Solid Polymer From Ethylenic Reactants Only Is Derived From Unsaturated Hydrocarbon Patents (Class 525/106)
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Patent number: 11377561Abstract: An alkenyl-functional polydiorganosiloxane is useful in a composition and a method for preparing a wood plastic composite article. The wood plastic composite article is useful as a building material. The polydiorganosiloxane may be added in liquid form to a composition, or may form part of a solid carrier component, used to make the wood plastic composite article.Type: GrantFiled: June 10, 2020Date of Patent: July 5, 2022Assignee: Dow Silicones CorporationInventors: Igor Chorvath, Marc-Andre Courtemanche, James Keenihan, Keith Bruce, Sean Gaal, Jodi Mecca
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Patent number: 11319425Abstract: The process of curing a silane-functionalized ethylenic polymer using a tin-based catalyst, e.g., dibutyltin dilaurate, is accelerated by the addition of a titanium (IV) oxide.Type: GrantFiled: September 25, 2018Date of Patent: May 3, 2022Assignee: Dow Global Technologies LLCInventors: Manish K. Mundra, Jeffrey M. Cogen, Marcio Teixeira Alves, Robert E. Scheid, Jr., Caroline M. Grand
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Patent number: 11078335Abstract: A method for preparing a graft copolymer having a polyolefin backbone and polyorganosiloxane pendant groups can be catalyzed by a Lewis Acid catalyst, Piers-Rubenstzjan catalyst, or hydrosilylation reaction catalyst. The graft copolymer prepared by the method is useful as a thermoplastic elastomer or as a compatibilizer in compositions containing both a polyolefin and a polyorganosiloxane.Type: GrantFiled: July 18, 2018Date of Patent: August 3, 2021Assignee: Dow Silicones CorporationInventors: Steven Swier, Zachary Kean, John B. Horstman
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Patent number: 10717829Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).Type: GrantFiled: May 1, 2019Date of Patent: July 21, 2020Assignee: Arkema Inc.Inventors: Leonard H. Palys, Peter R. Dluzneski, William P. Pavlek, Alfredo Defrancisci, Feng-Jon Chang, Marina Despotopoulou, Michael B. Abrams, Joseph M. Brennan, Isabelle Tartarin
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Patent number: 10441947Abstract: Novel, lubricious coatings for medical devices are disclosed. The coatings provide improved lubricity and durability, and are readily applied in coating processes. The present invention is also directed to a novel platinum catalyst for use in such coatings. The catalyst provides for rapid curing, while inhibiting cross-linking at ambient temperatures, thereby improving the production pot life of the coatings.Type: GrantFiled: August 9, 2016Date of Patent: October 15, 2019Assignee: Ethicon, Inc.Inventor: Duan Li Ou
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Patent number: 10316154Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).Type: GrantFiled: December 3, 2015Date of Patent: June 11, 2019Assignee: Arkema Inc.Inventors: Leonard H. Palys, Peter R. Dluzneski, William P. Pavlek, Alfredo Defrancisci, Feng-Jon Chang, Marina Despotopoulou, Michael B. Abrams, Joseph M. Brennan, Isabelle Tartarin
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Patent number: 9868650Abstract: A method for removing glyphosate from a solution by contacting the solution with a polymeric particle including a moiety selected from the group consisting of ammonium, amine and combinations thereof, wherein the moiety is positively charged in the solution.Type: GrantFiled: December 21, 2015Date of Patent: January 16, 2018Assignee: International Business Machines CorporationInventors: Robert D. Allen, Geraud J. Dubois, Young-Hye Na, Lianna C. Samuel, Joseph Sly, Ran Wang
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Patent number: 9796822Abstract: The present invention relates to an optical film that comprises a block copolymer that comprises a vinyl polymer block containing styrene or a derivative thereof, and a poly-dimethylsiloxane block, a retardation film using the same, a method of manufacturing them, and a liquid crystal display comprising the films.Type: GrantFiled: April 14, 2008Date of Patent: October 24, 2017Assignee: LG CHEM, LTD.Inventors: Hee-Jung Kim, Dong-Ryul Kim, Young-Whan Park, Dae-Woo Nam, Boong-Goon Jeong
