Oxygen Ring Atom Patents (Class 524/117)
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Publication number: 20100216922Abstract: A non-halogen flameproof polycarbonate resin composition is disclosed. The polycarbonate resin composition includes a base resin including (A) about 50 to about 100% by weight of a polycarbonate resin, (B) about 0 to about 50% by weight of a rubber modified aromatic vinyl resin, and (C) about 0 to about 50% by weight of an alkyl(meth)acrylate resin; and (D) about 0.5 to about 30 parts by weight of a cyclic t-butyl phosphonate compound, based on about 100 parts by weight of the base resin comprising (A), (B) and (C). The polycarbonate resin composition can have stability against fire and can be environmentally friendly since it does not contain a halogen flame retardant.Type: ApplicationFiled: May 10, 2010Publication date: August 26, 2010Applicant: CHEIL INDUSTRIES INC.Inventors: Min Soo LEE, Beom Jun JOO, Sang Hyun HONG, Byun Kun LEE
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Patent number: 7776945Abstract: Disclosed herein is a Polyester Fiber Having Excellent Light-Shielding and Flame Retardant Characteristic. The Polyester Fiber comprises: phosphorus-based flame retardant 0.05˜5% by weight, based on phosphorus atom; and inorganic particles having 0.05˜1 ?m average particle size 1-5% by weight, based on fiber weight. Further disclosed is Textile Goods prepared from the Polyester Fiber. The polyester fiber according to the present invention is prepared from polyester polymer having Intrinsic viscosity of 0.55˜0.75 dl/g and the Intrinsic viscosity difference of between the fiber and polymer (IV drop) is within 0.03 dl/g and it exhibits the excellent flame retardant and light shielding characteristic. Therefore, the polyester fiber can be applied to fiber for clothes, light shielding curtain for a car and blackout curtain for a house and theater.Type: GrantFiled: April 8, 2005Date of Patent: August 17, 2010Assignee: Hyosung CorporationInventors: Seung Cheol Yang, Eung Soo Kim, Yang Kuk Son
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Publication number: 20100204354Abstract: Disclosed are new compositions consisting of polyphosphonates and specific additive compositions that exhibit superior resistance to degradation due to exposure to air, high temperature and air, moisture or combinations thereof. Also disclosed are polymer mixtures or blends comprising these polyphosphonates/additive compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.Type: ApplicationFiled: February 3, 2010Publication date: August 12, 2010Applicant: FRX Polymers, Inc.Inventors: Dieter Freitag, Pin Go, Gad Stahl
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Publication number: 20100204374Abstract: Provided is a nucleating agent masterbatch for polyolefin resin excellent in dispersibility into a polyolefin resin, which nucleating agent masterbatch is capable of improving transparency and mechanical strength of the polyolefin resin, which is a crystalline polymer, which nucleating agent masterbatch is further excellent in resistance to heat coloring; and a polyolefin resin composition using the masterbatch. Specifically, provided is a nucleating agent masterbatch for polyolefin resin, wherein, based on 100 parts by mass of a fully hydrogenated petroleum resin (A) having a softening point of not lower than 100° C.Type: ApplicationFiled: August 20, 2008Publication date: August 12, 2010Inventors: Naoko Tanji, Tomonori Shimizu, Mitsuru Fukushima
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Patent number: 7772303Abstract: Disclosed herein is a flame retardant thermoplastic resin composition having excellent weatherability comprising (A) about 100 parts by weight of a rubber modified aromatic vinyl resin comprising (a1) about 15 to about 100% by weight of a grafted copolymer resin prepared by graft-polymerizing about 5 to 65% by weight of a rubbery polymer, about 10 to 95% by weight of an aromatic vinyl monomer and about 0 to 40% by weight of a monomer copolymerizable with said aromatic vinyl monomer; and (a2) about 0 to 85% by weight of a copolymer resin prepared by polymerizing about 40 to 90% by weight of an aromatic vinyl monomer and about 10 to 60% by weight of a monomer copolymerizable with said aromatic vinyl monomer; (B) about 0.1 to about 10 parts by weight of a ring-shaped alkyl phosphonate ester compound; and (C) about 0.05 to about 3 parts by weight of a HALS compound.Type: GrantFiled: December 11, 2007Date of Patent: August 10, 2010Assignee: Cheil Industries Inc.Inventors: Sang Hyun Hong, Seon Ae Lee, Min Soo Lee, Jin Hwan Choi
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Publication number: 20100184884Abstract: There is provided a resin composition that comprises a polycarbonate resin derived from an ether diol such as isosorbide and that is excellent in flame retardancy, heat resistance, thermal stability, rigidity, transparency and moldability. The resin composition is a flame-retardant resin composition comprising 1 to 60 parts by weight of phosphorus compound (component B) having a thermal decomposition temperature of not higher than 340° C. based on 100 parts by weight of polycarbonate resin (component A) that mainly comprises a recurring unit represented by the following formula (1).Type: ApplicationFiled: May 28, 2008Publication date: July 22, 2010Applicant: TEIJIN LIMITEDInventors: Toshiyuki Miyake, Masami Kinoshita, Mizuho Saito, Katsuhiko Hironaka
