Oxygen Ring Atom Patents (Class 524/117)
  • Patent number: 5322869
    Abstract: Styrene-based resin composition containing as main components (A) 100 parts by weight of a styrene-based polymer having mainly a syndiotactic configuration and (B) 0.01 to 25 parts by weight of one or more nucleating agents selected from the group consisting of (1) metal salts of organic acids having an average particle diameter of not more than 50 .mu.m, (2) inorganic compounds having an average particle diameter of not more than 50 .mu.m, (3) organophosphorus compounds having an average particle diameter of not more than 50 .mu.m, and (4) metal salts of ionic hydrocarbon copolymer, and a process for producing styrene-based resin moldings by molding the above styrene-based resin composition at a temperature between room temperature and 200.degree. C. The resin composition of the present invention is suitable for injection molding and extrusion molding, and provides moldings which are of high crystallinity and are excellent in heat resistance, solvent resistance, chemical resistance and so forth.
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: June 21, 1994
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Komei Yamasaki, Takashi Sumitomo, Toshikazu Ijitsu, Hiroshi Yamada, Toshihiro Furusawa
  • Patent number: 5292785
    Abstract: A stabilized composition of matter which comprises an organic material subject to oxidative, thermal or actinic degradation, and an effective stabilizing amount of a bisphosphite typified by formula I ##STR1## wherein n has a value of 0 or 1; Q is --CR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are independently hydrogen, alkyl or aryl; Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Z.sup.2, Z.sup.3, Z.sup.4 and Z.sup.5 are independently hydrogen, alkyl, cycloalkyl, aralkyl, aryl, cyano, acyl and hydrogen; and each Z represents an identical or different alkyl, aryl, aralkyl or alkaryl group.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: March 8, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Stephen D. Pastor, Sai P. Shum
  • Patent number: 5278279
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: January 11, 1994
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5250593
    Abstract: A polyolefin composition comprising a polyolefin, and the following components:(A) a phenolic compound which is a derivative of pentaerythritol,(B) a phenolic acrylate compound,(C) at least one organic phosphorous compound such as bis(2,6-di-t-butyl-4-methylphenyl) pentaerythritol diphosphite. This composition is stable against thermal processing, thermal oxidation and discoloration, and it is especially useful for fibers and films. Further incorporation of a polycondensate of dimethyl succinate with 1-(2-hydroxyethyl)-4-hydroxy-2,2,6,6-tetramethylpiperidine is effective to inprove the light stability of the composition.
    Type: Grant
    Filed: September 3, 1992
    Date of Patent: October 5, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tamaki Ishii, Shinichi Yachigo, Fumitoshi Kojima, Kanako Ida
  • Patent number: 5240622
    Abstract: Composition containing an organic polymer, with the exception of epoxy-based polymers, a lubricant, a metal-working fluid or a hydraulic fluid and, as stabilizer, at least one dioxaphosphorinane compound of the formulae ##STR1## wherein R.sub.1 to R.sub.6, R' and R" are independently hydrogen, alkyl, alkenyl, cycloalkyl or aryl, X.sup.+ is hydrogen, a metal cation or quaternary nitrogen atom, A is a n-valent hydrocarbyl moiety, n is 1 to 4, and m is 1 or 2.These compositions are stabilized against thermal, oxidative and/or actinic degradation. The abovementioned compounds are also very suitable as wear-resistant agents and high-pressure additives in lubricants.Some of the dioxaphosphorinane compounds are novel.
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: August 31, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Peter Nesvadba
  • Patent number: 5238979
    Abstract: Stabilizers for enhancing the resistance of synthetic resins to deterioration when exposed to elevated temperatures and/or ultraviolet light comprising from about 0.001 to about 10 parts by weight of a bisphenol phosphite having the formula ##STR1## wherein R.sub.1 is tertiary-butyl or tertiary-amyl, R.sub.2 is alkyl having from one to about nine carbon atoms, R.sub.3 is hydrogen or alkyl having from one to about four carbon atoms, and R.sub.4 is alkyl having from one to about thirty carbon atoms; and from about 0.001 to about 10 parts by weight of a phenol having the formula ##STR2## wherein R.sub.5 is alkyl having from one to about four carbon atoms; and R.sub.6 is hydrogen or alkyl having from one to about four carbon atoms; and stabilized synthetic resin compositions comprising such stabilizers.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: August 24, 1993
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Tohru Haruna, Kazunori Nishikawa
  • Patent number: 5234980
    Abstract: There is provided a fire retardant polycarbonate resin composition comprising a polycarbonate resin, a specific partially esterified phosphoric acid metal salt and a specific partially esterified phosphoric acid in specific proportions. The polycarbonate resin composition can provide a transparent molded article which are excellent in fire retardance and heat stability.
