Solid Polymer Or Solid Polymer-forming System Is Encapsulated In Or Impregnated In A Nonreactant Material Patents (Class 523/207)
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Patent number: 5965636Abstract: The stability of colloidal metal oxide particles which have been encapsulated in a polymer resin is extended by the addition of a solution polymerized polyacrylamide polymer.Type: GrantFiled: August 4, 1998Date of Patent: October 12, 1999Assignee: Callaway CorporationInventor: John C. Lark
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Patent number: 5955516Abstract: Additives for polymeric compositions are prepared by coating pigment with a dispersant, and thereafter dispersing the dispersant-coated pigment in a liquid nonaqeous polymeric carrier. Preferably, the dispersant-coated pigment is spray-dried. That is, most preferably, an aqueous dispersion of the pigment and dispersant is subjected to a spray-drying operation so as to obtain pigment coated with the dispersant. The dispersant-coated pigment will have an average particle size of about 5 .mu.m or greater, but is capable of breaking apart to average particle sizes of about 1 .mu.m or less when dispersed in a polymeric host material.Type: GrantFiled: March 3, 1997Date of Patent: September 21, 1999Assignee: BASF CorporationInventors: Donald Caswell, Frank R. Jones, Stanley A. McIntosh, Gary W. Shore, G. Daniel Gasperson
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Patent number: 5939470Abstract: The invention addresses a method of preparing a dry polymer bead preparation. To achieve this, the polymer beads are coated with a layer of an easily soluble substance which dissolves again in a liquid when the polymer beads are resuspended. The resuspension is thus largely free of agglomerates.Type: GrantFiled: June 6, 1997Date of Patent: August 17, 1999Assignee: Boehringer Mannheim GmbHInventor: Herbert Harttig
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Patent number: 5922809Abstract: The present invention is a polyurethane prepolymer comprising the reaction product of: A) a polyisocyanate; B) one or more compounds or polymers having isocyanate-reactive moieties; C) a dispersion triol containing from about 10 to about 60 percent by weight based on the dispersion of particles of an organic polymer which is nonreactive with the polyols and polyisocyanates having a particle size of from about 5 to about 50 microns; wherein the prepolymer has a free isocyanate content of from about 0.8 to about 2.2 percent. In another embodiment the invention is a one-part adhesive composition comprising the polyurethane prepolymer of the invention and a catalyst capable of catalyzing the reaction of isocyanate moieties with water.Type: GrantFiled: January 11, 1996Date of Patent: July 13, 1999Assignee: The Dow Chemical CompanyInventors: Shailesh S. Bhat, Sidky D. Rizk
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Patent number: 5898043Abstract: The present invention provides a powder coating composition comprising a resin powder comprising a film-forming resin and a crosslinking agent capable of giving rise to a crosslinking reaction with the resin, wherein the resin powder has a volume-average particle diameter of 3-17 .mu.m and a shape factor (SF) of 100.5-160. This powder coating composition can form a coating film having luster and smoothness and can be applied in a thin film.Type: GrantFiled: June 29, 1997Date of Patent: April 27, 1999Assignee: Nippon Carbide Kogyo Kabushiki KaishaInventors: Masami Uemae, Noriyuki Tonami, Yukinori Nakazato, Hiroshi Serizawa
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Patent number: 5889088Abstract: A stable aqueous suspension of composite particles each including a core formed from a solid or liquid particle and a coating layer formed on the core particle and including at least one high molecular weight surfactant compound having an average molecular weight of 1100 or more and at least one low molecular weight surfactant compound having an average molecular weight of 1100 or less and at least 400 below the average molecular weight of the high molecular weight surfactant compound and optionally a suspension stabilizer, is produced by subjecting a particulate solid substance or a liquid substance to a suspending treatment in an aqueous medium containing the above-mentioned high and low molecular weight surfactant compounds, and optionally the suspension stabilizer.Type: GrantFiled: February 7, 1997Date of Patent: March 30, 1999Assignee: Hodogaya Chemical Co., Ltd.Inventors: Atsushi Kisuno, Tatsuo Ansai, Shihoko Aizawa
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Patent number: 5889089Abstract: Polymeric compositions include a nonaqueous additive system having dispersant-coated pigments physically dispersed in a liquid nonaqueous polymeric carrier which may be added directly to a melt flow of a polymeric host material. The additive system employed in the polymeric systsms is most preferably in the form of a particulate paste which can be added in metered amounts (dosed) to a melt flow of the polymeric host material prior to being spun into filaments. By providing a number of additive systems having a number of different additive attributes, and controllably dosing one or more into the melt flow of host polymeric material, shaped objects of the polymeric material (e.g., melt-spun filaments) having different additive attributes may be produced on a continuous basis without shutting down the shaping operation.Type: GrantFiled: March 3, 1997Date of Patent: March 30, 1999Assignee: BASF CorporationInventors: Donald Caswell, Frank R. Jones, Stanley A. McIntosh, Gary A. Shore, G. Daniel Gasperson
