Silicon Containing Organic Material Having An Atom Other Than Si, C, H, Or Oxygen Patents (Class 523/213)
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Patent number: 6846855Abstract: A sizing composition and method for manufacturing such, which is suitable for use in manufacturing fiber-reinforced composites which have desirable properties such as high strength, high resistance to water and chemical degradation, and improved coloring. This is achieved in part by good adhesion of the sizing composition to the reinforcing fibers and the polymer matrix. The sizing composition includes an emulsion having a grafted polyolefin, two or more saturated fatty acids, and one or more silane coupling agents. When reinforcing fiber materials sized according to the invention are used in a molding process, the resulting composites are observed to show minimal discoloration.Type: GrantFiled: May 1, 2001Date of Patent: January 25, 2005Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Les E. Campbell, Sanjay P. Kashikar
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Patent number: 6831117Abstract: With the hardener particle of the present invention, because siloxane or an alkoxy group is bonded to a central metal located on a surface, an adhesive prepared by dispersing the hardener particles in an epoxy resin together with a silane coupling agent hardly causes reaction between the hardener particles and the silane coupling agent at ambient temperature whereby the preserving property of the adhesive is high. Because no siloxane is bonded to metal chelate or metal alcoholate at the part other than the surface of the hardener particles, the hardener particles are broken when the adhesive is heated, and the metal chelate and the metal alcoholate on the part other than the surface of the hardener particles reacts with the silane coupling agent to form cation, thereby polymerizing the epoxy resin with the cation to harden the adhesive even at low temperature within shorter time.Type: GrantFiled: December 5, 2002Date of Patent: December 14, 2004Assignee: Sony Chemicals CorporationInventor: Takayuki Matsushima
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Patent number: 6822020Abstract: Modified silica fillers are prepared by contacting silica with blends or mixtures containing diorganodihalosilanes and tetrahalosilanes in weight ratios of 1:0.1 to 1:2, respectively. While dialkyldichlorosilanes and tetrahalosilanes such as dimethyldichlorosilane and silicon tetrachloride, respectively, are most preferred, the blends or mixtures may also comprise compositions containing other silanes such as mercaptopropyltriethoxysilane.Type: GrantFiled: July 18, 2002Date of Patent: November 23, 2004Assignee: Dow Corning CorporationInventor: Anthony Revis
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Patent number: 6808808Abstract: A coating composition and a pigment comprising a surface-treated clay mixture used therein, and, optionally, microspheres, in which the coating composition comprises a curable or hardenable resin system into which is dispersed the pigment. High build, corrosion resistant coating compositions are provided having high pigment content, which translates into lower material costs, attributable at least in part to the particle packing benefits derived from the unique clay mixture used as a filler.Type: GrantFiled: January 14, 2003Date of Patent: October 26, 2004Inventors: Gary M. Freeman, William G. Setser
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Patent number: 6756425Abstract: A condensation curable silicone rubber composition is provided which is able to suppress increases in viscosity over time, has an adequate pot life and excellent mold releasability, and displays favorable urethane molding durability. The composition includes: (A) an organopolysiloxane represented by a general formula (I), wherein, each R1 represents, independently, a substituted or unsubstituted monovalent hydrocarbon group, and n represents a number which results in a viscosity at 25° C. of 100 to 500,000 mm2/s, with a viscosity at 25° C. of 100 to 500,000 mm2/s; (B) a surface-treated reinforcing fine silica powder with a specific surface area as measured by a BET method of at least 50 m2/g, and a tap density of 0.2 to 0.4 g/ml, which has undergone treatment with an organosilicon compound to produce a quantity of surface carbon of at least 2.5% by weight; and (C) a tin compound-based curing catalyst.Type: GrantFiled: November 12, 2002Date of Patent: June 29, 2004Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hiroshi Mogi, Yoshifumi Inoue
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Patent number: 6750285Abstract: One embodiment is directed to an adhesive composition that is clear, flexible, and is devoid of non-polar additives and comprises molecules that are polar and particles having a lipophilic surface. In one embodiment, the particles range from 7 nm to 3 &mgr;m in diameter and the adhesive layer is between 0.1 and 5 &mgr;m thick. The particles may be alkyl-converted fumed silica, porous polymer-coated surfaces, or styrene/divinyl benzene polymer. The particles absorb non-polar oils or lubricants that prevent adhesion between printable media and the adhesive layer of the film. The present disclosure is a general solution for oily or lubricated substrates or printed areas. Oily materials are used in inks, dry powder toners, liquid EP toners, and in printers and copiers. The present teachings allow the adhesive to bond well to print media surfaces.Type: GrantFiled: August 19, 2002Date of Patent: June 15, 2004Assignee: Hewlett-Packard Development Company, L.P.Inventor: John H. Stewart