    Type: Grant
    Filed: June 30, 1992
    Date of Patent: August 10, 1993
    Assignee: Teijin Chemicals, Ltd.
    Inventor: Yoji Ohira
  • Patent number: 5231124
    Abstract: Thermoplastic molding composition based on polyalkylene terephthalate, aromatic polycarbonate and, optionally, rubber-elastic polymer, which are provided with special phosphorus stabilizers, show good paintability and paint adhesion and, even after painting, show favorable low-temperature toughness and heat resistance.
    Type: Grant
    Filed: November 25, 1990
    Date of Patent: July 27, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karsten-Josef Idel, Jurgen Kirsch, Friedemann Paul, Lothar Meier, Hans-Georg Gehrke
  • Patent number: 5191000
    Abstract: The flameproofed, non-dripping polyalkylene terephthalate molding compounds according to the invention based on phosphoric acid esters may be used for the production of moldings. The fire behavior of the polyalkylene terephthalate molding compounds is improved by the addition of certain phosphoric acid esters, a surprising reduction in the phosphorus content of the molding compounds being achieved at the same time, particularly in combination with highly heat-resistant thermoplastics.
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: March 2, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott
  • Patent number: 5145941
    Abstract: The invention is a polyester and a method for producing a polyester fiber which has a combination of flame resistance and low pilling properties. The method comprises forming a polyester fiber made from a blend of two polyester polymers, one polyester polymer containing an oxysilicon compound and the second polyester polymer containing pentaerythritol and a phosphinic acid in the amount between 0.5 and 20 mole percent of the terephthalate acid and monomer. In particular, the invention also comprises the enhanced fiber formed by the process, as well as the fabrics having a pilling of about 3 to less than 5 as measured in accordance with ASTM D-3512-82.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: September 8, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Jerry T. Munday, Theodore D. Meiss
  • Patent number: 5132346
    Abstract: Compounds of the general formula ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl, or phenyl or naphthyl, each unsubstituted or substituted by 1 to 3 C.sub.1 -C.sub.4 alkyl groups, R.sub.3 and R.sub.4 are each independently of the other hydrogen or C.sub.1 -C.sub.4 alkyl, with the proviso that R.sub.3 and R.sub.4 may not simultaneously be hydrogen, and R.sub.5 is hydrogen, C.sub.1 -C.sub.6 alkyl, or phenyl or naphthyl, each unsubstituted or substituted by 1 to 3 C.sub.1 -C.sub.4 alkyl groups, and X is oxygen or sulfur, are very suitable flame retardants for polymers.
    Type: Grant
    Filed: August 7, 1991
    Date of Patent: July 21, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Peter Flury
  • Patent number: 5126387
    Abstract: A flame retardant composition comprises at least one cyclic phosphonate ester and at least one phosphono amide. The ester and the amide are present in a ratio by weight of 0.1 to 2:1. A co-curing agent (e.g. urea, ethylene urea or an amino-triazine) may be included. The composition may also contain a non-rewetting agent and/or a softening or conditioning agent. The composition is used for the flame retardant treatment of a fabric by first impregnating the fabric with an aqueous solution of the composition and then heating the impregnated fabric at at least 100.degree. C. and under acid pH conditions.
    Type: Grant
    Filed: March 1, 1991
    Date of Patent: June 30, 1992
    Assignee: Albright & Wilson Limited
    Inventor: Geoffrey Hand
  • Patent number: 5112891
    Abstract: A polycarbonate resin composition improved in heat resistance by the addition of an organic cyclic phosphite represented by the general formula: ##STR1## wherein R.sub.1 represents an alkyl group having 1 to 9 carbon atoms; R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and R.sub.3 represents an alkyl group having 1 to 30 carbon atoms.
