Solid Polymer From Ethylenic Reactants Only Is Derived From Unsaturated Hydrocarbon Patents (Class 525/106)
  • Patent number: 6995225
    Abstract: A proton conduction material having high proton conductivity and exhibiting high reactive gas permeability regardless of the percentage of water content is provided. This proton conduction material consists of a polymer material whose molecular structure has a strong acid functional group. This polymer material consists of a polymer of a mixture of a monomer having an end structure expressed by a formula (1) or a vinyl radical and a monomer expressed by a formula (2). A strong acid functional group is included in the structure of both the monomers. It is to be noted herein that R1, R2, R3, R4, R5 and R6 represent a hydrocarbon radical, a fluoro-substituted hydrocarbon radical, or a trimethylsiloxy radical. Because introduction of a structure in which a hydrocarbon radical is bonded to silicon weakens interaction and causes bulkiness, gaps are created among atoms. If the number of the gaps among the atoms increases, the diffusion coefficient of reactive gases increases.
    Type: Grant
    Filed: November 7, 2003
    Date of Patent: February 7, 2006
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Takuichi Arai, Hiroshi Hamaguchi
  • Patent number: 6989420
    Abstract: Coating liquid for producing insulating film having low dielectric constant is provided. It was achieved by coating liquid for producing insulating film having low dielectric constant comprising a thermosetting resin having carbon-carbon unsaturated bond, an organic solvent, and less than two molecular equivalents of water to the carbon-carbon unsaturated bond.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: January 24, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yuji Yoshida, Naoya Satoh
  • Patent number: 6972309
    Abstract: The present invention is based upon the unexpected finding that polyisoprene rubber which is clear and of high purity can be cured utilizing the curative system of this invention to attain an elongation at break of greater than 1200% without compromising the clarity or purity of the rubber. The curative system of this invention is comprised of a carbonyl inhibited platinum catalyst, and a branched crosslinking agent having at least 2 hydrosilyl groups per molecule. The curative system of this invention can be used to cure solid polyisoprene rubber that is used in a wide variety of application and is a particular value in curing polyisoprene rubber used in manufacturing sporting goods, healthcare, and medical products.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: December 6, 2005
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, Vanessa Marika Guscoff, Michael Joseph Rachita
  • Patent number: 6972313
    Abstract: The invention concerns a silicone composition cross-linkable by hydrosilylation into adhesive gel and absorber, characterized in that it comprises: (I) at least a polyorganosiloxane POS (I); (II) at least a polyorganosiloxane POS (II); (III) at least an adhesive promoter (III); (IV) hollow organic microspheres; (V) optionally at least a polyorganosiloxane POS (V) particularly useful as diluent of POS (I); (VI) an effective amount of hydrosilylation catalyst, preferably of the platinous type.
    Type: Grant
    Filed: October 4, 2002
    Date of Patent: December 6, 2005
    Inventors: Fabienne Howe, Christian Pusineri
  • Patent number: 6949603
    Abstract: In one embodiment the invention is a polymerizable composition comprising a) an organoborane amine complex; b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization; c) one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization; and d) a catalyst for the polymerization of the one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization. This composition may further comprise a compound which causes the organoborane amine complex to disassociate.
    Type: Grant
    Filed: June 1, 2004
    Date of Patent: September 27, 2005
    Assignee: Dow Global Technologies Inc.
    Inventors: Mark F. Sonnenschein, Steven P. Webb, Benjamin L. Wendt, Daniel R. Harrington
  • Patent number: 6942926
    Abstract: Siloxane cross-linked polyolefins provide for a composition that is more or less impermeable to gaseous sulfur compounds such as hydrogen sulfide providing for a protective coating for various articles of manufacture especially electronic components and a method of protecting various articles of manufacture from the effects of such gaseous sulfur compounds.
    Type: Grant
    Filed: April 18, 2003
    Date of Patent: September 13, 2005
    Assignee: General Electric Company
    Inventors: Xiaoqian Liu, Slawomir Rubinsztajn
  • Patent number: 6936663
    Abstract: Disclosed is a powder coating composition containing a powder coating resin and a polyhedral oligomeric silsesquioxane (“POSS”) compound.
