Solid Polymer From Ethylenic Reactants Only Is Derived From Unsaturated Hydrocarbon Patents (Class 525/106)
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Patent number: 6995225Abstract: A proton conduction material having high proton conductivity and exhibiting high reactive gas permeability regardless of the percentage of water content is provided. This proton conduction material consists of a polymer material whose molecular structure has a strong acid functional group. This polymer material consists of a polymer of a mixture of a monomer having an end structure expressed by a formula (1) or a vinyl radical and a monomer expressed by a formula (2). A strong acid functional group is included in the structure of both the monomers. It is to be noted herein that R1, R2, R3, R4, R5 and R6 represent a hydrocarbon radical, a fluoro-substituted hydrocarbon radical, or a trimethylsiloxy radical. Because introduction of a structure in which a hydrocarbon radical is bonded to silicon weakens interaction and causes bulkiness, gaps are created among atoms. If the number of the gaps among the atoms increases, the diffusion coefficient of reactive gases increases.Type: GrantFiled: November 7, 2003Date of Patent: February 7, 2006Assignee: Toyota Jidosha Kabushiki KaishaInventors: Takuichi Arai, Hiroshi Hamaguchi
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Patent number: 6989420Abstract: Coating liquid for producing insulating film having low dielectric constant is provided. It was achieved by coating liquid for producing insulating film having low dielectric constant comprising a thermosetting resin having carbon-carbon unsaturated bond, an organic solvent, and less than two molecular equivalents of water to the carbon-carbon unsaturated bond.Type: GrantFiled: November 25, 2002Date of Patent: January 24, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Yuji Yoshida, Naoya Satoh
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Patent number: 6972309Abstract: The present invention is based upon the unexpected finding that polyisoprene rubber which is clear and of high purity can be cured utilizing the curative system of this invention to attain an elongation at break of greater than 1200% without compromising the clarity or purity of the rubber. The curative system of this invention is comprised of a carbonyl inhibited platinum catalyst, and a branched crosslinking agent having at least 2 hydrosilyl groups per molecule. The curative system of this invention can be used to cure solid polyisoprene rubber that is used in a wide variety of application and is a particular value in curing polyisoprene rubber used in manufacturing sporting goods, healthcare, and medical products.Type: GrantFiled: June 17, 2004Date of Patent: December 6, 2005Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, Vanessa Marika Guscoff, Michael Joseph Rachita
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Patent number: 6972313Abstract: The invention concerns a silicone composition cross-linkable by hydrosilylation into adhesive gel and absorber, characterized in that it comprises: (I) at least a polyorganosiloxane POS (I); (II) at least a polyorganosiloxane POS (II); (III) at least an adhesive promoter (III); (IV) hollow organic microspheres; (V) optionally at least a polyorganosiloxane POS (V) particularly useful as diluent of POS (I); (VI) an effective amount of hydrosilylation catalyst, preferably of the platinous type.Type: GrantFiled: October 4, 2002Date of Patent: December 6, 2005Inventors: Fabienne Howe, Christian Pusineri
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Patent number: 6949603Abstract: In one embodiment the invention is a polymerizable composition comprising a) an organoborane amine complex; b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization; c) one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization; and d) a catalyst for the polymerization of the one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization. This composition may further comprise a compound which causes the organoborane amine complex to disassociate.Type: GrantFiled: June 1, 2004Date of Patent: September 27, 2005Assignee: Dow Global Technologies Inc.Inventors: Mark F. Sonnenschein, Steven P. Webb, Benjamin L. Wendt, Daniel R. Harrington
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Patent number: 6942926Abstract: Siloxane cross-linked polyolefins provide for a composition that is more or less impermeable to gaseous sulfur compounds such as hydrogen sulfide providing for a protective coating for various articles of manufacture especially electronic components and a method of protecting various articles of manufacture from the effects of such gaseous sulfur compounds.Type: GrantFiled: April 18, 2003Date of Patent: September 13, 2005Assignee: General Electric CompanyInventors: Xiaoqian Liu, Slawomir Rubinsztajn
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Patent number: 6936663Abstract: Disclosed is a powder coating composition containing a powder coating resin and a polyhedral oligomeric silsesquioxane (“POSS”) compound.Type: GrantFiled: July 6, 2004Date of Patent: August 30, 2005Assignee: Conano CorporationInventor: Robert Modisette
