Silicon Containing Organic Material Having An Atom Other Than Si, C, H, Or Oxygen Patents (Class 523/213)
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Patent number: 8802231Abstract: An insulating coating material includes a polyamide-imide resin insulating coating material, and surface-treated inorganic fine particles dispersed in the polyamide-imide resin insulating coating material. A viscosity measured by an E-type viscometer is 1000 to 4000 mPa·s at 30° C. and at a shear rate of 200 s?1 and 4000 to 12000 mPa·s at 30° C. and at a shear rate of 1 s?1. An insulated wire includes a rectangular conductor, and an insulating layer formed on the rectangular conductor and including the insulating coating material.Type: GrantFiled: February 14, 2012Date of Patent: August 12, 2014Assignees: Hitachi Metals, Ltd., Hitachi Magnet Wire Corp.Inventors: Yasuhiro Funayama, Hideyuki Kikuchi, Yuki Honda
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Publication number: 20140178643Abstract: A molded article is formed by molding a cycloolefin resin composition, in which the cycloolefin resin composition contains a cycloolefin resin and silica particles, the silica particles have an average primary particle size of 10 nm to 150 nm, the cycloolefin resin composition has a silica particle content of 15% by weight to 70% by weight, and the molded article has a linear expansion coefficient of 50×10?6/degrees (Celsius) or less in the temperature range of 0 degrees (Celsius) to 80 degrees (Celsius).Type: ApplicationFiled: July 11, 2012Publication date: June 26, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Katsumoto Hosokawa, Takahiro Kojima
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Publication number: 20140045972Abstract: A method for preparing an insulating varnish. The method includes: providing equivalence of an epoxy resin solution having a concentration exceeding 99 wt. % and acetone solution having a concentration of 40 wt. %, adding silane coupling agent-modified hexagonal boron nitride (BN) having a particle size of between 200 and 250 nm to the acetone solution and stirring; mixing the epoxy resin solution and the acetone solution and stirring, and dispersing the resulting mixture; adding to the mixture, low molecular weight polyamide resins as a curing agent, and stirring to uniformly disperse the curing agent; adding n-butane as a lubricant to the mixture and stirring, cooling the mixture to room temperature, adding di-n-butyl phthalate as a diluent to the mixture and stirring; and allowing the mixture to stand in a vacuum drier to remove bubbles to yield the insulating varnish, which is free of bubbles.Type: ApplicationFiled: August 9, 2013Publication date: February 13, 2014Applicant: Tianjin Jing Wei Electric Wire Co., Ltd.Inventors: Boxue DU, Shulin DONG
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Patent number: 8592037Abstract: Compositions containing a nanostructure, preferably a nanocrystal, are provided. The nanostructures have ligands bound to the surface. Such ligands are preferably siloxane containing ligands having at least one —COON group, although ligands having various ?P?O groups are also contemplated. The nanostructures can be embedded into a polymer such as a silicone polymer.Type: GrantFiled: October 20, 2011Date of Patent: November 26, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: J. Wallace Parce, Paul Bernatis, Robert Dubrow, William P Freeman, Joel Gamoras, Shihai Kan, Andreas Meisel, Baixin Qian, Jeffery A Whiteford, Jonathan Ziebarth
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Patent number: 8580027Abstract: Fluoroalkylsilane-treated metal oxide particles and a fluoroelastomeric binder are dispersed in a fluorinated solvent with a low boiling point and applied to a substrate via spray deposition. The spray deposition process rapidly produces a conformal coating that features low surface energy and surface topography with a large range of characteristic length scales and re-entrant curvature, thereby imparting superoleophobicity. The degree of superoleophobicity is readily adjusted by means of altering the ratio of particles to binder. The choice of particle and binder result in coatings with thermal stability for thousands of hours at temperatures up to 200 degrees Celsius as well as desirable mechanical characteristics.Type: GrantFiled: August 11, 2011Date of Patent: November 12, 2013Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Raymond Campos, Andrew J. Guenthner, Timothy S. Haddad, Joseph M. Mabry
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Patent number: 8575273Abstract: Certain embodiments described herein are directed to silane coupling agents that may be used, for example, to covalently couple a polymer to a filler. In some examples, devices that include the polymer-silane coupling agent-filler compositions are also described.Type: GrantFiled: November 26, 2008Date of Patent: November 5, 2013Assignee: Schlumberger Technology CorporationInventors: Huilin Tu, Agathe Robisson, Julien Ramier
