Si-c, Si-h Contains Dnrm, Metal-c Or Metal-h Bond Or Organic Compound Containing Si Patents (Class 524/730)
  • Patent number: 4537803
    Abstract: A fluid, insulating composition, useful for casting around conductors, is made from a liquid, polymerizable organic resin system, and a liquid, non-polymerizable organopolysiloxane dielectric filler partially soluble in the organic resin system and having the structural formula:(R).sub.3 --Si[OSi(R).sub.2)].sub.n OSi(R).sub.3,where n=0 to about 10, and each R group is selected from H, alkyl having from 1 to 6 carbons, and phenyl, where the dielectric is added in an amount such that, upon polymerization of the organic resin system to form a resin matrix containing dielectric filler, the dielectric will flow or diffuse through the resin matrix into cavities or voids in or bordering the composition or near any insulated conductors or other insulated articles.
    Type: Grant
    Filed: May 24, 1984
    Date of Patent: August 27, 1985
    Assignee: Westinghouse Corp.
    Inventors: Thomas W. Dakin, Stanley A. Studniarz, Terrence E. Chenoweth
  • Patent number: 4506058
    Abstract: There is provided a composition which vulcanizes at room temperature on exposure to moisture comprising a product resulting from mixing:(A) an organopolysiloxane consisting essentially of repeating R.sub.2 SiO units, where R is a C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radical;(B) an effective amount of condensation catalyst, and(C) an effective amount of self-bonding agent of the general formula ##STR1## where R.sup.1 is a C.sub.(1-7) monovalent hydrocarbon radical, R.sup.2 is a C.sub.(1-4) alkyl radical, C.sub.(1-4) acyl radical or a radical of the formula --CH.sub.2 CH.sub.2 O).sub.n R.sup.4, where n is 1 or 2 and R.sup.4 is a C.sub.(1-4) alkyl radical, R.sup.3 is a C.sub.(1-18) divalent hydrocarbon radical free of aliphatic unsaturation attached to a nitrogen atom of the urea nucleus through a non-aromatic carbon atom, Z is hydrogen or a C.sub.(1-4) alkyl radical and y equals 0 or 1.
    Type: Grant
    Filed: March 14, 1984
    Date of Patent: March 19, 1985
    Assignee: General Electric Company
    Inventors: Bruce A. Ashby, Gary M. Lucas
  • Patent number: 4499229
    Abstract: Stable, substantially acid-free, one-package moisture curable alkoxy terminated organopolysiloxane compositions are provided. These room temperature vulcanizable alkoxy terminated organopolysiloxane compositions use a condensation catalyst, a stabilizer, or scavenger for materials having chemically combined hydroxy radicals and diorganosulfoxide, such as dimethylsulfoxide which functions as a cure rate accelerator.
    Type: Grant
    Filed: April 1, 1983
    Date of Patent: February 12, 1985
    Assignee: General Electric Company
    Inventor: Thomas P. Lockhart
  • Patent number: 4481322
    Abstract: Integrally blended additives, consisting of a ternary mixture of gamma methacryloxypropyl trimethoxysilane, trimethylolpropane triacrylate and a siloxaneoxyalkylene block copolymer, in the absence of dicumyl peroxide do not consistently improve the mechanical properties of mica filled polyolefins. This is especially true under "low shear" melt processing conditions e.g. employing a conventional screw design in a single barrel extruder. However, when the ternary mixture is combined with a small amount of dicumyl peroxide (neat or dissolved in vinyltrialkoxy silane) there is a consistent improvement in composite mechanical properties above that of the composites containing the ternary mixture alone and in comparison to mica filled polyolefin composites without any additive or composites containing the peroxide alone. Furthermore, thermal aging tensile strength retention is improved in mica filled polypropylene composites containing the ternary mixture combined with dicumyl peroxide.
    Type: Grant
    Filed: March 30, 1983
    Date of Patent: November 6, 1984
    Assignee: Union Carbide Corporation
    Inventors: Robert E. Godlewski, Frederick D. Osterholtz
  • Patent number: 4471101
    Abstract: A new class of polyesteramides having improved properties is the reaction product of a polyol, an alkanolamine, a polycarboxylic acid and a norbornyl terminal group.
    Type: Grant
    Filed: November 4, 1983
    Date of Patent: September 11, 1984
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., James C. Uroda
  • Patent number: 4471078
    Abstract: A methacrylic resin capable of selectively absorbing light rays having a wavelength of 580 nm is advantageously produced either by dispersing or dissolving neodymium compound in a resin-forming starting material selected from monomeric methyl methacrylate, a monomer mixture composed mainly of methyl methacrylate and partially polymerized products thereof, and polymerizing the resin-forming starting material. A solvent capable of dissolving therein the resin-forming starting material and the neodymium compound may be incorporated in the resin-forming starting material.