    Type: Grant
    Filed: July 6, 2004
    Date of Patent: August 30, 2005
    Assignee: Conano Corporation
    Inventor: Robert Modisette
  • Patent number: 6933345
    Abstract: The nanoscopic dimensions of polyhedral oligomeric silsesquioxanes (POSS) and polyhedral oligomeric silicates (POS) materials ranges from 0.7 nm to 5.0 nm and enables the thermomechanical and physical properties of polymeric materials to be improved by providing nanoscopic reinforcement of polymer chains at a length scale that is not possible by physically smaller aromatic chemical systems or larger fillers and fibers. A simple and cost effective method for incorporating POSS/POS nanoreinforcements onto polymers via the reactive grafting of suitably functionalized POSS/POS entities with polymeric systems amenable to such processes is described. The method teaches that the resulting POSS-grafted-polymers are particularly well suited for alloying agents by nongrafted POSS entitles such as molecular silicas. The successful alloying of POSS-polymers is aided because their interfacial tensions are reduced relative to non-POSS containing systems.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: August 23, 2005
    Assignee: Hybrid Plastics, LLP
    Inventors: Joseph D. Lichtenhan, Frank J. Feher, Joseph J. Schwab, Sixun Zheng
  • Patent number: 6930147
    Abstract: The present invention relates to a vinyl polymer terminated in a silanol group, a hydrolyzable silyl group or an acrylic functional group, to a method of producing a vinyl polymer having a hydrolyzable silyl group at one or more termini thereof which comprises reacting a vinyl polymer having a silanol group at one or more termini thereof with a silicon compound having two or more silicon atom-bound hydrolyzable groups, and a method of producing a vinyl polymer having an acrylic functional group at one or more termini thereof which comprises reacting a vinyl polymer having a silanol group at one or more termini thereof with a silicon compound represented by the general formula (3): XSiR2—G—O—C(O)C(L)?CH2??(3) wherein X is a hydrolyzable group.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: August 16, 2005
    Assignee: Kaneka Corporation
    Inventors: Yoshiki Nakagawa, Kenichi Kitano, Masayuki Fujita
  • Patent number: 6918931
    Abstract: Yellow dye moiety-containing prepolymers with blue light absorbing priorities and methods for producing the same for use in the production of relatively high refractive index polymeric compositions are described herein. Polymeric compositions so produced are useful in the production of ophthalmic devices such as for example intraocular lenses and corneal inlays.
    Type: Grant
    Filed: September 8, 2003
    Date of Patent: July 19, 2005
    Assignee: Bausch & Lomb Incorporated
    Inventors: Yu-Chin Lai, Dominic V. Ruscio
  • Patent number: 6894115
    Abstract: Adhesive blend compositions having significantly improved adhesion to metals at elevated temperatures are provided. The compositions are blends of one or more polyolefin base resins, an acid or acid derivative modified polyolefin and silane modified polyolefin. A low level of adhesion promotor is optionally included in the blend.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: May 17, 2005
    Assignee: Equistar Chemicals, LP
    Inventor: Maged G. Botros
  • Patent number: 6889735
    Abstract: There is disclosed a pneumatic tire having a rubberized component comprising: (a) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (b) 1 to 50 phr of a dendrimer.
    Type: Grant
    Filed: January 28, 2003
    Date of Patent: May 10, 2005
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Uwe Ernst Frank, Friedrich Visel, Thierry Florent Edme Materne, Rene Jean Zimmer, Wolfgang Lauer, Marc Weydert, Thomas Schildbach, Annette Lechtenböhmer, Maurice Peter Catharina Jozef Klinkenberg
  • Patent number: 6878773
    Abstract: In a process for the preparation of an emulsion of a silicone organic block copolymer in water, a polydiorganosiloxane having terminal reactive groups (A), an organic material having terminal groups (B) which are reactive with the groups (A) and a catalyst are emulsified in water with a surfactant and the resulting emulsion is subjected to conditions under which the reaction between groups (A) and (B) proceeds in the presence of the catalyst, thereby forming a copolymer chain containing polysiloxane blocks and blocks of organic material. Preferred emulsions comprise a copolymer comprising polydiorganosiloxane blocks and organic blocks, having a viscosity in the range 10 to 1000000 Pa.s and a mean particle size of 0.3 to 1000 micrometers.
    Type: Grant
    Filed: January 30, 2001
    Date of Patent: April 12, 2005
    Assignee: Dow Corning S.A.