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Patent number: 8557896Abstract: An adhesive composition for semiconductor devices, an adhesive film, and a dicing die bonding film, the adhesive composition including an elastomer resin, an epoxy resin, a curable phenolic resin, a curing accelerator, a silane coupling agent, and a filler, wherein the silane coupling agent includes an epoxy group-containing silane coupling agent and a transition metal scavenging functional group-containing silane coupling agent.Type: GrantFiled: December 27, 2010Date of Patent: October 15, 2013Assignee: Cheil Industries, Inc.Inventors: Chul Jeong, Ki Tae Song, Han Nim Choi, Su Mi Im, Ah Ram Pyun, Sang Jin Kim
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Patent number: 8530546Abstract: This invention is drawn to a curable composition that has excellent smoothness when a plastic substrate is coated therewith. Also disclosed are active energy beam curable compositions, such as actinically curable compositions, that can be cured without using a photopolymerization initiator, or with the use of a small amount thereof. This object is achieved by the presence of surface treated inorganic oxide microparticles. Such particles are obtained by reacting an alkoxysilane compound (a1) represented by the Formula (1) below and inorganic oxide microparticles (a2) in the presence of water and an organic solvent: (P—SiO3/2)1-a(P—Si(R0)O2/2)a(O1/2R3)z (1) in which P denotes a maleimide containing group, R3 denotes a hydrogen atom or a monovalent organic group, R0 denotes a monovalent organic group, a is 0 or a positive number and satisfies 0?a <1, and z is a positive number and satisfies 0.1 ?z ?2.Type: GrantFiled: December 11, 2009Date of Patent: September 10, 2013Assignee: Toagosei Co., Ltd.Inventors: Kazumasa Inata, Eiichi Okazaki
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Patent number: 8513333Abstract: The invention relates to particles which have been functionalised by means of an inertised reactive group, i.e. by means of specific reversibly blocked isocyanate groups, and whose inertization can be reversed by means of an external influence.Type: GrantFiled: April 8, 2009Date of Patent: August 20, 2013Assignee: Merck Patent GmbHInventors: Matthias Koch, Jens Pradella
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Tire with rubber component containing combination of carbon black, silica and functionalized mineral
Patent number: 8415426Abstract: A tire is provided having a component comprised of a rubber composition containing at least one conjugated diene-based elastomer and a combination of rubber reinforcing fillers composed of rubber reinforcing carbon black, precipitated silica and granular functionalized mineral comprised of at least one of aluminum hydrate (ALOOH) and titanium dioxide. The granular mineral is functionalized by pretreatment with a coupling agent. The granular mineral fillers are pretreated with a coupling agent to promote a combination of rubber reinforcing effect for the mineral fillers and to promote a hydrophobation of the mineral fillers to promote their dispersability in the rubber composition.Type: GrantFiled: December 20, 2011Date of Patent: April 9, 2013Assignee: The Goodyear Tire & Rubber CompanyInventors: Kuo-Chih Hua, Ling Du -
Patent number: 8388859Abstract: A composition comprising a blocked and/or unblocked isocyanate compound and surface-modified nanoscale solid particles that comprise on the surface thereof organic radicals which comprise groups with an active hydrogen or precursors of such groups.Type: GrantFiled: December 5, 2005Date of Patent: March 5, 2013Assignee: Leibniz-Institut fuer Neue Materialien Gemeinnuetzige GmbHInventors: Carsten Becker-Willinger, Martin Kluke, Helmut Schmidt
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Patent number: 8378008Abstract: The invention relates to surface-modified non-halogenated mineral filler compositions comprising a particulate mineral filler core comprising hydroxide groups bound to divalent or trivalent metal ions, said particulate mineral filler core having on its surface (i) one or more short-chain organosilano groups each having one to three silicon-bound short-chain hydrocarbon groups having, independently, one to three carbon atoms, and (ii) one or more long-chain organosilano groups having one to three silicon-bound straight-chained or branched, saturated or unsaturated, long-chain hydrocarbon groups containing, independently, eight to twelve carbon atoms, wherein the long-chain organosilano groups are present in an amount of up to about fifty-five mole percent of combined molar amount of long-chain and short-chain organosilano groups.Type: GrantFiled: July 2, 2010Date of Patent: February 19, 2013Assignee: Momentive Performance Materials Inc.Inventor: Philbert E. Ramdatt
