Abstract: A dental filling resin composition is disclosed, comprising: a reaction product between an aluminosilicate glass powder containing at least one element selected from Ca, Sr, and Ra and an organic acid containing one or more carboxyl groups in one molecule thereof, a methanol-insoluble polymer, a monomer containing at least one unsaturated double bond and having no acidic group, and a polymerization initiator, and optionally a filler.The dental filling resin composition of the invention has not only superior mechanical characteristics and esthetics but also an ability to release a fluorine ion and therefore, can be suitably used for a wide variety of clinical applications such as filling restoration of tooth, core construction, or sealing of pit and fissure.

Abstract: This invention is directed to an aqueous coating composition containing about 40-90% by weight, based on the weight of the coating composition, of an aqueous carrier and 10-60% by weight, based on the weight of the coating composition, of a binder of(a) about 50 to 98%, based on the weight of the binder, of a crosslinked graft copolymer comprising:(i) 2 to 98%, based on the weight of the graft copolymer, of a polymeric backbone of polymerized mono ethylenically unsaturated monomers and 0.5-10.

Abstract: Orthopedic bone cements of low porosity, prepared by mixing together at least two liquid components under conditions that allow only minimal exposure to air, are disclosed. In a preferred system, each liquid component consists essentially of a solution of a linear (non-crosslinked) polymer or copolymer of methyl methacrylate (PMMA) dissolved in a non-crosslinking methyl methacrylate (MMA) monomer, with one such solution also containing an activator and a polymerization inhibitor and a second solution containing an initiator as well as a polymerization inhibitor. No reinforcing fillers are present, although a small amount (no more than 12% by weight of the total cement composition) of a radiopacifier may be included in the composition.

Abstract: Aqueous dispersions comprising emulsified polyolefins and metal salts of phosphoric acid esters which are useful for sizing glass fibers.

Abstract: A light conducting plate for back lighting which comprises a methacrylic copolymer resin comprising 90 to 99.5% by weight of a methyl methacrylate unit and 0.5 to 10% by weight of an alkyl acrylate unit containing 1 to 8 carbon atoms in the alkyl moiety thereof and having a reduced viscosity of 35 to 60 ml/g in chloroform, the chromaticity of said light conducting plate having x and y color coordinates both ranging from 0.01 to 0.001 as obtained according to JIS-Z-8701.

Abstract: A stainproofing composition having water- and oil-repellency, containing a polymer emulsion prepared by dissolving at least one polyfluoroalkyl group-containing compound selected from the group consisting of a polyfluoroalkyl group-containing (meth)acrylate polymer, a polyfluoroalkyl group-containing polyester, a polyfluoroalkyl group-containing maleate and a polyfluoroalkyl group-containing fumarate in at least one monomer selected from the group consisting of a (meth)acrylate ester, a vinyl ester, a styrene compound and vinylidene chloride, vinyl chloride, emulsifying the resultant solution in water to prepare an oil-in-water emulsion, and polymerizing the emulsion exhibits excellent water- and oil-repellency and stainproof properties. It is also superior in sedimentation stability of the emulsion.

Abstract: Acrylic compositions are provided which comprise a matrix of polymethyl methacrylate having dispersed within it particles comprising 75 to 90 weight percent of polymethyl methacrylate and greater than 10 to 25 weight percent of a comonomer comprising an ethylenically unsaturated monomer that copolymerizes with methyl methacrylate, wherein the particles further comprise more than 0.4 weight percent of a crosslinker.

Abstract: This invention provides polymers useful in coating compositions. The polymers are prepared via a free radical polymerization using ethylenically unsaturated monomers. The polymers of this invention possess pendant allylic groups which are capable of effecting free-radical flux when the compositions are applied to a substrate and exposed to oxygen. Coatings formed from preferred compositions possess superior solvent, print, and block resistance.

Abstract: A polymerization initiator composition comprising 100 parts by weight of an organic boron compound (A) and 10 to 150 parts by weight of an aprotic solvent (B) having a boiling point of 30.degree. to 150.degree. C.; and a dental or surgical adhesive composition containing the above polymerization initiator composition.

