Oh Group, E.g., Ether-alcohol Solvent, Etc. Patents (Class 524/376)
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Patent number: 5908886Abstract: Disclosed are a method for restoring a water-soluble quenching medium being used, of which the cooling characteristics have been deteriorated during use, to its original condition to have nearly the original cooling characteristics which the fresh medium has before use, and a water-soluble quenching medium thus restored to its original condition to have nearly the original cooling characteristics thereof. The method comprises adding to a quenching bath being used an aqueous solution comprising a water-soluble polymer (B) that has a larger weight average molecular weight than that of the water-soluble polymer (A) existing in the fresh water-soluble quenching medium to be in the fresh bath.Type: GrantFiled: February 4, 1997Date of Patent: June 1, 1999Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hitoshi Uchida, Eiichi Nakamura
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Patent number: 5900459Abstract: A method of improving the release and antideposition characteristics of a hard impermeable surface. A hard impermeable surface is coated with a film of an aqueous solution. The solution is formed by combining (i) a dimer of at least two alkoxy functional silanes, (ii) an aqueous silicone emulsion of a polydiorganosiloxane, and (iii) water. The film is allowed to dry on the hard impermeable surface or the film can be wiped to dryness. The solution may also contain a water soluble hydrophilic solvent such as propylene glycol.Type: GrantFiled: February 24, 1994Date of Patent: May 4, 1999Assignee: Dow Corning CorporationInventors: David Brian Selley, Dipak Narula, Anh Be
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Patent number: 5889079Abstract: An antislipping composition for a fastener having a head portion, comprising a crosslinked polymer prepared by the polymerization of an olefinic unsaturated carboxylic acid and a compound represented by a general formula (1) given below ##STR1## where R is a hydrogen atom or a methyl group, and the sum of 1, m and n is larger than 0 and not larger than 500, except that where R is a hydrogen atom and n is zero, l+m is not 1, a liquid medium containing at least one compound selected from the group consisting of glycol ethers and glycerin, and silicon carbide particles having acute corner portions.Type: GrantFiled: November 21, 1997Date of Patent: March 30, 1999Assignee: Konishi Co., Ltd.Inventors: Kenji Idemoto, Shigeru Nagasawa, Kenji Ueji, Kunihiko Asano, Toshiyuki Uenoyama
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Patent number: 5888279Abstract: An asphalt release agent for preventing hot road asphalt, especially polymer-modified asphalt, from sticking to surfaces of delivery truck beds is provided. The release agent includes a water-based mixture of polycycloaliphatic amines and polyalkylene glycols. The release agent is applied onto the truck beds to create a slippery non-stick surface so that the road asphalt which comes in contact with such truck bed surfaces will not adhere.Type: GrantFiled: August 6, 1998Date of Patent: March 30, 1999Assignee: Morton International, Inc.Inventors: Steven Todd Salmonsen, Michael Dean Frailey, James Joseph Proctor, Lawrence Paul Krantz, Susan Marie Crooks
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Patent number: 5886076Abstract: A polymer comprising styrene or substituted-styrene and carboxylated monomer is prepared by a solution polymerization process, comprising first a polymerization step, followed by a neutralization step, and then a distillation step. The polymers have relatively low molecular weights, generally below about 10,000, and can have higher styrene content than has hither been possible. The polymers are found to have good soil release properties and so to be particularly useful in cleaning compositions for fabric or hard surface cleaning.Type: GrantFiled: December 4, 1996Date of Patent: March 23, 1999Assignee: National Starch and Chemical Investment Holding CoporationInventors: Paul T. Kimpton, Robert W. Hodgetts
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Patent number: 5886073Abstract: Redistribution of polycarbonate compositions is effected in the presence of a tetraorganophosphonium hydroxide as catalyst and a catalyst decomposing amount of a polyhydroxyaliphatic compound such as glyceryl monostearate, pentaerythritol or ethylene glycol. Catalyst decomposition after redistribution improves the stability of the redistributed polycarbonate composition.Type: GrantFiled: November 3, 1997Date of Patent: March 23, 1999Assignee: General Electric CompanyInventors: Patrick Joseph McCloskey, David Michel Dardaris
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Patent number: 5877245Abstract: The reaction product ofA) a linking compound of formula IR.sup.1 (X).sub.3 (I)wherein each X group is a halogen or one X group is a halogen and two X groups with 2 carbon atoms from the R.sup.1 group and an oxygen atom form an epoxy group, and R.sup.1 is an alkanetriyl group containing from 3 to 10 carbon atoms;B) a compound of formula IIR.sup.2 (OA).sub.n --OH (II)wherein R.sup.2 is an aliphatic group containing from 4 to 36 carbon atoms, n is a number of from 1 to 200, and each OA group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group; andC) a compound of formula IIIH--(OA).sub.m --OH (III)wherein OA is as defined above, and m is a number of from 1 to 500;processes for its preparation; and methods for its use as a thickener in aqueous compositions.Type: GrantFiled: August 15, 1997Date of Patent: March 2, 1999Assignee: Henkel CorporationInventors: Michael S. Wiggins, David I. Devore
