Silicon Containing Organic Material Having An Atom Other Than Si, C, H, Or Oxygen Patents (Class 523/213)
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Patent number: 6268432Abstract: A filler/adhesive agent for display units containing a condensation reaction curable silicone composition including air oxidation-curable unsaturated compounds and for use as a filler or adhesive in display units whose construction is such that the cured product of said composition is exposed in the display section, which composition is capable of forming matte finished cured products with insignificant surface tact, is disclosed.Type: GrantFiled: September 30, 1999Date of Patent: July 31, 2001Assignee: Dow Corning Toray Silicone Co. Ltd.Inventors: Toshiki Nakata, Masayuki Onishi
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Patent number: 6265069Abstract: The present invention relates to inorganic particles, with the exception of silica, comprising at least one functionalized polyorganosiloxane grafted over all or part of their surface, the said polyorganosiloxane being functionalized by: at least one alkoxy group, and at least one organic group chosen from alkyls, alkenyls, mercaptoalkyls, sulphoxides, epoxys, (meth)acryloyloxy groups, amino groups, hydroxyl groups, siloxy groups, ethers, ketones, esters, phosphorus-containing groups or polymer portions comprising vinylaromatic, ether, amide or sulphur repeat units. The invention also relates to the process for the preparation of these particles. It also relates to compositions comprising the said particles and at least one thermoplastic polymer, particularly polyolefins.Type: GrantFiled: January 4, 1999Date of Patent: July 24, 2001Assignee: Rhodia ChimieInventors: Yves Bomal, Anny Guez, Gérard Velleret
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Patent number: 6265480Abstract: A silicone gel composition comprising (A) 100 parts by weight of an organopolysiloxane comprising 80 to 98 mole % of R(CH3)SiO2/2 units, 0.1 to 10.0 mole % of RSiO3/2 units, and 0.1 to 10 mole % of R(CH3)2SiO1/2 units, wherein R is methyl, phenyl, or alkenyl, and provided 0.25 to 4.0 mole % the R groups in the organopolysiloxane are alkenyl; (B) an organopolysiloxane having an average of at least 2 silicon-bonded hydrogen atoms per molecule in an amount sufficient to provide from 0.1 to 5 silicon-bonded hydrogen atoms per alkenyl group in component (A); (C) a platinum catalyst; (D) 0.01 to 10 parts by weight of a silica powder; and (E) 0.01 to 5 parts by weight of a thixotropic agent selected from at least one epoxy compound, at least one polyhydric alcohol, and mixtures thereof; wherein the silicone gel composition has an apparent viscosity ratio of 2.0 to 10.0 and cures to form a silicone gel having a ¼ consistency of 10 to 200.Type: GrantFiled: April 13, 2000Date of Patent: July 24, 2001Assignee: Dow Corning Toray Silicone Company, Ltd.Inventors: Hiroji Enami, Akihiro Nakamura
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Patent number: 6245834Abstract: Use of an effective amount of a specific combination of silicone compounds comprising the combination: of at least one functionalized polyorganosiloxane (abbreviated as POS) containing, per molecule, at least one functional siloxy unit (abbreviated as UN1) capable of binding chemically and/or physically with the hydroxylated surface sites of the silica particles, and of at least one functionalized organosilane (abbreviated as OS) containing, per molecule, at least one functional group (abbreviated as G1) capable of binding chemically and/or physically with the UN1 units and/or the hydroxylated sites of the silica particles and at least one other functional group (abbreviated as G2) capable of binding chemically and/or physically to the elastomer chains, as silica/elastomer coupling agent in the natural or synthetic elastomer compositions comprising a siliceous material as reinforcing filler intended for the manufacture of an article made of elastomer(s).Type: GrantFiled: July 7, 1998Date of Patent: June 12, 2001Assignee: Rhodia ChimieInventors: Yves Bomal, Olivier Durel
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Patent number: 6229036Abstract: Sulfanylsilanes of the formula X1X2X3Si—A—S—SiR1R2R3 are prepared by reacting mercaptosilanes of the formula X1X2X3Si—Alkyl—SH with chlorosilanes Cl—SiR1R2R3. They are used as coupling agents in rubber mixtures.Type: GrantFiled: September 29, 1999Date of Patent: May 8, 2001Assignee: Degussa-Hüls AktiengesellschaftInventors: Christoph Batz-Sohn, Hans-Detlef Luginsland
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Patent number: 6221950Abstract: Unvulcanized rubber mixture includes at least one rubber, aggregate, and at least one filler, wherein a surface of the at least one filler has been modified with a stimuli-sensitive substance. A filler for unvulcanized rubber mixtures includes a surface which has been modified with a stimuli-sensitive substance. A process for making an unvulcanized rubber mixture including at least one rubber, aggregate, and at least one filler, wherein a surface of the at least one filler has been modified with a stimuli-sensitive substance. The process includes coating a surface of at least one filler with a stimuli-sensitive substance to form at least one coated filler, and mixing the at least one coated filler with unvulcanized rubber and aggregate. A rubber product formed from an unvulcanized rubber mixture includes at least one rubber, aggregate, and at least one filler, wherein a surface of the at least one filler has been modified with a stimuli-sensitive substance.Type: GrantFiled: June 23, 1998Date of Patent: April 24, 2001Assignee: Continental AktiengesellschaftInventors: Gert Heinrich, Carla Recker