Abstract: Disclosed is an aqueous, silicone-modified acrylate polymer emulsion, which is an acrylate polymer emulsion produced by subjecting a monomer system (A) comprising an acrylate monomer selected from the group consisting of an acrylic ester, a methacrylic ester and a mixture thereof to emulsion polymerization in an aqueous medium in the presence of emulsifier (B) selected from the group consisting of a sulfonic acid group-containing ethylenically unsaturated monomer, a sulfonate group-containing ethylenically unsaturated monomer, and a mixture thereof, wherein the acrylate polymer emulsion is silicone-modified using a specific, silicone structure-containing modifier (C) during or after the emulsion polymerization.

Abstract: A latex comprising a free radically polymerized product, said product comprising at least two ethylenically unsaturated monomers, at least one of said monomers having an isocyanate group which is sterically hindered or blocked and at least one other of said ethylenically unsaturated monomers being free of isocyanate functional groups, in an aqueous emulsion in the presence of a free-radical polymerization catalyst, in a manner such that the sterically hindered or blocked isocyanate groups distribute in the outer layer of the latex particle and the method of making such.

Abstract: Polymers comprising reversible hydrophobic functionalities are disclosed. The preferred embodiment polymers comprise Lewis acid segments and Lewis base segments. The polymer segments are, by themselves, hydrophilic and will either swell or dissolve in water. When the segments are incorporated into a polymer according to the present invention, the segments form water-insoluble or hydrophobic complexes. Upon changes in pH, temperature or solvent type, these complexes may dissociate, giving large transitions in polymer viscosity, emulsification ability, mechanical strength or transport properties. These polymers are useful as reversible emulsifiers which form stable emulsions at acidic pH and unstable emulsions at basic pH, as water-borne thickeners having low viscosity at low pH and high viscosity at high pH, as superabsorbing resins, or as coatings for pharmaceutical or agricultural agents.

Abstract: The present invention relates to a mixer system for the production of water-thinnable coating compositions having a precisely defined color shade, from various base colors, which mixer system is characterized in that it comprisesA) various base colors A which contain less than 5% by weight of water, at least one color and/or effect pigment, organic solvent, at least one water-dilutable or water-dispersible acrylic polyurethane resin (A1) and/or polyacrylate resin (A2) and optionally auxiliaries and additives, andB) at least one pigment-free component B which contains water.The present invention also relates to a process for the production of coating compositions using this mixer system and to the use of the mixer system for the production of aqueous basecoats for the coating of automobile bodies and/or plastic parts, in particular for automotive refinishing.

Abstract: An ocular lens material comprising a copolymer obtained by copolymerizing a copolymerizable composition of which the main components are a diene polymer and a monomer capable of copolymerizing with the diene polymer, having high oxygen permeability, high refractive index and high mechanical strength, and being excellent in flexibility and shape recoverability, and its production process are disclosed.

Abstract: Provided are allyl-functional polymers having pendant enamine moieties and preferably also possessing pendant methacrylate groups. The presence of such groups in the polymer allows for a free-radical crosslinking reaction to take place during film formation and provides coatings having superior solvent resistance. Amino-containing waterborne particles can be prepared by reacting propylene imine with carboxylic acid-containing latexes. The amino-functionalized latexes are subsequently reacted at room temperature with for example acetoacetoxyethyl methacrylate. During ambient and thermal cure studies, clear films exhibited significant increases in solvent resistance, gel fraction, and crosslink density.

Abstract: A waterbased dispersion useful for forming aqueous coating composition containing dispersed pigment, an aqueous carrier and a branched polymer dispersant (binder);the branched polymer has a weight average molecular weight of about 5,000-100,000 and contains 20-80% by weight of a hydrophilic backbone and correspondingly 80-20% by weight of macromonomer side chains; whereinthe backbone is of polymerized ethylenically unsaturated monomers and 2-30% by weight, based on the weight of the backbone of polymerized ethylenically unsaturated monomers having an acid-functional group; and wherein at least 10% of the acid-functional groups are neutralized with an amine or an inorganic base and is hydrophilic in comparison to the side chains;the side chains are of macromonomers of polymerized ethylenically unsaturated monomers that are polymerized into the backbone via an ethylenically unsaturated group and the macromonomers have a weight average molecular weight of about 1,000-30,000 and wherein the weight ratio of pigmen

Abstract: This invention relates to aqueous, crosslinkable binder dispersions which have a low solvent content and contain hydroxy-functional polyethers, hydroxy-functional acrylate copolymers and hydroxy- and carboxy-functional acrylate copolymers, to a process for the production of these binders, to one and two-component binder compositions containing these binders and to the use of the binder compositions in coating compositions.

