Abstract: A composition comprising (A) at least one mercapto-functional organosilicon compound having an average of a least two mercapto groups per molecule and (B) a cure initiator. The mercapto-functional organosilicon compound may include mercapto-functional organosilanes, mercapto-functional organosiloxanes, and mercapto-functional copolymers. The compositions of the present invention polymerize or cure to form compositions comprising reaction products of components (A) and (B). The cure initiator is a metal salt that produces a uniform cure throughout the composition, regardless of the amount of oxygen present. The cured products range in properties from soft gels to though elastomers to hard resins and are useful as molded articles, electrical encapsulants, and sealants.

Abstract: The present invention provides the discovery of an improved radiation curable coating composition comprising at least one acrylic monomer, a photoinitiator, and an ultraviolet light absorber selected from triazine or a dibenzoyl resorcinol derivative or a mixture thereof, the dibenzoyl resorcinol derivative having the formula ##STR1## where Ar and Ar' are independently substituted or unsubstituted monocyclic or polycyclic aryl groups and R' is H or a linear or branched alkyl chain having less than about 10 carbons bearing a --Si(OR.sup.2).sub.3, where R.sup.2 is a C.sub.1 to C.sub.6 alkyl group.

Abstract: A coating composition particularly useful as a clear coating used over a pigmented base coat that has improved resistance to marring and to acid etching when exposed to natural weathering conditions containing 40-70% by weight of film forming binder and 30-60% by weight of a volatile liquid carrier for the binder; wherein the binder containsa.

Abstract: Cold-seal adhesives are disclosed that contain no natural rubber and are capable of forming dry coatings on flexible films which adhere to one another with commercially acceptable packaging strength at room temperature by pressure contact, but also allow such layered substrata to be reeled into rolls and stored for extended periods of time without blocking. The flexible films are usable in forming packages, particularly for comestibles and pharmaceuticals, without need for heat sealing. Such cold-seal adhesives are aqueous dispersions containing 30 to 55 percent of a polyurethane ionomer reaction product, having a T.sub.g of between about -50 to 10.degree. C., of a mixture of (a) a blend of between 0 and 40 percent polyester polyol and between 60 and 100 percent polyether polyol, (b) aliphatic diisocyanate and (c) dimethylol propionic acid and preferably containing 0.05 to 4 percent of grafted amorphous silica.

Abstract: A novel primer composition, which is especially adapted for promoting the adhesion of thermosetting rubbers to substrates having exceptionally inert surfaces, such a nickel, stainless steel and organic resins is disclosed. The composition comprises: (A) 100 parts, by weight, of an organosilicon compound selected from the group consisting of (1) alkenyltrialkoxysilane and (2) mild hydrolyzates of (1); (B) 0.01-200 parts, by weight, of a platinum compound; (C) 0.1-100 parts by weight of an organic titanic acid ester; and optionally (D) a solvent.

Abstract: The viscosity of a solvent is modified by thickening the solvent with a silicone latex. A silicone latex having a plurality of crosslinked polysiloxane particles is first prepared by mixing the siloxane polymer, a surfactant, and water; emulsifying the mixture to a gel phase; diluting the emulsion with water; adding a cure package (i.e., a catalyst, a crosslinker, or both, or a self catalytic crosslinker); and then without removing the water from the latex and after the particles of siloxane polymer in the latex have been cured, mixing the latex and solvent to thicken the solvent, forming viscous liquids, gels, and pastes. Water in the latex thickened solvent composition can be stabilized by adding a silicone polyether during mixing of the latex and the solvent.

Abstract: A coated particle is described, which includes a metal fluoride particle and a polysiloxane coating on the surface of the particle. A dental composition is also described, which includes the coated particle, a polymerizable monomer, and a polymerization initiator.

Abstract: The present invention provides for microporous ceramic materials having a surface area in excess of 70 m.sup.2 /gm and an open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.03 cm.sup.3 /gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and finely divided silicon carbide or silicon nitride, whose pyrolysis product in inert atmosphere or in an ammonia atmosphere at temperatures of up to less than about 1100.degree. C. gives rise to the microporous ceramics of the invention. Also provided is a process for the preparation of the microporous ceramics of the invention involving pyrolysis of the ceramic intermediate under controlled conditions of heating up to temperatures of less than 1100.degree. C. to form a microporous ceramic product.