    Inventors: Leon Andre Marteaux, Anne-Lise Girboux
  • Patent number: 6875534
    Abstract: A rubber composition comprising (A) a polyisobutylene polymer having an allyl radical at an end, (B) an optional organpolysiloxane, (C) an organohydrogenpolysiloxane having at least two SiH radicals per molecule, and (D) a platinum group metal catalyst forms a seal member on a periphery of one side of a polymer electrolyte fuel-cell separator. Due to improved acid resistance, weather resistance, creep resistance and gas permeability, the seal member remains effective for a long period of time.
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: April 5, 2005
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tsutomu Nakamura, Noriyuki Meguriya, Hironao Fujiki
  • Patent number: 6870005
    Abstract: A polymeric composition and process for making the same suitable for injection molding processes and procedures containing an olefinic polymer component selected from at least one a group which includes polyalkylenes, copolymers of polyalkylenes and a non-olefinic thermoplastic. The non-olefinic and olefinic polymeric components are present in random orientable locations in the initial polymeric composition. When injection molded against a temperature gradient, the resulting workpiece composed of the composition has distinctive regions of elevated non-olefinic concentration proximate the outwardly oriented surface and distinctive regions of elevated olefinic polymeric concentration proximate to interior regions of the workpiece. The non-olefinic thermoplastic may be at least one of thermoplastic polyamides, thermoplastic polyolefins and thermoplastic polycarbonates.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: March 22, 2005
    Assignee: ACI Technologies, LLC
    Inventor: Mark Lieberman
  • Patent number: 6852794
    Abstract: There is disclosed a pneumatic tire having a rubberized component comprising: (a) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (b) 1 to 110 phr of a polyhedral oligomeric silsesquioxanes.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: February 8, 2005
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Aaron Scott Puhala, David John Zanzig, Brian David Holden, Neil Arthur Maly
  • Patent number: 6849755
    Abstract: An organosilicon compound represented by the following general formula (1): wherein R1 is a hydrogen atom, a phenyl group or a halogenated phenyl group; R2 is a hydrogen atom or a methyl group; R3's are each a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms; X is a hydrolyzable group; Z1 is —R4—, —R4O— or —R4(CH3)2SiO—, where R4 is a substituted or unsubstituted divalent hydrocarbon group having 1 to 10 carbon atoms; Z2 is an oxygen atom or a substituted or unsubstituted divalent hydrocarbon group having 1 to 10 carbon atoms; and m is 0, 1 or 2 and n is 0, 1 or 2. When incorporated in silicone compositions, the organosilicon compound acts as a cross-linking agent having well-balanced photopolymerizability and condensation curability.
    Type: Grant
    Filed: October 26, 2001
    Date of Patent: February 1, 2005
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshiyuki Ozai, Hiroyasu Hara, Yoshifumi Inoue, Tomoyuki Goto
  • Patent number: 6846893
    Abstract: A mixture is provided comprising (a) at least one of an elastomeric thermoplastic, a non-elastomeric thermoplastic, an elastomeric thermoset and mixtures thereof, excluding polydiorganosiloxane fluids and (b) a polymer having soft polydiorganosiloxane units, hard polyisocyanate residue units, optionally, soft and/or hard organic polyamine residue units and terminal groups. The hard polyisocyanate residue and the hard polyamine residue comprise less than 50% by weight of the polydiorganosiloxane urea containing component. The polyisocyanate residue is the polyisocyanate minus the —NCO groups and the polyamine residue is the polyamine minus the —NH2 groups. The polyisocyanate residue is connected to the polyamine residue by urea linkages. The terminal groups are non-functional groups or functional groups. The polydiorganosiloxane urea containing component may be reactive under free-radical or moisture curing conditions.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: January 25, 2005
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Audrey A. Sherman, Mieczyslaw H. Mazurek, Walter R. Romanko, Patrick D. Hyde, Roy Wong, Albert I. Everaerts
  • Patent number: 6846004
    Abstract: A new adhesive coating composition, particularly for use on airbag fabrics, which is composed of a silicone polymer and an appreciable level of a copolymer of ethylene and a polar monomer, is provided. This coating provides excellent adhesive properties to the coated fabric and provides a synergistic effect such that lower gas permeability upon inflation may be obtained with this coating than might be achieved with the silicone polymer alone. Additionally, such a coating allows maximization of the adhesion characteristics on one-piece woven airbag fabric such that blistering upon high-pressure inflation can be reduced, while retaining a high degree of inflation gas retention. Fabric treated with this material in the manner described herein permits reduction in the cost of the coating itself (by reducing the use of expensive silicone polymers). Airbag fabrics and cushions, as well as methods of making and using such a novel airbag coating material are also encompassed within this invention.
