Silicon Containing Organic Material Having An Atom Other Than Si, C, H, Or Oxygen Patents (Class 523/213)
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Patent number: 5804613Abstract: Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer carbonyl-functional compound and/or a carboxylic acid-functional compound to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 .ANG. (as measured after water removal to a maximum of 5% by weight water), up to about 100 .ANG. and preferably in the range of about 10-45 .ANG., so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix.Type: GrantFiled: December 22, 1995Date of Patent: September 8, 1998Assignee: Amcol International CorporationInventors: Gary W. Beall, Semeon Tsipursky, Anatoliy Sorokin, Anatoliy Goldman
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Patent number: 5789466Abstract: Laser marking of pigmented fluoropolymer substrates is enhanced by using titanium dioxide pigment coated with organo silane.Type: GrantFiled: May 7, 1996Date of Patent: August 4, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: John Nicholas Birmingham, Jr., Dwight Alan Holtzen, James Francis Hunt, Robert Sterrett Jenkins, Peter Dwight Spohn, James Thomas Walnock
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Patent number: 5780531Abstract: The surface-modified fillers according to the invention are manufactured by treating oxidic or siliceous fillers with a silane of the formulaR.sup.1 R.sup.2 R.sup.3 Si--X.sup.1 --(--S.sub.x --Y--).sub.m --(--S.sub.x --X.sup.2 --SiR.sup.1 R.sup.2 R.sup.3).sub.nand are used for the manufacture of rubber vulcanizates, particularly tyres, with reduced dynamic damping and favourable abrasion behaviour.Type: GrantFiled: June 17, 1996Date of Patent: July 14, 1998Assignee: Bayer AGInventor: Thomas Scholl
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Patent number: 5777002Abstract: A method for preparing organopolysiloxane bases with high levels of fillers. The present inventors have found that by mixing the components of the base at a temperature below about 60.degree. C. for a period of time sufficient to effect essentially a homogeneous blend, a base composition is formed which can be further blended with a platinum group metal-containing catalyst, an organohydrogensiloxane, and optionally an inhibitor to form a curable liquid silicone rubber (LSR) composition. The curable LSR composition has improved flow characteristics and improved shelf life when compared to similar materials where the base is prepared at temperatures above about 60.degree. C. The improved flow characteristics allows larger quantities of fillers to be incorporated into the curable LSR composition while still maintaining acceptable flow characteristics.Type: GrantFiled: November 13, 1996Date of Patent: July 7, 1998Assignee: Dow Corning CorporationInventors: Lori Jean Conway, Thomas Edward Gray, Phillip Joseph Griffith, William James Schulz, Jr.
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Patent number: 5773489Abstract: Dental inorganic-organic composite fillers are disclosed, which do not scatter a visible light of from 360 to 830 nm in the particles thereof, has a refractive index nD by the D-line of sodium in the range of 1.460.ltoreq.nD.ltoreq.1.600, and which is represented by the following mean empirical formula:aM.sup.1 O.sub.x/2 .multidot.bSiO.sub.2 .multidot.cM.sup.2 O.sub.(4-i-j)/2 R.sup.1.sub.i R.sup.2.sub.jwhereinM.sup.1 is one or more members selected from Ti, Zr, Y, La, Ta, and Al, which is bonded to Si or M2 via the crosslinked oxygen; and x is a valence of M.sup.1 ;M.sup.2 is Si and/or Ti;R.sup.1 is a non-functional group; and R.sup.2 is an organic compound reacted with an organic functional group;i is 0, 1, or 2; and j is 1, 2, or 3, provided that i and j are satisfied with 1.ltoreq.(i+j).ltoreq.3; anda, b, and c are each a molar ratio, provided that a, b, and c are satisfied with 0.ltoreq.a/(a+b).ltoreq.0.65 and 0.02.ltoreq.c/(a+b).ltoreq.3.0.Type: GrantFiled: August 14, 1996Date of Patent: June 30, 1998Assignee: GC CorporationInventor: Hisashi Sato
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Patent number: 5763388Abstract: A process for the incorporation of silica into a polymer in latex in which a silica is treated with an organo silicon compound coupling agent in aqueous suspension to form a compatibilized silica and then contacting a polymer latex with the compatibilized silica whereby the silica becomes substantially uniformly distributed throughout the latex and can be recovered when the latex is coagulated to yield little residual silica in the liquid residue from the latex. Also described is a process for preparing the compatibilized silica.Type: GrantFiled: December 18, 1996Date of Patent: June 9, 1998Assignee: DSM Copolymer, Inc.Inventors: John W. Lightsey, David J. Kneiling, John M. Long