Abstract: A crosslinked polysiloxane dispersion comprising a siloxane polymer, polymer mixture, or polymer/solvent mixture, capable of crosslinking via condensation, addition or free radical reactions, and having a viscosity of greater than 5000 mPa.s but less than 500,000 mPa.s, if required, 0.1 to 10 weight parts of a crosslinking agent, and, if required, depending on the nature of the catalyst and silicon cure system, 0.000001 to 10 weight parts of a catalyst, 0.5 to 10 weight parts of a surfactant or surfactant mixture, and 0.5 to 25 weight parts water per 100 weight parts siloxane polymer. Optionally, adhesion promoters, pigments, reinforcing or non-reinforcing fillers, silicone resins, stabilizers, freeze/thaw additives, etc. may also be added to the dispersion.

Abstract: A curable silicone is used to encapsulate porous, photoluminescing silica nanoparticles having three-dimensional, web-like structures. The encapsulation protects the silica nanoparticles, preserves their photoluminescent effect, and can be used as a coating. The composition is used to prepare articles of manufacture by casting it on a substrate such as glass or a silicon wafer and curing it. Special effects can be obtained by using a mask on the substrate prior to deposit of nanoparticles and curing the silicone matrix.

Abstract: A highly storage-stable room-temperature-curable organopolysiloxane composition that cures to yield a product whose surface resists staining and that does not cause staining of the neighboring regions of the substrate in contact with said cured product. The organopolysiloxane composition is made from a polydiorganosiloxane, an imidazolinyl-functional organosiloxane, a filler, and a crosslinking compound which is a Si-bonded hydrolyzable group-containing organosilane or organosiloxane oligomer.

Abstract: The invention relates to a process for producing immobilized polysulphide silanes, characterized by the conversion of a halogenated alkyl silane (A), optionally in the presence of a further organic halogen compound (B), with a polysulphide (C) in the presence of water and an inorganic or organic carrier material, wherein the content of the carrier material in the (dried and water-insoluble) end product is 20 to 99.5 wt. %.The immobilized polysulphide silanes are used for producing rubber mixtures and vulcanisates, particularly for tires, which have a low rolling resistance and an enhanced thermal load capacity.

Abstract: A thermally expansible composition is provided as well as method of making the composition and actuators and other devices employing the composition. The composition comprises a mixture of silicone elastomer and a thermostatic wax, polymer, alloy or alloy mixture that melts below 400.degree. F. The composition is moldable by any common technique, may be handled at room temperature without heating or refrigeration and can be easily contained in an actuating device without seals other than an anti-extrusion closure seal. This composition can be used in actuators without seals or return springs or other reconsolidating means.

Abstract: A thermosetting resin or coating composition contains (a) a film-forming polyol resin, (b) a curing agent reactive with the polyol resin, (c) a hydrolyzate/polycondensate of tri- or tetraalkoxysilane, and (d) a catalyst for promoting the reaction between the polyol resin (a) and the curing agent (b).

Abstract: Finishing agents comprise the combination of an alkoxysilane surface active agent, a silanol condensing catalyst, and a nonaqueous liquid or solid medium, or the combination of an alkoxysilane surface active agent, an acid catalyst and a liquid or solid medium. In the latter embodiment, it is preferred that at least one of the alkoxysilane surface active agent and the acid catalyst be microencapsuled. The finishing agent permits formation of chemically adsorbed protecting films. Such protecting films are used for substrates of such equipments as electronics products, electric domestic products, automobiles, industrial equipment, mirrors, lenses for glasses and the like. The protecting films have a durability and heat, weather and abrasion resistance, and also water and oil repellent properties.

Abstract: A novel silicone system comprising a methoxy terminated silane or polysiloxane, an adhesion promoter and water, useful as a filler alone or in combination with other fillers is disclosed.

Abstract: A coating composition containing(A) a silyl group-containing vinyl polymer which has on the polymer chain ends or side chain thereof at least one silicon atom, to which a hydrolyzable group is linked, per polymer molecule,(B) a reaction product of an aminosilane compound with an epoxy compound(C) a hydrolyzable ester compound and(D) an inorganic pigment.The coating composition of the present invention has excellent film properties such as appearance, moisture resistance and grindability and is suitable for use as an undercoating and a primer coating.

