are separated. A product enhancing additive comprising halogen based organic or inorganic compounds is added. The resulting carbonaceous material is then cured to create the final product. The produced carbonous residue is well suited for capture of mercury. The present invention has the benefits of providing a use for scrap tires that would otherwise require disposal in a landfill, and also produces a product useful for capturing a harmful element, thereby providing multiple environmental and economic benefits.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: September 14, 2010
    Assignee: Senergy LLC
    Inventors: Alfred G. Comolli, David L. Tanner
  • Patent number: 7795320
    Abstract: The invention relates to a composition comprising a modified, random copolyetherester containing a modified, random polybutylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and combinations thereof; and contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that is derived from a polyethylene terephthalate component and polyalkylene oxide glycol, and contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: September 14, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Michael Determan, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Patent number: 7795329
    Abstract: Modular plastic structural composites having a web section disposed along a horizontal axis and at least one flange section disposed along a horizontal axis parallel thereto and integrally molded to engage the top or bottom surface of the web section, wherein said composite is formed from a mixture of (A) high density polyolefin and (B) a thermoplastic-coated fiber material, polystyrene, or a combination thereof. Composites molded in the form of I-Beams and bridges constructed therefrom are also disclosed.
    Type: Grant
    Filed: July 21, 2003
    Date of Patent: September 14, 2010
    Assignee: Rutgers, the State University of New Jersey
    Inventors: Thomas Nosker, Richard Renfree, Maryann Renfree, legal representative, James Kerstein, Louis Simon
  • Patent number: 7790777
    Abstract: Process for recovering at least one polymer in solution in a solvent by precipitation by means of a non-solvent fluid, whereby the precipitation takes place in a precipitation medium comprising two dispersants of which one [dispersant(I)] has a greater affinity for the non-solvent and the other [dispersant (II)] has a greater affinity for the solvent.
    Type: Grant
    Filed: July 14, 2004
    Date of Patent: September 7, 2010
    Assignee: Solvay S.A.
    Inventors: Eric Fassiau, Denis Geets
  • Publication number: 20100216902
    Abstract: The invention relates to a method for the pretreatment, reprocessing or recycling of thermoplastic material, wherein the plastic material to be treated is heated in at least one receptacle or reactor while undergoing constant mixing or movement and/or comminution at a temperature below the melting temperature of the plastic material, and as a result is at the same time crystallized, dried and/or purified, wherein at least one rotatable comminuting or mixing tool, with working edges that act on the material with a comminuting and/or mixing effect, is used for the mixing and/or heating of the plastic material, the heating taking place in particular by applying mechanical energy.
    Type: Application
    Filed: November 13, 2007
    Publication date: August 26, 2010
    Applicant: EREMA ENGINEERING RECYCLING MASCHINEN UND ANLAGEN GESELLSCHAFT M.B.H. FREINDORF UNTERFELDSTRASSE 3
    Inventors: Gerhard Wendelin, Klaus Feichtinger, Manfred Hackl
  • Patent number: 7772293
    Abstract: An improved process for the hydrolysis of nylon polymer is herein disclosed using ionic liquids and optionally one equivalent of sulfuric acid per amide residue of the polymer. The process provides for a simplified means for separation of the hydrolyzed polyamide constituent monomers.
    Type: Grant
    Filed: July 30, 2008
    Date of Patent: August 10, 2010
    Assignee: Invista North America S.A.R.L.
    Inventors: Keith Whiston, Stewart Forsyth, Kenneth R. Seddon
  • Patent number: 7750057
    Abstract: There is provided a method for obtaining an aqueous solution of an alkali metal salt of an aromatic dihydroxy compound by decomposing a waste aromatic polycarbonate by an alkali metal hydroxide aqueous solution. The method comprises (1) a dissolution step of dissolving a waste aromatic polycarbonate in a chlorinated hydrocarbon solvent, (2) a decomposition step of adding an alkali metal hydroxide aqueous solution to this solution to decompose the aromatic polycarbonate, (3) a re-dissolution step of adding water to this decomposed solution to dissolve a solid, (4) a two phase formation step of leaving the treated solution obtained in the step (3) to stand to form an organic solvent phase (organic phase) and an aqueous solution phase (aqueous phase), and (5) a separation/collection step of separating the aqueous phase from the organic solvent phase and collecting the aqueous phase.
    Type: Grant
    Filed: April 20, 2005
    Date of Patent: July 6, 2010
    Assignee: Teijin Chemicals, Ltd.
    Inventor: Kazuyoshi Ogasawara
  • Patent number: 7745503
    Abstract: The invention relates to the use of dialkyl carbonates as solvents for expanded polystyrene and to a new process for the recycling of expanded polystyrene. Said process comprises the volume reduction of expanded polystyrene by dissolution with a dialkyl carbonate, or a blend of dialkyl carbonates, the removal of the insoluble components by filtration, the selective precipitation of polystyrene with a non-solvent or a blend of non-solvents, the separation, drying and extrusion of the precipitated polystyrene. This process allows the recovery of pure polystyrene without altering its properties.
