Ethylenic Monomer Contains At Least One Carboxylic Acid Ester Group Patents (Class 524/533)
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Patent number: 12173105Abstract: The present invention provides an A-B block copolymer that enables preparation of a polymer emulsion useful as a binder component for an aqueous inkjet ink that is excellent in inkjet printability and is capable of forming a printed film excellent in durability, such as adhesiveness and rub resistance, on a substrate to be printed, such as a polyolefin-based plastic film. The block copolymer is an A-B block copolymer satisfying the following requirements (1-1) to (1-3). (1-1) Containing 90% by mass or more of a constituent unit derived from a methacrylate-based monomer or the like. (1-2) The chain A has a constituent unit (A-i) derived from methyl methacrylate or the like and a constituent unit (A-ii) derived from 2-ethylhexyl methacrylate or the like. (1-3) The chain B has a constituent unit (B) derived from methacrylic acid, a constituent unit (B-i) derived from methyl methacrylate or the like, and a constituent unit (B-ii) derived from 2-ethylhexyl methacrylate or the like.Type: GrantFiled: August 12, 2021Date of Patent: December 24, 2024Assignee: DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.Inventors: Hiroyuki Shimanaka, Jun Kamabayashi, Akifumi Tanaka, Toshie Okubo, Lu Tian, Yoshikazu Murakami, Sachio Yoshikawa
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Patent number: 11987530Abstract: The present disclosure provides a phase inversion pore-forming agent and a pore-forming method for a fly ash-based ceramic flat membrane support. The phase inversion pore-forming agent includes poly(oxyphenylene sulfone) and N-methylpyrrolidone (NMP), and is used in a preparation process of the fly ash-based ceramic flat membrane support. Pores can be formed through phase inversion, forming straight-through pores with gradient distribution inside the ceramic flat membrane support, thus avoiding a low porosity, a poor water flux, and uneven pore formation of the existing fly ash-based ceramic flat membrane support.Type: GrantFiled: December 28, 2023Date of Patent: May 21, 2024Assignee: Central South UniversityInventors: Zhiguo He, Hui Zhong, Weiqi Xie
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Patent number: 11680122Abstract: Emulsion polymers and coating compositions made therefrom that exhibit exceptional roller stability and stain resistance to both hydrophilic and hydrophobic stains, without sacrificing scrub resistance. The emulsion polymers include, as polymerized units formed at a pH between 3 and 9: a) at least one nonionic or anionic unsaturated monomer in an amount ranging between about 78 wt. % to less than 100 wt. % based on the overall weight of the polymer composition b) one or more strong acid monomer in an amount ranging from about 0.01 wt. % to 2 wt. % based on the overall weight of the polymer composition; and c) at least one lower alkyl acrylate monomer in an amount ranging between about 1 wt. % to 20 wt. % based on the overall weight of the polymer composition.Type: GrantFiled: February 16, 2021Date of Patent: June 20, 2023Assignee: Arkema Inc.Inventors: Wenjun Wu, Karen L. Wallace, Jeanne L. Stallings
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Patent number: 11655322Abstract: A multiphase emulsion polymer for aqueous coating compositions containing little or no organic solvent includes at least one soft phase and at least one hard phase prepared by a multi-stage emulsion polymerization. The hard phase contains a hard phase polymer having a glass transition temperature in a range from 10 C to 100 C which is more than 50 C higher than that of the soft phase polymer. The hard phase is formed as a first stage polymer and the one soft phase is subsequently polymerized in the presence of the first stage polymer. The hard phase polymer includes at least one carboxylic acid monomer and at least one ethylenically unsaturated monomer. A method of making a multiphase emulsion polymer for aqueous coating compositions containing zero or low levels of organic solvent is disclosed. Such aqueous coating compositions may simultaneously have excellent block resistance, freeze thaw stability and low temperature coalescence characteristics.Type: GrantFiled: February 5, 2013Date of Patent: May 23, 2023Assignee: Arkema Inc.Inventor: Wenjun Wu
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Patent number: 11512206Abstract: A sealant for screwing members contains: (a) a self-cross-linking aqueous emulsion; (b) a nanofiberized aramid fiber substance; and (c) a film-forming aid containing a mixture. The mixture contains a compound represented by formula 1: CH3O—(CH2CH2O)n—H. In formula 1, n is 4 or more. An equilibrium reflux boiling point of the overall mixture is 280° C. or higher.Type: GrantFiled: December 4, 2018Date of Patent: November 29, 2022Assignee: THREEBOND CO., LTD.Inventor: Erika Washino
