Abstract: The emulsion polymerization of free-radical-polymerizable monomers in the presence of a branched, poly(ethylene oxide) having a molecular weight of 4,000 to 19,000 and 1 to 250 mmol of the sum of the alkali metal and ammonium ions which are not bound to the emulsifier per liter of aqueous phase provides coarse, aqueous plastic dispersions. The process allows for the effective control of the particle size in the dispersion and yields carboxylated rubber dispersions which are suitable for the production of coating materials for carpets and paper.

Abstract: Resilient, crosslinked silicone elastomers shaped as elastoforming dies or form blocks for the stamping of sheet material workpieces, e.g., ultra-thin sheet metal, and well adopted for applications in the automotive industry, include a crosslinked fluid organopolysiloxane having at least one silicone-compatible organic or inorganic plasticizer within the crosslinked network thereof, said at least one plasticizer being stable and nonmigrating under elastoforming stamping conditions, and said at least one plasticizer being present in such amount that said plasticized silicone elastomer has a Shore 00 hardness of less than about 40.

Abstract: A silicone composition curable to a heat stabilized silicone elastomer comprising at least one polyorganosiloxane having the formula: ##STR1## where R is hydrogen or substituted or unsubstituted alkyl, alkenyl or aryl having less than 19 carbon atoms, each of A and D may be any of methyl, hydroxy or vinyl groups,0<m/n.ltoreq.1 and m+n>350,a complex comprising a transition metal salt of at least one polydentate chelating ligand having the formula: ##STR2## where each R.sub.1 may be an alkyl biradical having 1 to 6 carbon atoms or an aryl biradical having less than 19 carbon atoms R.sub.1, is an X' substituted R.sub.1, each of Z and E may be any of carboxy thiocarboxy, dithiocarboxy, or --N(R.sub.2).sub.2, --As(R.sub.2).sub.2, --S(R.sub.2) where each R.sub.2 may be any of hydrogen or an alkyl radical having 1 to 6 carbon atoms or any aryl radical having less than 19 carbon atoms, X' may be any of hydrogen, carboxy, thiocarboxy, dithiocarboxy, --N(R.sub.2).sub.2, --A.sub.s (R.sub.2).sub.2, or --S(R.sub.

Abstract: An antifouling paint composition comprising as a film-forming component a vinyl-type copolymer obtained by copolymerization of(A) 1 to 50% by weight of a specific polymerizable unsaturated polysiloxane compound,(B) 0 to 30% by weight of a specific polymerizable unsaturated alkoxysilane compound, and(C) 20 to 99% by weight of a polymerizable unsaturated vinyl monomer other than the compounds (A) and (B) above.

Abstract: The addition-curable composition of the present invention, because it comprises a special component as component (D), is characterized by an excellent bonding to any of various substrates with which it is in contact during curing. Component (D) is a mixture, or reaction product, of (a) a silicon-free compound which contains at least 1 alcoholic hydroxyl group and at least 1 alkenyl group in each molecule, and (b) an organosilane having in each molecule at least 1 alkoxy group and at least 1 epoxy or methacryloxy or acryloxy group.

Abstract: A process of polymerizing a polymerizable material in an inert organic liquid medium, in which the polymer formed from the monomer or monomers is insoluble, comprising dispersing the polymerizable material in the organic liquid in the presence of a finely, divided particulate material comprising an inorganic portion insoluble in the organic liquid medium and in combination therewith, preferably by covalent or ionic bonding, hydrocarbon chains containing at least 8 carbon atoms, the hydrocarbon chains being soluble in the organic liquid medium and heating the mixture to polymerize the polymerizable material to a required degree of polymerization. The process provides a means of stabilizing dispersion polymerizations which need to be carried out at very high temperatures to effect the polymerization.

Abstract: A coating composition comprising a colloidal silica, a partial condensate of organoalkoxysilane hydrolyzate, a polymer or a copolymer of unsaturated ethylenic monomers, a surface active agent and glycol derivatives, which is coated on a wheel for vehicles shows excellent properties such as adhesive property, filiform corrosion resistance, stain resistance, weather-resistance and impact resistance. A wheel coated with the coating composition for vehicles also shows excellent properties such as filiform corrosion resistance, stain resistance, weather-resistance and impact resistance.

