Nitrogen Atom As Part Of A Hetero Ring Dnrm Patents (Class 524/86)
  • Patent number: 6245118
    Abstract: Resinous compositions, especially synthetic resins and most especially arylate polymers, contain 2,3-dicyano-1,4-diaminoanthraquinone as a blue dye. Said compositions are characterized by improved weatherability in comparison with compositions containing other blue dyes.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: June 12, 2001
    Assignee: General Electric Company
    Inventor: Alexander Isaakovich Shakhnovich
  • Patent number: 6231936
    Abstract: Provided are articles such as packaging materials and medical devices having enhanced tolerance to radiation and heat, produced from a blend of from about 99% to about 50% by weight homo or copolymerized polypropylene and about 1% to about 50% by weight polyethylene produced by single-site catalysis, such polyethylene having a MWD between about 1 and about 4, and a CDBI greater than about 45%. Optionally, other blend components may be added, such as hindered amine stabilizers, secondary antioxidants, clarifying nucleators and secondary antioxidants. Also provided are processes for producing such articles.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: May 15, 2001
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: ReneƩ A. Kozimor, Robert C. Portnoy
  • Patent number: 6218450
    Abstract: A copolyester blend resistant to ultraviolet radiation includes a polyethylene terephthalate based copolyester having 1,4-cyclohexanedimethanol residues; an effective amount of an ultraviolet radiation absorber selected from the group consisting of benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof; from about 5 mol % to about 40 mol % isophthalic acid residues in the copolyester, and from 5 mol % to 20 mol % 4,4′-biphenyldicarboxylic acid residues present in the copolyester, wherein the mole percent of the diacid is based on 100 mole percent of dicarboxylic acid or equivalents. The copolyester blend is useful in making UV radiation resistant thermoformed articles.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: April 17, 2001
    Assignee: Eastman Chemical Company
    Inventor: David Richard Fagerburg
  • Patent number: 6187859
    Abstract: An improved light stable polyether/polyol based aliphatic urethane thermoplastic elastomer prepared from reacting inter alia a polyol having low terminal end unsaturation and an organic diisocyanate. The elastomer is characterized by ultra violet stabilizer being present in a range of 0.25% to 2.0% at a total concentration of 1.0% to 2.0%, an antioxidant being present at a total concentration of 0.10% to 1.0%, and colorants/pigment being present in a total concentration in a range from 1.0% to 2.05% to produce an elastomer capable of withstanding Xenon arc artificial weathering with DE≦3.00 after 2450 kilojoules of exposure.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: February 13, 2001
    Assignee: Davidson Textron Inc.
    Inventors: William M. Humphrey, Victor E. Gerard
  • Patent number: 6184306
    Abstract: The present invention relates to asymmetrical siloxy compounds of the formula wherein R1, R2 and R3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; and n is an integer of from 1 to 8.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: February 6, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thierry Florent Edme Materne, Giorgio Agostini, Friedrich Visel, Martin Paul Cohen
  • Patent number: 6184304
    Abstract: A photoluminescent material is prepared by preparing a gel from a solution of the resin in a solvent, and pyrolyzing the resin gel in oxygen by heating the gel to a temperature above approximately 400° C. for about two hours.
    Type: Grant
    Filed: July 19, 1999
    Date of Patent: February 6, 2001
    Assignee: Dow Corning Corporation
    Inventor: Udo C. Pernisz
  • Patent number: 6156236
    Abstract: A conductive organopolysiloxane composition is provided which includes (A) 100 parts by weight of an organopolysiloxane; and (B) 0.1 to 800 parts by weight of a conductive material obtained by subjecting a member selected from the group consisting of a conductive metal, a conductive metal compound, a filler surface-treated with a conductive metal and a filler surface-treated with a conductive metal compound, to surface treatment with a compound selected from the group consisting of a compound represented by the formula (1) and a compound represented by the formula (2). ##STR1## wherein R.sup.1 represents --O-- or --NH--, and R.sup.2 represents a hydrogen atom or a phenyl group. This composition is useful for the formation of a silicone rubber having a sufficient electrical conductivity and also stably retainable of electrical conductivity almost without undergoing a change in electrical conductivity even in a high-temperature environment.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: December 5, 2000
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Osamu Hayashida, Takeo Yoshida, Toshihide Shimizu, Tamaki Iida
  • Patent number: 6147145
    Abstract: A monomer composition is described, containing A) vinyl-containing monomers in which the vinyl bears a hetero-atom selected from the group consisting of the halogens, nitrogen, oxygen, sulfur or silicon, andB) at least one N-oxyl compound of a secondary amine which does not bear hydrogen on the .alpha.-carbons, in an amount effective as stabilizer against premature polymerization.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: November 14, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Aumuller, Andreas Koch, Heinz Friedrich Sutoris, Jacques Dupuis, Manfred Niessner
  • Patent number: 6113980
    Abstract: A method for improving the chargeability of a powder coating composition containing an organic film-forming binder, which method comprises incorporating into the powder coating composition at least two different compounds containing a residue of the formula (A) ##STR1## as electron donors.