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Patent number: 11427654Abstract: An aqueous coating composition useful in coating a variety of substrates, including interior or exterior portions of food or beverage cans. The coating composition includes a multi-stage polymeric latex having two or more emulsion polymerized stages in an aqueous carrier liquid, wherein the latex has one or both of: (i) a lower glass transition temperature (Tg) emulsion polymerized stage having a calculated Tg that is at least 20° C. lower than a calculated Tg of a higher Tg emulsion polymerized stage, or (ii) a gradient Tg with at least a 20° C. differential in the calculated Tg of monomers fed at the start of polymerization compared to monomers fed at the end of polymerization. When spray-applied on the interior of a food or beverage can, the composition exhibits a global extraction result of less than 50 ppm and a metal exposure value of less than 3 mA.Type: GrantFiled: February 28, 2020Date of Patent: August 30, 2022Assignee: SWIMC LLCInventors: Robert M. O'Brien, Mark Stuetelberg, Joseph D. Desousa, Mary Jo Scandolari, Nikolaus Koch, Stephen Pollin, Nusrah Hussain
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Patent number: 11267984Abstract: Described herein is a coating composition suitable for application to a building panel. The coating composition comprises inorganic pigment, liquid carrier, and a humectant comprising a first ester-containing compound. The liquid carrier may be present in an amount ranging from about 10 wt. % to about 30 wt. % based on the total weight of the coating composition. Described herein are also building panels coated with the coating composition and methods of their production.Type: GrantFiled: August 28, 2018Date of Patent: March 8, 2022Assignee: AWI Licensing LLCInventors: John E. Hughes, Steven L. Masia
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Patent number: 10858510Abstract: The invention relates to graft copolymers—based on non-cross-linked acrylate soft phases from which styrenic monomers are grafted—with a defined micro-structure, having a high transparency, toughness and weather resistance (UV-stability), a process for their preparation and their use, and also to polymer blends comprising said graft copolymers and styrenic polymers, and shaped articles produced therefrom and their use.Type: GrantFiled: August 9, 2017Date of Patent: December 8, 2020Assignee: INEOS STYROLUTION GROUP GMBHInventors: Norbert Niessner, Tobias Schulz, Oliver Carstensen, Konrad Knoll, Manfred Doering, Frank Schoenberger, Julien Fage
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Patent number: 10683405Abstract: The present invention relates to a liquid (meth)acrylic syrup for impregnating a fibrous substrate. The present invention relates in particular to a viscous liquid syrup mainly containing methacrylic or acrylic components. The invention also relates to a process for manufacturing such a syrup. The invention also relates to a process for impregnating a fibrous substrate comprising long glass fibers with said viscous liquid syrup. The invention also relates to a fibrous substrate preimpregnated with said syrup, which is useful for manufacturing transparent parts especially for the building sector. The present invention also relates to a manufacturing process for manufacturing transparent parts obtained via this process.Type: GrantFiled: March 10, 2014Date of Patent: June 16, 2020Assignee: Arkema FranceInventor: Pierre Gerard
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Patent number: 10626286Abstract: A low-VOC-emission waterborne coating is prepared from a waterborne acrylic emulsion, a hydrophilic cross-linking agent, a coalescing agent, additives and a pigment, and the waterborne acrylic emulsion is formed from performing emulsion polymerization on those reactive monomers including an alkyl-group-containing methyl acrylate, a hydroxyl-group-containing methyl acrylate, a carboxyl-group-containing methacrylic acid, a hydroxyl-group-containing acrylic polyester (polyether) polyol, and a methyl acrylate containing alkene-based unsaturated functional groups, which features high hardness, good adhesion, high luster, high acid resistance, high alkali resistance, good weatherability, high solvent resistance, high scrap resistance and high thermal shock resistance.Type: GrantFiled: November 20, 2017Date of Patent: April 21, 2020Assignee: NAN YA PLASTICS CORPORATIONInventors: Te-Chao Liao, Sen-Huang Hsu, Hung-Hsun Wu, Hui-Chun Chuang
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Patent number: 10246601Abstract: A colored fine particle dispersion including emulsified particles including a pigment and a polymer containing a constitutional unit derived from a compound (A) represented by formula (I) and a constitutional unit derived from a polymerizable monomer component including a hydrophobic vinyl-based monomer: wherein BO is a butyleneoxy group; EO is an ethyleneoxy group; M is a cation; m represents an average molar number of addition of BO and is a number of not less than 1 and not more than 10; and n represents an average molar number of addition of EO and is a number of not less than 4 and not more than 25; a process for producing the colored fine particle dispersion; a water-based ink for ink-jet printing including the colored fine particle dispersion; and a use of the colored fine particle dispersion as a colorant for a water-based ink for ink-jet printing.Type: GrantFiled: December 5, 2017Date of Patent: April 2, 2019Assignee: KAO CORPORATIONInventor: Yuuta Matsumoto
