Boron Dnrm Patents (Class 523/445)
  • Publication number: 20120077904
    Abstract: The present invention provides an epoxy resin composition comprising epoxy resin, phenolic resin, a cure accelerator and an inorganic filler; said epoxy resin comprises: (1) 20-50% of Formula I; (2) 10-40% of Formula II; and (3) 0-30% of Formula III and/or 0-40% of Formula IV, wherein Formula III and Formula IV are not 0% simultaneously; and wherein, R1 and R2 are independently hydrogen or alkyl of C1-C6; n is an integer from 0 to 50 in Formula I; the ratio of the number of phenolic hydroxyls in said phenolic resin to the number of epoxy groups in the epoxy resin mixture is 0.8-1.3; all said percentages are percentages relative to the total mass of the epoxy resin mixture.
    Type: Application
    Filed: September 30, 2011
    Publication date: March 29, 2012
    Inventors: Guangchao XIE, Xingming CHENG
  • Publication number: 20120064788
    Abstract: The present invention relates to fiber glass strands, yarns, fabrics, composites, prepregs, laminates, fiber-metal laminates, and other products incorporating glass fibers formed from glass compositions. The glass fibers, in some embodiments, are incorporated into composites that can be used in reinforcement applications. Glass fibers formed from some embodiments of the glass compositions can have certain desirable properties that can include, for example, desirable electrical properties (e.g. low Dk) or desirable mechanical properties (e.g., specific strength).
    Type: Application
    Filed: September 14, 2011
    Publication date: March 15, 2012
    Inventors: James Carl Peters, Juan Camilo Serrano, Hong Li, Cheryl A. Richards, Steven Joel Parks
  • Publication number: 20120065295
    Abstract: Disclosed is a curable system comprising at least two compositions (A) and (B), a method for the manufacturing of a cured product as well as cured products obtainable by the method.
    Type: Application
    Filed: March 25, 2010
    Publication date: March 15, 2012
    Applicant: Huntsman International LLC
    Inventors: Josef Grindling, Christian Beisele, Astrid Beigel, Cliff Beard, Ann Beard
  • Publication number: 20110274888
    Abstract: The invention relates to a composite material made up of at least one ceramic layer or at least one ceramic substrate and at least one metallization formed by a metallic layer on a surface side of the at least one ceramic substrate.
    Type: Application
    Filed: October 20, 2009
    Publication date: November 10, 2011
    Inventors: Xinhe Tang, Helmut Hartl
  • Publication number: 20110255258
    Abstract: Disclosed is a resin composition exhibiting a low thermal expansion coefficient, as well as higher heat resistance, flame resistance and insulation reliability than ever before when used in a multilayer printed wiring board that requires fine wiring work. Also disclosed are a prepreg, a resin sheet, a metal-clad laminate, a printed wiring board, a multilayer printed wiring board and a semiconductor device, all of which comprising the resin composition. The resin composition of the present invention comprises (A) an epoxy resin, (B) a cyanate resin and (C) an onium salt compound as essential components.
    Type: Application
    Filed: December 22, 2009
    Publication date: October 20, 2011
    Inventor: Kuniharu Umeno
  • Publication number: 20110257299
    Abstract: A composition comprising: a) an epoxy resin; b) a hardener; and c) a stabilizer comprising a metal-containing compound, the metal-containing compound comprising a metal selected from the group consisting of Group 11-13 metals and combinations thereof, wherein the composition is prepared from a halogen-containing compound is disclosed.
