Abstract: The invention relates to the use of poly(ethylene-co-propylene) glycol monoalkyl ether or polyethylene glycol monoalkyl ether or poly(ethylene-co-propylene) glycol or polyethylene glycol (meth)acrylic amide or ester monomers capable of contributing to stabilization in the course of a latex preparation process by emulsion polymerization of at least one polymerizable monomer in the presence of an ionizable polymerization initiator.

Abstract: The present invention relates to an active-energy-ray-curable coating composition containing, as essential components, a radical-polymerizable resin (I) containing a polymer structure (?) of a radical-polymerizable unsaturated monomer and a poly(perfluoroalkylene ether) chain (?), and having a resin structure in which a plurality of the polymer structures (?) are linked to each other with the poly(perfluoroalkylene ether) chain (?) therebetween and the polymer structures (?) each have a radical-polymerizable unsaturated group at a side chain thereof; and a polymerization initiator (II). The active-energy-ray-curable coating composition can be used as a coating material that imparts surface properties such as stain-proof properties.

Abstract: An aqueous coating composition (which optionally can coat plastic substrates) the composition comprising a block copolymer and a polymer P; where the block copolymer comprises at least blocks [A]x[B]y; where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism (optionally in solution in the presence of a control agent and a source of free radicals); and wherein block [A] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing water-dispersing functional groups; wherein block [B] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing plastic adhesion promoting functional groups; and wherein polymer P is prepared in the presence of blocks [A]x[B]y. The compositions may be used to coat plastic substrates, foam; surfaces having low surface energy, hydrophobic substrates and/or polyolefins.

Abstract: Adhesive encapsulating compositions for use in electronic devices such as organic electroluminescent devices, touch screens, photovoltaic devices, and thin film transistors are disclosed herein. The adhesive encapsulating compositions include pressure sensitive adhesives comprising one or more polyisobutylene resins, in combination with optional multifunctional (meth)acrylate monomers and/or optional tackifiers.

Abstract: The present disclosure provides a black ink-jet ink, having a pH greater than 7, comprising a first aqueous vehicle, a carbon black pigment, and an amphoteric polymeric dispersant, wherein the amphoteric polymeric dispersant is a block copolymer comprising an A block and a B block, wherein the A block is a segment consisting essentially of an amine monomer; and the B block is a segment comprising an acidic monomer and at least one hydrophobic monomer; wherein the dispersant is neutralized, and with the proviso that the acid number is greater that the amine number, and the B block does not contain an amine monomer. The disclosure further pertains to an ink set comprising this black ink and at least a second ink which contains a reactive species with appropriate cationic agent, salt, or pH capable of destabilizing the carbon black dispersion.

Abstract: The present invention relates to polymer dispersions in polyester polyols, a process for producing them and their use for the production of polyurethanes, in particular microcellular polyurethanes. These polyester polyols have sulfur atoms and are free of olefinically unsaturated groups.

Abstract: A resin composition includes: a polylactic acid resin; an impact-resistant resin which is superior in impact resistance to the polylactic acid resin and is incompatible with or hardly compatible with the polylactic acid resin; and a nucleating agent which promotes crystallization of the polylactic acid resin; the nucleating agent existing at least in the phase of the impact-resistant resin.

Abstract: To provide a resin composition excellent in conformability to special shapes and in holding power without the need of containing a low molecular softener such as a plasticizer, other than a polysiloxane, and a cured product and a sheet using it. A resin composition characterized by comprising (a) an acrylic rubber, (b) a compound containing at least two mercapto groups per molecule, (c) a compound containing at least two acryloyl and/or methacryloyl groups per molecule, (d) an acrylate and/or methacrylate having a C2-12 alkyl group, and (e) acrylic acid or methacrylic acid. The above resin composition which contains a thermally conductive filler. A cured product and sheet using it.

Abstract: The present invention relates to polymer dispersions in polyester polyols, a process for producing them and their use for the production of polyurethanes, in particular microcellular polyurethanes. These polyester polyols have sulfur atoms and are free of olefinically unsaturated groups.

