Sulfur, E.g., Factice, Etc. Patents (Class 524/302)
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Patent number: 12071498Abstract: Polymerizable compositions comprising a radically polymerizable resin can be polymerized in the absence of a peroxide initiator and other undesirable components. The polymerizable compositions and methods employ a manganese- or iron-containing salt or organic complex and a 1,3-dioxo compound with one or more other components. The polymerizable compositions have better storage stability and reduced gel time-drift.Type: GrantFiled: December 5, 2022Date of Patent: August 27, 2024Assignee: Polynt Composites USA, Inc.Inventors: Hildeberto Nava, James Anthony Skrobacki, Samuel T. Freeman
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Patent number: 11518834Abstract: Polymerizable compositions comprising a radically polymerizable resin can be polymerized in the absence of a peroxide initiator and other undesirable components. The polymerizable compositions and methods employ a manganese- or iron-containing salt or organic complex and a 1,3-dioxo compound with one or more other components. The polymerizable compositions have better storage stability and reduced gel time-drift.Type: GrantFiled: December 30, 2019Date of Patent: December 6, 2022Assignee: Polynt Composites USA, Inc.Inventors: Hildeberto Nava, James Anthony Skrobacki, Samuel T. Freeman
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Patent number: 11241907Abstract: An eraser for removing strokes of writing, painting and/or drawing implements, including at least one binder and at least one plasticizer, wherein the at least one plasticizer is a polyol ester.Type: GrantFiled: July 5, 2017Date of Patent: February 8, 2022Assignee: STAEDTLER MARS GMBH & CO. KGInventor: Andreas Thies
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Patent number: 10150859Abstract: A vulcanizable rubber composition includes an oil extended copolymer composition, an unsaturated rubber, filler, process oil and a vulcanizing agent, wherein the oil extended copolymer composition ion has a phase angle ?min of lower than 2.5, and includes: auxiliary agents, extender oil, and at least one ethylene-?-olefin-non-conjugated-diene copolymer having a weight average molecular weight (Mw) of at least 300,000 g/mol, an intrinsic viscosity higher than 4 measured in Xylene at 70° C., and a polydispersity (Mw/Mn) smaller than 3.Type: GrantFiled: December 4, 2015Date of Patent: December 11, 2018Assignee: ARLANXEO NETHERLANDS B.V.Inventors: Jacob Hubert Henri Beelen, Martin Van Duin, Christoph Gogelein
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Patent number: 9862524Abstract: Provided is a light-shielding container which has an ultraviolet-ray transmittance of 0% at wavelengths of 200-370 nm and to which contents are less apt to adhere. A light-shielding container for holding contents, characterized by having at least an inner layer composed of a thermoplastic resin, a first light-shielding layer composed of a resin containing an inorganic ultraviolet inhibitor and a second light-shielding layer composed of a resin containing an organic ultraviolet absorber, disposed in this order from the content side.Type: GrantFiled: February 19, 2013Date of Patent: January 9, 2018Assignee: KYORAKU CO., LTD.Inventors: Kentaro Uchihashi, Takeru Sano
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Patent number: 8999092Abstract: The present invention relates to aqueous-based compositions suitable for use in threadlocking applications comprising: a) at least one carboxyl group containing (co)polymer; b) at least one polymerizable monomer A containing one acryloyl group; c) at least one polymerizable compound B containing at least two acryloyl groups; d) at least one encapsulated free radical initiator; and e) water. The inventive aqueous-based compositions are preferably substantially free of volatile organic solvents.Type: GrantFiled: March 5, 2014Date of Patent: April 7, 2015Assignee: Henkel Ireland LimitedInventor: Peter Wrobel