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Patent number: 6933345Abstract: The nanoscopic dimensions of polyhedral oligomeric silsesquioxanes (POSS) and polyhedral oligomeric silicates (POS) materials ranges from 0.7 nm to 5.0 nm and enables the thermomechanical and physical properties of polymeric materials to be improved by providing nanoscopic reinforcement of polymer chains at a length scale that is not possible by physically smaller aromatic chemical systems or larger fillers and fibers. A simple and cost effective method for incorporating POSS/POS nanoreinforcements onto polymers via the reactive grafting of suitably functionalized POSS/POS entities with polymeric systems amenable to such processes is described. The method teaches that the resulting POSS-grafted-polymers are particularly well suited for alloying agents by nongrafted POSS entitles such as molecular silicas. The successful alloying of POSS-polymers is aided because their interfacial tensions are reduced relative to non-POSS containing systems.Type: GrantFiled: January 23, 2003Date of Patent: August 23, 2005Assignee: Hybrid Plastics, LLPInventors: Joseph D. Lichtenhan, Frank J. Feher, Joseph J. Schwab, Sixun Zheng
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Patent number: 6930147Abstract: The present invention relates to a vinyl polymer terminated in a silanol group, a hydrolyzable silyl group or an acrylic functional group, to a method of producing a vinyl polymer having a hydrolyzable silyl group at one or more termini thereof which comprises reacting a vinyl polymer having a silanol group at one or more termini thereof with a silicon compound having two or more silicon atom-bound hydrolyzable groups, and a method of producing a vinyl polymer having an acrylic functional group at one or more termini thereof which comprises reacting a vinyl polymer having a silanol group at one or more termini thereof with a silicon compound represented by the general formula (3): XSiR2—G—O—C(O)C(L)?CH2??(3) wherein X is a hydrolyzable group.Type: GrantFiled: September 2, 1999Date of Patent: August 16, 2005Assignee: Kaneka CorporationInventors: Yoshiki Nakagawa, Kenichi Kitano, Masayuki Fujita
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Patent number: 6918931Abstract: Yellow dye moiety-containing prepolymers with blue light absorbing priorities and methods for producing the same for use in the production of relatively high refractive index polymeric compositions are described herein. Polymeric compositions so produced are useful in the production of ophthalmic devices such as for example intraocular lenses and corneal inlays.Type: GrantFiled: September 8, 2003Date of Patent: July 19, 2005Assignee: Bausch & Lomb IncorporatedInventors: Yu-Chin Lai, Dominic V. Ruscio
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Patent number: 6894115Abstract: Adhesive blend compositions having significantly improved adhesion to metals at elevated temperatures are provided. The compositions are blends of one or more polyolefin base resins, an acid or acid derivative modified polyolefin and silane modified polyolefin. A low level of adhesion promotor is optionally included in the blend.Type: GrantFiled: December 17, 2002Date of Patent: May 17, 2005Assignee: Equistar Chemicals, LPInventor: Maged G. Botros
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Patent number: 6889735Abstract: There is disclosed a pneumatic tire having a rubberized component comprising: (a) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (b) 1 to 50 phr of a dendrimer.Type: GrantFiled: January 28, 2003Date of Patent: May 10, 2005Assignee: The Goodyear Tire & Rubber CompanyInventors: Uwe Ernst Frank, Friedrich Visel, Thierry Florent Edme Materne, Rene Jean Zimmer, Wolfgang Lauer, Marc Weydert, Thomas Schildbach, Annette Lechtenböhmer, Maurice Peter Catharina Jozef Klinkenberg
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Patent number: 6878773Abstract: In a process for the preparation of an emulsion of a silicone organic block copolymer in water, a polydiorganosiloxane having terminal reactive groups (A), an organic material having terminal groups (B) which are reactive with the groups (A) and a catalyst are emulsified in water with a surfactant and the resulting emulsion is subjected to conditions under which the reaction between groups (A) and (B) proceeds in the presence of the catalyst, thereby forming a copolymer chain containing polysiloxane blocks and blocks of organic material. Preferred emulsions comprise a copolymer comprising polydiorganosiloxane blocks and organic blocks, having a viscosity in the range 10 to 1000000 Pa.s and a mean particle size of 0.3 to 1000 micrometers.Type: GrantFiled: January 30, 2001Date of Patent: April 12, 2005Assignee: Dow Corning S.A.Inventors: Leon Andre Marteaux, Anne-Lise Girboux
