Polyvinyl Alcohol Or Modified Forms Thereof Patents (Class 524/557)
  • Patent number: 5504133
    Abstract: A composition for forming transparent conductive films comprises a tin-containing indium oxide (ITO) powder dispersed in a binder solution. The binder solution comprises a mixed organic solvent consisting of at least one polar solvent and at least one non-polar solvent, in which a polymer having a weight-average molecular weight of from 8,000 to 150,000 is dissolved. The polymer contains (a) an acidic functional group in such a proportion that the polymer has an acid number of from 0.5 to 15 mg-KOH/g, or (b) a polyalkylene glycol chain in a proportion of from 0.5% to 40% by weight, or both of (a) and (b) in the molecule. Alternatively, the binder solution comprises an actinic radiation-curable binder, which comprises an acrylate or methacrylate compound containing an acid phosphate group in the molecule. The composition can form, by coating, a transparent conductive film having improved electrical and optical properties.
    Type: Grant
    Filed: October 4, 1994
    Date of Patent: April 2, 1996
    Assignees: Mitsubishi Materials Corporation, Dai Nippon Toryo Co., Ltd.
    Inventors: Masato Murouchi, Toshiharu Hayashi, Akira Nishihara, Masaoki Ishihara
  • Patent number: 5498645
    Abstract: A modeling dough comprising a polar polymeric resin, water, a gellant, and a filler provides a dough resistant to flaking, cracking, and crumbling. In the disclosed invention, the polymeric resin is gelled, thereby providing a water-based resin system that is not sticky yet very ductile. After the dough is air-dried, the components are bound into a solid, durable product. The filler accounts for a large portion of the volume of the dough, so the overall volume is not greatly affected by water loss upon drying. The dough is water-based and easy to wash from skin, carpets, and other surfaces. Dyes and pigments can be easily incorporated into the formula. The dried product is sandable and paintable.
    Type: Grant
    Filed: October 11, 1994
    Date of Patent: March 12, 1996
    Assignee: Binney & Smith Inc.
    Inventors: Karen M. Mariano, Thomas Kauffman, Stacey A. Gregor
  • Patent number: 5496879
    Abstract: A solid or amorphous printing ink, especially a gravure printing ink, is fused to become printable in a fluidized condition. The ink is fixed on imprint material by solidification by heat extraction or cooling. The ink includes a binder-material having at least two component groups with each having at least one member, of which members of the first component group have the property to act as solvent for the members of the second group of components. The members of the first component group are solid state crystalline materials. The materials are solid at ambient temperature with a relatively low melting point. The members of the second component group are in a vitreous solid or amorphous condition at ambient temperature. These materials, especially polymers, are soluble in the molten first component group.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: March 5, 1996
    Assignee: Siegwerk Druckfarben GmbH & Co. KG
    Inventors: Rudolf Griebel, Karl A. Kocherscheid, Klaus Stammen
  • Patent number: 5494702
    Abstract: Solvent free liquid masking compositions comprise from about 5 to about 20 percent by weight of an aliphatic polyol; from about 5 to about 20 percent by weight of a plasticizer; from about 0.1 to about 1 percent by weight of a surfactant; and sufficient water to total 100 percent by weight. A method for protecting selected surfaces from paint in painting operations comprises applying a solvent free liquid masking composition to selected surfaces of an object where paint subsequently applied is not desired; allowing the liquid masking composition to dry, forming a film; painting the object, whereby surfaces carrying the film are protected from the application of paint; and removing the film.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: February 27, 1996
    Assignee: Alco Industries, Inc.
    Inventors: Sally J. Blaine, Kim K. Wilson
  • Patent number: 5482981
    Abstract: Disclosed are optically clear xerogel polymer compositions containing an interpenetrant.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: January 9, 1996
    Assignee: Pilkington Barnes Hind, Inc.