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Patent number: 7759417Abstract: Stabilizer compositions comprise phosphate of the formula (I) or (II), a phosphite of the formula (III), and a phenol of the formula (IV) as these formulas are defined herein. The stabilizer compositions are useful for stabilizing polymers. Methods for making stabilized polymer compositions involve intermixing the stabilizer compositions and the polymers, e.g., by extruding, pelletizing, and/or molding.Type: GrantFiled: May 10, 2007Date of Patent: July 20, 2010Assignee: Cytec Technology Corp.Inventors: John Mathew Zenner, Brent Sanders
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Patent number: 7754792Abstract: It is an object of the present invention to provide a polyester based artificial hair which has excellent setting properties, feeling and transparency and further has excellent flame-retardancy and controlled gloss of fiber surface while maintaining fiber properties possessed by a conventional polyester fiber such as heat resistance, strength and elongation and the like.Type: GrantFiled: April 8, 2005Date of Patent: July 13, 2010Assignee: Kaneka CorporationInventor: Toshiyuki Masuda
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Publication number: 20100152343Abstract: A rotation molded body obtained by rotation molding of a polyolefin composition comprising a polyolefin and a phosphite of the formula (I).Type: ApplicationFiled: December 9, 2009Publication date: June 17, 2010Inventors: Yoshikazu KIMURA, Ryoji Soma, Natsuko Sato
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Publication number: 20100137465Abstract: Certain cyclic phosphate ester compounds useful, inter alia, as halogen-free flame-retardant compounds, are disclosed. The compounds are particularly useful for providing flame retarded polyurethane foams.Type: ApplicationFiled: January 4, 2008Publication date: June 3, 2010Inventors: Jeffrey Stowell, Weihong Liu
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Patent number: 7714046Abstract: The present invention provides a process for producing a crystal nucleator composition comprising; a first step pulverizing 95% by mass or more of a crystal nucleator ingredient containing one or two or more kinds of specific compounds to a primary particle diameter of 0.8 ?m or smaller with a dry medium-stirring type pulverizer; and a second step mixing and pulverizing the pulverized crystal nucleator ingredient obtained in the previous step and a metal aliphatic carboxylate ingredient containing one or two or more kinds of specific metal aliphatic carboxylates.Type: GrantFiled: August 24, 2006Date of Patent: May 11, 2010Assignee: Adeka CorporationInventors: Manabu Ishii, Naoshi Kawamoto, Etsuo Tobita
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Publication number: 20100113637Abstract: The present subject matter relates generally to polymer compositions, and more particularly to irradiated polymer compositions comprising at least one non-phenolic stabilizer. The present polymer compositions comprise an unexpected balance of properties after being subjected to irradiation treatments, including an unexpected combination of a lower melt flow rate ratio (MFRr) and high melt tension after being irradiated, while minimizing negative yellowing effects.Type: ApplicationFiled: June 27, 2008Publication date: May 6, 2010Applicant: Basell Poliolefine Italia s.r.l,Inventors: Jeffrey D. Abata, Ronald F. Becker, Vu A. Dang, Anthony J. De Nicola, JR., Theodore Dziemianowicz
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Publication number: 20100093899Abstract: The invention provides a resin additive master batch which can contain a resin additive having a melting point of not higher than 80° C. to a high concentration, with which breakage of a strand does not occur and continuous production can be attained, and with which the surface tackiness of pellets is improved. The resin additive master batch comprises 80 to 150 parts by weight of (B) resin additive having a melting point of not higher than 80° C., and 0.3 to 5 parts by weight of (C) organic acid metal salt, with respect to 100 parts by weight of (A) polyolefin resin. As the (B) resin additive having a melting point of not higher than 80° C., a UV absorber, a hindered amine compound or a mixture thereof is preferred.Type: ApplicationFiled: January 30, 2008Publication date: April 15, 2010Applicant: ADEKA CORPORATIONInventors: Hitoshi Saitou, Mitsuru Fukushima