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Patent number: 5872164Abstract: A process is provided for preparing a resin composition for coloring which comprises the steps of a phase replacement and dehydration of a pigment (a); water (b); a thermoplastic resin (c), an aqueous dispersion or solution of a thermoplastic resin (d) or an aqueous compound (e) in a twin screw extruder. Also, there is provided a resin composition for coloring prepared by such a process. It is possible to efficiently manufacture a resin composition for coloring (master batch) which has excellent pigment dispersibility and which is capable of uniform coloring without causing color unevenness.Type: GrantFiled: September 19, 1997Date of Patent: February 16, 1999Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Masashi Koide, Yasuaki Machida, Junichi Suzuki
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Patent number: 5859121Abstract: Disclosed herein is a stable aqueous dispersant solution containing a high concentration of an EO/PO nonionic block copolymer incapable of liquid phase continuity at ambient temperatures, and a formulation and processing approach providing an effective combination of an anionic dispersant with a water miscible solvent in an aqueous system that allows the feasible production of a dispersant solution containing a high concentration of EO/PO nonionic block copolymer.Type: GrantFiled: July 17, 1997Date of Patent: January 12, 1999Assignee: Bayer CorporationInventor: John W. Brandriff
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Patent number: 5856376Abstract: A tire puncture sealant containing water in an amount of from about 6% to about 64% by weight; ethylene glycol in an amount of from about 36% to about 94%; styrene butadiene latex in an amount of about 3%; polyethylene powder and ground rubber in an amount from about 3% to about 6%; a minor effective amounts of an alkali metal carbonate, a cellulosic thickener, an alkali metal nitrite and a corrosion inhibitor. The polyethylene powder and ground rubber are preferably surface-activated and include various particle sizes.Type: GrantFiled: March 3, 1997Date of Patent: January 5, 1999Assignee: NCH CorporationInventor: Daniel W. Wong
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Patent number: 5849825Abstract: The invention relates to a process for increasing the proportion of components which are non-volatile under processing conditions, in basecoat compositions containing predominantly organic diluents or solvents, for the production of multicoat finishes, preferably metallic finishes. In the process according to the invention, up to 10% by weight of the components which are volatile under processing conditions, are replaced by an aliphatic polyether or by mixtures of aliphatic polyethers, the aliphatic polyethers having a mean molecular weight of not less than 300, containing not less than one hydroxyl group per molecule and being liquid under normal conditions.Type: GrantFiled: June 7, 1995Date of Patent: December 15, 1998Assignee: BASF Lacke & Farben AktiengesellschaftInventors: Rudolf Renz, Bodo Muller, Willy Vesper
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Patent number: 5840789Abstract: The present invention relates to aqueous compositions having pH of less than or equal to about 11 and which contain a thickening amount of an acrylate-based rheology modifier, which modifier contains an emulsion which is prepared by single-stage emulsion polymerization of a C.sub.2 -C.sub.6 alkyl ester of acrylic acid and/or a C.sub.1 -C.sub.6 alkyl ester of methacrylic acid, a monomer chosen from a vinyl-substituted heterocyclic compound containing at least one of a nitrogen or sulfur atom, (meth)acrylamide, a mono- or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylate, a mono or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylamide, and optionally cross-linking monomers and/or associative monomers, in the presence of water, a first surfactant, a free-radical initiator and an alcohol selected from C.sub.2 -C.sub.Type: GrantFiled: August 13, 1997Date of Patent: November 24, 1998Assignee: National Starch and Chemical Investment Holding CorporationInventors: Daniel W. Verstrat, Milagros C. Barron
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Patent number: 5821298Abstract: Incorporating highly ethoxylated molecules into the traditional aqueous wax emulsion results in significant improvement in formulation compatibility between the aqueous wax emulsion and the water borne urethane dispersions as evidenced by the increase in formulation clarity and stabilityType: GrantFiled: February 20, 1996Date of Patent: October 13, 1998Inventors: Michael A. Reynolds, Lawrence P. Novack