Abstract: A method capable of the continuous mass-production without pressurization and using a low drive force of highly uniform and very storage-stable organopolysiloxane emulsions. The method for the continuous preparation of organopolysiloxane emulsions includes processes (I) and (II). Process (I) is the continuous supply of (a) organopolysiloxane fluid or gum, (b) emulsifying agent, and (c) water to a mixer having a first-stage shearing and stirring mechanism with a stator and a turbine-type rotor having blades that are slanted obliquely from the radial direction when viewed from the axial direction, and a second-stage shearing and stirring mechanism with a stator and a turbine-type rotor having blades that describe spiral curves with respect to the axial direction, and the discharge of an organopolysiloxane-in-water emulsion with an organopolysiloxane content of 10 to 99 weight %. Process (II) is the introduction of dilution water and the emulsion of process (I) into a mixer as described for process (I).

Abstract: An organic solvent-based paint is provided which has, among other things, a perlitic component. The paint resists thermal loading and loss. A series addition of components provides the paint efficiently. The paint is useful for many substrates, including metals.

Abstract: Disclosed are compositions which can be used to form tamper-proof coatings on electronic devices. These compositions contain a silica precursor resin and a filler which reacts in an oxidizing atmosphere to liberate heat. Such compositions form coatings which, when oxidized by techniques such as plasma etching, wet etching, or cross-sectioning, liberate heat which causes destruction of the underlying substrate and, thus, inhibits further examination.

Abstract: a composition and method are disclosed whereby a substrate such as glass, plastic, metal, inorganic polymer coated substrate or inorganic coated substrate is provided with a durable non-wetting surface by treatment with a perfluoroalkylalkyl silane in a solvent which together form a composition which initially wets the surface. As the perfluoroalkylalkyl silane reacts with the surface, the remaining composition is repelled by the perfluoroalkylalkyl silane treated surface due to the difference between the surface tension of the solvent and the free energy of the treated surface, for expedient removal of the remaining composition from the treated surface.

Abstract: A coating composition comprising:a hydrolyzed or partially hydrolyzed alkoxysilane,a solvent,and an arylcyclobutene;is useful in a variety of applications, including coatings for multichip modules, flat panel displays and integrated circuits. The preferred alkoxysilanes correspond to the formula: ##STR1## wherein R is C.sub.1 -C.sub.6 alkylidene, C.sub.1 -C.sub.6 alkylene, arylene, or a direct bond; Y is C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl, aryl, 3-methacryloxy, 3-acryloxy, 3-aminoethylamino, or 3-amino; R' is independently in each occurrence C.sub.1 -C.sub.6 alkyl; and Z is C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl or OR'.

Abstract: An aqueous organosiloxane liquid composition in a homogeneous state is disclosed, which contains (A) aqueous modified organosilicon compound having at least one polyether group as a side chain, (B) liquid organopolysiloxane, (C) a cross-linking agent, (D) a curing catalyst and, optionally, (E) a filler. This composition undergoes uniform curing, when exposed to the atmosphere of a temperature of up to 300.degree. C., to form a siloxane polymer composition in a form of a film, fibers, a composite structure, a composite sheet or a building material. The composition can also be used as a coating composition or varnish.

Abstract: Method and apparatus for preparing uniform highly dispersed emulsions by using a low drive power and without pressurization, making possible continuous mass production of uniform organopolysiloxane emulsions. An organopolysiloxane, water and a emulsifying agent, are continuously fed across a first-stage shearing and stirring mechanism and a second-stage shearing and stirring mechanism. The first-stage mechanism is a stator and turbine-type rotor whose blades are slanted obliquely from the radial direction when viewed from the axial direction. The second-stage mechanism is a stator and turbine-type rotor whose blades describe spiral curves with respect to the axial direction. The two mechanisms are arranged serially and separated from one another by a relaxation zone.

Abstract: The present invention relates to organopolysiloxane-containing compositions which are self-dispersing in water, their preparation and their use. The compositions of the present invention are suitable for all uses where organosilicon compounds, especially in water-diluted form, can be employed. Such uses include uses as water repellant agents on building materials.