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Patent number: 5747562Abstract: Ink and coating compositions are disclosed comprising a silicon-treated carbon black. The silicon-treated carbon black may have at least one attached organic group, and the ink and coating compositions may comprise a combination of silicon-treated carbon black products, with and/or without at least one attached organic group, and untreated carbon black. Methods are disclosed for improving the jetness, improving the blue tone, improving the platewear, reducing the premix residue, modifying rheological properties, or improving waterfastness, of ink and coating compositions by incorporating therein silicon-treated carbon black.Type: GrantFiled: June 14, 1996Date of Patent: May 5, 1998Assignee: Cabot CorporationInventors: Khaled Mahmud, James A. Belmont, Curtis E. Adams, John K. Foster
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Patent number: 5741834Abstract: The present invention provides novel vinyl containing organopolysiloxane elastomers which possess excellent low compression set and heat aging characteristics and which can advantageously be formulated into liquid silicone elastomer moldable compositions.Type: GrantFiled: October 10, 1996Date of Patent: April 21, 1998Assignee: General Electric CompanyInventors: Brian John Ward, Edward Matthew Jeram, Richard Albert Striker
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Patent number: 5739181Abstract: Transparent substrates are rendered resistant to fogging by the application of a hardcoat composition comprising finely divided silica, a multi-functional olefin containing two or more olefinic moieties and one or more divalent oxyalkylene radicals having the formula:--((CX2).sub.n O).sub.x ((CX2)O).sub.y --where the sum of the x stoichiometric subscripts for each divalent oxyalkylene radical and the sum of the y stoichiometric subscripts for each divalent oxyalkylene radical when said sums are added together is ten or greater and the stoichiometric subscripts n and m are different and have values independently ranging from one to ten, where each X is independently selected from the group consisting of hydrogen, one to forty carbon atom monovalent hydrocarbon radicals and six to forty carbon atom monovalent aromatic hydrocarbon and an olefinically functionalized trialkoxysilane followed by curing.Type: GrantFiled: June 7, 1996Date of Patent: April 14, 1998Assignee: General Electric CompanyInventors: Igor V. Khudyakov, George F. Medford
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Patent number: 5719206Abstract: An aqueous coating composition includes: an inorganic particulate substance whose surface is modified with a silane coupling agent having at least one functional group selected from a group consisting of vinyl group, (meth)acryloyl group, epoxy group, and amino group; and an aqueous resin having a functional group which is reactive with the functional group of the silane coupling agent. The aqueous coating composition has excellent storage stability, pigment dispersion, coloring property, adhesion to various substrates, and printing properties, and can be used for various applications, such as printing ink, coating materials, adhesives, fiber treatment agents, surface treatment agents, and the like.Type: GrantFiled: April 28, 1995Date of Patent: February 17, 1998Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Takashi Mihoya, Shinya Fujimatsu, Koichi Iibuchi
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Patent number: 5719205Abstract: Synthetic resin particles having a hydrogen bond forming group are swollen, at least one metallic compound capable of forming a hydrogen bond is introduced into the synthetic resin particles, and the metallic compound is hydrolyzed and condensed within the synthetic resin particles and on and in the vicinity of the surface of the synthetic resin particles. An inorganic component is grown by this reaction, and at least part of the grown inorganic component 3 is fixed through a reaction with a hydrogen bond forming group present within the synthetic resin particles 1 and on and in the vicinity of the surface of the synthetic resin particles 1 to prepare a coating composition. The coating composition is coated on the surface of a substrate, and the resulting coating is dried at a temperature of the lowest film forming temperature or above to form a coating.Type: GrantFiled: January 13, 1995Date of Patent: February 17, 1998Assignee: Dai Nippon Printing Co., Ltd.Inventor: Toshio Yoshihara
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Patent number: 5717009Abstract: An adhesive composition which comprises:(A) 100 parts by weight of a polyorganosiloxane represented by the formula (I): ##STR1## (wherein R.sup.1 s may be the same or different from each other and each represent a monovalent hydrocarbon group or a halogen-substituted hydrocarbon group; and n is a positive integer);(B) 0.5 to 10 parts by weight of a tetraalkoxysilane represented by the following formula:R.sup.2.sub.a Si(OR.sup.3).sub.4-a (II)(wherein R.sup.2 represents an alkyl group having 1 to 3 carbon atoms, a phenyl group or a vinyl group; R.sup.3 represents an alkyl group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group having 3 to 6 carbon atoms; and a is 0 or 1),or a partially hydrolyzed condensate thereof; and(C) 0.1 to 15 parts by weight of a trialkoxysilane represented by the formula (III):R.sup.4 (R.sup.5).sub.b Si(OR.sup.6).sub.3-b (III)(wherein R.sup.4 represents a substituted or unsubstituted aminoalkyl group; R.sup.Type: GrantFiled: July 17, 1996Date of Patent: February 10, 1998Assignee: Toshiba Silicone Co., Ltd.Inventors: Shigeki Matsushita, Fumihiko Kobayashi
