Solid Polymer From Ethylenic Reactants Only Is Derived From Unsaturated Hydrocarbon Patents (Class 525/106)
  • Publication number: 20090326077
    Abstract: The present invention pertains to polyisobutylene urethane, urea and urethane/urea copolymers, to methods of making such copolymers and to medical devices that contain such polymers. According to certain aspects of the invention, polyisobutylene urethane, urea and urethane/urea copolymers are provided, which comprise a polyisobutylene segment, an additional polymeric segment that is not a polyisobutylene segment, and a segment comprising a residue of a diisocyanate. According to other aspects of the invention, polyisobutylene urethane, urea and urethane/urea copolymers are provided, which comprise a polyisobutylene segment and end groups that comprise alkyl-, alkenyl- or alkynyl-chain-containing end groups.
    Type: Application
    Filed: June 26, 2009
    Publication date: December 31, 2009
    Applicant: Cardiac Pacemakers, Inc.
    Inventors: Shrojalkumar Desai, Marlene C. Schwarz, Mark Boden, Mohan Krishnan, Michael C. Smith, Frederick H. Strickler, Daniel J. Cooke
  • Patent number: 7635730
    Abstract: The invention provides a golf ball material which includes, in mixture: (A) a metal-containing chelating agent (A1) or a mixture (A2) composed of a metal-containing chelating agent and an oxygen-containing inorganic metal compound; (B) one or more polymers selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers; and (C) one or more acid-containing polymers having an acid content of from 0.5 to 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic acid anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made with the material.
    Type: Grant
    Filed: December 29, 2006
    Date of Patent: December 22, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Publication number: 20090306283
    Abstract: Monocomponent water-hardening adhesive/sealant compositions comprising mixtures of at least one silane-functional polyoxyalkylene prepolymer and at least one silane-functional polyolefin are described. These compositions may optionally comprise other nonpolar plasticizers, as well as catalysts, fillers, and adhesives. Such adhesive/sealant compositions exhibit outstanding adhesion to plastic substrates and to painted surfaces, whereby the adhesion is maintained even after storage in wet conditions.
    Type: Application
    Filed: June 12, 2009
    Publication date: December 10, 2009
    Inventors: Matthias Kohl, Manfred Probster
  • Publication number: 20090263631
    Abstract: This invention provides a film forming composition for nanoimprinting, which has excellent resistance to etching with oxygen gas, can prevent the separation of a transfer pattern, can eliminate a problem of a holing time on a substrate, and is also excellent in transferability, and photosensitive resist, a nanostructure, a method for pattern formation using the same, and a program for realizing the method for pattern formation. The film forming composition for nanoimprinting comprises a polymeric silicon compound having the function of causing a photocuring reaction. Preferably, the polymeric silicon compound has a functional group cleavable as a result of response to electromagnetic waves and causes a curing reaction upon exposure to electromagnetic waves. More preferred are siloxane polymer compounds, silicon carbide polymer compounds, polysilane polymer compounds, and silazane polymer compounds, or any mixture thereof.
    Type: Application
    Filed: August 28, 2006
    Publication date: October 22, 2009
    Applicant: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Yoshinori Sakamoto, Naoki Yamashita, Kiyoshi Ishikawa
  • Patent number: 7601781
    Abstract: The present invention has for its object to provide a curable composition which, despite its low viscosity, gives a cured product with a high gel fraction, low residual tack, low modulus, high elongation and good flexibility. The present invention relates to a curable composition comprising the following two components: (A) a vinyl polymer having at least one crosslinking silyl group on the average per molecule: and (B) a photocurable substance, (C) an air oxidation-curable substance, (D) a high molecular plasticizer, (E) a reactive plasticizer or (F) a compound having one silanol group in its molecule and/or a compound capable of reacting with moisture to give a compound having one silanol group in the molecule.