Abstract: A light scattering material is prepared by mixing with and dispersing in a transparent elastomer matrix particles of a transparent material. The matrix has a Tg of lower than room temperature and the transparent material has a different index of refraction form the matrix.

Abstract: The invention concerns a process for the production of block copolymers or aqueous dispersions and emulsions thereof, whereby azo macroinitiators are reacted with radical-polymerizable monomers or a mixture of several radical-polymerizable monomers. The azo macroinitiators are obtained by reacting simple reactive azo compounds with prepolymers with a molecular weight between 400 and 20000, which possess at least 2 functional groups, e.g. polyurethanes or polyesters.The aqueous block copolymer dispersions and emulsions produced according to the invention are suitable for use for the production of paints, adhesives etc.

Abstract: A plugging compound for chemical fastening technology is based on a free-radically polymerizable resin and a free-radical initiator spatially separated therefrom. The plugging compound in question is a self-supporting and storage-stable material which can be inserted in that form directly into a drill-hole.

Abstract: The invention relates to an aqueous resin composition characterized by comprising 80 to 10 parts by weight of modified polyolefin with weight average molecular weight of 1000 to 100000, modified by copolymerizing polypropylene, polyethylene, copolymer of propylene or ethylene with .alpha.-olefin or degradation products of these under heat or with oxidizing agent, radical-generating agent or the like, with 0.1 to 20% by weight of one kind or not less than two kinds of acid anhydride, carboxylic acid or alcohol with radically polymerizable double bond, and 20 to 90 parts by weight of one kind or a mixture of two or more kinds of acrylic or methacrylic monomers, mixed or dissolved and polymerized in water in the presence of surfactant and polymerization initiator. And, the aqueous resin composition of the invention not only shows excellent adhesion to polyolefin, but also has adherence to other organic substrates and inorganic substrates.

Abstract: Synthetic resin particles having a hydrogen bond forming group are swollen, at least one metallic compound capable of forming a hydrogen bond is introduced into the synthetic resin particles, and the metallic compound is hydrolyzed and condensed within the synthetic resin particles and on and in the vicinity of the surface of the synthetic resin particles. An inorganic component is grown by this reaction, and at least part of the grown inorganic component 3 is fixed through a reaction with a hydrogen bond forming group present within the synthetic resin particles 1 and on and in the vicinity of the surface of the synthetic resin particles 1 to prepare a coating composition. The coating composition is coated on the surface of a substrate, and the resulting coating is dried at a temperature of the lowest film forming temperature or above to form a coating.

Abstract: The denture base relining resin comprises a powder component that is a methacrylate ester polymer powder with benzoyl peroxide added thereto and a liquid component that comprises a combination of methyl methacrylate, a methacrylate and a monomer having a specific structure with at least one compound selected from 4-dimethylaminobenzoate and 4,4'-dimethylaminobenzophenone, a specific tertiary amine and a polymerization inhibitor, all incorporated in said liquid component at specific ratios.

Abstract: An essentially stable monomer miniemulsion characterized by small monomer droplet size is prepared and is then polymerized to a polymer latex under free radical polymerization conditions. The monomer miniemulsions herein include, in addition to water, a surfactant, and a monomer or mixture thereof, one or more polymers which function as a polymeric co-surfactant. The monomer miniemulsions are characterized by average monomer droplet size of 10 to 500 nanometers, preferably 80 to 150 nanometers. The amount of polymer added as a co-surfactant is about 0.5 to about 5 percent by weight based on monomer weight. The monomer emulsion may contain either a single monomer or a monomer mixture. The monomer emulsion is polymerized under conventional emulsion polymerization conditions yielding a polymer latex having an average polymer particle size of 10 to 500 nanometers, preferably 80 to 150 nanometers, and a narrow particle size distribution, i.e., a polydispersity index of about 1.05 to about 1.40.