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Patent number: 9879148Abstract: A colored fine particle dispersion including emulsified particles including a pigment and a polymer containing a constitutional unit derived from a compound (A) represented by the following general formula (I) and a constitutional unit derived from a polymerizable monomer component including a hydrophobic vinyl-based monomer: wherein BO is a butyleneoxy group; EO is an ethyleneoxy group; M is a cation; m represents an average molar number of addition of BO and is a number of not less than 1 and not more than 10; and n represents an average molar number of addition of EO and is a number of ?4 and ?25; a process for producing the colored fine particle dispersion; a water-based ink for ink-jet printing including the colored fine particle dispersion; and a use of the colored fine particle dispersion as a colorant for a water-based ink for ink-jet printing.Type: GrantFiled: December 1, 2014Date of Patent: January 30, 2018Assignee: KAO CORPORATIONInventor: Yuuta Matsumoto
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Patent number: 9873804Abstract: Active-energy-ray-curable composition including: monofunctional monomers; and polymerization initiator, cured material of the composition satisfying 0.30?D?0.85, where D is difference between peak-area-ratios A and B in infrared-ATR and obtained by: the composition is coated on polycarbonate substrate to form coated film having average thickness of 10 ?m; the film is irradiated with active energy rays having light quantity of 500 mJ/cm2 at UV intensity of 1.Type: GrantFiled: October 21, 2016Date of Patent: January 23, 2018Assignee: Ricoh Company, Ltd.Inventors: Yuuki Mizutani, Mihoko Matsumoto, Masayuki Koyano, Azumi Miyaake, Shun Saito, Mio Kumai
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Patent number: 9777100Abstract: Polymer latex binders useful for preparing coating compositions containing low levels of, or which are substantially free of, volatile organic compounds (VOCs) such as volatile freeze-thaw additives are prepared by multistage emulsion polymerization, wherein one stage provides a copolymer having a relatively high glass transition temperature and containing an oxyalkylene-containing (meth)acrylate comonomer.Type: GrantFiled: December 2, 2016Date of Patent: October 3, 2017Assignee: Arkema Inc.Inventors: Wenjun Wu, Jihui Guo, Jeffrey A. Schneider
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Patent number: 9683146Abstract: Provided is an adhesive composition which is flexible, and exhibits excellent adhesion durability. The adhesive composition comprises (a) a 2-cyanoacrylic acid ester, (b) a polymer having a hydrolyzable silyl group, (c) an elastomer, and (d) an acid catalyst, in which the contents of the components (b), (c), and (d) are from 5 to 200 parts by mass, from 5 to 50 parts by mass, and from 0.0005 to 0.5 parts by mass, respectively, relative to 100 parts by mass of the component (a). Further preferably, the composition contains 0.001 to 5 parts by mass of (e) an onium salt relative to 100 parts by mass of the component (a).Type: GrantFiled: August 7, 2014Date of Patent: June 20, 2017Assignee: TOAGOSEI CO., LTD.Inventors: Kenichi Ishiazaki, Yushi Ando
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Patent number: 9527942Abstract: Polymer latex binders useful for preparing coating compositions containing low levels of, or which are substantially free of, volatile organic compounds (VOCs) such as volatile freeze-thaw additives are prepared by multistage emulsion polymerization, wherein one stage provides a copolymer having a relatively high glass transition temperature and containing an oxyalkylene-containing (meth)acrylate comonomer.Type: GrantFiled: February 5, 2013Date of Patent: December 27, 2016Assignee: Arkema Inc.Inventors: Wenjun Wu, Jihui Guo, Jeffrey A. Schneider
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Patent number: 9051492Abstract: A primer composition including a toughening agent can be applied to a surface to be bonded using a separate curable adhesive composition. The primer composition toughens cured reaction products of the adhesive composition. In some embodiments the primer composition can also enhance reactivity of the curable adhesive composition.Type: GrantFiled: March 26, 2012Date of Patent: June 9, 2015Assignee: Henkel IP & Holding GmbHInventors: Shabbir Attarwala, Ifeanyi Chris Broderick, Prakash S. Patel
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Patent number: 9034973Abstract: The object of the present invention is to provide an intermediate film for laminated glass which prevents reductions of transparency and appearance property caused by permeation of moisture and water. The above object is attained by the present invention, i.e., a composition for forming an intermediate film for a laminated glass which comprises ethylene-vinyl acetate copolymer and a compound having alkyleneoxy group. The composition of the present invention enables the formation of an intermediate film for a laminated glass that restrains white spots from occurring by the permeation of moisture and water.Type: GrantFiled: June 15, 2007Date of Patent: May 19, 2015Assignee: BRIDGESTONE CORPORATIONInventors: Takashi Tsuda, Makiko Shimada
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Publication number: 20150133591Abstract: Anaerobic curing formulations for sealing and/or blocking screws, nuts, bolts and screw or sealing caps are described. The sealing formulation comprises at least one acrylic resin and phenoxy-polyethoxy sulphate. The self-locking formulation comprises at least one diacrylate, an acrylic resin, a microencapsulated polymerisation initiator and a microencapsulated polymerisation accelerator. A method is described for coating a polymerization accelerator to obtain a microencapsulated polymerisation accelerator.Type: ApplicationFiled: May 18, 2012Publication date: May 14, 2015Applicant: Tecnologic 3 S.r.l.Inventors: Gaspare Aita, Antonio Calasso, JR.