Abstract: The present invention provides for microporous ceramic materials having a surface area in excess of 70 m.sup.2 /gm and an open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.03 cm.sup.3 /gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and finely divided silicon carbide or silicon nitride, whose pyrolysis product in inert atmosphere or in an ammonia atmosphere at temperatures of up to less than about 1100.degree. C. gives rise to the microporous ceramics of the invention. Also provided is a process for the preparation of the microporous ceramics of the invention involving pyrolysis of the ceramic intermediate under controlled conditions of heating up to temperatures of less than 1100.degree. C. to form a microporous ceramic product.

Abstract: Disclosed are coating compositions which include hydrogen silsesquioxane resin dissolved in saturated alkyl hydrocarbons. The compositions are useful for forming coatings which are thick and/or have good coating quality.

Abstract: The present invention provides a moisture-curable alkoxysilane functional polyurethane prepared from a hydroxy functional alkoxysilane. The hydroxy functional alkoxysilane is a hydroxyalkylenecarbamoylalkylene-alkoxysilanes referred to as a "hydroxycarbamoylsilane". The alkoxysilane functional polyurethanes may be used in a variety of applications to provide, for example, moisture-curable adhesives, sealants, putties and the like.

Abstract: Water soluble organosiloxane compounds are provided comprising an oligomer incorporating an addition product of at least two reactants wherein one reactant is at least one 3-glycidoxypropylalkoxy siloxane and the other reactant is at least one secondary hydroxyalkyl amine, optionally, an alkoxysilane different than 3-glycidoxypropylalkoxysilane; optionally, a primary or secondary amine different than the secondary hydroxyalkyl amine; and water.

Abstract: Method and apparatus for preparing uniform highly dispersed emulsions by using a low drive power and without pressurization, making possible continuous mass production of uniform organopolysiloxane emulsions. An organopolysiloxane, water and a emulsifying agent, are continuously fed across a first-stage shearing and stirring mechanism and a second-stage shearing and stirring mechanism. The first-stage mechanism is a stator and turbine-type rotor whose blades are slanted obliquely from the radial direction when viewed from the axial direction. The second-stage mechanism is a stator and turbine-type rotor whose blades describe spiral curves with respect to the axial direction. The two mechanisms are arranged serially and separated from one another by a relaxation zone.

Abstract: This application is concerned with room temperature vulcanizing compositions useful as mould making materials which are formed by mixing an alpha, omega dihydroxy polysiloxane, a condensation polydimethylsiloxane, catalyst and a crosslinking agent which comprises a tri- or tetra-alkoxy silane or siloxane in which the alkoxy groups contain more than two carbon atoms. Moulds made with these materials on epoxy masters show improved usage; the improvement is related to the size of the alkoxy "leaving group" and the proportion of crosslinker and condensation catalyst.

Abstract: Novel and highly reactive hydrolyzed silane emulsions are achieved by emulsifying a hydrolyzable alkoxysilane (e.g., or the like) in water in the presence of an effective amount of an emulsifier of sufficiently high HLB value (preferably 14 or greater) to simultaneously retain said hydrolyzable alkoxysilane compound in a substantially totally hydrolyzed state and inhibit said resulting hydrolyzed alkoxysilane compound from self-condensation. Such reactive emulsions containing hydrocarbon silanes are useful to produce durable coatings that impart water repellency and lubricity to substrates having siliceous, cellulosic or proteinaceous surfaces.

Abstract: Disclosed are aqueous solutions of polymeric organosiloxane-ammonium compounds which possess ion exchange properties and a method for manufacture from solid organopolysiloxanes. The solutions are used in the hydrophobing treatment of inorganic materials and building materials.

Abstract: Novel and highly reactive hydrolyzed silane emulsions are achieved by emulsifying a hydrolyzable alkoxysilane (e.g., perfluoroalkylethyltris(2-(2-methoxyethoxy)ethoxy)silane, 2-perfluoroalkylethyltris(2-(2-(2-methoxyethoxy)ethoxy)ethoxy) silane, 2-Perfluoroalkylethyltris(polyoxyethyleneglycolmonomethylether)silane or the like) in water in the presence of an effective amount of an emulsifier of sufficiently high HLB value (preferably 14 or greater) to simultaneously retain said hydrolyzable alkoxysilane compound in a substantially totally hydrolyzed state and inhibit said resulting hydrolyzed alkoxysilane compound from self-condensation. Such reactive emulsions containing fluorocarbon silanes are useful to produce durable coatings that impart oil and water repellency to substrates having siliceous, cellulosic or proteinaceous surfaces.