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Patent number: 6750282Abstract: The invention relates to a flameproof, essentially halogen-free polymer composition, containing the following: a) 100 parts by weight of a thermoplastic, cross-linkable or cross-linked, elastomeric and/or duroplastic polymer; b) 10 to 200 parts by weight of magnesium, calcium, zink and/or aluminiumhydroxide and/or their double hydroxides; c) 1 to 50 parts by weight of an organic intercalated sheet silicate.Type: GrantFiled: April 28, 2003Date of Patent: June 15, 2004Assignee: Süd-Chemie AGInventors: Norbert Schall, Thomas Engelhardt, Hubert Simmler-Hübenthal, Günter Beyer
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Patent number: 6727297Abstract: Thermoplastic molding compositions comprising, as substantive constituents A) from 5 to 95% by weight of a vinylaromatic polymer having a syndiotactic structure, B) from 2 to 50% by weight of an inorganic filler, C) from 1 to 45% by weight of an elastomeric, particulate graft polymer, D) from 1 to 10% by weight of a compatibilizer, and, where appropriate, E) from 1 to 45% by weight of an elastomeric particulate styrene-diene block copolymer whose diene fraction may have been completely or to some extent hydrogenated, and, where appropriate, F) from 1 to 35% by weight of a thermoplastic elastomer based on copolymers made from vinylaromatic monomers, dienes, and, where appropriate, 1,1-diphenylethylene, and, where appropriate, G) additives, where the total of the percentages by weight of A) to G) is 100.Type: GrantFiled: October 3, 2002Date of Patent: April 27, 2004Assignee: BASF AktiengesellschaftInventors: Michael Geprägs, Graham Edmund Mc Kee, Konrad Knoll
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Patent number: 6717003Abstract: This invention relates to a powder which is surface-treated by a novel silicone compound, and to a makeup containing this powder. In particular, it relates to a silicone compound which has good compatibility with oils such as ester oils and triglycerides or silicone oils, and to a makeup with a smooth feel, excellent dispersibility and excellent emulsification stability.Type: GrantFiled: February 2, 2001Date of Patent: April 6, 2004Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tetsuo Nakanishi, Ichiro Ono, Toru Shimizu
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Patent number: 6713143Abstract: A thermosetting low-dielectric resin composition which has a low dielectric constant and a low dielectric tangent for use in a printed circuit board and which has excellent adhesion to a metal and scatters almost no resin when used for forming a prepreg by punching or cutting, the composition comprising a component (a): siloxane-modified polyimide, component (b): a compound containing 2 methylallyl groups and having the following formula (1) or a compound containing 3 allyl groups or 3 methylallyl groups and having the following formula (1A), and component (c): a compound containing at least 2 maleimide groups. wherein R is a hydrogen atom or methyl group.Type: GrantFiled: December 31, 2001Date of Patent: March 30, 2004Assignee: Tomegawa Paper Co., Ltd.Inventors: Takeshi Hashimoto, Masaharu Kobayashi, Takeshi Sato, Daisuke Orino
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Patent number: 6706786Abstract: Disclosed is a resin composition containing the following components (A), and (B) or optionally, (C), (D), and (E): (A) an atactic polystyrene or a mixture of an atactic polystyrene and a rubber-like elastic substance: 30 to 95 parts by weight; (B) a syndiotactic polystyrene having a melting point of not higher than 255° C.: 70 to 5 parts by weight; (C) a polyphenylene ether having an intrinsic viscosity of 0.5 deciliter/g or less as measured in chloroform at 25° C.; (D) an inorganic filler; and (E) a polymer having compatibility or affinity with components (A) and (B) and having a polar group. The styrene resin composition exhibits improved solvent resistance and remarkable impact resistance. The composition of the invention is produced by kneading the components within a resin temperature range between the melting point of component (B) and 270° C.Type: GrantFiled: September 16, 2002Date of Patent: March 16, 2004Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akihiko Okada, Takuma Aoyama
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Patent number: 6696585Abstract: There are disclosed amphoteric nano-sized metal oxide particles functionalized with silyl esters of a phosphonate and composites thereof with an acrylate-based monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Also disclosed are the method making such functionalized particular by reacting a metal oxide with a silyl ester of a phosphonate in the presence of a non-aqueous solvent and in an inert atmosphere and the method of making the composites wherein the functionalized particles are admixed with an acrylate-based matrix monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Further disclosed is the method of dental repair wherein the composites are applied to a tooth and photopolymerized.Type: GrantFiled: September 22, 2000Date of Patent: February 24, 2004Assignees: Southwest Research Institute, Board of Regents, The University of Texas SystemInventors: Stephen T. Wellinghoff, Hong Dixon, Henry R. Rawls, Barry K. Norling
