Polyvinyl Alcohol Or Modified Forms Thereof Patents (Class 524/557)
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Patent number: 7112630Abstract: A water-soluble, antimicrobial active polymer and an ink composition are prepared by coupling an antimicrobial active compound to a branch of polyvinylalcohol. An excellent antimicrobial effect is provided without affecting the properties of the ink composition that includes the polymer. The polymer is added to the ink composition in an amount of 1 to 10 parts by weight based on 100 parts by weight of the ink composition. The ink composition provides extended storage stability due to no coagulation, effective antimicrobial effect even in a printed picture, and no irritation to human skin.Type: GrantFiled: August 25, 2003Date of Patent: September 26, 2006Assignee: Samsung Electronics Co., Ltd.Inventors: Kyung-hoon Lee, Seung Min Ryu, Yeon-kyoung Jung
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Patent number: 7078462Abstract: An automatic laundry or dishwashing product in unit dose form comprising at least three distinct zones for delivering into at least three different stages in the washing cycle. The product provides improved cleaning, care and finishing benefits.Type: GrantFiled: February 22, 2005Date of Patent: July 18, 2006Assignee: The Procter & Gamble CompanyInventors: Lynda Anne Speed, Glenn Steven Ward
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Patent number: 7071327Abstract: A superabsorbent polysaccharide can be obtained by crosslinking a polysaccharide or derivative thereof with at least 1% by weight of a flexible spacer having a chain length of at least 9 chain atoms and having terminal activated coupling groups. The flexible spacer may comprise a polyalkyleneglycol with a molecular weight from about 400 to 10,000. The coupling groups may be provided by divinyl sulphone units.Type: GrantFiled: March 9, 2001Date of Patent: July 4, 2006Assignee: SCA Hygiene Products ABInventors: Guiseppe Mensitieri, Fabrizio Porro, Luigi Nicolais, Alessandro Sannino
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Patent number: 7070731Abstract: The present invention provides a new dispersion stabilizer that satisfies, at a high level, the performances required for a dispersion stabilizer used for suspension polymerization. A method of producing a dispersion stabilizer that is useable for suspension polymerization of a vinyl compound and contains a vinyl alcohol polymer (A) includes producing the vinyl alcohol polymer (A) by heat-treating a vinyl alcohol polymer (B) at a temperature of 90 to 180° C. for 0.5 to 20 hours in an atmosphere in which an oxygen concentration is 8000 ppm or lower. The vinyl alcohol polymer (B) has a saponification degree of at least 60 mol % and contains a residual acetic acid group whose block character is in the range of 0.3 to 0.6.Type: GrantFiled: December 11, 2003Date of Patent: July 4, 2006Assignee: Kuraray Co., Ltd.Inventors: Masaki Kato, Kazuyuki Somemiya, Syunji Tago, Yoshiko Sho, legal representative, Yukiko Sho, legal representative, Masako Katayama, Yoko Nakano, Kiyohiko Sho, deceased
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Patent number: 7067575Abstract: A water-soluble film made from a resin composition comprising (A) 100 parts by weight of an anionic group-modified polyvinyl alcohol having a viscosity of 10 to 35 mPa·s measured at 20° C. with respect to a 4% by weight aqueous solution thereof, an average degree of hydrolysis of 80.0 to 99.9% by mole and a rate of anionic group modification of 1 to 10% by mole, (B) 20 to 50 parts by weight of a plasticizer, (C) 2 to 30 parts by weight of a filler, and (D) 0.01 to 2.5 parts by weight of a surfactant. The water-soluble film has an excellent water solubility, and is not gelled or insolubilized even if chemicals containing a boric acid substance, particularly sodium perborate, are packaged therein or even if it is put in an aqueous solution of a boric acid substance, particularly sodium perborate.Type: GrantFiled: November 10, 2003Date of Patent: June 27, 2006Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.Inventors: Syuichi Kitamura, Tomoyoshi Mizutani, Mitsuhiro Hasegawa, Hideki Oono
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Patent number: 7037350Abstract: A composition for chemical-mechanical polishing, comprising an aqueous solution and an abrasive that comprises polymer particles, is described. The polymer particles carry an electrical charge, such that nearby particles repel one another. Accordingly, aggregation of polymer particles may be reduced, minimized or eliminated. The composition may additionally comprise an oxidizing agent. A method of using the composition to polish a substrate surface, such as a substrate surface having a metal surface feature or layer, is also described. A substrate so polished may exhibit good surface characteristics, such as a relatively smooth surface or a reduced number of, or a lack of, microscratches on the surface of the substrate.Type: GrantFiled: July 14, 2003Date of Patent: May 2, 2006Assignee: DA NanoMaterials L.L.C.Inventors: Robert J. Small, Zhefei J. Chen