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Patent number: 6184306Abstract: The present invention relates to asymmetrical siloxy compounds of the formula wherein R1, R2 and R3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; and n is an integer of from 1 to 8.Type: GrantFiled: March 22, 2000Date of Patent: February 6, 2001Assignee: The Goodyear Tire & Rubber CompanyInventors: Thierry Florent Edme Materne, Giorgio Agostini, Friedrich Visel, Martin Paul Cohen
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Patent number: 6177505Abstract: A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1 (I) ≡Si—OCOR2 (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.Type: GrantFiled: August 30, 1996Date of Patent: January 23, 2001Assignee: The Yokohama Rubber Co., Ltd.Inventors: Fumito Yatsuyanagi, Kazunori Ishikawa, Yoshiaki Hashimura, Tetsuji Kawazura, Hiroyuki Kaido
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Patent number: 6147151Abstract: A tread rubber composition of excellent hydrophobic property and water repellency suitable to a studless tire of excellent performance on ice, comprising a diene rubber comprising at least one rubber selected from the group consisting of natural rubber, isoprene and polybutadiene as a main ingredient and, based on 100 parts by weight of the diene rubber, from 10 to 40 parts by weight of a clay comprising kaolinite as a main ingredient and having an oil absorption amount of from 50 to 70 g/100 g and 0.1 to 8 parts by weight of a silane coupling agent.Type: GrantFiled: November 21, 1994Date of Patent: November 14, 2000Assignee: Sumitomo Rubber Industries LimitedInventors: Takahiro Fukumoto, Yoko Nakada, Yoichi Mizuno, Kazuo Kadomaru
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Patent number: 6147143Abstract: The present invention provides a rubber composition and a pneumatic tire using the rubber composition. The rubber composition which comprises: a rubber component comprising a styrene-butadiene copolymer rubber or a blend of the styrene-butadiene copolymer rubber and another conjugated diene base rubber with the styrene-butadiene copolymer rubber being 70% by weight or more of the entire blend, and the entire content of styrene is 30 to 40% by weight of the entire rubber component; silica in an amount of 10 to 60 parts by weight per 100 parts by weight of the rubber component; a specific silane coupling agent, i.e., a bis(alkoxysilylalkyl)polysulfide having a polysulfide chain in which the distribution of sulfur is specified, in an amount of 1 to 20% by weight of the amount of silica; and carbon black, the sum of the amount of silica and carbon black being 60 to 130 parts by weight per 100 parts by weight of the rubber component.Type: GrantFiled: September 19, 1997Date of Patent: November 14, 2000Assignee: Bridgestone CorporationInventors: Shunji Araki, Kazuhiro Yanagisawa
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Patent number: 6140393Abstract: Rubber composition intended for the manufacture of tire casings which have mproved hysteretic properties and scorch safety, based on at least one elastomer and silica by way of reinforcing filler enclosing a reinforcing additive consisting of the mixture and/or the product of in situ reaction of at least one functionalized polyorganosiloxane compound containing, per molecule, at least one functional siloxy unit capable of bonding chemically and/or physically to the surface hydroxyl sites of the silica particles and at least one functionalized organosilane compound containing, per molecule, at least one functional group capable of bonding chemically and/or physically to the polyorganosiloxane and/or the hydroxyl sites of the silica particles and at least one other functional group capable of bonding chemically and/or physically to the polymer chains.Type: GrantFiled: January 10, 1997Date of Patent: October 31, 2000Assignee: Campagnie Generale des Etablissements Michelin-Michelin & CieInventors: Yves Bomal, Olivier Durel
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Patent number: 6130272Abstract: A process for making a flowable powdered base suitable for use in the formulation of liquid silicone rubber compositions that can be cured to form silicone elastomers. The process comprises (A) fluidizing a reinforcing silica filler in a high-shear mixer, (B) maintaining the content of the mixer at a temperature below about 60.degree. C. while adding to the mixer a silylating agent, a nitrogen containing compound to facilitate the silylation reaction, and water thereby forming an essentially homogeneous mixture comprising a treated reinforcing silica filler; (C) adding a polydiorganosiloxane having a viscosity of about 0.03 to 300 Pa.s at 25.degree. C. to the mixer and forming a flowable powdered base having an average particle size of from about 1 to 1000 microns, and (D) heating the flowable powdered base under conditions sufficient to remove volatiles.Type: GrantFiled: October 29, 1998Date of Patent: October 10, 2000Assignee: Dow Corning CorporationInventors: Steven F. Dopp, Phillip Joseph Griffith, Jary David Jensen, Herschel Henry Reese
