Mixing With Carbon, E.g., Graphite, Etc., Having Numerical Limitations, Other Than Amount, E.g., Included Herein Are Particle Size, Surface Area, Etc., Or Composition Or Product Thereof, Dnrm Patents (Class 524/495)
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Patent number: 7687564Abstract: There are provided black iron-based particles comprising iron/titanium composite oxide particles having a titanium element content (A) of 5 to 35% by atom based on an iron element content contained in the black iron-based particles, and a ratio of a titanium element content (B) (based on an iron element content contained in the portion dissolved) in a portion of the black iron-based particles, which is dissolved therefrom at an iron element dissolution percentage of 1% by weight, to the titanium content (A) of not less than 1.0. The black iron-based particles of the present invention are not only excellent in dispersibility, acid resistance, tinting strength and blackness, but also exhibit a less magnetization value. Also, the black paint and the rubber or resin composition of the present invention are excellent in acid resistance and blackness.Type: GrantFiled: May 15, 2006Date of Patent: March 30, 2010Assignee: Toda Kogyo CorporationInventor: Shinji Uemoto
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Patent number: 7687565Abstract: A rubber material, in particular for wiper blades of windshield wipers or for automotive tires, is described, containing at least one grade of rubber, at least one filler and processing adjuvants. Of at least one of the grades of rubber present, the rubber material contains a first and a second fraction which differ in viscosity in the unvulcanized state.Type: GrantFiled: November 17, 2004Date of Patent: March 30, 2010Assignee: Robert Bosch GmbHInventor: Robert Geilenkirchen
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Publication number: 20100068500Abstract: Compositions comprising a plurality of carbon nanotubes, a host polymer, and A block copolymer comprising a first block and a second block, wherein no block is compatible with the host polymer. In one aspect, the block copolymer is amphiphilic. In another aspect, the block copolymer may comprise a first block and a second block, wherein at least one of the first and second blocks comprises repeating units derived from a monomer having the general formula: (R)2C?C(R)(Rf) wherein Rf is selected from fluorine, a C1 to C10 fluorinated or perfluorinated alkyl group, and a C1 to C10 fluorinated or perfluorinated alkoxy group; each R is independently selected from F, H, Cl, Rf, a C1 to C10 alkyl group, and R2A, wherein R2 is a C1 to C10 alkylene group and A is selected from CO2M and SO3M, wherein M is selected from H, an ammonium and organo onium group.Type: ApplicationFiled: March 8, 2006Publication date: March 18, 2010Inventors: James M. Nelson, Ryan E. Marx, John W. Longabach
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Publication number: 20100069558Abstract: A (per)fluoroelastomeric composition curable by peroxidic way comprising for 100 phr of (per)fluoroelastomer: as filler, from 2 to 70 phr of carbon black having a surface area between 25 and 35 m2/g; as crosslinking agent, from 0.5 to 10 phr of a bis-olefin having general formula: wherein: R1, R2, R3, R4, R5, R6, equal to or different from each other, are H or C1-C5 alkyls; Z is selected between a linear or branched C1-C18 alkylene or cycloalkylene radical, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylene radical.Type: ApplicationFiled: June 28, 2007Publication date: March 18, 2010Applicant: SOLVAY SOLEXIS S.p. A.Inventors: Milena Stanga, Giovanni Comino, Stefano Arrigoni, Margherita Albano
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Patent number: 7678855Abstract: A rubber composition having a high hysteresis loss is provided without impairment of other physical properties, such as fracture characteristics. The rubber composition includes 100 parts by weight of a rubber component, 0.1 to 100 parts by weight of graphitized carbon material, and a lipid the amount of which is 0.02 to 0.2 times the amount of the graphitized carbon material. Preferably, the graphitized carbon material is carbon fiber grown from a vapor phase or graphitized carbon black, and the lipid is a fatty acid. Preferably, the rubber composition according to the present invention has a loss tangent tan ? in the range of 0.05 to 0.5 at a temperature of 60 degree C. after vulcanization.Type: GrantFiled: August 10, 2006Date of Patent: March 16, 2010Assignee: Bridgestone CorporationInventor: Nobumitsu Ohshima
