Abstract: An aqueous polymerizable hybrid organometalloglass composition, with polymeric molecular hybrid nanocrystals optionally self-assembled within the composition. The composition may be applied to a substrate to form a polymeric hybrid organometalloglass coating or dried and processed to form a polymeric hybrid organometalloglass powder.

Abstract: A process for producing an epoxy silane oligomer including a reaction glycidoxy silane and/or cycloaliphatic epoxy silane having 2 or 3 alkoxy groups and, optionally, a copolymerizable silane other than glycidoxy and cycloaliphatic epoxy silane, with less than 1.5 equivalents of water in the presence of a catalyst, wherein said water is continuously fed during the reaction.

Abstract: A method of controlling oil-absorbing properties of a silicone rubber powder characterized by keeping a silicone rubber powder in hot storage at a temperature in the range of 40° C. to 150° C. or in cold storage at a temperature in the range of 0° C. to 10° C.

Abstract: Silicone compositions that are cationically crosslinkable into hard, anti-mist/anti-fouling coatings, e.g., onto thermoplastic substrates, contain colloidal particles of non-functionalized silica and also: at least one crosslinkable and/or polymerizable silicone monomer, oligomer and/or polymer comprising: at least one structural unit of formula (I): Z1(R0)aSiO(3-a)/2??(I) in which: a=0, 1 or 2; the radicals R0, which may be identical or different when a>1, are each an alkyl, cycloalkyl, aryl, vinyl, or alkoxy radical, or a hydrogen atom; the radicals Z1, which may be identical or different when the number of units of formula (I) is greater than 1, are each an organic substituent comprising at least one epoxy and/or alkenyl ether and/or oxetane and/or dioxolane and/or carbonate reactive functional group; and a total number of silicon atoms per molecule at least equal to 2; and an effective amount of at least one cationic initiator; and optionally, at least one organic solvent.

Abstract: Materials crosslinkable at room temperature by condensation are based on organosilicon compounds which cure to give permanently resilient materials, and which employ one or more compounds of the metals Li, Na, K, Mg, Ca, or Sr as catalyst.

Abstract: A coating solution for obtaining sol-gel films, the coating solution being composed of a solid matter and a solvent, the solid matter including a silicon oxide oligomer obtained by subjecting an alkoxysilane to hydrolysis and polycondensation in an acid aqueous solution; the solvent including an organic solvent having a boiling point of 100° C. or higher and a viscosity of 3.5 mPa·s or lower and the aqueous acid solution, the number average molecular weight of the silicon oxide oligomer in terms of polystyrene being 500-4000, the content of the solid matter in the coating solution being 8-30 weight %, and the content of the silicon oxide oligomer in the solid matter being 10 weight % or greater.

Abstract: The present invention relates to a silicone resin composition including a silicone resin and metal oxide fine particles dispersed therein, the silicone resin being obtained by reacting a siloxane derivative having at least one selected from the group consisting of an alkoxysilyl group and a silanol group at a molecular end thereof and having a weight-average molecular weight (Mw) as determined by a gel permeation method of 300 to 6,000, with silica fine particles having silanol groups on a surface thereof.

Abstract: Methods of treating a subterranean formation comprising first introducing a pre-flush fluid into a subterranean formation having particulate matter therein. Then introducing a curable adhesive composition comprising a silane coupling agent and a polymer, the polymer having a reactive silicon end group into the subterranean formation subsequent to the pre-flush fluid. Then introducing an aqueous post-fluid fluid into the subterranean formation subsequent to the curable adhesive composition. Then allowing the curable adhesive composition to at least partially consolidate particulate matter within the subterranean formation.

Abstract: Novel compositions for use in image forming apparatus and fuser members. In particular, the novel composition is a hybrid networked material comprising fluorocarbon chains connected via silane linkages. The novel composition may be used in fuser members comprising a substrate and a top-coat layer disposed over the substrate.

Abstract: A composition and method of treating substrates, in particular substrates having a hard surface such as ceramics, metal or glass, to render them water, oil, stain, and dirt repellent is described.

Abstract: Materials crosslinkable at room temperature by condensation, based on organosilicon compounds which cure to give permanently resilient materials, are catalyzed by a compound of the main or subgroups I and II in conjunction with an inorganic acid as a catalyst.