Abstract: A coating composition is disclosed including an acrylic polyol, polyester polyol, a blend of curing agents, e.g., a blocked isocyanate and an aminoplast resin, and a liquid carrier. Optionally, pigmentation can be added, e.g., pigmentation adapted to provide camouflage under military specification MIL-C-46168D.

Abstract: Organic silicon-nitrogen compositions are prepared by the reaction of approximately equimolar amounts of a glycidoxyalkyltrialkoxysilane and a primary amine such as isobutylamine. They are useful as adhesion promoters in room temperature vulcanizable compositions comprising polyalkoxysilyl-terminated polydiorganosiloxanes.

Abstract: A semiconductor encapsulating material is obtained from a polyimide resin composition comprising (A) a polyaminobismaleimide resin, (B) a silicone monomer and/or oligomer having a hydroxyl or alkoxyl group bonded to a silicon atom and mixtures thereof, and (C) an inorganic filler wherein the weight ratio of polyaminobismaleimide resin (A) to silicone component (B) ranges from 99.5/0.5 to 70/30, and the weight ratio of polyaminobismaleimide resin (A) to inorganic filler (C) ranges from 100/50 to 100/1000.

Abstract: Certain bissilyl ureas have been found useful as adhesion promoters for silicone latex compositions. Self-bonding silicone elastomers are provided which exhibit enhanced adhesion to a variety of substrates.

Abstract: Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1- C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.

Abstract: Colloidal suspensions of organopolysiloxanes are prepared by mixing an organosilicon compound selected from the group consisting of mixtures of alkoxysilanes and/or partial hydrolysates thereof and an organo(poly)siloxane which is optionally free of alkoxy groups and contains a maximum of 8 siloxane units, which is mixed with at least one alkoxysilane and/or a partial hydrolysate thereof, with water in the presence of an emulsifier, at a maximum rate of 5 moles of organosilicon compound per hour per liter of water, in which the organosilicon compound and the water is fed continuously, but separately from one another, into a reactor, in which at least one of the two substances contains an emulsifier, while the alkanol is being continuously removed by distillation from the aqueous suspension continuously emerging from the reactor. The aqueous suspension from which the alkanol has been removed by distillation is, if desired, recycled back into the reactor.

Abstract: Cyclic aminoalkylsilane compositions are prepared by the reaction of approximately equimolar amounts of an aminoalkyltrialkoxysilane such as 3-aminopropyltrimethoxy-silane and a glycidyl ether such as methyl glycidyl ether. They are useful as adhesion promotors in room temperature vulcanizable compositions comprising polyalkoxysilyl-terminated polydiorganosiloxanes.

Abstract: The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two hydroxy groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two hydroxy groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.

Abstract: A sealant or coating composition admixture contains a blocked isocyanate-terminated prepolymer in which generally all of the NCO groups are blocked, a curing agent such as a polyamine or a polyimine, and a functional silane or siloxane nonreactive with blocked isocyanates. The sealants or coating compositions when cured have improved properties such as adhesion.

Abstract: Adhesive product for the bonding of steel, particularly in the automotive sheetwork processes proper to be used on ordinary non-degreased or oiled steel as well as on precoated steels of the electroplated or electrotinned type, even after being regreased, the said adhesive product being polyurethane-based and implementing polyol systems, comprising either one poylol or binary or ternary polyol mixtures or mixtures of more than three polyols modified by reaction with an epoxy resin.

Abstract: A curable composition comprising (A) an organic polymer containing at least one reactive silicon functional group crosslinkable to produce an elastomer by the formation of a siloxane bond in its molecule and (B) an organic silicon compound having a molecular weight of not less than 140 and represented by the formula (1):[(CH.sub.3).sub.3 SiO].sub.n R.sup.1 (1)wherein R.sup.1 is a residue of an alcohol or a weak acid which has a valency of n, and n is a positive integer. The composition of the invention can give cured product having excellent modulus and elongation as well as has excellent storage stability.

