Mixing With Carbon, E.g., Graphite, Etc., Having Numerical Limitations, Other Than Amount, E.g., Included Herein Are Particle Size, Surface Area, Etc., Or Composition Or Product Thereof, Dnrm Patents (Class 524/495)
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Patent number: 7989550Abstract: A rubber composition for a tire tread comprising (A) 100 parts by weight of a rubber component containing (a) 50 to 95 parts by weight of a diene-based rubber containing 50 to 100% by weight of an aromatic vinyl-conjugated diene copolymer rubber and (b) 5 to 50 parts by weight of a conjugated diene-based rubber gel having a toluene swelling index Qi of 16 to 70 and (B) 3 to 40 parts by weight, based upon 100 parts by weight of the total rubber component, of a copolymer resin of an aromatic vinyl and dipentene and/or pinene having a softening point of 100 to 150° C. and a high performance tire using the above rubber composition are disclosed.Type: GrantFiled: December 21, 2007Date of Patent: August 2, 2011Assignee: The Yokohama Rubber Co., Ltd.Inventors: Naoya Amino, Akitomo Sato
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Publication number: 20110184099Abstract: Polyamide moulding composition, in particular for use for components of electronic and/or electrical components, having the following composition: (A) 30-100% by weight of a partially aromatic, partially crystalline copolyamide made up of 100% by weight of diacid fraction composed of: 72.0-98.3% by weight of terephthalic acid (TPA) and/or naphthalenedicarboxylic acid; 28.0-1.7% by weight of isophthalic acid (IPA) and 100% by weight of diamine fraction composed of: 51.0-80.0% by weight of 1,6-hexanediamine (HMDA); 20.0-49.0% by weight of aliphatic, unbranched C9-C12-diamine; (B) 0-70% by weight of fillers and reinforcing materials; (C) 0-25% by weight of flame retardants; (D) 0-5% by weight of additives; where the components (A)-(D) add up to 100% by weight.Type: ApplicationFiled: January 26, 2011Publication date: July 28, 2011Applicant: EMS-PATENT AGInventors: Manfred HEWEL, Andreas BAYER
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Publication number: 20110184114Abstract: This invention relates to a rubber composition being excellent in the low heat buildup and fracture properties (resistance to crack growth). and more particularly to a rubber composition, characterized by compounding 10-100 parts by mass of an inorganic filler and/or carbon black based on 100 parts by mass of a rubber component including not less than 10 mass % of a modified conjugated diene-based polymer having a cis-1,4 bond content of not less than 90% and a vinyl bond content of not more than 1.2% and a primary amino group. In this case, the modified conjugated diene-based polymer is obtained by (1) reacting the predetermined conjugated diene-based polymer having an active terminal with a compound having two or more predetermined functional groups and (2) further reacting the resulting product with a compound having a primary amino group.Type: ApplicationFiled: March 10, 2009Publication date: July 28, 2011Applicant: Bridgestone CorporationInventors: Junko Matsushita, Yoichi Ozawa
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Patent number: 7985789Abstract: The invention concerns an aqueous specific silica-based nanocomposite polymer dispersion, a method for preparing same, a coating composition, in particular protective, containing said dispersion, for applications requiring high anti-corrosive, anti-abrasive and chemical resistance performances. It concerns an aqueous nanocomposite polymer dispersion obtainable by an emulsion polymerization process of at least one monomer composition in the presence of at least one aqueous silica nanoparticle dispersion, said monomer composition being added at least in one step into the reactor already containing the aqueous silica nanoparticle dispersion, said aqueous silica nanoparticle dispersion having an anionic character and being stable in a pH range between 2 to 10, and said emulsion polymerization being performed in the presence of at least one organic initiator free of any ionic group and in the absence of any monomer or cationic dispersant.Type: GrantFiled: February 22, 2007Date of Patent: July 26, 2011Assignee: Cray Valley S.A.Inventors: Jordi Albalat Perez, Carme Font i Panades, Jean-Yves Loze
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Patent number: 7985351Abstract: A liquid crystalline polyester resin composition comprising 100 parts by weight of a liquid crystalline polyester; 50 to 150 parts by weight of at least one whisker selected from aluminum borate whisker and titanium oxide whisker; and 1 to 30 parts by weight of carbon black having a specific surface area of at least 200 m2/g. This liquid crystalline polyester resin composition has excellent mechanical properties and provides an insulator which is hardly charged.Type: GrantFiled: August 2, 2005Date of Patent: July 26, 2011Assignees: Sumitomo Chemical Co., Ltd., NTN CorporationInventors: Hiroyasu Yamauchi, Mitsuo Maeda, Fuminori Satoji, Kenji Ito