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Publication number: 20100062247Abstract: A method of preparing a silicone resin film, the method comprising coating a release liner with a nanomaterial-filled silicone composition comprising a condensation-curable silicone composition and a carbon nanomaterial, and curing the silicone resin of the coated release liner; a silicone resin film prepared according to the preceding method, and a nanomaterial-filled silicone composition.Type: ApplicationFiled: November 22, 2006Publication date: March 11, 2010Inventors: Mark Fisher, Bizhong Zhu
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Patent number: 7674402Abstract: An electroconductive resin composition, comprising at least: a multi-component polymer-type resin binder (A) comprising a dispersed phase and a continuous phase, and having a number-average particle size of dispersed phase of 0.001-2 ?m, and an electroconductive material (B) in the form of powder and/or fiber. The electroconductive resin composition may preferably be used for a fuel cell separator.Type: GrantFiled: December 3, 2004Date of Patent: March 9, 2010Assignee: Showa Denko K.K.Inventors: Tadashi Iino, Zenichiro Izumi
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Publication number: 20100056695Abstract: This invention relates to a composite ring or segment of a ring, having use as a shroud of an airplane engine, comprising about 20 to about 70 weight percent of the thermoplastic polymer and about 30 to about 80 weight percent of the carbon fiber, and having a heat deflection temperature of at least 230° C. at 1.8 MPa as determined according to ASTM D648, and which provides thermal stability and wear resistance.Type: ApplicationFiled: August 28, 2009Publication date: March 4, 2010Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: Gregory R. Alms, Martin W. Prellwitz
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Patent number: 7671126Abstract: The invention relates to a tire having a tread which contains coal dust to promote a fast wearing tread running surface designed to expel internally heated tread rubber.Type: GrantFiled: December 3, 2008Date of Patent: March 2, 2010Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Steven Wayne Cronin, Thomas Charles Lippello, III, Mark Alan Keto, Larry Alan Kraus
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Patent number: 7666939Abstract: Dispersions of carbon nanotubes exhibiting long term stability are based on a polymer matrix having moieties therein which are capable of a donor-acceptor complexation with carbon nanotubes. The carbon nanotubes are introduced into the polymer matrix and separated therein by standard means. Nanocomposites produced from these dispersions are useful in the fabrication of structures, e.g., lightweight aerospace structures.Type: GrantFiled: May 11, 2006Date of Patent: February 23, 2010Assignees: National Institute of Aerospace Associates, The United States of America as represented by the Administrator of NASAInventors: Kristopher Eric Wise, Cheol Park, Emilie J. Siochi, Joycelyn S. Harrison, Peter T. Lillehei, Sharon E. Lowther
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Patent number: 7659337Abstract: A composition suitable for an air barrier such as an automotive tire innertube, innerliner, and aircraft tire innertube or innerliner, curing bladders, and other pneumatic devices is disclosed. The composition comprises an elastomer, a processing oil, and a grafted resin component.Type: GrantFiled: October 1, 2007Date of Patent: February 9, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Glenn Edward Jones, Mun Fu Tse, Hsien-Chang Wang, Kenneth Lewtas, William Moa-Tseng Chien, Walter Harvey Waddell
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Patent number: 7652098Abstract: The present invention relates to a resin composition for GHz-band electronic components, the composition comprising nanoscale carbon tubes and at least one member selected from the group consisting of thermoplastic resins, curable resins, and composite resins of thermoplastic resins and curable resins; wherein the nanoscale carbon tubes are present in an amount of 0.0001 to 0.4 wt. % based on the resin; and an electronic component obtainable from the resin composition, or the like.Type: GrantFiled: February 2, 2005Date of Patent: January 26, 2010Assignee: Osaka Gas Co., LtdInventors: Kouichi Yamaguchi, Hidekazu Hayama, Ren-De Sun, Masahiro Yamada, Hitoshi Nishino, Yasunori Yokomichi
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Patent number: 7652097Abstract: A polymer-extruded article produced by extrusion and vulcanization of a polymeric composition includes ethylene-?-olefin-nonconjugated polyene copolymer in an amount of 100 phr; carbon black in an amount ranging from more than 50 to 120 phr, the carbon black having an arithmetic average particle diameter of not smaller than 60 nm; a softener in an amount of not more than 100 phr; and thermo-expansive capsules in an amount ranging from 1 to 10 phr. The polymer-extruded article includes a surface section having an uneven surface derived from thermal expansion of the thermo-expansive capsules, and a rough surface derived from carbon particle of the carbon black and formed at the uneven surface derived form the thermal expansion of the thermo-expansive capsules.Type: GrantFiled: March 17, 2006Date of Patent: January 26, 2010Assignee: Kinugawa Rubber Ind. Co., Ltd.Inventors: Ryoko Nonaka, Masakazu Manaka