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Patent number: 8362129Abstract: A room-temperature-curable polyorganosiloxane composition includes: 100 parts by mass of polyorganosiloxane capped with hydroxyl groups at termini and having a viscosity (23° C.) of 0.02 to 1000 Pa·s; 1 to 200 parts by mass of a filler capable of imparting flame retardancy; 0.1 to 10 parts by mass of a partially hydrolyzed condensate of a silane compound of R1aSi(OR2)4-a wherein R1('s) and R2('s) independently represent a substituted/unsubstituted univalent hydrocarbon group, and ‘a’ represents a numerical value of 0?a?0.2 on average; 0.1 to 10 parts by mass of a silane compound of R32Si(OR4)2 wherein R3's and R4's) independently represent a substituted/unsubstituted univalent hydrocarbon group, or its partially hydrolyzed condensate having 3 or less Si atoms in its molecule; 0.Type: GrantFiled: December 17, 2008Date of Patent: January 29, 2013Assignee: Momentive Performance Materials Japan LLCInventor: Isao Iida
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Patent number: 8361622Abstract: Metal oxides are modified by aminohydrocarbyl-substituted monoalkyltrisiloxy groups in a defined percentage of T1 and T2 groups relative to total T groups wherein the T groups denote connectivity of siloxy bonds to the metal oxide have a high positive triboelectric chargeability, the triboelectric charge being stable even in conditions of high humidity.Type: GrantFiled: July 10, 2008Date of Patent: January 29, 2013Assignee: Wacker Chemie AGInventors: Torsten Gottschalk-Gaudig, Ute Volkel
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Patent number: 8357733Abstract: The present invention provides a process for making silica-filled rubber masterbatch using silica hydrophobated with a trimethoxy silane coupling agent that is soluble in an alcohol-water solution containing at least about 70 wt % water. One embodiment uses a mixture of trimethoxy silanes, one or more of which react with rubber to bond the silica to the rubber, and one or more of which do not react with rubber, but do hydrophobate the silica. Hydrophobated silica is mixed with latex polymer and incorporated into rubber during coagulation of the latex, which is preferably coagulated with calcium chloride. The present invention further provides a process for making the trimethoxy silane coupling agents. Preferred trimethoxy silane coupling agents include bis-(3-trimethoxysilylpropyl)-disulfide and bis-(3-trimethoxysilylpropyl)-tetrasulfide.Type: GrantFiled: July 23, 2009Date of Patent: January 22, 2013Assignees: Industrias Negromex, S.A. de C.V., Cooper Tire & Rubber CompanyInventors: Peter J. Wallen, Gregory C. Bowman, Howard A. Colvin, Christopher J. Hardiman, José Eduardo Rojas Reyna
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Patent number: 8329794Abstract: A polymer composition of a compatibilized silica in blends of acrylonitrile butadiene polymer and styrene butadiene polymer comprising six to ninety percent by weight of a compatibilized silica, at least one percent by weight of a coupling agent, at least one percent by weight of a styrene butadiene polymer, and at least one percent by weight of an acrylonitrile butadiene polymer is described herein. The polymer composition can have a minimum amount of at least ten percent by weight of 15:50 ratio, acrylonitrile to butadiene polymer, with the remainder being compatibilized silica.Type: GrantFiled: January 4, 2011Date of Patent: December 11, 2012Assignee: Lion Copolymer, LLCInventors: Lawrence Douglas Harris, Harold William Young, Deepak Rasiklal Parikh, Daniel Courtney Patton, Vernon Vincent Vanis
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Patent number: 8318833Abstract: The present invention is drawn to pigment suspensions, methods of forming pigment suspensions, and ink sets. The pigment suspension can comprise an aqueous liquid vehicle and a polymer-encapsulated pigment suspended in the liquid vehicle. The polymer-encapsulated pigment can include a pigment core, a passivation layer formed from a passivation component including an amphiphilic polymer and deposited on a surface of the pigment core, and a polymer-encapsulation layer attached to or deposited on the passivation layer.Type: GrantFiled: April 26, 2007Date of Patent: November 27, 2012Assignee: Hewlett-Packard Development Company, L.P.Inventor: Sivapackia Ganapathiappan