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Patent number: 6689468Abstract: The present invention provides an organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle including at least one oxide or mixed oxide, KA—O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R (Ia) wherein R is a linear, branched, cyclic or substituted alkyl group having from 1 to 50 carbon atoms; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA—O)—, SiO— or —Z; wherein remaining free valences of Si′ are each independently (KA—O)—, SiO—, —R, or —Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′Type: GrantFiled: October 5, 2001Date of Patent: February 10, 2004Assignee: Degussa AGInventors: Roland Edelmann, Jaroslaw Monkiewicz
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Patent number: 6663965Abstract: The invention concerns thermo-reversible materials. A material according to the invention comprises a support having grafted thereon a layer of a thermo-reversible polymer that can change from a hydrophilic state to a hydrophobic state depending on the temperature. This material can be used for the decontamination of aqueous effluents.Type: GrantFiled: June 12, 2002Date of Patent: December 16, 2003Assignee: Eastman Kodak CompanyInventor: Olivier J. Poncelet
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Patent number: 6635700Abstract: A composition of matter is disclosed wherein the composition comprises: A) at least one latent mercaptosilane coupling agent; and B) at least one additional mercaptan. Preferably, the composition comprises: A) at least one sulfur vulcanizable rubber; B) at least one latent mercaptosilane coupling agent; C) at least one latent mercaptosilane activator; D) at least one filler; and, optionally, E) at least one additional mercaptosilane. A two pass process for preparing cured articles, such as tires and/or tire treads, which employs the composition is also disclosed.Type: GrantFiled: December 15, 2000Date of Patent: October 21, 2003Assignee: Crompton CorporationInventors: Richard W. Cruse, Martin J. Hannon, Prashant G. Joshi, Frederick D. Osterholtz, Robert J. Pickwell
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Patent number: 6626987Abstract: A stable modified metal oxide sol which contains from 2 to 50 wt %, as calculated as metal oxides, of particles (c) comprising colloidal particles (a) of a metal oxide having primary particle diameters of from 2 to 60 nm, as nuclei, and a coating material (b) consisting of colloidal particles of an acidic oxide coated on the surface of the particles (a), and which has primary particle diameters of from 2 to 100 nm.Type: GrantFiled: August 14, 2000Date of Patent: September 30, 2003Assignee: Nissan Chemical Industries, Ltd.Inventors: Keitaro Suzuki, Yoshinari Koyama, Motoko Iijima
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Patent number: 6620861Abstract: There are provided an inorganic filler, multi-functional filler, an organic compound filler, a modified filler, and a dental coloring filler suitable in use as a filler in a dental composition, compositions having a resin matrix of an organic polymer material, as well as a process for producing the same. Disclosed are an inorganic filler which comprises an inorganic fine particle, wherein the surface of the inorganic fine particle is covered with polysiloxane. Also disclosed is a multi-functional filler which comprises an inorganic fine particle containing an acid reactive element, wherein a cement reactive phase is formed on the surface of the inorganic fine particle, and the cement reactive phase is further covered with polysiloxane. Also disclosed is an organic compound filler which comprises an organic-inorganic polymer particle or an organic polymer particle, wherein the surface of the organic-inorganic polymer particle or an organic polymer particle is covered with an inorganic film.Type: GrantFiled: November 17, 2000Date of Patent: September 16, 2003Assignee: Kabushiki Kaisha ShofuInventors: Toshiyuki Nakatuka, Yasuhisa Yasuda, Katsuya Kimoto, Mitsuharu Mizuno, Noriyuki Negoro
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Patent number: 6613825Abstract: Thermoplastic compositions are disclosed based on syndiotactic polymers of styrene, reinforced with rigid fillers, comprising: a) a crystalline syndiotactic polymer of styrene; b) a polyarylene-ether; c) 1-200 parts by weight, with respect to 100 parts of (a)+(b), one or more inorganic and/or organic rigid fillers; and d) a silanic compound with a compatibilizing function.Type: GrantFiled: November 30, 1998Date of Patent: September 2, 2003Assignee: Enichem S.p.A.Inventors: Raffaele Franco, Alessandro Moro, Marco Scapin, Riccardo Po′
