Two Or More Polymers Containing More Than One 1,2-epoxy Group, Two Or More Polymers Derived From Reactants Containing More Than One 1,2-epoxy Group, Or Combination Thereof, Or One Of Said Polymers And A Reactant Containing At Least One 1,2-epoxy Group Patents (Class 523/403)
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Patent number: 6489042Abstract: An electronic circuit device comprising at least one substrate having a photoimageable covercoat, comprising at least 95 weight percent of at least one epoxy-modified aromatic vinyl-conjugated diene block copolymer and a catalyst comprising an onium salt selected from a triarylsulfonium salt and a diaryliodonium salt, wherein the covercoat is formed by solvent coating or extrusion and then heat laminated onto at least a portion of the substrate.Type: GrantFiled: October 18, 2001Date of Patent: December 3, 2002Assignee: 3M Innovative Properties CompanyInventors: Ronald L. Imken, Robert S. Clough
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Publication number: 20020103274Abstract: A method for manufacture of particles for powder coating is disclosed in which the particles are prepared from a suspension obtained from a mixture of a thermosetting resin solution and an aqueous solution containing a water-soluble polymer.Type: ApplicationFiled: April 14, 1999Publication date: August 1, 2002Inventors: HARUHIKO SATOH, YUTAKA HARADA, ATSUSHI YAMADA
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Patent number: 6423367Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: July 27, 2001Date of Patent: July 23, 2002Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
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Publication number: 20020086918Abstract: Water-dilutable binders which are self-crosslinking at room temperature, comprising reaction products ABF with epoxy-amine adducts A and formaldehyde resin formers B selected from phenols B1, (substituted) ureas B2, melamine B3, guanamines B4, and mixtures of said resin formers, with formaldehyde F or compounds which give off formaldehyde under the reaction conditions, may be formulated, following at least partial neutralization, to give aqueous coating materials which give coatings affording outstanding corrosion protection.Type: ApplicationFiled: November 2, 2001Publication date: July 4, 2002Inventors: Willibald Paar, Roland Feola, Johann Gmoser, Michael Gobec
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Patent number: 6344152Abstract: The present invention relates to the use of cycloaliphatic diamines as cosolvents for hydrophobic amines in aqueous solution. The cycloaliphatic diamines of the present invention have a formula: where n is 1 or 2, each R is independently selected from a group consisting of: hydrogen, a 1 to 6 carbon aliphatic, and a 0 to 6 carbon containing amine, wherein each R is chosen such that the cosolvent amine comprises at least two amine groups; and a quantity of water to maintain said solution as a homogeneous phase. The cosolvent diamines have particular utility in the formation of water based epoxy resin curing agents. Superior water miscibility is achieved for hydrophobic amines through the use of cycloaliphatic amines as compared to conventional cosolvents.Type: GrantFiled: June 11, 1999Date of Patent: February 5, 2002Assignee: PRC-DeSoto International, Inc.Inventors: Randy Edwin Cameron, Frank Rawolle
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Patent number: 6342580Abstract: A process for obtaining aminopolyamide-epichlorohydrin resins with a 1,3-dichloro-2-propanol content which is undetectable by ordinary means of vapor-phase chromatography. The process consists of passing the products resulting from the successive condensation of aminopolyamides and epichlorohydrin through two columns of activated carbon. In this way, aqueous resins are obtained which are free of toxic products, and which are particularly valuable as wet strength additives in the manufacture of papers for medical, cosmetic or food contact uses.Type: GrantFiled: February 2, 2000Date of Patent: January 29, 2002Assignee: AtofinaInventors: Henri Laurent, Thierry Dreyfus, Chantal Poulet, Serge Quillet
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Patent number: 6338869Abstract: The present invention provides a coating composition capable of forming a coating film having good performances such as an adhesive property even if coated on a deteriorated coating film surface of a high rust-preventive coating film of a tar epoxy resin coating material and the like without providing pre-treatment, and a coating method thereof. The above coating composition is a coating composition of an organic solvent type or solventless type comprising an epoxy resin having at least one epoxy group in a molecule and an amine base curing agent as resin components, wherein moisture of 1 to 30 parts by weight per 100 parts by weight of the solid matter of the coating composition is contained.Type: GrantFiled: June 16, 2000Date of Patent: January 15, 2002Assignee: Kansai Paint Co., Ltd.Inventors: Tadashi Nakano, Akira Saito, Shigeo Inomata