    Type: Grant
    Filed: March 17, 2008
    Date of Patent: October 13, 2009
    Assignee: Kaneka Corporation
    Inventors: Masayuki Fujita, Nobuhiro Hasegawa, Yoshiki Nakagawa
  • Publication number: 20090221753
    Abstract: Provided in one aspect is a method of melt blending comprising providing an extruder possessing addition points from a zero point to a 100 point the length of the extruder; adding at least one thermoplastic and at least one curable polymer at the zero to 10 point of the extruder; adding at least one silicone hydride at the 5 to 30 point of the extruder; adding at least one metal catalyst at the 20 to 60 point of the extruder, with the proviso that the metal catalyst is added at least 5 points farther down the extruder than the silicone hydride. Provided in another aspect is a hydrosilylation curative composition comprising a silicone hydride having the formula wherein H is hydrogen, and each R? is independently selected from hydrogen and C1 to C10 alkyl groups; R? is selected from C1 to C10 alkyl groups; n is an integer from 5 to 45; and m is an integer from 5 to 45.
    Type: Application
    Filed: February 29, 2008
    Publication date: September 3, 2009
    Inventors: Tonson Abraham, Edward Blok, Kuo-Shein Shen, Norman Glenn Barber
  • Patent number: 7581505
    Abstract: The present invention involves a process for caulking a ship deck includes the steps of bonding planks of tropical wood on the subdeck of said ship, sealing said planks through the application of a moisture curable sealing composition, and allowing said composition to cure during an effective period of time, characterized in that said moisture curable sealing composition comprises one or more silyl-modified polyacrylate(s).
    Type: Grant
    Filed: November 16, 2005
    Date of Patent: September 1, 2009
    Inventors: Marcel I'Abee, Petrus Johannes Cornelius Vosters, Petrus Wilhelmus Johannes Van Beers
  • Patent number: 7553899
    Abstract: The present invention provides a flame retardant resin composition comprising the following component (A), component (B), component (C) and component (D), in which 0.1 to 50 parts by mass of the component (B), 0.001 to 30 parts by mass of the component (C) and 0.1 to 50 parts by mass of the component (D) are blended with 100 parts by mass of the component (A). Component (A): A rubber-modified styrene resin obtained by (co)polymerizing an aromatic vinyl compound or an aromatic vinyl compound and another vinyl monomer copolymerizable with the aromatic vinyl compound in a presence of a rubber-like polymer; Component (B): A thermally expandable graphite; Component (C): A layered clay material modified by a water-soluble polymer; and Component (D): At least one selected from the group consisting of silicone compounds, boron oxides, aminotriazine sulfate compounds and aminotriazine compounds. The resin composition is excellent in flame retardance and impact resistance.
    Type: Grant
    Filed: June 3, 2005
    Date of Patent: June 30, 2009
    Assignees: Techno Polymer Co., Ltd., LG Chem, Ltd.
    Inventors: Masaaki Mawatari, Sung-Ho Lee, Young-Ho Choi
  • Patent number: 7553904
    Abstract: A method of using olefin containing nanostructured chemicals and silanol containing nanostructured chemicals as high temperature resins is described. Vinyl containing nanostructured chemicals are particularity effective in thermosets as they control the motions of polymer chains, and segments, at the molecular level. Silanol containing nanostructured chemicals are particularity effective in thermosets containing polar groups as the silanol can enhance the reactivity of these groups. Because of their tailorable compatibility with fluorinated polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending and polymerization processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are heat distortion and flammability characteristics, permeability, optical properties, texture, feel and durability.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: June 30, 2009
    Assignee: Hybrid Plastics, Inc.
    Inventors: Joseph D. Lichtenhan, Qibo Liu, Yan-Jyh Lee, Xuan Fu, Sukhendu Hait, Joseph J. Schwab, Rusty L. Blanski, Patrick N. Ruth
  • Patent number: 7541401
    Abstract: Disclosed herein is an impact modifier for a polymer composition and a method of preparing the same. The impact modifier includes a core comprising a polyorganosiloxane, an acrylate polymer and a styrenic polymer; and a shell generally surrounding the core, the shell comprising a polymer attached to the core. The method includes providing a silicone rubber particle; adding a polymerizable styrenic compound into the silicone rubber particle; polymerizing the polymerizable styrenic compound within the particle to provide a styrenic polymer; adding a polymerizable acrylic compound into the silicone rubber particle; polymerizing the polymerizable acrylic compound within the silicone rubber particle to provide an acrylate polymer; and grafting a polymerizable compound onto the silicone rubber particle to provide a shell substantially surrounding the silicone rubber particle comprising the styrenic polymer and the acrylate polymer.