Abstract: The present invention relates to water-dilutable emulsion polymers prepared by multistep emulsion polymerization. To this end,(a1) 0.5 to 5.0% by weight of ethylenically unsaturated monomers containing carboxyl groups, and(a2) from 0.5 to 2.5% by weight of olefinically unsaturated carboxamides,where a total of from 1.0 to 8.0% by weight of hydrophilic ionic and hydrophilic nonionic olefinically unsaturated monomers are employed, and(b) from 92.0 to 99.0% by weight of further ethylenically unsaturated monomers containing no further functional groups,are polymerized in the first step of the emulsion polymerization, where the total amount of monomers in the first step is 100% by weight, and exclusively olefinically unsaturated monomers containing no further functional groups are polymerized in the second step of the emulsion polymerization, and the weight ratio between the monomers polymerized in the first step and the monomers polymerized in the second step is from 30-80%:20-70% by weight.

Abstract: Block copolymers denoted by AB from acrylic or methacrylic acid, the corresponding blocks being denoted by A, and from alkyl acrylate or methacrylate with the alkyl chain being C.sub.1 -C.sub.10, the corresponding blocks being denoted by B. Said copolymer blocks are used as wetting and/or dispersing agents for solid particles in an essentially organic medium consisting of a solvent or a mixture of solvents solubilizing the block B.The invention also concerns solid particle dispersions using the above-defined block copolymers.It also concerns compositions, in particular cosmetic compositions, containing said dispersions.

Abstract: The present invention relates to a casting resin based on curable acrylic and/or methacrylic ester and on finely divided inorganic filler, which contain as adhesion promoters organosilicon compounds and metal acid esters, the casting resin composition containing zirconium acetylacetonate and water. The invention also relates to a process for the preparation of the casting resins and to their use.

Abstract: A photocuring denture base lining material is disclosed, comprising:a powder component comprising a methacrylic acid ester polymer powder and/or a methacrylic acid ester polymer powder having from 0.01 to 5% by weight of a photocuring catalyst compounded therewith; anda liquid component comprising (a) from 10 to 40% by weight of benzyl methacrylate, (b) from 20 to 40% by weight of at least one of compounds represented by the following structural formula (1): ##STR1## wherein R represents an alkyl group, (c) from 20 to 70% by weight of at least one of methacrylic acid esters having two or three methacryloyl groups in one molecule, and (d) from 0.01 to 5% by weight of a photocuring catalyst. The photocuring denture base lining material of the invention is extremely low in the unpleasant odors and irritation, is superior in the fitness and the operability, and has a high surface hardness after curing.

Abstract: This invention discloses a process for preparing a latex which is particularly beneficial for utilization in manufacturing high performance masking tape, which comprises the sequential steps of (1) terpolymerizing a vinyl aromatic monomer, an alkyl acrylate monomer, and an alkyl propenoic acid monomer in an aqueous polymerization medium by free radical polymerization to produce a seed polymer latex; (2) neutralizing the seed polymer latex to a pH of about 6 to about 9 by the addition of an alkali; (3) adding additional vinyl aromatic monomer and alkyl acrylate monomer to the neutralized seed polymer latex; and (4) allowing the additional vinyl aromatic monomer and alkyl acrylate monomer to polymerize in a second polymerization step to a solids content of about 30% to about 50% to produce the latex which is particularly beneficial for utilization in manufacturing high performance masking tape; wherein about 30 percent to about 50 percent of the total amount of vinyl aromatic monomer polymerized is polymerized

Abstract: A non-aqueous dispersion containing, in addition to organic solvents,A) from 15-85% by weight of a dissolved film-forming component of hydroxyl group- and carboxyl-group containing polyesters, (meth)acrylic copolymers or mixtures thereof in which up to half the molecules may be esterified with 1 molecule of maleic acid each, andB) from 15-85% by weight of a disperse phase of uncross-linked (meth)acrylic copolymers having a hydroxyl number of at least 300, obtainable by the radical polymerization ofa) from 80-100% by weight of hydroxyalkyl (meth)acrylates andb) from 0-20% by weight of other .alpha.,.beta.-monounsaturated monomers in the dissolved film-forming component.

Abstract: This invention provides a composition for anchoring materials in or to masonry. The composition comprises a methacrylate ester monomer, a methacrylate ester polymer, a free-radical catalyst and a filler.

Abstract: Dyestuff-containing aqueous dispersions obtainable bya) preparation of at least two copolymers A) and B) in an organic solvent by solution polymerization,A) containing from 5 to 50 % by weight, based on A), of an ethylenically unsaturated acid andB) being essentially free of ethylenically unsaturated acids and the solution polymerization of the copolymers A) or B) being carried out in the presence of the other respective copolymer A) or B) already prepared,b) addition of a dyestuff before, during or after the solution polymerization,c) dispersion of the resulting solution in water andd) removal of the organic solvent if desired, are described.