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Patent number: 5717010Abstract: The present invention provides novel vinyl containing organopolysiloxane elastomers which possess excellent low compression set and heat aging characteristics and which can advantageously be formulated into liquid silicone elastomer moldable compositions.Type: GrantFiled: August 28, 1996Date of Patent: February 10, 1998Assignee: General Electric CompanyInventors: Brian J. Ward, Edward M. Jeram, Richard A. Striker
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Patent number: 5714529Abstract: Novel contrast media for use in ultrasonic imaging are described. Such contrast media may be comprised of an aqueous solution of one or more biocompatible polymers, wherein said biocompatible polymers are coated with and/or in admixture with at least one silicon containing compound. Alternatively, the contrast media may be comprised of an aqueous solution of one or more biocompatible synthetic polymers, or an aqueous solution of cellulose. The contrast media may be employed, if desired, with anti-gas agents and/or suspending agents.Type: GrantFiled: June 5, 1995Date of Patent: February 3, 1998Assignee: ImaRx Pharmaceutical Corp.Inventors: Evan C. Unger, Guanli Wu
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Patent number: 5714528Abstract: Novel contrast media for use in ultrasonic imaging are described. Such contrast media may be comprised of an aqueous solution of one or more biocompatible polymers, wherein said biocompatible polymers are coated with and/or in admixture with at least one silicon containing compound. Alternatively, the contrast media may be comprised of an aqueous solution of one or more biocompatible synthetic polymers, or an aqueous solution of cellulose. The contrast media maybe employed, if desired, with anti-gas agents and/or suspending agents.Type: GrantFiled: June 2, 1995Date of Patent: February 3, 1998Assignee: ImaRx Pharmaceutical Corp.Inventors: Evan C. Unger, Guanli Wu
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Patent number: 5712036Abstract: A high solubility size composition is provided which may be applied to glass fibers useful for reinforcing polymeric materials. The size composition includes: a first film former comprising a polyester-based thermoplastic polyurethane derived from a saturated, non-crosslinkable polyester; a second film former comprising at least one ingredient selected from i) a vinyl acetate glycidyl methacrylate copolymer and ii) a mixture of a vinyl acetate glycidyl methacrylate copolymer and a vinyl acetate homopolymer; a silane coupling agent; and water. Using glass fibers coated with the high solubility size composition allows the advantageous production of low-pigmented or non-pigmented molded parts having enhanced surface appearance and color uniformity.Type: GrantFiled: May 8, 1996Date of Patent: January 27, 1998Assignee: N.V. Owens-Corning S.A.Inventor: Willy H. Piret
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Patent number: 5708053Abstract: The present invention relates to silica-filled rubber compositions and their method of processing. The rubber compositions contain a mixture of 10 to 150 phr of a particulate precipitated silica having dispersed thereon, from 1 to 20 percent by weight based upon the weight of the silica, of a silane-modified elastomer.Type: GrantFiled: August 15, 1996Date of Patent: January 13, 1998Assignee: The Goodyear Tire & Rubber CompanyInventors: George Jalics, Adel Farhan Halasa, David John Zanzig
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Patent number: 5708054Abstract: A two-part composition comprising a liquid composition (I) composed of the components (A), (C), and (E) described below and a liquid composition (II) composed of the components (A) (B), (C), and (D) described below, which yield upon mixing a curable liquid silicone composition comprising(A) an alkenyl-substituted poyorganopolysiloxane;(B) a hydrogen-substituted organopolysiloxane in an amount that provides 0.3 to 10 moles silicon-bonded hydrogen from component (B) per 1 mole alkenyl in component (A);(C) an inorganic filler that has a specific surface of 50 to 500 m.sup.2 /g;(D) an alkoxy-substituted organopolysiloxane; and(E) platinum catalyst in a quantity sufficient to cure the instant composition;wherein the curable silicone composition that results when liquid composition (I) and liquid composition (II) are mixed, is thixotropic and has a viscosity, immediately upon the mixing that is greater than the viscosity of liquid composition (II).Type: GrantFiled: October 28, 1996Date of Patent: January 13, 1998Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Katsutoshi Mine, Takae Takeuchi, Kimio Yamakawa