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Patent number: 6875534Abstract: A rubber composition comprising (A) a polyisobutylene polymer having an allyl radical at an end, (B) an optional organpolysiloxane, (C) an organohydrogenpolysiloxane having at least two SiH radicals per molecule, and (D) a platinum group metal catalyst forms a seal member on a periphery of one side of a polymer electrolyte fuel-cell separator. Due to improved acid resistance, weather resistance, creep resistance and gas permeability, the seal member remains effective for a long period of time.Type: GrantFiled: June 20, 2002Date of Patent: April 5, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tsutomu Nakamura, Noriyuki Meguriya, Hironao Fujiki
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Patent number: 6870005Abstract: A polymeric composition and process for making the same suitable for injection molding processes and procedures containing an olefinic polymer component selected from at least one a group which includes polyalkylenes, copolymers of polyalkylenes and a non-olefinic thermoplastic. The non-olefinic and olefinic polymeric components are present in random orientable locations in the initial polymeric composition. When injection molded against a temperature gradient, the resulting workpiece composed of the composition has distinctive regions of elevated non-olefinic concentration proximate the outwardly oriented surface and distinctive regions of elevated olefinic polymeric concentration proximate to interior regions of the workpiece. The non-olefinic thermoplastic may be at least one of thermoplastic polyamides, thermoplastic polyolefins and thermoplastic polycarbonates.Type: GrantFiled: February 28, 2002Date of Patent: March 22, 2005Assignee: ACI Technologies, LLCInventor: Mark Lieberman
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Patent number: 6852794Abstract: There is disclosed a pneumatic tire having a rubberized component comprising: (a) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (b) 1 to 110 phr of a polyhedral oligomeric silsesquioxanes.Type: GrantFiled: August 7, 2002Date of Patent: February 8, 2005Assignee: The Goodyear Tire & Rubber CompanyInventors: Aaron Scott Puhala, David John Zanzig, Brian David Holden, Neil Arthur Maly
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Patent number: 6849755Abstract: An organosilicon compound represented by the following general formula (1): wherein R1 is a hydrogen atom, a phenyl group or a halogenated phenyl group; R2 is a hydrogen atom or a methyl group; R3's are each a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms; X is a hydrolyzable group; Z1 is —R4—, —R4O— or —R4(CH3)2SiO—, where R4 is a substituted or unsubstituted divalent hydrocarbon group having 1 to 10 carbon atoms; Z2 is an oxygen atom or a substituted or unsubstituted divalent hydrocarbon group having 1 to 10 carbon atoms; and m is 0, 1 or 2 and n is 0, 1 or 2. When incorporated in silicone compositions, the organosilicon compound acts as a cross-linking agent having well-balanced photopolymerizability and condensation curability.Type: GrantFiled: October 26, 2001Date of Patent: February 1, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Toshiyuki Ozai, Hiroyasu Hara, Yoshifumi Inoue, Tomoyuki Goto
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Patent number: 6846893Abstract: A mixture is provided comprising (a) at least one of an elastomeric thermoplastic, a non-elastomeric thermoplastic, an elastomeric thermoset and mixtures thereof, excluding polydiorganosiloxane fluids and (b) a polymer having soft polydiorganosiloxane units, hard polyisocyanate residue units, optionally, soft and/or hard organic polyamine residue units and terminal groups. The hard polyisocyanate residue and the hard polyamine residue comprise less than 50% by weight of the polydiorganosiloxane urea containing component. The polyisocyanate residue is the polyisocyanate minus the —NCO groups and the polyamine residue is the polyamine minus the —NH2 groups. The polyisocyanate residue is connected to the polyamine residue by urea linkages. The terminal groups are non-functional groups or functional groups. The polydiorganosiloxane urea containing component may be reactive under free-radical or moisture curing conditions.Type: GrantFiled: October 23, 1996Date of Patent: January 25, 2005Assignee: Minnesota Mining and Manufacturing CompanyInventors: Audrey A. Sherman, Mieczyslaw H. Mazurek, Walter R. Romanko, Patrick D. Hyde, Roy Wong, Albert I. Everaerts
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Patent number: 6846004Abstract: A new adhesive coating composition, particularly for use on airbag fabrics, which is composed of a silicone polymer and an appreciable level of a copolymer of ethylene and a polar monomer, is provided. This coating provides excellent adhesive properties to the coated fabric and provides a synergistic effect such that lower gas permeability upon inflation may be obtained with this coating than might be achieved with the silicone polymer alone. Additionally, such a coating allows maximization of the adhesion characteristics on one-piece woven airbag fabric such that blistering upon high-pressure inflation can be reduced, while retaining a high degree of inflation gas retention. Fabric treated with this material in the manner described herein permits reduction in the cost of the coating itself (by reducing the use of expensive silicone polymers). Airbag fabrics and cushions, as well as methods of making and using such a novel airbag coating material are also encompassed within this invention.Type: GrantFiled: September 24, 2002Date of Patent: January 25, 2005Assignee: Milliken & CompanyInventor: Richard Henry Parker