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Patent number: 8940831Abstract: The present invention provides a (meth)acrylic resin composition comprising a carboxylic acid group produced by heating a (meth)acrylic-based resin (C), wherein the (meth)acrylic-based resin (C) is obtained by polymerizing a monomer mixture (A) containing 80 to 99 wt % of a linear alkyl (meth)acrylate and 1 to 20 wt % of tertiary-butyl (meth)acrylate, in the presence of an acrylic acid ester-based crosslinked elastic particle (B) that is obtained by mixing and polymerizing 0.5 to 5 parts by weight of a polyfunctional monomer having at least two non-conjugated double bonds per molecule, with respect to 100 parts by weight of a monomer mixture containing 50 to 100 wt % of an alkyl acrylate monomer and 0 to 50 wt % of an alkyl methacrylate monomer. This composition can be used to produce a film having excellent chemical resistance (in particular, sun-screening agent resistance).Type: GrantFiled: March 11, 2014Date of Patent: January 27, 2015Assignee: Kaneka CorporationInventors: Hirofumi Inari, Katsuyuki Tanaka, Kimihide Nishimura
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Publication number: 20140191263Abstract: Disclosed herein is a resin composition for molding a reflector for a light-emitting semiconductor diode comprising about 25 to about 80 wt. % of an heat-resistant aromatic polyester, about 5 to 50 wt. % of titanium dioxide filler; and about 5 to 50 wt. % of a glass fibers having a flat surface. In another aspect of the present invention, there is also provided a reflector for a light-emitting semiconductor element, which includes a molded product of the resin composition. In a further aspect of the present invention, there is also provided a light-emitting semiconductor unit comprising a light-emitting semiconductor diode element, leads connecting electrodes of the light-emitting semiconductor diode element with external electrodes, respectively, and the reflector.Type: ApplicationFiled: March 27, 2013Publication date: July 10, 2014Inventors: Liang Wang, Takumi Shigeta, Hongtao Shi, Dake Shen
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Patent number: 8710134Abstract: The present invention provides a (meth)acrylic resin composition comprising a carboxylic acid group produced by heating a (meth)acrylic-based resin (C), wherein the (meth)acrylic-based resin (C) is obtained by polymerizing a monomer mixture (A) containing 80 to 99 wt % of a linear alkyl (meth)acrylate and 1 to 20 wt % of tertiary-butyl (meth)acrylate, in the presence of an acrylic acid ester-based crosslinked elastic particle (B) that is obtained by mixing and polymerizing 0.5 to 5 parts by weight of a polyfunctional monomer having at least two non-conjugated double bonds per molecule, with respect to 100 parts by weight of a monomer mixture containing 50 to 100 wt % of an alkyl acrylate monomer and 0 to 50 wt % of an alkyl methacrylate monomer. This composition can be used to produce a film having excellent chemical resistance (in particular, sun-screening agent resistance).Type: GrantFiled: November 9, 2007Date of Patent: April 29, 2014Assignee: Kaneka CorporationInventors: Hirofumi Inari, Katsuyuki Tanaka, Kimihide Nishimura
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Patent number: 8691900Abstract: The present invention relates to aqueous-based compositions suitable for use in threadlocking applications comprising: a) at least one carboxyl group containing (co)polymer; b) at least one polymerizable monomer A containing one acryloyl group; c) at least one polymerizable compound B containing at least two acryloyl groups; d) at least one encapsulated free radical initiator; and e) water. The inventive aqueous-based compositions are preferably substantially free of volatile organic solvents.Type: GrantFiled: April 20, 2012Date of Patent: April 8, 2014Assignee: Henkel IP & Holding GmbHInventor: Peter Wrobel
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Publication number: 20140031456Abstract: Disclosed is a process for the manufacture of a modified polyalkylene terephthalate such as modified polybutylene terephthalate. In particular, the process comprises employing a titanium-containing catalyst formed by the reaction product of tetraalkyl titanate and a complexing agent comprising a phosphorous, nitrogen or boron atom. The process is used to prepared modified polyalkylene terephthalates characterized by improved hydrostability, as well as compositions and compositions derived therefrom.Type: ApplicationFiled: July 25, 2013Publication date: January 30, 2014Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Husnu Alp Alidedeoglu, Tianhua Ding, Ganesh Kannan