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Patent number: 7019054Abstract: A formulation, and a process for making same, is disclosed which is useful as a coating or treatment for imparting oil and grease resistance to an underlying substrate. The formulation does not contain any fluorochemicals. At the same time, however, the formulation provides oil and grease resistance properties that are equivalent to known coatings and treatments which contain fluorochemicals, particularly those coatings which are permitted to come into direct contact with food products. Therefore, the formulation of the present invention is ideal for use as a coating for paper and paperboard, including paper packaging such as that utilized in food wrappers, food containers, food receptacles and the like, and for other shaped articles. The formulation is also useful as a coating or treatment for providing release properties to an underlying substrate without the use of silicone.Type: GrantFiled: August 15, 2001Date of Patent: March 28, 2006Inventors: Ajit S. Dixit, Melvin G. Mitchell, Jeanette M. Paris, Mark J. Andersen, Christy M. Huggins
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Patent number: 7015266Abstract: The invention is a polyvinyl alcohol film having an YI value of at most 20, which is formed of a modified polyvinyl alcohol having a degree of polymerization of from 1500 to 5000, an ethylene unit content of from 1 to 4 mol % and a 1,2-glycol bond content of at most 1.4 mol %. The polyvinyl alcohol film gives polarizing films that contain no impurities and have good polarization performance, durability and hue stability.Type: GrantFiled: March 13, 2003Date of Patent: March 21, 2006Assignee: Kuraray Co., Ltd.Inventors: Takanori Isozaki, Tetsushi Hayashi, Toshio Nakai, Naoki Fujiwara
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Patent number: 7014909Abstract: Volatile organic compounds containing carbonyl groups can be released by lithographic printing materials including inks, fountain solutions and printed materials. Volatile organic compounds containing carbonyl groups can also have a serious negative impact on the taste or odor of staple materials such as foodstuffs. The volatile materials can be retained in the lithographic compositions and printed materials can be trapped in the printed materials using an improved reactive technology involving a chemically reactive trap for such volatile carbonyl containing compounds.Type: GrantFiled: February 9, 2004Date of Patent: March 21, 2006Assignees: Graphic Packaging Corporation, Cellresin Technologies, LLCInventors: Boris Vasilyevich Rozynov, William J. Coyle, Willard E. Wood, Neil J. Beaverson
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Patent number: 6992130Abstract: The invention provides a polyvinyl acetal having a degree of acetalization of from 45 to 80 mol %, which is obtained through acetalization of a polyvinyl alcohol that contains from 1 to 15 mol % of ?-olefin units and has a 1,2-glycol bond content of from 1 to 3 mol %, a degree of polymerization of from 100 to 2000 and a degree of hydrolysis of from 80.0 to 99.99 mol %. The polyvinyl acetal has good waterproofness and good compatibility with plasticizer. Having the advantages, it is favorable for interlayer films for laminated glass, binders for ceramic forming, binders for ink or paint, and coating liquids for thermally-developable photographic materials.Type: GrantFiled: July 17, 2003Date of Patent: January 31, 2006Assignee: Kuraray Co., Ltd.Inventors: Takeshi Kusudou, Yousuke Kumaki, Naoki Fujiwara
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Patent number: 6984679Abstract: The invention relates to plasticizer-containing polyvinylbutyrals that are characterized by containing as the plasticizer at least one dibenzoate of alkylene and polyalkylene glycols. The invention further relates to a method for producing said compounds, and to their use in molding compounds of all types, especially for producing films that can for example be used as an intermediate layer in laminated safety glasses.Type: GrantFiled: December 22, 2001Date of Patent: January 10, 2006Assignee: Kurray Specialties Europe GmbHInventors: Bernd Papenfuhs, Martin Steuer
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Patent number: 6984690Abstract: The present invention relates to high-molecular-weight crosslinked polyvinyl butyrals obtainable by crosslinking a polyvinyl butyral with benzofuranone and/or with at least one derivative of the same, as crosslinking reagent, to their use, and to a process for their preparation.Type: GrantFiled: September 26, 2003Date of Patent: January 10, 2006Assignee: Ciba Specialty Chemicals Corp.Inventor: Bernd Papenfuhs
