Si-c, Si-h Contains Dnrm, Metal-c Or Metal-h Bond Or Organic Compound Containing Si Patents (Class 524/730)
  • Patent number: 5688902
    Abstract: Process for the preparation of polyimides or of their polypeptide hydrolysates which are at least 80% biodegradable, by thermal polycondensation of at least one amino acid, optionally followed by hydrolysis, the thermal polycondensation step being carried out in the presence of at least one "acid catalyst" chosen fromsulphuric, nitric, phosphorous, sulphurous, hydrofluoric, silicic and sulphonic acids, organic sulphonic acids containing less than 50 carbon atoms, amino acids bearing a non-carboxyl strong acid function, organic phosphonic acids, organic carboxylic acids having a pK.sub.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: November 18, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Marie Bernard, Jean-Luc LePage, Arnaud Ponce, Florence Tournilhac
  • Patent number: 5688573
    Abstract: A halogen-free acrylic urethane sheet material 10 is disclosed which can be marked by conventional printing methods and by radiation methods. The halogen-free acrylic urethane sheet material of the invention is manufactured from a polymer comprising components A, B and C whereincomponent A comprises a copolymer of(i) a monoester of acrylic or methacrylic acid and an aliphatic diol having 2 to 8 carbon atoms and(ii) an ester of acrylic or methacrylic acid and an aliphatic alcohol having 1 to 8 carbon atoms, and optionally a vinyl aromatic monomer as well as N-vinylpyrrolidone or N-vinylcaprolactame,said component A having a T.sub.g of 30.degree. C. to 100.degree. C.,component B comprising an aliphatic polyester diol with a molecular weight less than 20,000 andcomponent C comprising a polyfunctional isocyanate or blocked polyfunctional isocyanate.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: November 18, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Siegfried Goeb, Iris Maassen
  • Patent number: 5679727
    Abstract: A platinum curing organosiloxane composition having improved hysteresis characteristics when cured. The composition requires the presence of a diorganovinylsiloxy terminated polydiorganosiloxane having a viscosity within a range of about 20 Pa.multidot.s to 200 Pa.multidot.s at 25.degree. C. and containing essentially no ethylenically unsaturated hydrocarbon radicals bonded to non-terminal silicon atoms and a diorganovinylsiloxy terminated polydiorganosiloxane having a viscosity within a range of about 0.1 Pa.multidot.s to 200 Pa.multidot.s at 25.degree. C., where from 1 to 5 percent of the non-terminal repeating units of the siloxane comprise a vinyl radical. In addition, the present composition comprises 10 to 30 weight percent of a reinforcing silica filler that has been treated with hexamethyldisilazane and 1,1,3,3-tetramethyl-1,3-divinyldisilazane, and an organohydrogen siloxane crosslinker comprising at least ten silicon-bonded hydrogen atoms per molecule.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: October 21, 1997
    Assignees: Dow Corning Corporation, Dow Corning Taiwan, Incorporated
    Inventors: Phillip Joseph Griffith, Chu Yat Ho, Diane Marie Kosal, Jary David Jensen
  • Patent number: 5677411
    Abstract: Secondary contact adhesion or self-bonding in cured liquid injection molding silicone compositions is reduced by the inclusion in the composition of an inhibitor compound selected from the group consisting of phenyl fluids, titanate esters, and silicate esters.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: October 14, 1997
    Assignee: General Electric Company
    Inventors: Brian J. Ward, Robert A. Smith, Richard A. Striker
  • Patent number: 5668212
    Abstract: An aqueous organosiloxane liquid composition in a homogeneous state is disclosed, which contains (A) aqueous modified organosilicon compound having at least one polyether group as a side chain, (B) liquid organopolysiloxane, (C) a cross-linking agent, (D) a curing catalyst and, optionally, (E) a filler. This composition undergoes uniform curing, when exposed to the atmosphere of a temperature of up to 300.degree. C., to form a siloxane polymer composition in a form of a film, fibers, a composite structure, a composite sheet or a building material. The composition can also be used as a coating composition or varnish.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: September 16, 1997
    Assignee: Shizu Naito
    Inventor: Hiroyuki Naito
  • Patent number: 5610230
    Abstract: A liquid silicone rubber composition contains (A) an organopolysiloxane having at least two alkenyl groups, (B) a reinforcing silica filler, (C) a condensation catalyst, (D) a silanol group-containing siloxane wetter, (E) an organohydrogenpolysiloxane having at least two hydrogen atoms, and (F) a platinum catalyst. Components (C) and (D) assist in blending a large amount of the silica filler in the composition. The composition is smoothly flowing, quickly curable and suitable for injection molding.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: March 11, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takeo Yoshida, Manabu Narumi
  • Patent number: 5608031
    Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %,the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: March 4, 1997
    Assignee: Eastman Chemical Company
    Inventors: Cheuk C. Yau, Leslie S. Moody