Abstract: The invention concerns a process for the production of block copolymers or aqueous dispersions and emulsions thereof, whereby azo macroinitiators are reacted with radical-polymerizable monomers or a mixture of several radical-polymerizable monomers. The azo macroinitiators are obtained by reacting simple reactive azo compounds with prepolymers with a molecular weight between 400 and 20000, which possess at least 2 functional groups, e.g. polyurethanes or polyesters.The aqueous block copolymer dispersions and emulsions produced according to the invention are suitable for use for the production of paints, adhesives etc.

Abstract: A self-crosslinking composition contains: (a) an oil having an unsaturated fatty acid or an ester of an unsaturated fatty acid as one of its components, (b) a drier, and (c) a polymer or an elastomer that is capable of crosslinking in the absence of a peroxide. A forming (such as a floor tile, a linoleum long floor material, a wall material and a water-proof sheet) may be manufactured by forming and curing the self crosslinking composition and then adding a filler. Since the self-crosslinking composition is capable of crosslinking without using peroxide, the crosslinking reaction is easily conducted without using special equipment to reject air. The composition has a number of advantages over crosslinking methods that use peroxide, including decreased scorch generation, decreased permanent compressive strain, and superior heat resistance and anti-aging resistance. The composition is free from pollution of sulfur and metal and generates no harmful gas during waste incineration.

Abstract: An aqueous coating composition is provided which comprises a generally lipophilic crosslinkable binder, optionally a chemical curing/crosslinking agent for the crosslinkable binder, and a special reactive amphiphatic emulsifier comprising a lipophilic backbone having separately pendant therefrom (a) at least one activated unsaturated group and (b) at least one of a specified class of hydrophilic polyoxyalkylene groups, and possessing an HLB value of at least 6.0.

Abstract: A self-crosslinking composition contains: (a) an oil having an unsaturated fatty acid or an ester of an unsaturated fatty acid as one of its components, (b) a drier, and (c) a polymer or an elastomer that is capable of crosslinking in the absence of a peroxide. A forming (such as a floor tile, a linoleum long floor material, a wall material and a water-proof sheet) may be manufactured by forming and curing the self crosslinking composition and then adding a filler. Since the self-crosslinking composition is capable of crosslinking without using peroxide, the crosslinking reaction is easily conducted without using special equipment to reject air. The composition has a number of advantages over crosslinking methods that use peroxide, including decreased scorch generation, decreased permanent compressive strain, and superior heat resistance and anti-aging resistance. The composition is free from pollution of sulfur and metal and generates no harmful gas during waste incineration.

Abstract: Gels for thermotropic layers, obtainable by irradiation of a mixture comprisinga) an uncrosslinked polymer,b) monomers capable of free-radical polymerization andc) water or an organic solvent or mixtures thereof, with high-energy light.

Abstract: The present invention relates to a container or bag for garbage which repels animals such as cats, dogs, rats, and crows. The article is made from a composition comprising a polyolefin having 10 to 7000 ppm by weight of a compound selected from methyl salicylate, ethyl salicylate, propyl salicylate, n-butyl salicylate, iso-butyl salicylate, iso-amyl salicylate, and menthol.

Abstract: An air curing polymer composition is disclosed which contains acetoacetate functional polymer and an autoxidizable material. The composition cures on exposure to oxygen. One pack stable ambient curing compositions and a method of stabilizing acetoacetate functional groups to prevent hydrolysis are also disclosed.

Abstract: A solution for forming a graft substrate containing a graft initiator, a catalyst for activating the graft initiator, a first component of water dispersable polymer and a second component of a monomer, each of which includes a functional group for reaction with an activated site on the substrate for grafting thereto and water. A method for grafting at least one of the components to a fiber, yarn or fabric substrate is also disclosed wherein increased flame retarding and yarn integrity is achieved while simultaneously allowing control of fabric porosity. This method does not significantly reduce fabric pliability as compared to uncoated fabric. Furthermore, the graft component may be selectively applied polymer to produce a preferred porosity range or a cutting pattern for the fabric substrate. A fabric, a portion of which includes a graft component or components thereon, forms another embodiment of the invention.