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Patent number: 6127458Abstract: The invention provides an artificial stone of the following composition, having a deep color tone and gloss, and a highly dense and uniform structure.An inorganic fine particle component having a size of 10 to 70 mesh is used, and the sum of the inorganic fine particle component and an inorganic microparticle component having a size of 100 mesh under accounts for at least 85 wt. % of the entire product, and a resin component accounts for under 15 wt. %. All or part of the fine particle component is surface-coating-hardened in advance by an inorganic or organic substance. The artificial stone of the invention has a uniform composition of the individual components, and fine particles are exposed on the surface by polishing.Type: GrantFiled: July 9, 1997Date of Patent: October 3, 2000Assignee: Doppel Co., Ltd.Inventor: Tsuyoshi Sakai
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Patent number: 6114432Abstract: Disclosed herein are a diene rubber composition comprising 100 parts by weight of a diene rubber component composed of 10-100 wt. % of an amino group-containing diene copolymer rubber (A) having a composition (based on the bound amount) of 40-99.95 wt. % of a conjugated diene monomer, 0.05-20 wt. % of an amino group-containing monomer and 0-55 wt. % of an aromatic vinyl monomer, and 0-90 wt. % of another diene rubber (B), and 10-150 parts by weight of silica having a specific surface area of 50-220 m.sup.2 /g as determined by nitrogen absorption (BET method), and having excellent heat build-up resistance, tensile properties, abrasion properties and processability, and a preparation method thereof.Type: GrantFiled: September 24, 1997Date of Patent: September 5, 2000Assignee: Nippon Zeon Co., Ltd.Inventors: Yukio Takagishi, Masao Nakamura
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Patent number: 6103380Abstract: A modified particle is disclosed wherein a particle has an attached group having the formula: ##STR1## wherein Ar represents an aromatic group; R.sup.1 represents a bond, an arylene group, an alkylene group ##STR2## wherein R.sup.4 is an alkyl or alkylene group or an aryl or arylene group; R.sup.2 and R.sup.3, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.5, --NHR.sup.5, --NR.sup.5 R.sup.5, or --SR.sup.5, wherein R.sup.5, which is the same or different, represents an alkyl group or an aryl group; and Q represents a labile halide containing species. Also disclosed is a modified particle or aggregate having attached a group having the formula: ##STR3## wherein CoupA represents a Si-containing group, a Ti-containing group, or a Zr-containing group; R.sup.8 and R.sup.9, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.10, --NHR.sup.10, --NR.sup.10 R.sup.10, or --SR.sup.10, wherein R.sup.Type: GrantFiled: June 3, 1998Date of Patent: August 15, 2000Assignee: Cabot CorporationInventor: Wayne Devonport
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Patent number: 6096832Abstract: The present invention relates to asymmetrical siloxy compounds of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R.sup.4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; and n is an integer of from 1 to 8.Type: GrantFiled: February 18, 1999Date of Patent: August 1, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Thierry Florent Edme Materne, Giorgio Agostini, Friedrich Visel, Martin Paul Cohen
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Patent number: 6071997Abstract: A three-dimensional composite of silica spheres interconnected by resin is provided having a three-dimensional network structure including silica particles having the following structural and dynamic characteristics and a resin present in the internal pores of said network:(a) three-dimensionally interconnected spherical silica particles having a diameter of 6 to 30 .mu.m;(b) on the surface of said spherical silica particles, a specific surface area of 300 to 400 m.sup.Type: GrantFiled: May 14, 1997Date of Patent: June 6, 2000Assignee: Agency of Industrial Science and TechnologyInventors: Yuko Tanaka, Muneaki Yamaguchi, Hiromasa Ogawa, Katsutoshi Tanaka
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Patent number: 6046349Abstract: Oligomeric organosilicon compounds are disclosed of the formula I ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 independently of one another denote H, (C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4) alkoxy, (C.sub.1 -C.sub.4) haloalkoxy, (C.sub.1 -C.sub.4)haloalkyl, phenyl, aryl or aralkyl andZ denotes an alkylidene radical having 0-6 carbon atoms, x can be a statistical average of 1-6 andn=1-150 and . . . means that z can be bonded either to the one or the other C atom, and the particular free valency is occupied by a hydrogen.and their use in rubber mixtures and for the production of shaped articles, in particular pneumatic tires.Type: GrantFiled: June 30, 1999Date of Patent: April 4, 2000Assignee: Degussa-Huels AktiengesellschaftInventors: Christoph Batz-Sohn, Hans-Detlef Luginsland
