Treating Rubber (or Rubberlike Materials) Or Polymer Derived From A Monomer Having At Least Two Ethylenic Unsaturated Moieties Patents (Class 521/41)
  • Patent number: 8466205
    Abstract: The present invention pertains to carpet and methods of making and recycling carpet. In one aspect, the carpet includes: a primary backing which has a face and a back surface; a plurality of fibers attached to the primary backing and extending from the face of the primary backing and exposed at the back surface of the primary backing; an adhesive composition backing; and an optional secondary backing adjacent to the adhesive backing. The method of making carpet includes extrusion coating the adhesive composition onto the back surface of a primary backing to form the adhesive composition backing. The method of recycling carpet can recover one or more polymeric carpet components.
    Type: Grant
    Filed: October 4, 2010
    Date of Patent: June 18, 2013
    Assignee: Columbia Insurance Company
    Inventors: Jeffrey Wright, Kellie Ballew
  • Publication number: 20130150467
    Abstract: In a tire constituted with a thermoplastic material and a material different from the thermoplastic material, the thermoplastic material and the material different from the thermoplastic material are easily and efficiently separated. While a tire 10 formed of a thermoplastic material is being turned, heated air is ejected from a nozzle 46 of a heating apparatus 44, and the surface of a crown portion 16 is melted. An end portion of a cord 26 embedded in a helical arrangement, which is formed of a material different from the thermoplastic material, is extracted from the melted region, and is sequentially wound onto a reel 58.
    Type: Application
    Filed: August 12, 2011
    Publication date: June 13, 2013
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Yoshihide Kouno, Seiji Kon, Keiichi Hasegawa
  • Patent number: 8445553
    Abstract: Vulcanized rubber is devulcanized by contacting the vulcanized rubber with a terpentine liquid in a reaction mixture in the absence of an alkali metal.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: May 21, 2013
    Assignee: Green Source Energy, LLC
    Inventors: Liang-tseng Fan, Shahram Reza Shafie
  • Patent number: 8415402
    Abstract: A method for separating a polymer from carbon black in devulcanized rubber, the method comprising steps of inserting devulcanized rubber into a bath of a solvent, dissolving a polymer out of the devulcanized rubber and into a solution of the solvent and the polymer, removing the solution from the bath without disturbing an un-dissolved residue comprising carbon black, and recovering the un-dissolved residue.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: April 9, 2013
    Assignee: Rubreco Inc.
    Inventors: Brian Harrison, Hurdon Hooper, Ross Gilders, Leo Cheung, Matthew Ness
  • Patent number: 8394866
    Abstract: A method for preparing contaminated plastics ground into flakes, such as RPET or such polymers, having at least decontamination and SSP treatment steps, with at least one reactor, with heating to the process temperature taking place essentially outside the reactor. Also, a device for carrying out the method, and having at least one decontamination reactor and at least one SSP reactor, a device for heating plastic flakes to the process temperature being arranged upstream of the decontamination reactor. Also an SSP reactor having at least two individual reactors, and preferably between 3 and 7 individual reactors.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: March 12, 2013
    Assignee: Krones AG
    Inventors: Thomas Friedlaender, Thomas Rieckmann, Frank Marx
  • Patent number: 8394913
    Abstract: Method for producing polyphenylene ether, comprising preparing a polymerization solution of 10-25 parts by mass of a phenolic compound (M) and 75-90 parts by mass of an aromatic solvent (A) with the total of the compound and the solvent being 100 parts by mass, and 0.1-10 parts by mass of a catalyst (C) containing a metal salt; performing oxidative polymerization of the phenolic compound (M) by passing oxygen-containing gas through polymerization solution; stopping polymerization by mixing aqueous chelating agent solution into polymerization solution; subjecting a diphenoquinone compound produced as a by-product to quinone binding process or removal by reduction; and obtaining polyphenylene ether by separating aqueous phase through liquid-liquid separation. In the method for producing a polyphenylene ether, 0.001-0.004 part by weight of an ion catalyst (D) is added into the polymerization solution before the liquid-liquid separation.