  • Patent number: 5605721
    Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH .ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 25, 1997
    Inventor: Joseph W. Di Geronimo
  • Patent number: 5587502
    Abstract: The present invention provides a moisture-curable alkoxysilane functional polyurethane prepared from a hydroxy functional alkoxysilane. The hydroxy functional alkoxysilane is a hydroxyalkylenecarbamoylalkylene-alkoxysilanes referred to as a "hydroxycarbamoylsilane". The alkoxysilane functional polyurethanes may be used in a variety of applications to provide, for example, moisture-curable adhesives, sealants, putties and the like.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: December 24, 1996
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: Dean M. Moren, Ian R. Owen
  • Patent number: 5585186
    Abstract: A coating composition which imparts anti-reflective and anti-fog properties to substrates coated therewith. The coating composition utilizes an inorganic metal oxide in combination with silane or a siloxane oligomer. The coating compositions are particularly useful in the manufacture of disposable surgical masks and face shields.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: December 17, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Matthew T. Scholz, George V. Tiers
  • Patent number: 5569689
    Abstract: Addition-curable platinum group metal catalyzed silicone compositions are provided which utilize an adhesion promoter in the form of a Michael reaction product of a bis(aminoalkyl)tetraalkyldisiloxane, such as bis(aminopropyl)tetramethyldisiloxane, with an acryloxyorganotrialkoxysilane, for example, acryloxypropyltrimethoxysilane. The addition-curable silicone compositions can bond to plastic and metal substrates at temperatures of less than 100.degree. C. and in less than 1 hour, forming composites which fail cohesively upon separation.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: October 29, 1996
    Assignee: General Electric Company
    Inventor: Judith Stein
  • Patent number: 5567752
    Abstract: Silicon- and nitrogen-containing compositions prepared by the reaction of an aminoalkylsilane such as 3-aminopropyl- or 3-methylaminopropyltrimethoxysilane with a glycidoxyalkylsilane such as 3-glycidoxypropyltrimethoxysilane are useful as adhesion promoters in addition curable polyorganosiloxane compositions. The latter are illustrated by mixtures of vinyl-substituted polyorganosiloxanes and hydride polyorganosiloxanes, also containing at least one platinum group metal compound as a hydrosilylation catalyst.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: October 22, 1996
    Assignee: General Electric Company
    Inventors: Judith Stein, Jeffrey H. Wengrovius, Paul R. Willey
  • Patent number: 5561184
    Abstract: A room temperature curable silicone composition, comprising (A) 100 parts by weight of an organopolysiloxane each of both ends of which has one hydroxyl group, (B) 0.2 to 40 parts by weight of at least one compound selected from the group consisting of hydrolyzable silanes having 2 to 4 hydrolyzable groups and their partial hydrolysis-condensation products, (C) 1 to 100 parts by weight of a modified diorganopolysiloxane of which both ends have at least one group selected from the group consisting of a hydrogen atom, a substituted monovalent hydrocarbon group and alkoxy group having 1 to 10 carbon atoms, an unsubstituted hydrocarbon group and alkoxy group having 1 to 10 carbon atoms, and a hydroxyl group and that has a silicon-bonded modifying group made up of a substituted or unsubstituted monovalent organic group with 6 or more carbon atoms, and (D) a filler and a cured product thereof. A cured product good in peeling properties can be obtained.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: October 1, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kei Miyoshi, Yoshifumi Harada
  • Patent number: 5548002
    Abstract: It has been found that silicone resins which contain alkoxy functional groups and harden rapidly in the presence of moisture allow suitable one-component formulations as provisional fixing materials. The hardening rate can be adjusted by addition of suitable activators.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: August 20, 1996
    Assignee: Heraeus Kulzer GmbH & Co. KG
    Inventors: Peter Schwabe, Ottfried Schlak, Jens Winkel, Rainer Guggenberger, Oswald Gasser
  • Patent number: 5534588
    Abstract: A room temperature vulcanizable silicone rubber composition with high elongation and low modulus comprising 10-90 percent by weight polydiorganosiloxane having terminal hydroxyl groups, 1-10 percent by weight phenyl tris-functional ketoximino-containing silane crosslinker, 0-14 percent by weight of a reinforcing or 0-60 percent by weight of a nonreinforcing filler or semi-reinforcing filler or a mixture thereof for a total of all fillers in the range of from about 6-60 percent by weight, from 0-2.5 percent by weight of an organofunctional silane adhesion promoter and an optional plasticizer and catalyst. These compositions cure to elastic materials useful as caulking materials, adhesives, coatings and encapsulating materials for the construction and other industries.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: July 9, 1996
    Assignee: AlliedSignal Inc.