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Patent number: 5879805Abstract: A process for the preparation of a 1,2-vinyl-polybutadiene with an adjustable amount of vinyl linkages in the microstructure of the polymer which comprises polymerizing 1,3-butadiene in a gas phase reactor under polymerization conditions using an inert gas in the presence of a catalyst comprising: (a) a cobalt compound; (b) a compound selected from the group consisting of a phosphine, a xanthogen, a thiocyanide, a carbon disulfide, and mixtures thereof; and (c) an organoaluminum compound, and optionally a modifier (d) can be included in the catalyst composition. There is also provided a novel resin particle prepared by the process.Type: GrantFiled: September 9, 1997Date of Patent: March 9, 1999Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Monika Brady, Kevin Joseph Cann
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Patent number: 5880197Abstract: Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer amine and/or amide to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 .ANG. (as measured after water removal to a maximum of 5% by weight water), up to about 100 .ANG. and preferably in the range of about 10-45 .ANG., so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix. Alternatively, the intercalated complex can be exfoliated prior to combination with the organic liquid or the matrix polymer.Type: GrantFiled: December 22, 1995Date of Patent: March 9, 1999Assignee: AMCOL International CorporationInventors: Gary W. Beall, Semeon Tsipursky, Anatoliy Sorokin, Anatoliy Goldman
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Patent number: 5856377Abstract: A process for manufacturing thermosetting resin particles for powder coating use exhibiting improved anti-blocking property and workability is disclosed. The process include providing a suspension of the thermosetting resin particles in an aqueous medium and an emulsion or dispersion of a vinyl-based polymer having a relatively high Tg, respectively. The thermosetting resin particles are then treated with the emulsion while the resin particles are still suspended in or wetted with the aqueous medium to adhere the vinyl based polymer onto the resin particles forming a shell layer. The resin particles are dried and made to ready to use in the powder coating.Type: GrantFiled: March 10, 1997Date of Patent: January 5, 1999Assignee: Nippon Paint Co., Ltd.Inventors: Haruhiko Sato, Yutaka Harada
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Patent number: 5834545Abstract: Reverse phase polymer particles having a size below 10 .mu.m are provided as a solid product comprising a solid dispersion of the particles in a wax matrix which is solid at 20.degree. C. and which melts below 250.degree. C. The product may be made by dissolving the wax into the organic liquid phase of the product of a reverse phase emulsion polymerisation process followed by distillation of the organic liquid and cooling of the resultant product. The product is generally in particulate form and can be used as a flocculant or viscosifier, especially as a textile print paste thickener.Type: GrantFiled: October 11, 1995Date of Patent: November 10, 1998Assignee: Allied Colloids LimitedInventors: Norman Stewart Batty, Martin William Whitley, Adrian Swinburn Allen
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Patent number: 5817418Abstract: A carbon fiber covered on the surface with an aromatic polysulfone resin and then heated at 300.degree.-400.degree. C., a heat-resistant resin composition with excellent mechanical strength comprising 5-50% by weight of the carbon fiber and 95-50% by weight of a heat-resistant resin, and an internal combustion engine part, particularly an impeller of centrifugal compressor produced in one step, using the resin composition.Type: GrantFiled: May 3, 1995Date of Patent: October 6, 1998Assignees: Mitsui Chemicals, Inc., Nissan Motor Co., Ltd.Inventors: Yoshihisa Goto, Toshihiko Tsutsumi, Toshiaki Takahashi, Takatoshi Sagawa
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Patent number: 5789494Abstract: Methods and compositions for encapsulated polymeric gels swollen with nonaqueous reactive materials are provided. The methods include gel synthesis, swelling of a gel precursor with a first nonaqueous reactive material, and encapsulation of the swollen gel with a second nonaqueous reactive material. Gels precursors may be synthesized from crosslinking polymers, or alternatively, may be formed by crosslinking and polymerizing a monomer starting material. An accelerator may be utilized to facilitate swelling of the gel precursor with the first nonaqueous reactive material. Foams and composites may also be swollen with the first nonaqueous reactive material. The swollen gel is then contacted with a second nonaqueous reactive material such that an encapsulation layer is formed thereby. The encapsulated gels may be stored for subsequent use.Type: GrantFiled: June 7, 1995Date of Patent: August 4, 1998Assignee: Medlogic Global CorporationInventors: Barry Joseph Hand, E. C. Lupton, Jr., Lev Bromberg, Xiaohong Yu