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Patent number: 6300395Abstract: A hydrophilic coating having excellent hydrophilicity, which can prevent offensive odor generation, and which has a good antibacterial performance and formability, is formed on an aluminum-containing metal material by coating an aqueous hydrophilization treating liquid containing (A) a glycidyl group-containing, water-soluble organic compound; (B) a water-soluble polymeric or polymerizable compound having a tert-amino group and at least one hydrophilic functional group selected from sulfonic, phosphonic, carboxyl, polyalkyleneglycol, hydroxyl and amide groups; and (C) an antibacterial agent not decomposing at 100° C. or lower, on an aluminum-containing metal material; and heat-drying the coated liquid.Type: GrantFiled: December 5, 1995Date of Patent: October 9, 2001Assignee: Nikon Parkerizing, Co., Ltd.Inventors: Ryosuke Sako, Tomohiro Ohsako, Tatsuo Hibino
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Patent number: 6294270Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: December 23, 1998Date of Patent: September 25, 2001Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
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Patent number: 6184312Abstract: A resin composition comprising (A) an aromatic polycarbonate resin or aromatic epoxy resin and (B) a minor amount of an organosiloxane containing phenyl and alkoxy radicals is flame retardant and does not emit harmful gases when burned. It can be molded into parts having optical transparency.Type: GrantFiled: November 18, 1998Date of Patent: February 6, 2001Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kenji Yamamoto, Masaaki Yamaya, Akira Yamamoto, Yoshiteru Kobayashi
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Patent number: 6159556Abstract: The present invention relates to an aqueous powder coating dispersion comprising a solid, pulverulent component A and an aqueous component B, in which component A. is a powder coating comprisinga) at least one epoxide-containing binder with a content of from 30 to 45%, preferably from 30 to 35%, of glycidyl-containing monomers and, if desired, with a content of aromatic vinyl compounds, preferably styrene,b) at least one crosslinking agent, preferably straight-chain aliphatic dicarboxylic acids and/or carboxy-functional polyesters, andc) if desired, catalysts, auxiliaries, typical powder coating additives, such as degassing agents, levelling agents, UV absorbers, free-radical scavengers and antioxidants,and component B.Type: GrantFiled: February 6, 1998Date of Patent: December 12, 2000Assignee: BASF Coatings AGInventors: Dietmar Moller, Joachim Woltering
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Patent number: 6120716Abstract: An epoxy resin encapsulating material for molding in a semiconductor chip by the use of a transfer molding device. The material has constituents of an epoxy resin, a curing agent, an inorganic filler, and a release agent. The material consists of 99 wt % or more of granules having a diameter of 0.1 to 5.0 mm and 1 wt % or less of minute particles having a diameter of less than 0.1 mm. The mass of the material exhibit an angle of slide of 20 to 40.degree., which demonstrates good flowability free from clogging a passage leading to a mold cavity in the transfer molding device, thereby assuring enhanced encapsulation quality. The material is prepared firstly by kneading the encapsulating composition having the above constituents and by solidifying the composition into a semi-cured solid body of B-stage condition. The sem-cured solid body is then pulverized into pieces having a diameter of 5.0 mm or less. The pieces are composed of granules having a diameter of 0.1 mm to 5.Type: GrantFiled: March 10, 1999Date of Patent: September 19, 2000Assignee: Matsushita Electric Works, Ltd.Inventors: Takanori Kushida, Akio Kobayashi, Yosuke Obata, Hironori Ikeda, Taro Fukui, Masashi Nakamura
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Patent number: 6103788Abstract: The present invention relates to a curable resin composition for use in water-based coating materials which includes as essential components an emulsion polymer (A) containing tertiary amino groups obtained by carrying out emulsion polymerization of a vinyl monomer containing a tertiary amino group with another copolymerizable vinyl monomer in a water-based medium, and a compound (B) containing, at least, an epoxy group and a hydrolyzable silyl group, with this composition preferably also including a water-based compound (C) obtained by adding a neutralizing agent to a vinyl polymer (I) containing acidic groups and/or tertiary amino groups so as to neutralize at least 10% of the acidic groups and/or the tertiary amino groups, and then dispersing or dissolving in water, and/or a compound (D), which is not included in compound (B), and contains hydrolyzable silyl group and/or a silanol group.Type: GrantFiled: July 22, 1997Date of Patent: August 15, 2000Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Nobuo Harui, Akifumi Yamamoto, Hidehisa Nakamura