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Patent number: 7652096Abstract: A rubber composition for a tire tread including 100 parts by weight of a diene-based rubber and 5 to 150 parts by weight of carbon black having a nitrogen adsorption specific area N2SA (m2/g) of 80 to 150 and satisfying a relationship between a TINT (%) and dibutyl phthalate absorption DBPA (ml/100 g) of TINT (%)>1.4 DBPA (ml/100 g) and capable of increasing the frictional force without impairing the hysteresis loss.Type: GrantFiled: December 3, 2003Date of Patent: January 26, 2010Assignee: The Yokohama Rubber Co., Ltd.Inventors: Naoya Amino, Yoshihisa Inoue
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Patent number: 7645400Abstract: The object of the present invention is to provide a carbon nanotube composition that does not impair the characteristics of the carbon nanotubes itself, allows the carbon nanotubes to be dispersed or solubilized in a solvent, does not cause separation or aggregation of the carbon nanotubes even during long-term storage, has superior electrical conductivity, film formability and moldability, can be easily coated or covered onto a base material, and the resulting coated film has superior moisture resistance, weather resistance and hardness; a composite having a coated film composed thereof; and, their production methods.Type: GrantFiled: October 31, 2003Date of Patent: January 12, 2010Assignee: Mitsubishi Rayon Co., Ltd.Inventor: Takashi Saitoh
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Publication number: 20100003438Abstract: A thermoplastic composite material, which includes a thermoplastic, organic polymer; and a plurality of carbon nanotubes, is provided. The thermoplastic composite material exhibits a bulk volume resistivity of about 103 ?-cm (ohm cm) to 1010 ?-cm at 5,000 volts. Such thermoplastic composite materials may find utility in applications that require the thermoplastic to be capable of withstanding high voltage spikes, as would be encountered during a lightning strike.Type: ApplicationFiled: July 2, 2008Publication date: January 7, 2010Inventors: Edward W.S. Bryant, Clifton P. Breay
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Patent number: 7640957Abstract: This invention relates to high performance tires designed for high vehicular speeds having thin treads with a maximum thickness of about three centimeters with a running surface which is comprised of a rubber composition which is highly loaded with a combination of reinforcing filler and rubber processing oil. The combination of reinforcing filler is comprised of conductive carbon black and optionally at least one of classical rubber reinforcing carbon black and precipitated silica and their mixtures. This high level of a combination of selective reinforcing filler together with rubber processing oil in the tread rubber is provided to promote a reduction in internal heat generation within the thin tread during high vehicular speeds, particularly for vehicles intended to be used as race cars.Type: GrantFiled: September 23, 2005Date of Patent: January 5, 2010Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul Harry Sandstrom
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Patent number: 7642489Abstract: The present invention relates to a flexible electrothermal composite. In one embodiment, a flexible electrothermal composite includes a flexible polymer matrix and a number of carbon nanotubes dispersed in the matrix, the carbon nanotubes forming a plurality of conductive network in the polymer. The flexible electrothermal composite has high flexibility, resistance and intensity.Type: GrantFiled: November 17, 2006Date of Patent: January 5, 2010Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Chang-Hong Liu, Shou-Shan Fan
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Publication number: 20090326140Abstract: An object is to provide a resin material having high strength and high vibration-damping property. A resin material includes a matrix resin and carbon nanocoils contained therein. The carbon nanocoils have electrical conductivity, so that the matrix resin containing them can easily convert a vibration energy generated in the resin material into heat and thereby damp the vibration energy in a short time. In addition, since the carbon nanocoil is in a coiled form, vibration-damping property can be enhanced in comparison with that of conductive materials such as carbon nanotube and graphite.Type: ApplicationFiled: June 25, 2007Publication date: December 31, 2009Inventors: Yasuhito Shimada, Yasuo Kita, Toshikazu Nosaka, Yoshikazu Nakayama, Toshiyuki Okuda