    Inventors: Syed H. Askari, Hermann H. Neidlinger
  • Patent number: 5462981
    Abstract: The method of producing plasticized polyvinyl alcohol by mixing polyvinyl alcohol in the presence of an organic plasticizer and water in a quantity which is insufficient to dissolve the polyvinyl alcohol under normal conditions, includes the steps of:i) pre-plasticizing the polyvinyl alcohol at a maximum temperature no higher than its softening point so as to produce a pre-plasticized polyvinyl alcohol having a melting point below the softening point of the polyvinyl alcohol used, andii) further processing the pre-plasticized polyvinyl alcohol thus produced at a temperature above its melting point, under shear-stress conditions and for a period of time to produce a substantially homogeneous melt.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: October 31, 1995
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Vittorio Bellotti, Gianfranco Del Tredici, Roberto Ponti
  • Patent number: 5457153
    Abstract: Proposed is an aqueous coating composition based on a polyvinyl alcohol suitable for use to provide a protective film on various electronic materials. The composition comprises, as dissolved in water, a partially saponified polyvinyl alcohol having a specified average degree of polymerization and a specified degree of saponification, a fluorine-containing surface active agent and, optionally, a quaternary ammonium hydroxide. The liquid coating composition is preferably freed from sodium ions as an impurity by an ion-exchange treatment.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: October 10, 1995
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Yoshio Hagiwara, Isao Satoh, Hatsuyuki Tanaka, Toshimasa Nakayama
  • Patent number: 5451635
    Abstract: Polymers containing a high percentage of vinyl alcohol units may be blended with copolymers of alkyl methacrylates and unsaturated organic acids and processed into sheet, film, fiber and other objects which exhibit an useful balance of barrier and strength properties.
    Type: Grant
    Filed: July 28, 1993
    Date of Patent: September 19, 1995
    Assignee: Rohm and Haas Company
    Inventors: Edward E. LaFleur, William J. Work
  • Patent number: 5430090
    Abstract: The invention relates to a polyvinyl acetate resin composition comprising a hydrophilic polyvinyl acetate resin rendered soluble or dispersible in water by partial saponification or introduction of hydrophilic groups (A), a hydroxy fatty acid compound of not less than 6 carbon atoms (B) and a plasticizer (C).
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: July 4, 1995
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshihiko Miyamoto, Masahiro Saitoh
  • Patent number: 5412021
    Abstract: A water-base erasable ink composition for use in marking pens which comprises:(a) water as a solvent;(b) a colorant dispersed or dissolved in the water in an amount of 0.5-20% by weight:(c) a water soluble polyvinyl acetal resin as a film-forming agent in an amount of 0.1-15% by weight;and(d) an aqueous emulsion of an aliphatic carboxylic acid ester which is liquid and nonvolatile or only slightly volatile at room temperatures as a separating agent in a dry amount of 1-20% by weight.The ink composition preferably further comprises a polyoxyethylene polyoxypropylene block copolymer, or a lanoline derivative, in particular, ethoxylated cholesterol or ethoxylated isocholesterol, or both of these, as a writing separation assistant.
    Type: Grant
    Filed: August 19, 1993
    Date of Patent: May 2, 1995
    Assignee: Sakura Color Products Corporation
    Inventor: Mikihiko Nakanishi
  • Patent number: 5395873
    Abstract: The present invention relates to a composition for paste, designed, in particular, to be used as a toy paste, which is obtained by immobilization of an aqueous solution of polyvinyl alcohol with a borax.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: March 7, 1995
    Inventor: Henri Mizoule
  • Patent number: 5393804
    Abstract: There is provided a biodegradable composition as obtained from a melt comprising converted starch, a plasticizer and at least one member selected from alkenol homopolymers and/or alkenol copolymers which are combined under conditions sufficient to ensure uniform melt formation, in which the at least one member is present in the composition at a concentration of from 10 to 200 parts per 100 parts of dry converted starch.The invention further relates to methods of making the composition, and to articles made from said composition.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: February 28, 1995
    Assignee: Parke, Davis & Company
    Inventors: Eric George, Eddie Park, Paul A. Altieri, Charles W. Paul
  • Patent number: 5387641
    Abstract: A stable aqueous emulsion comprising:(1) between about 20 and about 50% weight percent synthetic polymer solids, said solids comprising a copolymer or a terpolymer derived from:(a) between about 60 and about 90 mole percent of a vinyl ester, optionally including vinyl alcohol derived from said vinyl ester;(b) between about 10 and about 40 mole percent of one or more water soluble monomers; and(c) between about 0 and about 10 mole percent of an alkyl acrylate or alkyl methacrylate wherein alkyl represents an alkyl group containing between 1 and 20 carbon atoms;(2) between about 0.5 and about 5.0 weight percent of one or more surfactants or protective colloids; and(3) the balance water;wherein said aqueous emulsion has a viscosity of less than 1000 cps at 25.degree. C. and wherein said emulsion can provide adhesive properties and a process for producing the emulsion is provided. The emulsion is particularly suited for use as a wallpaper prepaste adhesive.