    Type: Application
    Filed: January 6, 2009
    Publication date: October 20, 2011
    Applicant: Dow Global Technologies LLC
    Inventors: Tomoyuki Aoyama, Frank Y. Gong, Bernd Hoevel, Michael J. Mullins, Perrin Shao Ping Ren, Joey W. Storer, Hung-Jue Sue, Ludovic Valette, Anteneh Z. Worku, Raymond J. Thibault
  • Publication number: 20110237711
    Abstract: The invention relates to a heat curable composition for fire-resistant or intumescent composite parts, which is free of any halogen additive or halogen structure in the components thereof, and which comprises: a) 100 parts by weight of a dry resin, including a1) an unsaturated polyester having an acid index lower than 10 and/or a2) a vinyl ester; b) 40 to 200 parts by weight of a reactive thinner among ethylenically unsaturated monomers; c) 20 to 110 parts by weight of a thermal expansion agent selected from melamine and derivatives thereof, guanidine, glycine, urea, triisiocynurates, and azodicarbinamide; d) 0 to 250 parts by weight of aluminium trihydrate; e) 10 to 80 parts by weight of a carbonisation precursor agent selected from multifunctional polyols; f) 50 to 200 parts by weight of a compound selected from a phosphorus derivative and/or a boric acid derivative; g) optionally at least one metal oxide; h) optionally other additives and fillers; i) optionally reinforcements containing natural or syntheti
    Type: Application
    Filed: December 2, 2009
    Publication date: September 29, 2011
    Inventors: Serge Herman, Urbain Coudevylle, Thierry Foussard
  • Patent number: 8017671
    Abstract: The present invention discloses a thermosetting resin for expediting a thermosetting process. The thermosetting resin is composed of 100 parts of primary resin formed by mixing a brominized epoxy resin, a tetrafunctional epoxy resin and an epoxy resin with a high bromine content, and other materials including 35 parts of phenolic resin curing agent, 30 parts of tetrabromobisphenol A curing agent, 0.1 part of 2-ethyl-4-methylimidazole, 0.8 part Lewis acid, and 50˜70 parts of solvent, calculated based on every 100 parts of the primary resin by weight. The invention can expedite a thermosetting process and enhance the Tg of prepregs and clad laminates.
    Type: Grant
    Filed: June 12, 2009
    Date of Patent: September 13, 2011
    Assignees: ITEQ (WUXI) Electronic Technologies Co., Ltd., ITEQ Corporation
    Inventors: Yanhua Yuan, Meixin Ding
  • Patent number: 8003216
    Abstract: A heat-conductive dielectric polymer material having an inter-penetrating-network (IPN) structure includes a polymer component, a curing agent, and a heat-conductive filler uniformly dispersed in the polymer component. The polymer component includes a thermoplastic plastic and a thermosetting epoxy resin. The curing agent is used to cure the thermosetting epoxy resin at a curing temperature. The heat conductivity of the heat-conductive dielectric polymer material is larger than 0.5 W/mK. A heat dissipation substrate including the heat-conductive dielectric polymer material in the present invention has a thickness of less than 0.5 mm and bears a voltage of over 1000 volts.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: August 23, 2011
    Assignee: Polytronics Technology Corporation
    Inventors: David Shau Chew Wang, En Tien Yang, Jyh Ming Yu, Fu Hua Chu
  • Patent number: 7981977
    Abstract: The invention relates to a liquid resin composition for electronic components which is used in sealing of electronic components, comprising a liquid epoxy resin, a curing agent containing a liquid aromatic amine, and an inorganic filler, and further comprising at least one member selected from a hardening accelerator, silicone polymer particles, and a nonionic surfactant. There is thereby provided a liquid resin composition for electronic components, which is excellent in fluidity in narrow gaps, is free of void generation, is excellent in adhesiveness and low-stress characteristic and is excellent in fillet formation, as well as an electronic component device having high reliability (moisture resistance, thermal shock resistance), which is sealed therewith.
    Type: Grant
    Filed: December 8, 2006
    Date of Patent: July 19, 2011
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Kazuyoshi Tendou, Satoru Tsuchida, Shinsuke Hagiwara
  • Patent number: 7968195
    Abstract: The invention provides an adhesive sheet which can be stuck to a wafer at low temperatures of 100° C. or below, which is soft to the extent that it can be handled at room temperature, and which can be cut simultaneously with a wafer under usual cutting conditions; a dicing tape integrated type adhesive sheet formed by lamination of the adhesive sheet and a dicing tape; and a method of producing a semiconductor device using them. In order to achieve this object, the invention is characterized by specifying the breaking strength, breaking elongation, and elastic modulus of the adhesive sheet in particular numerical ranges.
    Type: Grant
    Filed: July 17, 2008
    Date of Patent: June 28, 2011
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Teiichi Inada, Michio Mashino, Michio Uruno
  • Patent number: 7968194
    Abstract: The invention provides an adhesive sheet which can be stuck to a wafer at low temperatures of 100° C. or below, which is soft to the extent that it can be handled at room temperature, and which can be cut simultaneously with a wafer under usual cutting conditions; a dicing tape integrated type adhesive sheet formed by lamination of the adhesive sheet and a dicing tape; and a method of producing a semiconductor device using them. In order to achieve this object, the invention is characterized by specifying the breaking strength, breaking elongation, and elastic modulus of the adhesive sheet in particular numerical ranges.