Abstract: An aqueous primer composition comprising a copolymer wherein a cationic monomer, a specific alkoxysilane monomer, a silane macromonomer and an ethylenically unsaturated monomer are contained in aqueous medium. For this reason, regardless of the alkalinity of the substrate, the aqueous primer composition can form a highly water-resistant, alkali-resistant, tough film. Furthermore, compared with the prior art, a higher concentration and a lower viscosity, so that the resulting primer composition shows excellent penetration into the substrate at high concentration and provides for sufficient substrate-reinforcing and water-proofing effects. Moreover, when forming a film thereby and forming a finish layer thereon, this composition shows a high affinity for the top coating or adhesive to insure a firm integration of the finish layer with the substrate surface.

Abstract: An electrorheological(ER) composite material with solid, elastomeric characteristics in the form of an elastomer matrix encompassing an ER fluid. This ER composite material changes certain of its physical properties in response to an imposed electric field (as do known ER fluids), but it has the advantage of maintaining a defined spatial volume without the need of sophisticated seals. It also provides desirable design features inherent in an elastic solid having the specific capability of being molded in conjunction with a containment surface to which it strongly adhesively bonds. Certain physical properties of these ER composite materials and their physical response to the application of an electric field may be varied by varying the properties and/or the proportions of the ER fluid component and the resin prepolymer component which are employed in formulating the composite.

Abstract: A primerless silicone hardcoat composition is provided which utilizes an acrylated or methacrylated polyurethane or an acrylic copolymer such as an acrylic polyol as an adhesion promoter in combination with silicone hardcoat ingredients.

Abstract: This invention provides a primer composition comprising (A) a polyorganosiloxane resin containing at least 0.01 mole of hydroxyl groups per 100 g of the resin represented by the average composition formula: (R.sup.1).sub.a SiO.sub.(4-a)/2 wherein each R.sup.1 represents a substituted or unsubstituted monovalent hydrocarbon group, and a is a value of 0.4 to 1.8; (B) an alkoxytitanium or a partially hydrolyzed product thereof; (C) an acid; and (D) a solvent. The primer composition can strongly adhere a condensation type room temperature curable silicone elastomer to the surface of the coated metal formed by applying a fluororesin coating, an acrylic resin coating or the like to a metal.

Abstract: Water based silicone coating compositions are provided offer superior coating properties, durability and resistance to high temperatures and to the effects of corrosive environments. These coating compositions are especially useful for coating the external and intricate internal surfaces of high temperature aluminum heat exchangers.

Abstract: A method of co-hydrolyzing silanes of the formulas HSi(OR).sub.3 and Si(OR).sub.4 to form a soluble resinous co-hydrolysate is disclosed. The method comprises hydrolyzing the silanes with water in an acidified oxygen containing polar organic solvent. The invention also relates to the soluble co-hydrolysates formed thereby as well as the method of using the co-hydrolysates to provide coatings on various substrates, including electronic devices.

Abstract: This invention relates to one-component silicone systems (herein referred to as 1-C-RTV compounds) which cure rapidly under the effect of moisture with elimination of certain carbonamides, develop good adhesion to many substrates in the process and give vulcanizates that are stable under extreme climatic conditions.

Abstract: A novel method for preparing an organically-modified, heat-curable silicone resin and the novel resin produced thereby are disclosed. In the method of the invention, a trialkoxysilane, a difunctional diorganosilicon compound, a polyol and a catalytic amount of an acidic cationic siloxane polymerization catalyst are reacted to substantial equilibrium to form an alkoxy-functional product. Substantially all the hydrolyzable alkoxy groups of the alkoxy-functional product are then hydrolyzed and the catalyst inactivated. The product is stripped of water and alcohol and may be diluted with a polar solvent such as xylene to the desired viscosity. The heat-cured resin product obtained in accordance with the invention has superior hardness, flexibility and solvent and impact resistance.