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Patent number: 5703147Abstract: A low density, high temperature resistant insulation material that is very thermally efficient, is easily moldable and is unaffected by water. The insulation material is especially suitable for use in aviation, aerospace and automotive applications. The insulation material contains inorganic fiber; inorganic binder; hydrophilic particulate inorganic material; hydrophobic particulate inorganic material; polymer; and preferably a setting agent and an opacifier.Type: GrantFiled: August 2, 1995Date of Patent: December 30, 1997Assignee: Schuller International, Inc.Inventors: Phillip Charles Martin, Monroe W. Shumate, William Michael Gregg
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Patent number: 5698619Abstract: The present invention relates to the use in a silica-filled rubber composition of an aminosilane compound of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms, alkyl radicals having 1 to 8 carbon atoms and aryl radicals having 6 carbon atoms, with the proviso that at least one of R.sup.1, R.sup.2 and R.sup.3 is an alkoxy radical; R.sup.4 is selected from the group consisting of alkylene groups having from 1 to 18 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; R.sup.5 is selected from the group consisting of hydrogen and alkyl groups having from 1 to 15 carbon atoms.Type: GrantFiled: June 24, 1996Date of Patent: December 16, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Martin Paul Cohen, Cheryl Ann Losey, Dane Kenton Parker
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Patent number: 5698309Abstract: Moldings, preferably comprising polyester which contains oxide particles which have been subjected to a surface modification with a silylating agent of the formula I?R.sup.1 R.sup.2 R.sup.3 !Si--(CH.sub.2).sub.l --X--R.sup.4 (I)whereinR.sup.1 is Cl or alkoxy having 1 to 6 carbon atoms,R.sup.2 and R.sup.3 are alkyl having 1 to 6 carbon atoms or R.sup.1,l is a number from 1 to 6,X is a single bond, O, NH, CONH or NHCONH,R.sup.4 is ##STR1## where Y is CH, ##STR2## Z is OR or two radicals Z together are --O-- or NR and m and n are a number from 0 to 6, or R.sub.4 is ##STR3## where X is a single bond and R, R' and R" are H or alkyl having 1 to 6 carbon atoms,and the use of said moldings are described.Type: GrantFiled: April 5, 1995Date of Patent: December 16, 1997Assignee: Hoechst AktiengesellschaftInventors: Hermann Dallmann, Joachim Kinkel, Kurt Marquard, Ludwig Pohl
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Patent number: 5693696Abstract: A modified polyurethane structionally incorporating filler having active hydrogen groups on a surface thereof into a polyurethane polymer. The filler is first fluidized with a polyol and then reacted with a linking component having an organo reactive group that is reactive with an isocyanate. Polyisocyanate and additional polyol are added to the reaction mixture such that the isocyanate reacts with the linking component and the polyol to form a polymer wherein the filler is an integral unit in the polymer. The resultant modified polyurethane has good dynamic properties and is surprisingly resilient. Preferred fillers are sand, clay talc and mixtures thereof.Type: GrantFiled: January 16, 1996Date of Patent: December 2, 1997Assignee: MCP Industries, Inc.Inventors: Thomas M. Garrett, Indulis Gruzins
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Patent number: 5688840Abstract: A process for preparing a room temperature-curable organopolysiloxane composition comprising (A) (A-1) a specific organopolysiloxane or a mixture of (A-1) and (A-2) a specific silicone compound or a partial hydrolysis product thereof, (B) silica powder having a specific surface area of 20 to 800 m.sup.2 /g, (C) a curing catalyst, and (D) a silane coupling agent or an organopolysiloxane having a specific substituent, which comprises adding component (D) to component (A) prior to kneading or at the time of kneading components (A) and (B). The composition exhibits excellent physical characteristics, excellent workability in terms of flowability, adhesion, and extrudability, undergoes no change in viscosity with time and, in particular, suffers no impairment of these characteristics when stored for a long period of time.Type: GrantFiled: October 4, 1995Date of Patent: November 18, 1997Assignee: Toshiba Silicone Co., Ltd.Inventor: Kazuhisa Ono
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Patent number: 5684064Abstract: A silicone composition is formed as a system including: a silicone compound, reactive group-containing modified silicic acid powder of which surface has been modified with an alkylsilane, a hexamethyldisilazane, a dimethylsilicone oil, or a mixture thereof, and an unsaturated group-containing silane compound; and inorganic fine powder carrying a surfactant. The silicone compound is preferably an addition reaction-type silicone rubber prepared from a dimethyl polysiloxane having a vinyl group, a methylhydrogenpolysiloxane and a platinum-based catalyst. The silicone composition is heat-cured to provide an elastic revolution body which is suitably used to constitute one or both of a fixing roller and a mating pressure roller in a roller fixing device for electrophotography.Type: GrantFiled: July 27, 1994Date of Patent: November 4, 1997Assignee: Canon Kabushiki KaishaInventor: Toshiyuki Miyabayashi