    Type: Grant
    Filed: January 30, 1998
    Date of Patent: September 5, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Hugh Stephen Laver
  • Patent number: 6103776
    Abstract: Phenolic amides, useful as stabilizers for organic materials such as polyols and polyurethanes, possess the general formula ##STR1## wherein n is 0 to 3, R.sub.1 is alkyl of from 1 to about 6 carbon atoms, R.sub.2 is hydrogen or alkyl of from 1 to about 6 carbon atoms, R.sub.3 is hydrogen or hydrocarbyl of up to about 20 carbon atoms, optionally containing one or more heterocyclic groups, R.sub.4 is hydrocarbyl of up to about 20 carbon atoms, optionally containing one or more heterocyclic groups, or R.sub.3 and R.sub.4 together with the nitrogen atom to which they are bonded are joined together to form a heterocyclic group, optionally containing one or more additional heterocyclic atoms.
    Type: Grant
    Filed: January 26, 1999
    Date of Patent: August 15, 2000
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Robert G. Rowland, John R. Baranski
  • Patent number: 6096832
    Abstract: The present invention relates to asymmetrical siloxy compounds of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R.sup.4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; and n is an integer of from 1 to 8.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: August 1, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thierry Florent Edme Materne, Giorgio Agostini, Friedrich Visel, Martin Paul Cohen
  • Patent number: 6090316
    Abstract: A method of making an aluminum hydroxide and melamine blend. The method comprises jet milling a quantity of coarse particle size melamine until a line particle size melamine is obtain which has a median particle size of from about 0.5 .mu.m to about 45 .mu.m, passing the fine particle size melamine through an air classifier and a cyclone separator, and admixing the fine particle size melamine with a quantity of surface treated aluminum hydroxide in a high speed mixer.
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: July 18, 2000
    Assignee: J. M. Huber Corporation
    Inventors: Weiming Zhu, Kurt Henry Moller, Paris W. Chen
  • Patent number: 6084037
    Abstract: In an epoxy resin composition comprising an epoxy resin, a curing agent, and an inorganic filler, there are blended a salt of trimellitic anhydride with 1,8-diazabicyclo(5.4.0)undecene-7 as a curing accelerator and a mercapto-containing silane coupling agent. The composition is shelf stable and smoothly flowing and cures into a product having improved adhesion, moisture resistance and electrical properties. The composition is suitable for the encapsulation of semiconductor devices.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: July 4, 2000
    Assignee: Shin -Etsu Chemical Co., Ltd.
    Inventors: Hisashi Shimizu, Minoru Takei, Masachika Yoshino, Toshio Shiobara
  • Patent number: 6084035
    Abstract: A resin composition for powder coating, comprising(A) a carboxyl group-containing resin having a number average molecular weight of 1000 to 20000, an acid value of 5 to 200 and a glass transition temperature of 30 to 120.degree. C.,(B) bis(.beta.-methylglycidyl)terephthalate of the formula (1): ##STR1## as a curing agent, and (D) at least one compound selected from the group consisting of amines having the linkage of the formula (2): ##STR2## in the molecule, a triarylphosphines and onium salts as a ring-opening polymerization inhibitor, the equivalent ratio of (.beta.-methylglycidyl group of the component (B))/(carboxyl group of the component (A)) being 0.5 to 3.0. The composition can give a product of curing excellent in impact resistance, weathering resistance and so on.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: July 4, 2000
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Satoru Miyake, Hisao Ikeda, Toshinari Koda, Motohiko Hidaka
  • Patent number: 6075072
    Abstract: A corrosion protective coating composition, applied over a metal surface, contains frangible microcapsules which rupture and release fluid upon impact or other stress likely to damage the coating. The fluid, from the microcapsules, contains a film forming component to cover the damaged area of the coating and a corrosion inhibitor for the metal surface.