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Patent number: 5804628Abstract: Elastomer films in which active chemical substances such as anticorrosive agents, lubricants or medications such as biocides are uniformly dispersed in the form of liquid droplets, process for their preparation and their applications.Stable emulsions comprising a continuous phase made up of a solution of elastomer in an organic solvent and a disperse phase including at least one active chemical substance in a solvent which is not miscible with the solution of elastomer, which are capable of being converted into elastomer films, and process for their preparation.The said elastomer film includes a dispersion of droplets of a solvent b which is not miscible with the elastomer, laden with at least one active chemical substance, which dispersion is stabilized by a block or graft copolymer comprising polyB blocks which are miscible with the said droplets and polyA blocks which are not miscible with these droplets.Type: GrantFiled: November 6, 1995Date of Patent: September 8, 1998Assignee: HutchinsonInventors: Rene Guy Busnel, Andre Cheymol, Gerard Riess
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Patent number: 5783303Abstract: A low VOC curable water-based coating composition is provided. The composition includes a urethane/acrylic copolymer having a Tg of greater than about 50.degree. C., a polyoxyethylene aryl ether plasticizer, an alkaline-stable crosslinker, and water, wherein the curable water-based coating composition includes less than about 5 wt-% volatile organic compounds, based on the total weight of the composition.Type: GrantFiled: January 31, 1997Date of Patent: July 21, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventor: Alexander C. Tsuei
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Patent number: 5767172Abstract: Water base ink compositions for directly filling in a ball-point pen comprising a dyestuff in the range of 3% to 10% by weight; a humectant in the range of 10% to 40% by weight; thixotropic agent in the range of 0.6% to 1.0% by weight, being composed of a cross-linkable acrylic acid polymer having a molecular weight ranging from 2,000,000 to 6,000,000; and water as a balance the water base ink compositions have no spinnability, tackiness tendency and possibility of drippings and runnings from a pen-point, and can be directly filled into a ball-point pen.Type: GrantFiled: June 6, 1996Date of Patent: June 16, 1998Assignee: Kabushiki Kaisha PilotInventor: Teruaki Fukasawa
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Patent number: 5753738Abstract: This invention relates to aqueous resin formulations comprising as cosolvent an alkoxy ethoxyethanol which (i) has 4-8 carbon atoms in the alkoxy group, (ii) has a boiling point at atmospheric pressure within the range from 200.degree. to 350.degree. C. and (iii) in mixtures with n-heptane in the ratio of 30:70 by weight respectively has specific miscibility characteristics. The cosolvent acts either as a solvent or coalescing aid in aqueous formulations used as coatings and paints.Type: GrantFiled: December 22, 1995Date of Patent: May 19, 1998Assignee: BP Chemicals LimitedInventors: Richard George Chapman, Nicholas John Hazel, Nevin John Stewart, Stephen Paul Goodwin, Andrew Richard Lucy
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Patent number: 5750613Abstract: This invention relates to aqueous, crosslinkable binder dispersions which have a low solvent content and contain hydroxy-functional polyethers, hydroxy-functional acrylate copolymers and hydroxy- and carboxy-functional acrylate copolymers, to a process for the production of these binders, to one and two-component binder compositions containing these binders and to the use of the binder compositions in coating compositions.Type: GrantFiled: July 30, 1996Date of Patent: May 12, 1998Assignee: Bayer AktiengesellschaftInventors: Harald Blum, Armin Sickert, Wieland Hovestadt
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Patent number: 5738843Abstract: This present invention is a composition for making artificial fingernails which is non-yellowing, and which polymerizes rapidly during use, and a method of making such composition, as well as a method of using the composition in the formation of artificial fingernails. Compositions of this invention comprise a liquid binder portion containing one or more monomeric methacrylate esters; optionally one or more di-, tri-, or multi-functional methacrylate esters, an alcohol, and a tertiary amine accelerator; a polymeric filler portion containing a finely divided polymer, and an organic peroxide polymerization initiator. The compositions of the present invention will polymerize in from about 120 seconds to about 360 seconds, resulting in a hard and resilient non-yellowing polymer.Type: GrantFiled: March 17, 1997Date of Patent: April 14, 1998Assignee: OPI Products, Inc.Inventor: Robert Eric Montgomery
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Patent number: 5723524Abstract: A composition for preventing or retarding the formation of gas hydrates or for reducing the tendency of gas hydrates to agglomerate, during the transport of a fluid comprising water and a hydrocarbon, through a conduit, comprising, (a) a polymer or copolymer selected from a terpolymer of vinyl pyrrolidone, vinyl caprolactam and an ammonium derivative monomer having from 6 to 12 carbon atoms, selected from the group consisting of dialkyl aminoalkyl methacrylamide, dialkyl dialkenyl ammonium halide and a dialkylamino alkyl acrylate or methacrylate, a copolymer of vinyl pyrrolidone and vinyl caprolactam, and a homopolymer of vinyl caprolactam, and (b) a low molecular weight glycol ether containing an alkoxy group having at least 3 carbon atoms.Type: GrantFiled: November 6, 1996Date of Patent: March 3, 1998Assignee: ISP Investments Inc.Inventors: Jeffrey M. Cohen, Philip F. Wolf, William D. Young