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Patent number: 9644089Abstract: A process for crosslinking an elastomer composition in the presence of an organic peroxide formulation is disclosed. The organic peroxide formulation may comprise additional compounds chosen from bis-, tri- and higher poly-maleimides, bis-, tri- and higher poly-citraconimides, peroxide-crosslinkable silicone elastomers, p-phenylenediamine based antiozonants, sulfur containing organic compounds which are accelerators for the sulfur curing (crosslinking) of polymers which are curable/crosslinkable by sulfur, and polysulfide polymers. Methods of manufacturing elastomer articles, methods of reducing mold-fouling, elastomer compositions, and elastomer articles made from the elastomer compositions are also disclosed.Type: GrantFiled: February 28, 2014Date of Patent: May 9, 2017Assignee: Arkema Inc.Inventors: Wayne Ranbom, Leonard H. Palys
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Patent number: 9631089Abstract: A thermoplastic polyurethane composite material composition includes a plastic base material and a curing agent, the plastic base material includes a thermoplastic polyurethane and a silicone gum including at least two alkenyl groups in each of molecules thereof, wherein the thermoplastic polyurethane and the silicone gum are uniformly mixed, and a weight ratio of the thermoplastic polyurethane and the silicone gum is ranging from 95.01:4.99 to 99.5:0.5. The curing agent is uniformly mixed with the plastic base material, wherein the curing agent has an adding amount enabling the silicone gum to crosslink to form a silicone rubber.Type: GrantFiled: January 7, 2016Date of Patent: April 25, 2017Assignee: EVERMORE CHEMICAL INDUSTRY CO., LTD.Inventors: Wei-Ho Ting, Pin-Jung Chen, Charles Huang, Shih-Chieh Wang
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Patent number: 9574052Abstract: A method of forming particles that includes performing a strong force attenuation of a mixture to form pre-particles. The mixture including a base compound and a dielectric additive having an elevated dielectric constant dispersed therein. The pre-particles are then dielectrically spun in an electrostatic field to further attenuate the pre-particles and form the particles.Type: GrantFiled: September 25, 2015Date of Patent: February 21, 2017Assignee: Gabae Technologies, LLCInventors: Evan Koslow, Jocelyn Tindale, Ryan Gerakopulos, Chitral Angammana, Tatiana Lazareva
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Patent number: 9365671Abstract: Provided are a styrene-based copolymer prepared from a mixture including (A) an aromatic vinyl-based compound, (B) an unsaturated nitrile-based compound, and (C) a silicone-based compound having two or more unsaturated reactive groups to thereby be capable of implementing a uniform and excellent low gloss property with minimal or no deterioration of physical properties such as impact resistance, heat resistance, and the like, and a thermoplastic resin composition including the same.Type: GrantFiled: December 2, 2014Date of Patent: June 14, 2016Assignee: Samsung SDI Co., Ltd.Inventors: Bo Eun Kim, Joo Hyun Jang, Jae Won Heo, Kwang Soo Park, Natarajan Senthilkumar, Il Jin Kim, Jun Sung Oh
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Patent number: 9353229Abstract: A method of forming particles that includes performing a strong force attenuation of a mixture to form pre-particles. The mixture including a base compound and a dielectric additive having an elevated dielectric constant dispersed therein. The pre-particles are then dielectrically spun in an electrostatic field to further attenuate the pre-particles and form the particles.Type: GrantFiled: August 14, 2013Date of Patent: May 31, 2016Assignee: GABAE Technologies LLCInventors: Evan Koslow, Jocelyn Tindale, Ryan Gerakopoulos, Chitral Angammana, Tatiana Lazareva
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Patent number: 9163332Abstract: A method of forming particles that includes performing a strong force attenuation of a mixture to form pre-particles. The mixture including a base compound and a dielectric additive having an elevated dielectric constant dispersed therein. The pre-particles are then dielectrically spun in an electrostatic field to further attenuate the pre-particles and form the particles.Type: GrantFiled: August 14, 2013Date of Patent: October 20, 2015Assignee: Gabae Technologies LLCInventors: Evan Koslow, Jocelyn Tindale, Ryan Gerakopoulos, Chitral Angammana, Tatiana Lazareva
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Patent number: 9039174Abstract: The present application relates to novel monomers comprising polycarbosiloxane monomers useful in certain specific embodiments in the manufacture of devices. More particularly, the present application relates to certain ethylenically unsaturated free radical polymerizable monomers comprising polycarbosiloxane monomers. Even more particularly, the present application pertains to monomers comprising polycarbosiloxane monomers which further comprise at least two ethylenically unsaturated free radical polymerizable groups.Type: GrantFiled: March 15, 2013Date of Patent: May 26, 2015Assignee: Bausch & Lomb IncorporatedInventors: Alok Kumar Awasthi, Jay F. Kunzler