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Patent number: 6833414Abstract: A cross-linkable fluoropolymer dispersion is described and involves a polymer product of at least one polymerizable acrylic and/or vinyl containing monomer and at least one hydrolytically stable silane containing monomer which are in the presence of an aqueous dispersion of at least one fluoropolymer. The present invention further relates to cross-linkable fluoropolymer blends wherein at least one polymer contains acrylic units, vinyl units, or both and at least one hydrolytically stable silane or silane containing group in the presence of at least one thermoplastic fluoropolymer. The silane or silane containing group can alternatively be present in the thermoplastic fluoropolymer. Methods of making the cross-linkable fluoropolymers are also described as well as products containing the cross-linkable fluoropolymer dispersions such as paints and coatings.Type: GrantFiled: February 12, 2002Date of Patent: December 21, 2004Assignee: Arkema Inc.Inventors: Claude C. Granel, Lotfi Hedhli, Ramin Amin-Sanayei, Kurt A. Wood
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Publication number: 20040249075Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material. The crosslinking agent includes a copolymer having at least 30 mol % of alternating structural units of a residue from a donor monomer and a residue from one or more acrylic acceptor monomers. The thermosetting composition may coat a substrate by coalescing the composition to form a continuous film and curing the composition. The thermosetting composition may be included as part of a multi-component composite coating composition that includes an optional primer coat, a base coat deposited from a pigmented film-forming composition, and a transparent top coat applied over the base coat, where either the base coat, the transparent top coat, or both, are deposited from the thermosetting composition.Type: ApplicationFiled: July 9, 2004Publication date: December 9, 2004Inventors: Karen S. Rechenberg, Simion Coca, Karen A. Barkac, James B. O'Dwyer, Linda J. Bowser
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Patent number: 6824881Abstract: Thermoplastic silicon block copolymers containing (A) a hard segment polymer constituent prepared from styrene, methylmethacrylate, butylacrylate, acrylonitrile, vinyl monomers, or mixtures therefore, and (B) a soft segment polymer constituent of general formula (I) G-[(SiR2O)mSiR2—X—]n(SiR2O)mSiR2-G wherein R is an optionally halogenated monovalent C1-18 hydrocarbon radical and X is a specific aryl group-containing, silicon bonded radical, and each G may be a radical (A)-Z-(Si) or Z′-(Si) wherein -Z- represents an aryl group-containing bivalent radical and Z′- represents a monovalent aryl group-containing radical, provided that there is, at most, one radical G and one radical Z′- in formula (I). In formula (I), m represents a whole number between 1 and 1000 and n represents 0 or a whole number between 1 and 20, provided that when n does not equal 0, 4≦n·m≦1000.Type: GrantFiled: June 23, 2003Date of Patent: November 30, 2004Assignee: Wacker-Chemie GmbHInventors: Hans Lautenschlager, Jochen Dauth, Wolfgang Keller, Theo Mayer, Kurt Stark
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Patent number: 6818701Abstract: A golf ball includes a portion formed from a golf ball-forming composition containing at least one kind selected from a crosslinked silicone rubber powder and a crosslinked silicone resin powder. Each of the crosslinked silicone rubber powder and the crosslinked silicone resin powder has an average particle size in a range of 60 to 500 &mgr;m. The golf ball is excellent in durability against repetitive hitting and adhesiveness of a coating film, and particularly, has a good resilience and a long flight distance in both a wide temperature range and a wide hitting head speed range.Type: GrantFiled: December 23, 2002Date of Patent: November 16, 2004Assignee: Bridgestone Sports Co., Ltd.Inventors: Yasushi Ichikawa, Rinya Takesue, Eiji Takehana
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Patent number: 6784247Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material. The crosslinking agent includes a copolymer having at least 30 mol % of alternating structural units of a residue from a donor monomer and a residue from one or more acrylic acceptor monomers. The thermosetting composition may coat a substrate by coalescing the composition to form a continuous film and curing the composition. The thermosetting composition may be included as part of a multi-component composite coating composition that includes an optional primer coat, a base coat deposited from a pigmented film-forming composition, and a transparent top coat applied over the base coat, where either the base coat, the transparent top coat, or both, are deposited from the thermosetting composition.Type: GrantFiled: February 4, 2003Date of Patent: August 31, 2004Assignee: PPG Industries Ohio, Inc.Inventors: Karen S. Rechenberg, Simion Coca, Karen A. Barkac, James B. O'Dwyer, Linda J. Bowser