Abstract: A composition and method for forming elastomeric pressure sensitive adhesives comprising a mixture of (A) a xylene-soluble resin copolymer of 0.6 to 0.9 triorganosiloxy units per SiO.sub.4/2 unit and having less than 0.7 weight % silicon-bonded hydroxyl units. (B) a polydiorganosiloxane fluid endcapped with silicon-bonded hydroxyl groups and having a viscosity of from about 50 to 300,000 cP. at 25.degree. C., an organosilicon compound containing an average of more than two silicon-bonded alkoxy groups per molecule, and a condensation catalyst. The cured elastomeric pressure sensitive adhesives formed from these compositions are useful as medical adhesives, such as those used for ostomy seals.

Abstract: Aqueous silicone dispersions containing (a) polydiorganosiloxanes having hydroxyl groups in the terminal units, (b) (organo)metallic compound(s), (c) a siliconate, and optionally, (d) a silicone resin.These aqueous silicone dispersions will cure to form elastomeric coatings or sealants when the water is removed by evaporation.

Abstract: Polyurethanes are provided which have a polymeric backbone including recurring urethane or urea groups or both and which are reaction products including macroglycols, diisocyanates, and preferably chain extending agents. The polyurethanes may take the form of poly(fluorosilicone urethanes) and include recurring organosilicone moieties from a fluoroalkylsiloxane reactant. When it is desired that these polyurethanes be capable of forming fibers in air, then the reactant charge should be such that the ratio of isocyanate equivalents to hydroxyl equivalents is less than 1.

Abstract: Storage-stable diorganopolysiloxanes curable into adhesive/elastomeric state, well adapted as coatings and sealants, e.g., for adhering a wide variety of building construction materials such as glass, aluminum and PVC, are comprised of an .alpha.,.omega.-dihydroxydiorganopolysiloxane polymer, a ketiminoxysilane crosslinking agent therefor, and an effective amount of a tackifier which comprises a (.DELTA..sup.2 -imidazolinyl)alkylsilane.

Abstract: The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two hydroxy groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two hydroxy groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.

Abstract: A one-component adhesive and/or sealing mass which is stable and pumpable at temperatures up to 30.degree. C. containsat least one prepolymer on the basis of a polyurethane, which contains from 0.1 to 15 percent by weight, referred to the prepolymer, of free, reactive isocyanate groups, andat least one with heat activatable hardener.Thereby the stoichiometric ratio between said prepolymer and said hardener is chosen in such a way that only a partial cross-linkage is possible during heating said mass to temperatures from 60.degree. C. to 180.degree. C., and that a product is obtained having from high viscous to plastic characteristics.The inventive masses may be used for bonding and/or sealing of one or more materials of the same or different origin to a composite.

Abstract: A silicone composition curable to a heat stabilized silicone elastomer comprising at least one polyorganosiloxane having the formula: ##STR1## where R is hydrogen or substituted or unsubstituted alkyl, alkenyl or aryl having less than 19 carbon atoms, each of A and D may be any of methyl, hydroxy or vinyl groups,0<(m/n).ltoreq.1 and m+n>350,a complex comprising a transition metal salt of at least one polydentate chelating ligand having the formula: ##STR2## where each R.sub.1 may be an alkyl biradical having 1 to 6 carbon atoms or an aryl biradical having less than 19 carbon, atoms R'.sub.1, is an X' substituted R.sub.1, each of Z and E may be any of carboxy thiocarboxy, dithiocarboxy, or --N(R.sub.2).sub.2, --A.sub.s (R.sub.2).sub.2, --S(R.sub.2) where each R.sub.2 may be any of hydrogen or an alkyl radical having 1 to 6 carbon atoms or any aryl radical having less than 19 carbon atoms, X' may be any of hydrogen, carboxy, thiocarboxy, dithiocarboxy, --N(R.sub.2).sub.2, --A.sub.s (R.sub.2).sub.

