Abstract: A size for carbon fibers and glass fibers comprises an epoxy resin and a polyester with a hydrophilic and a hydrophobic moiety in the molecule.

Abstract: A self-curing aqueous resin dispersion obtained by neutralizing a resin having at least one alicyclic epoxy group and at least two carboxyl groups in the molecule, with a base and dispersing the neutralized resin in water.

Abstract: An aqueous electrophoretic coating material, which can be deposited at the cathode and contains(A) 90 to 50% by weight, based on the total portion of synthetic resin vehicle, of one or several polycondensation, polymerization and/or poly-addition resins, the resin or, in the event that several resins are present, their mixture(a) having a number average molecular weight (Mn) of 700 to 10,000(b) having 1.2.times.10.sup.23 to 21.7.times.10.sup.23 lateral or terminal double bonds per 1,000 g, corresponding to a hydrogenation iodine number of 5 to 90,(c) optionally containing primary and/or secondary hydroxyl groups, corresponding to a hydroxyl number of 0 to 450 mg KOH/g of resin, and(d) tertiary amino groups corresponding to an amine number of 30 to 450 mg KOH/g of resin.

Abstract: This invention relates to a chlorine-containing resin molding characterized by its stabilization by aminocarboxylic acid and from which molding substantially no metallic ion is detected, and to material for use with the chlorine-containing resin molding consisting of 100 parts by weight of chlorine-containing resin and 0.5-5.0 parts by weight of aminocarbolyxic acid. According to the molding and the material for use therewith, there is no possibility of metallic ion dissolving from the molding in which a metallic stabilizer is conventionally used, with the result that the molding finds wide application in the industrial field related with electric parts including a semiconductor as a main item, medical treatment, chemicals and pharmaceuticals, and food stuffs, all subject to adverse effects by dissolution of metallic ion. Consideration for application of a nonmetallic agent is also given to the use of a coloring agent and a lubricant with respect to the molding and the material for use therewith.

Abstract: The invention relates to a heat-curable binder mixture which comprises an organic synthetic resin A and a crosslinking agent B. Said synthetic resin A can be an epoxy resin, a polyester resin or an acrylate resin having a number average molecular weight of 500 to 20,000 and at least 0.2 equivalent per 100 g of resin of primary and/or secondary amino groups and/or hydroxyl groups, and said crosslinking agent B is an organic compound having at least 2 .beta.-alkoxyalkyl ester groups per molecule.

Abstract: An epoxy resin-polyammonium salt emulsion is based on a liquid epoxy resin, a latent curing agent, an emulsifier, and water. The emulsion is used in epoxy resin-cement mortars, in alkaline curing cement mixtures, and in adhesive compositions based on hydraulically setting alkaline cement binders.

Abstract: A highly reactive, water-absorptive resin is prepared by (1) impregnating a highly water-absorptive resin having carboxyl or carboxylate groups and a water content of 50 percent by weight or lower with a hydrophilic polymer or monomer having a reactive group and (2) polymerizing said monomer or crosslinking said polymer with a crosslinking agent.

Abstract: Single package C-enamel can coatings of improved stability are prepared by first dispersing the zinc oxide pigment in a water compatible solvent containing a butylated urea formaldehyde or butylated melamine and adding the dispersed pigment to a vehicle comprising an aqueous blend of an epoxy-acrylic emulsion with an acrylic latex. The stability improvement is evident in the coating viscosity, the non-settling of the pigment on storage, and the flexibility adhesion in the applied coating.

Abstract: Aqueous dispersions useful as can coating compositions are made from the ammonia or amine salt of a carboxyl functional acrylic copolymer blended with phenolplast resins, polyepoxide resins partially reacted with a monofunctional acid and, optionally, an epoxidized hydrocarbon or vegetable oil.

Abstract: An epoxy resin-diammonium salt emulsion is based on a liquid epoxy resin, water, an emulsifier and a latent curing agent, wherein the emulsifier is(a) a polyvinyl alcohol obtained by saponification of polyvinyl acetate with a degree of hydrolysis of at least 70% and a molecular weight of at least 5,000,(b) a polyoxazoline having a molecular weight of 10,000-100,000, and/or(c) a copolymer of N-vinylpyrrolidone withvinyl esters of mono- or dibasic carboxylic acids of up to 6 carbon atoms,(meth)acrylic esters of mono- and dihydric alcohols of up to 6 carbon atoms,maleic, fumaric, crotonic acid and/orstyreneand wherein the latent curing agent is the salt from a(a) diamine of the formulaH.sub.2 N--CH.sub.2 --R--NH.sub.2 or H.sub.2 N--R--CH.sub.2 --R--NH.sub.2wherein R isan optionally substituted C.sub.4-9 -alkylene residue,an optionally substituted C.sub.6-9 -cyclo- alkylene residue, ora C.sub.

Abstract: Polymer concrete compositions comprising an unsaturated thermosettable resin(s) and/or ethylenically unsaturated monomer(s), an aggregate component and a water absorbent polymer are cured to provide polymer concrete with enhanced adhesion to substrates, especially wet concrete. A primer or coating composition for concrete comprising a water absorbent polymer and an unsaturated thermosettable composition is also disclosed.

