Creaming, Agglomerating, Or Coalescing A Solid Polymer Latex Or Aqueous Dispersion Wherein Solid Polymer Latex Or Aqueous Dispersion Is The Result Patents (Class 523/335)
  • Patent number: 6309787
    Abstract: A process comprising aggregating a colorant encapsulated polymer particle containing a colorant with colorant particles and wherein said colorant encapsulated latex is generated by a miniemulsion polymerization.
    Type: Grant
    Filed: April 26, 2000
    Date of Patent: October 30, 2001
    Assignee: Xerox Corporation
    Inventor: Chieh-Min Cheng
  • Patent number: 6300392
    Abstract: The present invention relates to the coagglomeration of random vinyl substituted aromatic/C4-C6 conjugated diolefin polymers with sulfur. Said coagglomerate is storage stable and easily blended with asphalt under a variety of mixing conditions. Further, polymer/asphalt blends prepared with the sulfur coagglomerated polymers show improved storage stability against phase separation.
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: October 9, 2001
    Assignee: BASF Corporation
    Inventors: Koichi Takamura, Paul Velasco, Peter Blanpain, John Cheng, Heinz Plaumann, Richard W Liu, Wayne Millican, Barry Baughman
  • Patent number: 6281281
    Abstract: To provide a filler-containing PTFE granular powder for molding, which has a high apparent density, a small electrostatic charge and excellent flowability and gives a molded article which is free from lowering of tensile strength and elongation and coloring attributable to a surfactant. Also a process for preparing the granular powder is provided. The granulation is carried out by wetting 100 parts by weight of a mixture of a PTFE powder and filler with 30 to 60 parts by weight of an aqueous solution containing an anionic surfactant in a concentration of not less than 10 times and less than 40 times the critical micelle concentration and then applying mechanical force to the mixture.
    Type: Grant
    Filed: May 7, 1998
    Date of Patent: August 28, 2001
    Assignee: Daikin Industries, Ltd.
    Inventors: Michio Asano, Tetsuo Shimizu, Shoji Kawachi
  • Patent number: 6268102
    Abstract: A process for the preparation of toner comprising mixing a colorant, a latex, optionally a wax and a polyaluminum sulfosilicate.
    Type: Grant
    Filed: April 17, 2000
    Date of Patent: July 31, 2001
    Assignee: Xerox Corporation
    Inventors: Michael A. Hopper, Raj D. Patel, Tanya J. Martin
  • Patent number: 6187825
    Abstract: A process for the continuous coagulation of aqueous dispersions of graft rubbers suitable for toughening thermoplastics is described. In the process, dispersions are transported through an apparatus having at least one shear element with a slotted stator and a rotating of the rotor within the stator, so that said dispersions are passed radially from the inside to the outside as a result of the rotation of the rotor in the shear element and, during or after passage through the slots of the rotor and stator, are subjected to such strong shearing that they coagulate, resulting in graft rubber coagulums which can be readily worked up even at a solids content of more than 50% by weight of elastomers.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: February 13, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Güntherberg, Jürgen Hofmann
  • Patent number: 6177483
    Abstract: A composition and uses of said composition are described for a latex based setting system for remedial and other operations within a wit bore. The composition comprises a pH-reducing agent and/or a coagulant. By controlling the amount of agent, the setting time of the system can be controlled in a range of 0.5 h to 15 h.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: January 23, 2001
    Assignee: Schlumberger Technology Corporation
    Inventors: Mostafa A Tehrani, Stephen N Davies, Geoffrey C Maitland
  • Patent number: 6174991
    Abstract: A process for the recovery of an initially living polymer from a cement produced in a polymerization process. The living polymer cement is shortstopped, washed, stabilised, coagulated and dried. The recovery process comprises adding a short stop to the polymer in the cement, washing catalyst residue from the polymer with water, adding an antioxidant Irganox 1520 to the cement to stabilise the polymer, adding epoxidised soya bean oil to the polymer to stabilise the polymer against colour degradation, and coagulating and drying the polymer. The pH of the cement is regulated in the range of from about 3 to about 7, and preferably from about 6 to about 7, during the catalyst wash and the coagulation steps of the recovery process. A product of the process is also described.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: January 16, 2001
    Assignee: Bayer Inc.
    Inventor: Roland Steiger
  • Patent number: 6130021
    Abstract: A process involving the mixing of a latex emulsion containing resin and a surfactant with a colorant dispersion containing a nonionic surfactant, and a polymeric additive and adjusting the resulting mixture pH to less than about 4 by the addition of an acid and thereafter heating at a temperature below about, or equal to about the glass transition temperature (Tg) of the latex resin, subsequently heating at a temperature above about, or about equal to the Tg of the latex resin, cooling to about room temperature, and isolating the toner product.