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Patent number: 7683112Abstract: There is provided a phosphite composition comprising 100 parts by weight of a phosphite represented by the formula (1) and 0.5 to 8 parts by weight of an aliphatic hydrocarbon lubricant having a softening point or a melting point of not higher than 115° C., wherein the content of the phosphite (1) in said composition is 30 to 99.5% by weight.Type: GrantFiled: November 9, 2007Date of Patent: March 23, 2010Assignee: Sumitomo Chemical Company, LimitedInventors: Kenji Kimura, Kunihito Miyake, Hideo Narahara
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Publication number: 20100059263Abstract: The invention provides a resin composition which develops excellent flame retardance after curing in spite of its being free from halogen-containing compounds and antimony compounds, which are liable to cause environmental load, and which can give a film meeting the recent sever demands for higher flexing resistance and insulation reliability. Specifically, the invention provides a resin composition which comprises (A) a polyimide precursor and (B) an adduct of an organophosphorus compound represented by formula (1) with a compound having four or more (meth)acrylate groups. It is preferable that the resin composition further contain (C) a phosphazene compound.Type: ApplicationFiled: April 30, 2008Publication date: March 11, 2010Applicant: Mitsui Chemicals, Inc.Inventors: Katsuhiko Funaki, Etsuo Ohkawado, Kousuke Hirota, Syuji Tahara
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Patent number: 7671143Abstract: Disclosed herein is a flame retardant polycarbonate resin composition having high heat resistance and good impact resistance. The flame retardant polycarbonate composition is prepared by incorporating into a polycarbonate resin a silicon-based core-shell graft copolymer, in which a vinyl monomer is graft polymerized onto a rubber comprising about 20 to about 95% by weight of silicon, and optionally a phosphoric acid ester compound. The present invention can accordingly provide superior flame retardance while maintaining good impact resistance, high flowability and high heat resistance.Type: GrantFiled: February 23, 2007Date of Patent: March 2, 2010Assignee: Cheil Industries Inc.Inventors: Bong Jae Lee, Kyoung Tae Kim, Sung Sig Min
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Publication number: 20100016196Abstract: A substituted phosphite suitable for lubricating base stocks and thermoplastic polymers represented by the structure: wherein R1 is selected from the group consisting of C1-C22 alkyl and C4-C22 cycloalkyl; R2 and R3 are selected to form a C5-C18 aryl; and R4 and R5 are selected from the group consisting of H, C1-C22 alkyl, C2-C22 alkenyl, C4-C22 cycloalkyl, and C5-C8 aryl. The substituted phosphite may be combined with at least one primary antioxidant as well as other additives.Type: ApplicationFiled: June 27, 2008Publication date: January 21, 2010Inventors: Michael E. Gelbin, Jun Dong
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Publication number: 20100004362Abstract: An object of the present invention is to provide a fiber made of polylactic acid and having excellent strength, heat resistance and heat shrinkage resistance and a manufacturing method thereof. The present invention relates to the fiber is made of a composition which comprises (i) poly(L-lactic acid) having a weight average molecular weight of 50,000 to 300,000 (component A), (ii) poly(D-lactic acid) having a weight average molecular weight of 50,000 to 300,000 (component B) and (iii) 0.01 to 5 parts by weight of a phosphate metal salt (component C) based on 100 parts by weight of the total of the components A and B and has a strength of 2.5 to 10 cN/dTex and a manufacturing method thereof.Type: ApplicationFiled: September 3, 2007Publication date: January 7, 2010Applicants: TEIJIN LIMITED, MUSASHINO CHEMICAL LABORATORY , LTD.Inventors: Midori Ikegame, Takaaki Matsuda, Shin To
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Patent number: 7635732Abstract: A process for producing a thermoplastic resin composition, comprising melting-kneading a thermoplastic resin and a neutralizing agent, and melting-kneading the melting-kneaded product obtained in a first step and a compound (I): wherein two R1s, two R2s, R4 and R5 each represent independently a hydrogen atom, an alkyl group etc.; two R3s each represent independently a hydrogen atom or an alkyl group; X represents a single bond, a sulfur atom or a —CHR6— group, wherein R6 represents a hydrogen atom, an alkyl group etc.; A represents an alkylene group or a *—COR7— group, wherein R7 represents a single bond or an alkylene group, and a symbol * represents a bond with an oxygen atom of a >P—O— portion; one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other of Y and Z represents a hydrogen atom, or an alkyl group.Type: GrantFiled: April 2, 2008Date of Patent: December 22, 2009Assignee: Sumitomo Chemical Company, LimitedInventors: Kenji Kimura, Ryoji Soma