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Patent number: 6982297Abstract: The invention is a film of a vinyl alcohol polymer that contains from 0.01 to 20 mol % of cationic group-containing units and contains from 0.5 to 24 mol % of ?-olefin units having at most 4 carbon atoms. The polyvinyl alcohol film gives polarizing films and polarizer which are resistant to water and have good polarizing properties and which are free from a problem of irregular coloration.Type: GrantFiled: December 12, 2002Date of Patent: January 3, 2006Assignee: Kuraray Co., Ltd.Inventors: Tetsushi Hayashi, Takanori Isozaki, Naoki Fujiwara
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Patent number: 6969552Abstract: A pellet to be used in a multi-layer laminate for storing liquid foods, comprising a hydrophilic reducing organic compound and a hydrophilic and water insoluble thermoplastic resin, wherein the hydrophilic reducing organic compound is kneaded with the hydrophilic and water insoluble thermoplastic resin. The kneaded compound comprised of the hydrophilic reducing organic compound and the hydrophilic and water insoluble thermoplastic resin is then kneaded with a hydrophobic thermoplastic resin and formed into a pellet. The pellet is such that 50 grams of the pellet when stored at 15° C. for one week in a sealed 180 ml container requires the presence of water in order to absorb oxygen.Type: GrantFiled: May 17, 1996Date of Patent: November 29, 2005Assignee: Tetra Laval Holdings & Finance, S.A.Inventors: Morio Hara, Norio Kobayashi, Jun Tanaka, Tadakatsu Ikenoya, Hiroaki Ogita
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Patent number: 6964990Abstract: A resin composition of an ethylene-vinyl alcohol copolymer adheres little to dies and ensures good long-run workability and self-purgeability and its shaped articles have good appearance with few voids and show diminished yellowing.Type: GrantFiled: December 12, 2000Date of Patent: November 15, 2005Assignee: Kuraray Co., Ltd.Inventors: Osamu Kazeto, Naokiyo Inomata, Naoyuki Himi
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Patent number: 6964992Abstract: This invention pertains to an ink jet recording medium comprises a flexible substrate and a coating composition coated on at least one surface of the substrate, wherein the coating composition comprises the product formed from the contact between fumed silica particles and at least one aminoorganosiloxane. The invention also pertains to a method for the preparation of such an ink jet recording medium and to methods for the preparation of a coating composition and a dispersion useful in the preparation of such an ink jet recording medium.Type: GrantFiled: May 16, 2002Date of Patent: November 15, 2005Assignee: Cabot CorporationInventors: Michael D. Morris, Michael S. Darsillo, David J. Fluck, Jason R. Hilton, Rudiger Laufhutte, Michael A. Lucarelli
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Patent number: 6953825Abstract: Treated carbonaceous compositions comprising a carbonaceous material, preferably a carbon black, and an ester polymer treating agent. Also disclosed are polymer compositions incorporating the treated carbonaceous compositions and articles of manufacture formed from the polymer compositions.Type: GrantFiled: November 22, 1995Date of Patent: October 11, 2005Assignee: Cabot CorporationInventors: Robert S. Whitehouse, Jameel Menashi, Thomas F. Reed
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Patent number: 6921790Abstract: The present invention is directed to a resin composition superior in barrier properties and also superior in flexibility, secondary processability and interlayer adhesiveness. The present invention is also directed to an environmentally friendly method for producing a resin composition, the method releasing no carboxylic acid such as acetic acid to the peripheral environment. The invention provides an EVOH resin composition (F) which has a content of an alkali metal salt (A), in terms of the alkali metal, of 0.1 to 20 ?mol/g and a content of a carboxyl acid or its salt (C), in terms of carboxylate radical, of 2 ?mol/g or less and which has an ethylene content of 5 to 60 mol % and a saponification degree of from 80 to 99 mol %. In addition, the invention provides a resin composition comprising the EVOH resin composition (F) and an EVOH having an ethylene content of 5 to 60 mol % and a degree of saponification of 99.2 to 100 mol %.Type: GrantFiled: July 22, 2004Date of Patent: July 26, 2005Assignee: Kuraray Co., Ltd.Inventors: Kenji Nakano, Naohiko Uchiumi, Kaoru Ikeda
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Patent number: 6881490Abstract: Inorganic particle/polymer composites are described that involve chemical bonding between the elements of the composite. In some embodiments, the composite composition includes a polymer having side groups chemically bonded to inorganic particles. Furthermore, the composite composition can include chemically bonded inorganic particles and ordered copolymers. Various electrical, optical and electro-optical devices can be formed from the composites.Type: GrantFiled: April 24, 2003Date of Patent: April 19, 2005Assignee: NanoGram CorporationInventors: Nobuyuki Kambe, Yigal Dov Blum, Benjamin Chaloner-Gill, Shivkumar Chiruvolu, Sujeet Kumar, David Brent MacQueen