    Inventors: Jeffrey A. Knepper, Dale R. Flackett, Edward T. Asirvatham
  • Patent number: 5534609
    Abstract: A siloxane composition is described comprising a polydiorganosiloxane have at least two unsaturated hydrocarbon groups per molecule, a polyorganohydrosiloxane network crosslinker that has at least three Si--H bonds per molecule, a silane or siloxane crosslinker that has at one --SiH.sub.3 group, a hydrosilation catalyst, and, optionally, a siloxane rheological control agent. The composition allows gels to be prepared that exhibit good adhesion to various substrates, and can also be used to temporarily inhibit catalyst activity. Prostheses and coatings can be produced with these compositions.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: July 9, 1996
    Assignee: OSi Specialties, Inc.
    Inventors: Kenrick M. Lewis, Eugene C. Ward
  • Patent number: 5530082
    Abstract: Compounds of the general formula(R.sup.3 O).sub.3-n R.sup.4.sub.m Si--(CH.sub.2).sub.z --XwhereinR.sup.3, R.sup.4 represent identical or different linear or branched C.sub.1 -C.sub.20 alkyl groups or alkoxyalkyl groups,X represents a halogen atom,an aminoaryl group, wherein the aromatic group can optionally carry, on one or more carbon atoms at any position, C.sub.1 -C.sub.20 alkyl groups or alkoxyalkyl groups, halogen atoms or other functional groups.or a hydroxyl group or a C.sub.1 -C.sub.20 alkoxyalkyl group, which is substituted at one or more carbon atoms at any position by one or more hydroxyl groups,n=0, 1 or 2 andz=an integer between 1 and 20 aresuitable as adhesion promoters in 1K-RTV compounds which have titanium compounds as condensation catalysts.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: June 25, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Robert Friebe, Wilhelm Weber, Karl-Heinz Sockel
  • Patent number: 5527872
    Abstract: There is provided electronic devices with dielectric layers obtained from boron-oxide doped, spin-on glass formulations which form glassy layers with high oxygen resistance. Suitable electronic devices include integrated circuits. With high oxygen resistance, the glassy layer formed maintains its integrity in subsequent processing. Also provided is a method for preparing boron-oxide doped, spin-on glass formulations with a high carbon content having a silane adhesion promoter and boron-dopant incorporated therein.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: June 18, 1996
    Assignees: AT&T Global Information Solutions Company, Hyundai Electronics America, Symbios Logic Inc.