    Type: Grant
    Filed: December 28, 2005
    Date of Patent: June 2, 2009
    Assignee: Cheil Industries Inc.
    Inventors: Han Su Lee, Byeong Do Lee, Sung Sig Min, Byung Choon Lee
  • Patent number: 7537712
    Abstract: An electrically conductive silicone rubber composition comprises, at least, (A) 100 parts by weight of an organopolysiloxane having at least two alkenyl groups per molecule, (B) an organopolysiloxane having at least two silicon-bonded hydrogen atoms per molecule (an amount sufficient to cure the present composition), (C) a platinum based catalyst (an amount sufficient to promote the cure of the present composition), (D) 50 parts by weight to 5,000 parts by weight of a metal based electrically conductive filler, and (E) 5 parts by weight to 500 parts by weight of spherical silicone rubber particles with a surface active agent content of not more than 0.3 wt %.
    Type: Grant
    Filed: March 3, 2003
    Date of Patent: May 26, 2009
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Ryoto Shima, Kazumi Nakayoshi, Hiroki Ishikawa
  • Publication number: 20090131591
    Abstract: Moisture curable alkoxysilyl-functional polymers crosslinkable to elastomers having improved recovery properties are prepared by incorporating in the curable composition, both an aminoalkylalkoxysilane and an epoxyalkylalkoxysilane.
    Type: Application
    Filed: May 14, 2007
    Publication date: May 21, 2009
    Applicant: WACKER CHEMIE AG
    Inventors: Wolfram Schindler, Elke Schwiebacher
  • Patent number: 7514505
    Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.
    Type: Grant
    Filed: August 3, 2005
    Date of Patent: April 7, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 7476708
    Abstract: A tire with a rubber containing component compound of a copolymer rubber having pendant hydroxyl groups; and a non-sulfur containing silane.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: January 13, 2009
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Georges Marcel Victor Thielen, Frank Schmitz
  • Patent number: 7465777
    Abstract: The present disclosure relates to hybrid polymers, methods of making such hybrid polymers, and medical devices that include the hybrid polymers. Such hybrid polymers are suitable for forming biomaterials in a predetermined shape for use in medical devices and medical device components. The hybrid polymers of the present disclosure are formed through a reactive extrusion process prior to being formed into the predetermined shape of the medical device or medical device component.
    Type: Grant
    Filed: March 2, 2006
    Date of Patent: December 16, 2008
    Assignee: Boston Scientific Scimed, Inc.
    Inventors: Michele L. Zoromski, Liliana L. Atanasoska, Robert W. Warner
  • Patent number: 7449521
    Abstract: The present invention provides an acrylic elastomer composition including an acrylic elastomer (A) and a polyorganosiloxane-containing graft polymer (B), and having excellent formability and mechanical physical properties, and both low-temperature characteristics and oil resistance. Acrylic rubber and an acrylic block copolymer can be used as the acrylic elastomer (A).
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: November 11, 2008
    Assignee: Kaneka Corporation
    Inventors: Kentaro Takesada, Takao Manabe
  • Publication number: 20080269362
    Abstract: The recycled thermosetting flour composites and method for preparing the same are disclosed. The silane coupling agent is used as a coincidental bridge between recycled thermosetting flour and plastic materials, to apparently promote the mechanical properties of composites by linking with each other. As a result, the recycled polyolefin and recycled thermosetting flour are applied through interfacial modification, coupling, modification, mixing and granulating process to generate a composite with better mechanical properties and recycle the resource.