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Patent number: 8232332Abstract: A curable composition is described, including a gel material derived from the curable composition, and medical articles including such material, wherein the transparent gel material includes a polymerized monofunctional poly(alkylene oxide) macromonomer component and a surface modified nanoparticle component.Type: GrantFiled: June 16, 2011Date of Patent: July 31, 2012Assignee: 3M Innovative Properties CompanyInventors: Kelly S. Anderson, Kevin M. Lewandowski, David J. Plaut, Wendy L. Thompson, Babu N. Gaddam
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Patent number: 8148449Abstract: The present invention concerns shape memory composites, methods of preparing same and the use of these composites, for example, for products prepared by injection molding techniques or coating applications.Type: GrantFiled: March 23, 2007Date of Patent: April 3, 2012Assignee: Helmholtz-Zentrum Geesthacht Zentrum fur Material—und Kustenforschung GmbHInventor: Andreas Lendlein
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Patent number: 8138369Abstract: A process for producing an adsorbent where a metal oxide is reacted with an alkoxy silane to produce an epoxy-functionalized metal oxide. This product is reacted with an amino-substituted propionic acid and a nitro-substituted fluorenone, and this product is grafted to the epoxy-functionalized metal oxide. This grafted product is the adsorbent, which may be contacted with a hydrocarbon mixture having at least one sulfur containing compound in order to remove this sulfur containing compound. Also disclosed is a process for adding polymerization groups to an adsorbent.Type: GrantFiled: June 6, 2008Date of Patent: March 20, 2012Assignee: Chevron U.S.A. Inc.Inventors: Xiaolin Wei, Scott Michael Husson, Marcus V. Dutra e Mello, Daniel Chinn
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Patent number: 8030374Abstract: An object of the present invention is to prevent, in blending an inorganic filler for the purpose of improving rigidity of a thermoplastic resin, deterioration in impact resistance and surface smoothness caused by the inorganic filler. The invention relates to a polyphenylene ether based resin composition containing (a) from 10 to 93% by weight of a polyphenylene ether based resin and optionally a styrene based resin, (b) from 2 to 20% by weight of a styrene based thermoplastic elastomer modified with an imidazolidinone compound, and (c) from 5 to 60% by weight of an inorganic filler that has been surface treated with a silane compound.Type: GrantFiled: August 8, 2003Date of Patent: October 4, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Juro Ozeki, Toru Yamaguti
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Patent number: 8029855Abstract: An inorganic oxide dispersion containing an organic solvent, and inorganic oxide particles surface-treated with at least one of a hydrolyzate and a partial condensate of an organosilane compound represented by formula (I), the inorganic oxide particles being dispersed in the organic solvent: (R10)m—SI(X)4-m (I) as defined herein, the surface treatment of the inorganic oxide particles being carried out in a presence of at least one of: (a) an acid catalyst; and (b) a metal chelate compound having Zr, Ti or Al as a center metal and at least one of an alcohol represented by formula: R3OH in which R3 represents an alkyl group having 1 to 10 carbon atoms, and a compound represented by formula: R4COCH2COR5 as defined herein, as a ligand.Type: GrantFiled: November 28, 2008Date of Patent: October 4, 2011Assignee: FUJIFILM CorporationInventor: Hiroyuki Yoneyama
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Patent number: 8008390Abstract: Polyoxymethylene molding compositions, their use, and moldings produced therefrom A ground molding composition is described, comprising a) a compounded material composed of i) at least one polyoxymethylene homo- and/or copolymer, ii) at least one impact modifier, and iii) optionally other conventional additives, which b) has been milled to give a powder at least 90% by weight of whose particles have a grain size of <600 ?m and a median grain size (D50) of from 100 to 500 ?m. These molding compositions can be processed to give moldings, in particular via rotomolding.Type: GrantFiled: September 14, 2006Date of Patent: August 30, 2011Assignee: Ticona GmbHInventors: Thomas Günnewig, Klaus Kurz, Guido Latz, Kirsten Markgraf
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Patent number: 7981949Abstract: A curable composition is described, including a gel material derived from the curable composition, and medical articles including such material, wherein the transparent gel material includes a polymerized monofunctional poly(alkylene oxide) macromonomer component and a surface modified nanoparticle component.Type: GrantFiled: May 23, 2006Date of Patent: July 19, 2011Assignee: 3M Innovative Properties CompanyInventors: Kelly S. Anderson, Kevin M. Lewandowski, David J. Plaut, Wendy L. Thompson, Babu N. Gaddam