    Type: Grant
    Filed: July 17, 2008
    Date of Patent: June 28, 2011
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Teiichi Inada, Michio Mashino, Michio Uruno
  • Publication number: 20110111662
    Abstract: This invention concerns a thermosetting resin system that is useful in the manufacture of high performance prepreg, laminate and composite materials as well as, prepregs, laminates and composites made from the thermosetting resin composition.
    Type: Application
    Filed: May 4, 2010
    Publication date: May 12, 2011
    Inventors: Martin Choate, Jyoti Sharma, Steve Peters, Kevin Rafferty
  • Publication number: 20110082239
    Abstract: A thermosetting epoxy composition contains a modified silicon dioxide and is suitable for use in preparing an epoxy laminate having a low coefficient of thermal expansion and good drilling workability, which modified silicon dioxide contains no crystal water, has low expansibility, and contains 40% to 80% by weight of silicon dioxide and 60% to 20% by weight of an inorganic additive, and the modified silicon dioxide is obtained by a high-temperature (above 1000° C.) sintering process followed by a crushing process.
    Type: Application
    Filed: September 29, 2010
    Publication date: April 7, 2011
    Applicant: NAN YA PLASTICS CORPORATION
    Inventor: Ming-Jen TZOU
  • Patent number: 7811475
    Abstract: There is provided a neutron shielding material which has heat resistance and has ensured neutron shielding performance even in a high-temperature environment during storage of a spent nuclear fuel for high burnup. A neutron shielding material having improved heat resistance and ensured neutron shielding performance due to the absence of an amine curing agent is provided by a neutron shielding material composition comprising a polymerization initiator, a polymerization component, a density increasing agent and a boron compound. As the polymerization component of the present invention, an epoxy component and an oxetane component are particularly preferably used.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: October 12, 2010
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventor: Noriya Hayashi
  • Patent number: 7795744
    Abstract: The objective of the present invention is to provides a cationically curable epoxy resin composition excellent in sealing and adhesive property specifically to glass, excellent reflow resistance property, moisture resistance and water resistance while keeping a good workability intrinsic to a light curable resins. The invention provides a cationically curable epoxy resin composition comprising: (a) an epoxy resin component; (b) a cationic photo-initiator; (c) a cationic thermal-initiator and (d) a filler selected from the group consisting of oxides, hydroxides and carbonates containing a Group II element in the long periodic table.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: September 14, 2010
    Assignee: Henkel Corporation
    Inventors: Chunfu Chen, Yoke Ai Gan
  • Patent number: 7781063
    Abstract: The present invention is a continuous high thermal conductivity resin featuring high thermal conductivity (HTC) materials 30 and a host resin matrix 32. The HTC materials 30 form a continuous organic-inorganic composite with the host resin matrix 32 via surface functional groups that are grafted to the HTC materials 30 and form covalent linkages with the host resin matrix 32. Phonons 34 tend to pass along the HTC materials 30 as they travel through the host resin matrix 32, and phonons 36 pass to the next HTC material if the distance between these materials is less than n.
    Type: Grant
    Filed: June 14, 2005
    Date of Patent: August 24, 2010
    Assignee: Siemens Energy, Inc.
    Inventors: James David Blackhall Smith, Gary Stevens, John William Wood
  • Patent number: 7776993
    Abstract: A reworkable thermoset epoxy-containing material that allows for a reworkable assembly such as a reworkable waferlevel underfilled microelectronic package. A method for using the reworkable thermoset material in the formation of a microelectronic package using this material.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: August 17, 2010
    Assignee: International Business Machines Corporation
    Inventors: Stephen Leslie Buchwalter, Claudius Feger, Gareth Hougham, Nancy LaBianca, Hosadurga Shobha
  • Publication number: 20100178358
    Abstract: A polysaccharide-based solid material including, in its mass, at least one active agent having bactericidal, fungal, insecticidal and/or flame-retardant properties, and at least one complexing agent and/or at least one polymeric matrix having a complexing agent. The active agent includes at least one compound selected from the group including boron, silica, aluminum, phosphorus, iodine, derivatives thereof, aluminosilicate derivatives, and mixtures thereof. The solid material is characterized by an improved stability and by reduced environmental impact, and makes it possible to prepare materials based on wood particles and woods having a particular resistance against environmental attacks such as moisture.