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Patent number: 5763557Abstract: The invention relates to the chemical bonding of a polymer/or polymers onto non-metallic substrates such as cellophane by ultrasonic techniques. The cellophane film is preactivated by contacting with silver nitrate solution followed by treatment with potassium hydroxide solution whereby particles of silver and silver oxide are uniformly distributed, in situ, over the surface of cellophane film. The pretreated cellophane film when contacted with grafting solution, that contains monomers, prepolymers, catalyst, graft initiator and other ingredients of the composition, which is being agitated with ultrasonic energy results in polymerization of monomer/prepolymer onto the surface of the cellophane film.Type: GrantFiled: September 24, 1996Date of Patent: June 9, 1998Assignee: Polymer Research Corp. of AmericaInventors: Mohan L. Sanduja, Carl Horowitz, Paul Thottathil
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Patent number: 5731134Abstract: Stable photographic coating compositions comprising a polymer latex are prepared by mixing an aqueous solution comprising gelatin with a latex dispersion of a polymer of the formula(A).sub.x (B).sub.y (C).sub.zwhereA and B are formed from nonionic monomers,C is formed from anionic monomers, andx, y and z are monomer weight fractions where x=0 to 1.0, y=0 to 1.0, x+y=about 0.98 to 1.0, and z=0 to about 0.02,wherein A, B, x and y are such that latex dispersions of polymers of the formula (A).sub.x (B).sub.y have calcium ion critical coagulation concentrations of less than 80 mM Ca.sup.+2 in gelatin solutions,wherein the gelatin of the aqueous solution mixed with the latex dispersion comprises a gelatin of low calcium ion content such that the coating composition has a calcium Ca.sup.2+ concentration of less than 2 mM. The method of the invention allows for the preparation of aqueous gelatin coating solutions comprising latex dispersions of polymers which are unstable in the presence of calcium ions.Type: GrantFiled: February 9, 1996Date of Patent: March 24, 1998Assignee: Eastman Kodak CompanyInventors: James Stephen Honan, John Bruce Walters, Thomas Haile Whitesides
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Patent number: 5728782Abstract: There is provided a process comprising polymerizing a compound selected from the group consisting of a conjugated diene, a vinyl-substituted aromatic compound, and mixtures thereof in a gas phase fluidized polymerization vessel under polymerization conditions in the presence of at least one anionic initiator, optionally in the presence of an inert particulate material. A novel resin particle produced by the process is also provided.Type: GrantFiled: December 6, 1996Date of Patent: March 17, 1998Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Monika Brady, Kevin Joseph Cann, David Joseph Dovedytis
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Patent number: 5721306Abstract: Intercalates formed by contacting the layer material, e.g., a phyllosilicate, with an intercalant polymer to sorb or intercalate the polymer between adjacent platelets of the layered material. Sufficient intercalant polymer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 50 .ANG. (as measured after water removal to a maximum of 5% by weight water), up to about 100 .ANG. and preferably in the range of about 10-45 .ANG., so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex is combined with an organic liquid into an unexpectedly viscous carrier material, for delivery of the carrier material, or for delivery of an active compound, e.g., a pharmaceutical, or cosmetic, or lubricant, e.g., food guide lubricants dissolved or dispersed in the carrier material. Alternatively, the intercalated complex can be exfoliated prior to combination with the organic liquid.Type: GrantFiled: September 8, 1995Date of Patent: February 24, 1998Assignee: AMCOL International CorporationInventors: Semeon Tsipursky, Gary W. Beall, Anatoliy Sorokin, Anatoliy Goldman
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Patent number: 5712330Abstract: There is disclosed a styrenic resin pellet having a length in the range of 2 to 100 mm which comprises a (A) styrenic polymer having syndiotactic configuration and containing a polar group and at least 10% by weight of a (B) glass fiber which is surface-treated with a coupling agent, is impregnated with the styrenic polymer, and has a length equal to the length of the pellet. The styrenic resin pellet is imparted with excellent moldability and improved in general physical properties such as impact resistance and heat resistance, thereby making itself well suited to the raw material for producing molded articles excellent in practical characteristics such as tensile creep at elevated temperatures higher than the glass transition temperature and vibrational fatigue characteristics at elevated temperatures.Type: GrantFiled: June 14, 1996Date of Patent: January 27, 1998Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Michio Funayama, Hiroki Fukui