    Type: Grant
    Filed: June 14, 1983
    Date of Patent: September 11, 1984
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventor: Kozo Ida
  • Patent number: 4468492
    Abstract: A low temperature curing composition prepared from an essentially silicon-free polymer and a silicon group-containing material is improved by utilizing a silicon group-containing material which is a hydrolyzable organosilicon group-containing polymer which is non-gelled and formed from an essentially silicon-free polymer having isocyanate or active hydrogen functional groups and an organosilicon group-containing material having functional groups reactive with the isocyanate and active hydrogen.
    Type: Grant
    Filed: July 15, 1983
    Date of Patent: August 28, 1984
    Assignee: PPG Industries, Inc.
    Inventors: Robert Piccirilli, Wen-Hsuan Chang
  • Patent number: 4460739
    Abstract: The adhesion of self-bonding, low modulus, one package, room temperature vulcanizable silicone compositions to a variety of substrates is effectively promoted by incorporation in the silicon composition, before curing, of a small effective amount of an adhesion promoting composition comprising at least one maleamidylalkyltrialkoxysilane or maleamidylalkyltriacyloxysilane compound of the formula: ##STR1## wherein A is divalent alkylene of from 2 to 6 carbon atoms and R.sup.1, R.sup.2 and R.sup.3 are, independently, C.sub.1 -C.sub.6 alkyl or C.sub.2 -C.sub.6 alkanoyl.
    Type: Grant
    Filed: July 1, 1983
    Date of Patent: July 17, 1984
    Assignee: General Electric Company
    Inventor: Bruce A. Ashby
  • Patent number: 4442239
    Abstract: Phosphate derivatives represented by the formula ##STR1## wherein R represents a group containing at least one reactive double bond and A represents a group which may optionally contain reactive double bonds are disclosed. The phosphate derivatives of the present invention have at least two reactive double bonds, and polymers prepared from these phosphate derivatives in the presence or absence of other polymerizable monomers are useful as fillers for human hard tissues such as bones and teeth.
    Type: Grant
    Filed: February 10, 1982
    Date of Patent: April 10, 1984
    Assignee: Sankin Industry Co., Ltd.
    Inventors: Masayoshi Tsunekawa, Shinzo Yoshida, Tamotsu Komura
  • Patent number: 4439630
    Abstract: A particular silicone dielectric fluid, having aliphatic hydrocarbon or substituted aliphatic hydrocarbon substituents, with a specific gravity of at least 1.02, is employed to encapsulate and insulate an electrical cable splice. The same particular silicone dielectric fluid, with a specific gravity of at least 1.02 is also used to fill an electrical cable's conductor interstices.
    Type: Grant
    Filed: May 6, 1981
    Date of Patent: March 27, 1984
    Assignee: Dow Corning Corporation
    Inventor: Eugene D. Groenhof
  • Patent number: 4435546
    Abstract: Polyalkylene terephthalates containing 0.5-30% by weight of monomeric aliphatic carboxylic acid esters have a higher crystallization speed and thus allow lower mold temperatures and shorter injection cycles. The polyalkylene terephthalates generally have intrinsic viscosities in excess of about 0.4 dl/g in 1:1 phenol tetrachloroethane at 25.degree. C. and are at least about 90 mol % terephthalic acid based. The ester additive is based on aliphatic cycloaliphatic or araliphatic carboxylic acids, with sebacic and adipic being preferred, and aliphatic, cycloaliphatic or araliphatic alcohols.Faster crystallization rates can be imparted to polyalkylene terephthalates by mixing them with the ester additive and melt homogenizing the mixture.
    Type: Grant
    Filed: May 18, 1979
    Date of Patent: March 6, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Bier, Rudolf Binsack
  • Patent number: 4431578
    Abstract: A particular dielectric fluid, having a composition with a specific gravity of at least 1.02 and consisting essentially of a silicone fluid and an additive, soluble in said silicone fluid, selected from the group consisting of trimethylsilyl treated (CH.sub.3).sub.3 SiO.sub.1/2 /SiO.sub.2 resin copolymer, dipropyleneglycoldibenzoate, dixylylethane, phenylxylylethane, and a mixture of [(CH.sub.3).sub.3 Si].sub.2 O treated silica and a silica aerogel, is employed to encapsulate and insulate an electrical cable splice. The same particular dielectric field composition is also used to fill an electrical cable's conductor interstices.
    Type: Grant
    Filed: November 27, 1981
    Date of Patent: February 14, 1984
    Assignee: Dow Corning Corporation
    Inventor: Eugene D. Groenhof
  • Patent number: 4429062
    Abstract: A silicon rubber mixture for surgical embolization composed of(a) a linear, low viscosity polysiloxane selected from the group consisting of dialkyl, alkylaryl, alkenylalkyl, and diaryl polysiloxanes having reactive functional groups selected from the group consisting of hydroxy, acyloxy, alkoxy and amino;(b) a cyclic dialkyl polysiloxane having the formula [R.sub.2 SiO].sub.4, wherein R is alkyl; anda pharmaceutically acceptable iodo-containing organosilicium X-ray contrast material or non-metallic organic X-ray contrast material. The mixture can be used in cerebrovascular surgery and general surgery for sugical embolization with the aid of a catheter.