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Patent number: 6096806Abstract: Epoxy resins, particularly those based on bisphenol A, can constitute the principal film forming polymer component of a storage stable autodepositable composition wherein the particle size distribution of all the film forming polymers in the composition satisfies certain criteria of size distribution, and an accelerator component which is an acid, oxidizing agent or complexing agent is present in amount sufficient to provide an oxidation-reduction potential at least 100 mV more oxidizing than a standard hydrogen electrode. Such dispersions can conveniently be prepared using a two stage process in which a solution of the film forming polymers is emulsified into water to form a preliminary dispersion and this preliminary dispersion is subjected to at least one particle size refinement stage in which the preliminary dispersion is forced through a narrow aperture.Type: GrantFiled: February 17, 1998Date of Patent: August 1, 2000Assignee: Henkel CorporationInventors: Brian L. Mueller, Elizabeth J. Siebert
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Patent number: 5962571Abstract: Process for making organic solvent-free aqueous crosslinkable polymer composition comprising: a) preparing an aqueous solution of an acid-functional oligomer with Tg 10 to 125.degree. C. and having crosslinker functional groups; b) conducting an aqueous emulsion polymerization to make an aqueous emulsion of an olefinic hydrophobic polymer in the presence of the aqueous oligomer solution, the hydrophobic polymer having Tg at least 25.degree. C. below that of the oligomer and optionally crosslinker functional groups, and c) combining with a crosslinking agent reactable with the crosslinker groups of the oligomer and polymer, said composition having Koenig hardness of .gtoreq.40 sec and minimum film forming temperature (MFFT) .ltoreq.55.degree. C. Also the aqueous composition so formed and its use in various applications. The aqueous composition has excellent properties and in particular an advantageous balance of MFFT and Koenig hardness.Type: GrantFiled: November 1, 1996Date of Patent: October 5, 1999Assignee: Zeneca Resins B.V.Inventors: Gerardus Cornelis Overbeek, Yvonne Wilhelmina Smak, Alfred Jean Paul Buckmann
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Patent number: 5925725Abstract: An emulsifier composition for water-dilutable epoxy resins comprise condensation products of an aliphatic polyol component having a weight-average molar mass (M.sub.w) of from 200 to 20,000 g/mol, where a mass fraction of at least 5%, has a weight-average molar mass (M.sub.w) of at least 4000 g/mol, and an epoxide component having of at least one epoxide compound having at least two epoxide groups per molecule and an epoxide group content of from 500 to 10,000 mmol/kg, the ratio of the number of hydroxyl groups to that of the epoxide groups (OH):(EP) being from 1:3.51 to 1:10. When the emulsifier is used for the preparation of aqueous epoxy resin systems, the end of the pot life is indicated by a sharp rise in viscosity.Type: GrantFiled: September 26, 1996Date of Patent: July 20, 1999Assignee: Vianova Resins GmbHInventors: Armin Pfeil, Dieter Dreischhoff, Stefan Petri, Claus Godau
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Patent number: 5925698Abstract: The present invention is directed to a powder coating composition containing at least one film forming resin and a non-flatting and slip-enhancing amount of at least one additive. The additive is a non-crosslinked reaction product of a hydroxy compound and a carboxylic acid where the reaction product contains at least one ester functionality and at least one straight chain hydrocarbyl group of about 10 to about 100 carbon atoms. The most preferred additive is sorbitan tristearate. The cured powder coatings exhibit lower coefficient of friction and substantial gloss retention.Type: GrantFiled: February 13, 1998Date of Patent: July 20, 1999Assignee: The Lubrizol CorporationInventor: Thomas F. Steckel
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Patent number: 5877239Abstract: An aqueous protective coating composition particularly useful for can coatings based on a polymeric binder comprises diepoxide crosslinked microgel particles. The microgel polymer is produced by dispersing into water a carboxyl functional acrylic-epoxy copolymer and combined with a carboxyl functional latex polymer along with a low molecular weight diepoxide, followed by coreaction and crosslinking between the carboxyl polymers and the diepoxide to form stable aqueous dispersed microgel particles. In a preferred aspect of the invention, the carboxyl latex polymer is a swollen latex polymer.Type: GrantFiled: August 18, 1997Date of Patent: March 2, 1999Assignee: The Glidden CompanyInventors: Gary P. Craun, Beth A. Smith, Neal S. Williams
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Patent number: 5855961Abstract: This invention relates to coating compositions including one or more resins having amino-reactive groups; one or more polyamine curing agents; and one or more aminourethanes. The aminourethanes can be reaction products of (i) oligomeric or polymeric compounds which contain at least one, preferably two or more terminal 2-oxo-1,3-dioxolane groups (cyclic carbonate groups), and (ii) amines containing at least one primary, preferably two or more primary and, if desired, also secondary and tertiary amino groups. The ratios of equivalents of C1):C2) typically is from 1:1 to 1:10, preferably from 1:1.05 to 1:5 and particularly preferably from 1:1.1 to 1:2, and the end product preferably contains one or more free primary amino groups. The composition further may contain, if desired, pigments, fillers, one or more organic solvents, water and conventional additives.Type: GrantFiled: May 12, 1997Date of Patent: January 5, 1999Assignee: Vianova Resins GmbHInventors: Michael Hoenel, Armin Pfeil, Thomas Budnick, Heiner Schwan