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Publication number: 20090280310Abstract: A melt-extrusion film formed by melt-extruding a resin composition containing (A) a specific amorphous polyolefin typified by an ethylene/norbornene copolymer and (B) a specific phosphite ester or aliphatic ester, wherein the number of gels having a size of 20 ?m or larger and existing in the film is 100 pieces/g or less.Type: ApplicationFiled: September 29, 2006Publication date: November 12, 2009Inventors: Hideaki Nitta, Masahiro Murakami, Hironobu Katoh, Kinji Hasegawa
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Publication number: 20090253837Abstract: The present invention provides a flame retardant polyester resin composition that is free from halogen and can have a high level of initial flame retardancy and maintain flammability even after a long-term heat aging test. By allowing an organophosphorous flame retardant (B) represented by the general formula (1) below: (where n=2 to 20) and a nitrogen compound (C) to be contained at a specific ratio with respect to a thermoplastic polyester resin (A), it is possible to obtain a flame retardant polyester resin composition that can have a high level of initial flame retardancy and maintain flammability even after a long-term heat aging test.Type: ApplicationFiled: March 30, 2006Publication date: October 8, 2009Applicant: Kaneka CorporationInventors: Kazuyuki Takagi, Noriyuki Suzuki
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Publication number: 20090247675Abstract: A thermoplastic polymer composition having excellent resistance to heat discoloration has been desired. There is provided a thermoplastic polymer composition characterized by comprising a thermoplastic polymer, phosphites represented by the formula (I), and at least one kind of erythritols selected from the group consisting of pentaerythritol, dipentaerythritol and tripentaerythritol: wherein R1, R2, R4 and R5 each independently denotes a hydrogen atom, an alkyl group or the like, and R3 denotes a hydrogen atom or an alkyl group; X denotes a single bond, a sulfur atom or a —CHR6 group (R6 denotes a hydrogen atom, an alkyl group or a cycloalkyl group); A denotes an alkylene group or a *—COR7 group (R7 denotes a single bond or an alkylene group, and * denotes a bonding hand on the side of oxygen), and one of Y and Z denotes a hydroxyl group or the like, and the other one of Y and Z denotes a hydrogen atom or an alkyl group).Type: ApplicationFiled: March 31, 2009Publication date: October 1, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Ryoji SOMA, Naoki INUI
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Publication number: 20090170987Abstract: An object of the present invention is to provide a process for producing a thermoplastic resin composition with a further improved hue, containing a neutralizing agent, and a compound (I). There is provided a process for producing a thermoplastic resin composition, comprising a second step of melting-kneading a melting-kneaded product obtained in a first step, and a compound (I). (wherein two R1s, two R2s, R4 and R5 each represent independently a hydrogen atom, an alkyl group etc., two R3s each represent independently a hydrogen atom or an alkyl group, X represents a single bond, a sulfur atom or a —CHR6— group, wherein R6 represents a hydrogen atom, an alkyl group etc., A represents an alkylene group or a *—COR7— group, wherein R7 represents a single bond or an alkylene group, and a symbol * represents a bond with an oxygen atom of a >P—O— portion, one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other of Y and Z represents a hydrogen atom, or an alkyl group.Type: ApplicationFiled: April 2, 2008Publication date: July 2, 2009Inventors: Kenji Kimura, Ryoji Soma
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Publication number: 20090088503Abstract: The present invention is intended to provide a non-halogen flame-retardant polyester resin composition that has a high level of low warping properties and is capable of providing a molded product free from sticky residue in which the bleed-out of the flame retardant is suppressed even when the molded product is exposed to a high temperature environment. The flame-retardant polyester resin composition, having a high level of low warping properties and capable of providing a molded product free from sticky residue in which the bleed-out of the flame retardant is suppressed even when the molded product is exposed to a high temperature environment, can be obtained by incorporating an organic phosphorus-based flame retardant represented by the following general formula (1) and an amorphous resin at a specific ratio relative to a thermoplastic polyester resin. where n is an integer from 2 to 15.Type: ApplicationFiled: September 25, 2006Publication date: April 2, 2009Applicant: KANEKA CORPORATIONInventors: Kazuyuki Takagi, Noriyuki Suzuki