    Type: Grant
    Filed: August 28, 1990
    Date of Patent: May 12, 1992
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Tohru Haruna, Masayuki Takahashi, Toshinori Yukino
  • Patent number: 5064885
    Abstract: This invention relates to aliphatic polycarbonates including sequential copolymers based on cyclic aliphatic carbonates and esters and block copolymers of blocks of polymerised cyclic aliphatic carbonates and blocks of polymerised vinyl compounds stabilized against thermal degradation containing 0.01 to 3.0% by weight, based on polymer, of a compound of trivalent phosphorus.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: November 12, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedemann Muller, Edgar Leitz, Herbert Eichenauer, Karl-Heinz Ott, Hans-Josef Buysch
  • Patent number: 5063264
    Abstract: A first crystalline polyolefin composition is provided, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I): ##STR1## wherein R represents an alkylidene group having from 1 to 4 carbon atoms or a sulfur atom; Ar.sub.1 and Ar.sub.2, which may be the same or different, each represents an alkylarylene group or a cycloalkylarylene group; and n represents 0 or 1, and (B) from 0.001 to 1 part by weight of at least one of (1) an aliphatic monocarboxylic acid salt with lithium or sodium, (2) a dithiocarbamic acid salt with lithium, sodium or potassium, (3) a 2-mercaptobenzothiazole salt with lithium, sodium or potassium, (4) a 2-mercaptobenzimidazole salt with lithium, sodium or potassium and (5) a benzotriazole salt with lithium, sodium or potassium.
    Type: Grant
    Filed: August 20, 1990
    Date of Patent: November 5, 1991
    Assignee: Chisso Corporation
    Inventor: Hirokazu Nakajima
  • Patent number: 5055507
    Abstract: Stabilizers for enhancing the resistance of synthetic resins to deterioration when exposed to elevated temperatures and/or ultraviolet light comprising from about 0.001 to about 10 parts by weight of a bisphenol phosphite having the formula ##STR1## wherein R.sub.1 is tertiary-butyl or tertiary-amyl, R.sub.2 is alkyl having from one to about nine carbon atoms, R.sub.3 is hydrogen or alkyl having from one to about four carbon atoms, and R.sub.4 is alkyl having from one to about thirty carbon atoms; and from about 0.001 to about 10 parts by weight of a phenol having the formula ##STR2## wherein R.sub.5 is alkyl having from one to about four carbon atoms; and stabilized synthetic resin compositions comprising such stabilizers.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: October 8, 1991
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Tohru Haruna, Kazunori Nishikawa
  • Patent number: 5039723
    Abstract: A synthetic resin composition stabilized particularly against the deterioration caused by the action of heat and light, which comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic phosphite compound represented by the following general formula (I) and 0.001 to 10 parts by weight of a hindered amine compound having a group represented by the following general formula (II) in its molecule: ##STR1## wherein R.sub.1 stands for a tert-butyl or tert-amyl group; R.sub.2 stands for a C.sub.1.about.9 alkyl group; R.sub.3 stands for a hydrogen atom or a C.sub.1.about.4 alkyl group and R.sub.4 stands for a C.sub.1.about.30 alkyl group.
    Type: Grant
    Filed: July 31, 1989
    Date of Patent: August 13, 1991
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Tohru Haruna, Kazunori Nishikawa
  • Patent number: 5034441
    Abstract: Disclosed is a styrene-based resin composition which comprises (a) 100 parts by weight of styrene-based polymer having a high degree of syndiotactic configuration, (b) 0.01 to 15 parts by weight of at least one nucleating agent selected from an organophosphorus compound and a metal salt of an organic acid, and (c) 0.01 to 15 parts by weight of at least one component selected from a polyoxyalkylene compound, a fatty acid and a derivative thereof.The composition can produce various molding products with excellent mold-releasing property, surface gloss, bending strength, bending modulus and heat resistance.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: July 23, 1991
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo
  • Patent number: 5030674
    Abstract: Flame retardant compositions comprise linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon and a minor quantity, relative to the polymer, of a thermally stable cyclic phosphonate ester and polytetrafluoroethylene resin.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: July 9, 1991
    Assignee: Shell Oil Company
    Inventor: Vincent J. Notorgiacomo, Jr.
  • Patent number: 5017633
    Abstract: A filled polyolefin, particularly polypropylene, containing a sterically hindered phenol antioxidant and a compound of formula I and/or II ##STR1## in which R is unsubstituted phenyl or phenyl substituted by 1 or 2 C.sub.1-12 alkyl groupsn is 0 or 1 andA is a monofunctional or difunctional residue of a phenyl, diphenyl, diphenyl ether, diphenylmethane or dibenzofuran,as processing stabilizer has good long-term stability even in the absence of conventional sulphur-containing co-stabilizers.