    Type: Grant
    Filed: August 31, 2004
    Date of Patent: June 29, 2010
    Assignee: Polimeri Europa S.p.A.
    Inventors: Marcello Notari, Franco Rivetti
  • Patent number: 7737191
    Abstract: A process and resulting product is provided in which vulcanized rubber crumb has selected chemical bonds broken and sulphur removal by biotreatment with hydrophobic bacteria, such as mycolic acid containing actinomycete bacteria of ‘mycolata’, without significant degradation of the hydrocarbon polymer. The products obtained from the use of these bacteria may be processed alone or in blends with virgin rubber and revulcanized to yield products of much higher quality than conventional reclaimed rubber materials.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: June 15, 2010
    Assignee: Recyclatech Group Limited
    Inventors: Nicholas Christofi, John Geoffrey, David Edward
  • Publication number: 20100144911
    Abstract: A method of depolymerizing formulated rubbers and polymer solids is described. The method utilizes a solvent at or above the solvent's critical pressure and critical temperature with a low ratio of solvent to the solid material. The resulting depolymerized material in either substantially solid or highly viscous liquid form can be repolymerized with the addition of more monomer.
    Type: Application
    Filed: November 24, 2009
    Publication date: June 10, 2010
    Inventors: William A. Farone, Tracy Palmer
  • Patent number: 7732503
    Abstract: The conventional techniques for recycling an electrical equipment including a hardened epoxy resin and electroconductive material has involved conventional problems that a catalyst is degraded to an extent that it can be no longer reused when a water is contained in a dissolving system. Moreover, moisture, when present in the dissolving system for treating an electrical equipment including an electroconductive material of aluminum, may react with aluminum to produce an aluminate compound which is transformed into aluminum oxide (alumina) under heating, which, in turn, may cause abnormal temperature rise to melt aluminum. This may be accompanied by formation of hydrogen which can cause danger of explosion. The present invention manages moisture content in the dissolving system by drying an object to be treated, a catalyst and a solvent prior to the dissolving treatment.
    Type: Grant
    Filed: February 26, 2008
    Date of Patent: June 8, 2010
    Assignee: Hitachi Industrial Equipment Systems Co., Ltd.
    Inventors: Kohei Sato, Tomohiro Kaizu
  • Patent number: 7728047
    Abstract: The invention relates to an enhanced process for the recycling of expanded polystyrene. Said process essentially comprises the reduction in volume of expanded polystyrene by means of dissolution in a solvent, separation of the insoluble components, selective precipitation of the polystyrene with an anti-solvent, separation, drying and extrusion of the precipitated polystyrene, recovery by distillation and recycling of the solvent. The process is characterized in that the anti-solvent is a butanol selected form n-butanol, iso-butanol or sec-butanol and the solvent is dimethyl carbonate, alone or in a mixture containing up to 25% by weight of butanol.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: June 1, 2010
    Assignee: Polimeri Europa S.p.A.
    Inventors: Marcello Notari, Franco Rivetti, Maurizio Ghirardini, Sergio Lombardini
  • Patent number: 7723460
    Abstract: It is possible to provide a shape-memory molded product having excellent shape-memory properties and recycling efficiency by using a shape-memory resin having a glass transition temperature (Tg) within the range of 40° C. to 200° C. and a dissociation temperature (Td) of a thermo-reversible reaction within the range of 50° C. to 300° C. and satisfying the relationship: Tg+10° C.?Td, wherein the resin is deformed at a temperature of Tg to less than Td, and cross-linked through a thermo-reversible reaction in which a covalent bond is formed by cooling and dissociated by heating.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: May 25, 2010
    Assignee: NEC Corporation
    Inventors: Midori Shimura, Kazuhiko Inoue, Masatoshi Iji
  • Patent number: 7713502
    Abstract: The invention relates to a process for recycling fuel cell components containing fluorine-containing and precious metal-containing constituents: in this process, the fluorine-containing constituents are separated off from the precious metal-containing constituents by treatment with a medium present in the supercritical state. Preference is given to using water as supercritical medium. After the fluorine-containing constituents have been separated off, the precious metal-containing residues can be recovered in a recycling process without harmful fluorine or hydrogen fluoride emissions. The fluorine-containing constituents can likewise be recovered. The process is used in the recovery of precious metals and/or fluorine-containing constituents from membrane fuel cells, electrolysis cells, batteries, sensors and other electrochemical devices.
    Type: Grant
    Filed: August 31, 2005
    Date of Patent: May 11, 2010
    Assignee: Umicore AG & Co. KG
    Inventors: Joachim Koehler, Ralf Zuber, Matthias Binder, Volker Baenisch, Marco Lopez
  • Publication number: 20100099781
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Application
    Filed: October 22, 2008
    Publication date: April 22, 2010
    Inventors: Gonglu TIAN, Scott J. Smith, Janet Pate-Linton