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Publication number: 20150133589Abstract: A pigment dispersion includes a pigment, a dispersing agent, a viscosity reducing compound and solvent. The dispersing agent includes a block acrylic compound or a graft acrylic compound.Type: ApplicationFiled: October 30, 2014Publication date: May 14, 2015Inventors: Brian C. AUMAN, Donald Douglas MAY
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Publication number: 20150059606Abstract: An object of the present invention is to provide a relief printing plate precursor for laser engraving that is excellent in rinsing properties for engraving residue and engraving sensitivity and can give a sharp engraved shape. Disclosed is a relief printing plate precursor for laser engraving comprising a relief-forming layer formed of a resin composition for laser engraving, or a crosslinked relief-forming layer obtained by crosslinking the relief-forming layer formed of the resin composition for laser engraving, wherein the resin composition for laser engraving comprises a binder polymer as Component A, and carbon black of which pH is higher than 6 and an average particle size when being dispersed into water is equal to or less than 500 nm as Component B.Type: ApplicationFiled: August 28, 2014Publication date: March 5, 2015Applicant: FUJIFILM CORPORATIONInventor: Yuichi YASUHARA
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Patent number: 8962741Abstract: The present invention provides an overcoat film which has excellent degree of planarization by optimizing the molecular weight of a binder resin included in a thermally curable resin composition for a protective film and the content of each component including the same. In a color filter according to the present invention, it is not necessary to light up all the red, green, and blue (RGB) pixels for eliciting a white light and perform a separate application process of a white portion because an overcoat film according to the present invention may serve as the white portion.Type: GrantFiled: August 12, 2011Date of Patent: February 24, 2015Assignee: LG Chem, Ltd.Inventors: Soon Chun Mok, Seung Hee Lee, Jong Hwi Hwang, Beom Su Park, Sung Hyun Kim, Dae Hyun Kim, Mi Hee Park, U Ra Lee
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Publication number: 20150051334Abstract: Polymer latex binders useful for preparing coating compositions containing low levels of, or which are substantially free of, volatile organic compounds (VOCs) such as volatile freeze-thaw additives are prepared by multistage emulsion polymerization, wherein one stage provides a copolymer having a relatively high glass transition temperature and containing an oxyalkylene-containing (meth)acrylate comonomer.Type: ApplicationFiled: February 5, 2013Publication date: February 19, 2015Applicant: Arkema Inc.Inventors: Wenjun Wu, Jihui Guo, Jeffrey A. Schneider
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Publication number: 20150047968Abstract: The present invention relates to the development and fabrication of thin-film polymer nanocomposites containing vertically aligned nanomaterials, such as single-walled carbon nanotubes (SWNTs). In certain embodiments, the present invention utilizes liquid crystal mesophases of hexagonally packed cylindrical micelles that orient with their long axes parallel to an applied magnetic field, thereby directing the alignment of the nanomaterials, such as SWNTs, sequestered in the micellar cores. In certain embodiments, the mesophase may be a stable, single-phase material containing monomers that can be polymerized after nanotube alignment to form the nanocomposite polymer.Type: ApplicationFiled: June 10, 2014Publication date: February 19, 2015Inventors: Menachem Elimelech, Chinedum Osuji, Meagan Mauter
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Patent number: 8921466Abstract: A process of modifying propylene polymers via melt grafting of polyfunctional monomer (PFMs) involving pre-initiative step thereby facilitating perfect absorption of PFMs on polymer matrix and initiate their grafting prior to reactive extrusion without using free radical initiators so that branching can be introduced in propylene polymer matrix. The modified propylene polymers showed enhanced shear sensitivity, increase in molecular weight, broadening of molecular weight distribution and strain hardening.Type: GrantFiled: January 14, 2011Date of Patent: December 30, 2014Assignee: Reliance Industries LimitedInventors: Uma Sankar Satpathy, Shashikant, Ajit Behari Mathur
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Publication number: 20140345821Abstract: A roll covering is particularly suitable for a roll for the treatment of a paper web, paperboard web, or any other web of fibrous material in a machine for the production and/or finishing the same. The roll covering encompasses at least one layer. The at least one layer is formed of a rubber composition that includes at least one (meth)acrylate compound and a rubber component with at least one crosslinked hydrogenated nitrile rubber. Further, the at least one layer has a recovery rate of at least 12 mm per second and/or a maximal degree of plastic deformation of 0.9%, and a maximal tan ? value of 0.16 determined in accordance with DIN 53513 at 60° C. in tension at 10 Hz, 15% static elongation, and 1% dynamic elongation.Type: ApplicationFiled: January 24, 2013Publication date: November 27, 2014Inventors: Peter Putschoegl, Stephan Ully