    Type: Grant
    Filed: July 6, 1989
    Date of Patent: May 21, 1991
    Assignee: Sandoz Ltd.
    Inventor: Guenther Tscheulin
  • Patent number: 5013776
    Abstract: A flame-retardant polycarbonate resin composition comprising 100 parts by weight of a polycarbonate resin and 0.001 to 5.0 parts by weight of at least one metal salt of an organic phosphoric acid ester represented by the following general formula [I] ##STR1## wherein R.sub.1 and R.sub.2, independently from each other, represent an alkyl or aryl group which is substituted or unsubstituted by halogen, at least one of R.sub.1 and R.sub.2 is an aryl group and when both R.sub.1 and R.sub.2 are aryl groups, they may be bonded to each other either directly or through an alkylene group or may form one fused ring, and M represents an alkali metal, and optionally 0.01 to 2.0 parts by weight of a micro-fibrous polytetrafluoroethylene.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: May 7, 1991
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Kouji Ishihata, Youichi Hironaka, Hisanaga Shimizu, Kazuo Kitamura, Takeshi Imagawa
  • Patent number: 4940772
    Abstract: A polyester, wherein pendent phosphorus atoms are bound to the main chain of the polyester, having an excellent flame resistance and a high intrinsic viscosity can be stably produced without deteriorating the properties of said polyester by preliminarily copolymerizing a polyester with a specific unsaturated compound and then reacting the unsaturated bond thus-formed with a specific phosphorus compound having a P-H bond.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: July 10, 1990
    Assignee: Nippon Ester Co., Ltd.
    Inventors: Tetsuo Matsumoto, Keizo Tsujimoto, Katsuto Matsuzawa, Shunichiro Hamada, Kouzi Shinogi, Satomi Nagai, Takayuki Imamura, Akiko Kuroyanagi
  • Patent number: 4929654
    Abstract: Disclosed are novel cyclic phosphite compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from hydrogen, alkyl, aralkyl, aryl, carboxy, alkoxycarbonyl or halogen;each R.sup.2 is independently selected from hydrogen, alkyl, aralkyl, alkoxy, aryl, carboxy, alkoxycarbonyl or halogen;R.sup.3 is (a) hydrogen, alkyl, cyclohexyl or aryl when n is 1; (b) alkylene, cyclohexylene, cyclohexylenedialkylene, arylene or a divalent group having the formula ##STR2## wherein R.sup.1 and R.sup.2 are defined above and A.sup.2 is 1,3- or 1,4-phenylene when n is 2; (c) alkanetriyl when n is 3; or alkanetetrayl when n is 4;n is 1, 2, 3 or 4; andA.sup.1 is 1,3-phenylene.Also disclosed are synthetic polymeric materials stabilized with one of the above compounds and phosphite chloride compounds from which the above compounds are prepared.
    Type: Grant
    Filed: October 4, 1988
    Date of Patent: May 29, 1990
    Assignee: Eastman Kodak Company
    Inventors: Richard H. S. Wang, Garry L. Myers
  • Patent number: 4912198
    Abstract: Cyclic carbonate oligomers are stabilized according to the present invention by admixing a composition containing cyclic carbonate oligomers with an amount of an organic phosphite sufficient to substantially prevent premature polymerization of the oligomers.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: March 27, 1990
    Assignee: General Electric Company
    Inventor: Luca P. Fontana
  • Patent number: 4885326
    Abstract: A synthetic resin composition comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic alkylphosphite compound of 2,2'-alkylidene-bisphenol (I) and 0.001 to 10 parts by weight of beta-(3,5-dialkyl-4-hydroxyphenyl)-propionic acid ester (II) and is stabilized to light and heat.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: December 5, 1989
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Tohru Haruna, Kazunori Nishikawa, Mitsuhiro Hamajima
  • Patent number: 4882374
    Abstract: Disclosed are novel cyclic phosphite compounds having the formula ##STR1## wherein R.sup.1 is hydrogen, alkyl or aralkyl; R.sup.2 is hydrogen or alkyl; R.sup.3 is alkyl or aryl; and R.sup.4 and R.sup.5 each is alkyl. Also disclosed are polyolefin compositions stabilized with one or more of the above compounds.