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Patent number: 5721306Abstract: Intercalates formed by contacting the layer material, e.g., a phyllosilicate, with an intercalant polymer to sorb or intercalate the polymer between adjacent platelets of the layered material. Sufficient intercalant polymer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 50 .ANG. (as measured after water removal to a maximum of 5% by weight water), up to about 100 .ANG. and preferably in the range of about 10-45 .ANG., so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex is combined with an organic liquid into an unexpectedly viscous carrier material, for delivery of the carrier material, or for delivery of an active compound, e.g., a pharmaceutical, or cosmetic, or lubricant, e.g., food guide lubricants dissolved or dispersed in the carrier material. Alternatively, the intercalated complex can be exfoliated prior to combination with the organic liquid.Type: GrantFiled: September 8, 1995Date of Patent: February 24, 1998Assignee: AMCOL International CorporationInventors: Semeon Tsipursky, Gary W. Beall, Anatoliy Sorokin, Anatoliy Goldman
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Patent number: 5719222Abstract: A water-based synthetic adhesive is composed of the thermosetting acrylic resin and the thermoplastic resin, which are bonded together by an interfacial agent in the presence of water. The adhesive is further composed of an acidic swelling agent capable of causing the adhesive to form a number of air-permeable pores when the adhesive is subjected to heat. The adhesive is still further composed of a consistency promoting agent to facilitate the application of the adhesive. A method for making the water-based synthetic adhesive includes a step in which a mixture containing water and the thermoplastic resin powder is formed. An interfacial agent and the thermosetting acrylic resin are added to the mixture before the mixture is stirred slowly at a predetermined temperature under at least one atmospheric pressure for a predetermined time so that the mixture becomes a paste, which is then subjected to a high-speed grinding at a low temperature for a predetermined period.Type: GrantFiled: February 8, 1996Date of Patent: February 17, 1998Inventor: Der-Shyan Chen
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Patent number: 5710207Abstract: A method of using compositions as foam regulators for water-based systems with a tendency to foam is provided. The method employs a block copolymer containing ester groups corresponding to general formula (I):A--(CH.sub.2 CH.sub.2 O).sub.n --B (I)in which n is an integer of 4 to 300, A is an optionally polymeric hydroxycarboxylic acid function and B is hydrogen, an alkyl or alkenyl radical containing 1 to 22 carbon atoms, a phenyl or benzyl radical or has the same meaning as A. Also provided is a granular free-flowing foam regulating formulation which contains 0.5% by weight to 30% by weight of the block copolymer containing ester groups adsorbed onto from 70% by weight to 99.5% by weight of a granular, substantially inorganic phosphate-free support material.Type: GrantFiled: April 10, 1996Date of Patent: January 20, 1998Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Moller, Ulrich Eicken, Herbert Fischer, Horst-W. Wollenweber, Wolfgang Gress, Christian de Haut, Ulrike Mahler, Manfred Gorzinski, Hans-Jurgen Sladek
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Patent number: 5705551Abstract: The cuttability of elastomeric pressure-sensitive adhesives, particularly of hot-melt tackified mutually immiscible elastomers, is improved by the addition of surfactants containing polyethylene-oxide and polypropylene-oxide blocks.Type: GrantFiled: June 20, 1994Date of Patent: January 6, 1998Assignee: Avery Dennison CorporationInventors: Yukihiko Sasaki, Jesse C. Ercillo
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Patent number: 5700857Abstract: A polyester resin composition made of a polyester resin containing a polyalkylene oxide soft segment component, a plasticizer, a crystallization promoter, and a brominated flame retardant is developed, said composition having good flame resistance and mechanical properties.Type: GrantFiled: June 25, 1996Date of Patent: December 23, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Atsushi Mukohyama