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Patent number: 6605655Abstract: Provided is a polyamide resin composition comprising a melt blend of (A) a polyamide resin, (B) a phyllosilicate, and (C) an olefin compound having a carboxylic acid anhydride group in the molecule or a polymer of the olefin compound, in which the phyllosilicate (B) has a reactive functional group bonded thereto and is such that the exchangeable metal ions existing in the inter layers are ion-exchanged with organic onium ions. The composition has a reduced inorganic ash content and has both high stiffness and high ductility. Optionally, the composition contains an inorganic filler apart from the phyllosilicate, an impact modifier, and a flame retardant, still having high stiffness and high ductility.Type: GrantFiled: March 29, 2000Date of Patent: August 12, 2003Assignee: Toray Industries, Inc.Inventors: Koya Kato, Toru Nishimura, Toru Yamanaka
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Patent number: 6593400Abstract: The present invention relates to a product, a process for its preparation and the use of such in plastic film production. More specifically, the present invention relates to an antiblock talc, a process for the preparation of such and its use as an additive in the production of polyolefin film. Polyolefin films produced according to the process of the present invention are useful in a broad range of packaging and film covering applications.Type: GrantFiled: June 30, 1999Date of Patent: July 15, 2003Assignee: Minerals Technologies Inc.Inventor: Donald Kendall Drummond
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Publication number: 20030114559Abstract: A process for producing a styrenic resin composition includes the step of compounding a styrenic resin with greater than 2 wt % water and an antioxidant which is prepared by blending (a) 20 to 99.9 wt % of organic phosphite or phosphonite with (b) 0.1 to 80 wt % of acid-binding metal salt treated with a surface conditioning agent, prior to compounding with the styrenic resin.Type: ApplicationFiled: September 20, 2002Publication date: June 19, 2003Applicant: CHI MEI CORPORATIONInventors: Wen-Yi Su, Perry Dong-Bi Shiueh
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Patent number: 6534568Abstract: Powder coating or adhesive formulations include as a component thereof a silane of formula (I) or hydrolyzates or condensates thereof where R1 is a hydrocarbon, acyl, alkylsilyl, or alkoxysilyl group, R2 is a monovalent hydrocarbon group; R3 is alkylene, optionally interrupted with one or more ether oxygen atoms; a is 0 or 1; Z is a direct bond or a divalent linking group; X is an m-valent organic group or H; and m is 1-20. The silanes are useful as crosslinkers, property modifiers and/or adhesion promoters. Powder adhesives may be similarly formed with the silanes of formula (I). Fillers or pigments, such as titanium dioxide fillers, which are treated with silanes, especially silanes having alkyl, epoxy, acryl, methacryl, polyether, amino, acid anhydride, hydroxyalkyl, carbamato or ureido functionality, may also be usefully employed in powder coating formulations.Type: GrantFiled: April 19, 2000Date of Patent: March 18, 2003Assignee: Crompton CorporationInventors: Lawrence E. Katz, Herbert E. Petty, Shiu-Chin Huang Su, Bruce A. Waldman, Bruce C. Barbera
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Patent number: 6500883Abstract: Fillers surface-modified by treatment with an organosilane- and/or organosiloxane-containing agent for preparing filled polyamide compositions.Type: GrantFiled: September 12, 2000Date of Patent: December 31, 2002Assignee: Degussa AGInventors: Helmut Mack, Peter Jenkner, Roland Edelmann, Dieter Barfurth, Alber-Johannes Frings, Burkhard Standke, Jaroslaw Monkiewicz, Michael Horn, Thomas Schlosser
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Publication number: 20020197483Abstract: A surface contacting member for toner fusing systems and processes. This surface contacting member has a fluoroelastomer surface layer containing amorphous silica that has been surface treated with at least one organoaminosilane.Type: ApplicationFiled: June 12, 2001Publication date: December 26, 2002Inventors: Jerry A. Pickering, Stephen V. Davis, Theodora Miller
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Publication number: 20020156157Abstract: The invention is a polymer resin that includes between about 20 and 200 ppm of an inert particulate additive, preferably selected from the group consisting of surface-modified talc and surface-modified calcium carbonate. The polymer resin is capable of being formed into low-haze, high-clarity bottles and films possessing reduced coefficient of friction.Type: ApplicationFiled: June 21, 2002Publication date: October 24, 2002Inventors: Walter Lee Edwards, Robert Joseph Schiavone
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Publication number: 20020156158Abstract: The invention is a polyester resin that includes between about 20 and 200 ppm of an inert particulate additive, preferably selected from the group consisting of surface-modified talc and surface-modified calcium carbonate. The invention is also a method of making the polyester resin, which is capable of being formed into low-haze, high-clarity bottles possessing reduced coefficient of friction.Type: ApplicationFiled: June 21, 2002Publication date: October 24, 2002Inventors: Walter Lee Edwards, Robert Joseph Schiavone, Carl Steven Nichols, Tony Clifford Moore