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Publication number: 20130295306Abstract: Disclosed are a copolymeric polyester resin composition having outstanding colour stability (transparency) and a production method therefor. The copolymeric polyester resin composition comprises: between 95 and 99.99 percent by weight of a copolymeric polyester resin having a structure which is obtained by the copolymerisation of a dicarboxylic acid component and a diol component that comprises isosorbide, and in which there is repetition of a dicarboxylic acid moiety derived from the dicarboxylic acid component and a diol moiety derived from the diol component; and between 0.01 and 5 percent by weight of an antioxidant selected from the group consisting of hindered phenol-based antioxidants, phosphite-based antioxidants, thioether-based antioxidants and mixtures thereof.Type: ApplicationFiled: January 30, 2012Publication date: November 7, 2013Applicant: SK CHEMICALS CO., LTD.Inventor: JVC KENWOOD Corporation
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Publication number: 20130269976Abstract: The invention relates to cover (insulation or jacket) compositions for wires or cables having a base polymer and a bismuth compound. The composition contains no significant amount of lead and no added fire retardant.Type: ApplicationFiled: August 8, 2012Publication date: October 17, 2013Applicant: General Cable Technologies CorporationInventors: Sarah Gerretsen, Amalendu Sarkar
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Publication number: 20130109793Abstract: The present invention relates to a new process for preparing polyisocyanates containing isocyanurate groups and being flocculation-stable in solvents from (cyclo)aliphatic diisocyanates.Type: ApplicationFiled: October 25, 2012Publication date: May 2, 2013Inventors: Harald SCHAEFER, Shintaro Gomyo, Jing He, Horst Binder, Liang Han, Woosuk Lee
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Publication number: 20120322928Abstract: The present invention relates to a thermosetting resin composition suitable for construction purposes comprising (i) a thiol, (ii) a resin containing at least one norbornene group and having a molecular weight Mn of at least 500 Dalton, and (iii) a methacrylate containing compound whereby the resin composition comprises methacrylate containing compound in an amount of at least 5 wt % and at most 75 wt %, whereby 100 wt. % is the sum of methacrylate containing compound and resin containing at least one norbornene group. The present invention further relates to a two-component resin system consisting of component A and component B, wherein one of the components (A) comprises a resin containing at least one norbornene group and a methacrylate containing compound, whereby component (A) contains methacrylate containing compound in an amount of at least 5 wt % and at most 75 wt %, whereby 100 wt.Type: ApplicationFiled: November 29, 2010Publication date: December 20, 2012Inventors: Johan Franz Gradus Antonius Jansen, Michael Alphonsus Cornelis Johannes Van Dijck, Guido Joseph Elisabeth Hensen
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Patent number: 8227534Abstract: An insulation compound for a medium-voltage power cable, comprising a polymer comprising ethylene and one or more C3-C8 alpha olefins; and one or more metal sulfides.Type: GrantFiled: November 18, 2009Date of Patent: July 24, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventor: Kent L. Chasey
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Patent number: 8222313Abstract: Radiation curable compositions, such as UV curable ink compositions, contain a polymeric dispersant, a curable material, that includes a carrier and at least one nanoscale fluorescent pigment particle and an optional non-fluorescent colorant. The fluorescent organic nanoparticle composition includes one or more fluorescent dyes dispersed in a polymeric matrix obtained by modified EA latex process or by emulsion polymerization. In a different embodiment, the nanoscale fluorescent pigment particle composition includes pigment molecules with at least one functional moiety, and a sterically bulky stabilizer compound including at least one functional group, the functional moiety of the pigment associates non-covalently with the functional group of the stabilizer, and the presence of the associated stabilizer limits the extent of particle growth and aggregation, to afford nanoscale-sized pigment particles.Type: GrantFiled: October 6, 2008Date of Patent: July 17, 2012Assignee: Xerox CorporationInventors: Gabriel Iftime, C. Geoffrey Allen, Maria M. Birau, Christopher A. Wagner, Daryl W. Vanbesien, Jordan H. Wosnick, Peter G. Odell