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Patent number: 7638574Abstract: This invention is based upon the discovered that crosslinked core-shell particles can be used as a filler in low cost emulsion styrene-butadiene rubber (ESBR) with excellent results being attained. In fact, such core-shell particle filled ESBR exhibits performance similar to silica filled solution styrene-butadiene rubber (SSBR) in terms of dynamic response, Payne effect, rebound and tan ? at 0° C. and 100° C. The utilization of such crosslinked core-shell particles in rubber compounds offers the additional advantage of weight reduction since the core-shell particles are significantly less dense than carbon black or silica fillers. The use of the crosslinked core-shell polymers of this invention in rubber formulations in place of silica also offers the advantage of not needing any expensive silane coupling agents to attain required levels of polymer/filler interaction. Accordingly, no silane coupling agent is used in the rubber compounds of this invention which leads to reduced cost.Type: GrantFiled: June 30, 2005Date of Patent: December 29, 2009Assignee: The Goodyear Tire & Rubber CompanyInventors: Ping Zhang, Lei Zheng, Feng Anne Xie, Eric Sean Castner
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Patent number: 7638573Abstract: The present invention provides a method to form a nanocomposite including blending a high molecular weight elastomer, a low molecular weight elastomer, and a clay to form a nanocomposite; wherein the high molecular weight elastomer has a weight average molecular weight greater than 250000; wherein the low molecular weight elastomer has a weight average molecular weight less than 150000. In another embodiment, the invention provides a method to form a nanocomposite including the steps of blending a low molecular weight elastomer and a clay to form a first mixture; blending a high molecular weight elastomer and the first mixture to form the nanocomposite; wherein the low molecular weight elastomer has a weight average molecular weight less than 150000; and, wherein the high molecular weight elastomer has a weight average molecular weight greater than 250000.Type: GrantFiled: April 7, 2006Date of Patent: December 29, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Hsien-Chang Wang, Ramanan Krishnamoorti, Mun F. Tse, Anthony J. Dias, David Y. Chung, Alan A. Galuska
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Publication number: 20090318606Abstract: It is disclosed a method for preparing a nano hybrid resin containing carbon nano materials as graphitizing agents with predetermined characteristics by formation of graphite phase in residual carbon.Type: ApplicationFiled: July 8, 2009Publication date: December 24, 2009Inventors: Mohamad Ali Sharif Sheikhaleslami, FARHAD GOLESTANIFARD, HOSSEIN SARPOOLAKY
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Publication number: 20090312480Abstract: A medical needle is made of a synthetic resin which is reinforced, including the point part of the needle, to reduce deformation during puncture, even when the needle is produced by injection molding. The needle is made of a synthetic resin composition which includes synthetic resin and reinforcing fiber having a length of 80 ?m or below and reinforcing fiber having a length exceeding 80 ?m. The number ratio of the former fiber to the whole fiber component is 40% to 90%. A synthetic resin composition for needles includes a synthetic resin and a reinforcing fiber component, wherein the composition is prepared by adding at least two kinds of fibers, namely a fiber having a mean length of 1 mm to 10 mm and a fiber having a mean length of 10 ?m to 100 ?m to the synthetic resin and kneading the obtained mixture.Type: ApplicationFiled: September 21, 2006Publication date: December 17, 2009Applicant: Terumo Kabushiki DaishaInventor: Hiromasa Kohama
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Patent number: 7632889Abstract: A cleaning blade, for use in an image-forming apparatus, formed by a molded resin composition containing a rubber component consisting of a thermosetting elastomer containing acrylonitrile as a constituent monomer thereof and having a bound acrylonitrile amount of 15 to 50%.Type: GrantFiled: September 13, 2006Date of Patent: December 15, 2009Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Mutsuki Sugimoto
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Patent number: 7632422Abstract: Carbon nanotubes, which carry surface functional groups on side walls thereof relative to lengths thereof, and a dispersant are added to a base liquid to provide a heat transport medium capable of achieving high heat conductivity while suppressing an increase in kinetic viscosity.Type: GrantFiled: February 15, 2008Date of Patent: December 15, 2009Assignees: Honda Motor Co., Ltd., GSI Creos CorporationInventors: Yoshiyuki Morita, Ayako Omori, Masanori Tomita, Masaru Ishibashi, Takashi Yanagisawa