    Type: Grant
    Filed: February 15, 2012
    Date of Patent: March 12, 2013
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Mutsumi Maeda, Hiroaki Furukawa
  • Patent number: 8383764
    Abstract: The invention relates to block polymers, for example, arborescent copolymer compounds, and to methods of making and purifying such compounds. In one embodiment, the invention relates to arborescent polymer compounds that contain one or more styrene polymeric blocks in combination with one or more isobutylene polymeric blocks. In another embodiment, the invention relates to methods for purifying arborescent polymer compounds that contain at least one styrene polymeric block in combination with at least one isobutylene polymeric block.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: February 26, 2013
    Assignee: The University of Akron
    Inventor: Judit E. Puskas
  • Publication number: 20130023595
    Abstract: There are disclosed a regenerated rubber, a method and apparatus for obtaining regenerated rubbers from vulcanized crumb rubber, such as rubber from scrap. The apparatus is a thermokinetic mixer having the particularity to have an air tight stationary chamber with inner non-uniform surface. The method comprises the steps of raising the speed of the rotor shaft in order to increase a temperature of a mixture made of vulcanized crumb rubber and a lubricant, such as oil, until a devulcanizing temperature is reached; and reducing the temperature of the mixture to a lower temperature during a second period of time. The method of the invention is environmentally friendly or “green”, since the regeneration method does not use chemicals, includes a shorter period of treatment at higher temperature avoiding the risks of rubber cracking and spontaneous combustion, and further allowing mass-production of regenerated rubber with lower energy consumption.
    Type: Application
    Filed: March 15, 2011
    Publication date: January 24, 2013
    Applicant: PHOENIX INNOVATION TECHNOLOGY INC.
    Inventors: Sylvain Martel, Stephen Murphy, Patrick Legault
  • Patent number: 8357726
    Abstract: A process for devulcanizing crosslinked elastomer particles comprising applying an alternating radio frequency dielectric field to a composition comprising crosslinked elastomer particles. The alternating radio frequency dielectric field preferably has a frequency between 1 and 100 MHz and a voltage between 1000 and 10,000 V.
    Type: Grant
    Filed: January 20, 2010
    Date of Patent: January 22, 2013
    Assignee: Vertex L.L.C.
    Inventor: Michel Marc
  • Patent number: 8349285
    Abstract: The invention relates a pyrolytic carbon black produced from pyrolyzed rubber, the pyrolytic carbon black having an ash content ranging between 9-15%, a toluene discoloration at 425 mu of between 80-90% transmission, an iodine adsorption between 30 and 45 mg/g; and, an n-dibutyl phthalate absorption number of or to 65 cc/100 gm.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: January 8, 2013
    Assignee: Raymond Chabot Inc.
    Inventors: Andrew D. E. MacIntosh, Vincent W. Y. Wong
  • Patent number: 8344036
    Abstract: A method of processing polymer materials, highly filled or otherwise to recover cyclic structures or monomers. The method involves providing a vessel having a heated side wall, an agitator, and at least one of an additional heated structure, other than the heated side wall, within the vessel and means for forming a thin coat of material processed in the vessel on said heated side wall. A polymer material is fed into the vessel and heated to a sufficient temperature to cause depolymerization of the polymer material into cyclic structures or monomers. The cyclic structures or monomers are removed from the vessel and collected. The method does not require the use of a solvent.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: January 1, 2013
    Assignee: Heritage Environmental Services, LLC
    Inventors: Perry Eyster, James Bratina, Thomas Roberts, Christian Peregrine
  • Patent number: 8344035
    Abstract: A process for making a carbonaceous material and a carbonous residue from scrap tires is disclosed. Tires are digested in an oil product. Steel and glass fibers are separated. A product enhancing additive comprising halogen based organic or inorganic compounds is added. The resulting carbonaceous material is then cured to create the final product. The produced carbonous residue is well suited for capture of mercury. The present invention has the benefits of providing a use for scrap tires that would otherwise require disposal in a landfill, and also produces a product useful for capturing a harmful element, thereby providing multiple environmental and economic benefits.