    Type: Application
    Filed: March 28, 2007
    Publication date: July 15, 2010
    Inventors: Louis Gastonguay, Michel Perrier, Paul-Étienne Harvey, Jean-Francois Labrecque, Michel Robitaille, André Besner
  • Publication number: 20100168279
    Abstract: This invention is a barrier composition comprising a resin or resin/filler system that is capable of being cured at low temperature while still maintaining superior barrier performance. This composition comprises (a) an aromatic compound having meta-substituted epoxy functionalities; (b) a multifunctional aliphatic amine; (c) optionally, one or more fillers; (d) optionally one or more adhesion promoters; (c) optionally, a phenolic cure accelerator.
    Type: Application
    Filed: March 30, 2006
    Publication date: July 1, 2010
    Inventors: Shengqian Kong, Sarah E. Grieshaber, Donald E. Herr
  • Patent number: 7745516
    Abstract: Water absorption resistant polyimide/epoxy-based compositions, like pastes (or solutions), are particularly useful to make electronic screen-printable materials and electronic components. A group of hydrophobic epoxies (and soluble polyimides) was discovered to be particularly resistant to moisture absorption. The polyimide/epoxy pastes made with these epoxies (and these polyimides) may optionally contain thermal crosslinking agents, adhesion promoting agents, blocked isocyanates, and other inorganic fillers. The polyimide/epoxy pastes of the present invention can have a glass transition temperature greater than 250° C., a water absorption factor of less than 2%, and a positive solubility measurement.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: June 29, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Thomas Eugene Dueber, John D. Summers, Brian C. Auman, Munirpallam Appadorai Subramanian, Nyrissa S. Rogado
  • Patent number: 7713621
    Abstract: This invention concerns a thermosetting resin system that is useful in the manufacture of high performance prepreg, laminate and composite materials as well as, prepregs, laminates and composites made from the thermosetting resin composition.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: May 11, 2010
    Assignee: Isola USA Corp.
    Inventors: Martin Choate, Jyoti Sharma, Steve Peters, Kevin Rafferty
  • Publication number: 20100072662
    Abstract: The present invention relates to a lead-free, non-toxic and arc resistant composite material having a thermosetting polymer, at least one heavy particulate filler, at least one light particulate filler and, optionally, at least one arc resistant filler. The composite material may be utilized in manufacturing articles used in radiation shielding and other applications where arc resistant and dielectric strength are desired.
    Type: Application
    Filed: September 30, 2009
    Publication date: March 25, 2010
    Applicant: GLOBE COMPOSITE SOLUTIONS, LTD.
    Inventor: Xiujun Wang
  • Patent number: 7652079
    Abstract: The present invention provides a polybutylene terephthalate resin composition which has an excellent vibration welding performance, an excellent resistance to heat shock, and is useful for a case, housing and the like of electric/electronic parts. Specifically, it provides a polybutylene terephthalate resin composition for vibration welding comprising (A) 100 parts by weight of a polybutylene terephthalate resin; (B) 20 to 100 parts by weight of a modified polyester copolymer containing 5 to 30% by mole of a comonomer; (C) 5 to 30 parts by weight of an elastomer selected from an acrylic-based copolymer having a glycidyl group and/or an ?-olefin.?,?-unsaturated carboxylic acid (ester).?,?-unsaturated carboxylic acid glycidylester-based ternary polymer; and (D) 60 to 150 parts by weight of a glass fiber.
    Type: Grant
    Filed: December 12, 2005
    Date of Patent: January 26, 2010
    Assignee: Wintech Polymer Ltd.