    Type: Grant
    Filed: February 6, 1989
    Date of Patent: November 21, 1989
    Assignee: Eastman Kodak Company
    Inventors: Richard H. S. Wang, Garry L. Myers
  • Patent number: 4882227
    Abstract: There is provided an electric conductive resin composition formed into a pellet, which includes an electric conductive filler comprising electric conductive fibers and a low-melting point metal, and being coated on the surface thereof with a thermoplastic resin. Flux and/or a phosphorus-based antioxidant may be added to the filler. There is also provided an electromagnetic wave shielding molded product prepared by using the electric conductive resin composition mentioned above, wherein the electric conductive fibers dispersed within the molded product are fixed each other through the low-melting point metal.
    Type: Grant
    Filed: March 9, 1988
    Date of Patent: November 21, 1989
    Assignee: Toshiba Chemical Corporation
    Inventors: Hidehiro Iwase, Keiichi Habata
  • Patent number: 4855345
    Abstract: Compounds of the formula I ##STR1## in which n is 1, 2 or 3, R.sup.1 is C.sub.1 -C.sub.5 -alkyl, cyclohexyl or .alpha.-methylcyclohexyl and, if n is 1, X is a group of the formula II or III ##STR2## in which R.sup.2 and R.sup.3 independently of one another are C.sub.1 -C.sub.8 -alkyl or cyclohexyl, Y is a direct bond, --S--, >S.dbd.O or a radical --CR.sup.4 R.sup.5 -- in which R.sup.4 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, phenyl or benzyl and R.sup.5 is hydrogen or C.sub.1 -C.sub.8 -alkyl, and Z is 1,2-alkylene or 1,3-alkylene having not more than 15 carbon atoms or o-phenylene, and, if n is 2, X is a group of the formula IV or V ##STR3## in which R.sup.6 is methyl or ethyl, and, if n is 3, X is a phosphorus atom, are suitable for stabilizing organic material against light-induced and/or thermo-oxidative degradation.
    Type: Grant
    Filed: June 10, 1987
    Date of Patent: August 8, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Siegfried Rosenberger, Hans-Rudolf Meier
  • Patent number: 4827010
    Abstract: A process for preparing cyclic phosphonic monoesters comprising subjecting aryloxyphosphines of defined formulae to flash pyrolysis, is provided. The aryloxyphosphines are those having the general formula ##STR1## where Ar is aryl and R is a hydrocarbyl radical capable of forming unsaturated hydrocarbon on severance of the C--O linkages.
    Type: Grant
    Filed: August 25, 1987
    Date of Patent: May 2, 1989
    Assignee: The British Petroleum Company p.l.c.
    Inventors: John I. G. Cadogan, Ian Gosney, Peter M. Wright, deceased
  • Patent number: 4824885
    Abstract: Stabilizers for organic polymers, consisting of one or more phosphorus-containing compounds of the family of alkyl- and/or phenyl-phosphites, alkyl- and/or phenyl-phosphonites, alkyl- and/or phenyl-diphosphonites, are directly added to the reaction mixture during the (co)polymerization of .alpha.-olefins or of mixtures thereof with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized, and show a thermo-oxidative resistance higher than that of the same polymeric compositions to which the same antioxidants have been added by a traditional route.
    Type: Grant
    Filed: July 6, 1987
    Date of Patent: April 25, 1989
    Assignee: Enichem Sintesi S.p.A.
    Inventors: Ambrogio Magni, Erik Bersanetti
  • Patent number: 4820772
    Abstract: A polyolefin composition having a superior resistance to impact-whitening, luster, impact resistance, mechanical strength and stiffness, particularly, mechanical strength and stiffness is provided, which composition is obtained by (1) blending (B) a high density ethylene polymer, (C) a non-crystalline ethylene-propylene random copolymer or a non-crystalline ethylene-propylene-non-conjugated diene random copolymer and a phosphate compound expressed by the following formula (I) (hereinafter referred to as compound (a)): ##STR1## wherein R.sub.1 represent sulfur or an alkylidene group of 1 to 4 carbon atoms; R.sub.2 and R.sub.3 each represent a hydrogen atom or the same or different alkyl groups of 1 to 8 carbon atoms; M represents a monovalent, divalent or trivalent metal atom; m represents 0 or 1; and n represents an integer of 1 to 3, with (A) a crystalline .alpha.