    Type: Grant
    Filed: March 13, 1998
    Date of Patent: June 13, 2000
    Assignee: 3M Innovative Properties Company
    Inventors: Curtis R. Guilbert, David G. Enos, Charles E. Boyer, III
  • Patent number: 6071981
    Abstract: A polymer composition comprising an anticoagulant carried in a water soluble polymer hydrogen bonded to a cellulose polymer. The composition is useful as sutures, implantable material, temporary grafts, vasculature connections and the like. The composition can be prepared by a method comprising the steps of: forming a solution in an amine oxide of a water-soluble polymer capable of hydrogen bonding, a cellulose polymer, and an anticoagulant and reducing the amount of amine oxide in the solution to solidify a solid polymer composition comprising the anticoagulant in the water soluble polymer and the cellulose polymer. The polymer compositions are particularly useful in temporary implants, sutures, grafts or the like.
    Type: Grant
    Filed: September 30, 1998
    Date of Patent: June 6, 2000
    Assignees: Aveka, Inc., Techmatch, Inc.
    Inventors: Dee Lynn Johnson, William A. Hendrickson
  • Patent number: 6039799
    Abstract: A paper coating composition which comprises:(I) a pigment,(II) an aqueous binder, and(III) a crosslinked amine compound obtainable by reacting a heterocyclic amine (a) and a glycidyl compound (b) having at least two glycidyl groups in the molecule,and a method for preparing the paper coating composition.
    Type: Grant
    Filed: August 25, 1998
    Date of Patent: March 21, 2000
    Assignee: Sumitomo Chemical Company Limited
    Inventors: Akira Kawamura, Toshiyuki Hasegawa, Akira Tanikawa
  • Patent number: 6040366
    Abstract: The compression set of elastomeric silicone compositions, addition cured injection moldable compositions, is reduced by the incorporation of nitrogen compounds wherein the nitrogen possesses at least one organic substituent and the nitrogen is tetravalent wherein the nitrogen is cationic. The adhesion of such compositions to thermoset or thermoplastic polymer substrates is improved by the addition of bis(trimethoxysilylpropyl)fumarate and a disilanol that may or may not contain alkenyl groups. The lubricity of such compositions is improved by the addition of compounds selected from the group consisting of diorganosiloxanes such as polydimethylsiloxanes, phenyl containing siloxanes such as copolymers of diphenylsiloxane with diorganosiloxanes and copolymers of methylphenylsiloxane with diorganosiloxanes, fluorosilicones such as silicones containing trifluoropropyl substituted siloxanes, polydimethylsiloxanes, aliphatic and aromatic hydrocarbons that are liquid between 0.degree. C. and 100.degree. C.
    Type: Grant
    Filed: February 27, 1998
    Date of Patent: March 21, 2000
    Assignee: General Electric Company
    Inventors: Frank S. Burkus, II, Edward M. Jeram, Slawomir Rubinsztajn
  • Patent number: 6040359
    Abstract: A washable dry erase coloring composition comprising an acid dye or polymeric dye colorant, a dye vehicle, a release agent, and an anionic dyeblocker. The dyeblocker additive may be an aromatic organic sulfonate and, preferably, is either a sulfonated naphthalene condensation product or a sulfonated phenol-formaldehyde condensation product. The dry erase coloring composition is suitable for use in marking on a whiteboard and enhances fugitivity from skin and fabrics. The dry erase coloring composition may optionally contain a film forming resin. More specifically, the invention is, in one preferred embodiment, a washable erasable whiteboard marker ink comprising an acid dye or polymeric dye, water, a film forming resin, a release agent and an aromatic organic sulfonate. In addition, the invention also includes a method of transferring an image from a whiteboard or non-porous surface to paper.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: March 21, 2000
    Assignee: Binney & Smith Inc.
