Silicon Containing Organic Material Having An Atom Other Than Si, C, H, Or Oxygen Patents (Class 523/213)
  • Patent number: 5804613
    Abstract: Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer carbonyl-functional compound and/or a carboxylic acid-functional compound to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 .ANG. (as measured after water removal to a maximum of 5% by weight water), up to about 100 .ANG. and preferably in the range of about 10-45 .ANG., so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: September 8, 1998
    Assignee: Amcol International Corporation
    Inventors: Gary W. Beall, Semeon Tsipursky, Anatoliy Sorokin, Anatoliy Goldman
  • Patent number: 5789466
    Abstract: Laser marking of pigmented fluoropolymer substrates is enhanced by using titanium dioxide pigment coated with organo silane.
    Type: Grant
    Filed: May 7, 1996
    Date of Patent: August 4, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: John Nicholas Birmingham, Jr., Dwight Alan Holtzen, James Francis Hunt, Robert Sterrett Jenkins, Peter Dwight Spohn, James Thomas Walnock
  • Patent number: 5780531
    Abstract: The surface-modified fillers according to the invention are manufactured by treating oxidic or siliceous fillers with a silane of the formulaR.sup.1 R.sup.2 R.sup.3 Si--X.sup.1 --(--S.sub.x --Y--).sub.m --(--S.sub.x --X.sup.2 --SiR.sup.1 R.sup.2 R.sup.3).sub.nand are used for the manufacture of rubber vulcanizates, particularly tyres, with reduced dynamic damping and favourable abrasion behaviour.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: July 14, 1998
    Assignee: Bayer AG
    Inventor: Thomas Scholl
  • Patent number: 5777002
    Abstract: A method for preparing organopolysiloxane bases with high levels of fillers. The present inventors have found that by mixing the components of the base at a temperature below about 60.degree. C. for a period of time sufficient to effect essentially a homogeneous blend, a base composition is formed which can be further blended with a platinum group metal-containing catalyst, an organohydrogensiloxane, and optionally an inhibitor to form a curable liquid silicone rubber (LSR) composition. The curable LSR composition has improved flow characteristics and improved shelf life when compared to similar materials where the base is prepared at temperatures above about 60.degree. C. The improved flow characteristics allows larger quantities of fillers to be incorporated into the curable LSR composition while still maintaining acceptable flow characteristics.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: July 7, 1998
    Assignee: Dow Corning Corporation
    Inventors: Lori Jean Conway, Thomas Edward Gray, Phillip Joseph Griffith, William James Schulz, Jr.
  • Patent number: 5773489
    Abstract: Dental inorganic-organic composite fillers are disclosed, which do not scatter a visible light of from 360 to 830 nm in the particles thereof, has a refractive index nD by the D-line of sodium in the range of 1.460.ltoreq.nD.ltoreq.1.600, and which is represented by the following mean empirical formula:aM.sup.1 O.sub.x/2 .multidot.bSiO.sub.2 .multidot.cM.sup.2 O.sub.(4-i-j)/2 R.sup.1.sub.i R.sup.2.sub.jwhereinM.sup.1 is one or more members selected from Ti, Zr, Y, La, Ta, and Al, which is bonded to Si or M2 via the crosslinked oxygen; and x is a valence of M.sup.1 ;M.sup.2 is Si and/or Ti;R.sup.1 is a non-functional group; and R.sup.2 is an organic compound reacted with an organic functional group;i is 0, 1, or 2; and j is 1, 2, or 3, provided that i and j are satisfied with 1.ltoreq.(i+j).ltoreq.3; anda, b, and c are each a molar ratio, provided that a, b, and c are satisfied with 0.ltoreq.a/(a+b).ltoreq.0.65 and 0.02.ltoreq.c/(a+b).ltoreq.3.0.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: June 30, 1998
    Assignee: GC Corporation
    Inventor: Hisashi Sato
  • Patent number: 5763388
    Abstract: A process for the incorporation of silica into a polymer in latex in which a silica is treated with an organo silicon compound coupling agent in aqueous suspension to form a compatibilized silica and then contacting a polymer latex with the compatibilized silica whereby the silica becomes substantially uniformly distributed throughout the latex and can be recovered when the latex is coagulated to yield little residual silica in the liquid residue from the latex. Also described is a process for preparing the compatibilized silica.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: June 9, 1998
    Assignee: DSM Copolymer, Inc.