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Patent number: 6033597Abstract: A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a compounding agent comprising a mixture of a polysiloxane having the following alkoxysilyl group (I) and having an average degree of polymerization of 3 to 10,000:.tbd.Si--OR.sup.1 (I).tbd.Si--OCOR.sup.2 (II)wherein, R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R.sup.2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms, and a sulfur containing silane.Type: GrantFiled: November 10, 1998Date of Patent: March 7, 2000Assignee: The Yokohama Rubber Co., Ltd.Inventors: Fumito Yatsuyanagi, Kazunori Ishikawa, Yoshiaki Hashimura, Tetsuji Kawazura, Hiroyuki Kaido
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Patent number: 6025415Abstract: Mixtures of oxidic and/or siliceous fillers and rubbers are produced by adding at least one water-repellent oxidic and/or siliceous filler to the solution of a rubber in an organic solvent in quantities from 0.5 to 300 parts by weight, based on 100 parts by weight of rubber, wherein the solution of the rubber may contain other auxiliary agents for working up, processing and stabilizing as well as additional fillers, and the solvent is subsequently removed by steam distillation at temperatures from 50 to 200.degree. C.Type: GrantFiled: July 2, 1998Date of Patent: February 15, 2000Assignee: Bayer AktiengesellschaftInventor: Thomas Scholl
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Patent number: 6022911Abstract: Colored substrate particles which are mainly used in metallic finish of automobiles, domestic electrical articles, tools and the like, decorative finish of plastics, printing ink and the like are disclosed herein. According to the present invention, adhesive property of a color pigment to substrate particles is improved by coating the surface of the color pigment with a specific surface-treatment agent. The colored substrate particles are preferably coated with a polymer polymerized by in situ polymerization, thereby the adhesion of the color pigment to the substrate particles can be further improved.Type: GrantFiled: January 15, 1999Date of Patent: February 8, 2000Assignee: Toyo Aluminium Kabushiki KaishaInventors: Yoshiki Hashizume, Satosi Kobayashi
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Patent number: 6022919Abstract: A coating composition which comprises (A) a resin having a glass transition temperature of 50 to 120.degree. C., a number average molecular weight of 2,000 to 100,000, a hydroxyl value of 50 to 150 mgKOH/g and an acid value of 1 to 25 mgKOH/g, which is produced by copolymerizing 10 to 90 percent by weight of (a) a (meth)acrylic acid ester of a C.sub.1 to C.sub.12 alkyl alcohol, 10 to 50 weight % of (b) a first polymerizable double bond-containing and hydroxyl group-containing monomer, 0.Type: GrantFiled: November 27, 1996Date of Patent: February 8, 2000Assignee: NOF CorporationInventors: Keiji Komoto, Keishi Yoshikai, Masahiko Hirono, Yoshifumi Ohama
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Patent number: 6011087Abstract: Modified mineral fillers, derived from either a coarse particle kaolin clay or a coarse particle ATH, having excellent utility in thermoset polymers as low paste viscosity fillers are disclosed. The method of treatment involves the use of specific weight ratio combinations of a silane and a long chain aliphatic alcohol. The treatment of clay can also involve the auxiliary use of a surfactant in small amounts, which is utilized to emulsify the silane and aliphatic alcohol treatment components in water either individually or as a co-emulsion blend prior to their addition to the clay. The surfactant, which is preferably a nonionic surfactant having a HLB value of 12-18, aides in uniformly treating all the clay particle surfaces with the silane/alcohol treatment combination. Coarse particle clays having general utility in the invention are those having an average Stokes equivalent particle diameter of at least 3.Type: GrantFiled: December 22, 1997Date of Patent: January 4, 2000Assignee: J.M. Huber CorporationInventors: Carl J. Marshall, Thomas J. Lynch, Gary M. Freeman
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Patent number: 6005028Abstract: Alkoxides with polymerizable groups are single source precursors for organic-inorganic hybrid composites possessing good mechanical properties. Additional function groups of the alkoxides provide enhanced adhesion to other surfaces, such as dentin. The selection of specific organic monomers having functional groups that are responsible for enhanced properties of the organic-inorganic hybrid composites is important. Single source precursors containing the desired functional groups are condensed and polymerized into the organic-inorganic hybrid composites with enhanced properties which are particularly useful as dental composites.Type: GrantFiled: August 12, 1996Date of Patent: December 21, 1999Assignee: Southwest Research InstituteInventor: Partha P. Paul