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Publication number: 20140316050Abstract: The present invention relates to an aqueous secondary copolymer dispersion comprising a copolymer (P) synthesized from a mixture of free-radically polymerizable monomers (M) comprising (M1) cycloaliphatic esters of acrylic and/or methylacrylic acid; (M2) vinyl esters of aliphatic carboxylic acids; (M3) hydroxy-functional, free-radically polymerizable monomers; (M4) carboxyl-functional, free-radically polymerizable monomers and (M5) hydroxyl- and carboxyl-free (meth)acrylic esters having C1 to C12 hydrocarbon radicals in the alcohol moiety and/or vinylaromatics. The mixture further comprises glycidyl esters of aliphatic carboxylic acids. The invention also relates to a method for the production of such a dispersion, to the use of the dispersion as a coating and as a binder in 2K polyurethane coatings.Type: ApplicationFiled: December 17, 2012Publication date: October 23, 2014Applicant: Bayer Intellectual Property GmbHInventors: Marc Claudius Schrinner, Heinz-Dietmar Gewiss, Nusret Yuva, Martin Melchiors
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Patent number: 8865812Abstract: A liquid sealant composition that can be cured by photoinitiation, heat-activated free radical initiation or both that includes an effective amount of an elastomeric acrylic polyolefin; an effective amount of a low molecular weight acrylic functional monomer component, the acrylic functional monomer component containing one or more unreacted acrylic or methacrylic double bonds, the low molecular weight acrylic functional monomer component having greater than 75% monofunctional monomers, wherein the elastomeric acrylic polyolefin is soluble in the low molecular weight acrylic functional monomer; at least one plasticizer; and at least one curing agent, the curing agent including at least one photoinitiator, at least one heat-activated free radical initiator, or a combination of at least one photoinitiator and at least one heat-activated free radical initiator.Type: GrantFiled: May 20, 2013Date of Patent: October 21, 2014Assignee: ND Industries, Inc.Inventor: Brian J. Phillips
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Patent number: 8859642Abstract: Fine polymer particles are dispersed as primary particles in a vinyl monomer to provide a high quality composition in which the dispersed state and stability of the particles are regulated to a high degree and to provide a curable composition being excellent in handleability and using fine polymer particles as a toughness-imparting agent. For the above, the curable composition of the present invention comprises 100 parts by weight of a vinyl monomer (A) and 0.1 to 100 parts by weight of fine polymer particles (B) having a volume average particle size of 0.05 to 1 m, in which the fine polymer particles (B) are dispersed in the form of primary particles in the vinyl monomer (A).Type: GrantFiled: January 13, 2010Date of Patent: October 14, 2014Assignee: Kaneka CorporationInventor: Masahiro Miyamoto
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Publication number: 20140272575Abstract: Embodiments are directed to a binder for a rechargeable lithium battery, the binder including a copolymer including a repeating unit represented by Chemical Formula X, a repeating unit represented by Chemical Formula Y-1, and a repeating unit represented by Chemical Formula Z, and lithium ions, where Chemical Formula X, Chemical Formula Y-1, and Chemical Formula Z are as described herein.Type: ApplicationFiled: March 11, 2014Publication date: September 18, 2014Applicants: AEKYUNG CHEMICAL CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Eon-Mi LEE, Byung-Joo CHUNG, Nam-Seon KIM, Yang-Soo KIM, Kwang-Sik CHOI
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Patent number: 8835533Abstract: The present invention relates to anaerobically curable compositions demonstrating resistance to elevated temperature conditions.Type: GrantFiled: October 14, 2009Date of Patent: September 16, 2014Assignee: Henkel US IP LLCInventors: Qinyan Zhu, Shabbir Attarwala
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Publication number: 20140228506Abstract: A two part high solids low volatile organic compounds durable curable waterproof liquid rubber formulation with a solids content of at least 60 percent solids by volume based on the total coating formulation, wherein a first component has EPDM, a solvent, a curative, an additive, and a blend of a pigment and a filler. The second component contains solvent and a metal drier.Type: ApplicationFiled: February 12, 2014Publication date: August 14, 2014Applicant: LION COPOLYMER GEISMAR, LLCInventors: Michael J. Molnar, Arthur J. Fontenot, III, Harold William Young, JR., Daniel S. Nelson, Augusto Caesar Ibay