    Inventors: John W. Lightsey, David J. Kneiling, John M. Long
  • Patent number: 5747562
    Abstract: Ink and coating compositions are disclosed comprising a silicon-treated carbon black. The silicon-treated carbon black may have at least one attached organic group, and the ink and coating compositions may comprise a combination of silicon-treated carbon black products, with and/or without at least one attached organic group, and untreated carbon black. Methods are disclosed for improving the jetness, improving the blue tone, improving the platewear, reducing the premix residue, modifying rheological properties, or improving waterfastness, of ink and coating compositions by incorporating therein silicon-treated carbon black.
    Type: Grant
    Filed: June 14, 1996
    Date of Patent: May 5, 1998
    Assignee: Cabot Corporation
    Inventors: Khaled Mahmud, James A. Belmont, Curtis E. Adams, John K. Foster
  • Patent number: 5741834
    Abstract: The present invention provides novel vinyl containing organopolysiloxane elastomers which possess excellent low compression set and heat aging characteristics and which can advantageously be formulated into liquid silicone elastomer moldable compositions.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: April 21, 1998
    Assignee: General Electric Company
    Inventors: Brian John Ward, Edward Matthew Jeram, Richard Albert Striker
  • Patent number: 5739181
    Abstract: Transparent substrates are rendered resistant to fogging by the application of a hardcoat composition comprising finely divided silica, a multi-functional olefin containing two or more olefinic moieties and one or more divalent oxyalkylene radicals having the formula:--((CX2).sub.n O).sub.x ((CX2)O).sub.y --where the sum of the x stoichiometric subscripts for each divalent oxyalkylene radical and the sum of the y stoichiometric subscripts for each divalent oxyalkylene radical when said sums are added together is ten or greater and the stoichiometric subscripts n and m are different and have values independently ranging from one to ten, where each X is independently selected from the group consisting of hydrogen, one to forty carbon atom monovalent hydrocarbon radicals and six to forty carbon atom monovalent aromatic hydrocarbon and an olefinically functionalized trialkoxysilane followed by curing.
    Type: Grant
    Filed: June 7, 1996
    Date of Patent: April 14, 1998
    Assignee: General Electric Company
    Inventors: Igor V. Khudyakov, George F. Medford
  • Patent number: 5719206
    Abstract: An aqueous coating composition includes: an inorganic particulate substance whose surface is modified with a silane coupling agent having at least one functional group selected from a group consisting of vinyl group, (meth)acryloyl group, epoxy group, and amino group; and an aqueous resin having a functional group which is reactive with the functional group of the silane coupling agent. The aqueous coating composition has excellent storage stability, pigment dispersion, coloring property, adhesion to various substrates, and printing properties, and can be used for various applications, such as printing ink, coating materials, adhesives, fiber treatment agents, surface treatment agents, and the like.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: February 17, 1998
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Takashi Mihoya, Shinya Fujimatsu, Koichi Iibuchi
  • Patent number: 5719205
    Abstract: Synthetic resin particles having a hydrogen bond forming group are swollen, at least one metallic compound capable of forming a hydrogen bond is introduced into the synthetic resin particles, and the metallic compound is hydrolyzed and condensed within the synthetic resin particles and on and in the vicinity of the surface of the synthetic resin particles. An inorganic component is grown by this reaction, and at least part of the grown inorganic component 3 is fixed through a reaction with a hydrogen bond forming group present within the synthetic resin particles 1 and on and in the vicinity of the surface of the synthetic resin particles 1 to prepare a coating composition. The coating composition is coated on the surface of a substrate, and the resulting coating is dried at a temperature of the lowest film forming temperature or above to form a coating.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: February 17, 1998
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventor: Toshio Yoshihara
  • Patent number: 5717009
    Abstract: An adhesive composition which comprises:(A) 100 parts by weight of a polyorganosiloxane represented by the formula (I): ##STR1## (wherein R.sup.1 s may be the same or different from each other and each represent a monovalent hydrocarbon group or a halogen-substituted hydrocarbon group; and n is a positive integer);(B) 0.5 to 10 parts by weight of a tetraalkoxysilane represented by the following formula:R.sup.2.sub.a Si(OR.sup.3).sub.4-a (II)(wherein R.sup.2 represents an alkyl group having 1 to 3 carbon atoms, a phenyl group or a vinyl group; R.sup.3 represents an alkyl group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group having 3 to 6 carbon atoms; and a is 0 or 1),or a partially hydrolyzed condensate thereof; and(C) 0.1 to 15 parts by weight of a trialkoxysilane represented by the formula (III):R.sup.4 (R.sup.5).sub.b Si(OR.sup.6).sub.3-b (III)(wherein R.sup.4 represents a substituted or unsubstituted aminoalkyl group; R.sup.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: February 10, 1998
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Shigeki Matsushita, Fumihiko Kobayashi
  • Patent number: 5717010
    Abstract: The present invention provides novel vinyl containing organopolysiloxane elastomers which possess excellent low compression set and heat aging characteristics and which can advantageously be formulated into liquid silicone elastomer moldable compositions.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: February 10, 1998
    Assignee: General Electric Company
    Inventors: Brian J. Ward, Edward M. Jeram, Richard A. Striker
  • Patent number: 5714529
    Abstract: Novel contrast media for use in ultrasonic imaging are described. Such contrast media may be comprised of an aqueous solution of one or more biocompatible polymers, wherein said biocompatible polymers are coated with and/or in admixture with at least one silicon containing compound. Alternatively, the contrast media may be comprised of an aqueous solution of one or more biocompatible synthetic polymers, or an aqueous solution of cellulose. The contrast media may be employed, if desired, with anti-gas agents and/or suspending agents.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: February 3, 1998
    Assignee: ImaRx Pharmaceutical Corp.