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Patent number: 6875809Abstract: Volatile organic compounds containing carbonyl groups can be released by lithographic printing materials including inks, fountain solutions and printed materials. Volatile organic compounds containing carbonyl groups can also have a serious negative impact on the taste or odor of staple materials such as foodstuffs. The volatile materials can be retained in the lithographic compositions and printed materials can be trapped in the printed materials using an improved reactive technology involving a chemically reactive trap for such volatile carbonyl containing compounds.Type: GrantFiled: May 25, 2001Date of Patent: April 5, 2005Assignees: Cellresin Technologies, LLC, Graphic Packaging International, Inc.Inventors: Boris Vasilyevich Rozynov, William J. Coyle, Willard E. Wood, Neil J. Beaverson
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Patent number: 6846875Abstract: The present invention relates to new hydrogels with improved mechanical properties and methods of their preparation. The hydrogels are formed from hydrophilic polymers having function hydroxyl groups and have low elasticity modulus typically less than about 10 kPa, a tensile strength above 1 MPa, an elongation above 50% which makes suitable as medical implants, in particular intraocular lenses. The hydrogels are prepared by a crosslinking method with a comparatively low concentration of hydrophilic polymer of a sufficiently high molecular weight dissolved in a good solvent.Type: GrantFiled: April 10, 2001Date of Patent: January 25, 2005Assignee: Pharmacia Groningen BVInventors: Albert Johan Pennings, Coenraad Jan Spaans, Jacqueline Hermina deGroot
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Patent number: 6841595Abstract: Process for the preparation of protective colloid-stabilized, emulsifier-free, aqueous dispersions based on at least two monomers selected from vinylaromatics, 1,3-dienes and/or (meth)acrylates, in the presence of assistants and, if required, further comonomers in an amount of from 0.1% by weight to 20% by weight, based on the total amount of monomers, wherein at least 10% by weight of the total amount of water are added to the reaction vessel only after the monomers have been added to the reaction vessel and the conversion is at least 40%, based on 100% of the monomers.Type: GrantFiled: July 3, 2002Date of Patent: January 11, 2005Assignee: PolymerLatex GmbH & Co. KGInventors: Davide Brizzolara, Herbert Vorholt
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Patent number: 6840992Abstract: The present invention provides a coating for inkjet media, which includes at least one hydrophobic filler particle; and a binder. Another embodiment of the invention provides an inkjet media, which includes the above-described coating coated on a substrate. Another embodiment of the invention provides a method of inkjet printing, which includes inkjet printing at least one inkjet ink onto a substrate coated with the above-described coating.Type: GrantFiled: April 11, 2001Date of Patent: January 11, 2005Assignee: Degussa AGInventors: Holger Glaum, Astrid Mueller
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Patent number: 6838029Abstract: The present invention relates to a method of producing an ethylene-vinyl alcohol copolymer resin.Type: GrantFiled: January 4, 2002Date of Patent: January 4, 2005Assignee: Kuraray Co., Ltd.Inventors: Takaharu Kawahara, Toshio Tuboi, Yukihiro Ohara, Masao Hikasa, Hiroshi Kawai
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Patent number: 6838505Abstract: A coating fluid for forming a coating on a support for use in inkjet printing comprises a liquid medium having dispersed therein (a) an inorganic oxide selected from aluminium oxide and silica, (b) a binder polymer, and (c) a polymeric crosslinking agent containing functional groups for reaction with the inorganic oxide. The components (a), (b) and (c) are preferably dispersed in an aqueous liquid and the relative amounts of inorganic oxide to polymeric crosslinking agent are from 500:1 to 15:1 preferably 250:1 to 20:1, the relative amounts of inorganic oxide to binder polymer are from 50:1 to 2:1 preferably 20:1 to 4:1 and the relative amounts of binder polymer to polymeric crosslinking agent are from 40:1 to 2:1 preferably from 20:1 to 3:1 the amounts being by weight on a dry basis.Type: GrantFiled: October 16, 2001Date of Patent: January 4, 2005Assignee: Eastman Kodak CompanyInventors: Malcom D. Purbrick, Ian M. Newington, Julie Baker
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Patent number: 6824602Abstract: An improved block paving sand comprising kiln dried sand mixed with a water-soluble polymer. The block paving sand is filled into gaps between blocks and then water is applied thereto. Upon contact with the water, the polymer coats the sand and then sets hard, thereby stabilising the block paving.Type: GrantFiled: August 30, 2002Date of Patent: November 30, 2004Inventors: Paul Andrew Darby, John Thomas Liddy