    Inventors: Katsunori Takayama, Takayuki Ishikawa
  • Patent number: 7585436
    Abstract: The present invention includes polymer films that comprise lanthanum hexaboride and an epoxy agent. The lanthanum hexaboride and epoxy agent can be incorporated into or onto a polymer film in any suitable manner. The addition of an epoxy agent surprisingly provides a stabilization effect to the lanthanum hexaboride, which allows for the production of polymer films that advantageously absorb infrared radiation and resist environmental degradation. Polymer films thus produced have a significant number of applications, for example, but not limited to, display devices, protective coverings, and glazing film applications.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: September 8, 2009
    Assignee: Solutia Incorporated
    Inventors: William Keith Fisher, Bruce Edward Wade, Paul Daniel Garrett
  • Patent number: 7579392
    Abstract: The invention is a formulation that contains: (1) a low-viscosity epoxy resin; (2) a phenolic chain extender whose concentration is less that 0.6 equivalents phenolic hydroxyl group per equivalent of the low-viscosity epoxy resin; (3) a catalyst that promotes self-curing reactions between epoxy groups; (4) an inhibitor that inhibits the activity of the catalyst under “B-staging” conditions; (5) less than 25 weight percent of a volatile organic solvent; and (6) optionally, a multifunctional cross-linking agent. The formulation contains low levels of volatile organic solvent, and can be used to make electrical laminates. It builds molecular weight controllably in B-staging, so that dripping is avoided but the prepreg can be easily laminated.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: August 25, 2009
    Assignee: The Dow Chemical Company
    Inventors: Joseph Gan, Alan R. Goodson
  • Patent number: 7521494
    Abstract: This invention concerns a thermosetting resin system that is useful in the manufacture of high performance prepreg, laminate and composite materials as well as, prepregs, laminates and composites made from the thermosetting resin composition.
    Type: Grant
    Filed: July 20, 2005
    Date of Patent: April 21, 2009
    Assignee: Isola USA Corp.
    Inventors: Martin Choate, Jyoti Sharma, Steve Peters, Kevin Rafferty
  • Patent number: 7446136
    Abstract: A cure system including a compatiblized and passivated refectory solid dispersed within a low temperature liquid curing agent is provided. An adhesive system including the cure system is provided, and an associated method. A device including the cured adhesive system is provided.
    Type: Grant
    Filed: June 23, 2005
    Date of Patent: November 4, 2008
    Assignee: Momentive Performance Materials Inc.
    Inventor: Slawomir Rubinsztajn
  • Patent number: 7405246
    Abstract: A cure system including a compatiblized and passivated refectory solid dispersed within a low temperature liquid curing agent is provided. An adhesive system including the cure system is provided, and an associated method. A device including the cured adhesive system is provided.
    Type: Grant
    Filed: June 23, 2005
    Date of Patent: July 29, 2008
    Assignee: Momentive Performance Materials Inc.
    Inventor: Slawomir Rubinsztajn
  • Patent number: 7381359
    Abstract: An encapsulant is described for an optoelectronic device or optical component, which provides a coefficient of thermal expansion of less than 50 ppm/° C., with a variation of less than ±30%, and further provides an optical transmittance of at least 20% at a wavelength in the range of 400 to 900 nm, at an encapsulant thickness of about 1 mm. The encapsulant includes a filler consisting essentially of glass particles having diameters smaller than 500 ?m, being essentially free of titania and lead oxide, and having a refractive index in the range of 1.48 to 1.60, with a variance of less than about 0.001.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: June 3, 2008
    Assignee: Yazaki Corporation
    Inventors: Yongan Yan, Douglas Meyers, Mark Morris, D. Laurence Meixner, Satyabrata Raychaudhuri
  • Patent number: 7378461
    Abstract: The invention relates to (1) a curable epoxy resin composition comprising (A) a non-gel type amine-modified epoxy resin which is obtained by reacting an epoxy resin with a polyamine and (B) at least one of boric acid and boric ester, (2) a powder form of the curable epoxy resin composition and a process for its production, and (3) a process for production of heat-resistant laminated sheets by using the curable epoxy resin composition. The invention provides (1) a curable epoxy resin composition capable of giving a cured article having a high glass transition temperature and excellent mechanical properties, (2) a powder form of curable epoxy resin composition having a high glass transition temperature, excellent mechanical properties and excellent storage stability and a process for its production, and (3) heat-resistant laminated sheets made by using the curable epoxy resin compositions and having excellent heat resistance and mechanical properties.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: May 27, 2008
    Assignee: Kawamura Institute of Chemical Research
    Inventors: Kazutoshi Haraguchi, Akira Ohbayashi
  • Publication number: 20080076856
    Abstract: A boron nitride composition having its surface treated with a coating layer comprising at least an organosilicon compound. In one embodiment, the boron nitride powder surface is first treated by either a calcination process, or by coating with at least an inorganic compound for the surface to have a plurality of reactive sites containing at least a functional group that is reactive to at least one functional group of the organosilicon compound.