    Type: Grant
    Filed: February 17, 1981
    Date of Patent: January 31, 1984
    Inventors: Emil Pasztor, Laszlo Lazar, Jozsef Nagy, Katalin Pallosy nee Becker
  • Patent number: 4421893
    Abstract: The invention disclosed in this application is the use of novel silanes in curable coatings to allow tinting or dyeing of the coatings after they are cured on certain substrates.An example of one such useful silane is ##STR1## The silanes and the curable coatings are also useful as antistat and antifog coatings.
    Type: Grant
    Filed: January 18, 1982
    Date of Patent: December 20, 1983
    Assignee: Dow Corning Corporation
    Inventors: Loren A. Haluska, Marcelle G. Molzahn
  • Patent number: 4419484
    Abstract: The present invention relates organopolysiloxane molding compositions which are capable of storage in the absence of moisture and which crosslink to give elastomers after the admission of water or steam, and are based on .alpha.,.omega.-dihydroxyorganopolysiloxanes and substances which produce crosslinking, a short-chain siloxane of the general formula ##STR1## being added, in addition to customary additives.
    Type: Grant
    Filed: January 22, 1982
    Date of Patent: December 6, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans Sattlegger, Karl Schnurrbusch, Theo Achtenberg
  • Patent number: 4414349
    Abstract: This invention relates to coating compositions prepared by prehydrolyzing the silane function of a silylated ultraviolet radiation screening compound and adding it to an aqueous silicone resin composition. Hydrolyzing the silane function renders the ultraviolet screen a silanol which is a compatible component in the silicone resin compositions contemplated.
    Type: Grant
    Filed: January 15, 1982
    Date of Patent: November 8, 1983
    Assignee: General Electric Company
    Inventors: Howard A. Vaughn, Jr., Ta-Yen Ching
  • Patent number: 4395507
    Abstract: The present invention relates to dimedone functional self-bonding room temperature vulcanizable silicone rubber compositions. The self-bond additive is selected from silyl maleates, silyl fumarates, silyl succinates, silyl isocyanurates and mixtures thereof. Preferably the self-bonding additive is prereacted with the cross-linking agent before they are incorporated into the RTV composition. This prereaction of the self-bonding additive and the cross-linking agent imparts shelf-stability to the composition.
    Type: Grant
    Filed: December 16, 1981
    Date of Patent: July 26, 1983
    Assignee: General Electric Silicones
    Inventors: John J. Dziark, Kazuto Shinohara
  • Patent number: 4384068
    Abstract: Pasty organopolysiloxane compositions having a penetration of from 80 to 400 and which can be thermoset into elastomers having good mechanical properties, are comprised of an intimate admixture of (i) 100 parts by weight of a diorganopolysiloxane oil having a viscosity of from 500 to 300,000 mPa.multidot.s at 25.degree. C., (ii) 7 to 85 parts by weight of reinforcing silicas having a specific surface area of at least 50 m.sup.2 /g, said reinforcing silicas comprising from 55 to 95% precipitated silica and 5 to 45% pyrogenic silica, (iii) 1 to 20 parts by weight of a structuring inhibitor, and (iv) 0.1 to 4 parts by weight of an organic peroxide cross-linking agent.
    Type: Grant
    Filed: January 7, 1982
    Date of Patent: May 17, 1983
    Assignee: Rhone-Poulenc Industries
    Inventors: Noel Bouverot, Paul Medard, Alain Viale
  • Patent number: 4373057
    Abstract: This invention is directed to a polyurethane product produced by a one step process, in the absence of a polymerization catalyst, with reactants, and additives, if any, being initially intermingled in the ambient room temperature range and reacted with intermingling in the absence of externally added heat. The reactants are (1) aliphatic, aromatic, or cycloaliphatic having at least two isocyanate groups and (2) diol/polyol compounds having at least two sterically unhindered hydroxyl groups. The product is a liquid, homogeneous adhesive material characterized by a natural absence of polymerization catalyst residue and capable of being cured because of the presence of unreacted isocyanate groups, the isocyanate reactant being charged in excess of the stoichiometric requirement of the diol/polyol reactant.
    Type: Grant
    Filed: September 14, 1981
    Date of Patent: February 8, 1983
    Assignee: Colamco, Inc.
    Inventor: James A. Hammond
  • Patent number: 4358575
    Abstract: A self-bonding additive for a dimedone functional one-component RTV in which the self-bonding agent is a dialkoxydisilylether functional silane.
    Type: Grant
    Filed: December 16, 1981
    Date of Patent: November 9, 1982
    Assignee: General Electric Company Silicone Products Business Division
    Inventors: Warren R. Lampe, Tyrone D. Mitchell, James A. Cella
  • Patent number: 4355135
    Abstract: What is disclosed are hard, abrasion resistant, tintable/dyeable coating compositions which are based on siloxane/silica hybrid coating resins. These materials are especially useful on transparent plastic substrates.
    Type: Grant
    Filed: November 4, 1981
    Date of Patent: October 19, 1982
    Assignee: Dow Corning Corporation
    Inventor: James R. January