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Patent number: 5686085Abstract: New lysine derivatives containing a containing an alkylsulphonyl or alkylaminocarbonyl group of formula (I):COOH--CH(NH.sub.2)--(CH.sub.2).sub.4 --NH--Xin which X represents an --SO.sub.2 R or --CONHR group, where R represents a linear or branched, saturated or unsaturated, alkyl radical having from 8 to 22 carbon atoms, salts thereof, and mixtures of the derivatives and the salts. A process for the preparation of these derivatives, salts, and mixtures and use of such derivatives, salts, and mixtures, especially in cosmetics. Compositions, especially cosmetic compositions, comprising the derivatives, salts, and mixtures.Type: GrantFiled: January 23, 1996Date of Patent: November 11, 1997Assignee: L'OrealInventors: Thierry Bordier, Michel Philippe
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Patent number: 5677372Abstract: An improved adhesion or bonding between diamond fibers and a matrix of at least one organic polymer such as a resin is achieved in a composite material reinforced with vapor-deposited diamond. To improve bonding to the matrix, hydrogen is removed from the surface of vapor-deposited diamond fiber. This can be achieved by heating the diamond under an oxidative atmosphere at a temperature of about 150.degree. C. to about 800.degree. C., or under a non-oxidative atmosphere at a temperature of about 800.degree. C. to about 1500.degree. C. The surface of the vapor-deposited diamond, which contains not more than about 1.times.10.sup.15 /cm.sup.2 of hydrogen atoms, is bonded to the matrix of resin for example with sufficient strength. To further improve bonding, diamond doped with B or N is employed as the reinforcing material or at least a surface layer thereof.Type: GrantFiled: December 8, 1995Date of Patent: October 14, 1997Assignee: Sumitomo Electric Industries, Ltd.Inventors: Yoshiyuki Yamamoto, Takahiro Imai, Takashi Tsuno, Naoji Fujimori
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Patent number: 5637635Abstract: The present invention provides a water dispersible particulate polymer composition having improved water dispersibility comprising a water soluble particulate polymer which has been contacted with a finely divided particulate dispersant comprised of at least one insoluble or sparingly soluble fatty acid or salt thereof so that the particles of the water soluble particulate polymer have dispersed thereon said finely divided particulate dispersant, a method for making said water soluble particulate polymer composition, and the use thereof in viscosifying water-based fluids.Type: GrantFiled: November 9, 1994Date of Patent: June 10, 1997Assignee: Phillips Petroleum CompanyInventor: Bharat B. Patel
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Patent number: 5621023Abstract: To produce colored particles with a 10-200 .mu.m average grain size simply, efficiently, and in high yields, in order to obtain suede-type paint constituents with excellent decorative features capable of producing finely detailed, marble-like, multi-color patterns. Water-insoluble particles and a polyvalent carboxylic acid resin with an acid value (solid-based) of about 20-120, either water-soluble or water-diffusing, are mixed in water; and after primary coated particles are formed on the surfaces of the water-insoluble particles on which the polyvalent carboxylic acid resin is adsorbed, a dispersion-stabilized emulsion resin containing a colored pigment is mixed in the dispersion liquid; and a metal salt is added to this mixture so that colored particles with an average particle size of about 10-200 .mu.m with a surface colored coating are obtained. The water-insoluble particles can be either synthetic resin particles or inorganic particles.Type: GrantFiled: December 9, 1994Date of Patent: April 15, 1997Assignee: Asahipen CorporationInventors: Yoshihiko Nishimura, Tadamitsu Hirata
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Patent number: 5614570Abstract: A method of producing easily densified high bulk fibers that have adhered particulates. The fibers have hydrogen bonding or coordinate covalent bonding functionalities, and a binder is applied to the fibers to bind the particles to the fibers. The binder has a functional group that forms a hydrogen bond or a coordinate covalent bond with the particles, and a functional group that forms a hydrogen bond with the fibers. A substantial portion of the particles that are adhered to the fibers are adhered in particulate form by hydrogen bonds or coordinate covalent bonds to the binder, and the binder is in turn adhered to the fibers by hydrogen bonds. Fibers containing particles bound by this method are easily densified.Type: GrantFiled: April 4, 1995Date of Patent: March 25, 1997Assignee: Weyerhaeuser CompanyInventors: Michael R. Hansen, Richard H. Young, Sr.