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Patent number: 7910634Abstract: Disclosed are aqueous dispersions of polymer-enclosed particles, such as nanoparticles. Also disclosed are methods for making an aqueous dispersion of polymer-enclosed particles, polymerizable polymers useful in such a method, powder coating compositions formed from such an aqueous dispersion, substrates at least partially coated with such a composition, and reflective surfaces comprising a non-hiding coating layer deposited from such a composition.Type: GrantFiled: May 25, 2006Date of Patent: March 22, 2011Assignee: PPG Industries Ohio, Inc.Inventors: Shawn A. DeSaw, Dennis L. Faler, W. David Polk
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Patent number: 7893132Abstract: The present invention in a first embodiment relates to a conduit or automotive wire consisting of an inner conductor core surrounded by a flame retardant layer made of a polymer composition in a continuous process which composition comprises (A) an olefin homo- and/or copolymer, (B) a silicone-group containing compound, and (C) an inorganic filler, wherein the ratio of the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C. of component (A) to the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C. of the composition is higher than 3.5, and the wire has a length of at least 100 m. In a second embodiment, the present invention relates to a power or communications cable or wire comprising a flame retardant layer made of a polymer composition comprising (A) an olefin homo- and/or copolymer, (B) a silicone-group containing compound, and (C) an inorganic filler, wherein the ratio of the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C.Type: GrantFiled: February 22, 2006Date of Patent: February 22, 2011Assignee: Borealis Technology OyInventors: Bernt-{hacek over (A)}ke Sultan, Jonas Jungkvist, Urban Andreason, Lars-Erik Ahlstrand
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Patent number: 7884149Abstract: A nanocomposite material suitable for electrical insulation includes a polymer compounded with a substantially homogeneously distributed functionalized nanoparticle filler. The nanocomposite material is produced by compounding the polymer with the functionalized nanoparticle filler by imparting a shear force to a mixture of the polymer and filler capable of preventing agglomeration of the filler whereby the filler is substantially homogeneously distributed in the nanocomposite material. The electrical insulation may be adapted for AC or DC high voltage, and may also be adapted for low or medium voltage to prevent formation of water tree structures.Type: GrantFiled: July 17, 2009Date of Patent: February 8, 2011Assignee: Rensselaer Polytechnic Institute, Inc.Inventors: John Keith Nelson, Walter Zenger, Robert John Keefe, Linda Sue Schadler Feist
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Patent number: 7846993Abstract: The present invention relates to an organic silica master batch elastomer prepared by mixing a conjugated diene based copolymer, a vinyl aromatic copolymer or a mixture thereof prepared by solution polymerization with organically modified silica in which the surface of silica is modified with a particular organosilicon compound and a silane coupling agent in solution. The resultant organic silica master batch elastomer exhibits improved mechanical properties, wear resistance and blending processability, and can provide the effect of extending durability of a tire.Type: GrantFiled: October 15, 2008Date of Patent: December 7, 2010Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Young Hoon Ko, Jae Young Ko, Seung Kyung Ko
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Patent number: 7816009Abstract: Particles of metal and non-metal oxides may be readily functionalized with organosilyl groups, even in the absence of catalysts, when methylene-spaced alkoxysilanes are used for functionalizing. When an excess of alkoxy groups relative to metal-OH groups are present, the resulting functionalized particles exhibit high reactivity, particularly upon exposure to moisture. Functionalization is particularly useful with particles of organopolysiloxane resins.Type: GrantFiled: September 30, 2005Date of Patent: October 19, 2010Assignee: Wacker Chemie AGInventors: Christoph Briehn, Thomas Köhler, Yolker Staniek, Richard Weidner, Oliver Schafer
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Patent number: 7767736Abstract: A composition is described comprising an organic polymer or a polymerizable monomer, having dispersed therein a surface-modified particle phase, in an amount sufficient to reduce the flammability of the polymer.Type: GrantFiled: December 5, 2005Date of Patent: August 3, 2010Assignee: 3M Innovative Properties CompanyInventor: Jimmie R. Baran, Jr.