Abstract: Non-aqueous dispersions are disclosed which contain (A) a relatively high molecular weight epoxy resin, (B) a non-aqueous dispersion medium, and (C) a dispersant such as a copolymer of (1) at least one polymerizable ethylenically unsaturated monomer containing a group reactive with an epoxy group and (2) at least one polymerizable ethylenically unsaturated monomer free of any groups reactive with an epoxy group.These dispersions are useful in coatings, electrical or structural laminates or composites, body solders, adhesives, caulking compounds, casting compounds, filament winding and the like.

Abstract: A cathode-precipitating electrodeposition coating composition consisting essentially of (A) 100 parts of a high-molecular-weight compound having a molecular weight of 500 to 10,000 and containing an amino group and a carbon-carbon double bond, (B) 3 to 200 parts by weight of a reaction product obtained by reacting an unsaturated carboxylic acid having 3 or 4 carbon atoms with the terminal glycidyl group of a glycidyl compound obtained by reacting a bisphenol with epichlorohydrin, and (C) 0.2 to 20 parts by weight of an oil-soluble manganese salt of a monoester of a 1,2-dicarboxylic acid or a manganese salt of sulfonated or maleinized polybutadiene having a molecular weight of 300 to 3,000.

Abstract: The composition comprises an aqueous polyelectrolyte polymer intermixed with a phosphated polymer and a self-curing water dispersed polymer containing copolymerized functional monomer and alkylol acrylamide monomer. The polyelectrolyte polymer is produced by copolymerizing ethylenically unsaturated monomers, including hydroxyl or carboxyl monomers in the presence of an ionizing agent.

Abstract: Provides new and improved water-reducible coating compositions and methods of making them. Three preferred processes are disclosed. These differ in the manner of incorporating and chemical nature of an extender polymer.Broadly, the process of the invention is one for forming an aqueous dispersion of a fluent resinous composition ofa. a mixture in an organic solvent of(i) an ionizable graft polymer of an epoxy resin and an addition polymerized resin, the addition polymerized resin being bonded to aliphatic backbone carbon atoms of the epoxy resin by carbon-to-carbon bonds, and(ii) an extender resin;b. an aqueous vehicle, andc. an ionizing agent;the ionization present from said combined components being sufficient to establish the components as a dispersion in the aqueous vehicle, and then addition polymerizing a quantity of addition polymerizable monomer, under addition polymerizing conditions, in said aqueous dispersion, the aqueous dispersion serving as a vehicle therefor.

Abstract: An improved, stabilized container coating composition of an amine solubilized hydrosol resin solution of:(a) an acrylic-poly(vinyl acetal) co-resin having a number average molecular weight above 10,000 and a glass transition temperature of -20.degree. C. to +60.degree. C.;(b) an epoxy resin having a molecular weight of 300 to 8,000; and on the average 2 or less than 2 epoxy groups per molecule; and(c) an aminoplast, a phenolplast resin, or combination thereof.

Abstract: A method for reducing extractable constituents of an undesirable monomer in compositions which comprise an ionic polymer and an addition polymer of the undesired monomer which comprises conducting an addition polymerization in the presence of the undesired monomer with another monomer which is copolymerizable therewith and which results in a less undesirable residue or a residue which is more easily removable, is disclosed.

Abstract: The metal adhesion and heat and water resistance of conventional neoprene latex adhesives are improved by the addition thereto of a polyfunctional amine and an epoxy resin wherein for every 100 parts by weight of dry neoprene, the epoxy is added in an amount of 10-40 parts and the amine is added in an amount sufficient to provide 50-150% of the stoichiometric amount required to cure the epoxy.

Abstract: Aqueous compositions suitable for sanitary can coatings comprising the neutralized water dispersible ionic polymer product of the reaction of an epoxy resin with acid polymer, and a different resin which is not necessarily self-dispersible in water, as well as several methods of preparing such compositions, are disclosed. The second resin which is not necessarily self-dispersible in water is introduced either preformed at any stage or is prepared, in situ, in the presence of the epoxy resin esterified with acid polymer either before the ionic epoxy resin-acid polymer product is dispersed in water. The epoxy resin-acid polymer product acts as a polymeric surfactant capable of keeping even a normally non self-dispersible second polymer in stable dispersion in water.

Abstract: A coating composition having a liquid carrier and a binder of a blend ofa. an acrylic polymer containing glycidyl groups andb. a crosslinkable polysiloxane having attached to the silicone atoms of its backbone alkyl groups, phenyl groups and hydroxyl groups;optionally, a fluorocarbon polymer can be added to the composition;the composition cures at ambient temperatures and provides a finish that is durable, weatherable and heat resistant and is particularly useful for coating pipes, tanks, vessels and stacks of plants and refineries that are subjected to weathering, chemicals and heat.

Abstract: An improved process for preparing epoxy acrylate dispersions from the reaction product of an epoxy resin and carboxyl containing polymer in the presence of tertiary amine in which the carboxyl containing polymer is formed, in situ, in the presence of a solvent solution of the epoxy resin and then subjected to the esterification reaction which can be conducted in a single pot.