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Patent number: 7629408Abstract: A tire tread comprising a rubber composition based on at least a diene elastomer, a reinforcing inorganic filler such as silica, an inorganic filler/elastomer coupling agent and carbon black in a very small quantity, in an amount of between 0.05 and 2.0 phr. The tires comprising such a tread have, after photo-oxidation treatment of the latter, a significantly improved grip on wet roads. Such photo-oxidizing treatment, in particular under visible UV radiation, may advantageously be performed during the manufacture of the treads or tires itself, in the uncured state or after vulcanization, or even later on in the life of said tires.Type: GrantFiled: January 20, 2006Date of Patent: December 8, 2009Assignee: Michelin Recherche et Technique S.A.Inventors: Stéphanie Cambon, Didier Vasseur
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Publication number: 20090298994Abstract: This invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a co-catalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in a field of polymers, especially that of nanotechnologies.Type: ApplicationFiled: June 10, 2009Publication date: December 3, 2009Applicant: Nanocyl S.A.Inventors: Philippe Dubois, Michael Alexandre, Daniel Bonduel, Michael Mainil
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Patent number: 7625444Abstract: Disclosed herein are carbon black surface-modified with benzene compound of Formula 1 described in the specification and a carbon black dispersion composition for a black matrix using the carbon black. The carbon black dispersion composition uses carbon black surface-modified with the benzene compound of Formula 1, or about 0.1 to about 20% by weight of a cardo compound selected from cardo monomers, oligomers, polymers and mixtures thereof. The carbon black dispersion composition can provide improved adhesive properties, uniformity and resolution of black matrix patterns, and no undercut is formed on the black matrix patterns.Type: GrantFiled: June 23, 2006Date of Patent: December 1, 2009Assignee: Cheil Industries Inc.Inventors: Kil Sung Lee, Jae Hyun Kim, Eui June Jeong, Chun Woo Lee
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Publication number: 20090292057Abstract: A composition for injection molding by which a reactive injection molded article of good mechanical strength and electrical conductivity is prepared is provided. The disclosed is a composition for injection molding which includes carbon fibrous structures in a liquid curing resin composition, at a rate of 0.1-20% by weight based on the total weight of the composition, wherein the carbon fibrous structure comprises a three dimensional network of carbon fibers each having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part with which the carbon fibers are tied together in the state that the concerned carbon fibers are externally elongated therefrom, and wherein the granular part is produced in a growth process of the carbon fibers.Type: ApplicationFiled: October 18, 2006Publication date: November 26, 2009Applicants: BUSSAN NANOTECH RESEARCH INSTITUTE INC., MITSUI & CO., LTD.Inventors: Koichi Handa, Subiantoro n/a, Takayuki Tsukada, Tsuyoshi Okubo, Jiayi Shan, Akira Yamauchi, Manabu Nagashima
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Publication number: 20090286079Abstract: Strengthened filaments and fibers are realized by mixing and dissolving monomer and catalyst in a solvent into open-ended nanotubes to form a polymer precursor prior to polymerization in which the open nanotubes are filled with monomer and catalyst. The remaining steps for forming a stabilized filament may follow the conventional sequence. The result is that the nanotubes are “doubly-embedded” in the polymer matrix (bonds to the polymer inside and extending through the nanotube and bonds to other polymer chains outside the nanotube) in the filament. These additional bonds provide additional mechanical strength. The number of bonds may be further enhanced by pretreating the nanotubes to create defects in the nanotubes to form sites along the inner and outer walls for additional polymer-to-nanotube bonds.Type: ApplicationFiled: May 16, 2008Publication date: November 19, 2009Inventors: Delmar L. Barker, Mead M. Jordan, W. Howard Poisl
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Patent number: 7619029Abstract: A fiber composite material, including: an elastomer; carbon nanofibers having an average diameter of 0.7 to 15 nm and an average length of 0.5 to 100 micrometers; and fibers having an average diameter of 1 to 100 micrometers and an aspect ratio of 50 to 500, the carbon nanofibers and the fibers being dispersed in the elastomer, and the elastomer including an unsaturated bond or a group exhibiting affinity to the carbon nanofibers.Type: GrantFiled: June 27, 2006Date of Patent: November 17, 2009Assignee: Nissin Kogyo Co., Ltd.Inventors: Toru Noguchi, Akira Magario