    Type: Grant
    Filed: May 25, 1993
    Date of Patent: February 7, 1995
    Inventors: Dominic W. K. Yeung, Richard E. Rice, Dipak Lad
  • Patent number: 5382623
    Abstract: The heterogeneous polymerization of water-insoluble polymer in CO.sub.2 is disclosed. The method comprises providing a heterogeneous reaction mixture comprising CO.sub.2, a monomer, and a surfactant, then polymerizing the monomer to form a water-insoluble polymer.
    Type: Grant
    Filed: February 17, 1994
    Date of Patent: January 17, 1995
    Assignee: The University of North Carolina at Chapel Hill
    Inventors: Joseph M. DeSimone, Elise E. Maury, James R. Combes, Yusuf Z. Menceloglu
  • Patent number: 5378758
    Abstract: Polymers containing a high percentage of vinyl alcohol units may be blended with copolymers of alkyl methacrylates and unsaturated organic acids, the copolymers prefereably containing an adhesion-promoting functionality, the blend preferably containing low levels of a plasticizer to improve melt flow, and the blends in molten form utilized as hot melt adhesives for the bonding of wood, paper, and other celulosic articles.
    Type: Grant
    Filed: December 21, 1993
    Date of Patent: January 3, 1995
    Assignee: Rohm and Haas Company
    Inventors: Robert M. Amici, Newman M. Bortnick, Roger K. Graham, Edward E. LaFleur, William J. Work
  • Patent number: 5376703
    Abstract: Process for lowering the residual monomer content in aqueous plastic dispersions based on polyvinyl esters.Preparation of vinyl ester polymers or vinyl ester copolymers containing aqueous plastic dispersions having reduced contents of undesired residual vinyl ester monomers, caused by the preparation, and, optionally, acetaldehyde from corresponding starting dispersions, such as are obtainable from ethylenically unsaturated monomers by conventional polymerization or copolymerization methods, by selective alkaline saponification of the residual vinyl ester monomers saponifiable under alkaline conditions in the dispersions and preferably simultaneous removal of the acetaldehyde and unsaponified residual vinyl ester monomers from the aqueous dispersions by distillation.
    Type: Grant
    Filed: March 26, 1993
    Date of Patent: December 27, 1994
    Assignee: Hoechst AG
    Inventors: Ernst Noelken, Helmut Rinno, Hans-Ullrich Huth
  • Patent number: 5367015
    Abstract: Preparation of soluble polyvinyl acetals having a low degree of crosslinking, which show improved melt viscosity characteristics, by acetalization of soluble polyvinyl alcohols having a low degree of crosslinking, which have been obtained by hydrolysis or alcoholysis of soluble copolymers having a low degree of crosslinking of vinyl esters and monomers having multiple ethylenic unsaturations, for example, glyoxal bisacrylamide. As against comparable non-crosslinked, soluble polyvinyl acetals, polyvinyl acetals having a low degree of crosslinking according to the present invention show increased intrinsic viscosities and surprisingly exhibit advantageous properties in thermoplastic forming, in particular when extruded in a plastified form. The polyvinyl acetals having a low degree of crosslinking furthermore have improved mechanical properties in comparison with non-crosslinked polyvinyl acetals and, in the form of plastified films, are particularly advantageously employed in the production of composite glass.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: November 22, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Matthias Gutweiler, Matthias Kroggel
  • Patent number: 5364892
    Abstract: A modeling dough comprising gelled poly(vinyl alcohol), water and a filler provides a dough resistant to flaking, cracking, and crumbling. In the disclosed invention, the poly(vinyl alcohol) resin is gelled, thereby providing a water-based resin system that is not sticky yet very ductile. Prior to drying, the dough also exhibits the properties of bounceability and the ability to pick up newsprint. After the dough is air-dried, the poly resin serves to bind the components into a solid, durable product. The filler accounts for a large portion of the volume of the dough, so the overall volume is not greatly affected by water loss upon drying. The dough is water-based and easy to wash from skin, carpets, and other surfaces. Dyes and pigments can be easily incorporated into the formula. The dried product is sandable and paintable.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: November 15, 1994
    Assignee: Binney & Smith, Inc.
    Inventors: Richard E. Miller, Karen Mariano
  • Patent number: 5354803
    Abstract: A surfactantless, formaldehyde-free polyvinyl alcohol graft copolymer binder emulsion for non-woven products is prepared comprising: 12% to 35% of a fully hydrolyzed low or ultra low molecular weight PVOH and 65% to 88% of a vinyl and/or acrylic monomer which is graft copolymerized with the PVOH through emulsion polymerization.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: October 11, 1994
    Assignee: Sequa Chemicals, Inc.