    Inventors: Andree F. Santini, Richard E. Miller
  • Patent number: 6037423
    Abstract: A polyester elastomer composition comprising a polyester block copolymer and a compound having, in one molecule, not less than two functional groups capable of reacting with a terminal group of the polyester block copolymer, and showing (A) a weight loss (volatility) at 150.degree. C., 2 hours of not more than 0.4% and (B) a gelation degree (gel fraction) at 250.degree. C., 4 hours of not more than 50%; and a polyester elastomer composition comprising a polyester block copolymer, a compound having, in one molecule, not less than two functional groups capable of reacting with a terminal group of the polyester block copolymer and a chain extender heating loss percentage satisfying the formula: (W1-W2)/W1.ltoreq.0.1, and a stabilizer comprising a tertiary amine as a part of its skeleton. From such composition, an elastomer molded product having fine mechanical strength, heat resistance and resistance to hydrolysis, which shows less volatility during heating and less gel and bleed out, can be obtained.
    Type: Grant
    Filed: September 9, 1999
    Date of Patent: March 14, 2000
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hirota Nagano, Toshio Hiramatsu, Hitoshi Ueno, Tsunehiro Ohshima
  • Patent number: 6031031
    Abstract: A thermoplastic molding composition comprisesA) from 1 to 97% by weight of a thermoplastic polyesterB) from 1 to 97% by weight of a polycarbonateC) from 1 to 40% by weight of an elastomer containing oxazoline groups and having a glass transition temperature (T.sub.g).ltoreq.0.degree. C.D) from 0.05 to 5% by weight of a bisoxazolineE) from 0 to 70% by weight of other additives and processing aids,where the total of the percentages by weight of components A) to E) is 100%.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: February 29, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Rolf Mulhaupt
  • Patent number: 6025433
    Abstract: To offer thermosetting paint compositions resistant to yellowing to brass, which give paint films of excellent resistance to yellowing due to brass, low-temperature curability, weather resistance, resistance to yellowing after stoving, acid resistance, scratch resistance, solvent resistance, adhesion and appearance. Thermosetting paint compositions, which are thermosetting paint compositions which are resistant to yellowing due to brass, characterized in that the paint-film-forming components include (A) a compound which has per molecule at least 2 functional groups which can react with an isocyanate group, at 49.6-90 wt %, (B) a blocked isocyanate which has par molecule at least 2 isocyanate groups blocked by an azole blocking agent, at 9.6-50 wt %, (C) an ultraviolet absorber and/or free radical scavenger, at 0.2-5 wt %, (D) an organotin compound at 0.1-3 wt %, and (E) an amino resin at 0.1-30 wt %.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: February 15, 2000
    Assignee: BASF Coatings AG
    Inventors: Kishio Shibatoh, Souichi Mori, Yasuhiro Monma
  • Patent number: 6015510
    Abstract: A flame retardant composition comprising coated particles, said particles having a core comprising melamine phosphate, melamine polyphosphate, melamine pyrophosphate, or mixtures thereof, said core having at least one coating comprising an organo silane, ester, polyol, dianhydride, dicarboxylic acid, melamine formaldehyde, or mixtures thereof; a polymer composition containing said flame retardant; a polymer composition containing a flame retardant comprising melamine phosphate, melamine polyphosphate, melamine pyrophosphate or mixtures thereof, and dicarboxylic acid, dianhydride, or mixtures thereof; and a process for preparation of said polymer compositions by increasing extruder throughput are disclosed.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: January 18, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Howard Wayne Jacobson, Robert Valentine Kasowski
  • Patent number: 5998515
    Abstract: The compression set of elastomeric silicone compositions, addition cured injection moldable compositions or millable compositions, is reduced by the incorporation of nitrogen compounds wherein the nitrogen possesses at least one organic substituent and the nitrogen is tetravalent wherein the nitrogen is cationic. The adhesion of such compositions to thermoset or thermoplastic polymer substrates is improved by the addition of bis(trimethoxysilylpropyl)fumarate and a disilanol that may or may not contain alkenyl groups.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: December 7, 1999
    Assignee: General Electric Company
    Inventors: Frank S. Burkus, II, Edward M. Jeram, Slawomir Rubinsztajn
  • Patent number: 5998516
    Abstract: The compression set of elastomeric silicone compositions, addition cured injection moldable compositions or millable compositions, is reduced by the incorporation of nitrogen compounds wherein the nitrogen possesses at least one organic substituent and the nitrogen is tetravalent wherein the nitrogen is cationic.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: December 7, 1999
    Assignee: General Electric Company
    Inventors: Frank S. Burkus, II, Edward M. Jeram, Slawomir Rubinsztajn
  • Patent number: 5989794
    Abstract: Disclosed is a polyalkylene naphthalate film, preferably the homopolymer of naphthalene-2,6-dicarboxylic acid and ethylene glycol (PEN), comprising a UV absorbing compound of general formula Q--CO--CO--X (explained in the description) for quenching of the UV fluorescence at 429 nm. The polymeric film is preferably used as support for a photographic material, preferably a colour negative or colour reversal photographic material.