    Inventor: Derryl D. J. Allman
  • Patent number: 5519081
    Abstract: Highly filled, curable compositions containing a curable liquid, e.g. methyl methacrylate; 20 to 80% by weight of a finely divided inorganic filler of defined particle size, e.g. silica; a functionalized polymer containing a low Tg component which is soluble in the curable liquid, e.g. a functionalized vinyl aromatic/conjugated diene block copolymer; and other components which diperse the filler in the curable liquid and couple the filler to the matrix can be used to produce cured composites which show improved resistance to stress induced by thermal cycling.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: May 21, 1996
    Assignee: Imperial Chemical Industries PLC
    Inventors: David P. Ashton, Geraldine A. Moorman, Roger N. Rothon
  • Patent number: 5519083
    Abstract: Highly filled, curable compositions containing a curable liquid, e.g. methyl methacrylate; 20 to 80% by weight of a finely divided inorganic filler of defined particle size, e.g. silica; a non-functionalized polymer containing a low Tg component which is soluble in the curable liquid, e.g. a non-functionalized vinyl aromatic/conjugated diene block copolymer; and other components which diperse the filler in the curable liquid and couple the filler to the matrix can be used to produce cured composites which show improved resistance to stress induced by thermal cycling.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: May 21, 1996
    Assignee: Imperial Chemical Industries PLC
    Inventors: David P. Ashton, Geraldine A. Moorman, Roger N. Rothon
  • Patent number: 5514322
    Abstract: An RIM method of thermoplastic resin comprises a process for preparing materials in which one compound (i) is mixed with a material for thermoplastic resin to prepare one mixture (I), and the other compound (ii) is mixed with a material for thermoplastic resin to prepare the other mixture (II), each of two compounds (i) and (ii) being inactive to the material for thermoplastic resin but producing a high-active anionic polymerization catalyst by their reaction, a process for polymerization in which the mixture (I) and the mixture (II) are mixed, injected into a mold, and polymerized by the anionic polymerization catalyst, an ejecting process in which a solidified thermoplastic resin molded body is ejected from the mold. Therefore, a polymerization reaction cannot be started before the material for thermoplastic resin is injected into the mold, and it begins soon after the material for thermoplastic resin is injected into the mold.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: May 7, 1996
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Yoshiyuki Noritake
  • Patent number: 5504147
    Abstract: A process for preparing a liquid silicone composition of the type which comprises (A) a diorganopolysiloxane having a viscosity of 1000 to 100,000 centipoises and having at least two reactive groups, (B) a filler mainly composed of SiO.sub.2 having a specific surface area of not smaller than 50 m.sup.2 /g, (C) a diorganopolysiloxane having a viscosity of from 10 to 1000 centipoises and substantially free of any terminal silanol group, (D) hexamethyldisilazane and/or (E) water is described. In the process, 10 to 100 wt % of the (A) and (C) components and 100% of the (B), (D) and, if present, (E) components are mixed under heating conditions of 100.degree. to 250.degree. C. for a time sufficient to obtain a uniform dispersion. If present, the balances of the (A) and (C) components are subsequently mixed with the dispersion.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: April 2, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Morio Ohashi
  • Patent number: 5498660
    Abstract: To a silicone rubber composition including (A) a diorganopolysiloxane having an aliphatic unsaturated hydrocarbon group, (B) an organohydrogenpolysiloxane having at least two SiH groups in a molecule, and (C) a platinum catalyst, is added (D) an organic silicon compound of the following general formula (2): ##STR1## wherein R.sup.2, R.sup.5, and R.sup.6 are independently selected from monovalent hydrocarbon groups free of an aliphatic unsaturated bond, R.sup.3 is a monovalent hydrocarbon group, R.sup.4 is hydrogen or methyl, and n is an integer of 0 to 3. The composition has a long pot life after addition of curing components (B) and (C) and is extrusion moldable into bubble-free transparent parts. The composition is prepared by mixing component (A) with components (B) and (C) while adding component (D) thereto.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: March 12, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaharu Takahashi, Manabu Narumi
  • Patent number: 5492951
    Abstract: The invention relates to a process for the treatment of the periphery of a glass, more particularly an encapsulated glass, which consists of treating part of the surface of the glass by at least one silane and a composition able to form a layer having free OH groups. This process is useful for treating glass so that a resin, such as a polyurethane, upon contact with the treated glass will readily adhere and bond to the glass. The treated glass can be fitted into car body bays or openings.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: February 20, 1996
    Assignee: Saint Gobain Vitrage International
    Inventors: Andre Beyrle, Philippe Armand
  • Patent number: 5489479
    Abstract: Room temperature vulcanizable silicone compositions are provided having improved shelf life, primerless adhesion, deep section cure, and low toxicity properties, comprising by weight:A. 100 parts of a polydiorganosiloxane having a viscosity of from about 100 to about 1,000,000 centipoise at 25.degree. C., wherein the silicon atoms at each polymer end chain is terminated with at least two alkoxy radicals, the organic group being a C.sub.1-15 monovalent hydrocarbon radical;B. an effective amount of a diorganotin bis beta-diketonate condensation catalyst;C. from about 0.1 to about 1.5 parts of a scavenger for hydroxy functional groups, preferably a disilazane or polysilazane;D. from about 0.6 to about 5 parts of an adhesion promoting polyalkoxysilane functionalized with ether, epoxy, isocyanato, cyano, acryloxy, and acyloxy, preferably with epoxy; andE. from 0 to about 10 parts of a crosslinking polyalkoxysilane.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: February 6, 1996
    Assignee: General Electric Company
    Inventors: Gary M. Lucas, Jeffrey H. Wengrovius
  • Patent number: 5487948
    Abstract: Bis(bis-silylalkyl) dicarboxylates, especially maleates and fumarates, are prepared by a three-step process including esterification of malaic or fumaric acid or a functional derivative thereof with a branched dienol such as 1,6-heptadien-4-ol to form an alkadienol ester, reaction of the olefinic groups in said ester with a chlorosilane and alcoholysis of the chlorine atoms attached to silicon. The products are useful as adhesion promoters in addition curable polyorganosiloxane compositions.