Abstract: A silicone resin composition is provided comprising a silicon base polymer obtained from dehydration reaction of a silicon base monomer comprising at least 70 mol % of a hydrolyzable silane compound (A). The hydrolyzable silane compound (A) has at least a pair of silicon atoms linked by a linking group which is an aliphatic hydrocarbon group or an aromatic ring-containing hydrocarbon group, and having attached thereto at least three substituent groups selected from hydrogen, hydroxyl and hydrolyzable groups. A proportion of aromatic structure-containing substituent groups is up to 30 mol % of the entire silicon-bonded substituent groups. The composition is suited to form an optical material.

Abstract: A silicone resin composition obtainable by reacting a bifunctional alkoxysilane and a trifunctional alkoxysilane in the presence of a dispersion of fine metal oxide particles. The silicone resin composition is suitably used in backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like.

Abstract: This invention relates to curable compositions containing hydroxyl compounds that carry silyl groups as well as to the use of said compositions.

Abstract: The invention relates to a composition comprising a binder, filler particles and water, wherein the binder comprises amorphous silica and a vinyl-functional silicone polymer. The invention also relates to a method of making this composition as well as to a method of coating a substrate comprising applying the composition onto the substrate.

Abstract: The invention relates to an antistatic coating composition comprising a hydrolyzate resulting from the at least partial hydrolysis of: a component A consisting of one or more compounds containing at least one polyalkylene oxide segment and at least one —Si(X)n hydrolyzable group, in which n is an integer ranging from 1 to 3 and the X groups are precursors of OH groups; at least one inorganic metal salt; and optionally, at least one component B, consisting of one or more compounds of formula Rn,Si(Z)4-n? or formula R1n1Ym1Si(Z1)4-n1-m1, in which the R groups are monovalent alkyl groups, the Z and Z1 groups are hydrolyzable groups or hydrogen atoms, the R1 groups are monovalent organic groups linked to the silicon atom through a carbon atom, the Y groups are monovalent organic groups linked to the silicon atom and containing at least one epoxy function, n? is an integer equal to O, 1 or 2, m1 and n1 are integers such that m1 is equal to 1 or 2 and n1+m1=1 or 2, component A and optional compo nent B being chosen

Abstract: The embodiments of the invention are directed to coatings and their uses. More particularly, the embodiments of the invention are directed to coating compositions that include silane-based precursors that are used to form coatings through a sol-gel process. The coatings so formed are characterized by anti-reflective, abrasion resistant, and anti-soiling properties. The coatings also have extended weatherability to heat, humidity, and protection against ambient corrosives. The coatings formed from the compositions described herein have wide application, including, for example, use as coatings on the outer glass of solar cells.

Abstract: An addition-curable silicone emulsion that exhibits stable curability even with a small amount of platinum. The curable emulsion composition is composed of an emulsion A and an emulsion B described below which are mixed together at the time of use, wherein the ratio of [number-average particle size of dispersed particles in emulsion A]/[number-average particle size of dispersed particles in emulsion B] is within a range from 0.4 to 2.0. The emulsion A comprises a specific alkenyl group-containing organopolysiloxane, a specific organohydrogenpolysiloxane, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm. The emulsion B comprises a specific alkenyl group-containing organopolysiloxane, a platinum-based complex, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm.

Abstract: A polyurethane resin composition comprising (A) a polycarbonate base polyurethane resin, (B) a P and N-containing non-halogen flame retardant, (C) a polyhydric alcohol, and (D) a silicone containing at least two reactive functional groups in the molecule obviates the problems of safety, environment and price and has sufficient flame retardance and improved mechanical properties such as tensile strength and elongation.

Abstract: Disclosed are a low-dielectric-constant thin film prepared from a silsesquioxane polymer matrix as a precursor, the silsesquioxane polymer matrix being a silsesquioxane sol prepared by adding a stereoisomer of a multireactive cyclosiloxane to an alkoxysilane, and a method for preparing the same. The disclosed low-dielectric-constant thin film retains a stable film state even at a curing temperature of ˜500° C. without being decomposed. Also, it exhibits a very uniform surface property with a low surface modulus and has such a superior coatability as to be coatable smoothly with no crack even with a thickness of 500 nm or larger. In addition, the low-dielectric-constant thin film according to the present disclosure may exhibit low dielectric property while having superior surface modulus and hardness.