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Publication number: 20110178224Abstract: A nanocomposite composition having a silicone elastomer matrix having therein a filler loading of greater than 0.05 wt %, based on total nanocomposite weight, wherein the filler is functional graphene sheets (FGS) having a surface area of from 300 m2/g to 2630 m2/g; and a method for producing the nanocomposite and uses thereof.Type: ApplicationFiled: November 12, 2010Publication date: July 21, 2011Applicant: The Trustees of Princeton UniversityInventors: Shuyang Pan, Ilhan A. Aksay, Robert K. Prud'Homme
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Publication number: 20110171451Abstract: It is an object of the present invention to provide a fluororesin film usable as the outermost layer of a back sheet for a solar cell module, which is a dark type fluororesin film having a sufficient electric insulation property and weather resistance, and which is particularly excellent in thermal resistance; and a back sheet for a solar cell module employing such a film. A dark type fluororesin film, which is a fluororesin film to be used for a back sheet of a solar cell module, which contains an ethylene-tetrafluoroethylene copolymer as the main component and contains from 1.0 to 4.5 parts by mass of a carbon black having a pH of from 8 to 10 as measured according to JIS K6221 section 6.4.2 based on 100 parts by mass of the ethylene-tetrafluoroethylene copolymer. Further, a back sheet 1 comprising a laminate including a fluororesin film 11 being the dark type fluororesin film as the outermost layer.Type: ApplicationFiled: March 23, 2011Publication date: July 14, 2011Applicant: ASAHI GLASS COMPANY, LIMITEDInventor: Hiroshi ARUGA
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Patent number: 7972536Abstract: The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.Type: GrantFiled: August 25, 2009Date of Patent: July 5, 2011Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: John W. Connell, Joseph G. Smith, Jr., Joycelyn S. Harrison, Cheol Park, Kent A. Watson, Zoubeida Ounaies
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Publication number: 20110160375Abstract: A carbon fiber composite material comprising 100 parts by mass of an elastomer, and 20 to 100 parts by mass of carbon nanofibers that have been oxidized and reduced in number of branch points. The carbon fiber composite material has a dynamic modulus of elasticity (E?) at 200° C. and 10 Hz of 10 to 1000 MPa, and a volume resistivity of 106 to 1018 ohms·cm.Type: ApplicationFiled: December 28, 2009Publication date: June 30, 2011Applicants: NISSIN KOGYO CO., LTD., MEFS KABUSHIKI KAISHA, SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Toru NOGUCHI, Hiroyuki UEKI, Shigeki INUKAI, Satoshi IINOU, Masaei ITO
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Publication number: 20110156356Abstract: The seal member includes a tetrafluoroethylene-propylene copolymer (FEPM) and carbon nanofibers. The seal member has a number of cycles to fracture of 10 or more when subjected to a tension fatigue test at a temperature of 150° C., a maximum tensile stress of 2 N/mm, and a frequency of 1 Hz. The seal member exhibits excellent heat resistance and abrasion resistance.Type: ApplicationFiled: December 28, 2009Publication date: June 30, 2011Applicants: NISSIN KOGYO CO., LTD., SCHLUMBERGER TECHNOLOGY CORPORATION, SHINSHU UNIVERSITY, MEFS KABUSHIKI KAISHAInventors: Toru NOGUCHI, Hiroyuki UEKI, Shigeki INUKAI, Masaei ITO, Raghu MADHAVAN, Morinobu ENDO, Satoshi IINOU
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Patent number: 7968639Abstract: The present invention provides a polyvinyl acetal powder which is excellent in flowability during the coating process when it is applied to a powder coating material. This polyvinyl acetal powder enables to obtain a coating film having good impact resistance and uniformity of thickness (uniformity of coating film thickness). The present invention also provides a powder coating material using the polyvinyl acetal powder. Specifically, the present invention is a polyvinyl acetal powder having an average particle diameter of 10 to 150 ?m, a maximum particle diameter of 250 ?m or less, and a melt flow rate of 1 to 200 g/10 min. as measured in accordance with JIS K7210: 1999. The present invention also is a powder coating material containing this polyvinyl acetal powder.Type: GrantFiled: April 26, 2007Date of Patent: June 28, 2011Assignee: Kuraray Co., Ltd.Inventors: Seiji Tanimoto, Koichiro Isoue, Makio Tokoh, Tamotsu Miura
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Patent number: 7968633Abstract: Free-flowing filler compositions containing sulfur-containing silane coupling agents, and a tire composition containing the filler composition, for use in the manufacture of tires.Type: GrantFiled: December 28, 2006Date of Patent: June 28, 2011Assignee: Continental AGInventors: W. Michael York, Richard W. Cruse, Eric Raymond Pohl, Prashant G. Joshi