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Publication number: 20140221560Abstract: The present invention relates to a process comprising contacting methyl methacrylate or styrene; a C1-C10-alkyl acrylate; and a polymerizable carboxylic acid monomer with a stable aqueous dispersion of first polymer particles, under emulsion polymerization conditions, to form a stable aqueous dispersion of second polymer particles. The first polymer particles have a Tg in the range of from ?30° C. to 30° C., and the monomers have a calculated Tg in the range of 50° C. to 120° C. The present invention also relates to the dispersion of second polymer particles, which is useful as a binder to improve freeze-thaw stability in a coatings formulation.Type: ApplicationFiled: January 31, 2014Publication date: August 7, 2014Inventors: James C. Bohling, Beth Cooper, Wei Gao, Linus W. Linder, Alvin M. Maurice
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Publication number: 20140205899Abstract: A binder for a rechargeable lithium battery includes a copolymer having a weight average molecular weight of about 10,000 to about 500,000 and including a repeating unit represented by Chemical Formula X and a repeating unit represented by Chemical Formula Y-1: The binder may be used in preparing an electrode for a rechargeable lithium battery and a rechargeable lithium battery including the electrode exhibits improved stability, rate capability, and cycle-life.Type: ApplicationFiled: January 10, 2014Publication date: July 24, 2014Applicants: AEKYUNG CHEMICAL CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Byung-Joo Chung, Eon-Mi Lee, Nam-Seon Kim, Yang-Soo Kim, Kwang-Sik Choi
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Publication number: 20140187659Abstract: The present invention provides a composition of which viscosity does not cause the problem of use at high temperature in the mounting process of electronic device. The present invention relates to a composition for electronic device comprising (a) a (meth)acrylic compound and (c) a particle having a functional group having metal scavenging functionality.Type: ApplicationFiled: March 7, 2014Publication date: July 3, 2014Applicant: HENKEL AG & CO KGAAInventors: Yusuke HORIGUCHI, Kenichiro SATO, Mieko SANO
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Publication number: 20140179823Abstract: The present invention provides low solvent or substantially solvent-free multi-ethylenically unsaturated acrylate composition imbibed particles of an acid functional group containing acrylic polymer for ultraviolet curing coating applications and methods of making the same wherein the acrylic polymer is formed by polymerizing in organic solvent, then neutralized and combined with a multi-ethylenically unsaturated acrylate composition prior to dispersing the mixture into water and, preferably, removing solvent.Type: ApplicationFiled: December 16, 2013Publication date: June 26, 2014Applicant: Rohm and Haas CompanyInventors: Andrew Hejl, Eric Greyson, Wenqin Wang
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Patent number: 8741982Abstract: A bioactive and osteoconductive bone cement is produced from polyacrylates or polymethylacrylates by addition of small amounts of polymerizable monomers containing anionic groups which cause the cement surface to mineralize after being incubated in simulated body fluid. The obtained mineralized layers contain calcium phosphate phases such that the formation of fibrous intermediate layers is prevented once the bone cement has been implanted in bones. Optionally, other additives, e.g. biocompatible calcium salts, biocompatible buffering substances, or x-ray contrast agents, antibiotics, antimicrobial agents, and/or anti-inflammatory agents can be added in order to improve the properties of the cement for individual purposes. The bone cement can be used for anchoring prosthesis components in the bone, stiffening bones, filling and reconstructing all types of bone defects, as dowels for bone screws, or as an implant material for anchoring screws and other implants used for osteosynthesis.Type: GrantFiled: May 9, 2006Date of Patent: June 3, 2014Assignee: InnoTERE GmbHInventor: Berthold Nies
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Patent number: 8741980Abstract: A hardenable two part acrylic composition, a polymer component of the two part hardenable composition and a method of producing a polymer component of the two part composition are disclosed. The hardenable two part acrylic composition includes an acrylic polymer composition first part and an acrylic monomer composition second part. The acrylic polymer composition first part includes a first type of acrylic polymer particles wherein each first type of acrylic polymer particle is formed of a network of coalesced emulsion polymerized acrylic microparticles or is macroporous. The acrylic polymer composition may include emulsion polymerised acrylic polymer particles of particle size between 10 and 2000 nm and includes the use of acrylic polymer particles formed of a network of coalesced emulsion polymerized acrylic microparticles as a dough time reduction agent in a hardenable two part acrylic composition.Type: GrantFiled: August 13, 2009Date of Patent: June 3, 2014Assignee: Lucite International UK LimitedInventors: Michael Stephen Chisholm, David McDonald, Sera Saheb Abed-Ali