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Publication number: 20090062436Abstract: The invention relates to flame retardant compositions, wherein at least one salt of an aromatic phosphoric acid ester is present in a polycarbonate substrate. The compositions attain the desirable V-0 rating, according to UL-94 (Underwriter's Laboratories Subject 94) and other excellent ratings in related test methods while preserving the excellent mechanical, chemical and thermal properties of polycarbonates, such as light transparency.Type: ApplicationFiled: February 12, 2007Publication date: March 5, 2009Inventor: Christine Breiner
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Patent number: 7497970Abstract: The chiral agent used for liquid crystal according to the present invention comprises a phosphoric acid amide represented by General Formula (1) below: in General Formula (1), the binaphthyl structure has an axial asymmetry of either (R) or (S); R1 and R2 may be identical or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkenyl group, an alkynyl group or an alkoxy group; R3 and R4 may be identical or different and each represents a hydrogen atom, an alkyl group or an aryl group.Type: GrantFiled: March 30, 2007Date of Patent: March 3, 2009Assignee: FUJIFILM CorporationInventor: Masatoshi Yumoto
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Patent number: 7495035Abstract: It is an object of the present invention to provide a photo-curable resin composition which provides a sealing agent for a flat panel display with good moisture permeation resistance and excellent adhesion. The present inventors have conducted extensive studies to solve the above-described problems, and as a result, they have found a photo-curable resin composition which comprises a cationic photopolymerization initiator (A), a cationically polymerizable compound (B), a cyclic polyether compound (C) and another organic compound (D), wherein the amount of (B) is 1.0 to 99.9% by mass and the amount of (C) is 0.0 to 10.0% by mass, both based on the sum of (B), (C) and (D), and the sum (F) of the fluorine atoms in a fluorine-containing organic compound is 0.0 to 40.0% by mass, based on the sum of (B), (C) and (D), and wherein at least 1/1000 mass ratio of the (B) component is a compound containing an oxetanyl group, and both of the contents of (C) and (F) are not 0.0% by mass at the same time.Type: GrantFiled: August 10, 2004Date of Patent: February 24, 2009Assignee: Mitsui Chemicals, Inc.Inventors: Yugo Yamamoto, Yasushi Mizuta, Yuichi Ito
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Publication number: 20090048377Abstract: Disclosed is a flame-retardant resin processed article having excellent flame retardance while being free from bleed-out. Specifically, a resin composition containing a cyclic phosphorus compound flame retardant, a hydrophilic silica powder having an average particle diameter of not more than 15 m, and a resin with the total content of the cyclic phosphorus compound and the hydrophilic silica powder being 10-45% by mass is molded into a certain shape or formed into a coating film. The hydrophilic silica powder is preferably composed of porous structures having a pore volume of not more than 1.8 ml/g and a pH of 4-7. More preferably, the hydrophilic silica powder has an oil absorption of not less than 50 ml/100 g in accordance with JIS K5101.Type: ApplicationFiled: May 10, 2006Publication date: February 19, 2009Applicants: Fuji Electric Holdings Co., Ltd., Nat Univ. Corp. Tokyo Univ of Agriculture and TechInventors: Toshiyuki Kanno, Yoshinobu Sugata, Hironori Yanase, Kiyotaka Shigehara
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Publication number: 20090043022Abstract: Disclosed herein is a Polyester Fiber Having Excellent Light-Shielding and Flame Retardant Characteristic. The Polyester Fiber comprises: phosphorus-based flame retardant 0.05˜5% by weight, based on phosphorus atom; and inorganic particles having 0.05˜1 ?m average particle size 1-5% by weight, based on fiber weight. Further disclosed is Textile Goods prepared from the Polyester Fiber. The polyester fiber according to the present invention is prepared from polyester polymer having Intrinsic viscosity of 0.55˜0.75 dl/g and the Intrinsic viscosity difference of between the fiber and polymer (IV drop) is within 0.03 dl/g and it exhibits the excellent flame retardant and light shielding characteristic. Therefore, the polyester fiber can be applied to fiber for clothes, light shielding curtain for a car and blackout curtain for a house and theater.Type: ApplicationFiled: April 8, 2005Publication date: February 12, 2009Applicant: Hyosung CorporationInventors: Seung Cheol Yang, Eung Soo Kim, Yang Kuk Son
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Publication number: 20080300349Abstract: To easily obtain a polyester having excellent mechanical properties, a satisfactory hue, and a high degree of flame retardancy. [MEANS FOR SOLVING PROBLEMS] The flame-retardant polyester is a polyester comprising ethylene terephthalate units as the main structural units and a phosphorus compound copolymerized or incorporated therein or is a resin composition comprising polyesters including that polyester. The flame-retardant polyester is characterized in that a polycarboxylic acid and/or polyol having three or more functional groups capable of forming an ester bond is contained in the polyester in a total amount of 0.05-2.Type: ApplicationFiled: November 22, 2005Publication date: December 4, 2008Applicant: Toyo Boseki Kabushiki KaishaInventors: Masaki Fuchikami, Shoji Koketsu, Tetsumori Atsuchi, Maki Sato