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Patent number: 7968640Abstract: A non-stick coating application for high heat welding environments comprised of a fluorinated polymer combined with acidified graphite to which a hardening agent, such as alumina, may be added in some embodiments.Type: GrantFiled: June 24, 2009Date of Patent: June 28, 2011Assignee: Teledyne Scientific & Imaging, LLCInventors: Rahul Ganguli, Ten-Luen T. Liao, Roberto S. Santos
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Patent number: 7968011Abstract: A conductive ink comprising 10 to 75 wt % of at least one solvent comprising ?20 wt % water; 0 to 50 wt % of at least one radiation curable material having a Mn in the range of from 50 to 10,000 g/mol; 5 to 70 wt % of at least one polyurethane having a Mw in the range of from 4,000 to 70,000 g/mol, 0 to 5 wt % of isocyanate-reactive component(s) bearing ionic or potentially ionic water-dispersing groups and a free isocyanate group content <0.5 wt % and 20 to 85 wt % of a conductive material.Type: GrantFiled: March 6, 2007Date of Patent: June 28, 2011Assignee: DSM IP Assets B.V.Inventors: Gerardus Cornelis Overbeek, Michael Arnoldus Jacobus Schellekens, Alfred Jean Paul Bückmann
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Patent number: 7968657Abstract: A thermoplastic compound is disclosed, comprising polyhydroxyalkanoate and macrocyclic poly(alkylene dicarboxylate) oligomer. Optionally the compound also includes additional polymers and functional additives to modify physical properties of the compound. Molded or extruded plastic articles can be made from the compound. The compound is ductile, in comparison to the polyhydroxyalkanoate without the macrocyclic poly(alkylene dicarboxylate) oligomer.Type: GrantFiled: October 19, 2007Date of Patent: June 28, 2011Assignee: PolyOne CorporationInventor: Roger W. Avakian
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Patent number: 7968634Abstract: Sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These silanes can be carried on organic and inorganic fillers. The invention also relates to tire compositions and articles of manufacture, particularly tires, made from elastomer compositions.Type: GrantFiled: December 28, 2006Date of Patent: June 28, 2011Assignee: Continental AGInventors: W. Michael York, Richard W. Cruse, Eric Raymond Pohl, Prashant G. Joshi
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Patent number: 7968635Abstract: Free-flowing filler compositions containing silated cyclic core polysulfide coupling agents, and rubber and tire compositions containing the filler compositions.Type: GrantFiled: December 28, 2006Date of Patent: June 28, 2011Assignee: Continental AGInventors: W. Michael York, Richard W. Cruse, Janna Jaeckel, Eric Raymond Pohl, Prashant G. Joshi
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Patent number: 7968636Abstract: Sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These silanes can be carried on organic and inorganic fillers. The invention also relates to tire compositions and articles of manufacture, particularly tires, made from the elastomer compositions described herein.Type: GrantFiled: December 28, 2006Date of Patent: June 28, 2011Assignee: Continental AGInventors: W. Michael York, Richard W. Cruse, Janna Jaeckel, Eric Raymond Pohl, Prashant G. Joshi
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Patent number: 7964656Abstract: A method for forming a vulcanizable composition of matter, the method comprising providing a polymer cement or latex comprising at least one rubber, adding at least one processing aid to the cement or latex to form a modified rubber cement or latex, isolating the rubber and at least one processing aid to form a premix, and mixing the premix with carbon black.Type: GrantFiled: February 1, 2007Date of Patent: June 21, 2011Assignee: Bridgestone CorporationInventors: Georg G. A. Böhm, Anthony J. Ramic, James D. Ulmer, William L. Hergenrother, Christine M. Rademacher, David F. Lawson, Sunil B. Sarkar
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Patent number: 7960467Abstract: A method of producing a carbon fiber composite material including: (a) masticating an elastomer to reduce the molecular weight of the elastomer to obtain a liquid elastomer; (b) mixing the elastomer obtained in the step (a) and carbon nanofibers having an average diameter of 0.5 to 500 nm to obtain a mixture; (c) increasing the molecular weight of the elastomer in the mixture obtained in the step (b) to obtain a rubbery elastic mixture; and (d) mixing the rubbery elastic mixture obtained in the step (c) to disperse the carbon nanofibers in the elastomer by a shear force to obtain a carbon fiber composite material.Type: GrantFiled: November 28, 2007Date of Patent: June 14, 2011Assignee: Nissin Kogyo Co., Ltd.Inventors: Toru Noguchi, Akira Magario, Kazuyuki Yokoyama