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Patent number: 8168707Abstract: A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % of a polyester, 10-49 wt % of an ABS impact modifier; 0 to 20 wt % of a multifunctional epoxy compound; 0-40 wt % of a filler; 0-2 wt % of a fibrillated fluoropolymer; and from more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 40-100 Joules at ?30° C.; a ductility of more than 90%, a permeability of more than 0 to less than or equal to 1.5 g/m2-day, measured after exposure Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break after exposure to Fuel E85 for 28 days at 70° C.Type: GrantFiled: August 7, 2008Date of Patent: May 1, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Parminder Agarwal, Donald Howard Ellington, Robert Russell Gallucci, Josephus Gerardus M. van Gisbergen, Vishvajit Chandrakant Juikar, Ihab Odeh, Sathish Kumar Ranganathan, Kenneth Frederick Miller, Veeraraghavan Srinivasan
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Patent number: 8066912Abstract: A conductive pattern forming ink for forming a conductive pattern on a substrate by a droplet discharge method, includes: metal particles; an aqueous dispersion medium in which the metal particles are dispersed; sugar alcohol derived from a disaccharide; and a polyglycerol compound having a polyglycerol skeleton. H shown in the following formula (I) is 0.10 to 0.80.Type: GrantFiled: December 2, 2008Date of Patent: November 29, 2011Assignee: Seiko Epson CorporationInventor: Naoyuki Toyoda
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Patent number: 7989518Abstract: Biocompatible material, in particular prosthetic material with improved resistance to oxidation, comprising UHMWPE and one or more antioxidants selected from the group consisting of lipoic acid, its analogs and derivatives, Vitamin C, coenzyme Q10, glutathione. It is also disclosed a process to prepare such material.Type: GrantFiled: July 12, 2007Date of Patent: August 2, 2011Inventors: Fabio Conteduca, Fabio D'angelo
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Patent number: 7834072Abstract: Non-aqueous disperson compositions, such as ink compositions, contain a polymeric dispersant, a polymeric resin, an organic liquid, and a nanoscale pigment particle composition including an organic monoazo laked pigment including at least one functional moiety, and a sterically bulky stabilizer compound including at least one functional group, wherein the functional moiety of the pigment associates non-covalently with the functional group of the stabilizer; and the presence of the associated stabilizer limits the extent of particle growth and aggregation, to afford nanoscale-sized pigment particles.Type: GrantFiled: November 1, 2007Date of Patent: November 16, 2010Assignee: Xerox CorporationInventors: Rina Carlini, C. Geoffrey Allen, Sandra J. Gardner
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Publication number: 20100069548Abstract: Two-component composition comprising a first component and a second component, wherein the first component being a resin composition comprising an unsaturated polyester resin or vinyl ester resin, a manganese compound and a thiol-containing compound; the molar ratio between the manganese and the thiol groups of the thiol-containing compound is from 4:1 to 1:1500; and the second component comprises a peroxide compound having formula ROOH, in which R is hydrogen or an optionally substituted alkyl group.Type: ApplicationFiled: July 5, 2007Publication date: March 18, 2010Applicant: DSM IP ASSETS B.V.Inventors: Johan Franz Gradus Antonius Jansen, Ronald Ivo Kraeger
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Patent number: 7553897Abstract: A novel organic thiol stabilizer for PVC is described herein. Specifically, this novel thiol stabilizer for PVC is dipentaerythritol hexakis(mercaptoacetate). The organic thiol stabilizer of the present invention, when blended with halogen-containing polymers such as PVC, or derivatives thereof, provides advantages in cost and/or performance relative to existing organic stabilizers for PVC.Type: GrantFiled: January 11, 2007Date of Patent: June 30, 2009Assignee: College of William and MaryInventor: William H Starnes, Jr.
