Solid Polymer Derived From Ethylenic Reactants Only (includes In Situ Reactants From Plural 1,2-epoxides) Patents (Class 523/406)
  • Patent number: 4444923
    Abstract: An improved process for preparing epoxy acrylate dispersions from the reaction product of an epoxy resin and carboxyl containing polymer in the presence of tertiary amine in which the carboxyl containing polymer is formed, in situ, in the presence of a solvent solution of the epoxy resin and then subjected to the esterification reaction which can be conducted in a single pot.
    Type: Grant
    Filed: December 30, 1982
    Date of Patent: April 24, 1984
    Assignee: Mobil Oil Corporation
    Inventor: William H. McCarty
  • Patent number: 4443568
    Abstract: The product and process is directed to polymerizing second stage ethylenically unsaturated monomers within an aqueous dispersion of a preformed epoxy based resinous material comprising a mixture of graft epoxy polymer containing grafted addition polymer grafted to the epoxy backbone, ungrafted epoxy polymer, and ungrafted addition polymer uniformly dispersed in water wherein the second stage monomers are polymerized in the presence of at least 0.1% of benzoin derivative reducing agent based on monomer weight in combination with a peroxide polymerization initiator.
    Type: Grant
    Filed: October 26, 1981
    Date of Patent: April 17, 1984
    Assignee: SCM Corporation
    Inventor: James T. K. Woo
  • Patent number: 4442247
    Abstract: An aqueous coating composition comprising from 45 to 98 parts by weight (solids) of aqueous resin(s) and from 2 to 55 parts by weight (solids) of finely divided water-insoluble resin(s), in which at least a part of said aqueous resin is selected from special type of cationic resins. The resins may have mutually reactive functional groups.
    Type: Grant
    Filed: August 25, 1982
    Date of Patent: April 10, 1984
    Assignee: Nippon Paint Company, Ltd.
    Inventors: Shinichi Ishikura, Kazunori Kanda, Shohachiro Yamaguchi
  • Patent number: 4442248
    Abstract: An aqueous coating composition comprising from 45 to 98 parts by weight (solids) of aqueous resin(s) and from 2 to 55 parts by weight (solids) of finely divided water-insoluble resin(s), in which at least a part of said aqueous resin is selected from amphoteric resins having both carboxyl and amino groups. The resins may have mutually reactive functional groups.
    Type: Grant
    Filed: September 3, 1982
    Date of Patent: April 10, 1984
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Kazunori Kanda, Shinichi Ishikura
  • Patent number: 4431689
    Abstract: A process is provided for coating a substrate by applying to a substrate an aqueous coating composition that comprises (a) an aqueous dispersion of a film forming polymer having a minimum film forming temperature not higher than 45.degree. C.; (b) a solid, particulate polymer having a softening temperature in the range of 45.degree. to 260.degree. C. and an average particle size in the range of 2 to 400 .mu.m and (c) a solid, rubberlike polymer having an average particule size in the range of 1 to 500 .mu.m, the resulting coating being cured at a temperature of 70.degree.-260.degree. C. The invention also relates to the liquid aqueous coating composition to be used in said process.
    Type: Grant
    Filed: May 21, 1982
    Date of Patent: February 14, 1984
    Assignee: Akzo N.V.
    Inventor: Gerhard Gunter
  • Patent number: 4420512
    Abstract: An aqueous emulsion type sizing agent for carbon fibers is disclosed. The sizing agent contains a compound represented by the following general formula (I): ##STR1## wherein A represents (C.sub.2 H.sub.4 O).sub.l or (C.sub.2 H.sub.4 O).sub.n (C.sub.3 H.sub.6 O).sub.m [l is 18 to 70; n is 18 to 70; and m is 2 to 50 (1.ltoreq.n/m.ltoreq.35)];a compound represented by the following general formula (II): ##STR2## wherein R represents C.sub.q H.sub.2q+1 or ##STR3## (q is 10 to 18; and p is 15 to 70); and an epoxy resin, a process for preparation of the agent, and the method for using it are also disclosed. The sizing agent has excellent emulsion stability and heat stability, and it can impart excellent bundling properties to carbon fibers.
    Type: Grant
    Filed: September 7, 1982
    Date of Patent: December 13, 1983
    Assignee: Toho Belson Co., Ltd.
    Inventors: Hiroyasu Ogawa, Mikio Shima
  • Patent number: 4399256
    Abstract: Surface-coating binders based on a copolymer which contains tertiary amino groups, blocked isocyanate groups, hydroxyl groups and ether groups and which, due to partial or complete salification with an acid, is water-soluble or water-dispersible.This copolymer contains, as copolymerized units, one or more olefinically unsaturated compounds possessing a tertiary amino group, an N-(1-alkenyl) isocyanate blocked with a CH--, OH-- or NH-acidic blocking agent, an adduct of an epoxy resin based on bisphenol A and epichlorohydrin, and having a molecular weight of from 380 to 3,500, with an olefinically unsaturated alcohol of 3 to 20 carbon atoms, and one or more other copolymerizable olefinically unsaturated compounds, and has a mean molecular weight of from 1,000 to 20,000.The novel surface-coating binder is used for the cathodic electrocoating of metallic articles.