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Patent number: 7960463Abstract: Particular embodiments are directed toward a rubber mixture comprising (i) a rubber; and (ii) a filler component, where the filler component includes a filler selected from the group consisting of amorphous aluminum hydroxycarbonate, amorphous aluminum hydroxyoxycarbonate, and amorphous aluminum oxycarbonate, where said amorphous aluminum hydroxycarbonate, amorphous aluminum hydroxyoxycarbonate, and amorphous aluminum oxycarbonate are characterized by a BET specific surface area of less than 40 m2/g.Type: GrantFiled: December 30, 2008Date of Patent: June 14, 2011Assignee: Bridgestone CorporationInventors: Xiao-Dong Pan, Pat Sadhukhan
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Patent number: 7960466Abstract: The present invention provides a natural rubber masterbatch effective in achieving a tread rubber composition which is suitable for heavy-duty tires for rough roads and which is effective in greatly enhancing the abrasion resistance of the tires without impairing the low heat build-up of the tires, a method of producing the natural rubber masterbatch, a rubber composition prepared using the natural rubber masterbatch, and a tire. In a mixing step of mixing a natural rubber latex with a slurry containing water and a carbon black dispersed therein, 10 to 100 weight parts of the carbon black is mixed with 100 weight parts of a natural rubber component in the natural rubber latex. The carbon black satisfies the following conditions: (1) N2SA is 120 to 180 m2/g; (2) the relationship between 24M4DBP and N2SA is represented by the inequality 15?24M4DBP?0.Type: GrantFiled: December 19, 2005Date of Patent: June 14, 2011Assignee: Bridgestone CorporationInventors: Hiroshi Yamada, Kazuhiro Yanagisawa
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Patent number: 7960460Abstract: This invention relates to novel free-flowing filler compositions containing sulfur-containing silane coupling agents, and to a rubber containing the filler composition.Type: GrantFiled: December 28, 2006Date of Patent: June 14, 2011Assignee: Momentive Performance Materials, Inc.Inventors: Richard W. Cruse, W. Michael York, Eric R. Pohl, Prashant Joshi
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Publication number: 20110133134Abstract: Compositions comprising graphene sheets, at least one olefin polymer, and at least one crosslinking agent and crosslinked compositions comprising graphene sheets and at least one olefin polymer. A method of making a crosslinked composition comprising graphene sheets and at least one olefin polymer, coatings comprising the compositions, and a method of coating a surface with the compositions are disclosed.Type: ApplicationFiled: June 9, 2010Publication date: June 9, 2011Applicant: VORBECK MATERIALS CORP.Inventors: Vipin Varma, Dan Scheffer
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Patent number: 7956106Abstract: An organic siloxane composite material containing polyaniline/carbon black and a preparation method thereof are disclosed. The organic siloxane composite material containing polyaniline/carbon black consists of a plurality of polyaniline/carbon black composites distributed in organic siloxane precursor while the organic siloxane composite material containing polyaniline/carbon black includes from 10 to 30 weight percent of polyaniline/carbon black composites. The preparation method of organic siloxane composite material containing polyaniline/carbon black includes the steps of: distributing a plurality of polyaniline/carbon black composites in organic siloxane precursor to produce a first solution; and adding a cross-linking agent into the first solution, after reaction with each other, an organic siloxane composite material containing polyaniline/carbon black is produced.Type: GrantFiled: October 30, 2007Date of Patent: June 7, 2011Assignee: Chung Shan Institute of Science and Technology, Armaments Bureau, M.N.D.Inventors: Cheng-Chien Yang, Kuo-Hui Wu, Wang Tsae Gu, Yuen-Hsin Peng
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Patent number: 7951850Abstract: A method of forming carbon nanotube-polymer composites includes the steps of forming a mixture solution including a plurality of carbon nanotubes dispersed in a co-solvent. The co-solvent includes an organic solvent and a second solvent being a short chain fluorinated carboxylic acid having a boiling point below 150° C. which is less oxidizing than nitric acid, and is soluble in both the organic solvent and water. The first polymer is mixed with the mixture solution to form a polymer including mixture. The co-solvent is removed from the polymer mixture to form a dispersed nanotube-polymer composite. The second solvent can be trifluoroacetic acid.Type: GrantFiled: March 18, 2008Date of Patent: May 31, 2011Assignee: University of Central Florida Research Foundation, Inc.Inventors: Qun Huo, Saiful Khondaker, Jianhua Zou, Lei Zhai, Hui Chen, Harish Muthuraman