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Patent number: 5814374Abstract: An aqueous coating composition having low VOC is provided. The invention provides excellent hardness and resistance properties in films formed from binders having glass transition temperatures below ambient temperature. The improvement in film properties comes from the binding of functionalized polyvinyl alcohol to a complementary functionalized latex binder. The low VOC compositions of this invention are useful for a variety of coatings including paints, stains, varnishes, mastics and adhesives.Type: GrantFiled: June 19, 1996Date of Patent: September 29, 1998Assignee: Rohm and Haas CompanyInventors: Asare Nkansah, Stewart Orlyn Williams, Richard Foster Merritt
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Patent number: 5811475Abstract: A method for producing a carbonaceous material including the step of contacting a carbon material with a polymer having in the molecule thereof one or more reactive group(s) selected from aziridine group, oxazoline group, N-hydroxyalkylamido group, epoxy group, thioepoxy group, isocyanato group, hydroxyl group, amino group, vinyl group, acryl group or methacryl group, and an alkoxycarbonyl group represented by the formula (I)R.sup.1 R.sup.2 R.sup.3 C--O--CO-- (I)wherein R.sup.1, R.sup.2 and R.sup.3 are the same or different groups and denote a hydrogen atom, or a specific organic residue.Type: GrantFiled: June 24, 1996Date of Patent: September 22, 1998Assignee: Nippon Oil Co., Ltd.Inventors: Takayuki Hirayama, Yoshifumi Morita, Haruyoshi Sato, Yutaka Otsuki
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Patent number: 5767175Abstract: An aqueous coating composition comprising an acrylic resin-modified epoxy resin (D), which is obtained by the reaction between a mixture of a bisphenol F based epoxy resin (A) and a bisphenol F based phenoxy resin (B) and an acrylic resin having carboxyl functionality (C), said acrylic resin-modified epoxy resin (D) being dispersed into water, preferably by using ammonia or amine, provides a composition with low viscosity, excellent storage stability and excellent application workability. In addition, the coating of the present invention can be applied to an interior surface and the resulting film has a smooth surface, excellent processability, excellent retorting resistant properties, excellent adhesion properties, and excellent corrosion resistant properties.Type: GrantFiled: February 1, 1996Date of Patent: June 16, 1998Assignee: Kansai Paint Company, Ltd.Inventors: Yasuo Kamekura, Tomokuni Ihara, Kaoru Morita
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Patent number: 5741835Abstract: A stable aqueous emulsions of epoxy resins are provided using an epoxy-functional polyether having the formula: ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.15 alkyl, aryl or alkylaryl group, R.sup.2 is a divalent aliphatic group, a divalent cycloaliphatic group, a divalent aryl group, or a divalent arylaliphatic group, R.sup.3 is independently a hydrogen or a C.sub.1 -C.sub.10 alkyl group, R.sup.8 is a divalent aliphatic group optionally containing ether or ester group(s) or together with R.sup.9 or R.sup.10 form a spiro ring optionally containing heteroatoms, and R.sup.9 and R.sup.10 are independently hydrogen or R.sup.9 or R.sup.10 together with R.sup.Type: GrantFiled: July 17, 1997Date of Patent: April 21, 1998Assignee: Shell Oil CompanyInventor: Charles John Stark
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Patent number: 5739184Abstract: The present invention relates to thermosetting resin compositions which may be used in the automotive industry as sealants to coat steel substrates. The thermosetting resin composition contains an epoxy resin, a rosin, an organometallic compound and, optionally, an elastomeric and/or thermoplastic polymeric binder.Type: GrantFiled: December 17, 1996Date of Patent: April 14, 1998Assignee: National Starch and Chemical CompanyInventors: David L. Marbry, David R. Duller
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Patent number: 5733970Abstract: An aqueous protective coating composition particularly useful for can coatings based on a polymeric binder comprises water dispersed diepoxide crosslinked microgel particles. The microgel polymer is produced by disposing in water a carboxyl functional, addition polymer modified, maleated glyceride oil copolymer and crosslinking aqueous disposed carboxyl copolymer with a low molecular weight diepoxide to form stable aqueous disposed microgel particles. The maleated glyceride oil can be modified by in-situ polymerizing ethylenic monomers with the maleated glyceride oil in the absence of water or in water to form either a water dispersed copolymer or an aqueous emulsion copolymer. The water disposed copolymer is subsequently heat reacted with diepoxide mixed with the copolymer to form aqueous dispersed microgel polymer particles.Type: GrantFiled: January 28, 1997Date of Patent: March 31, 1998Assignee: The Glidden CompanyInventor: Gary P. Craun