Abstract: A mixture of a benzophenone derivative having hydroxyl and alkoxysilyl groups and a benzophenone derivative having silyloxy and alkoxysilyl groups provides a reactive UV absorber which is unlikely to gel, stable during shelf storage, and curable. A coating solution comprising the UV absorber cures at room temperature to form a UV-screening film which has adhesion to glass and plastic substrates, scratch resistance, and bleed resistance, and maintains a UV-screening function over time.

Abstract: A dental filler and dental resin restorative composition containing the dental filler is provided. The dental filler is prepared by pre-treating an acid-reactive filler with a polymerizable monomer or oligomer pre-treatment chemical having at least one acid or acid-precursor functional group, at least one polymerizable unsaturated carbon-carbon bond, and a molecular weight of about 1,000 grams per mole or less.

Abstract: Multistage polymers predominantly stabilized by nonionic emulsifiers and derived from hard and soft monomer compositions containing vinyl esters, of which at least one monomer composition must contain an unsaturated compromisable organosilicon compound, are described. The plastic dispersions can be used as binders in emulsion paints and finishes and impart to these excellent scrub resistance in addition to good blocking resistance.

Abstract: Dimethicone copolyol polymers are synthesized from dimethicone copolyol macromers. Polymers containing the macromer repeating units are useful in a variety of applications including personal care, textile and industrial formulations to deliver softness, lubricity, fixative, humidity resistance, water repellency, gloss, surface modification, and surfactant properties.

Abstract: A composition for and method for bonding a substrate. In general, applied to a substrate will be a primer composition that includes an adhesion promoter, which is an adduct prepared by the reaction of at least one aromatic polyisocyanate compound, with an active hydrogen containing moiety of an organofunctional silane, and a prepolymer derived from the reaction of at least one aliphatic polyisocyanate and a polyol, and is at least partially reacted with an active hydrogen containing moiety of an organofunctional silane.

Abstract: A (thio)phenoxyphenyl phenyl silane composition is disclosed. A method of making the (thio)phenoxyphenyl phenyl silane composition is also disclosed, the method further including a step of purification. A high purity (thio)phenoxyphenyl phenyl silane composition suitable for use in the preparation of encapsulants for high brightness light emitting devices is further disclosed.

Abstract: This invention relates to a method of preparing anti-corrosive hybrid sol-gel film coating on zinc or zinc alloy coated metallic substrates comprising the steps of preparing a mixture of sol-gel from hydrolisable silicon alkoxides, sodium venadate solution combined with colloidal silica in a beaker and vigorously stirred; adding within 20 seconds of two separated phase formation between silica precursors and colloidal silica acetic acid or dilute nitric acid as a catalizer to initiate hydrolysis reaction of silicon alkoxides and condensation reaction in the sol gel composition, continuously stirring the mixture for about 24 hours to form a single phase solution, applying the solution on cleaned zinc or zinc alloy coated metal substrates to form a transparent sol-gel coating film and drying the coated substrates at 50° to 200° C. for 10 to 60 minutes.

Abstract: The present invention provides novel filled silicone compositions comprising a nano-particulate metal oxide filler selected from nano-particulate monoclinic alpha-phase bismuth oxide, nano-particulate erbium oxide, and mixtures thereof. The new composite compositions exhibit a combination of outstanding performance characteristics in both the cured and uncured states. Thus, the uncured formulations are typically free flowing liquids which are self-leveling, which de-gas readily under vacuum, are readily colorable through the addition of pigments, and which cure at temperatures of about 60° C. The cured compositions possess outstanding acoustic characteristics which make them ideally suited for use in applications such as acoustic lenses for medical imaging and therapy. For example, the acoustic impedance of compositions provided by the present invention is closely matched to the acoustic impedance of human tissue.

Abstract: The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts and also to novel organopolysiloxane polycondensation catalysts.

Abstract: Materials crosslinkable at room temperature by condensation are based on organosilicon compounds which cure to give permanently resilient materials, and which employ one or more compounds of the metals Li, Na, K, Mg, Ca, or Sr as catalyst.

Abstract: Materials crosslinkable at room temperature by condensation, based on organosilicon compounds which cure to give permanently resilient materials, are catalyzed by a compound of the main or subgroups I and II in conjunction with an inorganic acid as a catalyst.

Abstract: A method of controlling oil-absorbing properties of a silicone rubber powder characterized by keeping a silicone rubber powder in hot storage at a temperature in the range of 40° C. to 150° C. or in cold storage at a temperature in the range of 0° C. to 10° C.