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Patent number: 5679727Abstract: A platinum curing organosiloxane composition having improved hysteresis characteristics when cured. The composition requires the presence of a diorganovinylsiloxy terminated polydiorganosiloxane having a viscosity within a range of about 20 Pa.multidot.s to 200 Pa.multidot.s at 25.degree. C. and containing essentially no ethylenically unsaturated hydrocarbon radicals bonded to non-terminal silicon atoms and a diorganovinylsiloxy terminated polydiorganosiloxane having a viscosity within a range of about 0.1 Pa.multidot.s to 200 Pa.multidot.s at 25.degree. C., where from 1 to 5 percent of the non-terminal repeating units of the siloxane comprise a vinyl radical. In addition, the present composition comprises 10 to 30 weight percent of a reinforcing silica filler that has been treated with hexamethyldisilazane and 1,1,3,3-tetramethyl-1,3-divinyldisilazane, and an organohydrogen siloxane crosslinker comprising at least ten silicon-bonded hydrogen atoms per molecule.Type: GrantFiled: March 28, 1996Date of Patent: October 21, 1997Assignees: Dow Corning Corporation, Dow Corning Taiwan, IncorporatedInventors: Phillip Joseph Griffith, Chu Yat Ho, Diane Marie Kosal, Jary David Jensen
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Patent number: 5674935Abstract: A composition for in situ treating silica filler is provided, comprising a silanol-terminated, vinyl-containing polydiorganosiloxane which functions both as a processing aid and as a crosslinking agent in vulcanizable fluorosilicone and silicone elastomer compositions.Type: GrantFiled: August 16, 1996Date of Patent: October 7, 1997Assignee: General Electric CompanyInventors: Edwin Robert Evans, James Edward Doin
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Patent number: 5670583Abstract: A method of making metal oxide clusters in a single stage by reacting a metal oxide with a substoichiometric amount of an acid in the presence of an oxide particle growth terminator and solubilizer. A method of making a ceramer is also disclosed in which the metal oxide clusters are reacted with a functionalized polymer. The resultant metal oxide clusters and ceramers are also disclosed.Type: GrantFiled: August 31, 1994Date of Patent: September 23, 1997Assignee: Southwest Research InstituteInventor: Stephen T. Wellinghoff
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Patent number: 5665812Abstract: A sulfur-vulcanizable rubber composition of improved hysteresis, comprising ilica as reinforcing filler as well as a diene polymer functionalized with a functionalizing agent having the general formula (Y).sub.m --R.sup. --Si(OR.sup.2).sub.3-n --R.sup.3 n and suitable to be used for the manufacture of tires of reduced resistance to rolling.The functionalized diene polymers are prepared by addition to the living diene polymer under suitable mixing conditions of an amount of functionalizing agent such that the molar ratio of functionalizing agent to the number of active sites is equal to or greater than 1.Type: GrantFiled: April 3, 1995Date of Patent: September 9, 1997Assignee: Compagnie Generale des Establissements Michelin-Michelin & CieInventors: Jean-Noel Gorce, Gerard Labauze
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Patent number: 5648407Abstract: Compositions comprise (a) a curable resin sol comprising a colloidal dispersion of substantially spherical, substantially inorganic microparticles (e.g., surface-modified silica) in curable resin (e.g., epoxy resin); and (b) reinforcing fibers (e.g., carbon fibers). The compositions can be cured to provide fiber-reinforced composites which exhibit improved resin-dominated mechanical properties.Type: GrantFiled: May 16, 1995Date of Patent: July 15, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Douglas P. Goetz, Andrew M. Hine, William J. Schultz, Wendy L. Thompson
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Patent number: 5637629Abstract: Reinforced polyolefinic thermoplastic composition comprising a polyolefin, an aluminum and/or magnesium silicate and a maleamic silane.Type: GrantFiled: August 7, 1996Date of Patent: June 10, 1997Assignee: Enichem S.p.A.Inventors: Alessandro Moro, Italo Borghi, Paolo Venti, Domenico Vianello, Roberto Pippa
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Patent number: 5635557Abstract: A polypropylene composition which contains a polypropylene and one or more ingredients selected from an antistatic agent and a surface-treated or untreated fine powdery silica gives a propylene stretched film having a well-balanced transparency, slip property and blocking resistance.Type: GrantFiled: December 21, 1994Date of Patent: June 3, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Junichi Kimura, Minoru Takane, Yoichi Obata, Hiroyuki Tanimura