    Type: Grant
    Filed: September 24, 2002
    Date of Patent: January 25, 2005
    Assignee: Milliken & Company
    Inventor: Richard Henry Parker
  • Patent number: 6833414
    Abstract: A cross-linkable fluoropolymer dispersion is described and involves a polymer product of at least one polymerizable acrylic and/or vinyl containing monomer and at least one hydrolytically stable silane containing monomer which are in the presence of an aqueous dispersion of at least one fluoropolymer. The present invention further relates to cross-linkable fluoropolymer blends wherein at least one polymer contains acrylic units, vinyl units, or both and at least one hydrolytically stable silane or silane containing group in the presence of at least one thermoplastic fluoropolymer. The silane or silane containing group can alternatively be present in the thermoplastic fluoropolymer. Methods of making the cross-linkable fluoropolymers are also described as well as products containing the cross-linkable fluoropolymer dispersions such as paints and coatings.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: December 21, 2004
    Assignee: Arkema Inc.
    Inventors: Claude C. Granel, Lotfi Hedhli, Ramin Amin-Sanayei, Kurt A. Wood
  • Publication number: 20040249075
    Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material. The crosslinking agent includes a copolymer having at least 30 mol % of alternating structural units of a residue from a donor monomer and a residue from one or more acrylic acceptor monomers. The thermosetting composition may coat a substrate by coalescing the composition to form a continuous film and curing the composition. The thermosetting composition may be included as part of a multi-component composite coating composition that includes an optional primer coat, a base coat deposited from a pigmented film-forming composition, and a transparent top coat applied over the base coat, where either the base coat, the transparent top coat, or both, are deposited from the thermosetting composition.
    Type: Application
    Filed: July 9, 2004
    Publication date: December 9, 2004
    Inventors: Karen S. Rechenberg, Simion Coca, Karen A. Barkac, James B. O'Dwyer, Linda J. Bowser
  • Patent number: 6824881
    Abstract: Thermoplastic silicon block copolymers containing (A) a hard segment polymer constituent prepared from styrene, methylmethacrylate, butylacrylate, acrylonitrile, vinyl monomers, or mixtures therefore, and (B) a soft segment polymer constituent of general formula (I) G-[(SiR2O)mSiR2—X—]n(SiR2O)mSiR2-G wherein R is an optionally halogenated monovalent C1-18 hydrocarbon radical and X is a specific aryl group-containing, silicon bonded radical, and each G may be a radical (A)-Z-(Si) or Z′-(Si) wherein -Z- represents an aryl group-containing bivalent radical and Z′- represents a monovalent aryl group-containing radical, provided that there is, at most, one radical G and one radical Z′- in formula (I). In formula (I), m represents a whole number between 1 and 1000 and n represents 0 or a whole number between 1 and 20, provided that when n does not equal 0, 4≦n·m≦1000.
    Type: Grant
    Filed: June 23, 2003
    Date of Patent: November 30, 2004
    Assignee: Wacker-Chemie GmbH
    Inventors: Hans Lautenschlager, Jochen Dauth, Wolfgang Keller, Theo Mayer, Kurt Stark
  • Patent number: 6818701
    Abstract: A golf ball includes a portion formed from a golf ball-forming composition containing at least one kind selected from a crosslinked silicone rubber powder and a crosslinked silicone resin powder. Each of the crosslinked silicone rubber powder and the crosslinked silicone resin powder has an average particle size in a range of 60 to 500 &mgr;m. The golf ball is excellent in durability against repetitive hitting and adhesiveness of a coating film, and particularly, has a good resilience and a long flight distance in both a wide temperature range and a wide hitting head speed range.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: November 16, 2004
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yasushi Ichikawa, Rinya Takesue, Eiji Takehana
  • Patent number: 6784247
    Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material. The crosslinking agent includes a copolymer having at least 30 mol % of alternating structural units of a residue from a donor monomer and a residue from one or more acrylic acceptor monomers. The thermosetting composition may coat a substrate by coalescing the composition to form a continuous film and curing the composition. The thermosetting composition may be included as part of a multi-component composite coating composition that includes an optional primer coat, a base coat deposited from a pigmented film-forming composition, and a transparent top coat applied over the base coat, where either the base coat, the transparent top coat, or both, are deposited from the thermosetting composition.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: August 31, 2004