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Patent number: 5585184Abstract: A colorable resin particle having an outer shell of a non-sticky olefinic polymer having a flow index of less than 20 decigrams/minute and an inner core of at least 90 wt % of a sticky polymer, the resin particle being made in a gas phase fluidized bed reactor at or above the sticking temperature of the sticky polymer in the absence of an inert particulate material fluidization aid.Type: GrantFiled: September 29, 1994Date of Patent: December 17, 1996Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Edgar C. Baker, Jose F. Cevallos-Candau, Eric A. Lucas, John G. Victor, Allen Noshay
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Patent number: 5578672Abstract: Intercalates formed by mixing the phyllosilicate with a polymer and a liquid carrier, and extruding the mixture through a die-opening to adsorb or intercalate the polymer between adjacent phyllosilicate platelets. Sufficient polymer is adsorbed between adjacent phyllosilicate platelets to expand the adjacent platelets to a spacing of at least about 10 .ANG. (as measured after water removal), up to about 55 .ANG. and preferably in the range of about 30-40 .ANG., so that the intercalate easily can be exfoliated into individual platelets by heating the polymer to its melting point, to provide a matrix polymer/platelet composite material.Type: GrantFiled: June 7, 1995Date of Patent: November 26, 1996Assignee: Amcol International CorporationInventors: Gary W. Beall, Semeon Tsipursky, Anatoliy Sorokin, Anatoliy Goldman
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Patent number: 5539040Abstract: A polypropylene molding composition which comprises 0.5 to 15% by weight of dark mineral fibers, in particular basalt fibers, can be processed to moldings having a decorative surface. These moldings are used for domestic appliances, for motor vehicles, in the building sector for office items and many other applications.Type: GrantFiled: July 14, 1994Date of Patent: July 23, 1996Assignee: Hoechst AktiengesellschaftInventor: Jurgen Rohrmann
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Patent number: 5532288Abstract: Process for the preparation of a polysilane crosslinked by ioning radiation and process for the production of a composite material having a polysilane matrix. The preparation process consists of subjecting to ionizing radiation chosen from among X-rays and an electron bombardment, a formulation crosslinkable by ionizing radiation incorporating at least one polysilane having at least one vinyl termination.Type: GrantFiled: March 29, 1995Date of Patent: July 2, 1996Assignee: Aerospatiale Societe Nationale IndustrilleInventors: Daniel Beziers, Evelyne Chataignier, Patrick Noireaux
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Patent number: 5530050Abstract: Blended thermal spray powders are characterized by the presence of a ZrO.sub.2 component and a ceramic coated plastic component. The ceramic coated plastic component is made by attrition milling ceramic fine particles with plastic core particles, causing the ceramic fine particles to bind to the surface of the plastic core without the use of a binder. Abradable coatings formed by thermal spraying the powders have superior high-temperature properties such as heat resistance and yet abrade readily to form abradable seals.Type: GrantFiled: April 6, 1994Date of Patent: June 25, 1996Assignee: Sulzer Plasma Technik, Inc.Inventor: Subramaniam Rangaswamy
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Patent number: 5512610Abstract: A bone cement composition has adjustable rheological properties, high strength, and produces a uniform radiological image. The cement is characterized by controlled retention and release of additives incorporated in beads included in the dry component of the cement. The cement comprises beads containing a polymerization initiator in controllable concentrations from 0% to 5% or more by weight. These same beads or others may also contain an opacifier. The polymerization initiator and the opacifier may be selectively distributed throughout the beads or at specific radial locations in the beads. They may also be selectively placed in beads of a particular advantageous size range. Furthermore, in other embodiments of the invention, other advantageous additives can be incorporated in the beads such as dyes, antibiotics, bone growth factors, and other pharmacological or therapeutic agents.Type: GrantFiled: July 27, 1994Date of Patent: April 30, 1996Assignee: Zimmer, Inc.Inventor: Steve T. Lin
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Patent number: 5506280Abstract: A modeling dough comprising gelled poly(vinyl alcohol), water and a filler provides a dough resistant to flaking, cracking, and crumbling. In the disclosed invention, the poly(vinyl alcohol) resin is gelled, thereby providing a water-based resin system that is not sticky yet very ductile. Prior to drying, the dough also exhibits the properties of bounceability and the ability to pick up newsprint. After the dough is air-dried, the poly resin serves to bind the components into a solid, durable product. The filler accounts for a large portion of the volume of the dough, so the overall volume is not greatly affected by water loss upon drying. The dough is water-based and easy to wash from skin, carpets, and other surfaces. Dyes and pigments can be easily incorporated into the formula. The dried product is sandable and paintable.Type: GrantFiled: November 14, 1994Date of Patent: April 9, 1996Assignee: Binney & Smith Inc.Inventors: Richard E. Miller, Karen Mariano