    Inventors: Evan C. Unger, Guanli Wu
  • Patent number: 5714528
    Abstract: Novel contrast media for use in ultrasonic imaging are described. Such contrast media may be comprised of an aqueous solution of one or more biocompatible polymers, wherein said biocompatible polymers are coated with and/or in admixture with at least one silicon containing compound. Alternatively, the contrast media may be comprised of an aqueous solution of one or more biocompatible synthetic polymers, or an aqueous solution of cellulose. The contrast media maybe employed, if desired, with anti-gas agents and/or suspending agents.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: February 3, 1998
    Assignee: ImaRx Pharmaceutical Corp.
    Inventors: Evan C. Unger, Guanli Wu
  • Patent number: 5712036
    Abstract: A high solubility size composition is provided which may be applied to glass fibers useful for reinforcing polymeric materials. The size composition includes: a first film former comprising a polyester-based thermoplastic polyurethane derived from a saturated, non-crosslinkable polyester; a second film former comprising at least one ingredient selected from i) a vinyl acetate glycidyl methacrylate copolymer and ii) a mixture of a vinyl acetate glycidyl methacrylate copolymer and a vinyl acetate homopolymer; a silane coupling agent; and water. Using glass fibers coated with the high solubility size composition allows the advantageous production of low-pigmented or non-pigmented molded parts having enhanced surface appearance and color uniformity.
    Type: Grant
    Filed: May 8, 1996
    Date of Patent: January 27, 1998
    Assignee: N.V. Owens-Corning S.A.
    Inventor: Willy H. Piret
  • Patent number: 5708053
    Abstract: The present invention relates to silica-filled rubber compositions and their method of processing. The rubber compositions contain a mixture of 10 to 150 phr of a particulate precipitated silica having dispersed thereon, from 1 to 20 percent by weight based upon the weight of the silica, of a silane-modified elastomer.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: January 13, 1998
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: George Jalics, Adel Farhan Halasa, David John Zanzig
  • Patent number: 5708054
    Abstract: A two-part composition comprising a liquid composition (I) composed of the components (A), (C), and (E) described below and a liquid composition (II) composed of the components (A) (B), (C), and (D) described below, which yield upon mixing a curable liquid silicone composition comprising(A) an alkenyl-substituted poyorganopolysiloxane;(B) a hydrogen-substituted organopolysiloxane in an amount that provides 0.3 to 10 moles silicon-bonded hydrogen from component (B) per 1 mole alkenyl in component (A);(C) an inorganic filler that has a specific surface of 50 to 500 m.sup.2 /g;(D) an alkoxy-substituted organopolysiloxane; and(E) platinum catalyst in a quantity sufficient to cure the instant composition;wherein the curable silicone composition that results when liquid composition (I) and liquid composition (II) are mixed, is thixotropic and has a viscosity, immediately upon the mixing that is greater than the viscosity of liquid composition (II).
    Type: Grant
    Filed: October 28, 1996
    Date of Patent: January 13, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Katsutoshi Mine, Takae Takeuchi, Kimio Yamakawa
  • Patent number: 5703147
    Abstract: A low density, high temperature resistant insulation material that is very thermally efficient, is easily moldable and is unaffected by water. The insulation material is especially suitable for use in aviation, aerospace and automotive applications. The insulation material contains inorganic fiber; inorganic binder; hydrophilic particulate inorganic material; hydrophobic particulate inorganic material; polymer; and preferably a setting agent and an opacifier.