    Type: Grant
    Filed: April 13, 1998
    Date of Patent: October 10, 2000
    Assignee: Xerox Corporation
    Inventors: Raj D. Patel, Michael A. Hopper
  • Patent number: 6127461
    Abstract: The present invention relates to the coagglomeration of random vinyl substituted aromatic/C.sub.4 -C.sub.6 conjugated diolefin polymers with sulfur. Said coagglomerate is storage stable and easily blended with asphalt under a variety of mixing conditions. Further, polymer/asphalt blends prepared with the sulfur coagglomerated polymers show improved storage stability against phase separation.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: October 3, 2000
    Assignee: BASF Corporation
    Inventors: Koichi Takamura, Paul Velasco, Peter Blanpain, John Cheng, Heinz Plaumann, Richard Liu, Wayne Millican, Barry Baughman
  • Patent number: 6114415
    Abstract: A batchwise or continuous process for producing coagulated particles of polymer latex, involves partially or completely filling at least one receptacle with a fluid A which can be water, a polymer latex emulsion or a coagulant solution, the receptacle being equipped with baffles containing at least one orifice, injecting into the receptacle at least one fluid other than the fluid of the preceding stage, the injected fluid being a polymer latex emulsion and/or a coagulant solution, and in then creating and maintaining within the receptacle an oscillatory flow or an impulsive flow, in conjunction with the formation of eddies or of vortices.
    Type: Grant
    Filed: June 3, 1998
    Date of Patent: September 5, 2000
    Assignee: Elf Atochem, S.A.
    Inventors: Chris Bertelo, Laurent Gervat, Jerome Laffont, Malcolm Robert Mackley, Gilles Meunier
  • Patent number: 6110636
    Abstract: A surfactant free process for the preparation of toner comprising heating a mixture of an emulsion latex, a colorant, and a polyelectrolyte.
    Type: Grant
    Filed: October 29, 1998
    Date of Patent: August 29, 2000
    Assignee: Xerox Corporation
    Inventors: Daniel A. Foucher, Walter Mychajlowskij, Guerino G. Sacripante, Raj D. Patel
  • Patent number: 6110995
    Abstract: The use of falling-film evaporation and a concentration means such as centrifugal separation to dehydrate and concentrate a water-in-oil polymer emulsion or suspension is disclosed. In a preferred embodiment, a water-in-oil polymer composition containing less than about 25% active polymer solids is dehydrated in falling-film evaporator to produce an evaporator concentrate containing less than about 5.0% water. The evaporator concentrate then flows to a separation device such as a centrifuge, wherein oil is removed to produce a composition that is substantially a polymer and emulsifying surfactant-in-oil composition containing in excess of about 60 weight % polymer solids. The centrifuge raffinate may optionally be treated in a second separation means to capture additional polymer solids, with optional recycle of the oil-rich raffinate. The concentrated polymer composition is preferably stabilized with a steric stabilizer to produce a free flowing liquid product.
    Type: Grant
    Filed: July 12, 1994
    Date of Patent: August 29, 2000
    Assignee: Calgon Corporation
    Inventors: Wood E. Hunter, Kevin W. Frederick, Randy J. Loeffler
  • Patent number: 6096806
    Abstract: Epoxy resins, particularly those based on bisphenol A, can constitute the principal film forming polymer component of a storage stable autodepositable composition wherein the particle size distribution of all the film forming polymers in the composition satisfies certain criteria of size distribution, and an accelerator component which is an acid, oxidizing agent or complexing agent is present in amount sufficient to provide an oxidation-reduction potential at least 100 mV more oxidizing than a standard hydrogen electrode. Such dispersions can conveniently be prepared using a two stage process in which a solution of the film forming polymers is emulsified into water to form a preliminary dispersion and this preliminary dispersion is subjected to at least one particle size refinement stage in which the preliminary dispersion is forced through a narrow aperture.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: August 1, 2000
    Assignee: Henkel Corporation
    Inventors: Brian L. Mueller, Elizabeth J. Siebert
  • Patent number: 6080803
    Abstract: In a process for preparing coarse polymer dispersions Pg where a mixture M comprising at least one conjugated diene monomer A and at least one ethylenically unsaturated comonomer B is polymerized by free-radical aqueous emulsion polymerization in the presence of an emulsifier E and with or without further additives to form a fine polymer dispersion Pf and said fine polymer dispersion Pf is agglomerated to form a coarse such dispersion Pg, the agglomeration is carried out using a combination of chemical agglomeration and pressure agglomeration; the invention also relates to such coarse polymer dispersions and their use.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: June 27, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Claassen, Gerhard Blatz
  • Patent number: 6080815
    Abstract: The present invention relates to a process for producing a thermoplastic resin having high impact strength and good surface gloss, which comprises graft copolymerizing at least a vinyl cyanide compound and at least an aromatic vinyl compound for a short period of less than about 3 hours in the presence of rubber latex having high gel content. The rubber latex can be a mixture of two or more rubber latices having different particle size. The graft copolymer has the characteristics such that the degree of the inner occlusion into the resin is decreased and the degree of surface grafting is increased. Thereby, the resulted thermoplastic resin has a very high impact strength and good surface gloss, and the processability is greatly improved. In addition, when the graft copolymer is polymerized the level of coagulum formation is greatly decreased.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: June 27, 2000
    Assignee: LG Chemical Limited
    Inventors: Chang-Hong Lee, Young-Min Kim, Jin-Nyoung Yoo
  • Patent number: 6075081
    Abstract: A powder-free coagulant for use in latex dipping processes comprises a salt stable dispersion of a polychloroprene rubber and an inorganic metal salt. Optionally the coagulant will also contain a powder-free release agent, to aid release of the dipped article from the former, comprising a polypropylene wax emulsion and a cationic surfactant.