    Inventors: Louis R. Dragner, William C. Floyd
  • Patent number: 5354804
    Abstract: A thermoplastic resin is emulsified by feeding a thermoplastic resin composition obtained by melting and mixing 80 to 98 wt. % of the resin with 2 to 20 wt. % of poly(vinyl alcohol) in a biaxial extruder, supplying water from at least one supply port downstream from the melting zone and kneading the molten composition with water in the biaxial extruder.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: October 11, 1994
    Assignee: Tosoh Corporation
    Inventors: Jun Inada, Fumio Koshiro, Ryoichi Shimizu, Shinichi Sato
  • Patent number: 5349014
    Abstract: A process for the preparation of a polyvinyl butyral having improved properties comprises subjecting a polyvinyl alcohol in an aqueous medium in the presence of butyraldehyde and an acid catalyst and ethoxylated alkylphenol sulfate having the formulaC.sub.9 H.sub.19 --[O]C.sub.6 H.sub.4 --O--[]](CH.sub.2 --CH.sub.2 --O--[]]).sub.n SO.sub.3 Nawhere n=6 or n=7 effective as an emulsifier, neutralizing the reaction mixture to a pH of between 9 and 11, and thereafter recovering the polyvinyl butyral by separating it from the reaction liquor and thoroughly washing it with water.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: September 20, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert Degeilh
  • Patent number: 5349008
    Abstract: Disclosed herein is a process for suspension polymerization of a vinyl polymer which comprises using as the suspending agent a polyvinyl ester polymer having an ionic group at an end thereof or a polyvinyl alcohol polymer having a degree of hydrolysis of 90 mol % or less which is obtained by hydrolysis of the above polyvinyl ester polymer.According to the above-mentioned process, vinyl polymer granules having a sharp granulometric dispersion, high bulk density, high plasticizer absorption and low vinyl monomer residue are obtained.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: September 20, 1994
    Assignee: Kuraray Co., Ltd.
    Inventors: Shigeki Takada, Ken Yuki, Hitoshi Maruyama, Taku Tanaka, Kazunari Igarashi
  • Patent number: 5346935
    Abstract: The hydrogel of the invention contains polyvinyl alcohol (a hydrogel support), and a high water-absorbent resin and/or a hydrophilic high molecular compound, which are capable of containing a large amount of water. The rate of evaporation of water from this hydrogel is slow. The hydrogel retains water for a long time and releases an active ingredient gradually. The hydrogel containing a pharmacologically active substance is useful as a pharmaceutical preparation.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: September 13, 1994
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Yasuyuki Suzuki, Hisayoshi Shimizu
  • Patent number: 5322875
    Abstract: A polyvinylbutyral-based thermoplastic composition which is useful for forming thermoadhesive films for adhering bases onto a glazing. The composition comprises a polyvinylbutyral resin with a hydroxyl group content of between 22 and 26% by weight, a plasticizer for the resin and an orthosubstituted phenolic antioxidizing agent. This composition is useful for forming a thermoadhesive film having good adhesion at the surface of the glass and good stability at high temperatures.
    Type: Grant
    Filed: August 18, 1992
    Date of Patent: June 21, 1994
    Assignee: Saint-Gobain Vitrage
    Inventor: Daniel Dages
  • Patent number: 5308911
    Abstract: There are disclosed a secondary suspending agent for suspension polymerization of a vinyl compound (vinyl chloride, etc.) which comprises an aqueous dispersion comprising as the dispersoid, a polyvinyl ester having a degree of hydrolysis of 60 mol% or less, an average degree of polymerization of 4000 or more and an average particle diameter of 100 .mu.m or less; a suspension stabilizing agent comprising 5 to 70% by weight of the secondary suspending agent (PVA, etc.) and 30 to 95% by weight of a water-soluble high molecular compound having a degree of polymerization of 500 or more, the agent being used for suspension polymerization of a vinyl compound; and a process for producing a vinyl polymer (PVC, etc.) comprising suspension polymerizing a vinyl compound by the use of the above suspension stabilizing agent. Both the agents are well suited for producing vinyl polymer granules enhanced in absorption rate of plasticizer, bulk density, removality of residual monomer and porosity.
    Type: Grant
    Filed: March 9, 1993
    Date of Patent: May 3, 1994
    Assignee: Kuraray Co., Ltd.