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Publication number: 20150104598Abstract: A thermoplastic composition comprising from about 50 to about 99 by weight percent of a nylon 6,6 resin, from about 1 to about 50 by weight percent of a polymer performance modifier and about from 0.01 to about 25 by weight percent of a silicone based additive, wherein the silicone based additive comprises an ultrahigh molecular weight siloxane polymer that is unfunctionalized and non-reactive with the polyamide resin, wherein the thermoplastic composition has an impact strength value which is greater than the combination of the polyamide resin and the polymer performance modifier or the combination of the polyamide resin and the silicone based additive and wherein the thermoplastic composition has an ultimate tensile strength that is at least 80% that of the combination of the polyamide resin and the polymer performance modifier.Type: ApplicationFiled: December 19, 2014Publication date: April 16, 2015Applicant: INVISTA North America S.a.r.l.Inventor: Rajeev S. BHATIA
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Patent number: 8987379Abstract: A polycarbonate resin composition includes: (A) an aromatic polycarbonate in an amount of about 5 to about 95% by weight, (B) a siloxane-based polycarbonate in an amount of about 5 to about 90% by weight, and (C) a syndiotactic polystyrene in an amount of 0 to about 5% by weight. The polycarbonate resin composition can have excellent flowability, injection moldability, impact strength, chemical resistance, and transparency.Type: GrantFiled: June 30, 2013Date of Patent: March 24, 2015Assignee: Cheil Industries Inc.Inventors: Gi Ho Ahn, Tae Uk Kim, Jung Ki Kim
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Publication number: 20150037596Abstract: An adhesive sheet comprising a hot-melt adhesive layer. The hot-melt type adhesive layer comprises a modified polymer (A) to which a cross-linkable group is bonded and a polyolefin (B). The adhesive sheet can adhere to various adherends and the adhesive becomes less likely to squeeze out from an adherend in thermal fusion bonding and sealing of the adherend. In a laminate comprising the adhesive sheet the adhesive layer does not squeeze out from the adherend without being affected by the material of the adherend.Type: ApplicationFiled: October 22, 2014Publication date: February 5, 2015Inventors: Ai Takamori, Kenji Matsuda, Itsuro Tomatsu
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Publication number: 20150031798Abstract: A composite material is disclosed for use in a high-voltage device having a high-voltage electrical conductor, the material containing a polymeric matrix and at least one fiber embedded in the polymeric matrix, the fibers having an average diameter of less than about 500 nm.Type: ApplicationFiled: August 18, 2014Publication date: January 29, 2015Inventors: Jens ROCKS, Walter Odermatt
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Publication number: 20150025197Abstract: A process for preparing a reinforced and reactive thermoplastic composition having a continuous phase based on a thermoplastic polymer and dispersed therein is a discontinuous phase based on a reactive reinforcing agent that may be immiscible with the thermoplastic polymer is provided. A composition obtained by this process is also provided. The reinforcing agent is selected from the group consisting of epoxy resins, polyorganosiloxanes having SiH functional group(s), diisocyanates or polyisocyanates and mixtures thereof, comprises a grafting, a branching and/or a crosslinking, that are carried out in situ, by reactive compounding of these phases with a shear rate greater than 102 s?1, of the reinforcing agent onto the chain of the thermoplastic polymer, so that the discontinuous phase is dispersed homogeneously in the continuous phase in the form of nodules having a number-average size of less than 5 ?m.Type: ApplicationFiled: April 4, 2014Publication date: January 22, 2015Applicant: HutchinsonInventors: Nicolas Garois, Philippe Sonntag, Gregory Martin, Matthieu Vatan, Jacques Drouvroy
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Publication number: 20150018477Abstract: A polycarbonate resin composition for a vehicle exterior may include a polycarbonate resin, a silicone polycarbonate, and a syndiotactic polystyrene. The polycarbonate resin may be 45˜85% by weight, the silicone polycarbonate may 10˜50% by weight, and the syndiotactic polystyrene may be greater than 2% by weight and less than 7% by weight, with respect to a total weight of the composition. The polycarbonate resin composition may further include other additives such as a black pigment. The polycarbonate resin composition provides improved physical and/or chemical properties.Type: ApplicationFiled: December 19, 2013Publication date: January 15, 2015Applicants: Cheil Industries Inc., Hyundai Motor CompanyInventors: Hee-Joon LEE, Sang-Sun Park, Jun-Ho Chi, Hyun-Jung Cho, Jong-Chan Hur