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: June 13, 2000
    Assignee: Ansell Healthcare Products Inc.
    Inventors: Jeffery G. Nile, Stanley J. Gromelski, Nevin D. Gerber
  • Patent number: 6057388
    Abstract: A process of preparing a concentrate which is useful as a thickener for aqueous compositions is provided. The process comprises obtaining a solution of an associative thickener compound in an organic solvent capable of forming a low boiling azeotrope with water. The solution is essentially free of water at this point and is at a temperature above the boiling point of said low boiling azeotrope. Water is added to said solution and an azeotrope of water and said organic solvent is distilled. The rate of addition of water is sufficient to replace said azeotrope with water, but is insufficient to cause a second phase to form in the resulting mixture of said solution and said water. The process yields a concentrate of an associative thickener in water, which concentrate is essentially free of volatile organic solvents.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: May 2, 2000
    Assignee: Henkel Corporation
    Inventors: Michael Wiggins, Dipak Shah, Reuben H. Grinstein
  • Patent number: 6013700
    Abstract: To provide a process capable of preparing a modified PTFE granular powder, in which the ganular powder having excellent handling property, i.e. powder flowability and apparent density is prepared without using a finely pulverized powder and a molded article obtained from the granular powder has excellent physical properties, and a process capable of preparing a modified PTFE granular powder, in which the ganular powder is granulated with only water without using an organic liquid and further a molded article having a break down voltage equal to that in the case of using a finely pulverized powder of unmodified PTFE can be obtained. The granulation is carried out by stirring, in an aqueous medium, a powder of perfluoro(vinyl ether)-modified polytetrafluoroethylene prepared by suspension polymerization and having an average particle size of 100 to 300 .mu.m.
    Type: Grant
    Filed: February 10, 1998
    Date of Patent: January 11, 2000
    Assignee: Daikin Industries, Ltd.
    Inventors: Michio Asano, Shingo Tanigawa, Shoji Kawachi, Tetsuo Shimizu
  • Patent number: 6011089
    Abstract: Processes for spray drying water-soluble and water-swellable vinyl-addition polymer-containing dispersions, emulsions and microemulsions to obtain substantially dry water-soluble or water-swellable polymer particles, compositions of substantially dry water-soluble or water-swellable polymer particles, methods of agglomerating spray-dried polymer particles, and methods of using spray-dried polymer particles and agglomerates in water-treating, mining, paper, food processing, soil conditioning, solution thickening, biotechnological, and oil recovery applications are disclosed.
    Type: Grant
    Filed: June 21, 1996
    Date of Patent: January 4, 2000
    Assignee: Cytec Technology Corp.
    Inventors: William Bloor Davies, John Edward Healy, Gary Kaui Lani Miller, Joseph J. Kozakiewicz, Roderick G. Ryles
  • Patent number: 5962178
    Abstract: A process for the preparation of toner including(i) aggregating a colorant and a latex emulsion containing a resin, reactive surfactant, and an ionic surfactant to form toner sized aggregates,(ii) coalescing or fusing said aggregates; and optionally(iii) isolating the toner generated, washing, and drying the toner.
    Type: Grant
    Filed: January 9, 1998
    Date of Patent: October 5, 1999
    Assignee: Xerox Corporation
    Inventor: Chieh-Min Cheng
  • Patent number: 5959027
    Abstract: A polyurethane/urea/thiourea latex having a narrow molecular weight polydispersity and sub-micron particle size can be prepared by first preparing a high internal phase ratio (HIPR) emulsion of a polyurethane/urea/thiourea prepolymer, then contacting the emulsion with a chain-extending reagent under such conditions to form the polymer latex.