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Publication number: 20140107280Abstract: Self-bonding curable fluoroelastomer compositions are provided wherein the compositions including a) a fluoropolymer composition having at least one curable fluoropolymer; and b) a compound selected from the group consisting of aluminum acrylates, silicon acrylates, and ammonia acrylates, wherein the self-bonding curable fluoroelastomer composition is able to bond directly to a substrate. Bonded structures formed of such self-bonding compositions and a substrate having a surface bonded thereto are also described herein along with a method for bonding a self-bonding curable fluoroelastomer composition to a substrate surface. The fluoroelastomers herein may encompass both non-fully fluorinated (FKM) and fully fluorinated (FFKM) elastomers.Type: ApplicationFiled: December 20, 2013Publication date: April 17, 2014Applicant: Greene, Tweed of Delaware, Inc.Inventors: Jiazhong Luo, Eugene Gurevich, Joan Eberhard
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Publication number: 20140066553Abstract: A composite comprising a combination of a self-healing polymer matrix and a carbon fiber reinforcement is described. In one embodiment, the matrix is a polybutadiene graft copolymer matrix, such as polybutadiene graft copolymer comprising poly(butadiene)-graft-poly(methyl acrylate-co-acrylonitrile). A method of fabricating the composite is also described, comprising the steps of manufacturing a pre-impregnated unidirectional carbon fiber preform by wetting a plurality of carbon fibers with a solution, the solution comprising a self-healing polymer and a solvent, and curing the preform. A method of repairing a structure made from the composite of the invention is described. A novel prepreg material used to manufacture the composite of the invention is described.Type: ApplicationFiled: February 22, 2013Publication date: March 6, 2014Inventor: U.S.A. as represented by the Administrator of the National Aeronautics and Space Administration
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Patent number: 8642680Abstract: The present invention provides an active radiation curable ink composition for inkjet recording, the active radiation curable ink composition including: (A) a polymer containing a repeating unit having a radically polymerizable group and having a bicyclo ring structure or a tricyclo ring structure at a site forming a part of a main chain thereof, (B) a photopolymerization initiator, and (C) a radically polymerizable compound having a structure different from that of the (A) radical polymer.Type: GrantFiled: March 28, 2011Date of Patent: February 4, 2014Assignee: FUJIFILM CorporationInventor: Kazuhiro Yokoi
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Publication number: 20140031485Abstract: A method of photo-grafting onto a separation membrane a copolymer includes at least one of: For example, in Structure 1A, x1?2 and y1?1; R1 and R2 are independently selected from the group consisting of CH3 and H; R3 is independently selected from the group consisting of poly(oxyalkylene), quaternary ammonium salts, pyridinium salts, sulfonium salts, sulfobetaines, carboxybetaines, alcohols, phenols, tertiary amines, aryl groups; linear, branched and cyclic alkylenes; linear, branched and cyclic heteroalkylenes; linear, branched and cyclic fluoroalkylenes; and siloxyl; R4 is independently selected from the group consisting of linear, branched, and cyclic alkylenes; linear, branched and cyclic hetroalkylenes; linear, branched and cyclic fluoroalkylenes; phenyl; and siloxyl; and Z1 is 0 or 1.Type: ApplicationFiled: September 4, 2013Publication date: January 30, 2014Applicant: International Business Machines CorporationInventors: Jacquana T. Diep, Young-Hye Na, Ankit Vora
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Publication number: 20140015906Abstract: An ink composition includes (component A) a compound having a group represented by the following Formula (1), (component B1) a monofunctional polymerizable compound, and (component C) a coloring material: wherein, in Formula (1), Ra and Rb each independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; Ra and Rb may be bonded to each other to form a 4- to 6-membered alicyclic structure; Ra and Rb do not represent a hydrogen atom at the same time; and * represents a bonding site.Type: ApplicationFiled: September 17, 2013Publication date: January 16, 2014Applicant: FUJIFILM CORPORATIONInventors: Ippei NAKAMURA, Norihide SHIMOHARA, Koji HIRONAKA
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Publication number: 20140011946Abstract: A stabilizer composition comprising an AB type polymer for use in increasing Open Time of aqueous coating compositions is disclosed. The stabilizers compositions are of utility in many aqueous compositions including paints, stains, varnishes, adhesives and inks. Of particular interest is the use of the stabilizer compositions for in increasing the Open Time of latex paints as well as alkyd emulsion paints.Type: ApplicationFiled: April 19, 2007Publication date: January 9, 2014Inventors: Kirill Bakeev, Sung Gun Chu, Tara Lyn Everett, Dirk Kruythoff, Dekai Loo, Tuyen Thanh Nguyen, Willemina Geesien Salomons, Dirk Kruythoff