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Publication number: 20090148680Abstract: A conductive pattern forming ink for forming a conductive pattern on a substrate by a droplet discharge method includes: metal particles; an aqueous dispersion medium in which the metal particles are dispersed; inositol; and a polyglycerol compound having a polyglycerol skeleton. In the ink, H shown in the following formula (I) is 0.050 to 0.Type: ApplicationFiled: December 2, 2008Publication date: June 11, 2009Applicant: SEIKO EPSON CORPORATIONInventor: Naoyuki TOYODA
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Publication number: 20090145639Abstract: A conductive pattern forming ink for forming a conductive pattern on a substrate by a droplet discharge method includes: metal particles; an aqueous dispersion medium in which the metal particles are dispersed; galactitol; and a polyglycerol compound having a polyglycerol skeleton. In the ink, H shown in the following formula (I) is 0.10 to 0.Type: ApplicationFiled: December 2, 2008Publication date: June 11, 2009Applicant: SEIKO EPSON CORPORATIONInventor: Naoyuki TOYODA
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Publication number: 20090105363Abstract: A radiation curing composition suitable for building a three-dimensional object by a solid freeform method is disclosed. The composition includes one or more mono-functional monomers where a respective polymer has a Glass Transition Temperature higher than about 60° C. and one or more di-functional oligomers where a respective polymer has a Glass Transition Temperature lower than about 40° C. The functional groups of the components may include meth(acrylic) and the composition has a viscosity of about 50-500 cps at ambient temperature. Further, the concentration of the mono-functional monomer may be at least 30% by weight and the concentration of the di-functional oligomer may be at least 20% by weight.Type: ApplicationFiled: December 23, 2008Publication date: April 23, 2009Inventor: Eduardo NAPADENSKY
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Publication number: 20080226244Abstract: Using a compound of the following formula (1) makes it possible to provide an optical device having a reduced transmission loss. wherein R1 is an alkyl group having from 1 to 3 carbon atoms and having at least one fluorine atom, and R2 is an alkylene group having 1 or 2 carbon atoms.Type: ApplicationFiled: November 4, 2005Publication date: September 18, 2008Applicant: FUJIFILM CorporationInventors: Hirokazu Kyota, Hiroki Sasaki
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Patent number: 7317067Abstract: An object of the present invention is to provide a polycarbonate copolymer having excellent heat resistance and dimensional stability and heat resistant parts comprising the copolymer and suitable for use in various applications. The present invention is a polycarbonate copolymer comprising 5 to 95 mol % of recurring unit (component a) represented by the following general formula (I): and 95 to 5 mol % of recurring unit (component b) represented by the following general formula (II): (wherein Ra to Rd are each independently a hydrogen atom, a hydrocarbon group which may contain an aromatic group having 1 to 9 carbon atoms or a halogen atom, and W is a single bond, a hydrocarbon group which may contain an aromatic group having 1 to 20 carbon atoms or an O, SO, SO2, CO or COO group), and various heat resistant parts comprising the copolymer.Type: GrantFiled: March 24, 2003Date of Patent: January 8, 2008Assignee: Teijin ChemicalsInventors: Koki Ikeda, Toshimasa Tokuda, Yoshimasa Okamoto, Masato Ando
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Patent number: 7312266Abstract: Organic thiol compounds based on pentaerythritol and dipentaerythritol are described herein. More specifically, the compounds of the present invention are mixed esters of pentaerythritol and dipentaerythritol having at least one sulfhydryl group and preferably a plurality of sulfhydryl groups as well as at least one non-thiol-containing group. The organic thiol compounds are utilized to plasticize and/or heat stabilize halogen-containing polymer compositions especially poly(vinyl chloride) compositions. The compositions are substantially free or free of metal-based stabilizers, Lewis acids and terpenes. The compounds of the present invention are ideally utilized in polymers normally susceptible to deterioration and color change which can occur during processing of the polymer or exposure of the polymer to certain environments and surprisingly also serve as excellent plasticizers.Type: GrantFiled: October 12, 2004Date of Patent: December 25, 2007Assignee: The College of William and MaryInventors: William Herbert Starnes, Jr., Bin Du