    Type: Grant
    Filed: September 13, 2010
    Date of Patent: January 1, 2013
    Assignee: Senergy LLC
    Inventors: Alfred G. Comolli, David L. Tanner
  • Patent number: 8334325
    Abstract: The present invention relates to a method for preferentially breaking cross-links in a vulcanised rubber, thereby de-vulcanising the rubber, by the use of a supercritical fluid, such as carbon dioxide. The supercritical fluid maintained at an appropriate solubility parameter, swells the vulcanised rubber to a state of equilibrium swell. The cross links (3) become fully extended and under strain to hold the internal pressures caused by the solvent swelling affect of the supercritical gas. When equilibrium swell has been achieved, the pressure within the processing vessel is rapidly dropped to a level of not less than 60% of the level at which saturation took place, causing a degassing and expansion of the supercritical fluid that has been absorbed within the vulcanised rubber. The resulting three dimensional separation of the rubber molecules will put a further rapid strain on the cross links, causing them to break (7), thereby giving the affect of de-vulcanization.
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: December 18, 2012
    Assignee: Rubber-Regen LLP
    Inventors: Michiel Jan Dees, Philip James Hough
  • Patent number: 8318895
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: August 2, 2012
    Date of Patent: November 27, 2012
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 8309682
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: November 13, 2012
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 8304458
    Abstract: A method of reclaiming a cured elastomer material in the form of crumb or chips, comprising mixing the elastomer material with a devulcanization-aiding chemical composition and performing devulcanization by applying a shear-stress deformation while performing a mechanical disintegration into fine-ground crumbs under a controllable temperature not exceeding about 90 degrees C.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: November 6, 2012
    Assignee: Innovert Investments A.L. Ltd
    Inventor: Lev Beirakh
  • Patent number: 8304460
    Abstract: The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 ?m or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 ?m in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials.
    Type: Grant
    Filed: June 17, 2009
    Date of Patent: November 6, 2012
    Assignee: Rohm and Haas Company
    Inventors: Willie Lau, Donald C. Schall, Harry R. Heulings, IV, Kimberly B. Kosto, Joseph M. Rokowski
  • Patent number: 8304459
    Abstract: The present invention relates to a method for preferentially breaking cross-links in a vulcanized rubber, thereby de-vulcanizing the rubber, by the use of a supercritical fluid, such as carbon dioxide. The supercritical fluid maintained at an appropriate solubility parameter, swells the vulcanized rubber to a state of equilibrium swell. The cross links become fully extended and under strain to hold the internal pressures caused by the solvent swelling affect of the supercritical gas. When equilibrium swell has been achieved, the pressure within the processing vessel is rapidly dropped to a predetermined level causing a degassing and expansion of the supercritical fluid that has been absorbed within the vulcanized rubber. The resulting three dimensional separation of the rubber molecules will put a further rapid strain on the cross links, causing them to break, thereby giving the affect of de-vulcanization.
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: November 6, 2012
    Assignee: Rubber-Regen LLP
    Inventors: Philip J. Hough, Anthony N. Hough
  • Patent number: 8304463
    Abstract: A process for recovering waste latex material from a manufacturing plant, treating the recovered waste latex material, and subsequently utilizing the recovered and treated waste latex material in a manufacturing plant. Waste latex material is recovered and treated to provide a fine, sand-like material that is suitable for reintroduction into a latex adhesive manufacturing process.
    Type: Grant
    Filed: April 26, 2010
    Date of Patent: November 6, 2012
    Assignee: C & H Services of North Georgia, LLC
    Inventor: James Craig Hankins
  • Patent number: 8304457
    Abstract: A method and device for reprocessing used plastic containers, especially PET bottles, by analyzing the degree of contamination of the plastic, determining the decontamination process parameters as a function of the degree of contamination found in the analyzing step, and conducting a controlled decontamination of the plastic according to the decontamination process parameters thus determined. With this method and this device, it is thus possible to perform the decontamination process step in a controlled manner, yielding a more economical reprocessing method.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: November 6, 2012
    Assignee: Krones AG
    Inventors: Thomas Friedlaender, Maren Hofferbert, Hans-Jurgen Straubinger
  • Publication number: 20120252910
    Abstract: Partial oxidation of crumb rubber derived from environmental hazardous waste tires yields surface treated crumb rubber and a gas condensate which are used as blending stocks for making rubberized concrete with substantially improved mechanical strength as compared to the conventional rubberized concrete. The chemically more active rubber surface becomes hydrophilic, so it interacts with the hydrophilic surface of surrounding cement matrix much stronger. The gas condensate co-produced in the partial oxidation reactor consists of mainly active sulfur oxides (R—SOx—R) and serves as an excellent bonding agent to further enhance the bonding strength between the partially oxidized rubber particles and the cement mixes. The mechanically improved rubberized concrete is more versatile than conventional rubberized concrete.