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Patent number: 7615590Abstract: The present invention provides a rubber composition for a clinch, which highly improves steering stability and elongation properties in a balanced manner. Specifically, the present invention provides a rubber composition for a clinch comprising 20 to 70 parts by weight of carbon black containing silica and 0 to 50 parts by weight of carbon black, based on 100 parts by weight of a rubber component; wherein the total amount of the carbon black containing silica and the carbon black is 50 to 70 parts by weight.Type: GrantFiled: February 9, 2005Date of Patent: November 10, 2009Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Yoichi Mizuno
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Patent number: 7615281Abstract: A radio wave absorbing coating composition that exhibits an excellent absorption performance of radio waves in 40 MHz to 3 GHz frequency band is provided. The radio wave absorbing coating composition contains metal powder that is made up of a martensitic Fe—Cr—Ni alloy powder and/or a martensitic Fe—Ni alloy powder, carbon powder, resin, and solvent.Type: GrantFiled: June 23, 2006Date of Patent: November 10, 2009Assignees: Fujikura Kasei Co., Ltd.Inventors: Toshifumi Yamamoto, Hiroaki Watanabe, Satoshi Ogino, Takashi Takagai
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Publication number: 20090275689Abstract: The present invention relates to processes for producing high performance polymer composites via ultrasonic treatment after initial mixing. These high performance polymer composites made from a combination of polymer and nanofibers and/or nanotubes. The ultrasonic treating method of the disclosed allows a more highly dispersed polymer composite mixture which provides increased thermal, mechanical and electrical properties.Type: ApplicationFiled: June 5, 2007Publication date: November 5, 2009Applicant: THE UNIVERSITY OF AKRONInventor: Avraam ISAYEV
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Patent number: 7612138Abstract: An electromagnetic radiation attenuating material or coating consistent with certain embodiments of the present invention uses a binding matrix with an operative quantity of electromagnetic radiation attenuating nano-particles suspended in the binding matrix, wherein, the electromagnetic radiation attenuating nano-particles comprise onion-like-carbon (OLC) particles. In other embodiments, freestanding structures, aerosols and powders or suspensions contained within an enclosure provide EM or Radar absorption, particularly in the range of about 500 MHz to about 30 THz. This abstract is not to be considered limiting, since other embodiments may deviate from the features described in this abstract.Type: GrantFiled: January 24, 2006Date of Patent: November 3, 2009Assignee: International Technology CenterInventors: Vladimir Lvovich Kuznetsov, Olga Alexander Shenderova
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Patent number: 7608647Abstract: The present invention provides a resin composition and a resin molded article capable of designing to make specific properties, in particular, fuel barrier properties, consistent with impact resistance. The resin composition includes a mixture of a thermoplastic resin with fibers having lengths of from 4 to 20 mm. The fibers have melting points higher than a melting point of the thermoplastic resin or are infusible.Type: GrantFiled: September 22, 2005Date of Patent: October 27, 2009Assignees: Toyoda Gosei Co., Ltd., Toyota Jidosha Kabushiki KaishaInventors: Daisuke Tsutsumi, Koichiro Hayashi, Kenichi Yasunaga
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Patent number: 7608659Abstract: A conductive material mixed composition obtained by synthesizing a piperidyl group-containing high-molecular-weight polymer or copolymer that is composed of the constitutional unit represented by general formula (1) below and insoluble in tetrahydrofuran (THF) by polymerization in a liquid phase, immediately followed by mixing a conductive material with the polymer or copolymer in the liquid phase: wherein R1 represents a hydrogen atom, a hydroxyl group, an oxyl radical, an alkyl group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 18 carbon atoms; R2 and R3 each independently represent a hydrogen atom or a methyl group; R4 represents a hydrogen atom, an alkali metal atom, an alkyl group having 1 to 50 carbon atoms, an alkenyl group having 1 to 50 carbon atoms, an alkyl group having 1 to 50 carbon atoms, or a haloalkyl group having 1 to 50 carbon atoms; n represents a number of not less than 30; and m represents 0 or a positive number.Type: GrantFiled: June 17, 2008Date of Patent: October 27, 2009Assignee: Adeka CorporationInventors: Takayuki Taki, Atsuo Tomita, Hiroto Asano