    Inventors: Shigeki Takada, Hitoshi Maruyama, Naoki Fujiwara, Kazutoshi Terada
  • Patent number: 5308647
    Abstract: An improved liquid spray masking composition including an effective amount of a non-volatile polyhydroxy component is provided. The preferred polyhydroxy components comprise polyglycerols, especially triglycerols or larger polyglycerols. The presence of such materials in masking compositions improves performance of the compositions with respect to inhibition of high temperature swelling, blistering or spotting of the painted surface to which it is applied.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: May 3, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Larry R. Lappi
  • Patent number: 5306757
    Abstract: Disclosed is an emulsified alkenylsuccinic acid sizing agent useful for acid papermaking. The sizing agent has a solid concentration of at least 25% by weight and comprises an alkenylsuccinic acid which is the reaction product of a branched internal olefin and maleic anhydride and which has been dispersed in water by an emulsifying and dispersing agent comprising polyvinyl alcohol. The sizing agent results in good storage stability and has an excellent sizing effect at a low addition ratio immediately after completion of high-temperature papermaking and over a wide pH range.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: April 26, 1994
    Assignee: Mitsubishi Oil Co., Ltd.
    Inventors: Shigeto Hatanaka, Yoshio Takahashi, Hideto Umekawa
  • Patent number: 5302413
    Abstract: A vehicle masking material and method of use. The masking material in one embodiment includes polyvinyl alcohol, ethyl alcohol, a plasticizer, a surfactant composition including a functional derivative of a fluorinated alkyl chain, and water. The masking material is applied to a surface which is to be protected from paint overspray or other mechanical process, allowed to dry, and paint is applied. After drying of the paint, the masking material is removed by peeling or water washing.
    Type: Grant
    Filed: November 5, 1992
    Date of Patent: April 12, 1994
    Assignee: Cal-West Equipment Company, Inc.
    Inventors: Edward W. Woodhall, Nicholas Kondrats
  • Patent number: 5296535
    Abstract: This invention is for a liquid remoistenable adhesive composition having suitable high temperature and high humidity properties comprising water and a combination of a partially hydrolyzed polyvinyl alcohol and a chemically inert, non-thermoplastic, cold water insoluble, particulate additive which is compatible and dispersible with the polyvinyl alcohol and provides resistance to hygroscopic blocking and thermoplastic blocking.
    Type: Grant
    Filed: May 3, 1990
    Date of Patent: March 22, 1994
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Russell J. Nesiewicz, Christopher T. Fazioli
  • Patent number: 5290636
    Abstract: Improved flame retardant latex coatings are disclosed which comprise copolymers of ring-halogenated aromatic monomer units and alkyl acrylate/methacrylate monomer units, and which may additionally include at least one other monomer. In a first embodiment, the coatings include ring-brominated aromatic monomer units and alkyl acrylate and/or alkyl methacrylate monomer units. In a second embodiment, the coatings include these first two types of monomer units and further include third monomer units from unsaturated esters of saturated carboxylic acids, halogen-free aromatic monomers or unsaturated carboxylic or dicarboxylic acid monomers. In a third embodiment, the coatings include four monomer units, namely ring-brominated aromatic monomer units, alkyl acrylate/methacrylate monomer units, halogen-free aromatic monomer units and unsaturated carboxylic or dicarboxylic acid monomer units.
    Type: Grant
    Filed: April 29, 1992
    Date of Patent: March 1, 1994
    Assignee: Great Lakes Chemical Corp.
    Inventors: Richard S. Rose, Jin-liang Wang, Nicolai A. Favstritsky, David E. May, David J. Honkomp
  • Patent number: 5272200
    Abstract: An aqueous dispersion comprising a dispersoid of an ethylene-vinyl alcohol copolymer having an ethylene content of 15 to 65 mole % and a dispersion stabilizer of a saponified product of an ethylene-vinyl ester copolymer having an ionic group and having an ethylene content of 10 to 70 mole % and a saponification degree of at least 80%. According to the present invention, aqueous dispersions with high solid concentration and having excellent stability during storage or upon use. The film obtained by applying and then drying the aqueous dispersion has excellent gas barrier properties.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: December 21, 1993
    Assignee: Kuraray Co., Ltd.