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Karen S. Rechenberg, Simion Coca, Karen A. Barkac, James B. O'Dwyer, Linda J. Bowser
  • Patent number: 6780934
    Abstract: A room temperature-setting composition containing a polyoxyalkylene polymer (A) having a molecular weight ranging from 8000 to 50000 and having hydrolyzable silicon groups of the following formula (1): —SiXaR13−a  (1) wherein R1 is a C1-20 substituted or unsubstituted monovalent organic group, X is a hydroxyl group or a hydrolyzable group, a is 1, 2 or 3, provided that when more than one R1 group is present, the R1 groups may be the same or different, and when more than one X group is present, the X groups may be the same or different, the composition comprising, as an essential component, the polyoxyalkylene polymer, having a molecular weight ranging from 8000 to 50000 and having hydrolyzable silicon groups of formula (1), wherein a is 3, or the composition comprises a polyoxyalkylene polymer component as defined above which contains said essential specific polyoxyalkylene polymer component, and a polymer (B) made by polymerization of a polymerizable unsaturated group-containing monom
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: August 24, 2004
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takao Doi, Takashi Watabe, Tomoko Matsumoto, Tatsuo Onoguchi, Kaori Tsuruoka
  • Patent number: 6774167
    Abstract: Undesirable changes in shade brought about by low temperatures (Cold Stress Whitening) in impact-modified thermoplastic molding compositions F which comprise at least one elastomeric graft polymer A and at least one thermoplastic polymer B are reduced by adding from 10 to 200 ppm, based on the molding compositions F, of at least one polyorganosiloxane S to the impact-modified thermoplastic molding composition F.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: August 10, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Sabine Oepen, Norbert Niessner, Michael Breulmann, Norbert Güntherberg, Wil Duijzings
  • Patent number: 6761976
    Abstract: The composition comprises: an organopolysiloxane; a polymer material resistant to tearing; a first coupling agent compatible with said organopolysiloxane, and having hydroxyl first functional groups; and a second coupling agent compatible with said polymer and having second functional groups suitable for reacting with said hydroxyl first groups. Application to power accessories and cables.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: July 13, 2004
    Assignee: Nexans
    Inventors: Denis Cottevieille, Lionel Fomperie, Pascal Amigouet
  • Publication number: 20040127645
    Abstract: Disclosed is a copolymer prepared from a conjugated diene monomer and a vinyl aromatic monomer. The radial copolymer is prepared by coupling the terminal of a leaving polymer using a mixed coupling agent comprising the mixture of a multi-reactive polysiloxane and a tin halide compound, the leaving polymer being prepared by copolymerizing a conjugated diene monomer and a vinyl aromatic monomer in the presence of an organo lithium catalyst and a hydrocarbon solvent. The use of the radial copolymer improves the affinity to silica or carbon black used as a filler, and remarkably enhances processibility in the manufacture of tires as well as the properties (e.g., higher wet traction, lower rolling resistance, and higher tread wear) necessary for tires relative to the conventional products.
    Type: Application
    Filed: December 12, 2003
    Publication date: July 1, 2004
    Applicant: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Young-Hoon Ko, Jae-Young Koh, Hung-Kyu Choi, Hun-Jong Baik
  • Patent number: 6750289
    Abstract: A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: June 15, 2004
    Assignee: Shell Oil Company
    Inventors: Bridget Ann Spence, Ronald James Hoxmeier, Robert Charles Job
  • Patent number: 6737145
    Abstract: The present invention is concerned with an organic-inorganic composite graded material containing a composite material formed by chemically bonding an organic polymer compound and a metallic compound and having a component graded structure in which the content of the metallic compound continuously changes in the depth direction from the material surface, a process for the production of the above organic-inorganic composite graded material by forming a coating layer composed of a specific coating solution for forming the organic-inorganic composite film on an organic substrate and drying the coating layer under heat, a coating agent composed of the above organic-inorganic composite graded material for forming a coating film, and an article coated with the above coating agent.
    Type: Grant
    Filed: June 8, 2001
    Date of Patent: May 18, 2004
    Assignees: Ube Nitto Kasei Co., Ltd.