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Patent number: 7732047Abstract: A fiber size composition contains a modified polyolefin, a hydrophilic coupling agent, a boron-containing, fluorine-containing compound, a blend of at least two fatty acids and a compound selected from phosphorus(V) compounds and sulfur(VI) compounds, the fiber size composition being substantially free of conventional lower oxidation state antioxidants and optical brighteners. Composite materials produced from reinforcing fiber materials sized with a fiber size composition according to the invention exhibit improved properties such as, for example, increased strength and/or improved color stability.Type: GrantFiled: December 7, 2005Date of Patent: June 8, 2010Assignee: OCV Intellectual Capital, LLCInventors: Sanjay Kashikar, Jean-Marc Henrion, Les E. Campbell
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Publication number: 20100040858Abstract: A method of preparing carbon nanotube/polymer composite is disclosed, which includes: forming a layer of TiO2 on carbon nanotubes (CNTs) with a precursor of TiO2 by a sol-gel or hydrothermal method, a weight ratio of the TiO2 precursor to CNT being 0.3:1 to 30:1; modifying the TiO2-coated CNTs with a coupling agent to improve the affinity thereof to a polymer; and mixing a polymer with the resulting modified TiO2-coated CNTs to form a TiO2-coated CNT reinforced polymer composite. The mechanical properties of the polymer composite can be enhanced by using an additional fiber reinforcement material.Type: ApplicationFiled: October 20, 2009Publication date: February 18, 2010Applicant: National Tsing Hua UniversityInventors: Chen-Chi Martin Ma, Siu-Ming Yuen, Chia-Yi Chuang
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Publication number: 20090298369Abstract: Additive particles may be employed in sufficient amounts to impart superhydrophobicity to a coating system in which the additive particles are incorporated. The additive particles include carrier microparticles and a dense plurality of nanoparticles adhered to the surfaces of the carrier microparticles (e.g., preferably by electrostatic deposition or covalent bonding). The additive particles are advantageously incorporated into a coating material (e.g., a polymeric material) in amounts sufficient to render a substrate surface superhydrophobic when coated with the coating material. The substrate may be rigid (e.g., glass, ceramic or metal) or flexible (e.g., a polymeric film or sheet or a fabric). In some preferred embodiments, both the microparticle and nanoparticles are formed of silica and are surface treated with a hydrophobic treatment so as to impart superhydrophobic properties thereto.Type: ApplicationFiled: April 8, 2009Publication date: December 3, 2009Applicant: LUNA INNOVATIONS INCORPORATEDInventors: Bryan E. KOENE, Martin E. ROGERS, Jonas C. GUNTER
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Patent number: 7585563Abstract: A fiber-size composition contains a modified polyolefin, a hydrophilic coupling agent, and an enhancer with at least one of the following: a fluorine-containing compound, a hydrophobic coupling agent, a cyclic fatty acid, or at least two saturated fatty acids with at least one of said fatty acids having at least two acid groups. When reinforcing fiber materials sized with the composition are used to form composite articles, the articles show improved properties such as strength and color.Type: GrantFiled: November 5, 2004Date of Patent: September 8, 2009Assignee: OCV Intellectual Capital, LLCInventors: Sanjay Kashikar, Jean-Marc Henrion, Les E. Campbell
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Patent number: 7579397Abstract: A nanocomposite material suitable for electrical insulation includes a polymer compounded with a substantially homogeneously distributed functionalized nanoparticle filler. The nanocomposite material is produced by compounding the polymer with the functionalized nanoparticle filler by imparting a shear force to a mixture of the polymer and filler capable of preventing agglomeration of the filler whereby the filler is substantially homogeneously distributed in the nanocomposite material. The electrical insulation may be adapted for AC or DC high voltage, and may also be adapted for low or medium voltage to prevent formation of water tree structures.Type: GrantFiled: January 27, 2005Date of Patent: August 25, 2009Assignee: Rensselaer Polytechnic InstituteInventors: John Keith Nelson, Walter Zenger, Robert John Keefe, Linda Sue Schadler Feist
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Patent number: 7307121Abstract: This invention discloses a method for preparing rubber compositions that exhibit unique combinations of properties that are desirable for tire tread applications for enhanced snow/ice and wet traction, low rolling resistance and increased treadwear performance in comparison with conventional silica compounds. Specifically, a high reactively silane coupling agent, such as a mercaptosilane, is used in combination with a silane coupling typically used for silica tread compounds such as bis(triethoxylsilylpropyl)disulfide to treat silica pellets in a hydrocarbon solvent at elevated temperatures. The treated silica is then blended with solution elastomer cement in a hydrocarbon solvent. The deposited reactive silanes partially react with the elastomer molecules forming a layer of polymer grafted on the silica surfaced. This structure significantly improves the silica retention during the steam stripping operation. Almost 100% (99+%) silica retention has been achieved by this invention.Type: GrantFiled: March 19, 2004Date of Patent: December 11, 2007Assignee: The Goodyear Tire & Rubber CompanyInventors: Ping Zhang, Sun-Lin Chen