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Patent number: 5998504Abstract: The present invention relates to colloidal metal oxides having blocked isocyanate groups, which are based on the reaction product ofA) blocked isocyanate group-containing silanes corresponding to formula (I) ##STR1## wherein R represents hydrogen or an organic group having 1 to 40 carbon atoms,X, Y and Z represent identical or different organic groups having 1 to 30 carbon atoms which are inert to isocyanate groups below 100.degree. C., provided that at least one of these groups is a C.sub.1 -C.sub.4 -alkoxy group,Q represents an organic group which contains at least one isocyanate group reacted with a blocking agent andn is 2, 3 or 4 withB) colloidal metal oxides selected from Al, Si, Ti, Ta, W, Hf, Zr, Sn and Y.The present invention also relates to the use of modified metal oxides, either alone or in combination with compounds containing at least two isocyanate-reactive groups, for the preparation of optionally expanded polyurethane plastics, lacquers or coating agents.Type: GrantFiled: April 3, 1998Date of Patent: December 7, 1999Assignee: Bayer AktiengesellschaftInventors: Stefan Groth, Claus Kobusch, Lutz Schmalstieg, Lothar Puppe, Theodor Engbert, Manfred Bock, Gerhard Jonschker
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Patent number: 5990211Abstract: In a method for kneading a silane coupling agent-blended rubber composition prepared by blending a natural rubber and/or a diene group synthetic rubber with silica and a silane coupling agent, a coupling reaction of the silica with the silane coupling agent is carried out in a temperature range of 130 to 140.degree. C.Type: GrantFiled: December 20, 1996Date of Patent: November 23, 1999Assignee: Bridgestone CorporationInventor: Masashi Yano
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Patent number: 5985953Abstract: A compatibilized silica for incorporation into natural and synthetic polymers in latex form or dry blending operations is described. Said compatibilized silica is formed by the reaction of precipitated or fumed silica with organosilicon coupling compounds in aqueous suspension. Polymer-silica reinforced masterbatches are prepared by addition of the compatibilized silica slurry to natural and synthetic polymer latices. Also described is a process for preparing the compatibilized silica.Type: GrantFiled: October 17, 1997Date of Patent: November 16, 1999Assignee: DSM Copolymer, Inc.Inventors: John W. Lightsey, David J. Kneiling, John M. Long, Andrew C. Kolbert
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Patent number: 5973030Abstract: Liquid silicone rubber compositions that prior to cure have good fluidity and excellent moldability and that cure into a highly flame retardant silicone rubber with excellent high-voltage electrical insulating properties. The liquid silicone rubber compositions comprise: (A) polyorganosiloxane; (B) fumed silica; (C) surface-treated zinc carbonate powder as afforded by treating the surface of (a) zinc carbonate powder or basic zinc carbonate powder with (b) an organosilicon compound selected from organosilanes, organosilazanes, and organosiloxane oligomers; (D) polyorganohydrogensiloxane; and (E) platinum catalyst. The liquid silicone rubber compositions may further comprise (F) surface treated aluminum hydroxide powder, (G) triazole compound, and (H) a reaction mixture of (d) platinum compound and (e) 3,5-dimethyl-1-hexyn-3-ol.Type: GrantFiled: May 22, 1997Date of Patent: October 26, 1999Assignee: Dow Corning Toray Silicon Co., Ltd.Inventors: Takao Matsushita, Yasumichi Shigehisa, Yuichi Tsuji
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Patent number: 5962553Abstract: Nanocomposites are made by melt-blending a melt processable polymer having a high melt processing temperature and an organophosphonium cation modified layered clay. Such modified layered clay is more stable at the higher temperatures encountered during the melt processing of such a melt processable polymer than the modified layered clays used in the prior art, enabling the preparation of the nanocomposite.Type: GrantFiled: September 3, 1996Date of Patent: October 5, 1999Assignee: Raychem CorporationInventor: Mark W. Ellsworth
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Patent number: 5959005Abstract: Silica with the following physico-chemical properties:______________________________________ Specific surface m.sup.2 /g 80-400 Primary particle size nm 7-40 Tapped density g/l 50-300 pH value 3-10 Carbon content % 0.1-15 DBP number % <200 ______________________________________is produced by spraying a silica under intensive mixing, optionally with water or dilute acid at first and then with a surface-modifying reagent or a mixture of several surface-modifying reagents, then mixing, tempering, and subsequently destructuring/compressing and grinding.Type: GrantFiled: April 14, 1997Date of Patent: September 28, 1999Assignee: Degussa-Huls AktiengesellschaftInventors: Werner Hartmann, Juergen Meyer, Hauke Jacobsen, Thomas Hennig, Henning Karbe, Uwe Schachtely