    Type: Application
    Filed: November 9, 2006
    Publication date: March 27, 2008
    Applicant: General Electric Company
    Inventors: Hong Zhong, Eric Thaler
  • Patent number: 7332069
    Abstract: The present invention provides a curable cathodic corrosion protection powder coating, which comprises a thermosetting resin, a zinc borate compound, a curing agent in an amount effective to cure the coating. Further, the present invention also provides a method of cathode corrosion protection which includes the steps of subjecting the substrate to a mechanical treatment, applying to said treated steel surface, the cathodic protective coating, and polarizing the coated material as a cathode.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: February 19, 2008
    Assignee: E.I. du Pont de Nemours & Co.
    Inventor: Stephen J. Edmondson
  • Patent number: 7323234
    Abstract: The present invention provides a curable alkanolamine containing epoxy powder coating composition comprising at least one epoxy resin, at least one alkanolamine, a curing agent in an amount effective to cure the coating and optionally at least one zinc borate compound. Further, the present invention provides a method of cathode corrosion protection which includes the steps of subjecting a metal substrate to a mechanical treatment, applying the curable alkanolamine containing epoxy powder coating composition to the surface of the metal substrate, and polarizing the coated material as a cathode. The present invention also relates to a process for making and applying the alkanolamine containing epoxy powder coating compositions of the present invention.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: January 29, 2008
    Assignee: E.I. du Pont de Nemours & Company
    Inventors: Stephen J. Edmondson, Edward John Marx
  • Patent number: 7311972
    Abstract: An encapsulant is described for an optoelectronic device or optical component, which provides a coefficient of thermal expansion of less than 50 ppm/° C., with a variation of less than ±30%, and further provides an optical transmittance of at least 20% at a wavelength in the range of 400 to 900 nm, at an encapsulant thickness of about 1 mm. The encapsulant includes a filler consisting essentially of glass particles having diameters smaller than 500 ?m, being essentially free of titania and lead oxide, and having a refractive index in the range of 1.48 to 1.60, with a variance of less than about 0.001.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: December 25, 2007
    Assignee: Yazaki Corporation
    Inventors: Yongan Yan, Douglas Meyers, Mark Morris, D. Laurence Meixner, Satyabrata Raychaudhuri
  • Patent number: 7304102
    Abstract: An encapsulant for use with opto-electronic devices and optical components incorporates a filler made from a glass that has been processed into particle form and heated to a predetermined temperature for a predetermined time, along with an epoxy having an index of refraction matched to that of the glass and heated to a predetermined temperature for a predetermined time, to prevent settling of the filler particles after mixing the filler particles with the epoxy, and thereby obtaining uniform dispersion of the particles within the epoxy. The encapsulant provides for high light transmittance, and its coefficient of thermal expansion can be varied by varying the amount of filler without substantially altering the optical properties of the encapsulant. The coefficient of thermal expansion variation within the encapsulant preferably is less than 30%, due to uniform dispersion of the filler particles within the epoxy.
    Type: Grant
    Filed: December 7, 2004
    Date of Patent: December 4, 2007
    Assignee: Yazaki Corporation
    Inventors: Yongan Yan, Douglas Evan Meyers, Mark Allen Morris, D. Laurence Meixner, Satyabrata Raychaudhuri
  • Patent number: 7294660
    Abstract: An epoxy resin composition which comprises 100 parts by weight of an epoxy resin and 1 to 800 parts by weight of an aluminum borate whisker having an average fiber diameter of 0.25 ?m or less. The epoxy resin composition contains a large amount of the aluminum borate whisker being dispersed uniformly therein, is excellent in mechanical strength, and is suppressed with respect to the anisotropy of a mechanical property due to the direction of application.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: November 13, 2007
    Assignee: Asahi Denka Co., Ltd.