Abstract: A hybrid fiber-reinforced plastic composite material comprising a matrix of a plastic and hybrid fibers consisting of inorganic fibers and at least one kind of fibers selected from the group consisting of carbon fibers, glass fibers, boron fibers, aramide fibers and silicon carbide fibers having a carbon core, wherein(a) the inorganic fibers are inorganic fibers containing silicon, either titanium or zirconium, carbon and oxygen and being composed of(i) an amorphous material consisting substantially of Si, M, C and O where M represents Ti or Zr, or(ii) an aggregate consisting substantially of ultrafine crystalline particles with a particle diameter of not more than 500 .ANG. of .beta.-SiC, MC, a solid solution of .beta.-SiC and MC and MC.sub.1-x, and amorphous SiO.sub.2 and MO.sub.2, where M is as defined and x is a number represented by 0<x<1, or(iii) a mixture of the amorphous material (i) and the aggregate (ii),(b) the composite material has an interlayer shear strength of at least about 9 kg/mm.sup.

Abstract: The inventive silicon-based coating composition provides an antistatic surface-releasing coating layer on a plastic film without the need of any antistatic undercoating. The coating composition comprises, in addition to the conventional ingredients in similar coating compositions including a vinyl-containing organopolysiloxane, an organohydrogenpolysiloxane and a platinum catalyst, a salt, e.g. nitrate and perchlorate, of a metal of the Ist, IInd or VIIIth Group of the Periodic Table and a specific organopolysiloxane having at least one per molecule of alkanolic pendant groups of the formula HO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 CH.sub.2 --, in which n is 1 to 9.

Abstract: Aqueous emulsions of (A) an organopolysiloxane comprising aliphatic radicals that are bonded to silicon via oxygen which have a molecular weight of at least 620 g/mol, and (B) an emulsifier containing a salt of a water-soluble organic or inorganic acid and a polysiloxane which contains siloxane units having monovalent SiC-bonded radicals with basic nitrogen, in which the basic nitrogen is present in an amount of at least 0.5 percent by weight based on the weight of the polysiloxane, and not more than 5 percent by weight of a water-soluble solvent or octanols, based on the weight of the emulsifier (B).These emulsions may be used to impart hydrophobic properties to mineral substances by applying the emulsions to the mineral substances after they have been molded. These emulsions may also be used to impart hydrophobic properties to inorganic binding agents or they may be used as binding agents for inorganic fibrous materials or as binding agents in aqueous paints.

Abstract: Ethoxylated siloxane surfactants, and mixtures of such surfactants with curable silicone prepolymers. The mixtures are hydrophilic after cure, have semipermanent hydrophilicity, and are especially useful as dental impressions.

Abstract: Storage stable, water-free, RTV organopolysiloxane adhesives curable in the presence of water or atmospheric moisture, and comprising a dihydroxydiorganopolysiloxane polymer, fillers, an amine fraction and a curing catalyst, are characterized by incorporation therein of a polyalkoxylated organosilane having the formula:R'.sub.x Si[(OCH.sub.2 CH.sub.2).sub.p OCH.sub.3 ].sub.4-xwherein R' is methyl, vinyl, allyl, methallyl or phenyl, and p and x are each one or two.

Abstract: The adhesion of organopolysiloxane compositions curable by a platinum catalyzed hydrosilation reaction to various substrates, particularly plastics, is improved by the presence in said compositions of (1) an organosilicon compound containing an ethylenically unsaturated group and at least one alkoxy group and (2) at least one member from a specified class of compounds of aluminum or zirconium.

Abstract: An auto-adhering one-component room temperature vulcanizable silicone sealant composition generally utilizing a di-substituted mixed oxime-alkoxysilyalkyl area adhesion promoter compound. The sealant has low odor, is non-corrosive to ferrous or aluminum substrates, has good adhesion to many types of substrates, and eliminates the need for a silicone resin primer. In addition, it exhibits surprisingly good adhesion to oil contaminated surfaces.