    Inventors: Toshiya Watanabe, Kazuhito Hashimoto, Akira Fujishima, Kazuyuki Takami, Norihiro Nakayama, Taro Suzuki, Naoki Tanaka, Eisuke Tachibana, Tatsuhiko Adachi
  • Patent number: 6716919
    Abstract: A method of using nanostructured chemicals as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are time dependent mechanical and thermal properties such as heat distortion, creep, compression set, shrinkage, modulus, hardness and abrasion resistance. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, fire resistance, and improved oxygen permeability.
    Type: Grant
    Filed: March 26, 2001
    Date of Patent: April 6, 2004
    Assignee: Hybrid Plastics
    Inventors: Joseph D. Lichtenhan, Joseph J. Schwab, Andre Lee, Shawn Phillips
  • Patent number: 6713532
    Abstract: Solid blends of rubbery polymers and amorphous or crystalline polymers, said blends being free-flowing at temperatures lower than the glass transition temperature or crystalline melting temperature of the amorphous or crystalline polymer, are prepared by intimate mixing procedures. In general, said mixing conditions include high shear conditions sufficient to convert polymer A to dispersed particles coated with polymer B and produce a free-flowing powder blend.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: March 30, 2004
    Assignee: General Electric Company
    Inventors: Navjot Singh, Joseph Michael Anostario
  • Patent number: 6703446
    Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x  (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylam
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: March 9, 2004
    Assignee: FMC Corporation, Lithium Division
    Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 6699939
    Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x  (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylam
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: March 2, 2004
    Assignee: FMC Corporation, Lithium Division
    Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 6677279
    Abstract: The invention relates to a variety of uses for novel carbon monoxide containing polymers. More specifically, the invention employs the use of low molecular weight polymers containing carbon monoxide for use as adhesive additives and as fluids (e.g., solvents and synthetic base stocks).
    Type: Grant
    Filed: February 7, 2003
    Date of Patent: January 13, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Abhimanyu Onkar Patil, Donald Norman Schulz, Michael Gerard Matturro, Richard Henry Schlosberg
  • Patent number: 6670421
    Abstract: A polymeric composition and process for making the same suitable for injection molding processes and procedures containing an olefinic polymer component selected from at least one a group which includes polyalkylenes, copolymers of polyalkylenes and a thermoplastic polyamide. The polyamide and olefinic polymeric components are present in random orientable locations in the initial polymeric composition. When injection molded against a temperature gradient, the resulting workpiece composed of the composition has distinctive regions of elevated polyamide concentration proximate the outwardly oriented surface and distinctive regions of elevated olefinic polymeric concentration proximate to interior regions of the workpiece.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: December 30, 2003
    Assignee: ACI Technologies, LLC
    Inventor: Mark Lieberman
  • Patent number: 6660807
    Abstract: An additive for organic resin comprising a powder comprising (A) a liquid organopolysiloxane having at least 0.001 wt % of silicon-bonded hydrogen atoms and at least 50 dimethylsiloxy repeating units and (B) an inorganic powder; and an organic resin comprising the additive.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: December 9, 2003
    Assignee: Dow Corning Toray Silcone Co., Ltd.
    Inventors: Yoshitsugu Morita, Haruhiko Furukawa, Koji Shiromoto, Hiroshi Ueki
  • Patent number: 6649722
    Abstract: This invention is directed to ophthalmic materials and ophthalmic lenses that are a co-polymerization product of a (a) hydrophilic monomer with (b) a tris(siloxy)silyl group-containing monomer, (c) a wide variety of hydrophobic monomers (both aliphatic and aromatic) and usually a (d) polyfluorinated monomer, as well as optional monomers or monomer mixtures that can include a cationic monomer, a non-aromatic hydrophobic monomer and a poly(dimethylsiloxy)silyl group-containing monomer. A contact lens prepared from such a co-polymer exhibits enhanced water content, while maintaining exceptional oxygen permeability, thereby providing a lens that can be worn comfortably for prolonged periods of time. A process for the preparation of such lenses is also disclosed.