    Type: Application
    Filed: April 1, 2011
    Publication date: October 4, 2012
    Applicant: Chun Well Industry Co., Ltd.
    Inventors: Kuo-Ji Yen, Maw-Tien Lee, Liang-Hsign Chou, Jen-Ray Chang
  • Publication number: 20120184634
    Abstract: This invention proposes a method for thermal regeneration of waste rubber; add rough powder particle of waste rubber/environmental softener/powder material with weight ratio ranging among 100/8˜150/20˜1500 into mixing heater; first carry out oxygen-free heating and then divert into mixing cooler to cool below 100° C.; the discharge material is product; or set aside some or all powder material and then slowly add into mixing heater or/and add the same when the hot material has been diverted into mixing cooler; when the mixture has been cooled below 100° C., the discharged material is product; after initial mixing of the prepared material, directly divert the same into screw extruder and heat and get into mixing section; when the mixture has been cooled below 100° C.
    Type: Application
    Filed: September 30, 2010
    Publication date: July 19, 2012
    Inventors: Huihong Chen, Jiaqing Hu
  • Publication number: 20120178322
    Abstract: A coated fabric with a first fabric layer having a first surface and a second surface, wherein the first fabric layer is comprised of a first polymer, and a first coating layer that is disposed on at least a portion of the first surface of the first fabric layer, wherein the first coating layer is comprised of the first polymer is disclosed. Fabricating the coated fabric can comprise providing a fabric, and applying or bonding at least a portion of a polymeric layer onto at least a portion of a first surface. The coated fabrics can advantageously serve as a protective barrier against natural elements with a long service life. One of more coated fabrics can act as a barrier to prevent seepage of water into the ground and/or serve as a surface for printing and decoration. The present coated fabrics can also be tailored to specific applications.
    Type: Application
    Filed: March 26, 2010
    Publication date: July 12, 2012
    Inventors: Naresh R. Mehta, David A. Pettey, Jeffrey C. Flath
  • Patent number: 8202918
    Abstract: Methods and systems for processing waste materials and for manufacturing composite materials are disclosed herein. According to some embodiments, the heterogeneous waste includes a plastic component and a non-plastic component, and the non-plastic component includes a plurality of pieces of waste. The heterogeneous waste is heated to melt at least a portion of said plastic component and reducing a volume of said heterogeneous waste, and then mixed (e.g. by rotating a mixing chamber or by stirring) until at least some said pieces are each encapsulated by the melted plastic component. Upon cooling, the mixture optionally sets into a composite material. The presently disclosed invention does not require pre-sorting of the heterogeneous waste and is operative to process “as is” waste. Optionally, the waste is pre-sorted.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: June 19, 2012
    Inventors: Amit Azulay, Yuval Tamir
  • Patent number: 8188155
    Abstract: The present invention relates to a method for preferentially breaking cross-links in a vulcanized rubber, thereby de-vulcanizing the rubber, by the use of a supercritical fluid, such as carbon dioxide The supercritical fluid causes swelling of the said vulcanized rubber material, wherein the time of swelling is not more than 50% of the time required for full volume equilibrium swelling of the rubber in said supercritical fluid and the swelling is followed by a rapid reduction of the supercritical fluid pressure The cross links (3) become fully extended and under strain to hold the internal pressures caused by the solvent swelling affect of the supercritical gas When equilibrium swell has been achieved, the pressure within the processing vessel is rapidly dropped to a predetermined level causing a degassing and expansion of the supercritical fluid that has been absorbed within the vulcanized rubber The resulting three dimensional separation of the rubber molecules will put a further rapid strain on the cross l
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: May 29, 2012
    Assignee: Rubber-Regen LLP
    Inventors: Michiel Jan Dees, Philip James Hough
  • Patent number: 8168688
    Abstract: A process for making a solid component out of recycled paint sludge is provided. The process can include providing a paint sludge and providing a second material. Thereafter, the paint sludge and the second material are mixed to produce a paint sludge-second material mixture. The paint sludge-second material mixture is processed in order to produce a polymer containing precursor. The processing can include granulating or densifying the paint sludge-second material mixture. After the precursor has been produced, it can be placed within a molding machine and a solid component is molded. The molding machine can be an injection molding machine, an extrusion molding machine or a blow molding machine.