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Patent number: 6822044Abstract: The use of a copolymer (A) preparable by free-radical polymerization of a) at least one olefinically unsaturated monomer and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and of the general formula I R1R2C═CR3R4 (I) in which the radicals R1, R2, R3 and R4 each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; in an aqueous medium, in a clearcoat material used to produce clearcoats KL and multicoat color and/or effect coating systems ML.Type: GrantFiled: January 11, 2002Date of Patent: November 23, 2004Assignee: BASF Coatings AGInventor: Wolfgang Bremser
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Patent number: 6815075Abstract: A lithographic printing plate precursor comprising an image receiving layer and a waterproof substrate, wherein the image receiving layer comprises: needle filler particles or porous filler particles; and a binder resin comprising a complex of: a resin comprising at least one of a metal atom and a semimetal atom, each of the at least one of a metal atom and a semimetal atom being bonded to an oxygen atom; with a polymer compound represented by the following formula (I): wherein R1, R2, R3 and R4 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 8 carbon atoms; m is 0, 1 or 2; n is an integer of from 1 to 8; L represents a single bond or an organic linking group; and Y represents —NHCOR5, —CONH2, —CON(R5)2, —COR5, —OH, —CO2M or —SO3M wherein R5 represents alkyl group having 1 to 8 carbon atoms, and M represents a hydrogen atom, an alkali metal, alkaline earth metal or an onium.Type: GrantFiled: October 15, 2002Date of Patent: November 9, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Seishi Kasai, Sumiaki Yamasaki
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Patent number: 6806301Abstract: A single fluid lithographic printing ink composition includes a hydrophobic phase and a hydrophilic fluid phase. The hydrophilic fluid phase contains water or a liquid polyol or both. The hydrophobic phase contains a hydrogen bonding vinyl polymer that can hydrogen bond with the hydrophilic fluid phase. The vinyl polymers are preferably branched, but remain soluble in the hydrophobic phase. The invention provides stable inks that can be used as single fluid inks with excellent fountain stability and resistance to toning.Type: GrantFiled: January 21, 2002Date of Patent: October 19, 2004Assignee: Flint Ink CorporationInventors: Mark D. Latunski, Dennis R. Gelarden, Graham C. Battersby, Kevin P. Kingman, Rick A. Balyo, Michael V. Oberski
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Publication number: 20040204538Abstract: The invention discloses self-priming coating composition based on a vinyl terpolymer, a monomeric or oligomeric alkoxy amino resin cross linker and a multi component combination of two or more co-resins selected from (a) oligomeric saturated polyester resin, (b) oligomeric unsaturated polyester resin dissolved in an unsaturated monomer with a free radical initiator (c) oligomeric bifunctional phenolic resole resin and (d) oligomeric epoxy resin (e) low molecular weight polyurethane resin and (f) short to medium oil alkyd resin, wherein said vinyl terpolymer is predominantly polyvinyl formal with polyvinyl alcohol and polyvinyl acetate as two other co-polymers. The composition can be applied as a clear coat or as a pigmented composition with addition of pigment on ferrous and non-ferrous metallic substrate and is particularly suitable for continuous coil coating lines for both dark and light colour metal coatings.Type: ApplicationFiled: April 29, 2004Publication date: October 14, 2004Inventor: Dhrubo Bhattacharya
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Patent number: 6794466Abstract: The present invention elates to a vinyl acetate based polymer latex composition obtained by emulsion polymerization of: (a) polyvinyl alcohol, (c) a monomer mixture comprising vinyl acetate, and (d) optionally one or more additional co-monomer(s), in presence of (c) 0.0001-0.05 wt. % of a chain transfer agent, based on total monomer weight, said vinyl acetate based polymer latex composition having a weight average particle size ≧400 nm and a higher shear thinning factor than the vinyl acetate based polymer latex composition (a), (b) and (d) obtained in the absence of the chain transfer agent (c). According to one embodiment, emulsion polymerization is carried out in presence of 0.001 to 0.05 wt. % of a chain transfer agent selected from the group consisting of aldehydes and chain transfer agents having a similar chain transfer constant with regard to vinyl acetate as the monomer. According to another embodiment, emulsion polymerization is carried out in presence of 0.0001 to 0.01 wt.Type: GrantFiled: October 19, 2001Date of Patent: September 21, 2004Assignee: Air Products Polymers, L.P.Inventors: Helmut Zecha, Rudolf Weissgerber, Francis Petrocelli