    Inventors: Junnosuke Yamauchi, Akimasa Aoyama, Toshio Tsuboi, Satoshi Hirofuji, Takeshi Moritani
  • Patent number: 5270380
    Abstract: A method for extending the open time of an aqueous coating composition is provided. This method extends the time during which an aqueous coating can be applied or rebrushed without damaging the film. The open time improvement of this invention is useful for a variety of coatings including paints, stains, varnishes, adhesives, and inks. The aqueous coating composition contains a latex polymer and a modifying compound. More particularly, the latex polymer contains a first reactable group which is complementary to and reacts with a second reactable group in the modifying compound. The complementary reactable groups in the latex polymer and modifying compound provide ionic or covalent binding.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: December 14, 1993
    Assignee: Rohm and Haas Company
    Inventors: Linda A. Adamson, Richard F. Merritt, Asare Nkansah, Jungsik Lee
  • Patent number: 5270379
    Abstract: Fluid coating materials such as paints, ink pastes, personal care creams and the like having a water-base are thickened with an associative thickener which is a vinylamine polymer having a weight average molecular weight above 10.sup.5 and which has been modified by reaction with at least 0.2 mer percent of a linear monoaldehyde having 8 to 30 carbon atoms. A hydrolyzed polymer of N-vinylformamide which has been hydrophobically modified with an aldehyde such as dodecaldehyde, exhibits associative thickening characteristics and is useful in thickening water-based formulations.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: December 14, 1993
    Assignee: Air Products and Chemcials, Inc.
    Inventors: Thomas P. McAndrew, Andrew F. Nordquist, Robert K. Pinschmidt, Jr., Donald P. Eichelberger
  • Patent number: 5268415
    Abstract: Thin self-supporting green compact, less than 25.mu. thick, containing an inorganic substance and as a binder a polymer with a weight average molecular weight of more than 400,000, which polymer in a suitable solvent can form a thermoreversible gel above room temperature, the volume fraction of the inorganic substance being more than 45% relative to the total amount of binder plus inorganic substance and a process to prepare such green compacts.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: December 7, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Jan K. Pieterse, Cornelis W. M. Bastiaansen, Frans Heffels, Willibrordus M. G. F. Pontenagel
  • Patent number: 5262466
    Abstract: A masking composition, which serves to prevent diffusion of one metal into selected areas of a substrate of another metal when said composition is applied to said selected areas, comprises a suspension of a masking powder in an aqueous solution comprising water and water soluble alcohol in which is dissolved polyvinyl alcohol.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: November 16, 1993
    Assignee: Alloy Surfaces Co. Inc.
    Inventor: Alfonso L. Baldi
  • Patent number: 5230733
    Abstract: A water-soluble ink-jet dye for use in ink-jet printing is designed to undergo a reaction, initiated by the loss of water and natural neutralization, as the ink dries on paper, causing the dye to (1) change and lose solubility and (2) bind to the paper. The dye comprises a polymeric chain, to which one or more chromophores are attached. Also attached to the chain are a plurality of hydroxyl or amine groups, up to approximately one-half of which are converted to carboxyl groups. The ink containing the dye is maintained at a basic pH. Upon printing on a print substrate, the dye is neutralized, causing lactone (from hydroxyl groups) or lactam (from amine groups) ring formation. The resulting reacted dye is substantially totally waterfast on the print substrate.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: July 27, 1993
    Assignee: Hewlett-Packard Company
    Inventor: Norman E. Pawlowski
  • Patent number: 5221708
    Abstract: Floorings and flooring compositions containing a plasticized, preferably recovered, PVB resin. In a preferred aspect, the floorings and the flooring compositions contain a major amount of a second compatible resin such as non-plasticized PVB, and also a major amount of a composition insert filler. The floorings can contain substantially reduced levels of chlorine.
    Type: Grant
    Filed: August 6, 1991
    Date of Patent: June 22, 1993
    Assignee: Monsanto Company
    Inventor: Adolf A. Klaiber
  • Patent number: 5218022
    Abstract: The present invention relates to a protective coating composition for electrical or electronic circuits containing a curable polyvinyl acetal polymer and a non-ionic corrosion inhibitor such as an azole. The invention also relates to a method of protectively coating electrical or electronic circuits.
    Type: Grant
    Filed: August 8, 1989
    Date of Patent: June 8, 1993
    Inventor: Neil A. North
  • Patent number: 5186978
    Abstract: A vehicle masking material and method of use. The masking material in one embodiment includes polyvinyl alcohol, ethyl alcohol, glycerine or triethylene glycol, a surfactant, and water. The masking material is applied to a surface which is to be protected from paint overspray or other mechanical process, allowed to dry, and paint is applied. After drying of the paint, the masking material is removed by peeling or water washing.
    Type: Grant
    Filed: November 5, 1991
    Date of Patent: February 16, 1993
    Assignee: Cal-West Equipment Company, Inc.