    Type: Grant
    Filed: April 18, 1988
    Date of Patent: April 11, 1989
    Assignee: Chisso Corporation
    Inventors: Nobuo Goto, Hiroshisa Ishii, Hirokazu Nakajima
  • Patent number: 4812501
    Abstract: 1,3,2-oxazaphospholidine derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants.
    Type: Grant
    Filed: March 16, 1988
    Date of Patent: March 14, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
  • Patent number: 4794139
    Abstract: This invention relates to a thixotropic thickening agent and to a process for preparing the same. Such thixotropic thickening agents are particularly useful for thickening water reducible coatings. The thixotropic thickening agents of this invention are copolymers which are comprised of repeat units which are derived from methacrylic acid monomer, ethylacrylate monomer, and a water soluble crosslinking agent. The water soluble crosslinking agents which can be used include ethylene glycol dimethacrylate and alkylene bisacrylamides, such as N,N'-methylene bisacrylamide. A neutralized two weight percent aqueous solution of the thixotropic thickening agents of this invention will have a Brookfield RVT viscosity as measured at 50 rpm using a number 3 spindle within the range of 50 to 2000 centipoise (cps).
    Type: Grant
    Filed: September 22, 1986
    Date of Patent: December 27, 1988
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Jennifer T. Braden, Gary L. Burroway, Herbert L. Bullard, Donald A. Tedeschi
  • Patent number: 4755546
    Abstract: Thermal stabilization of olefin polymers, particularly polypropylene. Stabilization is accomplished by means of an ester of a pentaerythritol monoacetal. The ester contains a phenolic group.
    Type: Grant
    Filed: March 6, 1985
    Date of Patent: July 5, 1988
    Assignee: Borg-Warner Chemicals, Inc.
    Inventors: Ingenuin Hechenbleikner, William P. Enlow
  • Patent number: 4751319
    Abstract: 1,3,2-oxazaphospholidine derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants.
    Type: Grant
    Filed: February 2, 1987
    Date of Patent: June 14, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
  • Patent number: 4668722
    Abstract: New hindered piperidinoalcohol 1,1,1-trioxyalkanes are disclosed. In the 1,1,1-trioxyalkanes, at least on 1,1,1-trioxyalkane group is linked to the residue of an alcohol linked to the 4-position of a 2,2,6,6-tetraalkylpiperidine compound having 12 to 75 carbon atoms. For each 1,1,1-trioxalkane group, there are 1 to 3 tetraalkylpiperidine groups. The alkyl groups linked to the piperidine ring have from one to five carbon atoms each. The fourth substituent on the carbon atom of the 1,1,1-trioxyalkane is a hydrogen atom or an aliphatic group having one to five carbon atoms.The disclosed 1,1,1-trioxyalkanes protect a variety of synthetic resins against the deteriorative effects of exposure to actinic light.Stabilizer compositions comprising a disclosed 1,1,1-trioxyalkane and a known polymer stabilizer, as well as synthetic resin compositions stabilized with such stabilizer compositions, are also disclosed.
    Type: Grant
    Filed: December 13, 1985
    Date of Patent: May 26, 1987
    Inventor: Gerry P. Mack
  • Patent number: 4656209
    Abstract: The invention relates to thermoplastic molding compositions based on vinyl chloride polymers and containing, as stabilizer, 0.1 to 5% by weight of an aminouracil of the formula I ##STR1## wherein R.sup.1 is hydrogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl, phenyl, benzyl, C.sub.1 -C.sub.4 hydroxyalkyl, hydroxyphenyl, C.sub.2 -C.sub.8 alkoxyalkyl, C.sub.2 -C.sub.8 alkylthioalkyl, C.sub.6 -C.sub.10 cycloalkoxyalkyl, C.sub.6 -C.sub.10 cycloalkylthioalkyl, C.sub.8 -C.sub.14 aralkoxyalkyl, C.sub.8 -C.sub.14 aralkylthioalkyl, C.sub.7 -C.sub.14 aryloxyalkyl, C.sub.7 -C.sub.14 arylthioalkyl, --NHR.sup.4, in which R.sup.4 is hydrogen, phenyl or chlorine-substituted phenyl, and R.sup.2 and R.sup.3, each independently of the other, are C.sub.2 -C.sub.21 alkyl, C.sub.6 -C.sub.12 aryl or C.sub.7 -C.sub.19 aralkyl, while one of R.sup.2 and R.sup.3 may also be hydrogen.The addition of such aminouracils gives vinyl chloride polymers which are very well protected against heat-induced degradation.