    Type: Grant
    Filed: March 6, 2009
    Date of Patent: May 1, 2012
    Inventors: Dan Chrzanowski, Brandon Chrzanowski
  • Patent number: 8153699
    Abstract: A surfacing composition made of recycled paint, which requires no priming, has a non-reflective “flat” appearance, and is partially composed of dried paint. The composition provides a useful application for used or excess household paint, which would otherwise require special methods of disposal and potentially create future toxic cleanup problems. The composition is made of granular dried paint and a water-based sealer, which can be spread on a surface to repair imperfections. The surface can then be finished, and no priming is required. Due to the composition's flat appearance, the patch does not display any characteristic sheen where the repair has been made. The composition provides a simple means of recycling paint, and provides a simple and inexpensive means of repairing imperfections in walls and other surfaces while saving the step of priming the patch before painting or repainting.
    Type: Grant
    Filed: April 13, 2009
    Date of Patent: April 10, 2012
    Inventor: Larry Allen Holloway
  • Publication number: 20120077889
    Abstract: A method for producing thermoplastic elastomer is disclosed and comprises the step of: blending a mixture including particles of vulcanized rubber material and a molten thermoplastic material such that the rubber material is subjected to mechanical shearing forces and the surfaces of the rubber particles undergo homolytic bond scission to form chains of free radicals which cross-link with the thermoplastic material. Apparatus for carrying out the method, elastomers produced by the method and articles produced from the elastomers are also disclosed.
    Type: Application
    Filed: September 28, 2010
    Publication date: March 29, 2012
    Inventor: Neal A. Evans
  • Publication number: 20120065280
    Abstract: A method and device for processing of polymeric waste which may be associated with elements such as non-polymeric material or metals. In a specific embodiment the method includes the steps of (1) loading preliminarily deformed waste into a reaction chamber, (2) applying an aggressive medium to the waste for a time sufficient to convert the one or more polymers to fragments, and separate one of more polymers from their associated elements, and (3) subjecting the products of step (2) to mechanical separation of the associated elements from the polymer fragments. The method and device is particularly useful for the processing of tires including preliminarily deformed tire segments or shredded tire waste.
    Type: Application
    Filed: May 3, 2010
    Publication date: March 15, 2012
    Applicant: VR TEK PTY LTD
    Inventors: Michael Vainer, Boris Rozenblit
  • Patent number: 8106103
    Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a color predetermined to be desirable for reprocessing into at least one of such useful articles.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: January 31, 2012
    Assignee: Advanced Environmental Recycling Technologies, Inc.
    Inventors: Joe G. Brooks, Christopher Lynn Becker
  • Publication number: 20120004331
    Abstract: An automatic rubber powder plasticizing method which is used for recovery, processing and utilization of waste rubber, comprising the following steps: smash the waste rubber to powder in 10 meshes to 40 meshes, add some activator and softer according to certain weight ratio of rubber powder:activator:softener=1:0.3˜0.4%:8˜18%, evenly mix them, and then heat the mixture to 180˜320° C. and hold for 8˜15 min, afterwards, carry out desulfurization and plasticizing, then the plasticized rubber powder is obtained after cooling the resultant mixture. The invention also provides an apparatus for plasticizing which comprises a stirring unit (1), a feeding unit (2), a thermal reaction unit (3) and a cooling unit (4).
    Type: Application
    Filed: December 17, 2009
    Publication date: January 5, 2012
    Inventors: Rongbin Zhao, Guangfeng Li, Kuijiang Ji
  • Publication number: 20110269855
    Abstract: A process for devulcanizing crosslinked elastomer particles comprising applying an alternating electric field to a composition comprising crosslinked elastomer particles under compression. The alternating electric field preferably has a frequency between 1 and 100 MHz and a voltage between 1000 and 10,000 V, and may be applied between an apparatus that continuously conveys the particles through the field.