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Patent number: 6780934Abstract: A room temperature-setting composition containing a polyoxyalkylene polymer (A) having a molecular weight ranging from 8000 to 50000 and having hydrolyzable silicon groups of the following formula (1): —SiXaR13−a (1) wherein R1 is a C1-20 substituted or unsubstituted monovalent organic group, X is a hydroxyl group or a hydrolyzable group, a is 1, 2 or 3, provided that when more than one R1 group is present, the R1 groups may be the same or different, and when more than one X group is present, the X groups may be the same or different, the composition comprising, as an essential component, the polyoxyalkylene polymer, having a molecular weight ranging from 8000 to 50000 and having hydrolyzable silicon groups of formula (1), wherein a is 3, or the composition comprises a polyoxyalkylene polymer component as defined above which contains said essential specific polyoxyalkylene polymer component, and a polymer (B) made by polymerization of a polymerizable unsaturated group-containing monomType: GrantFiled: August 29, 2002Date of Patent: August 24, 2004Assignee: Asahi Glass Company Ltd.Inventors: Takao Doi, Takashi Watabe, Tomoko Matsumoto, Tatsuo Onoguchi, Kaori Tsuruoka
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Patent number: 6774167Abstract: Undesirable changes in shade brought about by low temperatures (Cold Stress Whitening) in impact-modified thermoplastic molding compositions F which comprise at least one elastomeric graft polymer A and at least one thermoplastic polymer B are reduced by adding from 10 to 200 ppm, based on the molding compositions F, of at least one polyorganosiloxane S to the impact-modified thermoplastic molding composition F.Type: GrantFiled: April 25, 2002Date of Patent: August 10, 2004Assignee: BASF AktiengesellschaftInventors: Sabine Oepen, Norbert Niessner, Michael Breulmann, Norbert Güntherberg, Wil Duijzings
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Patent number: 6761976Abstract: The composition comprises: an organopolysiloxane; a polymer material resistant to tearing; a first coupling agent compatible with said organopolysiloxane, and having hydroxyl first functional groups; and a second coupling agent compatible with said polymer and having second functional groups suitable for reacting with said hydroxyl first groups. Application to power accessories and cables.Type: GrantFiled: January 11, 2002Date of Patent: July 13, 2004Assignee: NexansInventors: Denis Cottevieille, Lionel Fomperie, Pascal Amigouet
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Publication number: 20040127645Abstract: Disclosed is a copolymer prepared from a conjugated diene monomer and a vinyl aromatic monomer. The radial copolymer is prepared by coupling the terminal of a leaving polymer using a mixed coupling agent comprising the mixture of a multi-reactive polysiloxane and a tin halide compound, the leaving polymer being prepared by copolymerizing a conjugated diene monomer and a vinyl aromatic monomer in the presence of an organo lithium catalyst and a hydrocarbon solvent. The use of the radial copolymer improves the affinity to silica or carbon black used as a filler, and remarkably enhances processibility in the manufacture of tires as well as the properties (e.g., higher wet traction, lower rolling resistance, and higher tread wear) necessary for tires relative to the conventional products.Type: ApplicationFiled: December 12, 2003Publication date: July 1, 2004Applicant: Korea Kumho Petrochemical Co., Ltd.Inventors: Young-Hoon Ko, Jae-Young Koh, Hung-Kyu Choi, Hun-Jong Baik
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Patent number: 6750289Abstract: A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.Type: GrantFiled: January 23, 2003Date of Patent: June 15, 2004Assignee: Shell Oil CompanyInventors: Bridget Ann Spence, Ronald James Hoxmeier, Robert Charles Job
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Patent number: 6737145Abstract: The present invention is concerned with an organic-inorganic composite graded material containing a composite material formed by chemically bonding an organic polymer compound and a metallic compound and having a component graded structure in which the content of the metallic compound continuously changes in the depth direction from the material surface, a process for the production of the above organic-inorganic composite graded material by forming a coating layer composed of a specific coating solution for forming the organic-inorganic composite film on an organic substrate and drying the coating layer under heat, a coating agent composed of the above organic-inorganic composite graded material for forming a coating film, and an article coated with the above coating agent.Type: GrantFiled: June 8, 2001Date of Patent: May 18, 2004Assignees: Ube Nitto Kasei Co., Ltd.Inventors: Toshiya Watanabe, Kazuhito Hashimoto, Akira Fujishima, Kazuyuki Takami, Norihiro Nakayama, Taro Suzuki, Naoki Tanaka, Eisuke Tachibana, Tatsuhiko Adachi