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Patent number: 7439287Abstract: The present invention relates to a flame retardant thermoplastic resin composition that contains a phenol resin derivative having good char formability, regardless of the base resin. A flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of a phenol resin derivative, and (C) about 0.1˜50 parts by weight of a phosphorous compound or a mixture of phosphorous compounds.Type: GrantFiled: November 16, 2006Date of Patent: October 21, 2008Assignee: Cheil Industries Inc.Inventors: Jae Ho Yang, Sang Hyun Hong, Gyu Chul Lee, Young Gil Jang, Su Hak Bae
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Patent number: 7435769Abstract: A flame-retardant synthetic resin composition characterized by comprising 1-40 parts by weight of at least one type of organic phosphorus compound represented by the following general formula (1): (wherein R1 represents alkyl, aralkyl, etc.) with respect to 100 parts by weight of a synthetic resin.Type: GrantFiled: March 24, 2004Date of Patent: October 14, 2008Assignees: Sanko Co., Ltd., Nicca Chemical Co., Ltd.Inventors: Daishiro Kishimoto, Toru Makino, Katsuya Okumura, Juji Uchida
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Patent number: 7411013Abstract: A flame-retardant resin composition comprises a base resin (A), an organic phosphorus compound (B) having a unit represented by the following formula (1a), and a flame-retardant auxiliary (C). Wherein Ar represents an aromatic hydrocarbon ring or a nitrogen-containing aromatic heterocycle; X1 represents an oxygen atom or a sulfur atom; Y1 and Y2 are the same or different and each represents a hydrocarbon group, an alkoxy group, an aryloxy group, or an aralkyloxy group; Z1 represents an alkylene group, or a nitrogen-containing bivalent group corresponding to an alkylamine; Y1 and Y2 may bind to each other, and Y1 and Y2 together with the adjacent phosphorus atom may form a ring; “a” denotes 0 or 1; and “b” denotes an integer of 1 to 6.Type: GrantFiled: December 24, 2003Date of Patent: August 12, 2008Assignee: Polyplastics Co., Ltd.Inventors: Hatsuhiko Harashina, Shinya Yamada
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Patent number: 7407997Abstract: A vinyl chloride polymer composition that contains a mixture of an alkylene-bridged bisphosphate composition, as a fire retardant, and a polyester plasticizer, which is the reaction product of an aliphatic diol and a dicarboxylic acid.Type: GrantFiled: November 2, 2005Date of Patent: August 5, 2008Assignee: Supresta LLCInventors: Paul Y. Moy, Lambertus A. DeKleine
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Patent number: 7405252Abstract: A vinyl chloride resin composition comprising 100 parts by mass of a vinyl chloride resin and a co-ground mixture of (a) 0.001 to 10 parts by mass of at least one member selected from the group consisting of an organic phosphoric ester compound and a metal salt thereof and (b) 0.001 to 10 parts by mass of a grinding aid. The composition is excellent in transparency, heat stability, and heat discoloration resistance.Type: GrantFiled: October 28, 2004Date of Patent: July 29, 2008Assignee: Adeka CorporationInventors: Hidehiro Ishizuka, Daisuke Takeda, Yutaka Yonezawa
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Publication number: 20080153950Abstract: Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X? is independently oxygen or sulfur, each m is independently zero or 1 when X? is oxygen and zero, 1 or 2 when X? is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.Type: ApplicationFiled: December 20, 2007Publication date: June 26, 2008Inventors: Ravi B. Shankar, William J. Kruper, David R. Wilson, Bruce A. King, Michelle L. Hudack, Daniel J. Murray, Chun Wang, William Gerald Stobby, Ted A. Morgan, Mark W. Beach, Inken Beulich, Ing Feng Hu
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Patent number: 7365114Abstract: The flameproof styrenic resin composition according to the present invention comprises (A) about 70 to 99.5 parts by weight of a rubber-modified polystyrene resin and (B) about 0.Type: GrantFiled: September 15, 2003Date of Patent: April 29, 2008Assignee: Cheil Industries Inc.Inventors: Sang Hyun Hong, Yae Ho Yang, Young Sik Ryu
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Publication number: 20080085957Abstract: It is an object of the present invention to provide a polyester based artificial hair which has excellent setting properties, feeling and transparency and further has excellent flame-retardancy and controlled gloss of fiber surface while maintaining fiber properties possessed by a conventional polyester fiber such as heat resistance, strength and elongation and the like.Type: ApplicationFiled: April 8, 2005Publication date: April 10, 2008Applicant: KANEKA CORPORATIONInventor: Toshiyuki Masuda