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Patent number: 6465544Abstract: Rubber composition intended for the manufacture of tire casings which have improved hysteretic properties and scorch safety, based on at least one elastomer and silica by way of reinforcing filler enclosing a reinforcing additive consisting of the mixture and/or the product of in situ reaction of at least one functionalized polyorganosiloxane compound containing, per molecule, at least one functional siloxy unit capable of bonding chemically and/or physically to the surface hydroxyl sites of the silica particles and at least one functionalized organosilane compound containing, per molecule, at least one functional group capable of bonding chemically and/or physically to the polyorganosiloxane and/or the hydroxyl sites of the silica particles and at least one other functional group capable of bonding chemically and/or physically to the polymer chains.Type: GrantFiled: October 30, 2000Date of Patent: October 15, 2002Assignee: Compagnie Generale des Etablissements Michelin-Michelin & CieInventors: Yves Bomal, Olivier Durel
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Patent number: 6465543Abstract: The present invention is a nanocomposite which is a dispersion of nanofiller particles derived from layered metal oxides or metal oxide salts. The nanocomposite is advantageously prepared by first swelling an untreated clay in water, then removing the water to form an organophilic clay that is dispersible in non-polar organic solvents. The organophilic clay can then be treated with an alkyl aluminoxane and subsequently a catalyst to form a complex that promotes olefin or styrenic polymerization and platelet dispersion. The nanocomposite can be prepared directly by in situ polymerization of the olefin or the styrene at the nanofiller particles without shear, without an ion exchange step, and without the need to incorporate polar substituents into the polyolefin or polystyrene.Type: GrantFiled: December 21, 2000Date of Patent: October 15, 2002Assignee: The Dow Chemical CompanyInventors: Michael Alexandre, Philippe G. Dubois, Robert J. E. G. Jerome, Miguel Garcia-Marti, Tao Sun, Juan M. Garces, Dean M. Millar, Alexander Kuperman
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Patent number: 6462104Abstract: The invention concerns a method for preparing a silica suspension in a silicone matrix, said suspension capable of being used for producing organopolysiloxanes crosslinkable by polycondensation. The invention aims at seeking a technical compromise between the rheology of said compositions and the mechanical properties of the resulting crosslinked elastomers. As a solution, the invention discloses a method for preparing a silica suspension treated with organosilazane in a silicone material comprising a linear reactive polyorganosiloxane bearing for example at each chain end a hydroxy group.Type: GrantFiled: August 27, 2001Date of Patent: October 8, 2002Assignee: Rhodia ChimieInventors: Dominique Canpont, Fabienne Howe, Alain Pouchelon
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Patent number: 6462115Abstract: A water repellent coating composition includes fine particles having functional groups on their surfaces and having a particle diameter ranging from 10 nm to 1 mm; a coupling agent containing (a) a functional group which is capable of reacting with the functional group of the fine particles and (b) a water repellent fluorinated group; a binder resin for binding the fine particles; and a solvent for the binder.Type: GrantFiled: August 15, 1997Date of Patent: October 8, 2002Assignees: Nippon Telegraph and Telephone Corporation, NTT Advanced Technology CorporationInventors: Masaya Takahashi, Susumu Fujimori, Mamoru Ishitani, Taketoshi Matsuura, Hisao Tabei, Yoshiaki Haga, Akira Nohara, Nobuhiro Funakoshi
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Patent number: 6455613Abstract: The invention relates to a tire having a least one component comprised of a rubber composition which contains aggregates of fumed silica reinforcement. Such tire component may be a tire tread.Type: GrantFiled: August 18, 2000Date of Patent: September 24, 2002Assignee: The Goodyear Tire & Rubber CompanyInventors: Rene Jean Zimmer, Marc Weydert
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Patent number: 6452106Abstract: A resin composition contains (a) 40-90 parts by weight of a block copolymer of polypropylene segments and ethylene-propylene copolymer segments which is modified with an acid anhydride, in which the polypropylene segment content is in the range 5 to 50 wt %, (b) 60-10 parts by weight of a styrene-based polymeric elastomer, or a styrene-based elastomer modified with an acid anhydride, and (c) 30-200 parts by weight of a metal hydroxide per 100 parts by weight of (a) and (b). This wear resistant halogen-free resin composition has high mechanical strength and flexibility and is suitable for extruding as an electrical wire covering for example for a wire used in an automobile.Type: GrantFiled: January 29, 2001Date of Patent: September 17, 2002Assignees: Sumitomo Wiring Systems, Ltd., Sumitomo Electric Industries, Ltd.Inventors: Tatsuya Hase, Masashi Sato, Hiroshi Fujimoto