    Type: Grant
    Filed: July 16, 1998
    Date of Patent: November 23, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventor: August Marien
  • Patent number: 5989333
    Abstract: Mixed crystal pigments of the quinacridone series New quinacridone mixed crystal pigments consisting ofa) from 85 to 99% by weight of unsubstituted .beta.-phase quinacridone of the formula (I) ##STR1## in which R.sup.1 and R.sup.2 are hydrogen atoms and b) from 1 to 15% by weight of one or more substituted quinacridones of the formula (I) in which the substituents R.sup.1 and R.sup.2 are identical or different and are chlorine, bromine or fluorine atoms or C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or carboxamido groups which can be substituted by C.sub.1 -C.sub.6 -alkyl groups, and R.sup.1 may additionally be hydrogen, are valuable quinacridones in the red-violet range.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: November 23, 1999
    Assignee: Clariant GmbH
    Inventors: Manfred Urban, Martin Boehmer, Dieter Schnaitmann
  • Patent number: 5985389
    Abstract: The present invention is a compositional blend having a polyester, an acetaldehyde reduction compound and less than 50 ppm of an optical brightener. The blend has utility for food and beverage molded containers where improved clarity and flavor retention are important without producing a haze. The acetaldehyde reduction compound can be a low molecular weight partially aromatic polyamide, a low molecular weight aliphatic polyamides or polyesteramide. The optical brightener preferably is a bis(benzoxazolyl) stilbene. Articles, and especially beverage containers, produced from the blend have a yellowness, b*, less than about 2.5.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: November 16, 1999
    Assignee: Eastman Chemical Company
    Inventors: James Samuel Nelson Dalton, Steven Lee Stafford, John David Hewa
  • Patent number: 5977220
    Abstract: A process to reduce the compression set of elastomeric silicone compositions, addition cured injection moldable compositions or millable compositions, comprises the incorporation of nitrogen compounds wherein the nitrogen possesses at least one organic substituent and the nitrogen is tetravalent wherein the nitrogen is cationic.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: November 2, 1999
    Assignee: General Electric Company
    Inventors: Frank S. Burkus, II, Edward M. Jeram, Slawomir Rubinsztajn
  • Patent number: 5965640
    Abstract: A crosslinkable acrylic rubber composition exhibiting superior balance between the storage stability and cure rate, and having only minimal risk of corroding metals or being contaminated by metals. The cured products made from the composition have excellent tensile strength, permanent compression set, and water resistance. The composition which comprises (1) a halogen-containing acrylic rubber, (2) a triazine thiol compound, (3) a dithiocarbamine acid derivative or a thiuram sulfide compound, or both, (4) a hydrotalcite compound or an organotin compound, or both, (5) an aromatic carboxylic acid compound or an acid anhydride thereof, or both, (6) a white filler with a pH of 2-10, and (7) a silane coupling agent.
    Type: Grant
    Filed: June 5, 1997
    Date of Patent: October 12, 1999
    Assignee: JSR Corporation
    Inventors: Nobutoshi Kobayashi, Minoru Tanaka
  • Patent number: 5965641
    Abstract: A description is given of a process for stabilising an organic polymer against ozone in the ambient air, which comprises adding to the polymer as stabiliser a monomeric sterically hindered piperidine compound, or an oligomeric or polymeric sterically hindered piperidine compound containing one or several triazine units, or a secondary sterically hindered piperidine compound, the piperidine compound containing in any case at least one unit of formula I ##STR1## wherein G is hydrogen or methyl, and G.sub.1 and G.sub.2 are hydrogen, methyl or, taken together, oxygen.With this process it is possible to make a more accurate prediction of the service time of the polymer and it helps to avoid unnecessarily high dosages of the stabiliser.