    Type: Grant
    Filed: December 6, 2000
    Date of Patent: November 18, 2003
    Assignee: Novartis AG
    Inventors: Howard S. Rosenzweig, Michael H. Quinn, Robert Tucker, Greg Carlson, Gerardo J. Ocampo
  • Patent number: 6645638
    Abstract: A silicone rubber adhesive composition comprising (A) a heat curable organopolysiloxane composition of the addition curing type or peroxide curing type, (B) reinforcing silica fines, (C) an adhesive agent, and (D) a compound having at least one ester group in a molecule is easily moldable within a short time by injection molding, suitable in primerless molding, and bondable with various thermoplastic resins. Integrally molded articles in which the silicone rubber adhesive composition is firmly bonded to the thermoplastic resin are obtainable without a need for modification of the resin.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: November 11, 2003
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Syuuichi Azechi
  • Patent number: 6639015
    Abstract: A coating liquid for forming a silica-containing film with a low-dielectric constant, which enables the formation of a low-density film having a dielectric constant as low as 3 or less and having excellent resistance to oxygen plasma and process adaptation but also in the adhesion to a substrate and film strength, is provided. The coating liquid for forming a silica-containing film with a low-dielectric constant comprises a polymer composition mainly constituted by (i) a polysiloxane and (ii) a readily decomposable resin, said polysiloxane being a reaction product between fine particles of silica and a hydrolyzate of at least one alkoxysilane represented by the following formula (I): XnSi(OR)4−n  (I),  wherein X represents a hydrogen atom, a fluorine atom, an unfluorinated or fluorinated alkyl group of 1 to 8 carbon atoms, an aryl group or a vinyl group; R represents a hydrogen atom, an alkyl group of 1 to 8 carbon atoms, an aryl group or a vinyl group; and n is an integer of 0 to 3.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: October 28, 2003
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Akira Nakashima, Michio Komatsu
  • Patent number: 6617021
    Abstract: An adhesive composition for semiconductor devices contains as essential components (A) epoxy resin, (B) phonolic resin, (C) epoxidized styrene-butadiene-styrene block copolymer and (D) diaminosiloxane compound. The adhesive composition is excellent in heat resistance, thermal cycle test and humidity resistance. An adhesive sheet employing the above adhesive composition is also provided.
    Type: Grant
    Filed: February 11, 2002
    Date of Patent: September 9, 2003
    Assignee: Tomoegawa Paper Co., Inc.
    Inventors: Masaharu Kobayashi, Osamu Oka, Yasuhiro Yoshii
  • Patent number: 6602964
    Abstract: Disclosed herein is a composition comprising: A) a moisture curable polymer selected from the group consisting of silylated polyurethanes, silylated polyethers, and mixtures thereof, and B) a silicone oligomer of the formula: [R3SiO1/2]m[O1/2Si(R)2O1/2]n[SiO3/2R]o[SiO4/2]p  (I) wherein: each R is independently selected from the group consisting of B, R1, —OR2, R3, and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by a Si—C bond; each R1 is independently a saturated or aromatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1 or an acyl group; each R3 is independently a monovalent organic group containing an aliphatic unsaturated hydrocarbon group; each R4 is a monovalent organic group linked to the Si atom of the siloxane oligomer backbone by a Si—C bond that does not include an aliphatic unsaturated hydrocarbon group and that has there
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: August 5, 2003
    Assignee: Crompton Corporation
    Inventors: Misty Huang, Richard E. Handel, Herbert Petty
  • Patent number: 6602953
    Abstract: A polyoxymethylene resin composition is provided which comprises a polyoxymethylene resin (A), a silicone compound-grafted polyolefinic resin (B-1) and a silicone compound (B-2), the amount of the silicone compound-grafted polyolefinic resin (B1) being 0.05 to 10 parts by weight on the basis of 100 parts by weight of the polyoxymethylene resin (A), and the ratio of (B1)/(B2) by weight in the composition being 99/1 to 70/30.
    Type: Grant
    Filed: June 29, 2001
    Date of Patent: August 5, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Mitsuhiro Horio, Yuuji Yoshinaga
  • Patent number: 6596402
    Abstract: Coatings are formed by applying to article a copolymer of a water soluble base polymer having graft polymerized thereto an organic moiety that includes a group that reacts with water to form a silanol group, and then curing the copolymer to form a crosslinked hydrogel coating that is absorbent, lubricious and substantially non-water soluble. Coating compositions, coated articles the subject coatings are also described.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: July 22, 2003
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Dave Soerens, Sohail Malik, Cameron G. Rouns, Sharon L. Greene, Archel A. Ambrosio
  • Publication number: 20030130424
    Abstract: A golf ball includes a portion formed from a golf ball-forming composition containing at least one kind selected from a crosslinked silicone rubber powder and a crosslinked silicone resin powder. Each of the crosslinked silicone rubber powder and the crosslinked silicone resin powder has an average particle size in a range of 60 to 500 &mgr;m. The golf ball is excellent in durability against repetitive hitting and adhesiveness of a coating film, and particularly, has a good resilience and a long flight distance in both a wide temperature range and a wide hitting head speed range.