Abstract: The present invention relates to copolymer surfactants and their use in, e.g., coatings such as latex paint and solvent-based paint, and to a method of dispersing colored pigments using the copolymer surfactant, colorant compositions in which at least one pigment is dispersed by a copolymer surfactant of the invention, a paint which has a colorant composition of the invention, and a method for making a paint having a colorant composition of the invention.

Abstract: The present invention provides an aqueous emulsion resin composition which comprises: (a) a resin composition containing at least one fluoroolefin polymer having crosslinkable group(s) at a terminus and/or a side chain of its molecule and at least one non-fluoroolefin polymer having crosslinkable group(s) at a terminus and/or a side chain of its molecule; and (b) at least one curing agent selected from the group consisting of isocyanates, melamines, hydrazides, carbodiimides, silanes and epoxides; and provides an aqueous emulsion resin compositions containing at least one chemically bonded product of a fluoroolefin polymer and a non-fluoroolefin polymer bonded to each other via at least one covalent bond at a terminus and/or a side chain of the molecules wherein one or both of the fluoroolefin polymer and the non-fluoroolefin polymer have crosslinkable group(s).

Abstract: Finely divided, cationic polymer dispersions which are obtainable by emulsion polymerization of ethylenically unsaturated monomers in an aqueous solution of a cationic prepolymer as a dispersant, wherein a cationic prepolymer is first prepared by polymerization of (a) from 10 to 45% by weight of at least one (meth)acrylate which has an amino group and/or a quaternary ammonium group, and/or one (meth)acrylamide which carries an amino group and/or a quaternary ammonium group, (b) from 40 to 85% by weight of at least one optionally substituted styrene, (c) from 0 to 20% by weight of acrylonitrile or methacrylonitrile, (d) from 1 to 15% by weight of at least one ethylenically unsaturated carboxylic acid or one ethylenically unsaturated carboxylic anhydride and (e) from 0 to 20% by weight of at least one nonionic, ethylenically unsaturated monomer differing from the monomers (b) and (c), the sum of (a)+(b)+(c)+(d)+(e) being 100% by weight, in a solution polymerization in a water-miscible organic solvent, and the

Abstract: The present invention relates to an aqueous coating composition having excellent freeze-thaw stability and a low-VOC content, comprising a multi-stage polymer dispersion comprising (a) an inner phase comprising at least one latex polymer derived from at least one monomer and at least one polymerizable alkoxylated surfactant having the structure: R1—R2 wherein R1 is an allyl group selected from the group consisting of CH3—CH?CH— and CH2?CH—CH2—, or an acrylic group and R2 is a radical comprising at least two carbon atoms and at least one oxyethylene or oxypropylene unit; (b) an outer phase having a glass transition temperature of from 30° C. to 110° C. containing at least one ethylenic unsaturated monomer (c) at least one pigment; (d) water; and (e) less than 3.0% by weight based on the total weight of the aqueous coating composition of anti-freeze agents.

Abstract: The present invention relates to a method for preparing a styrene-butadiene latex, more particularly to a method for preparing a styrene-butadiene latex comprising the steps of adding a transition boosting agent to a styrene-butadiene copolymer, stirring the mixture and deodorizing the product. Since unreacted residual monomers and volatile organic compounds are reduced significantly, foul smell during drying at high temperature, irritation to skin and eyes and foul smell of the final product can be prevented.

Abstract: Multipurpose digital inks and methods of printing images onto substrates using such inks are provided. Generally, the digital inks are UV-curable and comprise a multifunctional acrylate monomer, a monofunctional acrylate monomer, a polymer resin, and an oligomer. The inks may be used to digitally print images using an inkjet printer onto a variety of substrates, particularly those made from synthetic resin materials.