    Type: Application
    Filed: July 18, 2011
    Publication date: November 3, 2011
    Inventor: MICHEL MARC
  • Patent number: 7999012
    Abstract: Disclosed is a system to mechanically destroy printer toner cartridges and reclaim their constituent materials under a water shielded environment while providing a safer and more environmentally friendly recycling system. The present invention is an economical system that provides greater protection from possible fire or explosion and releases less irritating or possibly harmful airborne contamination than the currently available systems.
    Type: Grant
    Filed: October 20, 2008
    Date of Patent: August 16, 2011
    Inventors: Lacee Lamphere, Brian Ibarra, Donald Laffler, James Hardin
  • Patent number: 7985778
    Abstract: Synthetic resin containing ester bond is subjected to hydrolysis treatment to reclaim raw material component before polymerization. Method for decomposing and reclaiming synthetic resin having ester bond in composition structure thereof, by conducting hydrolysis treatment and then separation collection treatment. In the hydrolysis treatment, article containing synthetic resin to be decomposed and reclaimed is exposed to water vapor atmosphere filled under saturation water vapor pressure at treatment temperature at or below melting point of the synthetic resin. The synthetic resin in article to be treated is hydrolyzed by water vapor generated at the treatment temperature, to generate decomposition product before polymerizing to the synthetic resin containing an ester bond. The separation collection treatment is treatment in which the decomposition product generated by the hydrolysis treatment is separated into liquid component and solid component to be collected individually.
    Type: Grant
    Filed: March 6, 2007
    Date of Patent: July 26, 2011
    Inventor: Koichi Nakamura
  • Publication number: 20110178191
    Abstract: A process for devulcanizing crosslinked elastomer particles comprising applying an alternating radio frequency dielectric field to a composition comprising crosslinked elastomer particles. The alternating radio frequency dielectric field preferably has a frequency between 1 and 100 MHz and a voltage between 1000 and 10,000 V.
    Type: Application
    Filed: January 20, 2010
    Publication date: July 21, 2011
    Inventor: Michel Marc
  • Patent number: 7981940
    Abstract: Provided is a method of treating a sealing compound, in order to recover from the inside of a pneumatic tire the sealing compound that was used for repairing a puncture, the sealing compound including an aqueous solution having at least rubber latex dispersed therein, the method comprising: solid-liquid separating, by injecting a treating agent into the inside of a pneumatic tire into which the sealing compound was injected, the treating agent comprising at least one of a salt that is a reaction compound of an acid and a base and/or a water-soluble organic solvent, mixing the treating agent with the sealing compound inside the pneumatic tire, and aggregating and solidifying the rubber latex in the sealing compound.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: July 19, 2011
    Assignee: Bridgestone Corporation
    Inventors: Shinichi Iwasaki, Rieko Iwasaki, legal representative, Ryuji Izumoto, Daisuke Sugio
  • Patent number: 7959890
    Abstract: The invention relates to recycled rubber produced by a process comprising the steps of: a) shredding cleaned rubber tires into shreds less than 2? long; b) pyrolyzing the shreds in a reaction chamber of a thermal processor in a first anaerobic environment to produce a char; c) drawing off volatile organics from the reaction chamber; c) removing the char from the reaction chamber; d) cooling the char in a second anaerobic environment; e) removing metal and textile components from the char to obtain pyrolytic carbon black; f) milling and sizing the pyrolytic carbon black so obtained into particles of 325 mesh size or smaller; and, g) utilizing the pyrolytic carbon black from the previous step in a polymerization process that produces said recycled rubber. It also relates to the high quality pyrolytic carbon black recovered from this process.
    Type: Grant
    Filed: February 1, 2010
    Date of Patent: June 14, 2011
    Assignee: RIPP Resource Recovery Corporation
    Inventors: Andrew D. E. MacIntosh, Vincent W. Y. Wong
  • Patent number: 7947749
    Abstract: A system to recycle plastics, which enables a supply of recycled plastics having a stable quality required for the recycled products. A system to recycle a used plastic material as a resin material including (a) means to sort used plastic materials for the purpose of recycling said used plastic materials, (b) means to crush and melt said used plastic material after it has been sorted, (c) reviving means to regain a desired property, and (d) means to measure a physical property of a reclaimed plastic after it has been revived and to indicate said measured physical property for quality assurance.