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: October 12, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fran.cedilla.ois Gugumus
  • Patent number: 5936048
    Abstract: There are herein disclosed a method for preparing a modified resin which comprises thermal/reaction by the use of a norbornenyl group-containing compound typified by norbornenecarboguanamine or its derivative, a method for preparing an epoxy-modified resin which comprises the step of reacting the above-mentioned modified resin and an epoxide, a flame-retarding method, a thermal stabilization method, a compatibilizing method and a surface modification method which comprise utilizing the modified resin, as well as a coating resin composition and an adhesive resin composition containing the modified resin.According to the preparation methods of the present invention, the deterioration of a material scarcely occurs, and a functional group which is excellent in flame retardancy, thermal stability, compatibility and the like can be introduced to the resins.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: August 10, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tetsuya Oishi, Kazuo Sugazaki, Jin Suzuki
  • Patent number: 5869565
    Abstract: Described are compositions protected against thermal and oxidative degradation, comprisingA) a polyether polyol or mixtures of such polyols,B) at least one benzofuranone derivative of formula I ##STR1## wherein either two of R.sub.1, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are each independently of the other C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, the others being hydrogen,orR.sub.7 to R.sub.10 are hydrogen, or at most two of these radicals are each independently of the other methyl or methoxy, and R.sub.1 is --O--CHR.sub.3 --CHR.sub.5 --O--CO--R.sub.6,R.sub.2 and R.sub.4 are each independently of the other hydrogen or C.sub.1 -C.sub.6 alkyl,R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sub.5 is hydrogen, phenyl or C.sub.1 -C.sub.6 alkyl, andR.sub.6 is C.sub.1 -C.sub.4 alkyl,C) at least one compound from group of the phenolic antioxidants, and/orD) at least one compound from group of the amino antioxidants of the secondary amine type.
    Type: Grant
    Filed: May 6, 1996
    Date of Patent: February 9, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Margot Clauss
  • Patent number: 5863465
    Abstract: Emulsion-polymerization of electrically conductive polyaniline salts is disclosed. The process comprises combining water, a water-solubilizing organic solvent, an organic acid that is soluble in the organic solvent, an aniline monomer, and a radical initiator. An organic phase forms which contains the polyaniline salt of the organic acid wherein the organic phase is separable from an aqueous phase. The polyaniline salt so formed is soluble in organic carrier solvents at a concentration of 25 w/w % or greater.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: January 26, 1999
    Assignee: Monsanto Company
    Inventor: Patrick J. Kinlen
  • Patent number: 5859164
    Abstract: Uretdione-functional polyaddition compounds of the formula: ##STR1## where: ##STR2## R.sup.1 is R or linear, branched or cyclic alkylene radicals of 2-16 carbon atoms,R.sup.2 and R.sup.3 are identical or different hydrocarbon radicals of 1-14 carbon atoms,R.sup.4 is R.sup.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: January 12, 1999
    Assignee: Huels Aktiengesellschaft
    Inventors: Rainer Gras, Joern Volker Weiss, Elmar Wolf, Felix Schmitt
  • Patent number: 5856012
    Abstract: The invention relates to a process for the production of multilayer plastic sheets from special branched polycarbonates.
    Type: Grant
    Filed: August 11, 1995
    Date of Patent: January 5, 1999
    Assignee: Bayer AG
    Inventors: Steffen Kuhling, Hartmut Lower, Siegfried Anders, Jurgen Kirsch, Werner Verhoeven
  • Patent number: 5847033
    Abstract: This invention provides an adhesive for bonding a rubber and a glass product, having excellent degradation resistance and high tackiness. This adhesive comprises (1) a hydrogenated nitrile-butadiene rubber latex, (2) a resorcin-formaldehyde resin and (3) an ethyleneurea compound expressed by the following general formula: ##STR1## where R is a hydrocarbon group.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: December 8, 1998
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Yuji Kageyama
  • Patent number: 5847067
    Abstract: Urea- and uretdione-functional polyisocyanates having the following formula (I): ##STR1## where ##STR2## n is an integer of from 1 to 20; R.sup.1, R.sup.3 =not more than one linear or branched (cyclo)alkyl radical having 1-14 carbon atoms or H and at least one of the formula: ##STR3## R.sup.2 =R, linear or branched (cyclo)alkyl radical having 6 carbon atoms; R.sup.4, R.sup.5 =identical or different hydrocarbon radicals having 1 to 14 carbon atoms.