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Patent number: 8933185Abstract: An acrylic resin that can have excellent transparency, flowability and scratch-resistance property is prepared by polymerizing a monomer mixture comprising about 10 to about 25% by weight of (meth)acrylic acid alkyl ester monomer, about 50 to about 80% by weight of aromatic vinyl compound, and about 10 to about 25% by weight of vinyl cyanide compound.Type: GrantFiled: June 27, 2012Date of Patent: January 13, 2015Assignee: Cheil Industries Inc.Inventors: Don Keun Lee, Yu Ho Kim
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Publication number: 20140364567Abstract: The present disclosure relates to high molecular weight polystyrene-polydialkylsiloxane-polystyrene (“SDS”) triblock copolymer compositions and methods of separating one or more organic compounds from an aqueous solution using membranes derived from SDS triblock copolymers. The methods may be used to separate the one or more organic compounds from an aqueous solution produced in a fermentation process. In some embodiments, the one or more organic compounds include an alcohol, such as, for example, ethanol. In other embodiments, the one or more organic compounds include acetone. In other embodiments, the one or more organic compounds include acetone, ethanol, and n-butanol produced in an acetone-ethanol-n-butanol (ABE) fermentation process. In other embodiments, the one or more organic compounds include one or more byproducts produced in a fermentation process.Type: ApplicationFiled: November 9, 2012Publication date: December 11, 2014Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Nitash P. Balsara, Ali Evren Ozcam, Ashish K. Jha
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Patent number: 8871858Abstract: A thermoplastic composition comprising from 30 to 93 wt. % of an aromatic polycarbonate, from 0.5 to 20 wt. % of an impact modifier, from 0 to 25 wt. % of an aromatic vinyl copolymer, from 6 to 35 wt. % of a mineral filler, and from 0.01 to 4 wt. % of an organo-hydrosiloxane or a copolymer comprising an organo-hydrosiloxane and a polysiloxane, based on the total weight of the composition, has been found to exhibit improved mechanical properties and other characteristics and less degradation than filled thermoplastic compositions without the organo-hydrosiloxane. The composition optionally comprises an acid or acid salt. An article may be formed by molding, extruding, shaping or forming such a composition to form the article.Type: GrantFiled: May 31, 2006Date of Patent: October 28, 2014Assignee: Sabic Global Technologies B.V.Inventors: Andries Adriaan Volkers, Lydie Belot
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Publication number: 20140303270Abstract: A composite material which is elastic, which exhibits a resistive load under deformation which increases with the rate of deformation, which is unfoamed or foamed, comminuted or uncomminuted and which comprises i) a first polymer-based elastic material and ii) a second polymer-based material, different from i), which exhibits dilatancy in the absence of i) wherein ii) is entrapped in a solid matrix of i), the composite material being unfoamed or, when foamed, preparable by incorporating ii) with i) prior to foaming.Type: ApplicationFiled: June 20, 2014Publication date: October 9, 2014Inventors: Philip Charles Green, Richard Martin Palmer
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Publication number: 20140288236Abstract: The invention relates to silicone resins comprising metallosiloxane which contains for example Si—O-Aluminium bonds. It also relates to their use in thermoplastics, thermosettings organic polymers or any blends of the laters or rubbers or thermoplastic/rubbers blends compositions to reduce the flammability or to enhance scratch and/or abrasion resistance of the organic polymer compositions. It further relates to coatings containing such silicone resins for scratch and/or abrasion resistance enhancement or flame retardant properties.Type: ApplicationFiled: November 14, 2012Publication date: September 25, 2014Inventors: Michael Depierro, David Pierre, Vincent Rerat, Nanguo Liu, Gerald Witucki
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Patent number: 8840996Abstract: A process for making a silica-polyolefin composite. The process has the steps of (a) reacting silica particles and an alkyl halosilane in the presence of a solvent and a catalyst to form silane-functionalized silica particles and (b) reacting the silane-functionalized silica particles with a vinyl-terminated polyolefin. There are other processes for making a silica-polyolefin composites. There are other processes for making metal phosphate-polyolefin composites.Type: GrantFiled: December 19, 2011Date of Patent: September 23, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Andy Haishung Tsou, Shuji Luo, Donna Jean Crowther, Victor DeFlorio