    Type: Grant
    Filed: January 26, 1995
    Date of Patent: January 30, 1996
    Assignee: General Electric Company
    Inventor: Judith Stein
  • Patent number: 5486565
    Abstract: The present invention relates to organosiloxane compositions that are reaction products of 1) a silane containing at least 3 hydrolyzable groups per molecule, 2) a monohydric or polyhydric alcohol containing at least one organofunctional group and 3) a polyhydric alcohol containing no organofunctional groups or ethylenic unsaturation, wherein said reaction products contain at least two silicon atoms. The organosiloxane compositions are particularly useful as adhesion promoting additives for curable organosiloxane compositions, particularly those that cure by a platinum group metal-catalyzed hydrosilation reaction.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: January 23, 1996
    Assignee: Dow Corning Corporation
    Inventors: Theresa E. Gentle, Michael A. Lutz
  • Patent number: 5475076
    Abstract: The invention relates to organo(poly)siloxane compositions which have long shelf life in the absence of water, but can be crosslinked in the presence of water, even at room temperature, to give elastomers with elimination of alcohols, and to a process for the preparation of such compositions.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: December 12, 1995
    Assignee: Wacker-Chemie GmbH
    Inventors: Rudolf Braun, Petra Absmaier
  • Patent number: 5446113
    Abstract: A method is provided for making platinum catalyzed heat curable organopolysiloxane compositions which have an enhanced rate of cure by using a silicon hydride siloxane in combination with a devolatilized mixture of a vinyl silicone fluid and a reaction product of a zero valent platinum complex and a vinylsilane.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: August 29, 1995
    Assignee: General Electric Company
    Inventor: Larry N. Lewis
  • Patent number: 5438094
    Abstract: An adhesive silicone composition comprising (A) an alkenyl group-containing organopolysiloxane, (B) an organohydrogen-polysiloxane having at least three hydrogen atoms each directly bonded to a silicon atom in a molecule, (C) a compound having at least one aliphatic unsaturated group and at least two phenyl skeletons in a molecule, and (D) a platinum catalyst is well adhesive to both metals and reins, and even to difficult-to-adhere resins such as nylon, polycarbonate and acryl resins.
    Type: Grant
    Filed: July 1, 1994
    Date of Patent: August 1, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Hiroyasu Hara, Mikio Shiono, Masayuki Ikeno
  • Patent number: 5434214
    Abstract: Vibration dampening hydrosilation cured silicone formulations which cure at room temperature and, after a subsequent heat cure cycle, provide good primerless adhesion to aluminum and titanium substrates and improved adhesion to polymeric composite materials such as polyimide/glass fiber composite materials. The composition includes (a) a polyorganosiloxane having plural alkenyl groups thereon; (b) a polyorganosiloxane having plural silicon hydride groups thereon; (c) a hydrosilation catalyst, and (d) a combination of adhesion promoter compounds including at least one silane adhesion promoter compound; triallyl isocyanurate; and diallyl maleate. Still further improvements to polyimide substrates are provided when a primer is employed or the substrate is treated by a very brief exposure to a flame or to UV irradiation.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: July 18, 1995
    Assignee: Loctite Corporation
    Inventors: Mark Wolosen, Alfred A. DeCato
  • Patent number: 5432280
    Abstract: A gel-forming silicone composition comprising, compounded in a gel-forming base composition, a silane compound having the following general formula (1) or (2): ##STR1## wherein R.sup.1 is an alkyl or aryl group, R.sup.2 is an alkyl or alkoxyalkyl group, R.sup.3 and R.sup.4 are each a hydrogen atom, a methyl group or an ethyl group, R.sup.5 is an alkyl group or an ester linkage-containing group, and a, b and n are each an integer from 0 to 2. The composition is capable of forming, under mild conditions, a silicone gel which exhibits good adherence to a variety of substrates.