    Type: Grant
    Filed: March 17, 1998
    Date of Patent: September 28, 1999
    Assignee: The Dow Chemical Company
    Inventors: James J. Jakubowski, Wayne R. Willkomm, James E. Pate, III
  • Patent number: 5928829
    Abstract: A process for the preparation of a latex by for example, the polymerization of monomer in the presence of a catalytic chain transfer component, and an initiator.
    Type: Grant
    Filed: February 26, 1998
    Date of Patent: July 27, 1999
    Assignee: Xerox Corporation
    Inventors: Chieh-Min Cheng, Dwight J. Tshudy
  • Patent number: 5929139
    Abstract: A method for the recovery of microfine suspended particles from a suspension medium, characterized by subjecting a polymeric monomer suspended in a suspension medium to suspension polymerization thereby forming microfine globular particles in the suspension solution, adding microfine water-insoluble particles to said suspension solution of microfine globular particles thereby inducing cohesion of said microfine globular particles, and separating said microfine globular particles in the form of an aggregate from said suspension solution filtration.
    Type: Grant
    Filed: October 8, 1997
    Date of Patent: July 27, 1999
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshikuni Mori, Mitsuo Kushino, Hideki Oishi, Tadahiro Yoneda
  • Patent number: 5916935
    Abstract: A process of preparing a concentrate which is useful as a thickener for aqueous compositions is provided. The process comprises obtaining a solution of an associative thickener compound in an organic solvent capable of forming a low boiling azeotrope with water. The solution is essentially free of water at this point and is at a temperature above the boiling point of said low boiling azeotrope. Water is added to said solution and an azeotrope of water and said organic solvent is distilled. The rate of addition of water is sufficient to replace said azeotrope with water, but is insufficient to cause a second phase to form in the resulting mixture of said solution and said water. The process yields a concentrate of an associative thickener in water, which concentrate is essentially free of volatile organic solvents.
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: June 29, 1999
    Assignee: Henkel Corporation
    Inventors: Michael Wiggins, Dipak Shah, Reuben H. Grinstein
  • Patent number: 5916725
    Abstract: A process for the preparation of toner comprising mixing an amine, an emulsion latex containing sulfonated polyester resin, and a colorant dispersion, heating the resulting mixture, and optionally cooling.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: June 29, 1999
    Assignee: Xerox Corporation
    Inventors: Raj D. Patel, Walter Mychajlowskij, Daniel A. Foucher, Guerino G. Sacripante, Beng S. Ong
  • Patent number: 5885708
    Abstract: A latex antistatic adhesive comprising an emulsion of polymerized microdrops dispersed in an aqueous medium, having an average diameter less than about 0.1 .mu.m, and a glass transition temperature (Tg) of from about -120.degree. C. to about 25.degree. C., wherein the polymerized microdrops are derived from emulsion microdrops of reactive monomers, said adhesive including at least one (meth)acrylic monomer, at least one polar monomer, at least one reactive oligomer and at least 1% of a lithium salt.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: March 23, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ying-Yuh Lu, Steven D. Yau
  • Patent number: 5872173
    Abstract: Synthetic latex compositions and articles produced therefrom having improved tear strength while minimizing the effect on modulus. The compositions include a synthetic rubber latex and fumed silica typically present in an amount ranging between 0.5% and 5.0% by weight of rubber solids. In a preferred embodiment, the fumed silica is introduced into the synthetic rubber latex as an aqueous dispersion of fumed silica.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: February 16, 1999
    Assignee: Cabot Corporation
    Inventor: Joginder N. Anand
  • Patent number: 5856378
    Abstract: A powder coating composition, suitable for providing a coating having certain appearance or performance attributes, which includes composite particles that are agglomerates of individual particulate components fused or bonded together into composite particles such that the composite particles are air-fluidizable and can be applied to a substrate by electrostatic spray without causing the individual particles in the composite particles to break down under the mechanical and/or electrostatic forces associated with their application to a substrate.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: January 5, 1999
    Assignee: Courtaulds Coatings (Holdings) Limited
    Inventors: John Ring, Stephen Paul Cassidy, Andrew George Cordiner, Andrew Robert Morgan, Timothy Marc Handyside, John David Sinclair-Day
  • Patent number: 5747215
    Abstract: A process for the preparation of toner comprising(i) blending (a) a colorant dispersion containing a first ionic surfactant and an optional charge control agent with (b) a latex blend comprised of linear polymer and crosslinked polymer particles, optional nonionic surfactant and a second ionic surfactant with a charge polarity opposite to that of said first ionic surfactant in said colorant dispersion;(ii) heating the resulting mixture at about below the glass transition temperature (Tg) of the linear latex polymer to form toner sized aggregates; and(iii) subsequently heating said aggregate suspension about above the Tg of the linear latex polymer to effect fusion or coalescence of said aggregates, and wherein said linear polymer is of an M.sub.w of from about 20,000 to about 40,000.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: May 5, 1998