    Inventors: Edward W. Woodhall, Nicholas Kondrats
  • Patent number: 5171766
    Abstract: A modeling dough comprising gelled poly(vinyl alcohol), water and a filler provides a dough resistant to flaking, cracking, and crumbling. In the disclosed invention, the poly(vinyl alcohol) resin is gelled, thereby providing a water-based resin system that is not sticky yet very ductile. Prior to drying, the dough also exhibits the properties of bounceability and the ability to pick up newsprint. After the dough is air-dried, the poly(vinyl alcohol) resin serves to bind the components into a solid, durable product. The filler accounts for a large portion of the volume of the dough, so the overall volume is not greatly affected by water loss upon drying. The dough is water-based and easy to wash from skin, carpets, and other surfaces. Dyes and pigments can be easily incorporated into the formula. The dried product is sandable, carveable and paintable.
    Type: Grant
    Filed: July 24, 1991
    Date of Patent: December 15, 1992
    Assignee: Binney & Smith Inc.
    Inventors: Karen M. Mariano, Richard E. Miller
  • Patent number: 5143960
    Abstract: A composition comprising (i) a copolymer of ethylene; one or more polar unsaturated alcohols, acids, or esters; and a N-substituted maleimide or (ii) a copolymer of ethylene and one or more polar unsaturated alcohols, acids, or esters grafted with an N-substituted maleimide.
    Type: Grant
    Filed: September 12, 1989
    Date of Patent: September 1, 1992
    Assignee: Nippon Unicar Company Limited
    Inventors: Akitaka Senuma, Toshiyuki Nagai, Kiroku Tsukada, Akio Hayashi
  • Patent number: 5141973
    Abstract: A method of preparing a polyvinyl alcohol hydrogel contains the steps of charging an aqueous solution of a polyvinyl alcohol having a degree of hydrolysis of not less than 95 mol % and an average polymerization degree of not less than 500 into a container, the aqueous solution containing the polyvinyl alcohol in a concentration of not less than 5 wt. %, cooling the aqueous solution of the polyvinyl alcohol at a temperature of from - (minus) 9.degree. C. to - (minus) 3.degree. C., subjecting the aqueous solution of the polyvinyl alcohol to physical stimulation, and then maintaining the aqueous solution of the polyvinyl alcohol at a temperature of from - (minus) 5.degree. C. to + (plus) 5.degree. C. The polyvinyl alcohol hydrogel may be contained in a plastic container. An MRI phanton is composed of the plastic container containing such polyvinyl alcohol hydrogel.
    Type: Grant
    Filed: December 27, 1989
    Date of Patent: August 25, 1992
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Tomokazu Kobayashi, Toshio Morihiro
  • Patent number: 5137954
    Abstract: Sheet for safety glazings made of: a) polyvinyl butyral internally plasticized by the presence in the polymer of C.sub.7 to C.sub.15 aliphatic aldehyde groups and b) an external plasticizer in amount sufficient to provide a sheet glass transition temperature of about 25.degree. to 30.degree. C.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: August 11, 1992
    Assignee: Monsanto Company
    Inventors: Arijit M. DasGupta, Donald J. David, Roland J. Tetreault
  • Patent number: 5134021
    Abstract: Disclosed is an anti-fogging film having a multilayer structure comprised of at least two layers of a cured film formed on a substrate. The cured film contains as main components (A) polyvinyl alcohol and (B) at least one member selected from (a) colloidal silica having an average particle size of 5 to 200 m.mu., (b) an organic silicon compound of the formula R.sup.1 R.sup.2.sub.a SiX.sub.3-a in which R.sup.1 is an organic group having 1 to 10 carbon atoms, R.sup.2 is a hydrocarbon group having 1 to 6 carbon atoms, X is a hydrolyzable group and a is 0 or 1, and (c) a hydrolysis product of an organic silicon compound of the formula R.sup.1 R.sup.2.sub. SiX.sub.3-a in which R.sup.1, R.sup.2, X and a are as defined above, wherein the ratio S.sub.2 /S.sub.1 of the weight ratio S.sub.2 of component (A) to component (B) in the layer contiguous to the topmost surface layer to the weight ratio S.sub.1 of component (A) to component (B) in the topmost surface layer is at least 1.05.
    Type: Grant
    Filed: January 23, 1990
    Date of Patent: July 28, 1992
    Assignee: Toray Industries, Inc.
    Inventors: Hiroshi Hosono, Takashi Taniguchi
  • Patent number: 5112886
    Abstract: Polymers having pendent cationic quaternary nitrogen containing groups form salts with allantoin which provide for a film forming moisture barrier in skin conditioning lotions, ointments, cosmetics conditioning treatments, and pharmaceutical formulations.