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Patent number: 5494948Abstract: A mica-reinforced propylene resin composition having a volatile matter at 105.degree. C of 0.12% or less is obtained by heating and melting a mixture containing (A) a crystalline polypropylene, (B) mica treated with an organosilane compound, (C) a bismaleimide compound, and (D) an organic peroxide. It has excellent stiffness, heat resistance and dimensional stability, does not corrode a mold, and does not exhale an irritating odor during molding.Type: GrantFiled: September 26, 1994Date of Patent: February 27, 1996Assignee: Sumitomo Chemical Company, LimitedInventors: Taichi Nishio, Yuji Ikezawa
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Patent number: 5484835Abstract: There is provided a heat-resistant, propylene resin-based molding material, comprising the following components (A) and (B):component (A): 3 to 97% by weight of a resin-impregnated glass fiber bundle comprising:constituent (a.sup.1): 20 to 80 parts by weight of glass fibers having a length of at least 3 mm and an average diameter of 20 .mu.m or less, andconstituent (a.sup.2): 80 to 20 parts by weight of a crystalline propylene polymer at least partly modified with an unsaturated carboxylic acid or a derivative thereof, the MFR of the modified polymer being 50 g/10 min or more, in which the glass fibers are present in the constituent (a.sup.2) in such a state that they are arranged almost in parallel with one another; andcomponent (B): 97 to 3% by weight of a crystalline propylene polymer having an MFR of 50 g/10 min or more.Type: GrantFiled: May 31, 1994Date of Patent: January 16, 1996Assignee: Mitsubishi Chemical CorporationInventors: Yoshihiro Sobajima, Satoru Kinoshita, Masahide Hamaura
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Patent number: 5447977Abstract: A method of producing easily densified high bulk fibers that have adhered particulates. The fibers have hydrogen bonding or coordinate covalent bonding functionalities, and a binder is applied to the fibers to bind the particles to the fibers. The binder has a functional group that forms a hydrogen bond or a coordinate covalent bond with the particles, and a functional group that forms a hydrogen bond with the fibers. A substantial portion of the particles that are adhered to the fibers are adhered in particulate form by hydrogen bonds or coordinate covalent bonds to the binder, and the binder is in turn adhered to the fibers by hydrogen bonds. Fibers containing particles bound by this method are easily densified.Type: GrantFiled: November 15, 1993Date of Patent: September 5, 1995Assignee: Weyerhaeuser CompanyInventors: Michael R. Hansen, Richard H. Young, Sr.
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Patent number: 5446076Abstract: A method of stabilizing polymeric lattices comprising the addition of an organophilic clay which, when properly activated and dispersed, sets up a network that will suspend the polymer particles and retard the settling process is disclosed. The network is easily destroyed by the application of shear, but then reforms when shear is removed.Type: GrantFiled: May 23, 1994Date of Patent: August 29, 1995Assignee: Nalco Chemical CompanyInventors: Anthony G. Sommese, R. Nagarajan
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Patent number: 5434210Abstract: Thermal spray powders are characterized by the presence of a matrix-forming component, a solid lubricant component and a plastic component. Abradable coatings formed by thermal spraying the powders abrade readily to form abradable seals. The abradable coatings have a metal, metal alloy, or ceramic matrix with discrete inclusions of solid lubricant and plastic. The thermal spray powders may be prepared as mechanically fused agglomerates.Type: GrantFiled: September 28, 1992Date of Patent: July 18, 1995Assignee: Sulzer Plasma Technik, Inc.Inventors: Subramaniam Rangaswamy, Robert A. Miller
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Patent number: 5403873Abstract: There is provided a plastisol for use in a electrically conductive molded article comprising non-conductive high polymer particles having surfaces coated with an electrically conductive high polymer or non-conductive high polymer particles having surfaces coated with filler of electrically conductive fine particles, and a plastisizer compatible with the said non-conductive high polymer. The plastisol is excellent in fluidity and good in processability. Said plastisol can provide a molded article having excellent electrical conductivity and is suited for, e.g., production of floor materials or sealing materials having low static properties and formation of an electrically conductive path.Type: GrantFiled: February 11, 1993Date of Patent: April 4, 1995Assignee: Nippon Zeon Co., Ltd.Inventors: Eitaro Nakamura, Kazunori Ueki
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Patent number: 5401779Abstract: A thermotropic liquid crystalline polymer matrix having sized carbon fibers incorporated therein for reinforcement. The carbon fibers are coated on their surface with a sizing composition comprising a rigid polyimide coating which is derived from the reaction of at least one aromatic diamine, at least one dianhydride, and at least one aromatic tetracarboxylic acid diester in which the carboxylic acid groups and ester groups are ortho disposed. By the use of appropriate amounts of heat and pressure, multifilamentary bundles of carbon fibers are readily impregnated with thermotropic liquid crystalline polymer to form a prepreg having a uniform distribution of carbon fiber throughout.Type: GrantFiled: January 14, 1983Date of Patent: March 28, 1995Inventors: Robert Edelman, Richard D. Orwoll