Abstract: Aqueous dispersions of water-insoluble polyolefin-based adhesion promoters are formed by dissolving the adhesion promoter in at least one olefinically unsaturated monomer, forming a mini-emulsion with high shear in the presence of water, surfactant and other additives, and then polymerizing the monomer with a monomer-soluble, substantially water insoluble radical initiator. The polymerized product, a stable dispersion (latex) of polyolefin adhesion promoter and polymerized monomer in water, is useful as a primer or as an additive for improving the adhesion of coatings to polyolefin substrates.

Abstract: The invention concerns an aqueous viscoelastic fracturing fluid for use in the recovery of hydrocarbons. According to the invention, the fluid comprises a viscoelastic surfactant and a hydrophobically-modified polymer wherein the concentration of the hydrophobically-modified polymer is comprised between its overlap concentration c* and its entanglement concentration ce.

Abstract: Modified polyolefins are produced by reacting a functionalized polyolefin with one or more ethylenically unsaturated compounds having a functional group reactive with the functional group on the polyolefin. These modified polyolefins may then polymerize in the presence of a photoinitiator upon exposure to ultraviolet radiation and also have the capability of copolymerizing in the presence of a photoinitiator with other ethylenically unsaturated crosslinking agents upon exposure to ultraviolet radiation. These modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines, and therefore may be rendered water-dispersible. The modified polyolefins of the present invention significantly improve the adhesion of paints, inks, and adhesives to various plastic and metal substrates.

Abstract: The present invention relates to formed resinous articles derived from compositions comprising an ASA resin and a special visual effect additive.

Abstract: A method for producing a blend comprising randomly substituted mesogens comprising: providing one or more platform molecules have the following general structure: wherein at least one member selected from the group consisting of X and Y comprises one or more spacer groups; R2 is a bulky organic group whereby, when both X and Y are reacted with polymerizable groups to produce polymerizable mesogens, R2 provides sufficient steric hindrance to achieve a nematic state at room temperature while suppressing crystallinity of the polymerizable mesogens at room temperature; and, R1 and R3 are selected from groups less bulky than R2; and independently substituting at least one member selected from the group consisting of X and Y with a polymerizable group, thereby producing a blend of randomly substituted mesogens.

Abstract: A resin blend and method of producing the resin blend, the resin blend comprising one or more first liquid crystal monomer at a ratio to one or more secondary monomer, said secondary monomer and said ratio being adapted to maintain said resin blend in a nematic liquid crystalline state after addition of an inorganic filler at a temperature of 20° C. for about 30 minutes or more, the resin blend having a polymerization shrinkage of 3 vol. % or less.

Abstract: The present invention relates to a low-odor, polymerizable, cold-curing (meth)acrylate composition for floor coatings exhibiting low health hazards during application and consisting of (A) 50–100 wt % a (meth)acrylate; (B) 0–2 parts by weight per 1 part by weight of (A) of a pre-polymer that dissolves or swells in (A); (C) 2–5 parts by weight per 100 parts by weight of (A+B) of at least one paraffin and/or wax; (D) a redox system, containing an accelerator and a peroxide catalyst or initiator in an amount that is adequate for cold-curing of Component A; and (E) a conventional additive.

Abstract: The present invention provides a cyanoacrylate adhesive composition having high shear bond strength, peeling bond strength, tensile strength and impact bond strength and superior wear characteristics particularly in toy applications where hostile play environments demand hot-cold cycle resistance. The cyanoacrylate adhesive composition contains (a) up to 20% by weight of a cyanoacrylate monomer, (b) a styrene-based elastomeric block copolymer, and (c) a specific solvent which is selected to effect the solution of both components. The invention is also directed to a method of applying the instant adhesives to substrate surfaces.

Abstract: Dental resin cement materials having unique handling properties are provided that comprise a) filler, b) polymerizable resin, and c) a polymeric handling modifier that is dispersed in the polymerizable resin at 25° C. and that has a molecular weight of between about 500 and 100,000. Components a) b) and c) are present in an amount effective to achieve a Viscosity vs Shear Rate Curve that fits a power law model of F(x)=AxB. The correlation value of the material to this curve is greater than 0.85 for both the increasing and decreasing shear rate curves, and the value of B is less than about ?0.01. Resin cements are also provided that comprise acid functionality and water, but which do not comprise an acid reactive filler. Such cements may be self etching, thereby avoiding the need to carry out a separate acid etch step.