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Patent number: 6420456Abstract: Particles are hydrophobicized by treatment with a compound containing amino and silane groups, followed by treatment with a silane compound containing a hydrophobic group. The invention is particularly useful for treating hydrophilic mineral particles. The treated particles can be used, for example, as fillers in polymer masterbatches.Type: GrantFiled: May 21, 1998Date of Patent: July 16, 2002Assignee: Bayer Inc.Inventor: Ahti Koski
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Patent number: 6410765Abstract: There are disclosed amphoteric nano-sized metal oxide particles functionalized with silyl esters of a phosphonate and composites thereof with an acrylate-based monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Also disclosed are the method making such functionalized particular by reacting a metal oxide with a silyl ester of a phosphonate in the presence of a non-aqueous solvent and in an inert atmosphere and the method of making the composites wherein the functionalized particles are admixed with an acrylate-based matrix monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Further disclosed is the method of dental repair wherein the composites are applied to a tooth and photopolymerized.Type: GrantFiled: October 17, 2000Date of Patent: June 25, 2002Assignee: Southwest Research InstituteInventors: Stephen T. Wellinghoff, Hong Dixon, Henry R. Rawls, Barry K. Norling
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Patent number: 6391944Abstract: The invention concerns the preparation of a silica suspension in a silicon fluid, said suspension being used to produce silicon vulcanizable by polyaddition (RTV elastomers). The problem which the invention aims to solve is that of finding a technical compromise between the rheological and mechanical properties of the final RTV. The invention solves the problem by providing a method for preparing a silica suspension treated with hexamethyldisilazane (HMDZ) in a silicon fluid with siloxyl Si-Vinyl function, characterised in that it consists essentially in introducing HMDZ in the preparation medium, before and/or substantially while bringing at least part of the silicon fluid prepared with at least part of the particulate filler used, said introduction being carried out once or several times for a HMDZ fraction corresponding to a proportion not more than 8% by dry weight with respect to the total silica charge and after bringing together the POS and the filler.Type: GrantFiled: March 24, 2000Date of Patent: May 21, 2002Assignee: Rhodia ChimieInventors: Dominque Canpont, Andre Plantier, Alain Pouchelon
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Patent number: 6388001Abstract: High levels of silica, processing fluid and high molecular weight silicone polymer are compounded into a homogeneous silica filled composition without forming a preconcentrate of fumed silica and polymer. A fumed silica is fed into a unitary continuous compounding apparatus at a first location prior to addition of the silicone polymer. The fumed silica is then compounded with the silicone polymer, which is fed into the compounding apparatus at a location down-stream in the compounding apparatus from the first location. The compounding apparatus can be a co-rotating, intermeshing double screw extruder.Type: GrantFiled: December 21, 1999Date of Patent: May 14, 2002Assignee: General Electric CompanyInventors: Norberto Silvi, Mark Howard Giammattei
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Chemically modified silica fillers, process for producing, and silicone compositions containing same
Patent number: 6384125Abstract: This invention is a process for making modified silica filler comprising the steps of: (A) contacting an acidic aqueous suspension of precipitated or colloidal silica, optionally in the presence of a surfactant and/or a water-miscible solvent, with a combination of (a) a functionalizing coupling agent, and (b) an organometallic hydrophobing compound in a weight ratio of (a) to (b) of at least 0.001 to 1 to form an acidic aqueous suspension of chemically treated silica filler having a pH of 2.0 or less (B) treating the acidic aqueous suspension of the chemically treated filler with an acid-neutralizing agent to increase the pH of the suspension to a range of from greater than 2.0 to 10, and (C) recovering the chemically treated filler. This invention is also modified silica filler that has a pH of from about 5.0 to 10.0, where the silica filler is made by the method of this invention.Type: GrantFiled: August 11, 2000Date of Patent: May 7, 2002Assignee: Dow Corning CorporationInventors: Debora Frances Bergstrom, Lisa Marie Boswell, Mark David Fisher, James Richard Hahn, Timothy A. Okel, Clifford Carlton Reese -