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Patent number: 6790891Abstract: Environmentally safe, e.g. biodegradable, paint stripper compositions comprising 10-99 parts dimethyl esters of C4-C6 aliphatic dibasic acids, 0.1-40 parts polyvinyl butyral and 1-90 parts water. The compositions can be mixed, e.g. in high shear to provide stable emulsions which strip paint, e.g. varnish from wood. Certain embodiments of the invention also comprise water soluble organic solvents, water-miscible organic solvents, surfactants, emulsifiers, thickeners and/or pigments.Type: GrantFiled: April 16, 2003Date of Patent: September 14, 2004Assignee: UCB Chip Inc.Inventors: Paul E. Kestyn, Augustin T. Chen, Hong Zhao
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Patent number: 6777477Abstract: The invention relates to a coating solution for forming transparent conductive tin oxide film, a method for producing transparent conductive tin oxide film, and transparent conductive tin oxide film. The coating solution is capable of forming, from an inexpensive starting material such as tin oxide or tin chloride, strong tin oxide film endowed with excellent conductivity and transparency. The coating solution, which is intended to be used for forming, by way of coating, transparent conductive film predominantly containing tin oxide, contains stannic acid as its major component, and a water-soluble polymer having a polar group which is dissolved in the presence of at least one compound selected from the group consisting of ammonia and water-soluble amines.Type: GrantFiled: July 17, 2001Date of Patent: August 17, 2004Assignee: Toyo Gosei Kogyo Co., Ltd.Inventors: Kazuma Niume, Takashi Uchida, Masateru Kimura
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Patent number: 6770688Abstract: A water based ink composition for a ballpoint pen which is comprises an alkali-swelling associative thickener comprising a polymer having a carboxyl group and a hydrophobic group, a pigment, a polar solvent containing water, a pH controlling agent and other additives. It is a water based ink composition which is stable over a long period of time without settling of the pigment itself and can be filled into a ballpoint pen having simplified ink free type structure as is the case with a ballpoint pen using an oil based ink.Type: GrantFiled: April 29, 1999Date of Patent: August 3, 2004Assignee: Mitsubishi Pencil Kabushiki KaishaInventor: Masaru Miyamoto
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Patent number: 6759001Abstract: A method for producing an embossed PVA film, which includes embossing the film such that the crystallinity index of the emboss top is 0.50-0.90. The invention provides an embossed PVA film superior in resistance to blocking even when in a rolled state, in appearance to show the high quality of products, and in resistance to pinholes.Type: GrantFiled: May 17, 2001Date of Patent: July 6, 2004Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.Inventors: Tomoyoshi Mizutani, Syuichi Kitamura, Kenji Hasegawa, Manabu Miyato, Hideki Oono
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Patent number: 6756117Abstract: The present invention comprises the formation of photonic polymer-blend structures having tunable optical and mechanical properties. The photonic polymer-blend structures comprise monomer units of spherical microparticles of a polymer-blend material wherein the spherical microparticles have surfaces partially merged with one another in a robust inter-particle bond having a tunable inter-particle separation or bond length sequentially attached in a desired and programmable architecture. The photonic polymer-blend structures of the present invention can be linked by several hundred individual particles sequentially linked to form complex three-dimensional structures or highly ordered two-dimensional arrays of 3D columns with 2D spacing.Type: GrantFiled: December 20, 2002Date of Patent: June 29, 2004Assignee: The United States of America as represented by the United States Department of EnergyInventor: Michael D. Barnes
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Patent number: 6723783Abstract: Methods of making a modified pigment by reacting a first chemical group and a second chemical group to form a pigment having attached a third chemical group. The first chemical group includes at least one nucleophile and the second chemical group includes at least one electrophile, or vice versa. Resulting modified pigments, and ink compositions containing such pigments, are also described.Type: GrantFiled: January 5, 2001Date of Patent: April 20, 2004Assignee: Cabot CorporationInventors: Paul S. Palumbo, Curtis E. Adams