Abstract: Organopolysiloxane compositions comprising a polyorganosiloxane having olefinic unsaturation, an organohydrogen polysiloxane and a catalyst, exhibit improved adhesion to a number of substrates when it also comprises an organosilane of the general formula R'(RO).sub.2 SiR", wherein R denotes a monovalent hydrocarbon group, R' denotes an aliphatically unsaturated hydrocarbon or hydrocarbonoxy group and R" denotes an epoxy functional group. The organopolysiloxane compositions also exhibit reduced thixotropy over prior art compositions especially when a reinforcing silica filler is also present.

Abstract: A silicone crumb in a fine particulate form has an extrusion rate of at least 50 grams per minute through an orifice of 0.5 inch diameter under a pressure of 345 kilopascals and compression points of less than 1035 kilopascals. This crumb is made from a vinyl-containing polyorganosiloxane, a silicon-bonded hydrogen containing polysiloxane, a platinum catalyst, and a heat stability additive compound containing zirconium, titanium, or hafnium and organosiloxane. The crumb is useful in hydraulic applications where it is exposed to temperatures above 500.degree. F. for prolonged periods of time.

Abstract: The room temperature-curable organopolysiloxane composition of the invention is imparted with greatly improved stability in prolonged storage without being affected in respect of the curability. The composition is formulated, in addition to the base ingredients of a silanol- or alkoxy-terminated diorganopolysiloxane and a filler, with an alkenyloxy-containing silane compound in an amount of at least equimolar to the silanol groups and water in the base ingredients and a guanidino-containing organosilane compound in a limited amount.

Abstract: The invention is a reinforced reaction injection molded elastomer made by reacting in a closed mold amine terminated polyethers of greater than 1500 average molecular weight, having greater than 50% of their active hydrogens in the form of amine hydrogens, a chain extender, an aromatic polyisocyanate, a filler and an effective amount of a silane having the formula:(R').sub.y --Si--(R).sub.xwhere x+y=4; R' is a hydrophobic moiety and R is an alkoxy group, preferably methoxy or ethoxy.

Abstract: Silicone rubber matrices are used to contain and dispense volatile, organic liquids. The articles, as dispensors are improved by the addition of a compatibilizing agent to reduce migration of the organic liquid out of the matrix in the form of liquid drops or films. Higher loadings of the organic liquid into the rubber matrix are achieved without syneresis occurring.

Abstract: Novel methods are described for providing filled thermoplastic polymers by the integral addition, to the polymer/filler mixture, of a surfactant with or without a polymerizable unsaturated silicon compound containing at least one .ident.SiO-group and not more than five silicon atoms, e.g., a polymerizable unsaturated hydrolyzable silane, and/or a polymerizable unsaturated organic compound having two or more polymerizable unsaturated groups and novel filler/polymer compositions containing a surfactant are described. In addition novel integral additives containing surfactant and a polymerizable unsaturated silicon compound containing at least one .ident.SiO-group and not more than five silicon atoms, e.g., a polymerizable unsaturated hydrolyzable silane, and/or a polymerizable unsaturated organic compound having two or more polymerizable unsaturated groups are described.

Abstract: A high optical quality polyurethane coating layer, with self-repairing and fog-resistant properties, utilized for panes made of glass and/or plastic materials. The layer is formed from a reactive mixture composed 10 to 75% by weight of a biuret or an isocyanurate of 1,6 hexamethylenediisocyanate, having a content of about 15 to 25% weight of NCO radicals and having an average molecular weight between about 450 and 850 and comprised about 90 to 25% by weight of a polyalcohol component essentially comprised of a plurifunctional polyalcohol having about 0.4 to 17% of its percentage weight comprised of OH radicals, and having a molecular weight between about 200 and 15,000, and having ethoxy-propoxy chains, comprised 50 to 90% by weight of ethoxy radicals and 50 to 10% by weight of propoxy radicals.