    Type: Grant
    Filed: August 2, 1995
    Date of Patent: December 30, 1997
    Assignee: Schuller International, Inc.
    Inventors: Phillip Charles Martin, Monroe W. Shumate, William Michael Gregg
  • Patent number: 5698619
    Abstract: The present invention relates to the use in a silica-filled rubber composition of an aminosilane compound of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms, alkyl radicals having 1 to 8 carbon atoms and aryl radicals having 6 carbon atoms, with the proviso that at least one of R.sup.1, R.sup.2 and R.sup.3 is an alkoxy radical; R.sup.4 is selected from the group consisting of alkylene groups having from 1 to 18 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; R.sup.5 is selected from the group consisting of hydrogen and alkyl groups having from 1 to 15 carbon atoms.
    Type: Grant
    Filed: June 24, 1996
    Date of Patent: December 16, 1997
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Martin Paul Cohen, Cheryl Ann Losey, Dane Kenton Parker
  • Patent number: 5698309
    Abstract: Moldings, preferably comprising polyester which contains oxide particles which have been subjected to a surface modification with a silylating agent of the formula I?R.sup.1 R.sup.2 R.sup.3 !Si--(CH.sub.2).sub.l --X--R.sup.4 (I)whereinR.sup.1 is Cl or alkoxy having 1 to 6 carbon atoms,R.sup.2 and R.sup.3 are alkyl having 1 to 6 carbon atoms or R.sup.1,l is a number from 1 to 6,X is a single bond, O, NH, CONH or NHCONH,R.sup.4 is ##STR1## where Y is CH, ##STR2## Z is OR or two radicals Z together are --O-- or NR and m and n are a number from 0 to 6, or R.sub.4 is ##STR3## where X is a single bond and R, R' and R" are H or alkyl having 1 to 6 carbon atoms,and the use of said moldings are described.
    Type: Grant
    Filed: April 5, 1995
    Date of Patent: December 16, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hermann Dallmann, Joachim Kinkel, Kurt Marquard, Ludwig Pohl
  • Patent number: 5693696
    Abstract: A modified polyurethane structionally incorporating filler having active hydrogen groups on a surface thereof into a polyurethane polymer. The filler is first fluidized with a polyol and then reacted with a linking component having an organo reactive group that is reactive with an isocyanate. Polyisocyanate and additional polyol are added to the reaction mixture such that the isocyanate reacts with the linking component and the polyol to form a polymer wherein the filler is an integral unit in the polymer. The resultant modified polyurethane has good dynamic properties and is surprisingly resilient. Preferred fillers are sand, clay talc and mixtures thereof.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: December 2, 1997
    Assignee: MCP Industries, Inc.
    Inventors: Thomas M. Garrett, Indulis Gruzins
  • Patent number: 5688840
    Abstract: A process for preparing a room temperature-curable organopolysiloxane composition comprising (A) (A-1) a specific organopolysiloxane or a mixture of (A-1) and (A-2) a specific silicone compound or a partial hydrolysis product thereof, (B) silica powder having a specific surface area of 20 to 800 m.sup.2 /g, (C) a curing catalyst, and (D) a silane coupling agent or an organopolysiloxane having a specific substituent, which comprises adding component (D) to component (A) prior to kneading or at the time of kneading components (A) and (B). The composition exhibits excellent physical characteristics, excellent workability in terms of flowability, adhesion, and extrudability, undergoes no change in viscosity with time and, in particular, suffers no impairment of these characteristics when stored for a long period of time.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: November 18, 1997
    Assignee: Toshiba Silicone Co., Ltd.