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Patent number: 5700386Abstract: The subject invention involves processes for making granular compositions comprising soil release polymers, the polymers comprising at least about 10% of substantially linear esters having a backbone; the esters being uncapped or end-capped on one or both ends of the backbone; the esters comprising in their backbones oxyalkyleneoxy units and hydrophobic aryldicarbonyl units; the esters having a molecular weight of from about 500 to about 20,000; the polymers if in solid state having the tendency when exposed to moisture to spontaneously rearrange from an amorphous form which is readily soluble in water to a crystalline form which is relatively insoluble in water; the process comprising the following steps:a) taking the soil release polymers, in which are dispersed from 0% to about 25% alkylaryl or alkyl sulfonate crystallization-reducing stabilizers, in molten state at a temperature of at least about 180.degree. C.Type: GrantFiled: August 8, 1996Date of Patent: December 23, 1997Assignee: The Procter & Gamble CompanyInventors: Benjamin Edgar Chapman, Michael Timothy Creedon
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Patent number: 5696192Abstract: A polyoxyalkylene-modified organopolysiloxane that generates almost no odor with the passage of time, and a method for preparation of the polyoxyalkylene-modified organopolysiloxane. This organopolysiloxane bears polyoxyalkylene bonded to silicon across alkylene, and contains 5-1,000 ppm by weight of an antioxidant. It also has a peroxide value not exceeding 5 meq/kg, and a total content of aldehyde plus ketone not exceeding 100 ppm.Type: GrantFiled: November 15, 1996Date of Patent: December 9, 1997Assignee: Dow Corning Toray Silicone Co., Ltd.Inventor: Asao Harashima
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Patent number: 5684074Abstract: The invention provides a novel coating composition comprising a first component (i.e. 100 parts by weight of a fluorine-containing copolymer), a second component (i.e. 0.1-20 parts by weight of an alkyl silicate), and a third component (i.e. 0.05-3 parts by weight of a water-soluble polyether-modified silicone oil and/or 1-25 parts by weight of a polyoxytetramethylene glycol). The fluorine-containing copolymer has a hydroxyl value of 80-200 mg KOH per 1g thereof and is prepared by copolymerizing 40-65 mol % of a fluoroolefin, 14-50 mo1% of a copolymerizable vinyl-containing compound, 12-25 mol % of a polymerizable hydroxyl-containing compound, and 0.1-12 mol % of at least one other copolymerizable compound. A cured coated film prepared from the coating composition is superior in elasticity and weathering and stain resistances.Type: GrantFiled: October 25, 1995Date of Patent: November 4, 1997Assignee: Central Glass Company, LimitedInventors: Yoshi Hirashima, Kazuhiko Maeda, Kentaro Tsutsumi
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Patent number: 5663217Abstract: An ink jet ink especially for printing on to plain paper comprises a suspension in (a) non aqueous solvent of (b) a disperse phase comprising: (i)) a water-insoluble dyestuff which is insoluble in said solvent at the ink jet operating temperature and below; (ii) a water insoluble resinous dispersant for the dyestuff which in the amount used is capable of forming a solution in the said solvent at the ink jet operating temperature, (iii) a polymer binder to hold the dyestuff on the surface of the paper.Type: GrantFiled: July 9, 1993Date of Patent: September 2, 1997Assignee: XAAR LimitedInventor: Jurgen M. Kruse
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Patent number: 5661206Abstract: An admixture for modifying the fluidity of a cementitious mixture comprises a cement-dispersing agent which is an aqueous solution of polymer, in which solution an oxyalkylene-based defoaming agent is dissolved or dispersed in particles of no greater that 20 .mu.M diameter. The polymer is preferably a polymer which comprises units derived from unsaturated carboxylic acid monomer and the polymer is preferably prepared in the presence of the defoaming agent. Particular addition copolymers give particularly good results. The admixture permits good control of the fluidity of cementitious compositions and has extended shelf life.Type: GrantFiled: December 21, 1995Date of Patent: August 26, 1997Assignees: MBT Holding AG, Nippon Shokubai Co., Ltd.Inventors: Yoshio Tanaka, Akira Ohta, Hideyuki Tahara, Tsuyoshi Hirata
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Patent number: 5660178Abstract: A hydrophilic, pressure sensitive adhesive of a poly(ethylene oxide) derived network plasticized with an essentially non-volatile, polar plasticizer present in an amount sufficient to form a cohesive, pressure sensitive adhesive. The polymeric network is prepared from an oligomeric precursor comprising difunctional poly(ethylene glycol) moieties which have been end-capped with ethylenically unsaturation. The adhesive is useful as a biomedical adhesive for transmitting or receiving electrical signals as a component of a biomedical electrode. The adhesive is also useful as a drug delivery device to deliver pharmaceuticals or other active ingredients to or through mammalian skin. The adhesive is also useful as a component in a skin covering for protecting mammalian skin or mammalian skin openings with antimicrobial agents. A method of preparation of the adhesive is also disclosed.Type: GrantFiled: January 5, 1996Date of Patent: August 26, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Steven S. Kantner, Nancy J. Rustad, James S. Stefely