    Inventors: Seiichi Saito, Yoshihiro Fukuda, Takahiro Mori, Yoshinori Takahata
  • Patent number: 7183346
    Abstract: The present invention provides a curable cathodic corrosion protection powder coating, which comprises a thermosetting resin, a zinc borate compound, a curing agent in an amount effective to cure the coating. Further, the present invention also provides a method of cathode corrosion protection which includes the steps of subjecting the substrate to a mechanical treatment, applying to said treated steel surface, the cathodic protective coating, and polarizing the coated material as a cathode.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: February 27, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Stephen J. Edmondson
  • Patent number: 7169474
    Abstract: An epoxy resin composition comprising (A) an epoxy resin, (B) a phenolic resin, (C) a curing accelerator, and (D) an effective flux component selected from among abietic acid, palustric acid, levopimaric acid and dihydroabietic acid is low volatile and exhibits improved wetting and adherent properties to solder balls. The epoxy resin composition is used to cover and encapsulate a semiconductor chip, especially as no-flow underfill material, forming a highly reliable semiconductor device.
    Type: Grant
    Filed: February 5, 2004
    Date of Patent: January 30, 2007
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Tsuyoshi Honda
  • Patent number: 7169833
    Abstract: A liquid epoxy resin composition comprising (A) a liquid epoxy resin, (B) an aromatic amine curing agent comprising 5–100% by weight of a specific aromatic amine compound having a purity of at least 99%, (C) an inorganic filler, and (D) an ester organic solvent having a boiling point of 130–250° C. is useful for semiconductor encapsulation. The composition has an infiltration ability, adhesion to silicon chips, resistance to deterioration under hot humid conditions, and resistance to thermal shocks.
    Type: Grant
    Filed: March 25, 2004
    Date of Patent: January 30, 2007
    Assignee: Shin-Estu Chemical Co., Ltd.
    Inventors: Kazuaki Sumita, Kaoru Katoh, Tokue Kojima, Toshio Shiobara
  • Patent number: 7105614
    Abstract: A curable epoxy resin composition comprising at least: (A) a crystalline epoxy resin, (B) a phenol resin, and (C) a silicone resin composed of epoxy-containing organic groups and phenyl groups that define an average unit formula of this component. Component (C) is used in an amount of 0.1 to 500 parts by weight for 100 parts by weight of the sum of weights of components (A) and (B). The composition of the invention is suitable for transfer and injection molding and may find use as a curable epoxy resin composition for sealing parts of electrical and electronic devices.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: September 12, 2006
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yoshitsugu Morita, Hiroshi Ueki, Koji Nakanishi, Haruhiko Furukawa
  • Patent number: 7094844
    Abstract: A liquid epoxy resin composition comprising a liquid epoxy resin, an aromatic amine curing agent having a phenolic hydroxyl group in a skeleton, an inorganic filler, and a cure accelerator is useful for semiconductor encapsulation. The composition is adherent to the surface of silicon chips, does not deteriorate under hot humid conditions, and is fully resistant to thermal shocks.
    Type: Grant
    Filed: September 11, 2003
    Date of Patent: August 22, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kazuaki Sumita, Shingo Ando, Toshio Shiobara
  • Patent number: 7084194
    Abstract: A halogen-free resin composition is provided, comprising: (A) one or more phosphorous-containing epoxy resins; (B) a hardener; and (C) a hardening accelerator, wherein the hardener of component (B) has the structure represented by the following formula (I): wherein, each symbol is defined as in the specification. The halogen-free resin composition of the present invention has excellent thermal resistance and flame retardant property, and is thereby suitably useful in the application of adhesives, composite materials, laminated plates, printed circuit boards, copper foil adhesives, inks used for build-up process, semiconductor packaging materials, and the like.
    Type: Grant
    Filed: August 4, 2003
    Date of Patent: August 1, 2006
    Assignee: Chang Chun Plastics Co., Ltd.
    Inventors: Kuen-Yuan Hwang, An-Pang Tu, Chi-Yi Ju, Wen-Tsai Tsai
  • Patent number: 7064157
    Abstract: The present invention relates to a phosphorus-containing epoxy resin, which is an epoxy resin modified with a side chain having a reactive phosphorus-containing compound. Also, the present invention relates to a flame-retardant resin composition, which comprises: (1) the phosphorus-containing epoxy resin, (2) a halogen-free hardener having a reactive hydrogen capable of reacting with the epoxy group in epoxy resin, and (3) a hardener promoter. The flame-retardant resin composition described above has improved excellent heat resistance and flame retardant property, and is especially suitable for adhesive laminates, composite materials, printed circuit boards, adhesive material for copper foils, and is suitable for IC packaging materials.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: June 20, 2006
    Assignee: Chang Chun Plastics Co., Ltd.