    Type: Grant
    Filed: September 11, 1997
    Date of Patent: December 8, 1998
    Assignee: Huels Aktiengesellschaft
    Inventor: Rainer Gras
  • Patent number: 5847032
    Abstract: An aryletherketone copolymer having repeating units of the formula: ##STR1## wherein the ratio m:n is in the range of 1:99 to 99:1; wherein Ar is selected from the group consisting of: ##STR2## and wherein Ar' is selected from the group consisting of ##STR3## wherein Q is --O--, --CH.sub.2 -- or --CO--, is useful in the dispersion of active NLO chromophores containing a basic functionality to form optically clear films.
    Type: Grant
    Filed: May 8, 1997
    Date of Patent: December 8, 1998
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Narayanan Venkatasubramanian
  • Patent number: 5814689
    Abstract: The present invention relates to the preparation and use of novel polyurethane polyuretidione crosslinking agents in solvent and water borne coatings systems. These polyuretidione polyurethanes are characterized by their relatively low solution viscosity, and the ability to provide a relatively high crosslink density in the final, cured film, and thereby, coatings with the excellent physical properties and resistance to chemical and environmental exposure of known polyurethane systems without the potential for worker exposure to toxic isocyanates. This invention also relates to a process for the production of these polyuretidiones and their use in pseudo-one and two component coating compositions.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: September 29, 1998
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Stephen L. Goldstein, James M. O'Connor, Donald L. Lickei, Henry G. Barnowski, Jr., Willard F. Burt, Ronald S. Blackwell
  • Patent number: 5814690
    Abstract: A thermoplastic molding composition comprising poly(butylene terephthalate), a reinforcing component, and a mixed flame retardant containing melamine pyrophosphate and an aromatic phosphate oligomer in selected proportions exhibits improved flame resistance, relatively low melt viscosity for good melt processability, and good physical properties, particularly tensile strength and tensile elongation.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: September 29, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Robert Earl Penn
  • Patent number: 5773491
    Abstract: The object of the present invention is polycarbonate molding compositions containing polycarbonates, stabilizers of the general formula (I)R.sub.1 --X--CZ--Y--R.sub.2and optionally polypropylene glycols. The object of the present invention is also use of these molding compositions to produce items for medical applications.
    Type: Grant
    Filed: March 7, 1996
    Date of Patent: June 30, 1998
    Assignee: Bayer AG
    Inventors: Wolfgang Ebert, Ralf Hufen, Ru digerart, Gerhard Fennhoff
  • Patent number: 5770653
    Abstract: A resin composition includes a dicyclopentenyl-group containing unsaturated polyester resin, a phenothiazine derivative (a) and an anion producing compound (b). On the other hand, resin composition includes a thermosetting resin, a phenothiazine derivative (a), an anion producing compound (b) and a phosphorous ester (c). A manufacturing method of resin composition includes the step of obtaining a dicyclopentenyl-group-containing unsaturated polyester by polycondensing unsaturated polyester material including a compound having a dicyclopentenyl group, and the step of mixing a cross-linking monomer with the obtained dicyclopentenyl-group-containing unsaturated polyester, wherein the phenothiazine (a) and the anion producing compound (b) are added in at least one of those steps.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: June 23, 1998
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kenji Matsukawa, Toshio Hayashiya, Daisaku Yamamoto
  • Patent number: 5736070
    Abstract: The invention relates to an electroconductive coating composition with excellent conductivity, adhesion to copper foil and solder dip resistance which is suitable for the formation of a jumper circuit and an electromagnetic shield layer, a printed circuit board fabricated with the above composition, and a durable electromagnetic-shielded flexible printed circuit assembly, wherein said coating composition comprises, by weight, 100 parts of copper metal powder coated with 0.05-0.2 parts of titanate or/and zirconate, 5-30 parts of resole phenolic resin, 0.5-4 parts of a chelating agent, 0.1-5 parts of an adhesion improving agent and 0.5-7 parts of a conductivity improving agent. This composition is less expensive than the silver paste, superior to the latter in the conductivity and adhesion to copper foil of the coating film and in solder dip resistance, thus being suited for the construction of a jumper circuit and an electromagnetic shield layer. It lends itself well to the mounting of IC, MSI, LSI, etc.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: April 7, 1998
    Assignee: Tatsuta Electric Wire and Cable Co., Ltd.