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Patent number: 7160937Abstract: An aromatic polycarbonate resin composition having: 100 parts by weight of a resin component (A) mainly having an aromatic polycarbonate, 0.1 to 200 parts by weight of a solid inorganic compound (B), at least one compound (C) selected from the group consisting of an organic acid, an organic acid ester, and an organic acid anhydride, 0.001 to 1 part by weight of at least one organic acid metal salt (D) selected from the group consisting of an organic acid alkali metal salt and an organic acid alkaline earth metal salt, and 0.01 to 1 part by weight of a fluoropolymer (E), wherein compound (C) is present in an amount wherein a mixture of compounds (B) and (C) exhibits a pH value of from 4 to 8.Type: GrantFiled: December 26, 2003Date of Patent: January 9, 2007Assignee: Asahi Kasei Chemicals CorporationInventors: Kazuhiro Shibuya, Akira Miyamoto
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Patent number: 7081500Abstract: Blocked mercaptosilanes are provided in which the blocking group contains and unsaturated heteroatom or carbon chemically bound directly to sulfur via a single bond. This blocking group optionally may be substituted with one or more carboxylate ester or carboxylic acid functional groups. These silanes are used in manufacture of inorganic filled rubbers, with the silanes deblocked by a deblocking agent. Synthesis of the blocked mercaptosilanes is also provided.Type: GrantFiled: November 9, 2001Date of Patent: July 25, 2006Assignee: General Electric CompanyInventors: Richard W. Cruse, Robert J. Pickwell, Keith J. Weller, Eric R. Pohl
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Patent number: 6992124Abstract: The present invention relates to a synergistic additives mixture for producing calendered polyolefin articles, comprising A) at least one component from the group of peroxide-destroying phosphorus or sulfur compounds, B) at least one component from the group of phenolic antioxidants, C) at least one component from the group of sterically hindered amines, and D) if desired, further additives. Using this additive mixture prevents sticking to the hot roll surfaces and reduces the degradation of the polymer.Type: GrantFiled: February 3, 1999Date of Patent: January 31, 2006Assignee: Clariant GmbHInventors: Christian Wick, Gerhard Pfahler, Alexander Lichtblau
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Patent number: 6927247Abstract: Organic thiol compounds including mercaptophenylcarboxylates are disclosed which can be utilized to plasticize and/or stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.Type: GrantFiled: June 12, 2003Date of Patent: August 9, 2005Assignee: The College of William and MaryInventors: William Herbert Starnes, Jr., Soungkyoo Kim
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Patent number: 6919392Abstract: The heat and light stability imparted to vinyl halide polymers by metal compounds conventionally employed for this purpose is considerably improved by the presence of a mercapto ester such as 2-mercaptoethyl stearate. The esters can replace a substantial portion of the metal compound with no significant reduction in stability.Type: GrantFiled: April 20, 1992Date of Patent: July 19, 2005Assignee: Arkema Inc.Inventors: Jean-Yves Chenard, Jean-Claude Mendelsohn
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Patent number: 6881781Abstract: A non-toxic malleable, bounceable modeling compound stretchable in a manner similar to chewing gum which is particularly suitable for children. The compound is comprised essentially of a butyl rubber, vulcanized vegetable oil, one or more softening agents, an inorganic filler material, antioxidant and binder. The pliable compound can retain a molded shape for years and is an ideal sculpting material, stress reliever, and aid for improving dexterity. The compound is produced according to a tri-phase process that does not require heating or baking.Type: GrantFiled: December 1, 2003Date of Patent: April 19, 2005Assignee: The Wingum CompanyInventor: Guillermo Gamba
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Patent number: 6797757Abstract: The invention relates to articles of manufacture, such as for example, tires and industrial products, which have at least one component comprised of a rubber composition which contains particles of pre-sulfur vulcanized rubber (e.g. ground recycled rubber) and impure tetrathiodipropionic acid, namely a blend comprised primarily of tetrathiodipropionic acid and trithiodipropionic acids of a weight ratio thereof in a range of about 80/20 to about 30/70. Said blend is referred to herein as an S4/S3 blend. The S4/S3 blend may be introduced directly to a rubber composition or may be provided as particles of a composite of said S4/S3 and a particulate support therefor for a purpose of aiding the dispersion of the S4 and S3 within the elastomer host. Representative of such support, or carrier, may be, for example, silica, particularly amorphous precipitated silica, carbon black, clay, starch, calcium carbonate, calcium silicate, titanium dioxide and the like, wherein carbon black is preferred.Type: GrantFiled: May 8, 2002Date of Patent: September 28, 2004Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, George Frank Balogh