    Inventor: Kazuhisa Ono
  • Patent number: 5684064
    Abstract: A silicone composition is formed as a system including: a silicone compound, reactive group-containing modified silicic acid powder of which surface has been modified with an alkylsilane, a hexamethyldisilazane, a dimethylsilicone oil, or a mixture thereof, and an unsaturated group-containing silane compound; and inorganic fine powder carrying a surfactant. The silicone compound is preferably an addition reaction-type silicone rubber prepared from a dimethyl polysiloxane having a vinyl group, a methylhydrogenpolysiloxane and a platinum-based catalyst. The silicone composition is heat-cured to provide an elastic revolution body which is suitably used to constitute one or both of a fixing roller and a mating pressure roller in a roller fixing device for electrophotography.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: November 4, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventor: Toshiyuki Miyabayashi
  • Patent number: 5679727
    Abstract: A platinum curing organosiloxane composition having improved hysteresis characteristics when cured. The composition requires the presence of a diorganovinylsiloxy terminated polydiorganosiloxane having a viscosity within a range of about 20 Pa.multidot.s to 200 Pa.multidot.s at 25.degree. C. and containing essentially no ethylenically unsaturated hydrocarbon radicals bonded to non-terminal silicon atoms and a diorganovinylsiloxy terminated polydiorganosiloxane having a viscosity within a range of about 0.1 Pa.multidot.s to 200 Pa.multidot.s at 25.degree. C., where from 1 to 5 percent of the non-terminal repeating units of the siloxane comprise a vinyl radical. In addition, the present composition comprises 10 to 30 weight percent of a reinforcing silica filler that has been treated with hexamethyldisilazane and 1,1,3,3-tetramethyl-1,3-divinyldisilazane, and an organohydrogen siloxane crosslinker comprising at least ten silicon-bonded hydrogen atoms per molecule.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: October 21, 1997
    Assignees: Dow Corning Corporation, Dow Corning Taiwan, Incorporated
    Inventors: Phillip Joseph Griffith, Chu Yat Ho, Diane Marie Kosal, Jary David Jensen
  • Patent number: 5674935
    Abstract: A composition for in situ treating silica filler is provided, comprising a silanol-terminated, vinyl-containing polydiorganosiloxane which functions both as a processing aid and as a crosslinking agent in vulcanizable fluorosilicone and silicone elastomer compositions.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: October 7, 1997
    Assignee: General Electric Company
    Inventors: Edwin Robert Evans, James Edward Doin
  • Patent number: 5670583
    Abstract: A method of making metal oxide clusters in a single stage by reacting a metal oxide with a substoichiometric amount of an acid in the presence of an oxide particle growth terminator and solubilizer. A method of making a ceramer is also disclosed in which the metal oxide clusters are reacted with a functionalized polymer. The resultant metal oxide clusters and ceramers are also disclosed.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: September 23, 1997
    Assignee: Southwest Research Institute
    Inventor: Stephen T. Wellinghoff
  • Patent number: 5665812
    Abstract: A sulfur-vulcanizable rubber composition of improved hysteresis, comprising ilica as reinforcing filler as well as a diene polymer functionalized with a functionalizing agent having the general formula (Y).sub.m --R.sup. --Si(OR.sup.2).sub.3-n --R.sup.3 n and suitable to be used for the manufacture of tires of reduced resistance to rolling.The functionalized diene polymers are prepared by addition to the living diene polymer under suitable mixing conditions of an amount of functionalizing agent such that the molar ratio of functionalizing agent to the number of active sites is equal to or greater than 1.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: September 9, 1997
    Assignee: Compagnie Generale des Establissements Michelin-Michelin & Cie
    Inventors: Jean-Noel Gorce, Gerard Labauze
  • Patent number: 5648407
    Abstract: Compositions comprise (a) a curable resin sol comprising a colloidal dispersion of substantially spherical, substantially inorganic microparticles (e.g., surface-modified silica) in curable resin (e.g., epoxy resin); and (b) reinforcing fibers (e.g., carbon fibers). The compositions can be cured to provide fiber-reinforced composites which exhibit improved resin-dominated mechanical properties.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: July 15, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Douglas P. Goetz, Andrew M. Hine, William J. Schultz, Wendy L. Thompson
  • Patent number: 5637629
    Abstract: Reinforced polyolefinic thermoplastic composition comprising a polyolefin, an aluminum and/or magnesium silicate and a maleamic silane.
    Type: Grant
    Filed: August 7, 1996
    Date of Patent: June 10, 1997
    Assignee: Enichem S.p.A.