    Assignee: Xerox Corporation
    Inventors: Beng S. Ong, Walter Mychajlowskijj, Grazyna E. Kmiecik-Lawrynowicz, Raj D. Patel, David J. Sanders, Stephan V. Drappel
  • Patent number: 5744520
    Abstract: A process for the preparation of polymer compositions which comprises mixing a conductive component with an anionic polymeric latex containing a polymer; adding a cationic surfactant, or flocculant whereby the aggregation of the latex particles and the conductive component particles results; subsequently adding colloidal stabilizer, followed by the addition of a base to obtain a pH of from about 7 to about 12; heating above about the polymer glass transition temperature thereby enabling the severage, or breakage of the formed aggregated particles; further heating above about the polymer glass transition temperature enabling the coalescence of the polymer and conductive component particles; and optionally washing and drying the resulting coalesced product.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: April 28, 1998
    Assignee: Xerox Corporation
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Richard P. N. Veregin, Raj D. Patel, Michael A. Hopper, Maria V. McDougall
  • Patent number: 5688842
    Abstract: The present invention is a method of preparing a high internal phase ratio emulsion without phase inversion comprising the steps of:a) continuously merging into a disperser and in the presence of an emulsifying and a stabilizing amount of a surfactant, a continuous phase liquid stream having a flow rate R.sub.1, and a disperse phase liquid stream having a flow rate R.sub.2 ; andb) mixing the merged streams with a sufficient amount of shear, and with R.sub.2 :R.sub.1 sufficiently constant, to form the high internal phase ratio emulsion without phase inversion or stepwise distribution of an internal phase into an external phase;wherein R.sub.2 :R.sub.1 encompasses a range, the lower limit of which range being defined by a point where the volume average particle size of the high internal phase ratio emulsion begins to show an inverse dependence on R.sub.2 :R.sub.1, and wherein the upper limit of which range is just less than an R.sub.2 :R.sub.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: November 18, 1997
    Assignee: The Dow Chemical Company
    Inventors: James E. Pate, III, Nanette E. Lutenske, James Peters, Ronald R. Pelletier
  • Patent number: 5679724
    Abstract: An ink for ink jet printing includes an emulsifiable polymer resin and a pigment, and may be made by: (a) combining (1) an emulsion of an emulsifiable polymer resin in an anionic medium with (2) a pigment and a cationic surfactant; and (b) aggregating particles in the mixture of step (a) to a desired particle size, thereby producing a solution of aggregated particles. The particles can optionally be coalesced to alter the particle size of the particles.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: October 21, 1997
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Raj D. Patel, Marcel P. Breton, Michael A. Hopper, Grazyna E. Kmiecik-Lawrynowicz, Beng S. Ong
  • Patent number: 5677368
    Abstract: By utilizing the process of this invention, nitrile rubber latices having solids contents of greater than 60 percent can be prepared from standard nitrile rubber latices having solids contents of less than 30 percent. The present invention more specifically discloses a process for increasing the solids content of a low solids nitrile rubber latex which comprises the steps of (1) concentrating the low solids nitrile rubber latex by removal of water therefrom to produce an intermediate solids nitrile rubber latex having a solids content which is within the range of about 35 percent to about 45 percent, wherein the low solids nitrile rubber latex has a solids content which is less than about 30 percent; (2) subjecting the intermediate solids nitrile rubber latex to a pressure which is within the range of about 3.45.times.10.sup.6 Pa to about 6.9.times.10.sup.7 Pa at a temperature which is within the range of about 120.degree. F. to about 170.degree. F.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: October 14, 1997
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edwin Reed Dunn, Gary Lee Burroway
  • Patent number: 5660965
    Abstract: A process for the preparation of toner compositions, or toner particles comprising generating a latex comprised of a sulfonated polyester and olefinic resin in water; generating a pigment mixture comprised of said pigment dispersed in water; shearing said latex and said pigment mixture; adding an alkali (II) halide; stirring and heating to enable coalescence; followed by filtration and drying.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: August 26, 1997
    Assignee: Xerox Corporation
    Inventors: Walter Mychajlowskij, Guerino G. Sacripante, Raj D. Patel, Daniel A. Foucher
  • Patent number: 5650256