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Patent number: 7604031Abstract: A pneumatic tire having a rubber sidewall including (A) 30 to 80 phr of natural rubber; (B) 20 to 70 phr of cis 1,4-polybutadiene rubber; (C) from 10 to 100 phr of silica; and (D) from 1 to 30 phr of a particulate rubber gel filler selected from the group consisting of polybutadiene gel, styrene butadiene gel, acrylonitrile-butadiene gel, chloroprene gel, natural rubber gel, and mixtures thereof.Type: GrantFiled: December 7, 2007Date of Patent: October 20, 2009Assignee: The Goodyear Tire & Rubber CompanyInventors: David John Zanzig, Uwe Ernest Frank, Georges Marcel Victor Thielen, Manfred Josef Jung
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Patent number: 7598311Abstract: A method for manufacturing a rubber product including masticating polymer with carbon black and factice is provided. A high-quality rubber product manufactured by this method is also provided. According to the present method, the carbon black is prevented from separating from a polymer and reaggregating, while the work environment is not deteriorated. A rubber composition prepared by the present method can be vulcanized and molded to manufacture the rubber product.Type: GrantFiled: March 9, 2005Date of Patent: October 6, 2009Assignee: Tokai Rubber Industries, Ltd.Inventors: Hidehito Ikeda, Yoshio Okado
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Publication number: 20090247686Abstract: A carbon black with a ?D50/M greater than about 0.9. The carbon black has an aggregate heterogeneity index (HI) via QTM of greater than about 2.3. The carbon black has a ?D50 via DCP of greater than about 0.07. The QTM-HI of the present carbon black is unique for N100-200 series carbon blacks, as is the ?D50. The carbon black is a N200 carbon black with an oil absorption number (OAN) less than about 135 and a HI of greater than about 2.3. The carbon black is also a N200 carbon black with an oil absorption number (OAN) less than about 135 and a ?D50 of greater than about 0.07. The present invention also relates to a polymeric composition and to tires comprising a carbon black of the present invention.Type: ApplicationFiled: June 28, 2007Publication date: October 1, 2009Inventors: Weidong Wang, Charles R. Herd, Jorge A. Ayala
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Patent number: 7591915Abstract: A method of producing a metal material in which carbon nanofibers are dispersed around metal particles includes: (a) mixing an elastomer which includes an unsaturated bond or a group having affinity to the carbon nanofibers, the metal particles, and the carbon nanofibers, and dispersing the carbon nanofibers by applying a shear force to obtain a carbon fiber composite material; and (b) heat-treating the carbon fiber composite material to vaporize the elastomer in the carbon fiber composite material.Type: GrantFiled: May 23, 2005Date of Patent: September 22, 2009Assignee: Nissin Kogyo Co., Ltd.Inventors: Toru Noguchi, Akira Magario
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Patent number: 7592389Abstract: Electrically conductive polymer composite materials comprised of: a) an effective amount of substantially crystalline graphitic carbon nanofibers comprised of graphite sheets that are substantially parallel to the longitudinal axis of the nanofiber, preferably wherein said graphite sheets form a multifaceted tubular structure; and b) a polymeric component.Type: GrantFiled: May 11, 2005Date of Patent: September 22, 2009Assignee: Catalytic Materials, LLCInventors: R. Terry K. Baker, Nelly M. Rodriguez
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Publication number: 20090234058Abstract: An aqueous ink composition including a carbon black having a specific surface area of 200 m2/g or more but less than 300 m2/g according to a BET method, an organic solvent, a neutralizing agent and water, wherein the carbon black is coated with a water-insoluble resin including a structural unit represented by the following formula (I): wherein R1 represents a hydrogen atom or a methyl group, Ar represents an unsubstituted or substituted aromatic ring, and n represents an average repeating number and is from 1 to 6.Type: ApplicationFiled: March 12, 2009Publication date: September 17, 2009Applicant: FUJIFILM CorporationInventor: Misato Sasada
