Abstract: Aqueous coating composition comprising water insoluble resinous powder, aqueous resin, pigment and other optional additives including hardener, characterized by the fact that said water insoluble resinous powder is composed of a polymer obtained by reacting a mixture of epoxy resin and a resin having epoxy reactive functional groups, or a resin having both epoxy groups and epoxy reactive functional groups, with an amine in an amount sufficient to cause ring-opening of 10 to 50% of the total epoxy groups, or composed of carboxyl bearing resin admixed and reacted with high boiling basic compound. These compositions are excellent in storage stability, application characteristics and film performance.

Abstract: A cathode-depositing electrodeposition coating composition comprising an aqueous solution or dispersion containing(A) a reaction product of (1) epoxidized diene polymer, (2) an amine and optionally, (3) polymerizable unsaturated aliphatic acid;(B) a reaction product of bisphenol epoxy resin and a polymerizable aliphatic acid;(C) a blocked polyisocyanate compound; and(D) manganese dioxide or an organic salt of manganese, cobalt or copper.The composition gives a coating film having excellent properties when electrodepositing and baking at a relatively low baking temperature.

Abstract: Carbon fiber superior in processability and in physical properties as a composite is obtained by treating carbon fiber with an epoxy resin composition incorporating a polyalkylene ether glycol derivative represented by the following general formula (I) or (II): ##STR1## wherein R.sub.1 is alkylene of C.sub.1 to C.sub.30, R.sub.2 is alkyl of C.sub.1 to C.sub.30, R.sub.3 and R.sub.4 are each hydrogen or methyl, R.sub.5 is glycidyl, X is ether linkage (--O--) or ester linkage ##STR2## m and n are integers of 1 to 20.

Abstract: The invention pertains to coating compositions comprising self-curing water-dispersed polymers, epoxy-acrylic copolymers, and preferably including epoxy phosphate polymers. The self-curing water-dispersed polymers produced preferably by step-wise polymerization of ethylenically unsaturated monomers comprising alkylol acrylamide monomer, functional monomers, and other monomers, wherein the alkylol acrylamide monomers are copolymerized in the second stage monomer addition to preferentially locate alkylol acrylamide groups in the surface portion of the latex polymer particles. Melamine resins can be added to improve the cure properties of the coating composition. The coating compositions are advantageously sprayable compositions and are particularly useful for interior coatings for food and beverage containers.

Abstract: A self-curing water dispersed copolymer particularly useful for coatings for interiors of beverage containers comprises a self-curing water dispersed copolymer of polymerized ethylenic monomers, including alkylol acrylamide monomer and functional monomer, produced by copolymerizing the monomers in the presence of an epoxy phosphate additive.

Abstract: A polymeric composition useful for interior coatings for beverage containers comprises a polymeric mixture of epoxy-acrylic copolymer and epoxy phosphate ester.

Abstract: Provides new and improved water-reducible coating compositions and methods of making them. Three preferred processes are disclosed. These differ in the manner of incorporating and chemical nature of an extender polymer.Broadly, the process of the invention is one for forming an aqueous dispersion of a fluent resinous composition ofa. a mixture in an organic solvent of(i) an ionizable graft polymer of an epoxy resin and an addition polymerized resin, the addition polymerized resin being bonded to aliphatic backbone carbon atoms of the epoxy resin by carbon-to-carbon bonds, and(ii) an extender resin;b. an aqueous vehicle, andc. an ionizing agent;the ionization present from said combined components being sufficient to establish the components as a dispersion in the aqueous vehicle, and then addition polymerizing a quantity of addition polymerizable monomer, under addition polymerizing conditions, in said aqueous dispersion, the aqueous dispersion serving as a vehicle therefor.

Abstract: Aqueous coating composition, useful on metal substrates which are deep drawn after being coated, e.g., bottle caps, are made from (A) a blend of an aqueous solution of the reaction product of a glycidyl polyether of a dihydric phenol, a polyethylene glycol and phosphoric acid, (B) an aqueous dispersion of a glycidyl polyether of a dihydric phenol and, optionally, (C) an alkoxymethylmelamine.

Abstract: Aqueous powder suspensions for thermoset coatings are prepared by intimately blending a mixture of(a) an epoxy resin/amine adduct having terminal amino groups,(b) a curing agent (phenolic resin, aminoplast resin, non-acidic polyester+transesterification catalyst), and, optionally,(c) a solid epoxy resin, said blend having a softening point of at least 70.degree. C., and milling down in water to a particle size of less than 20 micrometers.

Abstract: The invention relates to a process for preparing compositions for coating metal substrates or work pieces in an aqueous bath, in which the substrate forms the cathode.In this process 5-35% by weight of at least one epoxy resin, 2-20% by weight of at least one ketone and/or hydrocarbon resin, 15-60% by weight of at least one cationic synthetic resin having functional groups--this compound is a 10-50% by weight dispersion or solution--, 5-30% by weight of at least one organic cross-linking agent, which is solid at ambient temperature and 0-73% by weight of pigments and/or conventional adjuvants are processed together in one or more stages in a grinding apparatus to form a homogeneous coating composition. At least one stage being a wet operation. The composition has a particle size of less than 100 .mu.m, preferably less than 15 .mu.m. The grinding bath is adjusted with water to the solids content required for application.