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Patent number: 6762231Abstract: Aromatic and aliphatic organic thiol compounds are disclosed which can be utilized to plasticize and/or stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.Type: GrantFiled: June 19, 2001Date of Patent: July 13, 2004Assignee: The College of William and MaryInventors: William Herbert Starnes, Jr., Bin Du
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Patent number: 6756435Abstract: The invention relates to a silica-filled, sulfur-vulcanizable rubber composition comprising an unsaturated rubber, 20 to 100 phr of a silica, 1.6 to 8 phr of a silica coupling agent, 0.05 to 5 phr of an antidegradant, 0.1 to 5 phr of a vulcanization accelerator, 0.1 to 10 phr of sulfur, and 0.5 to 5 phr of a quinone diimine, with the proviso that the antidegradant is not a quinone diimine. The invention also relates to a vulcanization process comprising mixing and heating said rubber composition and to rubber articles, such as pneumatic tires, comprising the rubber vulcanizate obtained by said process.Type: GrantFiled: December 11, 2001Date of Patent: June 29, 2004Assignee: Akzo Nobel NVInventors: Rabindra Nath Datta, Nicolaas Maria Huntink, Auke Gerardus Talma
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Patent number: 6747079Abstract: The invention concerns the use for increasing the life span of molds made of silicone elastomer crosslinking by polyaddition or polycondensation reaction, of an additive capable of stabilizing the silicone elastomer whereof the mold is constituted with respect to materials to be mouded, said additive corresponding the following formula (1) wherein R1 and R2 are linear or branched alkyl radicals or cycloaliphatic radicals having 1 to 40 carbon atoms. Preferably, said additive is methyl laurylthiopropionate. C12H25—S—CH2—CH2—CO—O—CH3. The invention also concerns the corresponding silicone compositions and the resulting molds.Type: GrantFiled: November 20, 2002Date of Patent: June 8, 2004Assignee: Rhodia ChimieInventors: Jérôme Bressieux, Thomas Deforth, Christian Pusineri
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Patent number: 6747081Abstract: Organic thiol compounds including aromatic, aliphatic, and diester ether compounds containing sulfhydryl groups are disclosed which can be utilized to plasticize and/or stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.Type: GrantFiled: June 14, 2002Date of Patent: June 8, 2004Assignee: The College of William and MaryInventor: William Herbert Starnes, Jr.
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Patent number: 6699921Abstract: There is provided a rubber composition whose run-flat durability is improved and in which precipitation of sulfur and a vulcanization accelerator on the rubber surface before vulcanization is prevented. Sulfur in an amount of 2 to 8 parts by weight and two or more vulcanization accelerators in a total amount of at least 5 parts by weight based on 100 parts by weight of a rubber component are used, at least one of the accelerators being a sulfen amide accelerator.Type: GrantFiled: November 20, 2001Date of Patent: March 2, 2004Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Keiji Ikeda
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Patent number: 6617384Abstract: The present invention provides a racing tire tread rubber composition which is used for producing a racing tire having excellent wet grippability and does not cause any excessive adhesion in tire production process steps such as kneading and extruding steps. The racing tire tread rubber composition is a composition comprising: 100 parts by weight of a diene-based rubber; a filler, the entirety of which is in the range of 100 to 250 parts by weight containing 20 parts by weight or more of silica; and 5 to 50 parts by weight of a factice.Type: GrantFiled: September 17, 1997Date of Patent: September 9, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Noboru Wakabayashi, Toru Iizuka
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Patent number: 6608115Abstract: Polyvinyl chloride resin compositions and methods of preparation and use thereof for increasing the degree of whiteness in finished polyvinyl chloride foam. The resin compositions contain sulfur compounds selected from sulfonic acid derivatives, sulfinic acid derivatives, and mercapto acetic acid sodium salt, and optionally contain water soluble salts and/or t-butyl hydroperoxide.Type: GrantFiled: January 21, 2003Date of Patent: August 19, 2003Assignee: Occidental Chemical CorporationInventors: Michael T. Moran, Thomas E. Moses, Sherry Rohn Clancy