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Patent number: 5661205Abstract: A method for producing a polychloroprene latex, which comprises copolymerizing chloroprene and an ethylenically unsaturated carboxylic acid in the presence of a polyvinyl alcohol, wherein a glycol ether is also present during the copolymerization.Type: GrantFiled: January 18, 1996Date of Patent: August 26, 1997Assignees: Denki Kagaku Kogyo Kabushiki Kaisha, Konishi Co., Ltd.Inventors: Mikitoshi Satoh, Masao Koga, Shigeru Nagasawa, Kunihiko Asano, Toshiyuki Uenoyama, Kunihiro Onishi
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Patent number: 5652289Abstract: A method for making a polymer, includes the step of polymerizing a mixture of a vinyl ester monomer, a (C.sub.1 -C.sub.12)alkyl (meth)acrylate monomer and a mono ethylenically unsaturated polar monomer by free radical initiated polymerization in an aqueous medium and in free presence of a colloidal stabilizer, a first poly(alkoxylated) alkyl phenol having less than or equal to 12 alkoxyl units per molecule and a second poly(alkoxylated) alkyl phenol having greater than 12 alkoxyl units per molecule, to form an emulsion of the polymer in the aqueous medium.Type: GrantFiled: October 11, 1995Date of Patent: July 29, 1997Assignee: Rohm and Haas CompanyInventors: Eric Karl Eisenhart, Bradley Anson Jacobs
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Patent number: 5643992Abstract: A water-based pressure sensitive adhesive formulation is provided with one or more high molecular weight linear aliphatic polymers. The resulting composition can be used to form stable filaments or delivered from the coating die of a premetered coater in the form of a stable sheet at a flow rate substantially less than the minimum delivery flow rate achievable using the formulation without polymer. Low levels of polymer can provide dramatic improvement in the viscosity of such compositions, without detrimental effect on the adhesive and other desireable qualities of the composition.Type: GrantFiled: June 2, 1995Date of Patent: July 1, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventor: Paul J. Northey
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Patent number: 5643669Abstract: A low VOC curable water-based coating composition is provided. The composition includes a urethane/acrylic copolymer having a Tg of greater than about 50.degree. C., a polyoxyethylene aryl ether plasticizer, an alkaline-stable crosslinker, and water, wherein the curable water-based coating composition includes less than about 5 wt-% volatile organic compounds, based on the total weight of the composition.Type: GrantFiled: February 8, 1996Date of Patent: July 1, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventor: Alexander C. Tsuei
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Patent number: 5637387Abstract: The present invention relates to storage-stable advanced polymaleimide compositions and prepreg products manufactured therefrom comprising (A) an advanced polymaleimide reaction product resulting from the advancement reaction of a polyimide and an alkenyl phenol; and (B) a phenothiazine added to component (A) after advancement.Type: GrantFiled: June 2, 1995Date of Patent: June 10, 1997Assignee: Ciba-Geigy CorporationInventors: Benjamin G. Chin, Roger Tietze
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Patent number: 5624987Abstract: This invention relates to a polyester composition comprising a blend of:(A) 99.5 to 75 weight % of a copolyester having an inherent viscosity of 0.1 to 1.2 dL/g and having a melting point in excess of 250.degree. C., comprising:(a) one or more dicarboxylic acids, and(b) a glycol component comprising at least 80 mole % 1,4-cyclohexanedimethanol; and(B) 0.5 to 25 weight % of one or more polyalkylene ethers,wherein the weight percentages of all components in said blend total 100 weight %.Type: GrantFiled: September 15, 1995Date of Patent: April 29, 1997Inventors: Andrew E. Brink, Sam R. Turner, Gerald T. Keep
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Patent number: 5610215Abstract: An aqueous emulsion coating composition exhibiting a viscosity of at least 20 centipoise, containing a binder with a molecular weight of preferably at least 50,000, and more preferably, greater than 500,000, and a glass transition temperature of at least 10.degree. C., and a filler, wherein the binder is present in about 20 parts to about 50 parts by weight and the filler up to about 60 parts by weight. The composition also contains effective amounts of one or more additives consisting of coalescents, humectants, thickeners, surfactants and defoamers. The composition is particularly well suited to application to substrates common to the hobby, modeling and toy industry. Generally, it is preferred to apply the hobby/modeling composition via an air brush and allow the coating to cure at temperatures at least 13.degree. C. for as long as one week to generate the maximum obtainable properties.Type: GrantFiled: November 24, 1993Date of Patent: March 11, 1997Assignee: Gregory A. KonradInventors: Mark A. Nonweiler, Gregory F. Konrad, Dennis A. Wiatrowski