Patent number: 6372843Abstract: The present invention relates to a process for preparing multifunctionalized polyorganosiloxanes (POSs) comprising alkoxyl functional siloxyl units and siloxyl units each having an SH functional group, which consists in introducing the SH functional group by the reaction of H2S on a precursor POS of formula: A—(RXSiO)a—(RYSiO)b—B where R is especially a C1-C6 alkyl radical, X is a C1-C15 alkoxyl radical, Y is a C2-C30 hydrocarbon group which includes an ethylenically unsaturated group from which the SH functionality derives, a is a number ranging from 1 to 150, b is a number ranging from 1 to 150, the number a+b ranging from 2 to 300 and A and B are terminal groups which are selected respectively, from, in particular, on the one hand (R)3SiO— radicals taken alone or as mixtures with (R)2XSiO— and/or R(X)2SiO— and/or (X)3SiO— radicals and on the other hand —Si(R)3 radicals taken alone or as mixtures with —SiX(R)2 and/or —Si(X)2R and/or —Si(Type: GrantFiled: April 19, 2000Date of Patent: April 16, 2002Assignee: Rhodia ChimieInventors: Pierre Barruel, Yves Bomal, Nathalie Guennouni, Gerard Mignani, Christian Priou
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Patent number: 6362253Abstract: Rubber composition intended for the manufacture of tire casings which have improved hysteretic properties and scorch safety, based on at least one elastomer and silica by way of reinforcing filler enclosing a reinforcing additive consisting of the mixture and/or the product of in situ reaction of at least one functionalized polyorganosiloxane compound containing, per molecule, at least one functional siloxy unit capable of bonding chemically and/or physically to the surface hydroxyl sites of the silica particles and at least one functionalized organosilane compound containing, per molecule, at least one functional group capable of bonding chemically and/or physically to the polyorganosiloxane and/or the hydroxyl sites of the silica particles and at least one other functional group capable of bonding chemically and/or physically to the polymer chains.Type: GrantFiled: October 30, 2000Date of Patent: March 26, 2002Assignee: Compagnie Generale des Establissements Michelin-Michelin & CieInventor: Olivier Durel
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Patent number: 6359046Abstract: The present invention discloses novel hydrocarbon core polysulfide silanes and methods of preparing the hydrocarbon core polysulfide silanes. Preferably, the silanes of the present invention contain assemblies of a single unit of a hydrolyzable silane group, tethered to one end of a chain of sulfur atoms, and several of these assemblies are bound to a common central hydrophobic core via the other end of the sulfur atoms chain. The hydrocarbon core polysulfide silanes may be incorporated into filled elastomeric compositions providing improved dispersiblity of the filler materials. Mineral fillers may be pre-treated with the hydrocarbon core polysulfide silanes prior to use in elastomeric compositions.Type: GrantFiled: September 8, 2000Date of Patent: March 19, 2002Assignee: Crompton CorporationInventor: Richard W. Cruse
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Patent number: 6350519Abstract: A modified particle or aggregate is disclosed wherein a particle has an attached group having the formula: wherein the substituents are defined in the disclosure. Modified particles with attached polymers are also disclosed as well as methods of making the modified products.Type: GrantFiled: June 2, 1999Date of Patent: February 26, 2002Assignee: Cabot CorporationInventor: Wayne Devonport
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Publication number: 20020019460Abstract: A synthetic fiber treatment agent composition capable of providing synthetic fibers, particularly synthetic fiber padding, with a better hand, smoothness, repulsion, and the like. The composition comprises an amino group-containing polyorganosiloxane with a high amino group content and specific terminal groups, and an amino group-containing polydiorganosiloxane with a low amino group content or a polydiorganosiloxane with no amino groups.Type: ApplicationFiled: April 16, 2001Publication date: February 14, 2002Applicant: Info.Disc., Citations, Cert. CopyInventors: Tsutomu Naganawa, Masaru Ozaki, Isao Ona, Tadashi Takimoto
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Publication number: 20020019461Abstract: To provide a liquid curable resin composition which can produce transparent cured products with a high refractive index, high hardness, and superior abrasion resistance, and can be suitably used as a coating material. A liquid curable resin composition comprising: (A) a poly-functional (meth)acrylic compound having at least three (meth) acryloyl groups in the molecule; (B) a reaction product obtained by the reaction of a compound having a polymerizable unsaturated group and alkoxysilyl group in the molecule and particles metal oxide, the metals being selected from the group consisting of zirconium, antimony, zinc, tin, cerium, and titanium; and (C) a radiation polymerization initiator.Type: ApplicationFiled: May 7, 2001Publication date: February 14, 2002Inventors: Takao Yashiro, Yuichi Eriyama, Isao Nishikawi, Takashi Ukachi
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Patent number: 6331605Abstract: Oligomeric organosilanepolysulfanes which are built up from the three structural units A and/or B and/or C, in which Y=H, CN, —(CH2)nSiRR1R2; n=1-8, R, R1, R2 and R3, independently, represent H, (C1-C4)alkyl, (C1-C4)alkoxy, halogen or a OSiR1R2R3 group; x, as a statistical average, is 1-6, z, as a statistical average, is 2-6, n is 1-8 and o, p and q are each a whole, positive number between 1 and 40 where o+p+q may be ≧2 and <40, with the proviso that at least one structural unit A or B is present, and their use in rubber mixtures and to produce molded items, in particular pneumatic tires.Type: GrantFiled: June 10, 1999Date of Patent: December 18, 2001Assignee: Degussa AktiengesellschaftInventors: Hans-Detlef Lunginsland, Christoph Batz-Sohn