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Patent number: 8613623Abstract: A radical-polymerizable acrylic insulating adhesive for NCF-bonding an electronic part to a circuit board includes a (meth)acrylate monomer, a film-forming resin, an inorganic filler, a silane coupling agent, and a radical polymerization initiator. The amount of the inorganic filler is 70 to 160 parts by mass with respect to a total of 100 parts by mass of the (meth)acrylate monomer and the film-forming resin. A radical polymerization cured product of the acrylic insulating adhesive exhibits a glass transition temperature of 150 to 185° C., a linear expansion coefficient (?1) of 30 to 35 ppm in a temperature range that is lower than the glass transition temperature, and a linear expansion coefficient (?2) of 105 to 125 ppm in a temperature range that is equal to or higher than the glass transition temperature. Further, ?2/?1 is greater than or equal to 3.4.Type: GrantFiled: September 2, 2009Date of Patent: December 24, 2013Assignee: Sony Chemical & Information Device CorporationInventor: Daisuke Sato
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VINYL CHLORIDE-BASED RESIN EMULSION, METHOD FOR PRODUCING SAME, WATER-BASED INK, AND RECORDING PAPER
Publication number: 20130331504Abstract: A vinyl chloride-based resin emulsion obtained by using a vinyl chloride-based polymer emulsion, which is obtained by subjecting a vinyl chloride monomer (B) or a monomer mixture comprising a vinyl chloride monomer (B) and an ethylenically unsaturated group-containing monomer (C) to emulsion polymerization in the presence of (A) a styrene-acrylic acid ester oligomer and/or an acrylic acid ester oligomer, as a seed (D), and subjecting a vinyl chloride monomer (E) or a monomer mixture comprising a vinyl chloride monomer (E) and an ethylenically unsaturated group-containing monomer (F) to emulsion polymerization using the seed (D). This vinyl chloride-based resin emulsion exhibits excellent water resistance, moisture resistance, high gloss and alcohol resistance if used in a water-based ink and exhibits excellent color development properties, water resistance, moisture resistance, color visibility, high gloss and release properties if used in a recording paper.Type: ApplicationFiled: March 14, 2012Publication date: December 12, 2013Applicant: NISSIN CHEMICAL INDUSTRY CO., LTD.Inventors: Yasuhiro Mitta, Yuji Gama -
Publication number: 20130321539Abstract: To provide a photopolymerizable inkjet ink, which contains monomer components, and a polymer or a copolymer of styrene, styrene derivative, acrylic acid ester, or acrylic acid, or any combination thereof, wherein the monomer components contain: t-butyl methacrylate, n-pentyl methacrylate, or n-hexyl methacrylate, or any combination thereof; and glycerol dimethacrylate, and wherein the photopolymerizable inkjet ink is free from a diluting solvent.Type: ApplicationFiled: May 23, 2013Publication date: December 5, 2013Inventor: Takao HIRAOKA
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Publication number: 20130310510Abstract: This invention relates to rapid drying lacquers that are particularly useful for automotive OEM refinish applications. The lacquer includes a novel graft copolymer with segmented (or block) arms as a replacement material for all or part of the cellulose acetate butyrate binder component. This invention is also directed to a process for producing coatings from the rapid drying lacquers. These lacquers are especially useful in providing chip and humidity resistant coatings, especially metallic effect coatings, having excellent adhesion and down flop or metallic effect.Type: ApplicationFiled: July 25, 2013Publication date: November 21, 2013Applicant: AXALTA COATING SYSTEMS IP CO LLCInventors: ROBERT JAMES BUTERA, RENEE J. KELLY, SHEAU-HWA MA
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Publication number: 20130309040Abstract: A liquid sealant composition that can be cured by photoinitiation, heat-activated free radical initiation or both that includes an effective amount of an elastomeric acrylic polyolefin; an effective amount of a low molecular weight acrylic functional monomer component, the acrylic functional monomer component containing one or more unreacted acrylic or methacrylic double bonds, the low molecular weight acrylic functional monomer component having greater than 75% monofunctional monomers, wherein the elastomeric acrylic polyolefin is soluble in the low molecular weight acrylic functional monomer; at least one plasticizer; and at least one curing agent, the curing agent including at least one photoinitiator, at least one heat-activated free radical initiator, or a combination of at least one photoinitiator and at least one heat-activated free radical initiator.Type: ApplicationFiled: May 20, 2013Publication date: November 21, 2013Applicant: ND INDUSTRIESInventor: Brian J. Phillips
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Publication number: 20130292054Abstract: The invention relates to a composition for a structural acrylic adhesive that comprises an adhesion promoter including a phosphate ester and a high molecular-weight polyamine as a polymerisation accelerator.Type: ApplicationFiled: July 8, 2013Publication date: November 7, 2013Inventor: Arnaud Curet