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Publication number: 20140221544Abstract: A method of using metallized and nonmetallized nanostructured chemicals as surface and volume modification agents within polymers and on the surfaces of nano and macroscopic particulates and fillers. Because of their 0.5 nm-3.0 nm size, nanostructured chemicals can be utilized to greatly increase surface area, improve compatibility, and promote lubricity between surfaces at a length scale not previously attainable.Type: ApplicationFiled: March 25, 2014Publication date: August 7, 2014Applicant: Hybrid Plastics, Inc.Inventors: Joseph D. Lichtenhan, Xuan Fu, Marion R. Blue, Paul Wheeler, Rahul Misra, Sarah Morgan
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Patent number: 8784711Abstract: The invention relates to a process for preparing a reinforced and reactive thermoplastic composition having a continuous phase which is based on at least one thermoplastic polymer and dispersed in which is a discontinuous phase based on at least one reactive reinforcing agent that may be immiscible with said at least one thermoplastic polymer, and also to a composition obtained by this process.Type: GrantFiled: August 2, 2011Date of Patent: July 22, 2014Assignee: HutchinsonInventors: Nicolas Garois, Philippe Sonntag, Grégory Martin, Matthieu Vatan, Jacques Drouvroy
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Patent number: 8735494Abstract: A method for preparing a polydiene polymer, the method comprising: (i) preparing an active polymerization mixture by introducing conjugated diene monomer, and optionally monomer copolymerizable therewith, and a lanthanide-based catalyst system; (ii) adding a nitrile compound containing a protected amino group to the active polymerization mixture; and (iii) adding a co-functionalizing agent to the active polymerization mixture.Type: GrantFiled: November 27, 2012Date of Patent: May 27, 2014Assignee: Bridgestone CorporationInventors: Steven Luo, Eiju Suzuki, Dennis R. Brumbaugh
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Publication number: 20140113988Abstract: To provide a resin composite material in which aggregation of silane compounds in the resin is suppressed and the linear expansion coefficient is lowered, and a method for producing the resin composite material. A resin composite material containing a resin and a silane compound 12 having a structure of the formula (1), wherein a molecular chain of the resin and a molecular chain of the silane compound 12 form an IPN structure or a semi-IPN structure, and a method for producing a resin composite material including a step of mixing a resin and a silane compound 12a to obtain a resin composition and an IPN structure formation step of allowing a plurality of the silane compounds 12a contained in the resin composition to be condensed with each other. Each of Rs in the formula (1) is independently selected from the group consisting of hydrogen, halogen and an arbitrary organic functional group and at least one thereof is a reactive organic functional group. x represents 1 or 1.5.Type: ApplicationFiled: January 8, 2013Publication date: April 24, 2014Applicant: SEKISUI CHEMICAL CO., LTD.Inventors: Daisuke Mukohata, Nobuhiko Inui
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Patent number: 8703891Abstract: A contact lens formed of a composition comprising the reaction product of: A) at least 10 weight percent, based on the total composition weight excluding solvent, of at least one silicone-containing monomer of the formula I: where n is from 1 to 3, m is from 9 to 15, each a independently is C1-4 alkyl, and each b independently is C1-4 alkyl; B) at least 10 weight percent, based on the total composition weight excluding solvent, of 3-methacryloxypropyl tris(trimethylsiloxy)silane; C) N-vinyl pyrrolidone; and D) at least one other non-ionic hydrophilic monomer wherein the combined amount of A) and B) is at least 20 weight percent based on the total composition weight excluding solvent, and wherein the N-vinyl pyrrolidone (NVP) is present in such an amount that the reaction product comprises polyvinyl pyrrolidone (PVP) homopolymer.Type: GrantFiled: September 24, 2012Date of Patent: April 22, 2014Assignee: Sauflon CL LimitedInventor: Robert Andrew Broad