    Type: Grant
    Filed: July 2, 1993
    Date of Patent: July 11, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hiroyasu Hara, Masayuki Ikeno, Takehide Okami
  • Patent number: 5420196
    Abstract: A one component room temperature vulcanizable silicone elastomer having primerless adhesion to polyacrylate useful as a sealant
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: May 30, 1995
    Assignee: General Electric Company
    Inventor: Gary M. Lucas
  • Patent number: 5412025
    Abstract: The present invention relates to a process to in-situ reactor-fill polyolefins. More specifically, the instant invention provides a process to reactor-fill polyolefins comprising the steps of (a) adding a sufficient amount of alpha-olefin to a filler prior to using the filler for in-situ polymerization; (b) prepolymerizing the mixture of step (a) by contacting the treated filler in random order of no specific sequence with a high activity polymerization catalyst, a cocatalyst, and, if necessary a cocatalyst modifier; and (c) adding an alpha-olefin under olefin polymerization reaction conditions to the reaction product of step (b) to form a reactor-filled composite. The prepolymerization step results in the formation of a sticky prepolymer on the surface and in the pores of the filler.The present invention further relates to reactor-filled polyolefin composites obtained from the process of the present invention.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: May 2, 1995
    Assignee: Quantum Chemical Corporation
    Inventor: Richard W. Fries
  • Patent number: 5405896
    Abstract: An adhesive silicone rubber composition of addition reaction curing type comprising (a) an organopolysiloxane containing an alkenyl group; (b) an organohydrogenpolysiloxane having at least one hydrogen atom directly attached to a silicon atom in a molecule; (c) an addition reaction catalyst; and (d) an adhesive agent selected from compounds of the following formulae (I), (II) and (III):A-(D-B).sub.x -D-A (I)C-(B-D).sub.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: April 11, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Shigeki Shudo, Akira Matsuda
  • Patent number: 5405929
    Abstract: A silicone composition having utility as an oil and water repellent coating for substrates when cured thereon is disclosed, said composition comprising:(A) 100 parts by weight of an organopolysiloxane that has a viscosity at 25.degree. C. of at least 40 centipoise and that contains at least 2 alkenyl groups in each molecule;(B) from 0.1 to 40 parts by weight of an organohydrogenpolysiloxane that contains at least 2 silicon-bonded hydrogen atoms in each molecule;(C) from 0.01 to 10 parts by weight of a perfluoroalkyl-containing organosilane having the general formula ##STR1## wherein R.sup.1 represents a monovalent hydrocarbon group, R.sup.2 represents a divalent hydrocarbon group, a is 2 or 3, and n is a number having a value of 4 to 12, with the proviso that R.sup.1 is not an alkenyl group; and(D) a catalytic quantity of a hydrosilylation-reaction catalyst.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: April 11, 1995
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventor: Hideki Kobayashi
  • Patent number: 5401796
    Abstract: A preparation process of aliphatic polyester having a weight average molecular weight of 15,000 or more by conducting a direct polycondensation reaction of an aliphatic polyhydric alcohol or a mixed aliphatic polyhydric alcohol and an aliphatic polybasic acid or a mixed aliphatic polybasic acid, or additionally a hydroxycarboxylic acid or a mixed hydroxycarboxylic acid or an oligomer of the hydroxycarboxylic acid in a reaction mixture containing an organic solvent.The aliphatic polyester thus obtained contains an extremely small amount of impurities, has low color and can exhibit satisfactory strength in the form of films, filaments and other shaped articles.