Abstract: The present invention relates to aqueous coating compositions containing A) at least one aqueous emulsion polymer, B) one or more polymer dispersions as a dispersion medium, C) at least one pigment, D) optionally a neutralizing agent and E) optionally a coatings additive. The present invention also relates to a process for preparing these aqueous coating compositions by preparing a dispersion paste by mixing components B), C) and D) with some of component E) and then component A) and the remainder of component E) are homogeneously blended with the dispersion paste. The present invention further relates to peelable coatings prepared from these coating compositions for the temporary protection of surfaces.

Abstract: Modified polyolefins are produced by reacting a functionalized polyolefin with one or more ethylenically unsaturated compounds having a functional group reactive with the functional group on the polyolefin. These modified polyolefins may then polymerize in the presence of a photoinitiator upon exposure to ultraviolet radiation and also have the capability of copolymerizing in the presence of a photoinitiator with other ethylenically unsaturated crosslinking agents upon exposure to ultraviolet radiation. These modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines, and therefore may be rendered water-dispersible. The modified polyolefins of the present invention significantly improve the adhesion of paints, inks, and adhesives to various plastic and metal substrates.

Abstract: An adhesion promoter comprises a polymeric strand with an epoxy-reactive group other than a phenolic hydroxyl group, and a crosslinking group that crosslinks the polymeric strand with a rubber in a crosslinking reaction, wherein the polymeric strand is water soluble in an amount of at least 10 g/l, and more preferably at least 100 g/l. Particularly contemplated adhesion promoters may further comprise styrene-butadiene-vinylpyridine copolymer, and may advantageously be employed as a replacement for resorcinol-formaldehyde latex in the fabrication of a rubber containing tire. Especially contemplated rubber compositions may additionally comprise maleinized polybutadiene to synergistically improve adhesion of the rubber to a polymeric fiber coupled via contemplated adhesion promoters.

Abstract: Provided is a rubber composition comprising an inorganic filler, a compound having at least one group A reacting with a rubber and two or more groups B adsorbing on the inorganic filler described above in the same molecule, a compound having the group A reacting with a rubber and an amino group in the same molecule or acrylate or methacrylate having a specific structure and further comprising, if necessary, a silane coupling agent. This makes it possible to provide a rubber composition which is excellent in the dispersibility of an inorganic filler, so that it does not elevate a viscosity of a non-vulcanized rubber and does not damage the processability and which does not bring about roughening on the surface of a rubber and is improved in a storage modulus.

Abstract: This invention provides a composition for anchoring materials in or to concrete or masonry. The composition comprises an alkylacrylate ester monomer, an alkylacrylate ester/methacrylic acid copolymer, a free-radical catalyst and a filler.

Abstract: A low shrinking polymerizable dental material, includes a mixture of a polymerizable di- or poly(meth)acrylate, an alkoxylated bisphenol dimethacrylate, a polymerizable monomer, a polymerization initiator and/or sensitizer, a stabilizer and a filler in a content of 70 to 85 percent. The volumetric shrinkage during polymerization is less than 2.0 vol.-%.

Abstract: An adhesion promoter comprises a polymeric strand with an epoxy-reactive group other than a phenolic hydroxyl group, and a crosslinking group that crosslinks the polymeric strand with a rubber in a crosslinking reaction, wherein the polymeric strand is water soluble in an amount of at least 10 g/l, and more preferably at least 100 g/l. Particularly contemplated adhesion promoters may further comprise styrene-butadiene-vinylpyridine copolymer, and may advantageously be employed as a replacement for resorcinol-formaldehyde latex in the fabrication of a rubber containing tire. Especially contemplated rubber compositions may additionally comprise maleinized polybutadiene to synergistically improve adhesion of the rubber to a polymeric fiber coupled via contemplated adhesion promoters.