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Patent number: 8703875Abstract: The invention relates to novel crosslinkable copolymers which are obtainable by (a) copolymerizing at least two different hydrophilic monomers selected from the group consisting of N,N-dimethyl acrylamide (DMA), 2-hydroxyethyl acrylate (HEA), glycidyl methacrylate (GMA), N-vinylpyrrolidone (NVP), acrylic acid (AA) and a C1-C4-alkoxy polyethylene glycol(meth)acrylate having a weight average molecular weight of from 200 to 1500, and at least one crosslinker comprising two or more ethylenically unsaturated double bonds in the presence of a chain transfer agent having a functional group; and (b) reacting one or more functional groups of the resulting copolymer with an organic compound having an ethylenically unsaturated group.Type: GrantFiled: February 27, 2013Date of Patent: April 22, 2014Assignee: Novartis AGInventors: Frank Chang, Norberto Arturo Medina
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Patent number: 8658738Abstract: A curable resin composition, comprising 100 parts by mass of a (meth)acrylic polymer (A) having, at a terminal thereof, at least one crosslinkable silyl group; 0.1 to 100 parts by mass of a diamine compound (B) having a monovalent or bivalent aliphatic or alicyclic hydrocarbon group that has 8 or more carbon atoms and may be branched and having at least one primary amino group; and 0.1 to 100 parts by mass of a diamine compound (C) having a monovalent aliphatic or alicyclic hydrocarbon group that has 8 or more carbon atoms and may be branched, and having a crosslinkable silyl group and/or a (meth)acryloyl group.Type: GrantFiled: June 24, 2009Date of Patent: February 25, 2014Assignee: Kaneka CorporationInventors: Jun Kotani, Nobuyuki Kobayashi, Hiroyuki Hosoda, Kazunori Ishikawa
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Patent number: 8637605Abstract: A moisture curable composition that includes a silage functional polyolefin, a first thermoplastic polymer that includes a thermoplastic elastomer selected from the group consisting of block copolymer selected from the group consisting of styrene-ethylene-butylene-styrene block copolymer, styrene-ethylene-propylene-styrene block copolymer, and combinations thereof, the block copolymer including no greater than 30 mole % styrene, saturated ethylene alphaolefin copolymer, butyl rubber, and combinations thereof, and polybutene having a number average molecular weight less than 5000, the composition being clear and resistant to ultraviolet light.Type: GrantFiled: October 19, 2010Date of Patent: January 28, 2014Assignee: H.B. Fuller CompanyInventors: Claudia Mosanu, Nathanael Hill
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Publication number: 20140018463Abstract: A surface-modified polymer is described, comprising a polymeric material and a self-assembling monolayer covalently bound thereto. The monolayer comprises monoethylene glycolated-OH (MEG-OH); 2-(3-trichlorosilyl-propyloxy)-ethyl-trifluoroacetate (7-OEG or MEG-TFA); 2,2,2-trifluoroethyl-13-trichlorosilyl-tridecanoate (TTTA); OEGylated TTTA (OEG-TTTA); S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl)-benzenethiosulfonate (OEG-TUBTS); or a combination thereof. Methods are described for forming a surface-modified polymer by surface activation, such as with plasma. By utilizing the surface-modified polymer to make medical equipment or devices for contacting biological fluids, a reduction in surface fouling and thrombus formation can result. Advantageously, polymeric equipment or components so modified may have a reduction in unwanted chemical interactions leading to fouling or clotting.Type: ApplicationFiled: July 4, 2013Publication date: January 16, 2014Applicant: ECONOUS SYSTEMS INC.Inventors: Michael THOMPSON, Sonia SHEIKH, Jack Chih-Chieh SHENG, Christophe BLASZYKOWSKI, Kiril FEDOROV
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Patent number: 8603599Abstract: There are provided, according to the present invention, a resin composition for hollow blow-molded article which is obtained in a high productivity on an industrial scale with excellent moldability and drawdown resistance, and the production method thereof, by melting and mixing a polyarylene sulfide resin including a terminal carboxyl group within the resin in an amount of 25 to 45 (?mol/g), and having a non-Newtonian index of 0.90 to 1.15 and also a melt viscosity as measured at 300° C. within the range of 1,000 poise to 3,000 poise and an epoxy group-containing polyolefin so that the proportion of the epoxy group-containing polyolefin is 5 to 30 parts by mass with respect to 100 parts by mass of the polyarylene sulfide resin; and a hollow blow-molded article with excellent mechanical strength, such as the heat resistance and impact resistance, and surface appearance, and the production method thereof.Type: GrantFiled: May 24, 2011Date of Patent: December 10, 2013Assignee: DIC CorporationInventors: Shingo Matsuo, Toshio Hinokimori