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Patent number: 6716919Abstract: A method of using nanostructured chemicals as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are time dependent mechanical and thermal properties such as heat distortion, creep, compression set, shrinkage, modulus, hardness and abrasion resistance. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, fire resistance, and improved oxygen permeability.Type: GrantFiled: March 26, 2001Date of Patent: April 6, 2004Assignee: Hybrid PlasticsInventors: Joseph D. Lichtenhan, Joseph J. Schwab, Andre Lee, Shawn Phillips
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Patent number: 6713532Abstract: Solid blends of rubbery polymers and amorphous or crystalline polymers, said blends being free-flowing at temperatures lower than the glass transition temperature or crystalline melting temperature of the amorphous or crystalline polymer, are prepared by intimate mixing procedures. In general, said mixing conditions include high shear conditions sufficient to convert polymer A to dispersed particles coated with polymer B and produce a free-flowing powder blend.Type: GrantFiled: February 28, 2003Date of Patent: March 30, 2004Assignee: General Electric CompanyInventors: Navjot Singh, Joseph Michael Anostario
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Patent number: 6703446Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamType: GrantFiled: June 21, 2002Date of Patent: March 9, 2004Assignee: FMC Corporation, Lithium DivisionInventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
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Patent number: 6699939Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamType: GrantFiled: June 21, 2002Date of Patent: March 2, 2004Assignee: FMC Corporation, Lithium DivisionInventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
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Patent number: 6677279Abstract: The invention relates to a variety of uses for novel carbon monoxide containing polymers. More specifically, the invention employs the use of low molecular weight polymers containing carbon monoxide for use as adhesive additives and as fluids (e.g., solvents and synthetic base stocks).Type: GrantFiled: February 7, 2003Date of Patent: January 13, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Abhimanyu Onkar Patil, Donald Norman Schulz, Michael Gerard Matturro, Richard Henry Schlosberg
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Patent number: 6670421Abstract: A polymeric composition and process for making the same suitable for injection molding processes and procedures containing an olefinic polymer component selected from at least one a group which includes polyalkylenes, copolymers of polyalkylenes and a thermoplastic polyamide. The polyamide and olefinic polymeric components are present in random orientable locations in the initial polymeric composition. When injection molded against a temperature gradient, the resulting workpiece composed of the composition has distinctive regions of elevated polyamide concentration proximate the outwardly oriented surface and distinctive regions of elevated olefinic polymeric concentration proximate to interior regions of the workpiece.Type: GrantFiled: August 3, 2001Date of Patent: December 30, 2003Assignee: ACI Technologies, LLCInventor: Mark Lieberman
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Patent number: 6660807Abstract: An additive for organic resin comprising a powder comprising (A) a liquid organopolysiloxane having at least 0.001 wt % of silicon-bonded hydrogen atoms and at least 50 dimethylsiloxy repeating units and (B) an inorganic powder; and an organic resin comprising the additive.Type: GrantFiled: October 31, 2001Date of Patent: December 9, 2003Assignee: Dow Corning Toray Silcone Co., Ltd.Inventors: Yoshitsugu Morita, Haruhiko Furukawa, Koji Shiromoto, Hiroshi Ueki
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Patent number: 6649722Abstract: This invention is directed to ophthalmic materials and ophthalmic lenses that are a co-polymerization product of a (a) hydrophilic monomer with (b) a tris(siloxy)silyl group-containing monomer, (c) a wide variety of hydrophobic monomers (both aliphatic and aromatic) and usually a (d) polyfluorinated monomer, as well as optional monomers or monomer mixtures that can include a cationic monomer, a non-aromatic hydrophobic monomer and a poly(dimethylsiloxy)silyl group-containing monomer. A contact lens prepared from such a co-polymer exhibits enhanced water content, while maintaining exceptional oxygen permeability, thereby providing a lens that can be worn comfortably for prolonged periods of time. A process for the preparation of such lenses is also disclosed.Type: GrantFiled: December 6, 2000Date of Patent: November 18, 2003Assignee: Novartis AGInventors: Howard S. Rosenzweig, Michael H. Quinn, Robert Tucker, Greg Carlson, Gerardo J. Ocampo