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Patent number: 5958598Abstract: Transparent substrates are rendered resistant to fogging by the application of a hardcoat composition comprising finely divided silica, a multi-functional olefin containing two or more olefinic moieties and one or more divalent oxyalkylene radicals having the formula:--((CX.sub.2).sub.n O).sub.x ((CX.sub.2).sub.m O).sub.y --where the sum of the x stoichiometric subscripts for each divalent oxyalkylene radical and the sum of the y stoichiometric subscripts for each divalent oxyalkylene radical when said sums are added together is ten or greater and the stoichiometric subscripts n and m are different and have values independently ranging from one to ten, where each X is independently selected from the group consisting of hydrogen, one to forty carbon atom monovalent hydrocarbon radicals and six to forty carbon atom monovalent aromatic hydrocarbon and an olefinically functionalized trialkoxysilane followed by curing.Type: GrantFiled: February 5, 1998Date of Patent: September 28, 1999Assignee: General Electric CompanyInventors: Igor V. Khudyakov, George F. Medford
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Patent number: 5948387Abstract: Novel contrast media for use in ultrasonic imaging are described. Such contrast media may be comprised of an aqueous solution of one or more biocompatible polymers, wherein said biocompatible polymers are coated with and/or in admixture with at least one silicon containing compound. Alternatively, the contrast media may be comprised of an aqueous solution of one or more biocompatible synthetic polymers, or an aqueous solution of cellulose. The contrast media may be employed, if desired, with anti-gas agents and/or suspending agents.Type: GrantFiled: May 9, 1997Date of Patent: September 7, 1999Assignee: Imarx Pharmaceutical Corp.Inventors: Evan C. Unger, Guanli Wu
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Patent number: 5948854Abstract: Alkoxy-functional room temperature vulcanizing (RTV) compositions, curable in the presence of moisture, comprising polymers containing on average at least 1.2 alkoxysilyl chain terminations per molecule, a tetraalkoxytitanium compound containing on average greater than 90 mole percent of the alkoxy groups as tertiary amyloxy groups, a filler, and an alkoxysilane. The addition of these components in amounts to satisfy defined molar ratios provide alkoxy-functional RTV compositions having both improved storage stability and improved green strength upon curing.Type: GrantFiled: September 25, 1997Date of Patent: September 7, 1999Assignees: Dow Corning S.A., Dow Corning CorporationInventors: Francois de Buyl, Robert H. Krahnke, Timothy B. Lueder, Richard A. Palmer
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Patent number: 5948835Abstract: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance, lower hysteresis at high temperature and comparable or increased hysteresis at low temperature compared to an elastomer containing an untreated carbon black. A variety of elastomers and formulations employing such elastomers are contemplated and disclosed. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed is method for preparing elastomers compounded with the treated carbon black.Type: GrantFiled: June 18, 1997Date of Patent: September 7, 1999Assignee: Cabot CorporationInventors: Khaled Mahmud, Meng-Jiao Wang, Robert A. Francis
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Patent number: 5936112Abstract: Mixtures are disclosed of bis(silylorganyl)polysulfanes and silylorganylthiocyanates, which are produced by reacting polysulfanes with cyanides. The inorganic thiocyanate formed is subsequently allowed to react with a haloalkylalkoxysilane to form the silylorganylthiocyanate. These substances are used in plastic and rubber mixtures reinforced with silica and optionally carbon black.Type: GrantFiled: July 10, 1998Date of Patent: August 10, 1999Assignee: Degussa AktiengesellschaftInventors: Thomas Gobel, Ulrich Deschler, Jorg Munzenberg, Gerd Zezulka
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Patent number: 5929143Abstract: The present invention provides novel vinyl containing organopolysiloxane elastomers which possess excellent low compression set and heat aging characteristics and which can advantageously be formulated into liquid silicone elastomer moldable compositions.Type: GrantFiled: October 16, 1997Date of Patent: July 27, 1999Assignee: General Electric CompanyInventors: Brian John Ward, Edward Matthew Jeram, Richard Albert Striker
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Patent number: 5922470Abstract: An article comprising a soft, polysiloxane elastomer having a hardness of 5-55 durometer units (Shore 00), the elastomer having a pressure sensitive adhesive on at least one of its surfaces is described. A process for bonding a pressure sensitive adhesive to the soft polysiloxane elastomeric is also described.Type: GrantFiled: May 26, 1995Date of Patent: July 13, 1999Assignee: Schering-Plough HealthCare Products, Inc.Inventors: Ronald L. Bracken, Gerald R. Dever, Ronald M. Feret, Daniel B. Snyder
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Patent number: 5912283Abstract: Colored substrate particles which are mainly used in metallic finish of automobiles, domestic electrical articles, tools and the like, decorative finish of plastics, printing ink and the like are disclosed herein. According to the present invention, adhesive property of a color pigment to substrate particles is improved by coating the surface of the color pigment with a specific surface-treatment agent. The colored substrate particles are preferably coated with a polymer polymerized by in situ polymerization, thereby the adhesion of the color pigment to the substrate particles can be further improved.Type: GrantFiled: July 19, 1996Date of Patent: June 15, 1999Assignee: Toyo Aluminium Kabushiki KaishaInventors: Yoshiki Hashizume, Satosi Kobayashi