Abstract: An aqueous primer composition comprising a copolymer wherein a cationic monomer, a specific alkoxysilane monomer, a silane macromonomer and an ethylenically unsaturated monomer are contained in aqueous medium. For this reason, regardless of the alkalinity of the substrate, the aqueous primer composition can form a highly water-resistant, alkali-resistant, tough film. Furthermore, compared with the prior art, a higher concentration and a lower viscosity, so that the resulting primer composition shows excellent penetration into the substrate at high concentration and provides for sufficient substrate-reinforcing and water-proofing effects. Moreover, when forming a film thereby and forming a finish layer thereon, this composition shows a high affinity for the top coating or adhesive to insure a firm integration of the finish layer with the substrate surface.

Abstract: This invention provides polymers useful in coating compositions. The polymers are prepared via a free radical polymerization using ethylenically unsaturated monomers. The polymers of this invention possess pendant allylic groups which are capable of effecting free-radical flux when the compositions are applied to a substrate and exposed to oxygen. Coatings formed from preferred compositions possess superior solvent, print, and block resistance.

Abstract: A monomer-rich acrylic syrup is cast including about 10% to about 20% ground acrylic particles. During curing, the particles absorb over half their weight in monomer, and a cured sheet is formed in which the matrix monomer and uncrosslinked polymer form a phase which extends through the particles, while the particles appear to be fused together. Including a crosslinker in the syrup further insures the interpenetration of the matrix phase into the swollen particles. A textured surface is formed, which is useful as an anti-slip surface in bathtubs and shower stalls, after thermoforming.

Abstract: A coating composition for forming a composite metal oxide film containing: (A) at least one member selected from the group consisting of a reaction product, a partial hydrolyzate of the reaction product, and a partial acylated product of the reaction product wherein the reaction product is obtained by a reaction between at least one compound containing a carbonyl group and at least one metal compound; (B) a polyhydric alcohol compound; and (C) at least one member selected from the group consisting of a metal carboxylate compound; a metal nitrate compound; and a metal nitrite compound, which coating solution may also contain an alcohol-soluble polymer, and a process of making the same.

Abstract: Crosslinkable aqueous-based coating compositions are described which are covalently bonded to a wooden surface to which they are applied. The compositions contain a crosslinkable polymer, a mono and/or polyethylenically unsaturated monomer which can be graft polymerized onto cellulose molecules present in said wooden surface, a water soluble peroxy free radical polymerization catalyst, a source of cations capable of creating free radical sites in said cellulose molecules and, optionally, a crosslinking agent for said crosslinkable polymer. The coating may be air dried under ambient conditions to provide a crosslinked coating which is chemically bonded to the underlying wooden surface.

Abstract: An organic colloidal dispersion of polar polymeric microparticles synthesized directly in a non-aqueous polar medium is disclosed. The dispersion is particularly useful for controlling rheological properties such as sag and metallic flake orientation in coating compositions.

Abstract: A textile sizing composition comprising one or more aqueous-based dispersions containing between about 15 and about 50 percent by weight solids wherein said solids comprise one or more polymers derived from one or more ethylenically unsaturated monomers, said solids having an average particle size of less than 100 nanometers is disclosed.

Abstract: An air curing polymer composition is disclosed which contains acetoacetate functional polymer and an autoxidizable material. The composition cures on exposure to oxygen. One pack stable ambient curing compositions and a method of stabilizing acetoacetate functional groups to prevent hydrolysis are also disclosed.

Abstract: Flame retardant latex compositions are disclosed which include natural or synthetic latex grafted with ring-halogenated, ethylenically unsaturated aromatic monomers. The graft latex is used alone or in combination with non-grafted natural or synthetic latex. The compositions are useful as coatings for a wide variety of applications, including fabric backcoatings, carpetings, paints, adhesives, sealants, caulks, non-woven binders and so on.

Abstract: Novel pressure-sensitive adhesives are described which show significant resistance to solvents and working fluids such as jet fuel, hydraulic fluid, de-icing fluid and the like. Adhesive compositions comprise nonaqueous dispersions of copolymers of acrylic monomers prepared in the presence of a vinyl-substituted fluoroalkyl siloxane having the general formula I and a macromonomeric stabilizer. The adhesives prepared from the adhesive compositions exhibit excellent adhesion to glass, aluminum, and low surface-energy materials such as fluoroalkyl siloxane elastomers.