Abstract: Waterdispersible cationic resins are formed by reacting the components comprising at least(A) an epoxidized polydiene,(B) a bisglycidylether of a polyphenol,(C) an amide compound, which is formed by one or more higher, substantially multiply unsaturated fatty acids and a polyamine and which may comprise a ketimine group or a hydroxy group, and possibly(D) an organic secondary amine and/or(E) a partially and/or fully masked polyisocyanate, which product comprises excess epoxide groups and carbon-carbon double bonds and which resins can be made waterdispersible with an acid under formation of cationic groups. A composite is provided comprising the cationic resin superposed on a conducting substrate and a method is described for forming the composite.

Abstract: The invention provides an adhesive composition of the two-part separate application type comprising solutions A and B. The solution A is an aqueous solution of a high polymer having an amide bond or an imide bond within the molecule, or an aqueous dispersion obtained by adding a rubber latex and/or synthetic resin emulsion to the aqueous solution of the high polymer. The solution B is an aqueous solution of a dialdehyde compound, or an aqueous solution or dispersion obtained by adding a crosslinking agent for crosslinking the high polymer of the solution A to the aqueous solution of the dialdehyde compound.

Abstract: The invention relates to a cathodically depositable aqueous electro-dip lacquer coating composition containing as synthetic resin binder(A) from 50 to 99% by weight, based on the total quantity of synthetic resin binder, of one or more amino-1,2-epoxy resins, the amino-1,2-epoxy resin or--where several amino-1,2-epoxy resins are present--the mixture of amino-1,2-epoxy resins(a) having an average molecular weight (Mn) of from 700 to 10,000,(b) containing per 1000 molecular weight units from 0.2 to 3.6 lateral or terminal ethylenic double bonds corresponding to a hydrogenation iodine number of from 5 to 90,(c) containing primary and/or secondary alcoholic hydroxyl groups corresponding to a hydroxyl number of from 30 to 450 and(d) having an amine number of from 30 to 150,(B) from 1 to 50% by weight of a substantially non-acid polyester of a polycarboxylic acid containing at least two terminal or lateral, saturated and/or unsaturated .beta.

Abstract: An aqueous emulsion type sizing agent for carbon fibers is disclosed. The sizing agent contains a compound represented by the following general formula (I): ##STR1## wherein A represents (C.sub.2 H.sub.4 O).sub.l or (C.sub.2 H.sub.4 O).sub.n (C.sub.3 H.sub.6 O).sub.m [l is 18 to 70; n is 18 to 70; and m is 2 to 50 (1.ltoreq.n/m.ltoreq.35)];a compound represented by the following general formula (II): ##STR2## wherein R represents C.sub.q H.sub.2q+1 or ##STR3## (q is 10 to 18; and p is 15 to 70); and an epoxy resin, a process for preparation of the agent, and the method for using it are also disclosed. The sizing agent has excellent emulsion stability and heat stability, and it can impart excellent bundling properties to carbon fibers.

Abstract: Low-solvent, stable, aqueous dispersion of(a) 35 to 65% by weight of epoxide resin having a mean epoxide equivalent weight of about 250 to about 5,000 and(b) a non-ionic dispersant in the form of a polyalkylene glycol derivative, which contains as component (b) 2 to 20% by weight of dispersant comprising condensation products of polyalkylene glycols having molecular weights of 200 to 20,000 and polyglycidyl ethers of polyhydric phenols having an epoxide equivalent weight of 100 to 2,000 in an equivalent ratio of OH to epoxide groups of 1:(0.85 to 1.5),(c) 0.2 to 20% by weight of organic solvent having a boiling point below 160.degree. C. and(d) 35 to 60% by weight of water,where the proportions always total 100% by weight, the particle size is on average less than 1 .mu.m and the total solids content of the dispersion is 10 to 80% by weight, and a process for its preparation, and its use for preparing shaped articles, in particular surface coatings.

Abstract: A thermosetting resinous binder composition, heat-curable in combination with a transesterification-promoting metal compound as a catalyst to provide an insoluble infusible coating, comprising a mixture of:(1) a non-acidic resinous compound essentially free of ethylenical unsaturation, having a molecular weight of at least 900 and a hydroxyl content of at least 0.

Abstract: Epoxy resin compositions are disclosed which have an exceptional capacity to penetrate tightly wound wire bundles such as tertiary coils in high voltage flyback transformers. The subject compositions are therefore useful for encapsulating such coils.

Abstract: The invention is an improved process for preparing epoxy resin/phosphoric acid reaction products having high enough phosphomonoester contents to be water-dispersible (as base salts) and low enough free acid contents to yield water-resistant cured coatings. The phosphoric acid is provided as an acid source material deriveable by the reaction of a hydroxylic P--OH functionality-limiting agent (blocking agent) with phosphoric anhydride as such or as a reaction product thereof with less than six molecular proportions of water. A resin solvent, which may also function as the P--OH blocking agent but otherwise is inert and acceptable as part of the final coating resin formulation, is employed as the reaction medium. The epoxide/acid reaction is allowed to proceed, effectively in the absence of water, until the content in the reaction mixture of species indistinguishable from H.sub.3 PO.sub.4 by base-titration has dropped to a minimum.

Abstract: A process for preparing thermoset polymer spheres by polymerizing a thermosettable polymer such as a vinyl ester resin or an unsaturated polyester resin in water containing a suspending agent in the presence of a catalyst and an accelerator is improved by employing an organic suspending agent as the suspending agent.