    Inventors: Kuen Yuan Hwang, Hong-Hsing Chen, An Pang Tu, Huan-Chang Chao
  • Patent number: 7008983
    Abstract: Polymer compositions comprising polyester, boron component, and epoxy component. Articles made from these compositions, particularly articles requiring excellent hydrolysis resistance properties.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: March 7, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: William E. Garrison, James Michael McKenna
  • Patent number: 6974846
    Abstract: Polymer compositions comprising polyester, boron component, and epoxy component. Articles made from these compositions, particularly articles requiring excellent hydrolysis resistance properties.
    Type: Grant
    Filed: May 3, 2005
    Date of Patent: December 13, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: William E. Garrison, James Michael McKenna
  • Patent number: 6936664
    Abstract: The present invention discloses reworkable epoxy compositions suitable for encapsulation of and underfill for electronic components comprising (a) a curable epoxy component which is the reaction product of an epoxidized 1-alkenyl ether or 1-cycloalkenyl ether and a polycarboxylic acid, the reaction product being substantially free of unreacted acid or acid impurities; and (b) a curing agent for the epoxy component, wherein the reaction products of the epoxy composition are reworkable. The cured epoxy compositions of this invention contain thermally labile weak ?-alkoxy ester linkages which provide for the reworkable aspect of the invention.
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: August 30, 2005
    Assignee: Henkel Corporation
    Inventors: John G. Woods, Susanne D. Morrill, Jianzhao Wang, Brendan J. Kneafsey
  • Patent number: 6919420
    Abstract: Reworkable thermoset acid-cleavable acetal and ketal based epoxy oligomers can be B-staged into a tack free state. Compositions containing the epoxy oligomers are employed in a reworkable assembly such as a wafer-level underfilled microelectronic package.
    Type: Grant
    Filed: December 5, 2002
    Date of Patent: July 19, 2005
    Assignee: International Business Machines Corporation
    Inventors: Stephen Leslie Buchwalter, Claudius Feger, Gareth Hougham, Nancy LaBianca, Hosadurga Shobha
  • Patent number: 6830815
    Abstract: The present invention relates to an anti-friction and anti-wear liquid coating composition for use with parts made of materials that have softening points below about 300° F. and articles so coated. The present invention also relates to a method of coating parts made from a low softening point materials with an anti-friction and anti-wear hard coating composition. The coating composition comprises a mixture of (i) solid lubricants comprising boron nitride, graphite and molybdenum disulfide, (ii) a thermoset resin system, (iii) catalyst for curing the resin system and (iv) a solvent system comprising highly volatile solvents. The coating composition is applied to the part and cured to form a coating on the part.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: December 14, 2004
    Assignee: Ford Motor Company
    Inventor: V. Durga Nageswar Rao
  • Patent number: 6797972
    Abstract: A high-polymer neutron shielding material which scarcely reduces the hydrogen number density when exposed to a high temperature of 150 to 200° C. for a long time period A heat-setting type epoxy resin is employed. The base resin is selected from various epoxy resins such as bisphenol A type epoxy resin. The hardener is selected from alicyclic polyamine, polyamide amine, aromatic polyamine, acid anhydride, and so on. These materials are mixed and hardened at a temperature higher than the room temperature. To give a flame resistance to the hardened resin, a fire retardant such as magnesium hydroxide is added to the mixture. To improve the neutron shielding performance of the hardened resin, a neutron absorbing material is added to the mixture. Further, to increase the moderating performance, hydrogenated bisphenol A epoxy resin is used as the base resin or metal hydride or hydrogen absorbing alloy is added.
    Type: Grant
    Filed: September 6, 2002
    Date of Patent: September 28, 2004
    Assignee: Hitachi, Ltd.
    Inventors: Mamoru Kamoshida, Masashi Oda, Takashi Nishi, Kiminori Iga, Masashi Shimizu
  • Patent number: 5150841
    Abstract: A battery operated hand-held dispenser which operates efficiently at lower power levels than prior art devices. The dispenser as included therein has spray, foam or stream, dispensing capabilities coupled with pump mechanisms, vent mechanisms and positive closures.
    Type: Grant
    Filed: May 23, 1991
    Date of Patent: September 29, 1992
    Assignee: DowBrands Inc.
    Inventors: Scott A. Silvenis, Paul B. Monaghan, Arthur A. Massucco, Richard H. Spencer, William R. Gagne