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Patent number: 6716930Abstract: A method for processing a solution of ethylene-vinyl alcohol copolymer in a solvent other than water, which involves continuously substituting a part of the solvent in the solution with water to produce a high-concentration ethylene vinyl alcohol copolymer solution without gelling, whereby an ethylene-vinyl alcohol copolymer solution is fed into a column vessel selected from a plate column and a packed column, and a part of the solvent in the solution is substituted with water in the column vessel.Type: GrantFiled: August 7, 2001Date of Patent: April 6, 2004Assignee: Kuraray Co., Ltd.Inventors: Noboru Yanagida, Masafumi Mikami
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Patent number: 6716905Abstract: The invention relates to a coating agent, containing at least one conversion product (A) and at least one suitable additive (C), (A) being produced according to a method comprising the following step (i): (iv) reacting a reaction mixture comprising at least one radically convertible monomer in radical conditions, (a) in the presence of at least one radical initiator and a compound (I) of formula (II) wherein R1 to R4 each represent, independently of each other, hydrogen, an unsubstituted or substituted alkyl radical, cycloalkyl radical or aralkyl radical or an unsubstituted or a substituted aromatic hydrocarbon radical, on the condition that at least two of R1 to R4 represent an unsubstituted or a substituted aromatic hydrocarbon radical, in an aqueous phaseType: GrantFiled: June 21, 2001Date of Patent: April 6, 2004Assignees: Coatings AG, BASF AktiengesellschaftInventors: Wolfgang Bremser, Frank Strickmann, Maximilian Bendix, Wolfgang Paulus, Roman Benedikt Raether, David Christie
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Publication number: 20040054069Abstract: A polyvinyl alcohol obtained by hydrolysis of a polyvinyl ester that contains silyl group functionalized monomer units.Type: ApplicationFiled: July 11, 2003Publication date: March 18, 2004Applicant: Kurary Co., Ltd.Inventors: Takeshi Kusudou, Atsushi Jikihara, Naoki Fujiwara
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Patent number: 6706805Abstract: Building materials containing copolymers derived from vinyl ester, (meth)acrylic ester and optionally ethylene comonomers, stabilized with a polyvinylalcohol protective colloid, as their aqueous dispersions or as redispersible polymer powders which are redispersible in water, exhibit improved processing properties and set properties. The copolymers are obtained by emulsion or suspension copolymerization in an at least two step process wherein a) the vinyl ester component is polymerized, optionally with ethylene and further copolymerizable comonomers, to a conversion of from 90 to 100% by weight in a first step, and b) the ester(s) of (meth)acrylic acid are subsequently added and polymerized in a second step. The copolymer dispersion obtained may be dried to form a redispersible copolymer powder.Type: GrantFiled: May 22, 2002Date of Patent: March 16, 2004Assignee: Wacker Polymer Systems, GmbH & Co. KGInventor: Hans-Peter Weitzel
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Patent number: 6693148Abstract: A humidity responsive control device consists of a package having at least one face that is a permeable to liquid and gases and water vapor and is formed by mixing together a) 5 to 50% by weight of a hygroscopic polyacrylate and/or PVA polymer, b) 10 to 60% of porous silica minerals such as vermiculite and perlite, c) 5 to 50% of an absorbent such as zeolite or activated carbon for small molecules such as ammonia and d) 5 to 60% by weight of an aqueous emulsion of a mixture of an active ingredient of one or more of a bacteriocidal, fungicidal or odor masking compounds. The device is effective at eliminating and masking odors under varying humidity conditions.Type: GrantFiled: October 8, 2002Date of Patent: February 17, 2004Assignee: Puro-Systems PTY LTDInventors: David John Tomlinson, Wayne John Linklater
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Patent number: 6689433Abstract: Ink-receiving print media products capable of producing high quality printed images which are light-fast, humid-fast, have low coalescence (graininess) levels, and are characterized by other beneficial attributes. The print media products have at least one ink-receiving layer supported by a substrate. The ink-receiving layer includes a binder blend designed to achieve the aforementioned goals, namely, gelatin, a poly(vinyl alcohol-polyethylene oxide) copolymer, and a poly((styrene)-(n-butyl acrylate)-(methyl methacrylate)-(2-(tert-butylamino) ethyl methacrylate)) copolymer. One or more optional pigments and/or additional binders can also be included within the ink-receiving layer. The ink-receiving layer may optionally be employed in combination with one or more additional material layers thereover or thereunder which can contain, for example, one or more pigments and/or binders.Type: GrantFiled: May 6, 2002Date of Patent: February 10, 2004Assignee: Hewlett-Packard Development Company, L.P.Inventors: Bor-Jiunn Niu, Stefan Schuttel, Meinrad Schaer