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Patent number: 5726235Abstract: An aqueous coating composition wherein fine grains coated with water soluble resin composed of three monomers are contained in aqueous medium, each of said fine grains are composed of aqueous resin of ethylenically unsaturated monomer and aqueous colloidal silica, which are coexistent each other. Therefore, the aqueous coating composition is superior in not only contamination resistance, but also waterproof and weatherproof. The paint film formed by the above aqueous coating composition is excellent in its strength. Accordingly, this aqueous coating composition is useful for a coating base of exterior type coating material.Type: GrantFiled: April 14, 1995Date of Patent: March 10, 1998Assignee: National Starch and Chemical Investment Holding CorporationInventors: Motoyuki Takagi, Takeshi Baba
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Patent number: 5726230Abstract: Disclosed is an aqueous coating composition which comprises a water-dispersible resin and an ester of a polyglycerin ether with a fatty acid.Type: GrantFiled: October 20, 1995Date of Patent: March 10, 1998Assignee: Kansai Paint Company, LimitedInventors: Masahiro Murata, Toshio Kurihara, Akira Suehiro, Syuichi Ikenoue
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Patent number: 5719210Abstract: A method of preparing a self-dispersing epoxy resin composition is provided. The method comprises reacting a polyepoxide with a polyoxyalkylene polyol wherein the equivalent ratio of epoxide groups of said polyepoxide to hydroxyl groups of said polyoxyalkylene polyol is greater than 10:1, to form an polyol-epoxy adduct and reacting said polyol-epoxy adduct with a polyepoxide and a polyhydric alcohol to form a self-dispersing epoxy resin. Also provided are aqueous dispersions of the self-dispersing epoxy resin and coating compositions comprising the same. The coating compositions are particularly useful as industrial maintenance coatings.Type: GrantFiled: November 26, 1996Date of Patent: February 17, 1998Assignee: Henkel CorporationInventors: Kartar S. Arora, Shailesh Shah
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Patent number: 5708058Abstract: Aqueous low-solvent coating compositions comprising a modified epoxy resin dispersion comprising an epoxy resin which is prepared by condensation of one or more epoxide compounds having at least two epoxide groups per molecule with an aromatic polyol; a dispersant comprising a condensation product of an aliphatic polyol and an epoxide compound having at least two epoxide groups per molecule; a diluent consisting of ethylenically unsaturated otherwise inert or, if desired, functional monomers capable of free-radical polymerization or copolymerization, and water, and also an aqueous curing agent for the modified epoxy resin (I), which is suitable for curing at room temperature or at elevated temperatures (forced drying), components (I) and (II) being employed in proportions by mass such that the ratio of the number of epoxide groups which are capable of reaction to the number of amine hydrogen atoms is between 1:0.75 and 1:2. The coating compositions can be employed to produce matt coatings and in adhesives.Type: GrantFiled: September 25, 1996Date of Patent: January 13, 1998Assignee: Vianova Resins GmbHInventors: Armin Pfeil, Bernhard Stengel-Rutkowski, Claus Godau
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Patent number: 5684096Abstract: Water-in-oil emulsions are broken by the use of adducts prepared by reacting high molecular weight polyalkylene glycol with ethylene oxide, or diglycidyl ether, or both ethylene oxide and diglycidyl ether. The adduct demulsifiers may be used alone or as a blend with other demulsifiers.Type: GrantFiled: February 14, 1996Date of Patent: November 4, 1997Assignee: Nalco/Exxon Energy Chemicals, L.P.Inventors: Grahame N. Taylor, Richard Mgla
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Patent number: 5677006Abstract: This invention relates to coating compositions including one or more resins having amino-reactive groups; one or more polyamine curing agents; and one or more aminourethanes. The aminourethanes can be reaction products of (i) oligomeric or polymeric compounds which contain at least one, preferably two or more terminal 2-oxo-1,3-dioxolane groups (cyclic carbonate groups), and (ii) amines containing at least one primary, preferably two or more primary and, if desired, also secondary and tertiary amino groups. The ratios of equivalents of C1):C2) typically is from 1:1 to 1:10, preferably from 1:1.05 to 1:5 and particularly preferably from 1:1.1 to 1:2, and the end product preferably contains one or more free primary amino groups. The composition further may contain, if desired, pigments, fillers, one or more organic solvents, water and conventional additives.Type: GrantFiled: June 1, 1995Date of Patent: October 14, 1997Assignee: Hoechst AktiengesellschaftInventors: Michael Hoenel, Armin Pfeil, Thomas Budnick, Heiner Schwan