Abstract: Water based silicone coating compositions are provided that offer superior coating properties, durability and resistance to high temperatures and to the effects of corrosive environments. These coating compositions are especially useful for coating the external and intricate internal surfaces of high temperature aluminum heat exchangers.

Abstract: Heat curable primerless silicone compositions are provided comprising an aqueous/organic solvent silicone dispersion in combination with an adhesion promoter, such as acrylate or methacrylate ester, for example, a caprolactone acrylate or methacrylate adhesion promoter. Composites of a thermoplastic substrate, such as a polycarbonate, and the thermally cured primerless silicone compositions are also provided.

Abstract: A liquid coating composition for the formation of a liquid crystal display element insulating film, which comprisesa) hydrolyzed product of tetraalkoxysilane of the general formula (1) below and trialkoxysilane of the general formula (2) below,b) an aluminum salt, andc) a deposition inhibitor, dissolved in an organic solvent.Si(OR).sub.4 (1)wherein R represents a C1-5 alkyl groupR.sup.1 Si(OR.sup.2).sub.3 (2)wherein R.sup.1 represents an alkyl, alkenyl or aryl group, and R.sup.2 represents a C1-5 alkyl group. The liquid coating composition according to the present invention is useful as an insulating film for a liquid crystal display element, as it exerts no adverse influence on the display property thereof.

Abstract: A method of producing 0.01 to 70 wt. % aqueous solutions of sulfonated organosilicon compounds having the formula[(HO).sub.3 Si-R.sup.1 -SO.sub.3.sup.- ].sub.x M.sup.x+ (I)or oligomeric siloxane derivatives thereof, condensed via oxygen bridges. The solution optionally also contains compounds of formula (III) e.g., Si(OH).sub.4 or Al(OH).sub.3, or the like, or derivatives thereof condensed via oxygen bridges. The ratio of Si atoms of formula (I) to the sum of Si and/or Al atoms of formula (III) is 1:0 to 1:3, and the total concentration of compounds (I)+(III) is 0.01 to 70 wt. %. The starting material for the method is a polymeric di-, tri-, or tetrasulfane compound made up of units having the formula: ##STR1## wherein R.sup.1 has the same meaning as in formula (I), and y=2, 3 or 4. The starting material of formula (IV) is suspended in water. The suspension is mixed at 10.degree. to 100.degree. C. with hydrogen peroxide and is then agitated at 30.degree. to 150.degree. C.

Abstract: A poysiloxane resin composition includes a blend of silanols, colloidal silica, an ultraviolet-absorbing material, and a dye for correcting the color of a film formed from the resin composition. The silanols include a silanol from the group having the formula R.sub.w Si(OH).sub.x or R.sub.y Si(OR').sub.z where (w+x) or (y+z)=4, and R and R' are organic radicals without any crosslinking sites, silanol from the group having the formula R"Si(OR'").sub.3 where R" is a hydrogen atom or an organic radical and R"' is an organic radical containing a crosslinking site. The resin may be cured at 420.degree. F. The ultraviolet-absorbing material may be a benzophenone, a benzotriazole, or a benzothiazole. A process for forming the resin composition includes reacting the silanols and the ultraviolet-absorbing material under continuous agitation for about six hours.

Abstract: A stable aqueous dispersion having a particle size in the range of about 10 to about 200 nanometers containing specific silanes carrying at least one hydrophobic moiety and at least one water-solubilizing moiety is claimed along with the process for treating a cellulosic substrate and the treated cellulosic product resulting therefrom. The aqueous dispersions are stable for at least 20 days without externally added surfactant.

Abstract: A silicone rubber composition having thermal conductivity higher than 5.times.10.sup.-3 cal/cm.multidot.sec.multidot..degree.C. and excellent workability in various molding processes, which comprises A) 95-50 parts by weight of an organopolysiloxane having an average polymerization degree of 6,000-12,000, B) 5-50 parts by weight of an organopolysiloxane having an average polymerization degree of 200-2,000, C) 500-1,200 parts by weight of a spherical aluminum oxide powder and D) a curing agent ample for curing the composition consisting of A) to C) .

Abstract: A primerless silicone hardcoat composition is provided which utilizes polycaprolactone polyol as an adhesion promoter in combination with silicone hardcoat ingredients,