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Patent number: 5635547Abstract: The process comprises the steps of (A) mixing a base material (A-1), which is obtained by mixing an organopolysiloxane and a reinforcing silica and then heating the resulting mixture, with an aminosilane compound (A-2) represented by the formula:(R.sup.1).sub.n Si[N(R.sup.2).sub.2 ].sub.(4-n)wherein a plurality of R.sup.1 may be the same or different and are each a substituted or unsubstituted monovalent hydrocarbon group, a plurality of R.sup.2 may be the same or different and are each a substituted or unsubstituted monovalent hydrocarbon group, and n is 2 or 3; to allow them to react; and (B) heating the reaction mixture obtained in the step (A) under normal pressure or reduced pressure to remove an unreacted aminosilane compound and a by-product amine, contained in the reaction mixture.Type: GrantFiled: April 5, 1995Date of Patent: June 3, 1997Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaharu Takahashi, Minoru Igarashi
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Patent number: 5627241Abstract: A method of making an organopolysiloxane sheet or tube polymer involves contacting a sheet or tube silicate with an organo-H-chlorosilane to form an organosiloxane sheet or tube polymer with pendent .tbd.Si--H groups. Subsequently, the organosiloxane sheet or tube polymer with pendent .tbd.Si--H groups is contacted with an alkenyl group containing compound in the presence of a hydrosilation catalyst. The catalyst is used in an amount effective to catalyze a hydrosilation reaction between the alkenyl group on the alkenyl group containing compound and the hydride functionality on the organosiloxane sheet or tube polymer with pendent .tbd.Type: GrantFiled: September 19, 1996Date of Patent: May 6, 1997Assignees: Dow Corning Corporation, Case Western UniversityInventors: Chenggang Chen, Dimitris E. Katsoulis, Malcolm E. Kenney
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Patent number: 5618869Abstract: A rubber composition suitable for use in tread of tires, particularly studless tires having increased digging and adhesive frictions to improve characteristics on icy roads of the tires without substantial deterioration of the durability of the tires or with minimizing the deterioration, which comprises a diene rubber component, 3 to 30 parts by weight of an ebonite powder and 0.1 to 3 parts by weight of a silylating agent, respectively, per 100 parts by weight of the rubber component.Type: GrantFiled: December 19, 1995Date of Patent: April 8, 1997Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kazuo Kadomaru, Yoichi Mizuno
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Patent number: 5616639Abstract: The invention relates to a tire with a rubber tread which is primarily reinforced with silica where the rubber of the said tread is composed of an elastomer base of at least three butadiene based synthetic rubbers comprised of two isoprene/butadiene copolymer elastomers having spatially defined Tg's, and a cis 1,4-polybutadiene elastomer.Type: GrantFiled: May 24, 1995Date of Patent: April 1, 1997Assignee: The Goodyear Tire & Rubber CompanyInventor: Danielle Lucas
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Patent number: 5607997Abstract: This composition comprises (A) a diorganopolysiloxane terminated with hydroxyl groups at both ends of its molecular chain having a viscosity of 25 to 1,000,000 cSt at 25.degree. C., (B) a low molecular weight organosilane or straight chain organosiloxane having silanol groups, such as HO(Me.sub.2 SiO)H, Me.sub.3 SiO[Me(OH)SiO].sub.2 SiMe.sub.3 or mixtures thereof, (C) a hydrolyzable silane, and (D) a silica filler having a specific surface area of 50 m.sup.2 /g or more. The composition has good non-flowability and exhibits good application workability when surface-finishing with spatula, and therefore is useful as building sealing materials.Type: GrantFiled: October 11, 1995Date of Patent: March 4, 1997Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tsuneo Kimura, Yoshio Inoue
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Patent number: 5605982Abstract: Organopolysiloxane sheet or tube polymers are made by contacting a sheet or tube silicate with an alkenyl group containing chlorosilane to form an alkenylsiloxy polymer, and subsequently contacting the alkenylsiloxy sheet or tube polymer with a hydrosilane or hydrosiloxane in the presence of a hydrosilation catalyst, to catalyze a reaction between the alkenyl group on the alkenylsiloxy polymer and hydride functionality on the hydrosilane or hydrosiloxane. Silylalkoxysiloxane sheet or tube polymers are made by contacting a sheet or tube silicate with an acidic solution of an alkenyl alcohol to form a polymeric sheet or tube alkenyloxysiloxane, and subsequently contacting the alkenyloxysiloxane with a hydrosilane or hydrosiloxane in the presence of a hydrosilation catalyst, to catalyze a reaction between the alkenyl group on the alkenyloxysiloxane and hydride functionality on the hydrosilane or hydrosiloxane.Type: GrantFiled: October 12, 1995Date of Patent: February 25, 1997Assignees: Dow Corning Corporation, Case Western Reserve UniversityInventors: Timothy C. Chao, Malcolm E. Kenney, Dimitris E. Katsoulis