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Patent number: 6586509Abstract: A composition for an insulating layer of an electric cable wherein the composition contains an ethylene plastic as the base resin and further contains up to about 5% by weight of additives including antioxidant, and peroxide cross-linking agent. The composition is characterised in that the antioxidant additive includes a compound of the formula (V): R1(—(C+O)O—)k(CH2)1—S—(CH2)m(—OO(C═O)—)nR2 where R1 and R2, which are the same of different, are C7-C23 alkyl, C7-C23 alkenyl, R3—Ar—, Ar—R3—, or AR—, where R3 is C8-C24 alkyl and Ar is c6-c14 aryl; k and n, which are the same of different, are 0 or 1, l and m, which are the same or different, are integers ≧0; with the proviso that the compound is free from phenolic groups; and that the compositions is free from compounds having the formula (VI): R—O—(C═O)—CH2CH2SCH2CH2—(C═O)—O—R where R is a C8-C20 alkyl group.Type: GrantFiled: December 26, 2000Date of Patent: July 1, 2003Assignee: Borealis Technology OyInventors: Jan-Ove Boström, Ruth Dammert, Bill Gustafsson, Annika Smedberg
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Publication number: 20030032685Abstract: The invention relates to articles of manufacture, such as for example, tires and industrial products, which have at least one component comprised of a rubber composition which contains particles of pre-sulfur vulcanized rubber (e.g. ground recycled rubber) and high purity trithiodipropionic acid, wherein said trithiodipropionic acid is preferably provided as particles of a carbon black composite comprised of carbon black and said high purity trithiodipropionic acid. Said high purity trithiodipropionic acid is comprised of polythiodipropionic acids containing at least 80 weight percent trithiodipropionic acid based upon said polythiodipropionic acids.Type: ApplicationFiled: June 29, 2001Publication date: February 13, 2003Inventors: Lawson Gibson Wideman, George Frank Balogh
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Patent number: 6506827Abstract: A rubber composition which contains the following components (A)-(D) and is free from any zinc-containing compounds that would cause trouble at the time of use of the final products: (A): an ethylene-&agr;-olefin copolymer rubber and/or ethylene-&agr;-olefin-non-conjugated diene copolymer rubber, (B): magnesium oxide, (C): carbon black, (D): at least one compound selected from the following compounds (D-1)-(D-3): (D-1): compounds containing a thio group and a carboxylic acid ester group in the molecule, (D-2): compounds containing a phenolic hydroxyl group in the molecule, (D-3): compounds containing an acyl group and an imino group in the molecule, provides vulcanized products including radiator hoses, heater hoses and radiator packings with improved age resistance.Type: GrantFiled: March 8, 2001Date of Patent: January 14, 2003Assignee: Sumitomo Chemical Company, LimitedInventor: Sadayuki Nakano
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Publication number: 20020052436Abstract: The present invention provides a racing tire tread rubber composition which is used for producing a racing tire having excellent wet grippability and does not cause any excessive adhesion in tire production process steps such as kneading and extruding steps. The racing tire tread rubber composition is a composition comprising: 100 parts by weight of a diene-based rubber; a filler, the entirety of which is in the range of 100 to 250 parts by weight containing 20 parts by weight or more of silica; and 5 to 50 parts by weight of a factice.Type: ApplicationFiled: September 17, 1997Publication date: May 2, 2002Inventors: NOBORU WAKABAYASHI, TORU IIZUKA
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Patent number: 6362264Abstract: Disclosed is a composition of matter which provides heat and color stability to polyvinyl chloride resins, especially of the flexible type, said composition consists essentially of (A) about 10 to about 40 parts by weight of a zinc carboxylate; (B) about 50 to about 80 parts by weight of an alkyl ester of thiodipropionic acid; and (C) abqut 5 to about 20 parts by weight of a phenolic antioxidant. A PVC resin containing the above composition of matter is also disclosed.Type: GrantFiled: December 20, 1996Date of Patent: March 26, 2002Assignee: CK Witco CorporationInventor: Kook Jin Bae
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Patent number: 6342549Abstract: Cycloolefin resin pellets of the present invention comprises a cycloolefin resin pellet and a powdery coating material and/or a liquid coating material, the melting point or the glass transition point of the coating material being 200° C. or lower, and the coating material being adhered onto the surface of the cycloolefin resin pellets, so that the molded product thereof is excellent in transparency.Type: GrantFiled: January 5, 1996Date of Patent: January 29, 2002Assignees: Mitsui Chemicals, Inc., Ticona GmbHInventors: Toshiyuki Hirose, Yohzoh Yamamoto, Toshio Kimura, Shinji Osato
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Publication number: 20010031816Abstract: A rubber composition which contains the following components (A)-(D) and is free from any zinc-containing compounds that would cause trouble at the time of use of the final products:Type: ApplicationFiled: March 8, 2001Publication date: October 18, 2001Inventor: Sadayuki Nakano