    Inventors: Alessandro Moro, Italo Borghi, Paolo Venti, Domenico Vianello, Roberto Pippa
  • Patent number: 5635557
    Abstract: A polypropylene composition which contains a polypropylene and one or more ingredients selected from an antistatic agent and a surface-treated or untreated fine powdery silica gives a propylene stretched film having a well-balanced transparency, slip property and blocking resistance.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: June 3, 1997
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Junichi Kimura, Minoru Takane, Yoichi Obata, Hiroyuki Tanimura
  • Patent number: 5635547
    Abstract: The process comprises the steps of (A) mixing a base material (A-1), which is obtained by mixing an organopolysiloxane and a reinforcing silica and then heating the resulting mixture, with an aminosilane compound (A-2) represented by the formula:(R.sup.1).sub.n Si[N(R.sup.2).sub.2 ].sub.(4-n)wherein a plurality of R.sup.1 may be the same or different and are each a substituted or unsubstituted monovalent hydrocarbon group, a plurality of R.sup.2 may be the same or different and are each a substituted or unsubstituted monovalent hydrocarbon group, and n is 2 or 3; to allow them to react; and (B) heating the reaction mixture obtained in the step (A) under normal pressure or reduced pressure to remove an unreacted aminosilane compound and a by-product amine, contained in the reaction mixture.
    Type: Grant
    Filed: April 5, 1995
    Date of Patent: June 3, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaharu Takahashi, Minoru Igarashi
  • Patent number: 5627241
    Abstract: A method of making an organopolysiloxane sheet or tube polymer involves contacting a sheet or tube silicate with an organo-H-chlorosilane to form an organosiloxane sheet or tube polymer with pendent .tbd.Si--H groups. Subsequently, the organosiloxane sheet or tube polymer with pendent .tbd.Si--H groups is contacted with an alkenyl group containing compound in the presence of a hydrosilation catalyst. The catalyst is used in an amount effective to catalyze a hydrosilation reaction between the alkenyl group on the alkenyl group containing compound and the hydride functionality on the organosiloxane sheet or tube polymer with pendent .tbd.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: May 6, 1997
    Assignees: Dow Corning Corporation, Case Western University
    Inventors: Chenggang Chen, Dimitris E. Katsoulis, Malcolm E. Kenney
  • Patent number: 5618869
    Abstract: A rubber composition suitable for use in tread of tires, particularly studless tires having increased digging and adhesive frictions to improve characteristics on icy roads of the tires without substantial deterioration of the durability of the tires or with minimizing the deterioration, which comprises a diene rubber component, 3 to 30 parts by weight of an ebonite powder and 0.1 to 3 parts by weight of a silylating agent, respectively, per 100 parts by weight of the rubber component.
    Type: Grant
    Filed: December 19, 1995
    Date of Patent: April 8, 1997
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Kazuo Kadomaru, Yoichi Mizuno
  • Patent number: 5616639
    Abstract: The invention relates to a tire with a rubber tread which is primarily reinforced with silica where the rubber of the said tread is composed of an elastomer base of at least three butadiene based synthetic rubbers comprised of two isoprene/butadiene copolymer elastomers having spatially defined Tg's, and a cis 1,4-polybutadiene elastomer.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: April 1, 1997
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Danielle Lucas
  • Patent number: 5607997
    Abstract: This composition comprises (A) a diorganopolysiloxane terminated with hydroxyl groups at both ends of its molecular chain having a viscosity of 25 to 1,000,000 cSt at 25.degree. C., (B) a low molecular weight organosilane or straight chain organosiloxane having silanol groups, such as HO(Me.sub.2 SiO)H, Me.sub.3 SiO[Me(OH)SiO].sub.2 SiMe.sub.3 or mixtures thereof, (C) a hydrolyzable silane, and (D) a silica filler having a specific surface area of 50 m.sup.2 /g or more. The composition has good non-flowability and exhibits good application workability when surface-finishing with spatula, and therefore is useful as building sealing materials.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: March 4, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tsuneo Kimura, Yoshio Inoue
  • Patent number: 5605982
    Abstract: Organopolysiloxane sheet or tube polymers are made by contacting a sheet or tube silicate with an alkenyl group containing chlorosilane to form an alkenylsiloxy polymer, and subsequently contacting the alkenylsiloxy sheet or tube polymer with a hydrosilane or hydrosiloxane in the presence of a hydrosilation catalyst, to catalyze a reaction between the alkenyl group on the alkenylsiloxy polymer and hydride functionality on the hydrosilane or hydrosiloxane. Silylalkoxysiloxane sheet or tube polymers are made by contacting a sheet or tube silicate with an acidic solution of an alkenyl alcohol to form a polymeric sheet or tube alkenyloxysiloxane, and subsequently contacting the alkenyloxysiloxane with a hydrosilane or hydrosiloxane in the presence of a hydrosilation catalyst, to catalyze a reaction between the alkenyl group on the alkenyloxysiloxane and hydride functionality on the hydrosilane or hydrosiloxane.