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Patent number: 5654360Abstract: The invention provides a water-based coating composition in two pack form comprising:i) in a first pack a substantially non-aqueous solution of a silicon-containing polymer which is soluble in water miscible organic solvents and essentially soluble in aqueous media, the silicon groups on the polymer being of formula (1):--SiR.sup.1.sub.a R.sub.3-a (1)in which a is 0 to 2, R.sup.1 is Cl-6 alkyl and R is OH or a hydrolysable group, andii) in a second pack a polymer in dispersion in an aqueous liquid carrier for the composition,where the non-volatile binder solids content of the composition is at least 5% by weight and the molar concentration of silicon in the composition is greater than 0 and less than 0.5.Type: GrantFiled: December 14, 1995Date of Patent: August 5, 1997Assignee: Imperial Chemical Industries PLCInventor: Peter David Palasz
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Patent number: 5631312Abstract: A floor paint composition superior in resistance to oil and solvents, and in early strength. The composition is mainly composed of a synthetic resin emulsion based on an from anion copolymer obtained from the copolymerization of .alpha.-type hemihydrate gypsum, cement and ethylene unsaturated monomer. The ratio of weight of .alpha.-type hemihydrate gypsum to cement is between 80:20 and 95:5. The ratio of the solid content of the synthetic resin relative to 100 parts by weight of the mixture of .alpha.-type hemihydrate gypsum and cement is between 15 and 35 parts by weight. The anion copolymer contains at least one unit of a monomer selected from the group consisting of ethylene unsaturated carboxylic acid, ethylene unsaturated sulfonic acid and ethylene unsaturated phosphonic acid. The copolymer can include an ethylene unsaturated monomer having at least one organic silicon radical. The synthetic resin emulsion can include epoxy silane.Type: GrantFiled: May 21, 1996Date of Patent: May 20, 1997Assignees: Kikusui Chemical Industries Co., Ltd., Hoechst Industry LimitedInventors: Izumi Takada, Noriyuki Niwa, Ikuo Imaizumi
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Patent number: 5612394Abstract: Aqueous epoxy resin dispersion comprising (A) an epoxy resin which is a condensation product of (A-1) from 50 to 95% by weight, preferably from 55 to 85% by weight, of one or more epoxide compounds having at least two epoxide groups per molecule and an epoxide equivalent mass of from 100 to 2000 g/mol, (A-2) from 5 to 50% by weight, preferably from 15 to 45% by weight, of an aromatic polyol; and (A-3) from 0 to 25% by weight, preferably from 0 to 10% by weight, of modifying compounds containing at least two epoxide-reactive groups; (B) a dispersant comprising (B-1) a condensation product of a polyol having a weight-average molecular mass (M.sub.Type: GrantFiled: June 2, 1994Date of Patent: March 18, 1997Assignee: Hoechst AktiengesellschaftInventors: Armin Pfeil, Michael Hoenel, Paul Oberressl, Dieter Dreischhoff, Stefan Petri
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Patent number: 5602193Abstract: A stable aqueous emulsions of epoxy resins are provided using an epoxy-functional polyether having the formula: ##STR1## wherein Q is A or B, R.sup.1 is independently a divalent hydrocarbon group, R.sup.2 is a divalent aliphatic group optionally containing ether or ester groups or together with R.sup.3 or R.sup.4 form a spiro ring optionally containing heteroatoms, and R.sup.3 and R.sup.4 are independently hydrogen or R.sup.3 or R.sup.4 together with R.sup.2 form a spiro ring optionally containing heteroatoms such as oxygen, X and Y are independently hydrogen, methyl or ethyl group with the provision that if X is methyl or ethyl, Y is hydrogen or if Y is methyl or ethyl, X is hydrogen and n+m+o is a positive real number from about 15 to 450, and where Q is B, n+o is a real number in an amount effective to provide emulsifying property.Type: GrantFiled: October 31, 1995Date of Patent: February 11, 1997Assignee: Shell Oil CompanyInventor: Charles J. Stark
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Patent number: 5589534Abstract: An aqueous coating composition is provided which comprises a generally lipophilic crosslinkable binder, optionally a chemical curing/crosslinking agent for the crosslinkable binder, and a special reactive amphiphatic emulsifier comprising a lipophilic backbone having separately pendant therefrom (a) at least one activated unsaturated group and (b) at least one of a specified class of hydrophilic polyoxyalkylene groups, and possessing an HLB value of at least 6.0.Type: GrantFiled: January 10, 1994Date of Patent: December 31, 1996Assignee: Akzo Nobel N.V.Inventors: Carl W. Metzger, Bernhard H. Feith, Ute Gruber, Angelika A. Zedler, Mario M. M. van Wingerde