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Patent number: 5605949Abstract: An improved latex composition is provided that has been found to exhibit a superior ability to form a substantially uniform polymeric film when applied to a substrate. The composition is capable of being handled and applied to a substrate in the absence of excessive foaming. The aqueous composition includes as essential components specified concentrations of a specifically-defined normally liquid predominantly hydrophobic nonionic alcohol ethoxylate surfactant, and a solely hydrophobic defoaming agent (e.g., a hydrocarbon-based mineral oil). It is possible for the composition to be applied even to a hydrophobic substrate (e.g., a polyester film substrate). Compositions of the present invention, following application to a substrate and the volatilization of the water component, form a substantially uniform polymeric film that can serve as a coating or adhesive.Type: GrantFiled: October 11, 1994Date of Patent: February 25, 1997Assignee: BASF CorporationInventors: Michael J. Anchor, Rebecca P. Hollis, Gregory W. Drewno
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Patent number: 5603924Abstract: This present invention is a composition for making artificial fingernails which is non-yellowing, and which polymerizes rapidly during use, and a method of making such composition, as well as a method of using the composition in the formation of artificial fingernails. Compositions of this invention comprise a liquid binder portion containing one or more monomeric methacrylate esters; optionally one or more di-, tri-, or multi-functional methacrylate esters, an alcohol, and a tertiary amine accelerator; a polymeric filler portion containing a finely divided polymer, and an organic peroxide polymerization initiator. The compositions of the present invention will polymerize in from about 120 seconds to about 360 seconds, resulting in a hard and resilient non-yellowing polymer.Type: GrantFiled: August 4, 1995Date of Patent: February 18, 1997Assignee: OPI Products, Inc.Inventor: Robert E. Montgomery
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Patent number: 5599863Abstract: Provided are methyl methacrylate polymers admixed with particular polyalkylene glycols, ethers or esters, optionally with BHT, which show good chemical resistance, as well as maintenance of optical properties and minimal yellowing on exposure to sterilizing gamma radiation.Type: GrantFiled: June 17, 1994Date of Patent: February 4, 1997Assignee: Cyro IndustriesInventor: Daniel Zimmerman
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Patent number: 5585459Abstract: A process for producing raw rubber from a deproteinized natural rubber is disclosed, which comprises coagulating rubber particles in the deproteinized natural rubber latex by: (1) adding a nonionic surfactant having a cloud point of from 20.degree. to 100.degree. C. and a molecular weight of 300 or more to the deproteinized natural rubber latex and heating the latex to a temperature not lower than the cloud point of the nonionic surfactant; or (2) adding a coagulation assistant selected from the group consisting of: (a) an anionic surfactant, (b) an amphoteric surfactant, (c) a nonionic surfactant, (d) a nonionic or amphoteric oligomer or polymer, and (e) an anionic oligomer or polymer, to the deproteinized natural rubber latex; and then recovering the coagulated rubber particles. According to the process of the present invention, raw rubber containing substantially no metal ion can be produced with a high efficiency.Type: GrantFiled: May 12, 1994Date of Patent: December 17, 1996Assignees: Kao Corporation, Sumitomo Rubber Industries, Ltd.Inventors: Yasuyuki Tanaka, Yuichi Hioki, Masaharu Hayashi, Naoya Ichikawa, Toshiaki Sakaki
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Patent number: 5585189Abstract: The present invention discloses a pigment dispersion composition for depositing a multiplicity of pores existing in anodic oxide films formed on a surface of an aluminum or aluminum alloy material by way of electrophoresis for coloration, the pores being preliminarily enlarged to have a diameter of 50 nm to 250 nm. The pigment dispersion composition comprises water, a pigment dispersant and a pigment. The pigment dispersed in the pigment dispersion composition has a median particle size of not greater than 250 nm in a particle-size distribution thereof with not greater than 30% of the pigment particles being impassable through a sieve having a mesh size of 300 nm. The pigment dispersion composition is useful for coloration of the anodic oxide films, and has excellent repeated-coloration characteristics.Type: GrantFiled: May 26, 1995Date of Patent: December 17, 1996Assignee: Sakura Color Products CorporationInventors: Hiroshi Inoue, Shigeyasu Inoue, Seishiro Ito
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Patent number: 5576378Abstract: Polymers with a high glass transition temperature are used in cement additives to produce a portland cement mortar or concrete that does not have the initial stickiness typical of prior art polymer-modified portland cement compositions and does not form a crust on the surface when exposed to air drying, thus improving the working time of the mix. This simplifies equipment cleaning and permits the use of transit mixers for field applications of polymer-modified concrete. The properties of the mortar and concrete modified with these materials, both in the plastic and hardened state, are equivalent or superior to those of the currently available products which use film-forming materials. Within the scope of this invention are a redispersible powdered cement additive, a redispersible polymer powder and a ready-to-use portland cement composition, as well as related processes.Type: GrantFiled: February 24, 1994Date of Patent: November 19, 1996Assignee: The Dow Chemical CompanyInventors: Louis A. Kuhlmann, James W. Young, Jr., Daniel Moldovan