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Patent number: 6645638Abstract: A silicone rubber adhesive composition comprising (A) a heat curable organopolysiloxane composition of the addition curing type or peroxide curing type, (B) reinforcing silica fines, (C) an adhesive agent, and (D) a compound having at least one ester group in a molecule is easily moldable within a short time by injection molding, suitable in primerless molding, and bondable with various thermoplastic resins. Integrally molded articles in which the silicone rubber adhesive composition is firmly bonded to the thermoplastic resin are obtainable without a need for modification of the resin.Type: GrantFiled: July 11, 2001Date of Patent: November 11, 2003Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hironao Fujiki, Syuuichi Azechi
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Patent number: 6639015Abstract: A coating liquid for forming a silica-containing film with a low-dielectric constant, which enables the formation of a low-density film having a dielectric constant as low as 3 or less and having excellent resistance to oxygen plasma and process adaptation but also in the adhesion to a substrate and film strength, is provided. The coating liquid for forming a silica-containing film with a low-dielectric constant comprises a polymer composition mainly constituted by (i) a polysiloxane and (ii) a readily decomposable resin, said polysiloxane being a reaction product between fine particles of silica and a hydrolyzate of at least one alkoxysilane represented by the following formula (I): XnSi(OR)4−n (I), wherein X represents a hydrogen atom, a fluorine atom, an unfluorinated or fluorinated alkyl group of 1 to 8 carbon atoms, an aryl group or a vinyl group; R represents a hydrogen atom, an alkyl group of 1 to 8 carbon atoms, an aryl group or a vinyl group; and n is an integer of 0 to 3.Type: GrantFiled: April 28, 2000Date of Patent: October 28, 2003Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Akira Nakashima, Michio Komatsu
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Patent number: 6617021Abstract: An adhesive composition for semiconductor devices contains as essential components (A) epoxy resin, (B) phonolic resin, (C) epoxidized styrene-butadiene-styrene block copolymer and (D) diaminosiloxane compound. The adhesive composition is excellent in heat resistance, thermal cycle test and humidity resistance. An adhesive sheet employing the above adhesive composition is also provided.Type: GrantFiled: February 11, 2002Date of Patent: September 9, 2003Assignee: Tomoegawa Paper Co., Inc.Inventors: Masaharu Kobayashi, Osamu Oka, Yasuhiro Yoshii
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Patent number: 6602964Abstract: Disclosed herein is a composition comprising: A) a moisture curable polymer selected from the group consisting of silylated polyurethanes, silylated polyethers, and mixtures thereof, and B) a silicone oligomer of the formula: [R3SiO1/2]m[O1/2Si(R)2O1/2]n[SiO3/2R]o[SiO4/2]p (I) wherein: each R is independently selected from the group consisting of B, R1, —OR2, R3, and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by a Si—C bond; each R1 is independently a saturated or aromatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1 or an acyl group; each R3 is independently a monovalent organic group containing an aliphatic unsaturated hydrocarbon group; each R4 is a monovalent organic group linked to the Si atom of the siloxane oligomer backbone by a Si—C bond that does not include an aliphatic unsaturated hydrocarbon group and that has thereType: GrantFiled: February 4, 2002Date of Patent: August 5, 2003Assignee: Crompton CorporationInventors: Misty Huang, Richard E. Handel, Herbert Petty
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Patent number: 6602953Abstract: A polyoxymethylene resin composition is provided which comprises a polyoxymethylene resin (A), a silicone compound-grafted polyolefinic resin (B-1) and a silicone compound (B-2), the amount of the silicone compound-grafted polyolefinic resin (B1) being 0.05 to 10 parts by weight on the basis of 100 parts by weight of the polyoxymethylene resin (A), and the ratio of (B1)/(B2) by weight in the composition being 99/1 to 70/30.Type: GrantFiled: June 29, 2001Date of Patent: August 5, 2003Assignee: Asahi Kasei Kabushiki KaishaInventors: Mitsuhiro Horio, Yuuji Yoshinaga
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Patent number: 6596402Abstract: Coatings are formed by applying to article a copolymer of a water soluble base polymer having graft polymerized thereto an organic moiety that includes a group that reacts with water to form a silanol group, and then curing the copolymer to form a crosslinked hydrogel coating that is absorbent, lubricious and substantially non-water soluble. Coating compositions, coated articles the subject coatings are also described.Type: GrantFiled: December 29, 2000Date of Patent: July 22, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Dave Soerens, Sohail Malik, Cameron G. Rouns, Sharon L. Greene, Archel A. Ambrosio