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Patent number: 7279515Abstract: Resorcinol carbonate-based phosphate esters are prepared by reacting resorcinol carbonates with phosphorous oxychloride or a chlorophosphate. The resorcinol carbonates can be synthesized by the reaction of resorcinol with phosgene or diphenyl carbonate. The resorcinol carbonate-based phosphate esters can be used as flame retardants and perhaps flowing agents.Type: GrantFiled: September 21, 2005Date of Patent: October 9, 2007Inventors: Raj B. Durairaj, Gary A. Jesionowski
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Publication number: 20070155875Abstract: A polymer composition includes a rubber-modified aromatic vinyl resin and a cyclic phosphonate ester compound. Embodiments of the composition demonstrate good impact strength, flame retardancy, heat resistance. Some embodiments additionally demonstrate moisture resistance and low heat sag. A shaped article and an electronic device can be made from the flame retardant polymer composition.Type: ApplicationFiled: November 17, 2006Publication date: July 5, 2007Inventors: Jeong Hwan Ku, Sang Hyun Hong, Su Hak Bae, Jin Hwan Choi
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Patent number: 7169837Abstract: A flame retardant resin composition comprising: (A) 100 parts by weight of a resin component (component a) containing at least 50% by weight of a high impact polystyrene, and (B) 1 to 50 parts by weight of a phosphorous-containing compound (component b) represented by the following general formula (I): wherein A and A? are the same or different and represent —OR or -Q wherein R and Q represent an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group having 5 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or an aryl group having 6 to 15 carbon atoms. According to the present invention, there are provided a polystyrene resin composition containing substantially no halogen and having heat resistance, particularly a high heat distortion temperature under load, and an article from the composition.Type: GrantFiled: December 17, 2003Date of Patent: January 30, 2007Assignee: Teijin Chemicals, Ltd.Inventors: Katsuhiro Yamanaka, Kazuhiko Koya, Yutaka Taketani
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Patent number: 7166651Abstract: A shelf-stable two-part self-adhering dental composition and method. The composition comprises (a) at least one acidic compound containing at least one acidic moiety selected from the group consisting of where R is an alkyl or aryl group; (b) at least one polymerizable monomer without any acidic group where the polymerizable group is selected from the group consisting of an acrylate, a methacrylate and a vinyl group; (c) a substituted thiourea selected from the group consisting of 1-(2-pyridyl)-2-thiourea and 1-(2-tetrahydrofurfuryl)-2-thiourea; and (d) a hydroperoxide compound with at least one hydroperoxide group attached to a tertiary carbon. The first and second parts are then mixed immediately prior to application, applied to a dental substrate, and hardened. The bond strength of the mixed composition to dentine substrate is at least 3 MPa. The composition has excellent shelf-life and is self-adhering to various dental substrates such as a tooth, metal alloy and porcelain.Type: GrantFiled: May 19, 2003Date of Patent: January 23, 2007Assignee: Kerr CorporationInventor: Xuejun Qian
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Patent number: 7151126Abstract: The present invention relates to a flame retardant thermoplastic resin composition that contains a polyphenylene ether resin and a phenol resin derivative, both of them having good char formability, regardless of the base resin. A flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of polyphenylene ether, (C) about 0.1˜100 parts by weight of a phenol resin derivative, and (D) about 0.1˜50 parts by weight of a phosphorous compound or a mixture of phosphorous compounds. The thermoplastic resin composition may contain up to 5.0 parts by weight of an anti-dripping agent based on 100 parts by weight of the base resin.Type: GrantFiled: December 26, 2001Date of Patent: December 19, 2006Assignee: Cheil Industries Inc.Inventors: Jae Ho Yang, Sang Hyun Hong, Gyu Chul Lee, Bok Nam Jang, Sung Hee Ahn
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Patent number: 7148275Abstract: The present invention relates to a flame retardant thermoplastic resin composition that contains a phenol resin derivative having good char formability, regardless of the base resin. A flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of a phenol resin derivative, and (C) about 0.1˜50 parts by weight of a phosphorous compound or a mixture of phosphorous compounds.Type: GrantFiled: December 26, 2001Date of Patent: December 12, 2006Assignee: Cheil Industries Inc.Inventors: Jae Ho Yang, Sang Hyun Hong, Gyu Chul Lee, Young Gil Jang, Su Hak Bae