    Type: Grant
    Filed: April 7, 1989
    Date of Patent: May 12, 1992
    Assignee: ICI Americas Inc.
    Inventor: Charalambos J. Phalangas
  • Patent number: 5110859
    Abstract: Novel polyvinyl alcohols include, in the polymeric backbone, vinyl units containing pendant hydrophobic groups. The polymers are made by hydrolysis of corresponding polyvinyl acylates under conditions are avoid hydrolysis of the pendant hydrophobic groups from the polymer. These groups are preferably bonded into the polymer as allyl ether units. The hydrophobic units act as internal plasticizers in films or other shaped articles formed from the polymers and, in particular, gives significant benefit in viscosity and other rheology characteristics of aqueous compositions formed from the polymer.
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: May 5, 1992
    Inventors: Peter Flesher, David Farrar
  • Patent number: 5093401
    Abstract: Casting solutions for the production of light-polarizing films or sheets contain, relative to the sum of weights (A)+(B)+(C)+(D)=100% by weight, (A) 30-95% by weight, preferably 40-75% by weight, of water, (B) 1-40% by weight, preferably 4-30% by weight, of vinyl, alcohol polymer, (C) 0.01-5% by weight, preferably 0.02-2% by weight, of the dichroic dyestuff, (D) 0.1-75% by weight, preferably 0.5-50% by weight, of one or several organic compounds from the group consisting of aliphatic polyols having 2-6 C atoms, aliphatic ether polyols having 2-6 C atoms, C.sub.1 -C.sub.4 -alkyl ethers of aliphatic polyols having 2-6 C atoms, aliphatic aminoalcohols having 2-4 C atoms, amides of aliphatic C.sub.1 -C.sub.4 -carboxylic acids, and, if desired, a C.sub.1 -C.sub.4 -monoalcohol, and, if desired (E) further additives customary for casting solutions, for example stabilizers, and wherein if using glycerol solely, the weight ratio of glycerol: vinylalcohol polymer is about 0.2-1:1, preferably 0.3-0.5:1.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: March 3, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Claussen, Friedrich W. Krock
  • Patent number: 5077332
    Abstract: A carefully balanced formulation of a chromate-free wash-primer to be applied to the surface of predetermined metals as a surface conditioner to inhibit the spread of corrosion and to act as a tie-coat. The formulation comprises a mixture of polyvinyl butyl resin and an anti-corrosive pigment selected from salts of borates and salts of phosphates. It does not contain toxic components and therefore does not pose hazards to either operators or the environment, upon application or during subsequent thermal operations or maintenance procedures on metal substrates. The physical and application properties of the product according to the present invention are comparable to those of conventional wash-primers, which are based on zinc tetraoxy chromate, polyvinyl butyral solution in organic solvents and phosphoric acid used as the catalyst for the system.
    Type: Grant
    Filed: January 18, 1989
    Date of Patent: December 31, 1991
    Assignee: Her Majesty the Queen in right of Canada, as represented by the Minister of National Defence
    Inventors: Paul Blattler, Marek Szandorowski
  • Patent number: 5071906
    Abstract: A polarizing film comprising a uniaxially stretched film containing a polyvinyl alcohol having a degree of polymerization of at least about 2,500, and at least one polarizing agent selected from iodine and a dichroic dye, as well as a process for the production of the same. This polarizing film is superior in heat resistance and moist heat resistance to conventional films and has excellent optical properties, such as a high polarizing coefficient and transmittance.
    Type: Grant
    Filed: November 16, 1990
    Date of Patent: December 10, 1991
    Assignee: Unitika Ltd.
    Inventors: Chikafumi Tanaka, Masami Shiozawa, Minoru Nishinohara
  • Patent number: 5061515
    Abstract: The present invention is directed to lacquer binders containing polyvinyl acetal which are suitable for the formation of films and coatings and contain mixtures ofa) polyvinyl acetals andb) organic compounds containing (i) carbodiimide and/or uretone imine groups and (ii) blocked isocyanate groups,the mixtures containing from 1 to 300 parts by weight of component b) per 100 parts by weight of component a).The invention is also directed to a process for the formation of coatings on heat resistant substrates by coating these substrates with a coating composition containing binder, inert solvent and optionally the conventional auxiliary agents and additives used in lacquer technology, followed by curing of the coating at temperatures above about 80.degree. C., characterized in that the coating compositions used contain binders of the type mentioned above. Finally, the present invention is directed to these coated heat resistant substrates.
    Type: Grant
    Filed: April 5, 1990
    Date of Patent: October 29, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Willi Dunwald, Hans Schlegel