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Patent number: 8598273Abstract: Polymer electrolytes offer increased safety and stability as compared to liquid electrolytes, yet there are a number of new challenges that polymer electrolytes introduce. A polymer electrolyte, as disclosed herein, is a block copolymer that has a block that provides mechanical strength and a novel, ionically-conductive polymer block with a backbone that is both highly flexible and highly conductive with high conductivity pendant chains attached, thus increasing the concentration of lithium coordination sites and improving ionic conductivity. Previous strategies for comb-type conductive polymers have focused on attaching either conductive pendant chains to a flexible non-conductive backbone or conductive pendant groups to a marginally flexible conductive backbone.Type: GrantFiled: February 26, 2010Date of Patent: December 3, 2013Assignee: Seeo, Inc.Inventors: Hany Basam Eitouni, Bing R. Hsieh
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Patent number: 8569417Abstract: The invention relates to a process for grafting hydrolysable silane groups to a polyolefin in which ethylene units, if present, form less than 50% by weight of the total polyolefin. The polyolefin is reacted with an unsaturated silane, having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polyolefin. The unsaturated silane has the formula R?—CH?CH—Z (I) or R?—C?C—Z (II) in which Z represents an electron-withdrawing moiety substituted by a —SiRaR?(3-a) group wherein R represents a hydrolysable group; R? represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; and R? represents hydrogen or a group having an electron withdrawing or any other activation effect with respect to the —CH?CH— or —C?C— bond.Type: GrantFiled: July 2, 2009Date of Patent: October 29, 2013Assignee: Dow Corning CorporationInventors: Michael Backer, Francois De Buyl, Valerie Smits, Damien Deheunynck
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Patent number: 8535770Abstract: A pearlescent container comprising about 86% to about 99.99% of a thermoplastic material having a Total Luminous Transmittance value of at least about 80%, about 0.01% to about 5% of a siloxane fluid having a viscosity of no greater than about 1,000,000 cst, wherein said thermoplastic material and said siloxane fluid are immiscible, forms a lamellar structure, and have a Refractive Index difference of at least about 0.1.Type: GrantFiled: November 8, 2012Date of Patent: September 17, 2013Assignee: The Procter & Gamble CompanyInventors: Ping Wang, Liang Yang, John Andrew McDaniel, Gian Armand Juliana DeBelder, Gaoyang Wang
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Publication number: 20130220516Abstract: An underwater pelletizing method for pelletizing brittle hydrocarbon resins with low melt viscosity. A feed material comprising the hydrocarbon resin is formed into a melt, extruded through a die into a water bath below the Tg of the hydrocarbon resin to form a plurality of extrudates and cut adjacent the die surface to form a slurry of resin pellets. A graft monomer and/or other reactants, such as a hydrosilylation agent, may be introduced into the resin melt to chemically modify the hydrocarbon resin.Type: ApplicationFiled: August 25, 2011Publication date: August 29, 2013Inventors: Eugene Ronald Uhl, Edward J. Blok, Dennis Kumor, Randal Howard Kerstetter, III, Ronald DeYoung
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Patent number: 8481604Abstract: The present invention provides a crosslinkable and expandable elastomeric material based on and/or containing siloxane polymer, the process for manufacturing of such material and the use of such material and its blends and composites.Type: GrantFiled: February 1, 2011Date of Patent: July 9, 2013Assignee: Armacell Enterprise GmbHInventors: Jürgen Weidinger, Mark E. Harakal, Joseph Naseri
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Patent number: 8460770Abstract: Polymer compositions comprise a (i) silane-functionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., ?,?,??,??˜tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light-crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.Type: GrantFiled: October 13, 2008Date of Patent: June 11, 2013Assignee: Dow Global Technologies LLCInventors: Bharat I. Chaudhary, Jeffrey M. Cogen, Saurav S. Sengupta