    Type: Grant
    Filed: April 7, 1981
    Date of Patent: August 16, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Jurgen Gimpel, Karl-Heinz Feuerherd, Hans-Uwe Schenck
  • Patent number: 4379872
    Abstract: Amphoteric amino sulfonate derivatives of epoxy resins having at least one terminal group of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen or methyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.20 alkyl or substituted alkyl, and R.sub.4 is C.sub.1 -C.sub.6 alkylene or substituted alkylene, which are reaction products of an epoxy resin having a plurality of terminal groups of the formula: ##STR2## wherein R.sub.1 and R.sub.2 are as defined, with an amino sulfonate of the formula:R.sub.3 --NH--R.sub.4 --SO.sub.3 Mwherein R.sub.3 and R.sub.4 are as defined, and M is a cation.
    Type: Grant
    Filed: August 17, 1981
    Date of Patent: April 12, 1983
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Shin-Ichi Ishikura, Kazunori Kanda, Ryuzo Mizuguchi
  • Patent number: 4369290
    Abstract: Resinous coating compositions can be expediently heat cured by phenol compounds containing at least two methylene amine groups which are conjugated with the aromatic alcohol group or phenol group. The hydroxyl group substantially increase the reactivity of the aminomethyl functionality whereby active hydrogen containing resins can be effectively cross-linked.
    Type: Grant
    Filed: March 12, 1979
    Date of Patent: January 18, 1983
    Assignee: SCM Corporation
    Inventors: James M. Evans, James T. K. Woo
  • Patent number: 4356277
    Abstract: Coating compositions which may be applied by conventional techniques as well as by electrodeposition are provided by reacting a polyglycidyl ether of a polyphenol with an amino acid containing at least one amine group and one carboxyl group, wherein the amine group of the acid is preferentially reactive with the epoxy groups of the polyglycidyl ether. The resultant product can then be solubilized by neutralizing at least a portion of the acid functionality thereof with an amine or other base. Especially useful amino acids are the aminobenzoic acids.
    Type: Grant
    Filed: August 28, 1978
    Date of Patent: October 26, 1982
    Assignee: PPG Industries, Inc.
    Inventor: William J. Birkmeyer
  • Patent number: 4349651
    Abstract: A water soluble addition copolymer is formed by reaction admixing a monomer having a pendant vinyl group attached to at least one ring structure selected from the group consisting of nitrogen containing heterocyclic ring structures and aromatic ring structures and their mixtures, and a monomer selected from the group consisting of maleic anhydride, fumaronitrile, tetracyanoethylene, maleimide and their mixtures, where such addition copolymer can be used alone, as curable an insulating coating composition, or can be added to a resin, to form a curable resinous insulating coating composition.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: September 14, 1982
    Assignee: Westinghouse Electric Corp.
    Inventor: James D. B. Smith
  • Patent number: 4348309
    Abstract: Spheres of cured vinyl ester resin of a size useful as a flattening agent in paper coating compositions are prepared by a process of adding an aqueous phase containing polyvinyl alcohol to a stirred vinyl ester resin phase containing a free-radical catalyst to form a resin-in-water dispersion followed by addition of a promoter and the resin allowed to cure.
    Type: Grant
    Filed: October 9, 1980
    Date of Patent: September 7, 1982
    Assignee: The Dow Chemical Company
    Inventor: Warren W. Pruess
  • Patent number: 4341682
    Abstract: Non-gelled compositions containing hydroxy ester copolymer having carboxyl groups and substantially free of oxirane groups are disclosed which are the esterification reaction product of(a) acidic addition copolymer; and(b) a polyepoxide which has been partially defunctionalized by reaction with carboxyl containing polybutadiene polymer. The resulting composition is neutralized with amine, is self-emulsifiable in water and is useful for coatings.
    Type: Grant
    Filed: December 23, 1980
    Date of Patent: July 27, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4325857
    Abstract: A durable antisoiling coating composition for textile filaments and articles made therefrom comprises a perfluoroalkyl ester of a citric acid urethane and fluorinated alcohols in combination with a modified epoxy resin which is the reaction product of a carboxyl-functional vinyl polymer, an epoxy resin and a tertiary amine. The composition can be applied as an aqueous dispersion, including a non-ionic textile lubricant based on poly(ethylene glycol). The dispersion can be used as a spin finish to provide durable protection to filaments, particularly nylon filaments.
    Type: Grant
    Filed: May 13, 1980
    Date of Patent: April 20, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Nitin J. Champaneria, Lee R. Harper, Edward A. Hosegood