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Patent number: 5567747Abstract: The invention relates to a water-based oxidizing printing ink especially suited for flexographic printing. The ink comprises an epoxy ester resin, an inorganic and/or organic pigment, a drier, a cyclodextrin and water. Preferably, the ink also includes a drier activator such as 2,2'-bipyridyl and a wax.Type: GrantFiled: July 18, 1995Date of Patent: October 22, 1996Assignee: Sun Chemical CorporationInventors: Anthony R. Cappuccio, Athanasios P. Rizopoulos
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Patent number: 5561174Abstract: Disclosed is a liquid epoxy resin composition comprising (A) a liquid epoxy resin, (B) a dimethylpolysiloxane having epoxy groups at its both ends, and (C) a dispersing agent comprising the reaction product of (C-1) a dimethylpolysiloxane having amino groups or carboxyl groups reactive with epoxy resins at its side chains or both ends and having phenyl groups or polyether groups for improving its compatibility with epoxy resins at its side chains, and (C-2) an epoxy resin having the same structure as the component (A). The composition has a reduced internal stress, while maintaining the heat resistance intrinsic to epoxy resins, and has excellent resistance, crack resistance and heat shock resistance.Type: GrantFiled: September 29, 1995Date of Patent: October 1, 1996Assignee: Murata Manufacturing Co., Ltd.Inventors: Yoshinori Saito, Masaaki Hirayama, Shunjiro Imagawa, deceased
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Patent number: 5552458Abstract: The present invention is a composition comprising an optically variable pigment modified with a silane functional compound and a copolymer which is a polymeric backbone having a reactive functionality thereon to react with the silane functional compound. The invention also includes a process for treating the optically variable pigment, and a coating composition containing the treated optically variable pigment.Type: GrantFiled: May 11, 1995Date of Patent: September 3, 1996Assignee: BASF CorporationInventors: Jon R. Hall, Clint W. Carpenter, Stuart K. Scott
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Patent number: 5523336Abstract: The invention is directed to an aqueous coating composition composed of chlorinated polyolefins and one or more water-borne, self-emulsifying epoxy resins. The epoxy resin is formed from a combination of aromatic polyols, diepoxy compounds and a condensation product formed from diepoxy compounds and aliphatic polyols. The composition is free of emulsifiers yet forms homogenous mixtures in aqueous media. The composition exhibits strong bonding to plastic substrates.Type: GrantFiled: February 16, 1995Date of Patent: June 4, 1996Assignee: Heberts GmbHInventors: Peter Schreiber, Udo Hellmann, Werner Stephen, Michael Prescher
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Patent number: 5523363Abstract: A resin composition for aqueous coating, comprising, as the main components, a resin having hydroxyl group(s) and cationic group(s) and a certain novolac-substituted phenol type epoxy resin. This composition has excellent bath stability and low-temperature curability and is useful in cationic electrocoatings, in particular.Type: GrantFiled: September 30, 1993Date of Patent: June 4, 1996Assignee: Kansai Paint Co., Ltd.Inventors: Toshio Fujibayashi, Haruo Nagaoka
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Patent number: 5521246Abstract: The present invention is directed to improved aqueous dispersions containing polyurethane/vinyl polymers and to a method for making such aqueous polyurethane-vinyl polymer dispersion. The aqueous dispersions comprise a urethane prepolymer having carboxyl functionality therein and a vinyl monomer polymerized therewith. The improvement in these dispersions resides in shelf-stability and self crosslinkability at low temperature with the polyurethanes having the carboxyl functionality in quaternary form and such dispersions containing polymer having pendant epoxide groups. When the aqueous dispersions are cast as a film and the water removed, crosslinking between the carboxyl group and epoxide group occurs.Type: GrantFiled: July 25, 1994Date of Patent: May 28, 1996Assignee: Air Products and Chemicals, Inc.Inventors: Chao-Fong Tien, Chung-Ling Mao, Jeanine M. Snyder, Adalgery Beck
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Patent number: 5508325Abstract: An aqueous protective coating composition particularly useful for can coatings is based on a polymeric binder comprising epoxy crosslinked microgel particles. The microgel polymer is produced by dispersing into water a carbon grafted, carboxyl functional acrylic-epoxy copolymer, and combined with low molecular weight diepoxide, followed by coreaction and crosslinking between the carboxyl copolymer and diepoxide to form stable aqueous dispersed microgel particles.Type: GrantFiled: January 19, 1995Date of Patent: April 16, 1996Assignee: The Glidden CompanyInventors: Gary P. Craun, David J. Telford, Henry J. DeGraaf