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Patent number: 5385959Abstract: The present invention relates to a capsule for use in heavy duty liquid compositions which capsule comprises:(1) a component subject to degradative attack; and(2) a composite polymer which in turn comprises a hydrophilic portion and hydrophobic polymer core particle.Type: GrantFiled: March 25, 1993Date of Patent: January 31, 1995Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Liang S. Tsaur, Michael P. Aronson
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Patent number: 5364892Abstract: A modeling dough comprising gelled poly(vinyl alcohol), water and a filler provides a dough resistant to flaking, cracking, and crumbling. In the disclosed invention, the poly(vinyl alcohol) resin is gelled, thereby providing a water-based resin system that is not sticky yet very ductile. Prior to drying, the dough also exhibits the properties of bounceability and the ability to pick up newsprint. After the dough is air-dried, the poly resin serves to bind the components into a solid, durable product. The filler accounts for a large portion of the volume of the dough, so the overall volume is not greatly affected by water loss upon drying. The dough is water-based and easy to wash from skin, carpets, and other surfaces. Dyes and pigments can be easily incorporated into the formula. The dried product is sandable and paintable.Type: GrantFiled: December 14, 1992Date of Patent: November 15, 1994Assignee: Binney & Smith, Inc.Inventors: Richard E. Miller, Karen Mariano
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Patent number: 5362517Abstract: Particulate water-soluble or water-swellable polymeric material is provided with a substantially uninterrupted continuous coating of crystalline material. Single particles or aggregates having a size below 1 mm in size can be made by mixing the polymeric particles with a substantially saturated or supersaturated aqueous solution of crystallizable material (optionally a melt of hydrate crystallizable material) and thereby depositing it as a continuous crystalline coating on the particles.Type: GrantFiled: January 15, 1993Date of Patent: November 8, 1994Assignee: Allied Colloids LimitedInventors: Peter Flesher, David Farrar, Malcolm Skinner, Brian Dymond
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Patent number: 5334626Abstract: A bone cement composition has adjustable rheological properties, high strength, and produces a uniform radiological image. The cement comprises beads containing a polymerization initiator in controllable concentrations from 0% to 5% or more by weight. These same beads or others may also contain an opacifier. The polymerization initiator and the opacifier may be selectively distributed throughout the beads or at specific radial locations in the beads or within the beads in specific strata. They may also be selectively placed in beads of a particular advantageous size range. Furthermore, in other embodiments of the invention, other advantageous additives can be incorporated in the beads such as dyes, antibiotics, bone growth factors, and other pharmacological or therapeutic agents.Type: GrantFiled: July 28, 1992Date of Patent: August 2, 1994Assignee: Zimmer, Inc.Inventor: Steve T. Lin
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Patent number: 5334644Abstract: Aqueous application systems for applying additives to polymeric particles, methods of preparing aqueous emulsions which include at least one processing, stabilizing or other functional polymer additive and an emulsifiable wax. Also disclosed are methods of applying additives to polymeric particles and to polymeric particles treated by such methods.Type: GrantFiled: March 2, 1993Date of Patent: August 2, 1994Assignee: Eastman Chemical CompanyInventors: William C. Gose, Kenneth W. Hyche
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Patent number: 5319001Abstract: A coloured powder coating composition consists of solid particles, each of which comprises a solid polymeric binder system and at least a majority of which contain at least one colouring agent. The composition is a mixture of particles of at least two different colours. The size of the particles is sufficiently low that when the powder coating is applied to a substrate and heated to form a continuous coating the differences in colour in the cured powder coating arising from the different coloured particles cannot be discerned by the human eye. The size of the particles is preferably below 10 microns in the largest dimension. The particles are preferably agglomerated into composite particles of mean particle size 15 to 75 microns for application by electrostatic spray.Type: GrantFiled: July 25, 1991Date of Patent: June 7, 1994Assignee: Courtaulds Coating (Holdings) UnitedInventors: Andrew R. Morgan, John D. Sinclair-Day, Timothy M. Handyside
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Patent number: 5308896Abstract: A method of producing easily densified high bulk fibers that have adhered particulates. The fibers have hydrogen bonding or coordinate covalent bonding functionalities, and a binder is applied to the fibers to bind the particles to the fibers. The binder has a functional group that forms a hydrogen bond or a coordinate covalent bond with the particles, and a functional group that forms a hydrogen bond with the fibers A substantial portion of the particles that are adhered to the fibers are adhered in particulate form by hydrogen bonds or coordinate covalent bonds to the binder, and the binder is in turn adhered to the fibers by hydrogen bonds. Fibers containing particles bound by this method are easily densified.Type: GrantFiled: August 17, 1992Date of Patent: May 3, 1994Assignee: Weyerhaeuser CompanyInventors: Michael R. Hansen, Richard H. Young, Sr.