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Publication number: 20040014875Abstract: Adhesives and primer compositions that include water, a polymer and a pH indicator. The adhesives and primers have a visually-detectable color when wet, and preferably dry to a clear or transparent film, while having good flow and spreadability. The adhesives and primers provide a visual indication of wetness by including a pH indicator such that when the composition is wet, the pH indicator is colored such that the color and the intensity of the color provides a visual indication of wetness; sufficiency of thickness; and uniformity of application of the adhesive or primer.Type: ApplicationFiled: April 23, 2003Publication date: January 22, 2004Applicant: ROMAN DECORATING PRODUCTSInventors: Gerald Russo, Merle Houck, Bob Puchalski
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Patent number: 6680354Abstract: The present invention is a process for preparing high concentration polyvinyl alcohol (PVA) aqueous mixtures, wherein the PVA solid concentration is at least 14% in the mixture.Type: GrantFiled: July 23, 2002Date of Patent: January 20, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: William J. Knapp, Richard K. Grenville
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Patent number: 6673870Abstract: A composition of polyolefin, ester additive, and hyperbranched polymer with improved tensile energy-to-break value compared to polyolefins wihtout the hyperbranched polymer. The concentration of the hyperbranched polymers can be between about 0.1% and about 10% by weight of the polyolefins. The polyolefins have a melt flow index of about 14 g/10 min or greater.Type: GrantFiled: May 13, 2002Date of Patent: January 6, 2004Assignee: The Procter & Gamble CompanyInventors: Blair Alex Owens, Nancy Eckert Jackson, Dimitris Ioannis Collias
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Publication number: 20030207972Abstract: Environmentally safe, e.g. biodegradable, paint stripper compositions comprising 10-99 parts dimethyl esters of C4-C6 aliphatic dibasic acids, 0.1-40 parts polyvinyl butyral and 1-90 parts water. The compositions can be mixed, e.g. in high shear to provide stable emulsions which strip paint, e.g. varnish from wood. Certain embodiments of the invention also comprise water soluble organic solvents, water-miscible organic solvents, surfactants, emulsifiers, thickeners and/or pigments.Type: ApplicationFiled: April 16, 2003Publication date: November 6, 2003Inventors: Paul E. Kestyn, Augustin T. Chen, Hong Zhao
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Patent number: 6624222Abstract: Environmentally safe, e.g. biodegradable, paint stripper compositions comprising 10-99 parts dimethyl esters of C4-C6 aliphatic dibasic acids, 0.1-40 parts polyvinyl butyral and 1-90 parts water. The compositions can be mixed, e.g. in high shear to provide stable emulsions which strip paint, e.g. varnish from wood. Certain embodiments of the invention also comprise water soluble organic solvents, water-miscible organic solvents, surfactants, emulsifiers, thickeners and/or pigments.Type: GrantFiled: January 24, 2001Date of Patent: September 23, 2003Assignee: UCB CHIP Inc.Inventors: Paul E. Kestyn, Augustin T. Chen, Hong Zhao
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Patent number: 6620889Abstract: The invention relates to crosslinked polymerizates which are capable of absorbing, which are based on partially neutralized, monoethylenically unsaturated monomers that carry acidic groups, which exhibit improved properties, in particular, with regard to their ability to transport liquids when in a swollen state, and which have been subsequently crosslinked on the surface thereof with a combination consisting of an organic crosslinker compound, with the exception of polyols, and of a cation provided in the form of a salt in an aqueous solution.Type: GrantFiled: August 29, 2001Date of Patent: September 16, 2003Assignee: Stockhausen GmbH & Co. KGInventors: Richard Mertens, Jörg Harren
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Patent number: 6613833Abstract: A method for producing an aqueous ethylene-vinyl alcohol copolymer (EVOH) composition that ensures efficient removal of alcohol not worsening the environment in and around working areas, and which provides EVOH pellets of the aqueous composition, which can be produced stably and can be washed rapidly, the method involving introducing an EVOH solution that contains at least 50 parts by weight, relative to 100 parts by weight of EVOH therein, of an alcohol having a boiling point of not higher than 100° C., into a vessel, and contacting it with water vapor in the vessel, thereby letting the alcohol out along with water vapor and taking the resulting aqueous EVOH composition that contains from 0 to 10 parts by weight of the alcohol and from 10 to 500 parts by weight of water, relative to 100 parts by weight of EVOH therein, out of the vessel; and the EVOH pellets obtained by cutting the aqueous EVOH composition obtained in the method.Type: GrantFiled: August 7, 2001Date of Patent: September 2, 2003Assignee: Kuraray Co., Ltd.Inventors: Takaharu Kawahara, Toshio Tuboi, Yukihiro Ohara