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Patent number: 5604288Abstract: A method for preparing a thermoplastic resin composition, said method comprising hot-kneading, in the absence of a radical-generating catalyst,(A) 100 parts by weight of a thermoplastic resin; and(B) 0.1 to 200 parts by weight of an alkenyl-functional polyorganosiloxane filled with amorphous silica micropowder, wherein the weight ratio of said silica micropowder to said alkenyl-functional polyorganosiloxane is 0.01:100 to 50:100, whereby the polyorganosiloxane of component (B) is chemically bonded to resin (A).Type: GrantFiled: November 29, 1995Date of Patent: February 18, 1997Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Haruhiko Furukawa, Akihiro Nakamura, Akihiko Shirahata
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Patent number: 5599868Abstract: A process for compounding filler materials and polymers for the preparation of vulcanizable rubber compositions comprises the steps of combining at least one polymer and other compounding ingredients with a filler treated with a liquid in an amount of from about 10 to 60 percent by weight, based upon the combined weight of the liquid and the filler under conditions sufficient to uniformly distribute the filler to form a pre-blend; and mixing the pre-blend until the filler is suitably dispersed throughout the polymer. A vulcanizable rubber composition containing a filler prepared by combining at least one polymer and other compounding ingredients with a filler treated with a liquid in an amount of from about 10 to 60 percent by weight, based upon the combined weight of the liquid and the filler under conditions sufficient to uniformly distribute the filler to form a pre-blend; and mixing the pre-blend until the filler is suitably dispersed throughout the polymer.Type: GrantFiled: April 19, 1994Date of Patent: February 4, 1997Assignee: Bridgestone CorporationInventors: Georg G. A. Bohm, William M. Cole
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Patent number: 5597853Abstract: A silicone rubber composition comprising an organopolysiloxane and a reinforcing silica filler can be improved in crepe hardening and shelf stability by blending a specific compound as a wetter.Type: GrantFiled: November 7, 1994Date of Patent: January 28, 1997Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kunio Itoh, Toshio Shinohara, Masaharu Takahashi
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Patent number: 5578659Abstract: A polyarylene sulfide resin composition having excellent metal corrosion resistance and excellent mechanical properties is composed of 100 parts by weight of a polyarylene sulfide resin; from 0.1 to 10 parts by weight of a specific metal compound the surface of which has been pretreated with a first alkoxysilane compound; from 0 to 10 parts by weight of a second alkoxysilane compound; and from 5 to 500 parts by weight of an organic filler.Type: GrantFiled: June 23, 1995Date of Patent: November 26, 1996Assignee: Polyplastics Co., Ltd.Inventors: Sachio Anada, Nozomu Nakagawa, Kazutomo Tokushige, Toshikatsu Nitoh
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Patent number: 5571851Abstract: A silane treated calcined clay, used as a filler in plastics such as polyamide or nylon resins, has improved tensile strength and flexural strength without substantial loss of impact strength, said calcined clay having been treated with a blend of silanes comprising an aminosilane and an alkylsilane.Type: GrantFiled: June 7, 1995Date of Patent: November 5, 1996Assignee: J.M. Huber CorporationInventors: Gary Freeman, Carl J. Marshall
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Patent number: 5561176Abstract: A process for treating fillers, preferably precipitated silica, to improve the physical property profile of heat curable and room temperature vulcanizable silicone rubbers and a composition for room temperature vulcanizable rubbers comprising the silica filler treated by the process of the invention.Type: GrantFiled: September 7, 1995Date of Patent: October 1, 1996Assignee: General Electric CompanyInventors: Theresa A. Garafalo, Robert A. Smith
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Patent number: 5539051Abstract: There are disclosed a resin composition for coating which comprises a mixture of(i) a non-aqueous dispersion type resin containing(A) a vinyl polymer soluble in an organic solvent mainly comprising an aliphatic hydrocarbon, and(B) a vinyl polymer particle which is insoluble in the organic solvent and obtained by polymerizing a polymerizable unsaturated compound in the organic solvent using the vinyl polymer (A) as a dispersant, and(ii) a solvent type resin of(C) a vinyl polymer having a silyl group represented by the formula (I) which is soluble in the organic solvent: ##STR1## wherein R.sup.1 represents an alkyl group, an aryl group or an aralkyl group, X represents a halogen atom, an alkoxy group, an acyloxy group or a hydroxy group, and k is an integer of 1 to 3,and a paint containing the same.Type: GrantFiled: October 15, 1993Date of Patent: July 23, 1996Assignee: Hitachi Chemical Company Co., Ltd.Inventors: Kuniaki Satou, Tsutomu Mamiya, Takashi Amano, Akira Hironaka