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Patent number: 5304588Abstract: A core-shell resin particle composed of a mixture of rubber and inert material with a core containing a majority of rubber while the shell contains a majority of inert material.Type: GrantFiled: May 21, 1992Date of Patent: April 19, 1994Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Robert L. Boysen, Cliff R. Mure, Leonard S. Scarola, Aaron S. Rhee
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Patent number: 5300539Abstract: This invention relates to a continuous process for incorporating additives into or onto polymer granules by high speed/high intensity mixing of entrained polymer granules and additive particles, wherein the additive is provided in the form of an additive dispersion.Type: GrantFiled: December 28, 1992Date of Patent: April 5, 1994Assignee: Shell Oil CompanyInventor: Ananda M. Chatterjee
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Patent number: 5298537Abstract: Incorporation of an encapsulated nucleant made from an encapsulant polymer and a nucleant, wherein the encapsulant polymer is selected from linear low density polyethylene, high density polyethylene, and polypropylene, into polyoxymethylene compositions results in a decrease in the center line porosity of polyoxymethylene extruded stock shape parts, without also reducing the rate of extrusion. The compositions are especially useful for extrusion into stock shape parts, such as rod, slab, sheet, and tube stock, which are used for machined parts (like artificial limbs and complex gears), die cut parts (like washers and gaskets), and control cable inners.Type: GrantFiled: April 9, 1992Date of Patent: March 29, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventor: Shailaja R. Vaidya
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Patent number: 5283266Abstract: A microcapsule adhesive for preventing the loosening of screws and the like, which is superior in storage stability, adhesive force and safety, and which is comprised of an epoxy resin as a core material; a urea-formaldehyde resin, a melamine-formaldehyde resin, a polyurethane or a urea-urethane resin as a wall material; a water-soluble polyacetal resin binder; and a non-volatile, water-soluble or -dispersible amine-based curing agent.Type: GrantFiled: November 23, 1992Date of Patent: February 1, 1994Assignee: Three Bond Co., Ltd.Inventors: Satoshi Matsuo, Ikuzo Usami, Makoto Kurihara, Kunihiko Nakashima
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Patent number: 5277963Abstract: A filter material suitable for making protective clothing comprising an air-permeable pliable textile support, substantially spherical adsorber particles, and an adhesive discontinuously securing said particles to said textile support, wherein the adsorber particles comprise a copolymer based mainly on styrene and divinylbenzene, eventually crosslinked by CH.sub.2 -bridges.Type: GrantFiled: February 23, 1993Date of Patent: January 11, 1994Assignee: Blucher GmbHInventors: Hasso von Blucher, Ernest de Ruiter
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Patent number: 5274010Abstract: A process for warp-free pigmenting of polyolefins comprising(A)(i) adsorbing a polyvinyl alcohol film onto the surface of an organic pigment particle,(ii) coating the surface of the polyvinyl alcohol coated organic pigment particle with one or more films of linear or branched homopolymers or copolymers selected from the group consisting of acrylic polymers based on acrylic acid, methacrylic acid, alkyl esters of acrylic or methacrylic acid and mixtures thereof, and(iii) admixing said pigment particles with a polyolefin; or(B)(i) adsorbing a film of hydrolysed zirconium acetylacetonate onto the surface of an organic ##STR1## in which R is methyl or ethyl and m is a number from 1 to 6, onto the surface of the hydrolysed zirconium acetylacetonate coated organic pigment particle, (ii) coating the surface of organic pigment particle coated in accordance with step (B)(i) with one or more films of linear or branched homopolymers or copolymers selected from the group consisting of acrylic polymers based on acrylic acType: GrantFiled: July 5, 1991Date of Patent: December 28, 1993Assignee: Ciba-Geigy CorporationInventors: Philippe Bugnon, Fritz Herren