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Patent number: 5464887Abstract: An aqueous electrocoating composition useful in a method of electrodeposition contains an electrodepositable resin, optionally a curing agent and a microparticulate crosslinked unsaturated polyester flatting agent. The microparticulate flatting agent provides the desired flatting effect without compromising coating properties such as corrosion resistance and flexibility.Type: GrantFiled: April 8, 1994Date of Patent: November 7, 1995Assignee: PPG Industries, Inc.Inventors: Matthew S. Scott, Gregory J. McCollum, Chester J. Szymanski, Craig A. Wilson
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Patent number: 5460889Abstract: A coating composition comprises an alkyd resin based topcoat and a water dilutable coating comprising an epoxy resin-modified polyester binder which is water-dilutable upon base neutralization of the free carboxyl groups and is prepared by the reaction of (A) a polyester containing (cyclo)aliphatic groups having at least six carbon atoms derived from (a.sub.1) a polycarboxylic acid with at least three carboxyl groups and/or (a.sub.2) a polyol with at least one carboxyl group, (a.sub.3) a polycarboxylic acid with two carboxyl groups and (a.sub.4) a polyol; and (B) a bisphenol epoxide resin.Type: GrantFiled: January 10, 1995Date of Patent: October 24, 1995Assignee: BASF AktiengesellschaftInventors: Lutz-Werner Gross, Ulrich Poth, Dieter Hille, Klaus Weidemeier
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Patent number: 5459180Abstract: Polyol/epoxy adducts obtained by reaction of(A) an aliphatic polyol having an average molecular weight (Mw) of 200 to 2000 and(B) an epoxy compound having at least two epoxy groups per molecule and an epoxy equivalent weight of 100 to 2000,the equivalent ratio of the OH groups to the epoxy groups being 1:3.51 to 1:10, preferably 1:4 to 1:9, particularly preferably 1:45 to 1:8, and the epoxy equivalent weight of the adduct being between 150 g/eq and at least 800 g/eq, preferably between 250 g/eq and 1000 g/eq which adducts serve as nonionic emulsifiers in water-dilutable epoxy liquid resins.Type: GrantFiled: October 12, 1994Date of Patent: October 17, 1995Assignee: Hoechst AGInventors: Armin Pfeil, Joerg-Peter Geisler, Claus Godau, Bernhard Stengel-Rutkowski, Matthias Meyer, Stefan Petri
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Patent number: 5424340Abstract: Aqueous epoxy resin dispersions containing(A) an epoxy resin which is a condensation product of one or more epoxy compound(s), of an aromatic polyol and, if used, of a modifying compound having at least two groups which are reactive with epoxides,(B) a dispersing agent in the form of a condensation product of an aliphatic polyol and an epoxy compound, the equivalent ratio of the OH groups to the epoxy groups being 1:0.8 to 1:3.5,(C) a carboxyl-containing or -releasing curing agent for the epoxy resin comprising one or more carboxyl-containing compound(s), at least one of these compounds having a functionality of at least three carboxyl groups per molecule, and(D) if desired customary additives, components (A), (B) and (C) being used in such amounts by weight that the equivalent ratio of the epoxy groups of component (A) capable of reacting to the carboxyl groups of component (B) is at least 1:0.5.Type: GrantFiled: March 23, 1994Date of Patent: June 13, 1995Assignee: Hoechst AktiengesellschaftInventors: Armin Pfeil, Joerg-Peter Geisler, Paul Oberressl, Dieter Dreischhoff
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Patent number: 5380565Abstract: A substrate is spray coated with a composition containing an epoxy resin-modified polyester binder which is water-dilutable upon base neutralization of the free carboxyl groups and is prepared via the reaction of A) a polyester containing (cyclo)aliphatic groups having at least six carbon atoms derived from (a.sub.1) a polycarboxylic acid with at least three carboxyl groups and/or (a.sub.2) a polyol with at least one carboxyl group, and (a.sub.3) a polycarboxylic acid with two carboxyl groups and (a.sub.4) a polyol; and (B) a bisphenol epoxy resin.Type: GrantFiled: October 5, 1993Date of Patent: January 10, 1995Assignee: BASF L+F AktiengesellschaftInventors: Lutz-Werner Gross, Ulrich Poth, Dieter Hille, Klaus Weidemeier
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Patent number: 5367005Abstract: The invention relates to a heatset printing ink especially suitable for the intaglio printing of security documents, particularly currency. The ink comprises: a) an epoxy resin ester reacted with an unsaturated monobasic acid and a reactive monomer, b) a cationic polyamide/ epichlorohydrin resin, c) a glycol and/or glycol ether, d) a pigment and e) a drier.Type: GrantFiled: May 12, 1994Date of Patent: November 22, 1994Assignee: Sun Chemical CorporationInventor: Solomon J. Nachfolger
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Patent number: 5362775Abstract: An epoxy resin composition comprising (i) an epoxy resin, (ii) a phenolic curing agent, (iii) an organophosphorous curing agent, (iv) alumina, and (v) a separating means for separating the organophosphorous curing agent and the alumina, which may be a coating over the surfaces of the organophosphorous curing agent.Type: GrantFiled: March 24, 1992Date of Patent: November 8, 1994Assignees: Nippondenso Co., Ltd., Shin-Etsu Chemical Co., Ltd.Inventors: Akira Shintai, Hiroshi Shibata, Toshio Shiobara, Koji Futatsumori, Seizi Katayama, Yasutaka Yoshida