    Type: Grant
    Filed: May 17, 1982
    Date of Patent: April 7, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Wolfgang Wehner, Hermann O. Wirth
  • Patent number: 4618633
    Abstract: A halogen-free self-extinguishing thermoplastic composition comprising as the flame retardant, one or more phosphorus-containing compounds or elemental phosphorous, a polyphenylene ether, a styrene-acrylonitrile copolymer, a phenol/aldehyde resin, a terpolymer of styrene, acrylonitrile and a hydroxy-containing ester of acrylic or methacrylic acid on which a polyphenylene ether is grafted, and optionally, a diene elastomer having grafted thereon styrene and acrylonitrile monomers.
    Type: Grant
    Filed: September 5, 1985
    Date of Patent: October 21, 1986
    Assignee: BASF Aktiengesellschaft
    Inventors: Christof Taubitz, Volker Muench, Juergen Hambrecht, Adolf Echte, Karl H. Illers
  • Patent number: 4605692
    Abstract: Hydroxyphenylthio-substituted phosphites of the formula ##STR1## prepared by the reaction of the appropriate phosphorus and phenol compounds, said phosphites being useful as stabilizers of organic polymers and lubricating oils to counteract the degradative effects of light, heat and air.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: August 12, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: John D. Spivack, Ramanathan Ravichandran
  • Patent number: 4529533
    Abstract: Substituted 2-(2,6-di-t-butyl-4-alkylphenoxy)-4H-1,3,2-benzodioxaphosphorins that are readily prepared, for example from hindered phenols and ortho-methylolphenols, are effective heat and anti-oxidant stabilizers for organic materials subject to degradation by heat and oxygen, and provide particularly efficient stabilizer systems when combined with hydroxyphenylalkyleneyl isocyanurates.
    Type: Grant
    Filed: September 17, 1982
    Date of Patent: July 16, 1985
    Assignee: The B. F. Goodrich Company
    Inventor: Dwight W. Chasar
  • Patent number: 4524166
    Abstract: Primary or secondary amino substituted hindered phosphites of the formula ##STR1## are prepared by reaction of the appropriate phosphorus and phenol compounds, said hindered phosphites being useful as stabilizers of organic polymers and lubricating oils.
    Type: Grant
    Filed: September 14, 1984
    Date of Patent: June 18, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: John D. Spivack, Stephen D. Pastor
  • Patent number: 4508861
    Abstract: A thermally stabilized polyetherimide composition is disclosed which contains a polyetherimide and a stabilizing amount of an antioxidant having a molecular weight of 400 and is selected from the group of hindered phenols, aryl phosphonites, organic phosphites, thioesters or mixtures thereof. The stabilized polyetherimides exhibit a prolonged stability under conditions of elevated temperatures.
    Type: Grant
    Filed: December 29, 1983
    Date of Patent: April 2, 1985
    Assignee: General Electric Company
    Inventor: Roger W. Avakian
  • Patent number: 4507416
    Abstract: Novel stabilizers for organic materials subject to degradation, 2,4,6-tris(substituted phenoxy)-1,3,5,2,4,6-trioxatriphosphorinanes are prepared by the reaction of substituted-phenylphosphorodichloridites, water and amines. The 2,4,6-tris(substituted phenoxy)-1,3,5,2,4,6-trioxatriphosphorinanes, form effective stabilizer combinations with hindered and partly hindered phenols such as hydroxyphenylalkyleneyl isocyanurates, particularly when used in polymers, polyolefins, for example.
    Type: Grant
    Filed: May 12, 1983
    Date of Patent: March 26, 1985
    Assignee: The B. F. Goodrich Company
    Inventor: Dwight W. Chasar
  • Patent number: 4495320
    Abstract: 3,6-di-t-butyl-2-naphthyl catechol phosphite is readily prepared by the reaction of catechol phosphorodichloridite and 3,6-di-t-butylnathphol in the presence of a trialkyl amine in a solvent. The 3,6-di-t-butyl-2-naphthyl catechol phosphite is an excellent stabilizer for polymers, including polypropylene, and forms synergistic combinations with hydroxyphenylalkyleneyl isocyanurates that provide excellent resistance to polymer breakdown during processing.