    Type: Grant
    Filed: November 5, 2008
    Date of Patent: May 24, 2011
    Assignee: Sony Corporation
    Inventors: Daisuke Hasegawa, Yasuhito Inagaki, Haruo Watanabe, Masahiro Sawaguchi
  • Patent number: 7935737
    Abstract: Compositions of matter including articles derived from (a) from 5 to 99.99 wt % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate and (2) contains a at least one residue derived from polyethylene terephthalate selected from the group consisting of antimony, germanium, diethylene glycol groups, isophthalic acid groups, cis isomer of cyclohexane dimethanol, trans isomer of cyclohexane dimethanol, sodium benzoate, alkali salts, napthalane dicarboxylic acids, 1,3-propane diols, cobalt, cobalt-containing compounds, and combinations thereof, and (b) from 0.01 to 95 wt. % of a member selected from the group consisting of (1) fillers, (2) a carboxy reactive component, (3) polyethyelene terephthalate, (4) a component including a polycarbonate and an impact modifier. The articles may be derived from various conversion processes, e.g., injection molding processes, extrusion processes, thermoforming processes, melt-blown process.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: May 3, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Vikram Gopal, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Patent number: 7935736
    Abstract: The invention relates to a method for recycling polyesters or polyester mixtures from polyester-containing waste, in which the polyester or the polyester mixture is dissolved in a solvent and subsequently free-flowing particles are precipitated herefrom with a precipitant. The precipitant is thereby chosen such that subsequent separation of precipitant and solvent is made possible in a simple manner.
    Type: Grant
    Filed: April 13, 2005
    Date of Patent: May 3, 2011
    Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.
    Inventors: Andreas Mäurer, Udo Knauf, Gerd Wolz, Michael Frankl, Otto Beck
  • Patent number: 7910688
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: October 22, 2008
    Date of Patent: March 22, 2011
    Assignee: Evonik Stockhausen Inc.
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 7902264
    Abstract: A composition comprising a polytrimethylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) contains at least one residue derived from the polyethylene terephthalate component. Methods for making such copolymers and articles made from such copolymers.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: March 8, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Michael Determan, Dhaval Shah
  • Publication number: 20110054051
    Abstract: Processes for recovering natural rubber from an aqueous natural rubber latex that contains extractables and one or more additives and that is essentially free of lignocellulosic plant material are described. Natural rubber in the latex is separated from the water. Preferably, the amount of non-rubber extractables in the natural rubber is reduced by one or more extraction steps yielding a dried natural rubber.
    Type: Application
    Filed: April 14, 2009
    Publication date: March 3, 2011
    Inventors: William M. Cole, Georg G.A. Bohm, Walter Tomaszewski, Yingyi Huang
  • Patent number: 7893120
    Abstract: A pulverized thermoplastic resin product such as a pulverized thermoplastic product containing a black pigment, a mixture of a pulverized thermoplastic product containing a colored pigment and a pulverized thermoplastic product containing a colored pigment, or a pulverized thermoplastic product containing two or more different colored pigments can be converted into colored reclaimed resin particles by a method comprising the steps of mixing the pulverized resin product with a white pigment and a black pigment, melting the resulting mixture, and converting the molten mixture into solid particles. The colored reclaimed resin products can be utilized in various field.
    Type: Grant
    Filed: February 4, 2008
    Date of Patent: February 22, 2011
    Assignee: UBE Industries, Ltd.
    Inventors: Yoshiki Suzuki, Tatsushi Ako, Yukimasa Tanaka, Saburou Hinenoya, Yasuo Kita
  • Patent number: 7884140
    Abstract: Techniques for creating recycled plastic materials from waste plastic materials are described. A recycled plastic material contains at least a primary polymer, a secondary polymer, and residual additives. Predetermined properties of the recycled plastic material can be controlled by selecting the types of waste plastic materials used in the recycling feed, determining the types and amounts of recycled plastic material recovered from a separation process and blending the recycled plastic material with other materials.
    Type: Grant
    Filed: April 14, 2003
    Date of Patent: February 8, 2011
    Assignee: MBA Polymers, Inc.