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Patent number: 6329449Abstract: The invention relates to a process for the preparation of finely divided rubbers (rubber powders) by precipitation from aqueous mixtures, which comprise filler in the form of suspensions, water-soluble salts of a metal of groups IIa, IIb, IIIa and VIII of the periodic table of the elements arid a rubber latex (polymer latex), aqueous emulsions of a rubber or rubber solution, in which one or more organosilicon compound(s) containing at least one alkoxy group is or are dissolved or emulsified, optionally in the presence of a surface-active substance, in water, or the compounds mentioned are mixed directly, optionally with a surface-active substance, with an aqueous suspension of an oxidic or silicatic finely divided filler or a mixture of these fillers at a temperature of 10 to 60° C., preferably at room temperature, while stirring, the amount of this mixture envisaged for incoporation in the rubber, based on the filler content, in general being divided into two batches.Type: GrantFiled: September 22, 1999Date of Patent: December 11, 2001Assignee: PKU Pulverkautschuk Union GmbHInventors: Udo Gorl, Reinhard Stober, Hartmut Lauer, Uwe Ernst
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Patent number: 6323260Abstract: Particles are hydrophobicized by treatment with a compound containing amino and silane groups. The invention is particularly useful for treating hydrophilic inorganic particles. The treated particles can be used, for example, as a compound agent for polymers. The production and use of a predispersion or concentrate comprising a major amount of the treated particles and a binder is also described.Type: GrantFiled: November 20, 1998Date of Patent: November 27, 2001Assignees: Bayer Inc., Rhein Chemie CorporationInventors: Ahti A. Koski, Anders H. Johansson
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Patent number: 6303730Abstract: The invention relates to transparent organic/inorganic composites with low hydroxyl group content, based on silicic acid heteropolycondensates having extremely low water uptakes. These composites are obtained for example by nonhydrolytic condensation of chlorosilanes with polymerizable groups and optionally fluorinated groups, with the help of a condensation agent (e.g., t-butanol) capable of non-hydrolytic condensation of this chlorosilane, and thermal and/or photochemical polymerization of the obtained condensation product, preferably in the presence of preferably fluorinated organic monomers.Type: GrantFiled: August 19, 1999Date of Patent: October 16, 2001Assignee: Institut fur Neue Materialien gemeinnutzige GmbHInventors: Kira Fries, Martin Mennig, Helmut Schmidt, Ulrich Sohling, Qiwu Xing, Michael Zahnhausen
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Patent number: 6288143Abstract: A method for preparing the first component of a two-component room temperature-vulcanizable (RTV) silicone composition comprises (a) preparing a filler/oil masterbatch by (i) adding an unreactive silicone oil and untreated, aggregated filler particles to a mixer; (ii) adding a filler treating agent such as an organosilane, a polyorganosilane or a silazane to the unreactive silicone oil/filler mixture; and (iii) mixing the unreactive silicone oil/filler mixture and treating agent under conditions sufficient to breakdown the aggregated filler particles to an average size of less than about 300 nm for a time of less than about 24 hours to form the filler/oil masterbatch; and (b) adding said filler/oil masterbatch to a reactive silicone oil.Type: GrantFiled: May 3, 1996Date of Patent: September 11, 2001Assignee: General Electric CompanyInventors: Paul J. Caradori, Robert Augustine Smith, Michael Allen Zumbrum
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Patent number: 6277902Abstract: The present invention relates to rubber compounds comprising one or more soluble rubbers, hydrophobized filler, and one or more sulfane-silane compounds on an inorganic or organic support and to a process for making them. The novel rubber compounds are suitable for moldings of every kind, especially tires or tire treads having low rolling resistance and high resistance to abrasion.Type: GrantFiled: April 16, 1999Date of Patent: August 21, 2001Assignee: Bayer AktiengesellschaftInventor: Thomas Scholl
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Method for fabricating endodontic orthodontic and direct restorations having infused ceramic network
Patent number: 6271282Abstract: A direct filling material and method of using the same. A powdered ceramic is mixed with a saline mixture. A curable resin is also maid with the powdered ceramic to forma a paste. After the paste has been used to fill a cavity, used in a preform or the like it is cured in site to form an interconnected ceramic and resin network.Type: GrantFiled: November 23, 1999Date of Patent: August 7, 2001Assignee: Trustees of Boston UniversityInventor: Russell A. Giordano