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Patent number: 5910523Abstract: Composites from a semi-crystalline polyolefin and nanometer sized fillers with improved modulus, tensile strength and crack growth resistance are disclosed. The nanometer sized fillers are first functionalized with an aminosilane. Thereafter, a carboxylated or maleated polyolefin is grafted to the filler through an amine-carboxyl reaction. The resulting modified filler is dispersed in a semi-crystalline polyolefin (eg. polyethylene or polypropylene). Co-crystallization between the carboxylated or maleated polyolefin and the semi-crystalline polyolefin can improve interaction between the filler and semi-crystalline polyolefin.Type: GrantFiled: December 1, 1997Date of Patent: June 8, 1999Inventor: Steven David Hudson
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Patent number: 5908879Abstract: A coated particle is described, which includes a metal fluoride particle and a polysiloxane coating on the surface of the particle. A dental composition is also described, which includes the coated particle, a polymerizable monomer, and a polymerization initiator.Type: GrantFiled: July 25, 1997Date of Patent: June 1, 1999Assignee: Kuraray Co., Ltd.Inventors: Mitsunobu Kawashima, Kenichi Hino
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Patent number: 5908878Abstract: The present invention is a heat curable polyorganosiloxane composition comprising (A) a first polydiorganosiloxane having two diorganoalkenylsiloxy terminal groups per molecule and a total concentration of unsaturated hydrocarbon radicals of 0.118 to 0.156 mole percent; (B) a second polydiorganosiloxane having two diorganoalkenysiloxy terminal groups per molecule, and no detectable concentration of pendant unsaturated hydrocarbon radicals; (C) a third polydiorganosiloxane having two diorganoalkenysiloxy terminal groups per molecule and a total concentration of unsaturated hydrocarbon radicals of 1.37 to 2.24 mole percent; wherein the weight ratio of polydiorganoiloxanes (A), (B), and (C) satisfy the relationship (C)/(A+B)=0.0379 to 0.1071 and A/B=1.460 to 2.115; (D) a crosslinker containing silicone-hydrogen bonds, wherein the ratio of silicone-hydrogen bonds to the total ethylenically unsaturated hydrocarbon radicals present on the polydiorganosilanes (A), (B), and (C) is from 1.00 to 2.Type: GrantFiled: September 22, 1997Date of Patent: June 1, 1999Assignee: Dow Corning CorporationInventors: Judith Diane Fairclough Baity, Chana Wilson Evans, Alan La Verne Himstedt
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Patent number: 5904988Abstract: Room temperature vulcanizable coating compositions, useful as anti-fouling coatings for marine structures such as ships, are prepared by a method comprising the steps of first blending a particulate reinforcing filler such as silica with a non-reactive polyorganosiloxane oil under high shear conditions, and subsequently combining the resulting masterbatch with at least one reactive polyorganosiloxane having a relatively low viscosity, a condensation catalyst and a crosslinking agent. The resulting compositions are sprayable in the absence of solvents, although solvents may be added if desired.Type: GrantFiled: May 27, 1997Date of Patent: May 18, 1999Assignee: General Electric CompanyInventors: Judith Stein, Timothy Brydon Burnell
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Patent number: 5900450Abstract: A method for preparing a three dimensionally connected silica spheres-resin composite, which comprises hydrolyzing and polymerizing a low molecular weight polyalkoxysilane in the presence of an acid catalyst in a mixed solution of the low molecular weight polyalkoxysilane and a water-soluble polymer in a solvent mixture of water and alcohol to obtain a three dimensional connected silica spheres, impregnating the three dimensional connected silica spheres with at least one material selected from resin-forming monomers and resin-forming prepolymers, and curing the material. The composite obtained by the above method retains its strength even at high temperatures where the organic matter undergoes pyrolysis or burnout.Type: GrantFiled: May 22, 1997Date of Patent: May 4, 1999Assignee: Agency of Industrial Science & TechnologyInventors: Yuko Tanaka, Muneaki Yamaguchi, Hiromasa Ogawa, Katsutoshi Tanaka
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Patent number: 5863968Abstract: A high-consistency organosiloxane composition comprising fluorinated and non-fluorinated polyorganosiloxanes, which upon the addition of suitable cure components can be cured to form elastomers having improved tear strength and good resistance to hydrocarbon oil weep. The present composition comprises a reinforcing silica filler that has been treated with a tetraalkyldisilazane.Type: GrantFiled: April 19, 1996Date of Patent: January 26, 1999Assignee: Dow Corning CorporationInventors: Paul Thomas Irish, Myron Timothy Maxson