    Abstract: A process for the preparation of toner comprising:(i) preparing a pigment dispersion, which dispersion is comprised of a pigment, and an ionic surfactant;(ii) shearing said pigment dispersion with a latex or emulsion blend comprised of resin, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant and a nonionic surfactant, and wherein said resin contains an acid functionality;(iii) heating the above sheared blend below about the glass transition temperature (Tg) of the resin to form electrostatically bound toner size aggregates;(iv) adding anionic surfactant to stabilize the aggregates obtained in (iii);(v) coalescing said aggregates by heating said bound aggregates above about the Tg of the resin;(vi) reacting said resin of (v) with acid functionality with a base to form an acrylic acid salt, and which salt is ion exchanged in water with a base or a salt, optionally in the presence of metal oxide particles, to control the toner triboelectrical charge, which toner i
    Type: Grant
    Filed: October 2, 1996
    Date of Patent: July 22, 1997
    Assignee: Xerox Corporation
    Inventors: Richard P. N. Veregin, Maria N. V. McDougall, Francisco E. Torres, Raj D. Patel, Grazyna E. Kmiecik-Lawrynowicz, T. Hwee Ng, Arthur Helbrecht
  • Patent number: 5645968
    Abstract: A process for the preparation of toner comprising(i) preparing, or providing a cationic emulsion resin latex comprised of a resin derived from at least one olefinic nonpolar monomer, a cationic olefinic monomer, a cationic free radical initiator, and optionally a chain transfer agent in an aqueous mixture comprised of a nonionic surfactant and a cationic surfactant, and which mixture is heated at a temperature of from about 60.degree. C. to about 95.degree. C.
    Type: Grant
    Filed: October 7, 1996
    Date of Patent: July 8, 1997
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Maureen M. Kedian, Raj D. Patel, Walter Mychajlowskij, Beng S. Ong
  • Patent number: 5633304
    Abstract: A process is provided for agglomerating small rubber particles in an aqueous latex to form large rubber particles. The process involves the addition of a water soluble organic acid and a water soluble organic anhydride to the latex prior to agglomeration of the rubber particles to facilitate agglomeration of the rubber particles into large rubber particles which are essentially free of coagulum. The latex of large rubber particles is useful in the preparation of ABS polyblends.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: May 27, 1997
    Assignee: General Electric Company
    Inventor: Donald M. Kulich
  • Patent number: 5627004
    Abstract: A process for the preparation of negatively charged toner comprising:(i) preparing a pigment dispersion, which dispersion is comprised of a pigment, an ionic surfactant, and optionally a charge control agent;(ii) shearing said pigment dispersion with a latex or emulsion blend comprised of a resin of styrene-vinylidene chloride-acrylic acid, styrene-vinyl chloride-acrylic acid, styrene-chloroprene-acrylic acid, styrene-butylacrylate-vinylidene chloride-acrylic acid, styrene-butylacrylate-vinyl chloride-acrylic acid, styrene-butadiene-vinylidene chloride-acrylic acid, or styrene-isoprene-vinylidene chloride-acrylic acid, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant and a nonionic surfactant;(iii) heating the above sheared blend below about the glass transition temperature (Tg) of the resin to form electrostatically bound toner size aggregates with a narrow particle size distribution; and(iv) heating said bound aggregates above about the Tg of the resin.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 6, 1997
    Assignee: Xerox Corporation
    Inventor: Bernard Grushkin
  • Patent number: 5593807
    Abstract: A process for the preparation of toner compositions comprising:(i) preparing an emulsion latex comprised of sodio sulfonated polyester resin particles of from about 5 to about 500 nanometers in size diameter by heating said resin in water at a temperature of from about 65.degree. C. to about 90.degree. C.(ii) preparing a pigment dispersion in a water by dispersing in water from about 10 to about 25 weight percent of sodio sulfonated polyester and from about 1 to about 5 weight percent of pigment;(iii) adding the pigment dispersion to a latex mixture comprised of sulfonated polyester resin particles in water with shearing, followed by the addition of an alkali halide in water until aggregation results as indicated by an increase in the latex viscosity of from about 2 centipoise to about 100 centipoise;(iv) heating the resulting mixture at a temperature of from about 45.degree. C. to about 80.degree. C.
    Type: Grant
    Filed: May 10, 1996
    Date of Patent: January 14, 1997
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Raj D. Patel
  • Patent number: 5594048
    Abstract: An article of manufacture comprising a substrate and a water-based ink composition free of volatile organic compounds which is water resistant upon curing. The water-based ink composition contains a water-based particulate pigment dispersion free of volatile organic compounds. Methods for making the water-based particulate dispersions, the water-based inks containing such dispersions and for disposing the water-based pigment dispersion and the water-based ink composition containing such pigment dispersions on a substrate are also disclosed.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: January 14, 1997
    Assignee: Southpac Trust International, Inc.