Abstract: An aqueous coating composition comprising from 45 to 98 parts by weight (solids) of aqueous resin(s) and from 2 to 55 parts by weight (solids) of finely divided water-insoluble resin(s), in which at least a part of said aqueous resin is selected from amphoteric resins having both carboxyl and amino groups. The resins may have mutually reactive functional groups.

Abstract: An aqueous coating composition comprising from 45 to 98 parts by weight (solids) of aqueous resin(s) and from 2 to 55 parts by weight (solids) of finely divided water-insoluble resin(s), in which at least a part of said aqueous resin is selected from special type of cationic resins. The resins may have mutually reactive functional groups.

Abstract: A process is provided for coating a substrate by applying to a substrate an aqueous coating composition that comprises (a) an aqueous dispersion of a film forming polymer having a minimum film forming temperature not higher than 45.degree. C.; (b) a solid, particulate polymer having a softening temperature in the range of 45.degree. to 260.degree. C. and an average particle size in the range of 2 to 400 .mu.m and (c) a solid, rubberlike polymer having an average particule size in the range of 1 to 500 .mu.m, the resulting coating being cured at a temperature of 70.degree.-260.degree. C. The invention also relates to the liquid aqueous coating composition to be used in said process.

Abstract: A composition useful in coatings, binders, adhesives, and the like comprises a stable blend of a carboxylic acid copolymer emulsion and a halohydroxy propyl ammonium copolymer solution. The blend is curable, after activation by base, to a crosslinked insoluble alloy polymer.

Abstract: Compositions suitable for bonding fibrous substrates comprise a liquid hydrophilic air-curing polymer and an unsaturated thermoplastic polymer latex.

Abstract: Aqueous dispersions of fluorocarbon polymers in combination with the water-borne reaction product of (a) carboxyl-functional polymers, (b) polyepoxides and (c) tertiary amines are provided. Such dispersions can be applied to a variety of substrates by either conventional coating techniques or electrodeposition, and provide coatings that exhibit excellent release properties and high lubricity.

Abstract: The invention provides a novel water-swellable polymeric composition useful as a leakage-preventing material filling an interstice, for example, in a concrete body or at a pipe joint. The polymeric composition comprises (a) a hydrophilic or water-soluble polymer having carboxyl groups in the molecule, (b) a water-soluble epoxy compound having at least two epoxy groups per molecule and (c) a rubbery polymer as blended with the components (a) and (b) in the form of an aqueous dispersion, e.g. a rubber latex, having been dried and subjected to a heat treatment, preferably, as impregnating a fibrous core material.

Abstract: Polymer dispersions characterized in that they contain N-methylol(meth)acrylamide groups, comprising30-65% by weight of methylmethacrylate,10-17% by weight of ethylacrylate,10-30% by weight of butylmethacrylate,5-20% by weight of styrene,3-10% by weight of N-methylol(meth)acrylamide,and containing as a coalescing agent from about 5 to 15% by weight, based on the dispersion, of a blend comprising20-65% by weight of a high boiling paint solvent such as 2,2,4-trimethylpentane-1,5-diol-monotrimethylacetate and80-35% by weight of ethylene glycol monoethyletheracetate, and/or ethylene glycol monobutyletheracetate,optionally in conjunction with basic varnishes based on cationic water-soluble acrylic copolymers, are described. The dispersions when used in coating compositions for coating wood surfaces provide a coating on wood having good mar resistance, hardness, and flexibility, while accentuating the wood grain and color.

Abstract: Aqueous dispersions of fluorocarbon polymers in combination with the water-borne reaction product of (a) carboxyl-functional polymers, (b) polyepoxides and (c) tertiary amines are provided. Such dispersions can be applied to a variety of substrates by either conventional coating techniques or electrodeposition, and provide coatings that exhibit excellent release properties and high lubricity.

Abstract: Sizing composition for glass fibers, method of making same, method of making sized glass fibers and sized glass fibers are provided to have improved sized glass fibers for use in thermosetting molding compounds. The improved sized glass fibers are produced with improved processability and have good handling characteristics and give improved properties to thermosetting molding compounds.The sizing composition is an aqueous sizing composition having water soluble or dispersible, liquid epoxy resin, melamine formaldehyde condensate, polyamide resin and thermoplastic plasticizing agent, and one or more silane coupling agents.The method of preparing the sizing composition involves adding the melamine formaldehyde condensate and polyamide resin before the addition of or in the presence of the epoxy resin.The sized glass fibers are in contact with dried residue of the epoxy resin, melamine formaldehyde-polyamide reaction product, thermoplastic plasticizing agent and one or more silane coupling agents.

Abstract: Room temperature curable latices can be produced by copolymerizing ketimine derivative ethylenically unsaturated monomers with conventional ethylenically unsaturated monomers in an emulsion process at a controlled pH greater than about 7.2 to produce a coagulum-free latex containing blocked amine (--NH.sub.2) groups. In use, the pH of the latex can be adjusted to acidic below 7 to generate unblocked reactive amino groups which can be cured or cross-linked at about room temperature with water-dispersed polymers such as epoxy, double bond or isothiocyanate containing polymers.