    Type: Grant
    Filed: March 29, 1994
    Date of Patent: March 28, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Takeshi Kashima, Taiji Kameoka, Chojiro Higuchi, Masanobu Ajioka, Akihiro Yamaguchi
  • Patent number: 5399601
    Abstract: A room temperature curable composition suitable as top coat and providing coating films having good properties such as surface appearance, gloss, stain resistance, weatherability and adhesion and a small contact angle with water, which comprises (A) an acrylic copolymer having a specific reactive silicon-containing group such as alkoxysilyl group, (B) a specific hydrolyzable silicon compound and/or its partial hydrolysis condensation product, (C) a specific curing catalyst such as an organic carboxylic acid, a combination of an organic carboxylic acid with an organic amine, or an organometallic compound, and (D) an adhesion improving agent such as a silane coupling agent or its reaction product with an epoxy compound.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: March 21, 1995
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Akira Kusumi, Hitoshi Tamai, Naotami Ando, Hisao Furukawa
  • Patent number: 5389692
    Abstract: A co-polymer composition for coating porous structural material includes a compatible surfactant resulting in a structural inter-bonding between the coating composition and the structural material. The co-polymer composition cured in a layer of unsupported foam has sufficient strength to be used as a substitute for comparably or larger sized layers of re-enforced concrete for conducting fluids while resisting compressive loads. A co-polymer foam composition for coating structural material cures to have an atmosphere-facing surface that is substantially impervious to corrosive substance penetration.
    Type: Grant
    Filed: August 25, 1993
    Date of Patent: February 14, 1995
    Inventor: Richard L. Bertram
  • Patent number: 5385973
    Abstract: The present invention relates to a process for preparing flowable, stable and hardenable compositions, comprising mixing:a) a liquid basis constituted by at least one polymerizable monomer;b) a finely ground mineral filler;c) a silanizing agent for the mineral filler; andd) a hydrolysis catalyst of the silanizing agent, selected from the ammonium salts of organic acids.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: January 31, 1995
    Assignee: Vedril S.p.A.
    Inventors: Franco Marciandi, Dario Giudici, Marco Binaghi
  • Patent number: 5382651
    Abstract: A method for the production of polyester suitable to be molded into a film with excellent surface properties.The method comprises passing dispersion-in-water type silica sol with pH 8 to 11 including sodium oxide as a stabilizer and silica particles with average diameters 0.01 to 0.3 .mu.m through a column of cation exchange resin having the following formula 1 and the strong basic anion exchange having the following formula 2, in sequence to adjust the pH value to 2 to 4, adding an hydrogen bonding agent and ethylene glycol thereto, heating the resultant silica sol under a reduced pressure to remove water, so as to obtain dispersion-in-ethylene glycol type silica sol, and adding 0.01 to 5% by weight of the dispersion-in-ethylene glycol type silica sol, as based on the weight of polyester to be produced, at any step during the ester interchange reaction.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: January 17, 1995
    Assignee: Cheil Synthetics, Inc.
    Inventors: Kwang T. Kim, Tae H. Kim, Seung B. Jun
  • Patent number: 5380788
    Abstract: Room temperature vulcanizable platinum group metal catalyzed silicone compositions are provided which utilize an N-heterocyclic adhesion promoter, such as 2,6 bis(trimethoxysilyltrimethyleneoxy)pyridine. Cohesive bonding is effected on various substrates.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: January 10, 1995
    Assignee: General Electric Company
    Inventors: Judith Stein, Mark W. Davis
  • Patent number: 5373035
    Abstract: An adhesive composition comprising an alpha-cyanoacrylate and a hydrophobic silica surface-treated with dimethyldichlorosilane, the composition being characterized in that the composition has incorporated therein at least one of a polyether-modified silicone or alcohol-modified silicone in an amount of 0.05 to 5.0% based on the weight of the composition.
    Type: Grant
    Filed: January 5, 1993
    Date of Patent: December 13, 1994
    Assignee: Ohara Paragium Chemical Co., Ltd.