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Patent number: 8461263Abstract: The present invention provides an end-modified diene copolymer having excellent compatibility with silica as a reinforcement material, and a preparation process thereof, in which the end-modified diene copolymer is prepared by preparing a living polymer of a conjugated diene monomer and/or a vinyl aromatic monomer, modifying the living polymer with a reactive organosiloxane compound, and then modifying the end of the living polymer, to which the organosiloxane compound has not been coupled, with an organosilane compound having various functional groups. When the end-modified diene copolymer is used as a rubber material in the manufacture of a silica tire, the dispersion of silica in the copolymer can be improved and the bonding strength between silica and the rubber can be significantly increased, thereby manufacturing a high-quality silica tire.Type: GrantFiled: October 20, 2011Date of Patent: June 11, 2013Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Jae Young Ko, Dae Hyung Lee, Cheol Min Park
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Patent number: 8461268Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.Type: GrantFiled: November 15, 2011Date of Patent: June 11, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 8450419Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.Type: GrantFiled: August 24, 2010Date of Patent: May 28, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Publication number: 20130115461Abstract: A composition is disclosed comprising a polyethylene powder having: (a) a specific density of 930 kg/m3 or less; (b) a melt index MI2 greater than 0.5 g/10 min; (c) a ratio of HLMI/MI2 of less than 25, where HLMI is high load melt index measured under a load of 21.6 kg; (d) a bulk density of at least 350 kg/m3; and (e) a d50 greater than 500 ?m, and absorbed within said powder at least 1 wt % of a liquid additive.Type: ApplicationFiled: July 13, 2011Publication date: May 9, 2013Applicant: Ineos Europe AGInventors: Dominique Jan, Yves-Julien Lambert
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Publication number: 20130102733Abstract: A method of preparing core-shell submicron spheres is disclosed. The method comprises steps hereafter. An emulsion containing a core monomer is heated to a temperature of 10° C. below its boiling point to the boiling point. A core forming step is performed by adding an initiator solution to the heated emulsion to form cores by polymerizing the core monomer. When the conversion of the above polymerization is 10% to 95%, a shell forming step is performed by adding a shell monomer into the emulsion, at a temperature of 50° C. below the emulsion's boiling point to the boiling point thereof, to form shells, respectively surrounding the cores, by polymerizing the shell monomer.Type: ApplicationFiled: March 22, 2012Publication date: April 25, 2013Applicant: NATIONAL CENTRAL UNIVERSITYInventors: Hui Chen, Ming-Yu Lo, Yu-Cheng Kuo
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Publication number: 20130102734Abstract: A photosemiconductor protective material comprising a chain olefin-cyclic olefin copolymer elastomer composed of a chain olefin and a cyclic olefin as polymerizable components is prepared. The elastomer may comprise an ?-chain C2-4olefin and a polycyclic olefin as polymerizable components, and the molar ratio of the ?-chain C2-4olefin relative to the polycyclic olefin may be 80/20 to 99/1 in a ratio of the ?-chain C2-4olefin/the polycyclic olefin. The photosemiconductor protective material may further contain an organic silicon compound having a hydrolytically condensable group. The organic silicon compound may be a silane coupling agent having a (meth)acryloyl group. A photosemiconductor protective material 1 as the protective material is suitable as a solar cell encapsulant or filler 3 for encapsulating a solar cell 4. The photosemiconductor protective material has a high transparency and a high weather resistance and a proper elasticity and effectively protects a photosemiconductor.Type: ApplicationFiled: April 13, 2011Publication date: April 25, 2013Applicant: DAICEL CORPORATIONInventors: Akira Takaragi, Takahiro Iwahama, Takahiro Tei, Ryuta Tomoyose
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Patent number: 8404783Abstract: The invention relates to novel crosslinkable copolymers which are obtainable by (a) copolymerizing at least two different hydrophilic monomers selected from the group consisting of N,N-dimethyl acrylamide (DMA), 2-hydroxyethyl acrylate (HEA), glycidyl methacrylate (GMA), N-vinylpyrrolidone (NVP), acrylic acid (AA) and a C1-C4-alkoxy polyethylene glycol (meth)acrylate having a weight average molecular weight of from 200 to 1500, and at least one crosslinker comprising two or more ethylenically unsaturated double bonds in the presence of a chain transfer agent having a functional group; and (b) reacting one or more functional groups of the resulting copolymer with an organic compound having an ethylenically unsaturated group.Type: GrantFiled: July 10, 2007Date of Patent: March 26, 2013Assignee: Novartis AGInventors: Frank Chang, Norberto Arturo Medina