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Patent number: 7285584Abstract: The invention relates to a tire having at least one component comprised of a rubber composition which contains a hydrophobated, pre-silanized silica, namely a pre-silanized silica hydrophobated with an epoxidized soybean oil and/or epoxidized rubber tree seed oil in situ within said rubber composition. Such tire component may be, for example although not limited to, a tire tread, sidewall and/or sidewall insert.Type: GrantFiled: December 16, 2005Date of Patent: October 23, 2007Assignee: The Goodyear Tire & Rubber CompanyInventors: Wen-Liang Hsu, Shingo Futamura, Kuo-Chih Hua, Kenneth Allen Bates, Ping Zhang
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Patent number: 7252885Abstract: A surface contacting member for toner fusing systems and processes. This surface contacting member has a fluoroelastomer surface layer containing amorphous silica that has been surface treated with at least one organoaminosilane.Type: GrantFiled: November 18, 2004Date of Patent: August 7, 2007Assignee: Eastman Kodak CompanyInventors: Jerry A. Pickering, Stephen V. Davis, Theodora Miller
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Patent number: 7250080Abstract: An improved process for making an organosilicon compound surface-treated titanium dioxide material, comprising (a) forming a mixture of the titanium dioxide material in water, (b) wet milling the mixture, (c) adjusting the pH of the slurry resulting from step (b) to between about 5.0 and about 8.5, (d) after step (c), removing the titanium dioxide material from the mixture by vacuum or pressure filtration, (e) after step (d), washing the titanium dioxide material so removed, (f) after step (e), converting the washed titanium dioxide material to a fluid dispersion having a pH of from about 3.5 to less than about 7 via addition of a fluidizing agent comprising a water-soluble monoprotic acid, (g) after, or concurrently with, step (f), adding to the resulting dispersion of titanium dioxide material an organosilicon compound, with mixing, and (h) spray drying the dispersion of the washed titanium dioxide material resulting from step (g) to yield a dry titanium dioxide pigment powder.Type: GrantFiled: September 6, 2006Date of Patent: July 31, 2007Assignee: Tronox LLCInventors: Daniel H. Craig, Mark D. Westmeyer
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Patent number: 7226962Abstract: The invention provides a method for increasing the viscosity of halogenated (brominated) elastomeric copolymers of a C4 to C7 isomonoolefin (isobutylene) and a para-alkylstryrene (p-methylstyrene) by mixing the copolymer with a silica or clay particulate filler which has been contacted with an aminosilane containing at least one C1 to C4 alkoxy group and at least one primary, secondary or tertiary amine group. The resulting elastomer compositions are used to prepare thermoplastic elastomer blend compositions, containing more finely dispersed elastomers which results in compositions having improved mechanical properties.Type: GrantFiled: April 30, 2002Date of Patent: June 5, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: Andy H. Tsou, Hsien-Chang Wang, Kenneth O. McElrath, Ilan Duvdevani, Michael K. Lyon, Mun Fu Tse
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Patent number: 7141618Abstract: Powder coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed.Type: GrantFiled: June 3, 2002Date of Patent: November 28, 2006Assignee: PPG Industries Ohio, Inc.Inventors: John R. Schneider, Daniela White, Anthony M. Chasser, James B. O'Dwyer, Thomas R. Hockswender
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Process for the preparation of a suspension of silica in an optionally crosslinkable silicone matrix
Patent number: 7084193Abstract: The invention relates to the preparation of a suspension of precipitated silica in a silicone oil, this suspension being usable for the production of silicones crosslinkable by polyaddition or polycondensation (RTV elastomers). The object of the invention is to seek a compromise between on the one hand the cost and on the other hand the rheology and mechanical properties of the final RTVs. The invention achieves this object by providing a process for the preparation of a suspension of precipitated silica, treated with hexamethyldisilazane (HMDZ), in a crosslinkable silicone oil. This HMDZ is introduced in at least two fractions. The 1st fraction on the one hand corresponds to a proportion less than or equal to 15% by dry weight, based on the total amount of HMDZ, and on the other hand is first brought into contact with the precipitated silica and the water. The invention further relates to the production of a silicone elastomer composition from this suspension and to the composition thus obtained.Type: GrantFiled: November 21, 2001Date of Patent: August 1, 2006Assignee: Rhodia ChimieInventors: Scott Jackson, Alain Pouchelon -