Abstract: A surface treatment process comprises (a) providing at least one substrate having at least one major surface; (b) combining (1) at least one curable oligomeric or polymeric polysilazane comprising at least one chemically reactive site, and (2) at least one fluorochemical compound comprising (i) at least one organofluorine or heteroorganofluorine moiety that comprises at least about six perfluorinated carbon atoms, and (ii) at least one functional group that is capable of reacting with the polysilazane through at least one of the chemically reactive sites; (c) allowing or inducing the polysilazane and the fluorochemical compound to react to form at least one curable organofluorine-modified polysilazane; (d) applying the curable organofluorine-modified polysilazane or its precursors to at least a portion of at least one major surface of the substrate; and (e) curing the curable organofluorine-modified polysilazane to form a surface treatment.

Abstract: Anti-reflective coatings and coating solutions, optically transparent elements and improved processes for preparing AR coatings and coating solutions are described. The anti-reflective coatings are formed from at least two different alkoxy silane materials in a base catalyzed reaction.

Abstract: A curable composition comprises (A) an organic/inorganic composite in which a hydrolyzable silyl group and/or SiOH group-containing polysiloxane is bonded to a vinyl polymer through a Si—C bond, and (B) an organic UV absorber having a molecular weight of at least 500 and a weight retentivity of at least 95% when held at 150° C. for 24 hours in an open state. The curable composition is coated and cured to an article, whereby the article is endowed with satisfactory weathering resistance while minimizing coloration or degradation.

Abstract: The present invention relates to a composition designed to be a release agent applied to the surface of a molding apparatus and method of using the composition in molding operations. The composition includes a siloxane composition, hydrophilic matting particles, a cross linking agent, a binding agent having hydrophobic and hydrophilic characteristics. The composition may optionally include a carrier. The composition is designed to be applied to the surface of a mold, allowing for repeated use without the need for re-applying the composition between uses.

Abstract: A composite resin is produced by hydrolyzing and condensing a silane compound (2) containing a bissilane compound (B) represented by: XnR3-nSi—Y—SiR3-nXn??(B) wherein Y is a divalent organic group which is optionally substituted with a fluorine atom or a divalent organic group which optionally contains an aromatic ring, R is a monovalent organic group, X is OH group or a hydrolyzable group, and n is 1, 2, or 3; in the presence of (1) porous and/or hollow inorganic oxide fine particles (A); and which is an integral mixture of component (1) and component (2) which has undergone the hydrolysis and the condensation. The composite resin has voids in the resin since it contains porous and/or hollow inorganic oxide fine particles, and the composite resin can also be formed into a cured article or a cured coating with a reduced refractive index since it contains air which has the lowest refractive index.

Abstract: The present invention provides a coating composition for antireflection that includes a) a low refractive material having a refractive index of 1.2 to 1.45, b) a high refractive material having a refractive index of 1.55 to 2.2 and comprising high refractive fine particles and an organic substituent, in which the difference in the surface energy between two materials is 5 mN/m or more; an antireflection film manufactured using the coating composition for antireflection; and a method of manufacturing the antireflection film. According to the present invention, the antireflection film having excellent antireflection characteristic can be manufactured by one coating process, thereby reducing manufacturing cost.

Abstract: Pt-catalyzed, addition-crosslinking silicone compositions which are self-adhesive at room temperature, develop adhesion rapidly on unpretreated substrates, and contain a functional alkoxy ?-silane as an adhesion promoter.

Abstract: A process of repairing a plasma etched low-k dielectric material having surface-bound silanol groups includes exposing at least one surface of the dielectric material to (a) a catalyst so as to form hydrogen bonds between the catalyst and the surface-bound silanol groups obtaining a catalytic intermediary that reacts with the silane capping agent so as to form surface-bound silane compounds, or (b) a solution comprising a supercritical solvent, a catalyst, and a silane capping agent so as to form hydrogen bonds between a catalyst and the surface-bound silanol groups obtaining a catalytic intermediary that reacts with the silane capping agent so as to form surface-bound silane compounds. Horizontal networks can be formed between adjacent surface-bound silane compounds.

Abstract: A coating composition and coating for ophthalmic lenses and other polymeric substrates having a unique combination of excellent solution stability, rapid cure rate, improved mar resistance, rapid dye absorption, and improved receptivity towards antireflective coatings. The coating comprises an abrasion resistant polymer and a dye-absorption-enhancing oligomer. The coating is tinted after curing with a dye to provide light absorbency in the coating.