    Inventors: Hiroshi Uemura, Etsuo Yoshida
  • Patent number: 5364896
    Abstract: The triorganosiloxydiphenylsilanols of the present invention are novel silicone compounds that are useful as plasticizers for silicone rubbers. The present invention also relates to a method for preparing these compounds in high yield and purity and a method for preparing filled curable organosiloxane compositions using the present compounds as plasticizers.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: November 15, 1994
    Assignee: Dow Corning Toray Silicone Co., Ltd
    Inventors: Tadashi Okawa, Shuji Yamada
  • Patent number: 5364921
    Abstract: A composition curable to a silicone rubber exhibits adhesion to metal and glass substrates under both dry and wet conditions where the composition contains an alkenyl-containing polydiorganosiloxane, an organohydrogensiloxane, a hydrosilation catalyst containing platinum, an (epoxy-functional organo)trialkoxysilane, an alkoxy-silicon compound, and a titanium compound having Ti--O--CH bonds and the molar amount of alkoxy-silicon compound exceeds the molar amount of (epoxyfunctional organo)trialkoxysilane.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: November 15, 1994
    Assignee: Dow Corning Corporation
    Inventors: Thomas E. Gray, Michael E. Kunselman, Richard A. Palmer
  • Patent number: 5356716
    Abstract: The present invention relates to waterproofing sealer compositions that protect various types of porous substrates from deterioration due to water absorption and thus extend their useful lives. Example of porous substrate are concrete, brick, masonry, ceramics, stones, cloth, wood and the like. These waterbased compositions comprise alkali metalalkylsiliconates, alkali silicates, polymers, diluents and additives.These sealer compositions do not change appearance and character of the substrate surface.
    Type: Grant
    Filed: September 4, 1992
    Date of Patent: October 18, 1994
    Inventor: Pratim R. Patel
  • Patent number: 5331043
    Abstract: A silane-containing methacrylate resin composition which produces non-yellowing polymers. The composition contains 20-99.9% by weight (meth)acrylic acid ester, optionally other comonomers or polymers and softeners as well as 0.1-30% by weight of a silane. 100 parts by weight of this mixture are polymerized in the presence of a free radical initiator, Cu.sup.2+ and a quaternary amine. The components can be stored in premixtures and brought to reaction. The polymer can be used in glass laminates.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: July 19, 1994
    Assignee: Degussa Aktiengesellschaft
    Inventors: Klaus-Uwe Koch, Heidi Mich
  • Patent number: 5326844
    Abstract: A primer composition has blended therein an organic silicon compound having in a molecule at least one group of the formula: ##STR1## wherein R.sup.1 is a monovalent hydrocarbon group or a group represented by QSi( R.sup.4 O).sub.a (R.sup.5).sub.3-a, Q is a divalent organic group, R.sup.4 and R.sup.5 each are a monovalent hydrocarbon group, a is an integer of 0 to 3, R.sup.2 and R.sup.3 each are a hydrogen atom or a monovalent hydrocarbon group, and n is 0, 1 or 2. The primer composition is a useful adhesive since it is effective for joining silicone elastomers and similar adherends to supports such as paint coated metals and resins.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: July 5, 1994
    Assignee: Shin-Etsu Chemical Company, Limited
    Inventors: Hironao Fujiki, Masanobu Miyakoshi, Takeo Yoshida, Yoshifumi Inoue, Masatoshi Arai
  • Patent number: 5312855
    Abstract: The adhesive organopolysiloxane composition contains a compound having two or more allyl ester groups in combination with an adhesion imparting agent of a silicon compound having at least one group selected from the group consisting of an alkoxy group and an epoxy containing hydrocarbon group and also having at least one silicon-bonded hydrogen atom. This composition is markedly improved in adhesion to various substrates and durability of the adhesion.
    Type: Grant
    Filed: February 1, 1993
    Date of Patent: May 17, 1994
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Takehide Okami
  • Patent number: RE35223
    Abstract: Cyclic aminoalkylsilane compositions are prepared by the reaction of approximately equimolar amounts of an aminoalkyltrialkoxysilane such as 3-aminopropyltrimethoxy-silane and a glycidyl ether such as methyl glycidyl ether. They are useful as adhesion promotors in room temperature vulcanizable compositions comprising polyalkoxysilyl-terrninated polydiorganosiloxanes.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: April 30, 1996
    Assignee: General Electric Company
    Inventor: Judith Stein