    Type: Grant
    Filed: October 12, 1995
    Date of Patent: February 25, 1997
    Assignees: Dow Corning Corporation, Case Western Reserve University
    Inventors: Timothy C. Chao, Malcolm E. Kenney, Dimitris E. Katsoulis
  • Patent number: 5604288
    Abstract: A method for preparing a thermoplastic resin composition, said method comprising hot-kneading, in the absence of a radical-generating catalyst,(A) 100 parts by weight of a thermoplastic resin; and(B) 0.1 to 200 parts by weight of an alkenyl-functional polyorganosiloxane filled with amorphous silica micropowder, wherein the weight ratio of said silica micropowder to said alkenyl-functional polyorganosiloxane is 0.01:100 to 50:100, whereby the polyorganosiloxane of component (B) is chemically bonded to resin (A).
    Type: Grant
    Filed: November 29, 1995
    Date of Patent: February 18, 1997
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Haruhiko Furukawa, Akihiro Nakamura, Akihiko Shirahata
  • Patent number: 5599868
    Abstract: A process for compounding filler materials and polymers for the preparation of vulcanizable rubber compositions comprises the steps of combining at least one polymer and other compounding ingredients with a filler treated with a liquid in an amount of from about 10 to 60 percent by weight, based upon the combined weight of the liquid and the filler under conditions sufficient to uniformly distribute the filler to form a pre-blend; and mixing the pre-blend until the filler is suitably dispersed throughout the polymer. A vulcanizable rubber composition containing a filler prepared by combining at least one polymer and other compounding ingredients with a filler treated with a liquid in an amount of from about 10 to 60 percent by weight, based upon the combined weight of the liquid and the filler under conditions sufficient to uniformly distribute the filler to form a pre-blend; and mixing the pre-blend until the filler is suitably dispersed throughout the polymer.
    Type: Grant
    Filed: April 19, 1994
    Date of Patent: February 4, 1997
    Assignee: Bridgestone Corporation
    Inventors: Georg G. A. Bohm, William M. Cole
  • Patent number: 5597853
    Abstract: A silicone rubber composition comprising an organopolysiloxane and a reinforcing silica filler can be improved in crepe hardening and shelf stability by blending a specific compound as a wetter.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: January 28, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kunio Itoh, Toshio Shinohara, Masaharu Takahashi
  • Patent number: 5578659
    Abstract: A polyarylene sulfide resin composition having excellent metal corrosion resistance and excellent mechanical properties is composed of 100 parts by weight of a polyarylene sulfide resin; from 0.1 to 10 parts by weight of a specific metal compound the surface of which has been pretreated with a first alkoxysilane compound; from 0 to 10 parts by weight of a second alkoxysilane compound; and from 5 to 500 parts by weight of an organic filler.
    Type: Grant
    Filed: June 23, 1995
    Date of Patent: November 26, 1996
    Assignee: Polyplastics Co., Ltd.
    Inventors: Sachio Anada, Nozomu Nakagawa, Kazutomo Tokushige, Toshikatsu Nitoh
  • Patent number: 5571851
    Abstract: A silane treated calcined clay, used as a filler in plastics such as polyamide or nylon resins, has improved tensile strength and flexural strength without substantial loss of impact strength, said calcined clay having been treated with a blend of silanes comprising an aminosilane and an alkylsilane.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 5, 1996
    Assignee: J.M. Huber Corporation
    Inventors: Gary Freeman, Carl J. Marshall
  • Patent number: 5561176
    Abstract: A process for treating fillers, preferably precipitated silica, to improve the physical property profile of heat curable and room temperature vulcanizable silicone rubbers and a composition for room temperature vulcanizable rubbers comprising the silica filler treated by the process of the invention.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: October 1, 1996
    Assignee: General Electric Company
    Inventors: Theresa A. Garafalo, Robert A. Smith
  • Patent number: 5539051
    Abstract: There are disclosed a resin composition for coating which comprises a mixture of(i) a non-aqueous dispersion type resin containing(A) a vinyl polymer soluble in an organic solvent mainly comprising an aliphatic hydrocarbon, and(B) a vinyl polymer particle which is insoluble in the organic solvent and obtained by polymerizing a polymerizable unsaturated compound in the organic solvent using the vinyl polymer (A) as a dispersant, and(ii) a solvent type resin of(C) a vinyl polymer having a silyl group represented by the formula (I) which is soluble in the organic solvent: ##STR1## wherein R.sup.1 represents an alkyl group, an aryl group or an aralkyl group, X represents a halogen atom, an alkoxy group, an acyloxy group or a hydroxy group, and k is an integer of 1 to 3,and a paint containing the same.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: July 23, 1996
    Assignee: Hitachi Chemical Company Co., Ltd.