Abstract: This invention relates to a mould material binding agent system for the manufacture of foundry mould parts. This binding agent system contains, as components, a solution of a phenol-containing polyol having at least two OH-groups in the molecule and a polyisocyanate, optionally in the form of a solution, having at least two NCO-groups in the molecule, which react with each other to a cold-hardening binding agent with formation of polyurethane. As polyisocyanate component there are used (optionally phenyl-substituted) diphenyl-4,4', diisocyanates having a content of more than 10% by wt. (referred to the total quantity of polyisocyanate), preferably more than 20% by wt., of the isomeric diphenyl-2,4'-diisocyanate (likewise optionally phenyl-substituted), which also contain an addition of a small quantity of acid chlorides and/or chlorosilanes.

Abstract: A composition for artificial marble which comprises a polymer composition in which an inorganic substance and an organic polymer are firmly bound in one body and a vinyl compound, said polymer composition being obtained by polymerizing a polymerizable vinyl monomer, in the presence of at least one monomer selected from the group consisting of carboxylic acid monomer, sulfonic acid monomer, and sulfonate monomer, in an aqueous polymerization system containing an inorganic substance dispersed therein; and a processs for producing artificial marble from said composition by cast polymerization with the addition of a polymerization initiator.

Abstract: A release coating used in cooking and baking comprising a thermosettable polyorganosiloxane resin, a noncurable polydiorganosiloxane fluid, and a combination of at least two metal containing compounds. Optionally, the coatings may contain carboxylic acid.

Abstract: Curable silicon prepolymers are made hydrophilic after cure by mixing the prepolymer with ethoxylated nonionic surface active agent or cationic or amphoteric fluorochemical surface active agent. The cured silicones have semipermanent hydrophilicity and are especially useful as dental impressions.

Abstract: This invention relates to stabilized adhesives, to which silyl esters are added for stabilization.

Abstract: The organopolysiloxane composition of the invention gives a cured silicone rubber article which is remarkably insusceptible to the accumulation of static electricity even in a prolonged service at an elevated temperature without sacrifice in respect of the performance of the permanent compression set. The inventive organopolysiloxane composition comprises, in addition to conventional components in silicone rubber compounds, an organosilicon compound, e.g. organopolysiloxane, having at least one .omega.-cyano-substituted n-alkyl group in a molecule in a specified amount.

Abstract: A composition for treating a solid material to give it antimicrobic, hydrophilic and antistatic properties comprises siloxane compound which has one or more alkoxysilylalkyl groups and one or more polyoxyalkylene groups and a silane having antimicrobial properties. In a preferred embodiment the composition is used to treat fibers and fiber-containing materials. The composition can further contain a curing agent for the siloxane. Emulsion compositions are particularly useful.

Abstract: Siloxane fluid blends containing a thiofunctional polysiloxane fluid and an organopolysiloxane fluid are stabilized against degradation in the presence of kaolin clays at elevated temperatures by adding an amine containing compound to blends of siloxane fluids.

Abstract: Thiofunctional polysiloxane fluids are stabilized against degradation in the presence of kaolin clay by adding an amine containing compound to the thiofunctional polysiloxane fluids.

Abstract: This invention relates to a mould material binding agent system for the production of foundry mould parts. This binding agent system contains as components a solution of a phenol-containing polyol having at least two OH groups in the molecule and a polyisocyanate, optionally also in the form of a solution, having at least two NCO groups in the molecule, which react with one another to a cold-hardening binding agent with formation of polyurethane. According to the invention there is also added to the polyisocyanate component a chlorosilane, which for example may comprise one or more compounds of the group trimethyl chlorosilane, dimethyl dichlorosilane, methyl trichlorosilane, tetrachlorosilane, diethyl chlorosilane, vinyl trichlorosilane and diphenyl dichlorosilane. The added quantity is preferably 0.01-2% by wt. relative to the polyisocyanate component.

Abstract: One-part moisture-curable polyurethane adhesive, coating, sealant, or casting compositions containing a blend of isocyanate-functional prepolymer, terpene-phenolic resin, and silane compound. The compositions adhere to a variety of unprimed substrates, and resist moisture and UV exposure.