    Inventors: Donald E. Weder, Motiur Rahman
  • Patent number: 5578674
    Abstract: What is claimed is a coherent, elastomeric, solid, free-standing film comprising an organic phase comprising: (a) one or more block copolymer(s) corresponding to the formula:A--B--X.sub.m --(B--A).sub.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: November 26, 1996
    Assignee: The Dow Chemical Company
    Inventors: David R. Speth, Brian W. Walther, Ronald R. Pelletier
  • Patent number: 5567760
    Abstract: Aqueous dispersions, and films prepared therefrom, comprising an organic phase of block copolymers and optional extenders wherein the block copolymers corresponds to the formula:A-B-X.sub.m -(B-A).sub.nwherein each A is a polymer block of a monovinylidene aromatic monomer and conjugated dienes, each B is a polymer block of one or more conjugated dienes and, optionally, one or more monovinylidene aromatic monomers, X is the remnant of a multifunctional coupling agent, m is 0 or 1, and n is an integer from 1 to 5. Each A polymer block has a weight average molecular weight from 4,000 to 15,000 Daltons. Each B polymer block has a weight average molecular weight from 20,000 to 200,000 Daltons. The total monovinylidene monomer content is from 6 to 30 percent by weight of the organic phase. The effective phase volume of the A polymer block in the organic phase is from 8 to 20 percent. Thin elastomeric articles prepared from the emulsions have improved tensile strength properties.
    Type: Grant
    Filed: November 15, 1994
    Date of Patent: October 22, 1996
    Assignee: The Dow Chemical Company
    Inventors: Brian W. Walther, Gary R. Marchand
  • Patent number: 5563204
    Abstract: An aqueous dispersion is claimed which is capable of forming a free-standing, coherent, elastomeric, solid film which, after drying and annealing at 80.degree. C. for 30 minutes, demonstrates a tensile strength of about 11.0 MPa or greater wherein the dispersion comprises: I. an organic phase comprising: (a) one or more block copolymer(s) corresponding to the formula A-B-X.sub.m -(B-A).sub.n, wherein each A polymer block consists essentially of a monovinylidene aromatic monomer, having a weight average molecular weight from about 8,000 to about 15,000 Daltons, each B polymer block consists essentially of a conjugated diene and, optionally, a monovinylidene aromatic monomer having a weight average molecular weight from about 30,000 to about 200,000 Daltons, X is the remnant of a multifunctional coupling agent, m is 0 or 1, and n is an integer from 1 to 5, and (b) optionally, an extender for the block copolymer which is compatible with the B block; II. a surfactant; and III.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 8, 1996
    Assignee: The Dow Chemical Company
    Inventors: David R. Speth, Ronald R. Pelletier, Brian W. Walther
  • Patent number: 5559168
    Abstract: A method for the production of microfine colored particles, characterized by subjecting a polymeric monomer suspended in a suspension medium to suspension polymerization in the presence of a coloring agent and/or a magnetic powder thereby forming microfine globular colored particles possessing an average particle diameter in the range of from 3 to 50 .mu.m, heat treating said microfine globular colored particles with water as a heating medium at a temperature in the range of from 50.degree. C. to 130.degree. C. thereby inducing fusion of said particles and giving rise to blocks of fused particles, and then disintegrating said blocks of particles to an average particle diameter substantially equal to the average particle diameter of said microfine globular colored particles existent prior to said fusion.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: September 24, 1996
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshikuni Mori, Mitsuo Kushino, Hideki Oishi, Tadahiro Yoneda
  • Patent number: 5556911
    Abstract: Aqueous dispersions, and films prepared therefrom, comprising an organic phase of block copolymers and optional extenders wherein the block copolymers corresponds to the formula:A--B--X.sub.m --(B--A).sub.nwherein each A is a polymer block of a monovinylidene aromatic monomer and conjugated dienes, each B is a polymer block of one or more conjugated dienes and, optionally, one or more monovinylidene aromatic monomers, X is the remnant of a multifunctional coupling agent, m is 0 or 1, and n is an integer from 1 to 5. Each A polymer block has a weight average molecular weight from 4,000 to 15,000 Daltons. Each B polymer block has a weight average molecular weight from 20,000 to 200,000 Daltons. The total monovinylidene monomer content is from 6 to 30 percent by weight of the organic phase. The effective phase volume of the A polymer block in the organic phase is from 8 to 20 percent. Thin elastomeric articles prepared from the emulsions have improved tensile strength properties.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: September 17, 1996
    Assignee: The Dow Chemical Company
    Inventors: Brian W. Walther, Gary R. Marchand
  • Patent number: 5541252
    Abstract: The invention relates to a process for the preparation of low viscous, water soluble polymer dispersions on an aqueous basis with a high concentration of the active substance, containing a polymerizate A) synthesized from the monomeric components, hydrophobic monomers and optionally amphiphilic monomers, which exhibit an average molecular weight M.sub.w of at least 5.times.10.sup.5 Dalton and contain at least one polymeric dispersing agent D), where in a first step an aqueous dispersion PD) is prepared from the polymerizate A) and at least one polymeric dispersing agent D); in a second step an aqueous, highly concentrated dispersion PD') is prepared from the aqueous dispersion PD) by extracting the water; and in a third step an aqueous dispersion PD") with a high content of the active substance is prepared through the addition of an aqueous dispersion of at least one polymeric dispersing agent D) to the concentrated dispersion PD'), and where the second and third process step can be repeated in succession.