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Patent number: 7588700Abstract: Disclosed is an electromagnetic shielding material with enhanced shielding effectiveness and mechanical property by employing a carbon nanotube and a metal as an electrical conductor. The electromagnetic shielding material includes a polymer resin for a matrix and two conductive fillers having a carbon nanotube and a metal, wherein a volume percent of the carbon nanotube ranges about 0.2% to about 10% and a volume percent of the metal powder ranges about 7.0% to about 30% so that the total volume percent of the conductive filler is in a range of about 7.2% to about 40%.Type: GrantFiled: October 15, 2004Date of Patent: September 15, 2009Assignee: Electronics and Telecommunications Research InstituteInventors: Jong-Hwa Kwon, Hyung-Do Choi, Ho-Gyu Yoon, Yoon-Jin Kim
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Patent number: 7588699Abstract: The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400–800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.Type: GrantFiled: November 1, 2002Date of Patent: September 15, 2009Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Cheol Park, Kent A. Watson, Zoubeida Ounaies, John W. Connell, Joseph G. Smith, Joycelyn S. Harrison
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Patent number: 7589143Abstract: A method for reducing cure shrinkage of a thermoset resin includes forming a plurality of surface modified nanofibers. The surface modified nanofibers are formed by soaking nanofibers in an oxidizing acidic solvent. An oxidizing agent is added to the soaking nanofibers, thereby generating heat sufficient for at least one of in-situ oxidation and in-situ exfoliation of a subsurface of each of the nanofibers. Excess oxidizing agent and acidic solvent are removed from the nanofibers, which are then dried. The dried nanofibers have reduced surface hydrophobicity. The surface modified nanofibers are substantially uniformly dispersed into the thermoset resin. The surface modified nanofibers are adapted to reduce cure shrinkage of the thermoset resin during subsequent curing processes.Type: GrantFiled: September 22, 2005Date of Patent: September 15, 2009Assignee: GM Global Technology Operations, Inc.Inventors: Gholam-Abbas Nazri, Chen-Shih Wang
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Patent number: 7589134Abstract: The invention relates to an adhesive composition containing a special silane cross-linking polymer and fine-particle coated calcium carbonate and soot. 20 to 50 ml of fine-particle coated calcium carbonate and soot are provided for every 100 g of polymer, and the volume ratio of fine-particle coated calcium carbonate and soot is between 70:30 and 30:70. The inventive adhesive composition is characterized by having good mechanical properties, a high electrical volume resistance and a good applicability.Type: GrantFiled: November 30, 2007Date of Patent: September 15, 2009Assignee: Sika Technology AGInventors: Ueli Pfenninger, Ursula Stadelmann, Annemarie Kuelling
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Patent number: 7588065Abstract: The subject of the present invention is the use of cohesive, low-hysteresis compositions comprising small amounts of reinforcing fillers to produce profiled filing members arranged in the bottom zone of tires in order to improve the life thereof.Type: GrantFiled: February 10, 2000Date of Patent: September 15, 2009Assignee: Michelin Recherche et Technique, S.A.Inventor: Frédéric Serre
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Publication number: 20090227723Abstract: Provided is a resin molding material having a remarkably excellent abrasion resistance while maintaining a favorable mechanical strength. The resin molding material is improved in deterioration of the abrasion resistance caused by an abrasive powder generated from an inorganic substance, particularly from a glass fiber or the like. The resin molding material contains a resin, a carbon substance and an inorganic substance. The carbon substance contains an adhesive carbon substance.Type: ApplicationFiled: November 10, 2006Publication date: September 10, 2009Inventors: Michiko Kaya, Hiroto Oda, Teiichi Inada
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Publication number: 20090226708Abstract: The present invention provides a pressure-sensitive adhesive composition, which comprises a pressure-sensitive adhesive, a carbon nano material and a dispersing agent, the carbon nano material being dispersed with the dispersing agent in the pressure-sensitive adhesive, and a pressure-sensitive adhesive sheet, which comprises a substrate sheet and a pressure-sensitive adhesive layer composed of the pressure-sensitive adhesive composition of the present invention, the pressure-sensitive adhesive layer being formed on one surface or both surfaces of the substrate sheet. The pressure-sensitive adhesive composition and the pressure-sensitive adhesive sheet are superior in the antistatic property or the conductive property.Type: ApplicationFiled: March 3, 2009Publication date: September 10, 2009Applicant: LINTEC CorporationInventors: Satoshi NAGANAWA, Mikihiro Kashio