    Inventors: Hisatoshi Murakami, Shinichi Wakita, Tsunehiko Terada, Shohei Morimoto
  • Patent number: 5712362
    Abstract: The invention relates to a process for the production of UV-stable polycarbonates, to the polycarbonates obtainable in accordance with the invention and to their use for the production of sheets, more particularly plastic panels.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: January 27, 1998
    Assignee: Bayer AG
    Inventors: Thomas Scholl, Peter Bier
  • Patent number: 5708065
    Abstract: This invention relates to flame retardants for polyester and polyamide compositions, and specifically relates to compositions containing (1) about 30 to about 70 weight percent of a polyester or a synthetic, aliphatic polyamide or a mixture thereof; (2) about 15 to about 40 weight percent of glass or mineral reinforcing agent; and (3) a flame retardant of (a) about 20 to about 30 weight percent of melamine phosphate and up to about 10 weight percent of a charring catalyst; (b) about 15 to about 30 weight percent of melamine phosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former; (c) about 5 to about 45 weight percent of melamine pyrophosphate; (d) about 15 to about 30 weight percent of melamine pyrophosphate and up to about 10 weight percent of a charring catalyst; (e) about 15 to about 30 weight percent of melamine pyrophosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former, or (f) about 20
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: January 13, 1998
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Marvin Michel Martens, Robert Valentine Kasowski, Kevin Bodle Cosstick, Robert Earl Penn
  • Patent number: 5686540
    Abstract: The present invention provides a process for the preparation of a biodegradable lactic acid-based polyester composition excellent in thermal stability, storage stability, flexibility, heat resistance, mechanical and physical properties and moldability which comprises kneading a lactic acid-based polyester and a polyester consisting of dicarboxylic acid component(s) and diol component(s) with a chelating agent, an acidic phosphoric acid ester, a molecular weight increasing agent, etc., and then devolatizing the kneaded mixture. The present invention also provides a molding process of the foregoing lactic acid-based polyester composition.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: November 11, 1997
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventor: Yasutoshi Kakizawa
  • Patent number: 5621052
    Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-triazines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: April 15, 1997
    Assignee: Cytec Technology Corp.
    Inventors: Jeno G. Szita, Paul S. Waterman
  • Patent number: 5618865
    Abstract: This invention relates to flame retardants for polyester and polyamide compositions, and specifically relates to compositions containing (1) about 30 to about 70 weight percent of a polyester or a synthetic, aliphatic polyamide; (2) about 15 to about 40 weight percent of glass or mineral reinforcing agent; and (3) a flame retardant of (a) about 20 to about 30 weight percent of melamine phosphate and up to about 10 weight percent of a charring catalyst; (b) about 15 to about 30 weight percent of melamine phosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former; (c) about 25 to about 30 weight percent of melamine pyrophosphate; (d) about 15 to about 30 weight percent of melamine pyrophosphate and up to about 10 weight percent of a charring catalyst; or (e) about 15 to about 30 weight percent of melamine pyrophosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former, wherein all percents by weight ar
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: April 8, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Marvin M. Martens, Robert V. Kasowski
  • Patent number: 5567356
    Abstract: Electrically-conductive polyaniline salts that are soluble in xylene and an emulsion-polymerization process for producing the salts is disclosed. The process comprises the steps of combining water, a water soluble organic solvent, a hydrophobic organic acid, an aniline monomer, and a radical initiator and allowing the mixture to form the electrically-conductive polyaniline salt of the acid.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: October 22, 1996
    Assignee: Monsanto Company
    Inventor: Patrick J. Kinlen