    Type: Application
    Filed: December 23, 2002
    Publication date: July 10, 2003
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventors: Yasushi Ichikawa, Rinya Takesue, Eiji Takehana
  • Patent number: 6590032
    Abstract: A thermoplastic resin composition comprising (A) 100 weight parts thermoplastic resin, (B) 0.1 to 100 weight parts of a mixture of (b-1) thermoplastic resin and (b-2) polyorganosiloxane that has a viscosity at 25° C. of at least 1,000,000 mPa·s, and (C) 0.1 to 100 weight parts polyorganosiloxane-bonded thermoplastic resin in which (c-1) thermoplastic resin and (c-2) polyorganosiloxane are chemically bonded to each other.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: July 8, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Haruhiko Furukawa, Koji Shiromoto, Hiroshi Ueki, Yoshitsugu Morita
  • Patent number: 6579941
    Abstract: An adhesive construction, characterized by excellent converting and adhesive performance, comprises a facestock, a face-side adhesive (FSA) in contact with a first surface of the facestock, and a liner-side adhesive (LSA) in contact with the FSA. The FSA is compounded with an organopolysiloxane or modified organopolysiloxane. Single layer constructions, and multilayer constructions comprising more than two adhesive layers, and unique adhesive compositions, are also provided. The constructions can be run in high-speed converting presses and adhere well to a variety of substrates.
    Type: Grant
    Filed: June 12, 2000
    Date of Patent: June 17, 2003
    Assignee: Avery Dennison Corporatoin
    Inventors: Yukihiko Sasaki, Jesse C. Ercillo, Le Hoa Hong
  • Patent number: 6576082
    Abstract: The present invention provides a primer composition comprising (A) a vinyl polymer having a main chain substantially comprising vinyl copolymer chain and at least one silicon-containing group having a hydroxy group or a hydrolyzable group bonded to a silicon atom and capable of crosslinking by forming a siloxane bond at the terminal end of the main chain and/or side chain, and (B) (a) a saturated hydrocarbon polymer having at least one silicon-containing group having a hydroxy group or a hydrolyzable group bonded to a silicon atom and capable of crosslinking by forming a siloxane bond, and/or (b) a polybutadiene polymer having at least one silicon containing group having a hydroxy group or a hydrolyzable group bonded to a silicon atom and capable of crosslinking by forming a siloxane bond, which can remarkably improve the adhesion to various kinds of substrates, and which is particularly useful when applied to the isobutylene series sealing material.
    Type: Grant
    Filed: March 8, 2001
    Date of Patent: June 10, 2003
    Assignee: Kaneka Corporation
    Inventors: Toshihiko Okamoto, Junji Takase
  • Patent number: 6569942
    Abstract: There is disclosed a rubber composition comprising: (A) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (B) 1.5 to 50 phr of a silicon coupled oligomer of the formula: where R1 and 2 are individually selected from the group consisting of where R3 is selected from the group consisting of alkyls having 1 or 4 carbon atoms; w is an integer of from 9 to 149, x is an integer of from 1 to 100, y is an integer of from 1 to 100, and z is an integer of from 1 to 100 with the proviso that the sum total of x, y and z in each R1 and R2 ranges from 3 to 100.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: May 27, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Marc Weydert, Wolfgang Lauer, Friedrich Visel, Rene Jean Zimmer, Francois Kayser
  • Patent number: 6555620
    Abstract: The addition of a compound containing an aliphatically unsaturated bond as a storage stability improver to a hydrosilylating addition reaction type hardenable electrically-conductive composition comprising at least one alkenyl group-containing isobutylene polymer which can undergo hydrosilylation reaction per molecule and an electrical conductivity-providing material makes it possible to obtain an electrically-conductive composition having an excellent storage stability at high temperatures. Further, the use of such an electrically-conductive composition makes it possible to provide an electrically-conductive roller having an excellent productivity and processability and an excellent stability of electrical properties against environmental change.
    Type: Grant
    Filed: December 31, 2001
    Date of Patent: April 29, 2003
    Assignee: Kaneka Corporation
    Inventors: Takao Manabe, Masashi Sakaguchi