    Type: Grant
    Filed: April 12, 1995
    Date of Patent: July 30, 1996
    Assignee: Rohm GmbH
    Inventors: Gunter Schmitt, Joachim Carl, Manfred Braum, Peter Quis, Petra Schliessmann
  • Patent number: 5539021
    Abstract: The present invention is a method of preparing a high internal phase ratio emulsion without phase inversion comprising the steps of:a) continuously merging into a disperser and in the presence of an emulsifying and a stabilizing amount of a surfactant, a continuous phase liquid stream having a flow rate R.sub.1, and a disperse phase liquid stream having a flow rate R.sub.2 ; andb) mixing the merged streams with a sufficient amount of shear, and with R.sub.2 :R.sub.1 sufficiently constant, to form the high internal phase ratio emulsion without phase inversion or stepwise distribution of an internal phase into an external phase;wherein R.sub.2 :R.sub.1 encompasses a range, the lower limit of which range being defined by a point where the volume average particle size of the high internal phase ratio emulsion begins to show an inverse dependence on R.sub.2 :R.sub.1, and wherein the upper limit of which range is just less than an R.sub.2 :R.sub.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: July 23, 1996
    Assignee: The Dow Chemical Company
    Inventors: James E. Pate, James Peters, Nanette E. Lutenske, Ronald R. Pelletier
  • Patent number: 5527658
    Abstract: A process for the preparation of toner comprising:(i) preparing a pigment dispersion comprised of pigment, an ionic surfactant, and optionally a charge control agent;(ii) shearing said pigment dispersion with a latex comprised of resin, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant, and a nonionic surfactant;(iii) heating the above sheared blend of (ii) about below the glass transition temperature (Tg) of the resin, to form electrostatically bound toner size aggregates with a volume average diameter of from between about 2 and about 15 microns and with a narrow particle size distribution as reflected in the particle diameter GSD of between about 1.15 and about 1.30, followed by the addition of a water insoluble transition metal containing powder ionic surfactant in an amount of from between about 0.05 and about 5 weight percent based on the weight of the aggregates; and(iv) heating said bound aggregates about above the Tg of the resin to form toner.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: June 18, 1996
    Assignee: Xerox Corporation
    Inventors: Michael A. Hopper, Raj D. Patel, H. Bruce Goodbrand, Grazyna E. Kmiecik-Lawrynowicz
  • Patent number: 5510399
    Abstract: A process for the chemical agglomeration of a finely dispersed, aqueous synthetic rubber emulsion which involves:contacting the finely dispersed, aqueous synthetic rubber emulsion with an agglomeration agent of a water-soluble or water-dispersible copolymer, wherein the copolymer contains10 to 90% by weight of one or more hydrophobic, water-insoluble, olefinically unsaturated monomers; and90 to 10% by weight of one or more hydrophilic, water-soluble and salt-forming, olefinically unsaturated monomers;at a temperature and concentration sufficient to cause agglomeration of the finely dispersed, aqueous synthetic rubber emulsion,and the use of the thus obtained high solids synthetic rubber emulsion in the production of foamed shaped articles and foamed latices is provided.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: April 23, 1996
    Assignee: Huels Aktiengesellschaft
    Inventor: Thomas Sauer
  • Patent number: 5502161
    Abstract: An improved process for preparing free flowing tetrafluoroethylene (TFE) polymer powders is disclosed in which a TFE polymer powder is (1) wetted with an aqueous solution containing a wetting agent selected from the group consisting of (a) ethylene glycol ethers, (b) propylene glycol ethers and (c) diols or triols, (2) agglomerated and (3) dried.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: March 26, 1996
    Assignee: ICI Americas Inc.
    Inventors: Leonard W. Harvey, Eric N. Martin