Abstract: One embodiment is directed to an adhesive composition that is clear, flexible, and is devoid of non-polar additives and comprises molecules that are polar and particles having a lipophilic surface. In one embodiment, the particles range from 7 nm to 3 &mgr;m in diameter and the adhesive layer is between 0.1 and 5 &mgr;m thick. The particles may be alkyl-converted fumed silica, porous polymer-coated surfaces, or styrene/divinyl benzene polymer. The particles absorb non-polar oils or lubricants that prevent adhesion between printable media and the adhesive layer of the film. The present disclosure is a general solution for oily or lubricated substrates or printed areas. Oily materials are used in inks, dry powder toners, liquid EP toners, and in printers and copiers. The present teachings allow the adhesive to bond well to print media surfaces.

Abstract: This invention provides barrier materials and devices prepared from multi-stage polymer compositions that protect active ingredients and beneficial agents in an aqueous system and that are triggered to release such agents to an environment of use.

Abstract: Marine paint composition comprising: a first polymer comprising from 20 to 70 wt % of monomer units A of at least one hydrolysable either tin or silicium ester of an olefinically unsaturated carboxylic acid or salt of copper, zinc, calcium of an olefinically unsaturated carboxylic acid, the balance being monomer units C selected from the group consisting of esters of ethylenically unsaturated carboxylic acids with C1-C18 alcohols, styrene, alpha-methyl styrene, vinyl toluenes, and mixtures thereof; a second polymer comprising from 5 to 40 wt % of at least one monomer B selected from the group consisting of the N-vinyl lactam monomers of general formula CH2═CH—NR′″″—CO—R′, the N-vinyl amides of general formula CH2═CH—N—CO—R″, the monomer of general formula CH2═CR′″—COO—R″″—NR′″″—CO—R′, the monomers of general formula CH2═CR′″—COO&m

Abstract: A solvent-based water- and oil-repellent agent composition, which contains a graft copolymer having a repeating unit derived from a vinyl monomer having a perfluoroalkyl group and a repeating unit derived from a polymerizable cyclic acid anhydride and an organic solvent, has high product stalibity and high dilution stability and can give high water- and oil-repellency.

Abstract: Aqueous water repellent coating compositions comprising admixtures of (i) water-based water repellent compositions and (ii) water-reducible film-forming polymers are disclosed.

Abstract: Pressure sensitive adhesive formulations of an acrylic polymer grafted with a hydrogenated rubber. In one embodiment, the polymer contains a hydroxyalkyl (meth)acrylate ester which is crosslinked with a titanium-containing chelated metal alkoxide. The adhesive formulations provide an exceptional combination of adhesion to low energy surfaces and high temperature cohesive strength.

Abstract: A low shrinking polymerizable dental material, includes a mixture of a polymerizable di- or poly(meth)acrylate, an alkoxylated bisphenol dimethacrylate, a polymerizable monomer, a polymerization initiator and/or sensitizer, a stabilizer and a filler in a content of 70 to 85 per cent. The volumetric shrinkage during polymerization is less than 2.0 Vol.-%.

Abstract: Pressure sensitive adhesive formulations of an acrylic polymer grafted with a hydrogenated rubber. In one embodiment, the polymer contains a hydroxyalkyl (meth)acrylate ester which is crosslinked with a titanium-containing chelated metal alkoxide. The adhesive formulations provide an exceptional combination of adhesion to low energy surfaces and high temperature cohesive strength.

Abstract: Mixtures containing at least one functionalized low-molecular rubber A, at least one cross-linking agent B having groups which are reactive with respect to the functional groups of the rubber A, accelerators/catalysts C for the cross-linking reaction between A and B, possibly reactive diluents D, vulcanization chemicals E, and also fillers F and auxiliary substances G, with at least one of the average functionalities of the constituents A and B being at least 2, and their use as anti-corrosive coating agents.