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Publication number: 20110124792Abstract: The invention relates to a rubber mixture comprising at least one rubber and at least one low-PAH-content carbon black, where the low-PAH-content carbon black has (A) an iodine number of from 17 to 75 mg/g, (B) an STSA surface area of from 17 to 64 m2/g, (C) an iodine number:STSA surface area ratio >1.06 mg/m2, (D) an OAN number of from 60 to 160 ml/100 g, (E) a COAN number of from 40 to 110 ml/100 g, (F) a mode greater than 100 nm and (G) benzo(a)pyrene content <2 ppm. The rubber mixture can be used to produce technical rubber items and tyres.Type: ApplicationFiled: November 19, 2010Publication date: May 26, 2011Applicant: Evonik Degussa GmbHInventors: Joachim FRÖEHLICH, Paul Dieter MESSER, Michael WARSKULAT, Luis MOLINARI, Vanni VITALI
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Patent number: 7947764Abstract: This invention provides a cationic electrodeposition coating composition which exhibits high paint stability, forms coating film excelling in conductivity, intimate adhesion, corrosion resistance, finished appearance and acid resistance, and is capable of forming uniform electrocoated film also on substrates having uneven surfaces, characterized by comprising a conductive filler dispersion paste, base resin and a curing agent, said paste being formed by dispersing a conductive filler (A) composed of high conductive carbon black (a1) and at least one conductive powder (a2) selected from furnace black, graphite and conductive whisker, using a pigment-dispersing resin (B), the composition (i) containing 30-100 wt parts of a conductive filler (A) which contains at least 2 wt parts of high conductive carbon black (a1), per 100 wt parts of combined solid content of the base resin and the curing agent, (ii) the weight ratio of the conductive powder (a2)/high conductive carbon black (a1) being within a range of 0.Type: GrantFiled: July 13, 2006Date of Patent: May 24, 2011Assignee: Kansai Paint Co., Ltd.Inventors: Masaaki Shinohara, Toshiharu Soga, Naoya Haruta
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Publication number: 20110112234Abstract: The present invention relates to novel pigment mixtures, comprising two different components A and B, wherein component A is a graphite in the form of platelets (graphite nanoplatelets), which have an average particle size of below 50 microns and a thickness below 100 nm, and component B is an organic, or inorganic pigment. The use of graphite nanoplatelets in a pigment mixture with organic and/or inorganic pigments, especially effect pigments (component B), allows the preparation of metallic like colorations with a maximal opacity (background substrate disappears totally) while keeping a good rheological behavior (low concentration use).Type: ApplicationFiled: June 10, 2009Publication date: May 12, 2011Applicant: BASF SEInventors: Veronique Hall-Goulle, Rebekka Zillhardt, Philippe Bugnon
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Patent number: 7939167Abstract: The present invention provides a resin composition comprising a thermoplastic resin (A), an inorganic compound having a volume resistance of less than about 10?3 ?·m and relative permeability of more than about 5,000 (B) and fiber filler (C). The resin composition of the present invention can have high impact strength and high electrical conductivity, and high electromagnetic interference (EMI) and radio frequency interference (RFI) shielding properties. The resin composition of the present invention can accordingly have multiple functions and can be used for electrical/electronic devices.Type: GrantFiled: December 29, 2009Date of Patent: May 10, 2011Assignee: Cheil Industries Inc.Inventors: Sung Jun Kim, Young Sik Ryu
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Patent number: 7939595Abstract: A method for reducing cure shrinkage of a thermoset resin includes forming a plurality of surface modified nanofibers. The surface modified nanofibers are formed by soaking nanofibers in an oxidizing acidic solvent. An oxidizing agent is added to the soaking nanofibers, thereby generating heat sufficient for at least one of in-situ oxidation and in-situ exfoliation of a subsurface of each of the nanofibers. Excess oxidizing agent and acidic solvent are removed from the nanofibers, which are then dried. The dried nanofibers have reduced surface hydrophobicity. The surface modified nanofibers are substantially uniformly dispersed into the thermoset resin. The surface modified nanofibers are adapted to reduce cure shrinkage of the thermoset resin during subsequent curing processes.Type: GrantFiled: August 14, 2009Date of Patent: May 10, 2011Assignee: GM Global Technology Operations LLCInventors: Gholam-Abbas Nazri, Chen-Shih Wang