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Patent number: 5863969Abstract: The present invention provides novel vinyl containing organopolysiloxane elastomers which possess excellent low compression set and heat aging characteristics and which can advantageously be formulated into liquid silicone elastomer moldable compositions.Type: GrantFiled: October 20, 1997Date of Patent: January 26, 1999Assignee: General Electric CompanyInventors: Brian J. Ward, Edward M. Jeram, Richard A. Striker
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Patent number: 5861448Abstract: A platinum curing organosiloxane composition having improved hysteresis characteristics when cured. The composition requires the presence of a diorganovinylsiloxy terminated polydiorganosiloxane having a viscosity within a range of about 20 Pa.multidot.s to 200 Pa.multidot.s at 25.degree. C. and containing essentially no ethylenically unsaturated hydrocarbon radicals bonded to non-terminal silicon atoms and a diorganovinylsiloxy terminated polydiorganosiloxane having a viscosity within a range of about 0.1 Pa.multidot.s to 200 Pa.multidot.s at 25.degree. C., where from 1 to 5 percent of the non-terminal repeating units of the siloxane comprise a vinyl radical. In addition, the present composition comprises 10 to 30 weight percent of a reinforcing silica filler that has been treated with hexamethyldisilazane and 1,1,3,3-tetramethyl-1,3-divinyldisilazane, and an organohydrogensiloxane resin crosslinker comprising greater than 5 silicon-bonded hydrogen atoms per molecule.Type: GrantFiled: January 31, 1997Date of Patent: January 19, 1999Assignee: Dow Corning CorporationInventors: Phillip Joseph Griffith, Chu Yat Ho, Diane Marie Kosal
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Patent number: 5852099Abstract: The object of the present invention is a rubber composition which is inted for the manufacture of tires and has a base of precipitated silicas "doped" with aluminum, the aluminum content being between .gtoreq.0.35% and .ltoreq.3% by weight of silica. Said composition has improved working properties as well as improved hysteresis properties.Type: GrantFiled: March 5, 1996Date of Patent: December 22, 1998Assignee: Compagnie Generale des Etablissements Michelin--Michelin & CieInventor: Robert Vanel
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Patent number: 5852108Abstract: A composite particulate material for resin reinforcement which comprises an inorganic particulate material (A) and an elastic polymer (B) having a glass transition temperature of -10.degree. C. or below and also having functional groups capable of forming chemical bonds with resins to be reinforced, said components (A) and (B) accounting for 50-99 wt % and 50-1 wt %, respectively, of their total amount. A process for producing said composite particulate material. A reinforced resin composition incorporated with said composite particulate material. The resin composition yields molded articles which are improved in mutually contradicting properties (that is, impact strength vs. stiffness and elongation at break vs. heat resistance) and which have mechanical properties with less anisotropy. It offers good characteristic properties which are hardly attained by conventional engineering plastic materials.Type: GrantFiled: February 7, 1996Date of Patent: December 22, 1998Assignee: Toray Industries, Inc.Inventors: Toru Yamanaka, Mitsunari Sotokawa, Shinobu Nakashima
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Patent number: 5827908Abstract: An epoxy resin composition is provided that mainly comprises an epoxy resin, a curing agent, and an inorganic filler, and that cures into a product having a coefficient of water diffusion of up to 1.times.10.sup.-4 cm.sup.2 /hr. at a thickness of 3 mm under humid conditions at 85.degree. C. and RH 85%, wherein 1-50% by weight of an inorganic water absorbing agent such as molecular sieve, silica gel and porous silica is added to the epoxy resin composition. The composition offers cured products having fully low moisture permeability and is thus suitable as a pre-molded hollow package-forming material.Type: GrantFiled: February 6, 1997Date of Patent: October 27, 1998Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuhiro Arai, Tadaharu Ikeda, Toshio Shiobara
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Patent number: 5804644Abstract: A rubber composition comprising(A) 100 parts by weight of a raw material rubber which contains not less than 30% by weight of at least one partially hydrogenated rubber of a conjugated diene rubber, wherein 5 to 70% of the unsaturated double bonds of the conjugated diene portion thereof have been hydrogenated;(B) 10 to 150 parts by weight of a silica;(C) 0.1 to 20 parts by weight of an organo-silane coupling agent; and(D) 0.1 to 10 parts by weight of a vulcanizing agent. The rubber composition of the present invention has extremely excellent resilience, low exothermic property, and excellent wet skid resistance, and further improved processability, and therefore, by utilizing the characteristics, can be used to make industrial parts such as tires for various types of automobiles, rubber vibration insulators, belts, and the like.Type: GrantFiled: January 15, 1997Date of Patent: September 8, 1998Assignee: Asahi Kasei Kabushiki KaishaInventors: Yasunobu Nakafutami, Akira Saito, Tsuyoshi Sugiyama