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Patent number: 5534588Abstract: A room temperature vulcanizable silicone rubber composition with high elongation and low modulus comprising 10-90 percent by weight polydiorganosiloxane having terminal hydroxyl groups, 1-10 percent by weight phenyl tris-functional ketoximino-containing silane crosslinker, 0-14 percent by weight of a reinforcing or 0-60 percent by weight of a nonreinforcing filler or semi-reinforcing filler or a mixture thereof for a total of all fillers in the range of from about 6-60 percent by weight, from 0-2.5 percent by weight of an organofunctional silane adhesion promoter and an optional plasticizer and catalyst. These compositions cure to elastic materials useful as caulking materials, adhesives, coatings and encapsulating materials for the construction and other industries.Type: GrantFiled: May 18, 1995Date of Patent: July 9, 1996Assignee: AlliedSignal Inc.Inventors: Jeffrey A. Knepper, Dale R. Flackett, Edward T. Asirvatham
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Patent number: 5498781Abstract: The present invention is a composition comprising an optically variable pigment modified with a silane functional compound and a copolymer which is a polymeric backbone having a reactive functionality thereon to react with the silane functional compound. The invention also includes a process for treating the optically variable pigment, and a coating composition containing the treated optically variable pigment.Type: GrantFiled: May 23, 1994Date of Patent: March 12, 1996Assignee: BASF CorporationInventors: Jon R. Hall, Clint W. Carpenter, Stuart K. Scott
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Patent number: 5494948Abstract: A mica-reinforced propylene resin composition having a volatile matter at 105.degree. C of 0.12% or less is obtained by heating and melting a mixture containing (A) a crystalline polypropylene, (B) mica treated with an organosilane compound, (C) a bismaleimide compound, and (D) an organic peroxide. It has excellent stiffness, heat resistance and dimensional stability, does not corrode a mold, and does not exhale an irritating odor during molding.Type: GrantFiled: September 26, 1994Date of Patent: February 27, 1996Assignee: Sumitomo Chemical Company, LimitedInventors: Taichi Nishio, Yuji Ikezawa
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Patent number: 5494949Abstract: The invention relates to oxide particles which have a surface modification by covalently bonded organic groups which allow covalent bonding into polymer materials. These particles are particularly advantageous in their use as fillers or modifying agents in polymer materials, in particular polymer films.Type: GrantFiled: June 1, 1994Date of Patent: February 27, 1996Assignees: Merck Patent Gesellschaft mit beschrankter Haftung, Hoechst AktiengesellschaftInventors: Joachim Kinkel, Kurt Marquard, Ludwig Pohl
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Sulfur cured rubber composition containing epoxidized natural rubber and carboxylated nitrile rubber
Patent number: 5489628Abstract: A pneumatic tire having a sulfur cured rubber composition as a circumferential tread. The sulfur cured rubber composition is composed of, based on 100 parts by weight of rubber, from about 1.0 to 15 parts by weight of epoxidized rubber; from about 1.0 to 15 parts by weight of a carboxylated nitrile rubber; and 98 to 70 parts by weight of a rubber selected from the group consisting of medium vinyl polybutadiene, styrene-butadiene rubber, synthetic cis-1,4-polyisoprene, synthetic 3,4-polyisoprene, natural rubber, cis-polybutadiene, styrene-isoprene rubber, styrene-isoprene-butadiene rubber, acrylonitrile-butadiene rubber and mixtures thereof. The sulfur cured rubber composition is further composed of a silica filler and a silica coupling agent.Type: GrantFiled: May 30, 1995Date of Patent: February 6, 1996Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul H. Sandstrom -
Sulfur cured rubber composition containing epoxidized natural rubber and carboxylated nitrile rubber
Patent number: 5489627Abstract: The present invention relates to a sulfur cured rubber composition particularly suited for use in tire treads. The sulfur cured rubber composition is composed of, based on 100 parts by weight of rubber, from about 1.0 to 15 parts by weight of epoxidized rubber; from about 1.0 to 15 parts by weight of a carboxylated nitrile rubber; and 98 to 70 parts by weight of a rubber selected from the group consisting of medium vinyl polybutadiene, styrene-butadiene rubber, synthetic cis-1,4-polyisoprene, synthetic 3,4-polyisoprene, natural rubber, cis-polybutadiene, styrene-isoprene rubber, styrene-isoprene-butadiene rubber, acrylonitrile-butadiene rubber and mixtures thereof. The sulfur cured rubber composition is further composed of a silica filler and a silica coupling agent.Type: GrantFiled: May 30, 1995Date of Patent: February 6, 1996Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul H. Sandstrom