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Patent number: 7938996Abstract: Process, apparatus, compositions and application modes are provided that relate to nanofiber spinning without the use of superacids in the spinning solution. The methods employ either acids or bases for a flocculation solution. The advances disclosed therein enable the use of nanofibers, including carbon nanotubes, for a variety of applications including, but not limited to, electromechanical actuators, supercapacitors, electronic textiles, and in devices for electrical energy harvesting.Type: GrantFiled: September 30, 2005Date of Patent: May 10, 2011Assignee: Board of Regents, The University of Texas SystemInventors: Ray H. Baughman, Mikhail Kozlov, Von Howard Ebron, Ryan Capps, John P. Ferraris
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Patent number: 7935276Abstract: The present invention relates to novel composites that incorporate carbon nanospheres into a polymeric material. The polymeric material can be any polymer or polymerizable material compatible with graphitic materials. The carbon nanospheres are hollow, graphitic nanoparticles. The carbon nanospheres can be manufactured from a carbon precursor using templating catalytic nanoparticles. The unique size, shape, and electrical properties of the carbon nanospheres impart beneficial properties to the composites incorporating these nanomaterials.Type: GrantFiled: December 20, 2006Date of Patent: May 3, 2011Assignee: Headwaters Technology Innovation LLCInventors: Bing Zhou, Cheng Zhang, Martin Fransson, Raymond B. Balée
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Patent number: 7935754Abstract: An automotive body panel containing a polymer composite formed of at least one polymer and a modified graphite oxide material, which is a thermally exfoliated graphite oxide with a surface area of from about 300 m2/g to 2600 m2/g.Type: GrantFiled: August 19, 2008Date of Patent: May 3, 2011Assignee: The Trustees of Princeton UniversityInventors: Robert K. Prud'Homme, Ilhan A. Aksay, Douglas Adamson, Ahmed Abdala
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Patent number: 7935275Abstract: A shaped resin article comprising a polyamide (A) (comprising at least two different polyamide components), a polyphenylene ether (B) and a partially hydrogenated block copolymer (C) (obtained by partially hydrogenating a block copolymer comprising an aromatic vinyl polymer block and a conjugated diene polymer block) including a block copolymer (C-1) having a number average molecular weight of from 200,000 to 300,000, wherein (A) is present as a continuous phase in which (B) is dispersed to form a dispersed phase, and (C) is present in the continuous phase of (A) and/or the dispersed phase of (B), wherein the surface area of the polyamide (A) exposed on the overall surface of the shaped resin article is at least 80%, based on the surface area of the shaped resin article.Type: GrantFiled: April 16, 2004Date of Patent: May 3, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Takaaki Miyoshi, Kazuya Noda, Mitsuhiro Horio, Yuuji Yoshinaga
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Publication number: 20110095238Abstract: The present invention relates to novel composites that incorporate carbon nanospheres into a polymeric material. The polymeric material can be any polymer or polymerizable material compatible with graphitic materials. The carbon nanospheres are hollow, graphitic nanoparticles. The carbon nanospheres can be manufactured from a carbon precursor using templating catalytic nanoparticles. The unique size, shape, and electrical properties of the carbon nanospheres impart beneficial properties to the composites incorporating these nanomaterials.Type: ApplicationFiled: January 6, 2011Publication date: April 28, 2011Applicant: HEADWATERS TECHNOLOGY INNOVATION, LLC.Inventors: Bing Zhou, Cheng Zhang, Martin Fransson, Raymond B. Balée
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Patent number: 7932316Abstract: A composition that includes functionalized polymers and one or more types of particulate filler exhibits both an increased gum Mooney viscosity and a decreased compound Mooney viscosity relative to a comparable composition that includes only one such functionalized polymer. The functionalized polymers include first and second types of functionalities which exhibit a non-covalent interaction that has a bond energy of from about 0.1 to about 20 kJ/mol.Type: GrantFiled: December 17, 2007Date of Patent: April 26, 2011Assignee: Bridgestone CorporationInventors: Yuan-Yong Yan, Steven Luo
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Patent number: 7932307Abstract: A natural rubber wet masterbatch rubber composition comprising a mixture of a natural rubber latex with a slurry solution containing a carbon black dispersed therein, which satisfies the followings: (1) a CATB specific surface area (m2/g) in the range of 60<CTAB<110, (2) a 24M4DBP (m3/100 g) in the range of 55<24M4DBP<75, (3) a CATB specific surface area and a tint strength (TINT) having the relationship of TINT>0.41×CTAB+81, and (4) a compounding amount of 10 to 100 parts by mass relative to 100 parts by mass of natural rubber. The natural rubber wet masterbatch rubber composition can be suitably used for improving the resistance to fracture and to crack propagation of a tire, a steel coating rubber for a rubber product for industrial use, and the like.Type: GrantFiled: February 1, 2006Date of Patent: April 26, 2011Assignee: Bridgestone CorporationInventors: Hiroshi Yamada, Kazuhiro Yanagisawa