    Inventors: Brian L. Riise, Laurence E. Allen, III, Ron C. Rau, Michael B. Biddle
  • Publication number: 20110015284
    Abstract: The present invention relates to a method for preferentially breaking cross-links in a vulcanized rubber, thereby de-vulcanizing the rubber, by the use of a supercritical fluid, such as carbon dioxide The supercritical fluid causes swelling of the said vulcanized rubber material, wherein the time of swelling is not more than 50% of the time required for full volume equilibrium swelling of the rubber in said supercritical fluid and the swelling is followed by a rapid reduction of the supercritical fluid pressure The cross links (3) become fully extended and under strain to hold the internal pressures caused by the solvent swelling affect of the supercritical gas When equilibrium swell has been achieved, the pressure within the processing vessel is rapidly dropped to a predetermined level causing a degassing and expansion of the supercritical fluid that has been absorbed within the vulcanized rubber The resulting three dimensional separation of the rubber molecules will put a further rapid strain on the cross l
    Type: Application
    Filed: August 12, 2008
    Publication date: January 20, 2011
    Applicants: DSM IP ASSETS B.V., RUBBER-REGEN LLP
    Inventors: Michiel Jan Dees, Philip James Hough
  • Patent number: 7846985
    Abstract: Methods and systems for processing waste materials and for manufacturing composite materials are disclosed herein. According to some embodiments, the heterogeneous waste includes a plastic component and a non-plastic component, and the non-plastic component includes a plurality of pieces of waste. The heterogeneous waste is heated to melt at least a portion of said plastic component and reducing a volume of said heterogeneous waste, and then mixed (e.g. by rotating a mixing chamber or by stirring) until at least some said pieces are each encapsulated by the melted plastic component. Upon cooling, the mixture optionally sets into a composite material. The presently disclosed invention does not require pre-sorting of the heterogeneous waste and is operative to process “as is” waste. Optionally, the waste is pre-sorted.
    Type: Grant
    Filed: September 28, 2005
    Date of Patent: December 7, 2010
    Assignee: Yuval Tamir
    Inventors: Amit Azulay, Yuval Tamir
  • Patent number: 7846225
    Abstract: The present invention provides a process which utilizes biodiesel and other high boiling esters containing short alkyl groups to produce liquid fuels from fluff. The fluff is added to a solvent having a predetermined cycle starting solvent volume. An energy source is introduced into the solvent for a predetermined time at a predetermined temperature and pressure to form a product. The energy source is removed and the product is cooled to a predetermined temperature to produce the fuel. The invention also encompasses the fuel formed by the process described.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: December 7, 2010
    Assignee: Recarbon Corp.
    Inventors: Howard Gonchar, Roman Bielski, Donald Keiper, Ken Battle
  • Patent number: 7842106
    Abstract: The present invention provides an economic process which utilizes biodiesel and other high boiling esters containing short alkyl groups to produce liquid fuels from polymeric materials such as, for example, used tires. In a first embodiment, polymeric material is dissolved/suspended/dispersed in biodiesel upon heating to form a product containing between about 10% and about 35% by weight of polymeric material. At least some of the biodiesel is recovered and reused to dissolve/suspend/disperse additional polymeric material to form additional product. After a predetermined number of cycles, the accumulated product is used as a fuel. In a second embodiment, polymeric material is dissolved/suspended/dispersed upon heating in biodiesel to form a mixture containing between about 30% and about 90% by weight of the polymeric material to be used as heavy fuel oil to be burned as is or bulk refined. The present invention also encompasses the fuel formed by the processes described.
    Type: Grant
    Filed: July 30, 2007
    Date of Patent: November 30, 2010
    Assignee: Recarbon Corp.
    Inventors: Howard Gonchar, Roman Bielski, Ken Battle, Donald Keiper
  • Patent number: 7807727
    Abstract: The invention relates to a method for selectively separating mixed synthetic organic materials such as filled or non-filled polymers and/or copolymers that are wastes, particularly used, for recycling in order to upgrade them. These synthetic organic materials result from the destruction by crushing of automobiles and durable consumer goods that have reached the end of their serviceable lives. Said selective separation method acts by separating these materials with regard to a density threshold selected in a dense medium consisting of separating fluid liquid suspensions composed of powdery particles dispersed in an aqueous phase. These suspensions are stabilized by using a dynamic stabilizing means at a density threshold value selected for causing the selective separation of a determined fraction from the mixture of the used materials to be separated.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: October 5, 2010
    Assignee: Galloo Plastics
    Inventors: Hugues De Feraudy, Henri Seinera