    Type: Grant
    Filed: May 27, 1983
    Date of Patent: January 22, 1985
    Assignee: The B. F. Goodrich Company
    Inventor: Dwight W. Chasar
  • Patent number: 4463113
    Abstract: Bis-phenol phosphates, are provided, represented by the formula: ##STR1## wherein: R is selected from the group consisting of a carbon-to-carbon bond; thio sulfur --S--; and alkylidene ##STR2## in which R.sub.3 and R.sub.4 are selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms, and cycloalkyl, including cycloalkylidene in which R.sub.3 and R.sub.4 are taken together as part of a cycloalkylene ring, having from three to about twelve carbon atoms;R.sub.1 and R.sub.2 are each selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms; and cycloalkyl having from three to about twelve carbon atoms;m is 0 or 1;M is a metal atom which can be monovalent or polyvalent; and n is the valence of the metal atom M, ranging from one to about four;useful to improve clarity of polyolefin resin compositions in an amount within the range from 0.005 to 5 parts by weight per 100 parts of resin.
    Type: Grant
    Filed: May 20, 1982
    Date of Patent: July 31, 1984
    Inventors: Yutaka Nakahara, Mitsuo Akutsu, Tohru Haruna, Masayuki Takahashi
  • Patent number: 4456717
    Abstract: The present invention is directed to stabilizer compositions or thermoplastic polycarbonates based on phosphites and siloxane-oxetane compounds. These stabilizers protect the polycarbonate against heat and oxidative degradation, and in addition, increase the hydrolysis resistance of the polycarbonate. The present invention is also directed to a process for stabilizing polycarbonate and to the stabilized polycarbonate produced therefrom.
    Type: Grant
    Filed: June 8, 1983
    Date of Patent: June 26, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Erich Eimers, Rolf Dhein, Klaus Kircher
  • Patent number: 4439564
    Abstract: 2-[Alkyl substituted-phenoxy]-2,3-dihydro-1,2-benzoxaphosphole 2-oxide, cyclic phosphonates prepared, for example from hindered phenols and ortho-methylolphenols, are effective heat stabilizers and antioxidants for organic materials subject to degradation by heat, oxygen and the like, and result in effective stabilizer systems when combined with hydroxyphenylalkylenyl isocyanurates.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: March 27, 1984
    Assignee: The B. F. Goodrich Co.
    Inventor: Dwight W. Chasar
  • Patent number: 4433087
    Abstract: Alkylated 2,2'-biphenylene phosphonates are prepared by reacting alkylated 2,2'-biphenol with phosphoros trichloride in an organic solvent and then with a base such as sodium hydroxide. Said phosphonates are useful as stabilizers of organic polymers and lubricating oils, especially as stabilizers for polyolefins, polyesters, and polycarbonates.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: February 21, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: John D. Spivack
  • Patent number: 4423174
    Abstract: Synthetic resin compositions of improved resistance to deterioration by heat and light are provided containing a 2,2,6,6-tetramethyl piperidyl ether having the formula: ##STR1## The compounds of the invention can be prepared by the reaction of the 2,2,6,6-tetramethyl piperidyl alcohol R.sub.1 -OH with (poly) trimethylol alkane, (poly) pentaerthritol, or an alcohol containing an oxetane ring, to form the ether.The etherification is carried out by the conventional method, for example, by the reaction of R.sub.1 -OH with the organic sulfonate of the above-mentioned alcohols, or by the reaction of R.sub.1 -OH with the halogenated above-mentioned alcohols in the presence of an alkali or acid acceptor.The compounds where n is equal to 2 or more can be prepared by chain opening polymerization of the corresponding compound containing the oxetane ring.
    Type: Grant
    Filed: July 26, 1982
    Date of Patent: December 27, 1983
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Motonobu Minagawa, Naohiro Kubota, Ryoji Kimura
  • Patent number: 4414345
    Abstract: Compounds of the formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.18 alkyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.18 alkyl, andA is a substituted primary or secondary aliphatic or alicyclic, aromatic or araliphatic amine, in which the substituents are identical or different, a heterocyclic amine or a hydrazine derivative.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: November 8, 1983
    Assignee: Ciba-Geigy Corporation
    Inventor: Michael Rasberger