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Patent number: 7928159Abstract: A process for providing interaction between particulate filler and a functionalized polymer involves a composition that includes at least three components: (1) a polymer that includes a functional group including an acidic cation of a primary or secondary amine functionality, (2) a material including a functionality capable of reacting with the acidic cation, and (3) particulate filler. The amine functionality from (1) is allowed to interact with (3) after being neutralized by the action of the acid-reactive functionality from (2). The process is useful in the formation of vulcanizates and articles made therefrom.Type: GrantFiled: May 26, 2006Date of Patent: April 19, 2011Assignee: Bridgestone CorpororationInventor: Yuan-Yong Yan
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Patent number: 7928157Abstract: This invention relates to a tire with a tread of a rubber composition which contains zinc rosinate within and on the surface of said rubber composition. Said zinc rosinate promotes enhanced wet traction for said tire tread by actually replacing a more conventional zinc stearate for a tire tread rubber composition. Said zinc rosinate is a product of a combination of rosin acid and zinc oxide formed in situ within said rubber composition. Said more conventional zinc stearate is a product of a combination of stearic acid and zinc oxide formed in situ within a tread rubber composition.Type: GrantFiled: September 10, 2007Date of Patent: April 19, 2011Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Joseph Kevin Hubbell, Thomas Charles Lippello, III
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Publication number: 20110086735Abstract: A friction drive belt (B) includes a pulley contacting portion (13) which is made of a rubber composition of an ethylene-?-olefin elastomer as raw rubber in which carbon black having an iodine adsorption number of 40 mg/g or lower, and 3-10 parts by mass of short aramid fiber (14) relative to 100 parts by mass of the raw rubber are blended.Type: ApplicationFiled: June 4, 2009Publication date: April 14, 2011Applicant: BANDO CHEMICAL INDUSTRIES, LTD.Inventors: Shinji Takahashi, Hisashi Matsuda
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Patent number: 7919547Abstract: A water-dispersible composition including a nanofiller-containing epoxy resin and a low temperature nonionic surfactant having a molecular weight of less than about 7,000 Daltons; and optionally an anionic surfactant or optionally a high temperature nonionic surfactant. The water-dispersible composition can be used to prepare an aqueous dispersion of the nanofiller-containing epoxy resin. The aqueous dispersion advantageously has a long shelf- stability. One method for preparing the aqueous dispersion includes using a high internal phase ratio emulsion process.Type: GrantFiled: June 4, 2008Date of Patent: April 5, 2011Inventors: Eva-Maria Michalski, Manuela Ehreiser
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Patent number: 7919558Abstract: A rubber composition containing (i) a conjugated diene-based rubber gel having a toluene swelling index of 16 to 70, (ii) a diene-based rubber such as natural rubber, polyisoprene rubber, aromatic vinyl-conjugated diene copolymer rubber and/or polybutadiene rubber, and (iii) an optional carbon black and/or silica and (a) a pneumatic tire using this composition as a high hardness reinforcing layer extending from a bead along a tire sidewalls, in which the fluidity and dimensional stability at the time of extrusion are improved, while maintaining a sufficient hardness of a high hardness reinforced rubber, (b) a pneumatic tire using this composition as two ends of a tire tread extrudate, maintaining a flex fatigue of the two ends of the tread, in which the extrudability and extrusion dimensional stability are improved and (c) a pneumatic tire using the composition as a 1.Type: GrantFiled: February 22, 2005Date of Patent: April 5, 2011Assignees: The Yokohama Rubber Co., Ltd., Zeon CorporationInventors: Naoya Amino, Misao Hiza, Takashi Shirokawa, Masao Nakamura, Koichi Endo
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Patent number: 7919013Abstract: Thermoplastic molding compositions comprising A) from 40 to 96.2% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of an impact-modifying polymer which comprises functional groups, C) from 1 to 50% by weight of fibrous or particulate fillers or a mixture of these, D) from 0.2 to 5% by weight of a lubricant, E) from 0.5 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of other added materials, where the total of the percentages by weight of components A) to F) is 100%.Type: GrantFiled: July 17, 2007Date of Patent: April 5, 2011Assignee: BASF SEInventors: Martin Weber, Xaver Hopfenspirger, Steffen Funkhauser, Walter Heckmann, Jörg Schnorr, Raquel Fernandez Rodiles, Rainer Klenz, Hagen Stawitzki