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Publication number: 20030130424Abstract: A golf ball includes a portion formed from a golf ball-forming composition containing at least one kind selected from a crosslinked silicone rubber powder and a crosslinked silicone resin powder. Each of the crosslinked silicone rubber powder and the crosslinked silicone resin powder has an average particle size in a range of 60 to 500 &mgr;m. The golf ball is excellent in durability against repetitive hitting and adhesiveness of a coating film, and particularly, has a good resilience and a long flight distance in both a wide temperature range and a wide hitting head speed range.Type: ApplicationFiled: December 23, 2002Publication date: July 10, 2003Applicant: BRIDGESTONE SPORTS CO., LTD.Inventors: Yasushi Ichikawa, Rinya Takesue, Eiji Takehana
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Patent number: 6590032Abstract: A thermoplastic resin composition comprising (A) 100 weight parts thermoplastic resin, (B) 0.1 to 100 weight parts of a mixture of (b-1) thermoplastic resin and (b-2) polyorganosiloxane that has a viscosity at 25° C. of at least 1,000,000 mPa·s, and (C) 0.1 to 100 weight parts polyorganosiloxane-bonded thermoplastic resin in which (c-1) thermoplastic resin and (c-2) polyorganosiloxane are chemically bonded to each other.Type: GrantFiled: April 10, 2001Date of Patent: July 8, 2003Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Haruhiko Furukawa, Koji Shiromoto, Hiroshi Ueki, Yoshitsugu Morita
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Patent number: 6579941Abstract: An adhesive construction, characterized by excellent converting and adhesive performance, comprises a facestock, a face-side adhesive (FSA) in contact with a first surface of the facestock, and a liner-side adhesive (LSA) in contact with the FSA. The FSA is compounded with an organopolysiloxane or modified organopolysiloxane. Single layer constructions, and multilayer constructions comprising more than two adhesive layers, and unique adhesive compositions, are also provided. The constructions can be run in high-speed converting presses and adhere well to a variety of substrates.Type: GrantFiled: June 12, 2000Date of Patent: June 17, 2003Assignee: Avery Dennison CorporatoinInventors: Yukihiko Sasaki, Jesse C. Ercillo, Le Hoa Hong
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Patent number: 6576082Abstract: The present invention provides a primer composition comprising (A) a vinyl polymer having a main chain substantially comprising vinyl copolymer chain and at least one silicon-containing group having a hydroxy group or a hydrolyzable group bonded to a silicon atom and capable of crosslinking by forming a siloxane bond at the terminal end of the main chain and/or side chain, and (B) (a) a saturated hydrocarbon polymer having at least one silicon-containing group having a hydroxy group or a hydrolyzable group bonded to a silicon atom and capable of crosslinking by forming a siloxane bond, and/or (b) a polybutadiene polymer having at least one silicon containing group having a hydroxy group or a hydrolyzable group bonded to a silicon atom and capable of crosslinking by forming a siloxane bond, which can remarkably improve the adhesion to various kinds of substrates, and which is particularly useful when applied to the isobutylene series sealing material.Type: GrantFiled: March 8, 2001Date of Patent: June 10, 2003Assignee: Kaneka CorporationInventors: Toshihiko Okamoto, Junji Takase
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Patent number: 6569942Abstract: There is disclosed a rubber composition comprising: (A) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (B) 1.5 to 50 phr of a silicon coupled oligomer of the formula: where R1 and 2 are individually selected from the group consisting of where R3 is selected from the group consisting of alkyls having 1 or 4 carbon atoms; w is an integer of from 9 to 149, x is an integer of from 1 to 100, y is an integer of from 1 to 100, and z is an integer of from 1 to 100 with the proviso that the sum total of x, y and z in each R1 and R2 ranges from 3 to 100.Type: GrantFiled: February 25, 2002Date of Patent: May 27, 2003Assignee: The Goodyear Tire & Rubber CompanyInventors: Marc Weydert, Wolfgang Lauer, Friedrich Visel, Rene Jean Zimmer, Francois Kayser
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Patent number: 6555620Abstract: The addition of a compound containing an aliphatically unsaturated bond as a storage stability improver to a hydrosilylating addition reaction type hardenable electrically-conductive composition comprising at least one alkenyl group-containing isobutylene polymer which can undergo hydrosilylation reaction per molecule and an electrical conductivity-providing material makes it possible to obtain an electrically-conductive composition having an excellent storage stability at high temperatures. Further, the use of such an electrically-conductive composition makes it possible to provide an electrically-conductive roller having an excellent productivity and processability and an excellent stability of electrical properties against environmental change.Type: GrantFiled: December 31, 2001Date of Patent: April 29, 2003Assignee: Kaneka CorporationInventors: Takao Manabe, Masashi Sakaguchi