Patent number: 7056449Abstract: An aqueous silica dispersion containing silica particles dispersed in an aqueous medium is provided. The surfaces of the silica particles are treated with reacted aminosilane compound. The aqueous silica dispersion also contains anionic polymeric dispersing agent. The dispersion of the silica particles into an aqueous medium containing both anionic polymeric dispersing agent and aminosilane compound allows the preparation of aqueous silica dispersions at higher solids and/or low viscosities than aqueous silica dispersions that are prepared without either the anionic polymeric dispersing agent or the aminosilane compound. The aqueous silica dispersion is combinable with aqueous emulsion polymers to modify the physical or appearance properties of articles formed from the emulsion polymer.Type: GrantFiled: August 4, 2003Date of Patent: June 6, 2006Assignee: Rohm and Haas CompanyInventor: Joseph Michael Hoefler
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Patent number: 6991852Abstract: A silica-based material that includes a silica-based substrate and a polymerized organic material disposed thereon. The polymerized organic material is made from reactive organic moieties bonded to the silica-based substrate.Type: GrantFiled: March 11, 2003Date of Patent: January 31, 2006Assignee: Regents of the University of MinnesotaInventors: Peter W. Carr, Marc A. Hillmyer, Huqun Liu, Hao Luo, Lianjia Ma, Brian C. Trammell
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Patent number: 6939903Abstract: A process for preparing a composite material is disclosed wherein the process comprises: A) sizing a natural fiber with a reactive organosilane; B) mixing the sized natural fiber with a polyolefin resin; and C) adding a functionalized polyolefin coupling agent to the mixture of the sized natural fiber and the polyolefin resin to provide said composite material.Type: GrantFiled: April 16, 2003Date of Patent: September 6, 2005Assignee: Crompton CorporationInventors: William D. Sigworth, Roger A. Cheney, Louis M. Panzer, Henry L. Mei
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Patent number: 6933327Abstract: A dental polymerizable and curable composition that can be used as a dental composite restorative featuring excellent handling property at the time of filling, a small contraction upon polymerization, a high bending strength, excellent surface smoothness and wear resistance, and a very good matching of color tone to the natural tooth after restored.Type: GrantFiled: August 16, 2001Date of Patent: August 23, 2005Assignee: Tokuyama CorporationInventors: Junichiro Yamakawa, Hideki Kazama
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Patent number: 6927244Abstract: A heat-resistant vibration damping rubber composition wherein 20-80 parts by weight of a powder of silica having a BET specific surface area of 20-70 m2/g is mixed with 100 parts by weight of an ethylene-propylene-diene rubber material, and a sulfur-containing silane coupling agent and a mercapto-based silane coupling agent are both mixed with the ethylene-propylene-diene rubber.Type: GrantFiled: April 30, 2003Date of Patent: August 9, 2005Assignee: Tokai Rubber Industries, Ltd.Inventors: Norihito Kimura, Akihiro Shibahara
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Patent number: 6916524Abstract: A marking (4, 5) is formed in an outer layer (3; 23; 43) comprising a polymer material with an inorganic main chain and with certain visual properties by at least one region (9; 29; 49) of the outer layer (3; 23; 43) of which at least one of the visual properties shows a deviation, visible to the human eye, from the same property in other regions (9; 29; 49?) of the outer layer (3; 23; 43). Since the marking (4, 5) is obtained by means of at least a locally changed visual property of material of the outer layer (3; 23; 43) itself, the marking (4, 5) does not constitute a substantial interruption of the outer layer (3; 23; 43), and the application of the marking (4, 5) does not cause any substantial unevennesses in the outer layer (3; 23; 43). The following are further described: an element having such an outer layer (3; 23; 43) and a method of applying such a marking (4, 5).Type: GrantFiled: November 6, 2000Date of Patent: July 12, 2005Assignee: Koninklijke Philips Electronics N.V.Inventor: Keng Kit Yeo
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Patent number: 6849673Abstract: A coating composition comprising, in admixture, a resin and aminosilane surface-treated barium sulfate particles, and methods of using it as a film forming coating. Low blistering, highly corrosion resistant and low viscosity coating compositions are provided.Type: GrantFiled: July 2, 2003Date of Patent: February 1, 2005Assignee: J. M. Huber CorporationInventor: Thomas J. Lynch
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Patent number: RE43452Abstract: The present invention provides a rubber composition and a pneumatic tire using the rubber composition. The rubber composition which comprises: a rubber component comprising a styrene-butadiene copolymer rubber or a blend of the styrene-butadiene copolymer rubber and another conjugated diene base rubber with the styrene-butadiene copolymer rubber being 70% by weight or more of the entire blend, and the entire content of styrene is 30 to 40% by weight of the entire rubber component; silica in an amount of 10 to 60 parts by weight per 100 parts by weight of the rubber component; a specific silane coupling agent, i.e., a bis (alkoxysilylalkyl)polysulfide having a polysulfide chain in which the distribution of sulfur is specified, in an amount of 1 to 20% by weight of the amount of silica; and carbon black, the sum of the amount of silica and carbon black being 60 to 130 parts by weight per 100 parts by weight of the rubber component.Type: GrantFiled: November 23, 2004Date of Patent: June 5, 2012Assignee: Bridgestone CorporationInventors: Shunji Araki, Kazuhiro Yanagisawa