    Inventors: Kuniaki Satou, Tsutomu Mamiya, Takashi Amano, Akira Hironaka
  • Patent number: 5534588
    Abstract: A room temperature vulcanizable silicone rubber composition with high elongation and low modulus comprising 10-90 percent by weight polydiorganosiloxane having terminal hydroxyl groups, 1-10 percent by weight phenyl tris-functional ketoximino-containing silane crosslinker, 0-14 percent by weight of a reinforcing or 0-60 percent by weight of a nonreinforcing filler or semi-reinforcing filler or a mixture thereof for a total of all fillers in the range of from about 6-60 percent by weight, from 0-2.5 percent by weight of an organofunctional silane adhesion promoter and an optional plasticizer and catalyst. These compositions cure to elastic materials useful as caulking materials, adhesives, coatings and encapsulating materials for the construction and other industries.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: July 9, 1996
    Assignee: AlliedSignal Inc.
    Inventors: Jeffrey A. Knepper, Dale R. Flackett, Edward T. Asirvatham
  • Patent number: 5498781
    Abstract: The present invention is a composition comprising an optically variable pigment modified with a silane functional compound and a copolymer which is a polymeric backbone having a reactive functionality thereon to react with the silane functional compound. The invention also includes a process for treating the optically variable pigment, and a coating composition containing the treated optically variable pigment.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: March 12, 1996
    Assignee: BASF Corporation
    Inventors: Jon R. Hall, Clint W. Carpenter, Stuart K. Scott
  • Patent number: 5494948
    Abstract: A mica-reinforced propylene resin composition having a volatile matter at 105.degree. C of 0.12% or less is obtained by heating and melting a mixture containing (A) a crystalline polypropylene, (B) mica treated with an organosilane compound, (C) a bismaleimide compound, and (D) an organic peroxide. It has excellent stiffness, heat resistance and dimensional stability, does not corrode a mold, and does not exhale an irritating odor during molding.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: February 27, 1996
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Taichi Nishio, Yuji Ikezawa
  • Patent number: 5494949
    Abstract: The invention relates to oxide particles which have a surface modification by covalently bonded organic groups which allow covalent bonding into polymer materials. These particles are particularly advantageous in their use as fillers or modifying agents in polymer materials, in particular polymer films.
    Type: Grant
    Filed: June 1, 1994
    Date of Patent: February 27, 1996
    Assignees: Merck Patent Gesellschaft mit beschrankter Haftung, Hoechst Aktiengesellschaft
    Inventors: Joachim Kinkel, Kurt Marquard, Ludwig Pohl
  • Patent number: 5489628
    Abstract: A pneumatic tire having a sulfur cured rubber composition as a circumferential tread. The sulfur cured rubber composition is composed of, based on 100 parts by weight of rubber, from about 1.0 to 15 parts by weight of epoxidized rubber; from about 1.0 to 15 parts by weight of a carboxylated nitrile rubber; and 98 to 70 parts by weight of a rubber selected from the group consisting of medium vinyl polybutadiene, styrene-butadiene rubber, synthetic cis-1,4-polyisoprene, synthetic 3,4-polyisoprene, natural rubber, cis-polybutadiene, styrene-isoprene rubber, styrene-isoprene-butadiene rubber, acrylonitrile-butadiene rubber and mixtures thereof. The sulfur cured rubber composition is further composed of a silica filler and a silica coupling agent.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: February 6, 1996
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Paul H. Sandstrom
  • Patent number: 5489627
    Abstract: The present invention relates to a sulfur cured rubber composition particularly suited for use in tire treads. The sulfur cured rubber composition is composed of, based on 100 parts by weight of rubber, from about 1.0 to 15 parts by weight of epoxidized rubber; from about 1.0 to 15 parts by weight of a carboxylated nitrile rubber; and 98 to 70 parts by weight of a rubber selected from the group consisting of medium vinyl polybutadiene, styrene-butadiene rubber, synthetic cis-1,4-polyisoprene, synthetic 3,4-polyisoprene, natural rubber, cis-polybutadiene, styrene-isoprene rubber, styrene-isoprene-butadiene rubber, acrylonitrile-butadiene rubber and mixtures thereof. The sulfur cured rubber composition is further composed of a silica filler and a silica coupling agent.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: February 6, 1996
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Paul H. Sandstrom