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Patent number: 7915335Abstract: A rubber composition is provided that attains both low heat generating property and high reinforcement property simultaneously at high levels, is capable of attaining low fuel consumption through the tire, is excellent in durability, and is good in workability and surface property. The rubber composition contains 100 parts by weight of a diene rubber component, from 0.5 to 50 parts by weight of bagasse charcoal having a BET specific surface area of from 10 to 300 m2/g, and at least one of carbon black and silica. The total amount of the bagasse charcoal, the carbon black and the silica is preferably from 30 to 100 parts by weight per 100 parts by weight of the diene rubber component.Type: GrantFiled: September 2, 2008Date of Patent: March 29, 2011Assignee: Toyo Tire & Rubber Co., Ltd.Inventor: Shinya Yamamoto
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Patent number: 7910652Abstract: The invention relates to a polyamide moulding compound containing 70 to 99.5% by weight of at least one thermoplastic polyamide and 0.5 to 30% by weight of at least one polyamide oligomer with linear or branched chain structure with a number average molar mass of 800 to 5000 g/mol with basic end groups which are at least partially NH2 end groups, and carboxyl end groups, one of these end groups being present in excess and the concentration of the end group present in excess being at most 300 mmol/kg.Type: GrantFiled: March 24, 2006Date of Patent: March 22, 2011Assignee: Ems-Chemie AGInventors: Paul Schwitter, Georg Stoeppelmann, Alex Stolarz, Helmut Thullen
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Patent number: 7910650Abstract: Methods of preparing conductive thermoset precursors containing carbon nanotubes is provided. Also provided is a method of preparing conductive thermosets containing carbon nanotubes. The carbon nanotubes may in individual form or in the form of aggregates having a macromorpology resembling the shape of a cotton candy, bird nest, combed yarn or open net. Preferred multiwalled carbon nanotubes have diameters no greater than 1 micron and preferred single walled carbon nanotubes have diameters less than 5 nm. Carbon nanotubes may be adequately dispersed in a thermoset precursor by using a extrusion process generally reserved for thermoplastics. The thermoset precursor may be a precursor for epoxy, phenolic, polyimide, urethane, polyester, vinyl ester or silicone. A preferred thermoset precursor is a bisphenol A derivative.Type: GrantFiled: August 20, 2007Date of Patent: March 22, 2011Assignee: Hyperion Catalysis International, Inc.Inventors: Alan Fischer, Timothy Jozokos, James Leacock, Andrew Rich
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Patent number: 7906043Abstract: The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.Type: GrantFiled: August 31, 2009Date of Patent: March 15, 2011Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: John W. Connell, Joseph G. Smith, Joycelyn S. Harrison, Cheol Park, Kent A. Watson, Zoubeida Ounaies
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Patent number: 7902285Abstract: Sulfur-vulcanizable rubber mixture without aromatic process oils, in particular for the tread rubber of vehicle pneumatic tires, containing at least one diene rubber, carbon black, mineral oil plasticizer, and resin. A vehicle pneumatic tire with a tread rubber that is composed at least partially of a rubber mixture of this type vulcanized with sulfur is also disclosed.Type: GrantFiled: January 12, 2007Date of Patent: March 8, 2011Assignee: Continental AktiengesellschaftInventors: Joachim Dumke, Dietmar Soehnen, Annette Stark, Christian Struebel, Hajo Weinreich
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Patent number: 7902275Abstract: Composite materials are disclosed having low filler percolation thresholds for filler materials into the composite matrix material along with methods of controlling filler interconnectivity within the composite matrix material. Methods are, thus, disclosed that provide the ability to control the desired properties of the composites. The composites of the present disclosure are characterized by a “pseudo-crystalline” microstructure formed of matrix particles and filler particles where the matrix particles are faceted and substantially retain their individual particle boundaries and where the filler particles are interspersed between the matrix particles at the individual matrix particle boundaries such that the filler particles form a substantially interconnected network that substantially surrounds the individual faceted matrix particles.Type: GrantFiled: May 24, 2010Date of Patent: March 8, 2011Assignee: Georgia Tech Research CorporationInventors: Rosario A. Gerhardt, Runqing Ou, Zhi Li, Robert J. Samuels, Charles J. Capozzi