Abstract: The invention is accomplished with a curable composition, which contains a resin component A with a subsidiary component a, a resin, which can be polymerized by free radicals, and a curing agent component B with a subsidiary component b, a peroxide curing agent. Before use of the curable composition, the components A and B are kept spatially separated and curing takes place only after components A and B have been mixed. To improve such curable compositions, it is proposed that a subsidiary component c, the leuco form of a dye, especially of a triphenylmethane dye, be added to component A. By following such a procedure, it is achieved that the peroxide activity and the progress of the mixing are monitored simultaneously without delaying the curing of the composition.

Abstract: A method of making ionomeric particulate compositions by suspension polymerization are provided. The method comprises the steps of (a) forming an aqueous phase comprising an acid monomer, a metal oxide, and at least a first and a second surfactant, the first being a monomer surfactant; (b) forming an oil phase comprising at least one vinyl monomer; and (c) suspension polymerizing the aqueous phase with the oil phase to yield an ionomeric particulate composition. The resulting particulates do not have pressure sensitive tack. Particle size in the range of less than 10 micrometers can be made. The ionomeric particulate is made in the absence of a chain transfer agent and thus can have high molecular weight.

Abstract: A cyanoacrylate adhesive contains an added ester, the ester used being at least one partial and/or full ester of monobasic or polybasic aliphatic carboxylic acids containing 1 to 5 carbon atoms directly attached to one another and monohydric to pentahydric aliphatic alcohols containing 1 to 5 carbon atoms directly attached to one another, the number of carbon atoms directly attached to one another in the other aliphatic groups being at most three where one aliphatic group contains 4 or 5 carbon atoms.

Abstract: Use of OO-t-amyl-O(2-ethylhexyl)monoperoxycarbonate as a curing catalyst for bulk molding compounds (“BMC”s) and sheet molding compounds (“SMC”s) is provided.

Abstract: A polymeric dispersant for pigments based on an acrylic graft copolymer wherein the graft copolymer has a weight average molecular weight of about 5,000-100,000 and comprises a hydrophobic polymeric backbone and discrete anionic and nonionic hydrophilic side chains attached to the backbone. These graft copolymers are useful as dispersants in aqueous systems, and are particularly useful in formulating exterior water borne coatings for automobiles and trucks.

Abstract: The present invention provides a resin composition comprising:

Abstract: A polyvinyl alcohol copolymer latex composition comprises an intimate polymer composition obtained from 10% to 60% by weight of a substantially hydrolyzed low molecular weight polyvinyl alcohol (PVOH); 2% to 80% by weight of at least one diene; 2% to 80% by weight of at least one hydrophobic monomer other than a diene and optionally either up to 10% by weight of at least one hydrophilic ethylenically unsaturated acid monomer or up to 40% by weight of a cationic monomer. The copolymer latex composition can be prepared as an emulsion from an aqueous blend of the above listed monomers which are generally added at various stages during the polymerization and a free radical initiator, surfactants, and, if desirable, chain transfer agents. Up to 80% of the PVOH may be added after the monomers have been polymerized.

Abstract: A pressure-sensitive adhesive comprising acrylic microspheres and at least two substantially different binders.

Abstract: The present invention provides a lowly-adhesive coating material comprising 99 to 33% by weight of a fluorine-containing acrylic polymer obtained by polymerizing a monomer composition mainly comprising acrylate or methacrylate having C6-16 perfluoroalkyl groups and 1 to 67% by weight of a fluorine-type oil.

Abstract: The present invention provides a tough denture and a method for producing the denture, which includes solid PMMA as a main component, being added to polar elastomer selected from a group of polyacrylate rubber copolymer, methylmethacrylate-alkylacrylate-styrene terpolymer, and fluororubber, and is fabricated in a process of being mixed and injected into a denture mold. A PMMA denture of present invention shows improved safety to living organisms and increased productivity of molding because of excellent mechanical properties and remarkable elution volume decrease after polymerization in comparison with ordinary type dentures of heat-polymerized PMMA. Furthermore, it is possible to widely apply the denture clinically because of good adaptability in oral applications with economical advantages.