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Patent number: 7138447Abstract: The present invention provides a thermoplastic polymer composition mainly comprising a block copolymer prepared by extending, with a specific polyurethane component, the polymer chain of a block copolymer, which may be hydrogenated, having a polymer block of an aromatic vinyl compound and a polymer block of a conjugated diene. The thermoplastic polymer composition according to the present invention is excellent in handling properties and melt-moldability, because it shows non-tackiness. By using the thermoplastic polymer composition according to the present invention, a molded article having high qualities can be produced with good productivity.Type: GrantFiled: July 9, 2002Date of Patent: November 21, 2006Assignee: Kuraray Co., Ltd.Inventor: Hidekazu Saito
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Patent number: 7087667Abstract: A flame retardant resin composition consisting essentially of: (A) 100 parts by weight of the total of resin components (components A) which include at least 60 wt % of an aromatic polyester resin; (B) an organic phosphorus compound (component B-1) represented by the following general formula (1) and having an acid value of 0.7 mgKOH/g or less or an organic phosphorus compound (component B-2) represented by the following general formula (2); (C) 0 to 50 parts by weight of a flame retardancy improving resin (component C); and (D) 0 to 200 parts by weight of a filler (component D), and a molded article thereof. Wherein, when the organic phosphorus compound is the component B-1, the amount of the component B-1 is 1 to 100 parts by weight and when the organic phosphorus compound is the component B-2, the component B-2 is used in combination with a biscumyl compound (component B-3), the amount of the component B-2 is 5 to 3.0 parts by weight, and the amount of the component B-3 is 0.01 to 5 parts by weight.Type: GrantFiled: May 14, 2002Date of Patent: August 8, 2006Assignee: Teijin Chemicals, Ltd.Inventors: Katsuhiro Yamanaka, Yutaka Taketani
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Patent number: 7067569Abstract: The invention relates to a synergistic mixture comprising a) at least one compound selected from the group consisting of the phosphites of the formula (I) to (V), of the phosphonites of the formulae (VI) to (IX) and (XV), of the di/oligophosphonites of the formulae (X) and (XI) and of the phosphinites of the formulae (XII) to (XIV), and b) at least one compound selected from the group consisting of the phosphanes of the formula (XVI), the di/oligophosphanes of the formulae (XVII) and (XVIII), and of the cyclophosphanes of the formula (XIX), and also to a process for stabilizing polymers with respect to thermooxidative degradation by addition and incorporation of a synergistic mixture of this type.Type: GrantFiled: July 13, 2001Date of Patent: June 27, 2006Assignee: Clariant Finance (BVI) LimitedInventor: Peter Staniek
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Patent number: 7067076Abstract: The invention is directed to a phosphonate composition having flame retardant properties. The phosphonate composition of the invention has the general formula: wherein R1 and R2 are independently C1–C4 alkyl, R3 is H or C1–C4 alkyl, and R4 is linear or branched C9–C22 alkyl, C9–C22 cycloalkyl, C9–C22 aryl or C9–C22 aralkyl and n=0 or 1. The invention is also directed to a method of producing the phosphonate composition having flame retardant properties.Type: GrantFiled: July 29, 2004Date of Patent: June 27, 2006Assignee: Rhodia Inc.Inventors: Shiming Wo, Dwight Shamblee
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Patent number: 7060744Abstract: A phosphazene composition which has a content of volatile components of not less than 0.02% by weight and not more than 1.0% by weight when it is heated at 200° C. for 2 hours; is excellent in resistance to hydrolysis, and when the phosphazene composition is added to a resin, there is provided a resin composition which highly maintains the balance of resistance to hydrolysis, flame retardancy and stability of electric characteristics in a high-frequency field of not less than 1 GHz.Type: GrantFiled: August 27, 2003Date of Patent: June 13, 2006Assignee: Asahi Kasei Chemicals CorporationInventors: Fumiki Murakami, Jun-ichi Nakahashi, Atsushi Nanasawa, Tomoyuki Fujita
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Patent number: 7018567Abstract: An antistatic flame retardant composition comprises a polycarbonate resin; an impact modifier comprising polysiloxane; an antistatic agent; and a flame retardant in a an amount greater than or equal to about 9 wt % of the total composition. Owing to its excellent antistatic, impact and flame retardant properties, the composition can be used in electrical and electronic equipment and precision machinery where high fabrication temperatures and high usage temperatures are often encountered.Type: GrantFiled: July 22, 2002Date of Patent: March 28, 2006Assignee: General Electric CompanyInventor: Michael C. Murray