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Patent number: 5574081Abstract: This invention relates to a paint composition comprising a clay-containing pigment system, a latex binder, a polysaccharide thickener, and 0.005% to 2%, based upon the weight of the pigment, of a blocking agent which serves to prevent more than 20% of the polysaccharide thickener from being adsorbed onto the clay pigment surface, whereby the paint composition exhibits improved appearance and application performance.Type: GrantFiled: October 11, 1994Date of Patent: November 12, 1996Assignee: Aqualon CompanyInventor: Gijsbert Kroon
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Patent number: 5571567Abstract: Dip molding of thermoplastic polyurethane elastomers to form medical and surgical gloves, condoms, instrument and appliance covers, and other rubber goods is improved by a controlled viscosity, controlled rate of evaporation solvent system, including a strong polar solvent, a weak solvent or non-solvent to control viscosity, and a blush resistor to control the rate of evaporation and the effects of humidity. For particularly enhanced barrier film formation, a leveling agent is also included. One or more layers are dipped in sequential steps in thicknesses of 0.5 to 1.5 mils per layer, with complete integral film formation and substantially complete freedom from porosity and pin holes. Cross-linkable polyurethanes may be cured after fully molded.Type: GrantFiled: June 7, 1995Date of Patent: November 5, 1996Assignee: Polygenex International, IncInventor: Tilak M. Shah
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Patent number: 5554673Abstract: Dip molding of thermoplastic polyurethane elastomers to form medical and surgical gloves, condoms, instrument and appliance covers, and other rubber goods is improved by a controlled viscosity, controlled rate of evaporation solvent system, including a strong polar solvent, a weak solvent or non-solvent to control viscosity, and a blush resistor to control the rate of evaporation and the effects of humidity. For particularly enhanced barrier film formation, a leveling agent is also included. One or more layers are dipped in sequential steps in thicknesses of 0.5 to 1.5 mils per layer, with complete integral film formation and substantially complete freedom from porosity and pin holes. Cross-linkable polyurethanes may be cured after fully molded.Type: GrantFiled: November 29, 1993Date of Patent: September 10, 1996Assignee: Polygenex International, Inc.Inventor: Tilak M. Shah
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Patent number: 5554675Abstract: A composition useful in printing inks exemplified as comprising:(1) from about 4 to about 80% by weight of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from about 1.0 to about 60% by weight of pigment material;(3) from about 0.05 to about 30% by weight of a nonionic, polyether type property modifier; and(4) from substantially none to about 90% by weight of water.Type: GrantFiled: May 9, 1994Date of Patent: September 10, 1996Inventors: Gary T. Clark, John N. Rasar, Rebecca R. Stockl
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Patent number: 5552456Abstract: The invention relates to a gel used as a drag reducing slurry. The slurry stored aboard a vessel and is pumped into the region of laminar flow adjacent the vessel to reduce drag. The slurry is a thixotropic media composed of a surfactant coating the individual particles of drag reducing polymer resin as well as an anionic surfactant and a carrier liquid. The slurry forms a micelle structure and thus has an extremely long shelf life.Type: GrantFiled: August 26, 1974Date of Patent: September 3, 1996Assignee: The United States of America as represented by the Secretary of the NavyInventors: Robert F. Supcoe, Ira M. Felsen, William T. Donahue
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Patent number: 5536768Abstract: A hydrophilic, pressure sensitive adhesive of a poly(ethylene oxide) derived network plasticized with an essentially non-volatile, polar plasticizer present in an amount sufficient to form a cohesive, pressure sensitive adhesive. The polymeric network is prepared from an oligomeric precursor comprising difunctional poly(ethylene glycol) moieties which have been end-capped with ethylenically unsaturation. The adhesive is useful as a biomedical adhesive for transmitting or receiving electrical signals as a component of a biomedical electrode. The adhesive is also useful as a drug delivery device to deliver pharmaceuticals or other active ingredients to or through mammalian skin. The adhesive is also useful as a component in a skin covering for protecting mammalian skin or mammalian skin openings with antimicrobial agents. A method of preparation of the adhesive is also disclosed.Type: GrantFiled: January 5, 1996Date of Patent: July 16, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Steven S. Kantner, Nancy J. Rustad, James S. Stefely