Abstract: The invention relates to coatings with a contact angle hysteresis in water as measured by the tilting plate method of at most 20° made from silyl-terminated linear prepolymers which may cross-link with the surface of the substrate for coating, wherein the silyl-terminated linear prepolymers may be obtained by reaction of compounds of general formula (I): X-A-X? (I), where A=a polyoxyalkylene chain of ethylene oxide units or ethylene oxide and propylene oxide units with a maximum fraction of 50 wt.

Abstract: A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me2SiCH2—, where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least five equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about fifteen equivalents.

Abstract: A binder formulation is provided that is capable of forming a heat and erosion resistant coating on the surface of a substrate, particularly a substrate comprising titanium or aluminum. The binder formulation comprises a metal alkoxide compound, such as a titanium alkoxide and an organosilane, such as 3-glycidoxypropyltrimethoxysilane (GTMS). The binder material may be capable of strongly bonding the binder to the substrate. The binder coating may also include one or more additives that may help improve the heat resistance and impact absorbance of the coating. The binder may also include one or more pigments so that the resulting sol-gel coating has a desired appearance and properties. The sol-gel coating can be cured under ambient conditions and does not require additional heat curing.

Abstract: A silicon-containing compound of formula (1), and a curing composition containing a silicon-containing compound of formula (1) wherein Z is hydrogen, a silicon-containing compound of formula (1) wherein Z is C2-C4 alkenyl or alkynyl and a hydrosilylation catalyst. The composition has excellent handling and curing properties and provides a cured product with excellent heat resistance and flexibility. In formula (1), Ra—Rg=C1-C12 saturated aliphatic hydrocarbon group or C6-C12 aromatic hydrocarbon group. Re and Rf do not simultaneously represent C1-C12 saturated aliphatic hydrocarbon group; Y?C2-C4 alkylene; Z=hydrogen or C2-C4 alkenyl or alkynyl; K is 2-7; T is 1-7; P is 0-3; and M and N are numbers selected such that N:M=1:1 to 1:100, that all M's and N's total at least 15, and that the mass average molecular weight of the compound of formula (1) is 3,000 to 1,000,000.

Abstract: An emulsion for preparing a low-conductivity surface for powder coating, the emulsion including an emulsified organofunctional silane solution. A pre-powder coating emulsion provides a surface with conductivity. A non-conductive object having applied to an exterior surface of the object the emulsion including an emulsified organofunctional silane solution.

Abstract: An encapsulant composition is provided. The encapsulant composition includes at least one silicone resin monomer and at least one resin monomer selected from the group consisting of acrylic resin monomers and epoxy resin monomers, a filler of about 0.1-15 wt % of the encapsulant composition, and an initiator. The invention also provides a method for fabricating an encapsulant material.

Abstract: The present invention relates to a coating composition for a film with low refractive index and a film prepared therefrom, and more precisely, a coating composition with low refractive index which contains dispersed porous organic/inorganic hybrid nano-particles or a colloid containing the dispersed nano-particles, a photocurable compound having unsaturated functional groups, photoinitiator or photosensitizer, or an organic siloxane thermosetting compound, and a solvent and a film prepared therefrom. According to the present invention, porous particles have been formed by using a structural regulator in a silane compound at a specific size, in order to be fitted for a film with low refractive index, and then the structural regulator has been eliminated by a simple process before forming the film, resulting in preparation of a film with extremely low refractive index at a low temperature of up to 120° C.

Abstract: The present invention has its object to provide a liquid-form modified product of polyhedral polysiloxane which is excellent in moldability and transparency, and a composition produced using the modified product. In addition, the present invention can provide an easy-to-handle modified product and composition. The present invention provides a modified product of polyhedral polysiloxane which is obtainable by modifying a polyhedral polysiloxane compound (a) with a compound (b), and a composition containing the modified product. The polyhedral polysiloxane compound (a) has an alkenyl group and/or a hydrosilyl group, and the compound (b) has a hydrosilyl group and/or an alkenyl group each capable of hydrosilylation with the component (a).

Abstract: A fluid for dispensation on a substrate. In one implementation, the fluid comprises a set of fluid parameters to facilitate dispensation of the fluid from the system. In another implementation, the fluid comprises a set of fluid parameters specific to a polymerizable material.