    Type: Application
    Filed: February 19, 2008
    Publication date: October 30, 2008
    Applicant: FAR EAST UNIVERSITY
    Inventors: Chen-Feng Kuan, Chia-Hsun Chen, Min-Chi Chung, Hsu-Chiang Kuan, Kun-Chang Lin, Hsin-Chin Peng
  • Patent number: 7432327
    Abstract: A composition made from a transparent polysiloxane-polycarbonate copolymer and styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate, the composition being transparent. A thin-walled article may be made from such a composition. A transparent composition made by combining a transparent polysiloxane-polycarbonate copolymer with styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate, to produce a transparent composition. An article made by forming a transparent composition comprising a transparent polysiloxane-polycarbonate copolymer, styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate into an article.
    Type: Grant
    Filed: December 30, 2004
    Date of Patent: October 7, 2008
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Katherine Glasgow, Naresh Alle
  • Publication number: 20080241532
    Abstract: The invention relates to a composition for yarns, fibres or filaments which can be deposited on these yarns, fibres or filaments in order to improve the properties of these yarns, fibres or filaments, in particular the resistance to abrasion. The invention also relates to a process for producing these yarns, fibres or filaments, and also to a rope comprising these yarns, fibres or filaments, and to their use.
    Type: Application
    Filed: January 20, 2005
    Publication date: October 2, 2008
    Inventors: Christian Wattenhofer, Paul Schaffner
  • Patent number: 7422796
    Abstract: Disclosed are films comprising highly neutralized blends of ethylene acid copolymers, organic acid salts and ethylene containing polymers (e.g. ethylene/alkyl (meth)acrylate copolymers) and/or silicon-containing polymers to provide high oxygen permeability values (OPV). Such polymeric film and polymeric film structures have improved oxygen permeability and desirable water vapor transmission, formability, and structural strength to be useful in wrapping food products requiring breathable films such as case ready meat, fish, sausage, fresh produce, and the like.
    Type: Grant
    Filed: July 19, 2005
    Date of Patent: September 9, 2008
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: John Chu Chen
  • Publication number: 20080207430
    Abstract: The present invention pertains to a method for producing a polysilane-polycarbosilane copolymer solution, which comprises the preparation of a polysilane, obtained by the disproportionation of a methylchlorodisilane or a mixture of methylchlorodisilanes of the formula Si2MenCl6-n with a Lewis base as the catalyst, a subsequent thermal crosslinking of the polysilane to form an infusible polysilane-polycarbosilane copolymer that is soluble in inert solvents, as well as the production of said solution by the dissolution of the polysilane-polycarbosilane copolymer in an inert solvent. In addition, the present invention also pertains to a method for producing oxygen-depleted ceramic fibers and other molded bodies having a composition similar to that of SiC.
    Type: Application
    Filed: May 2, 2005
    Publication date: August 28, 2008
    Inventors: Jurgen Clade, Erich Seider, Dieter Sporn, Erika Brendler, Thomas Lange, Gerhard Roewer, Dorit Meinhold
  • Patent number: 7417089
    Abstract: This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, wherein the article has improved tensile strength and improved tear strength, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an ether moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy) silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold.
    Type: Grant
    Filed: October 12, 2006
    Date of Patent: August 26, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Michael Joseph Rachita, Vanessa Marika Guscoff, Lawson Gibson Wideman
  • Publication number: 20080161463
    Abstract: This invention relates to novel free-flowing filler compositions containing silated cyclic core polysulfide coupling agents, and to a rubber containing the filler composition.
    Type: Application
    Filed: December 28, 2006
    Publication date: July 3, 2008
    Inventors: Richard W. Cruse, W. Michael York, Eric R. Pohl, Prashant Joshi
  • Patent number: 7388038
    Abstract: The present invention has for its object to provide a curable composition which, despite its low viscosity, gives a cured product with a high gel fraction, low residual tack, low modulus, high elongation, and good flexibility. The present invention relates to a curable composition comprising the following two components: (A) a vinyl polymer having at least one crosslinking silyl group on the average per molecule: and (B) a photocurable substance, (C) an air oxidation-curable substance, (D) a high molecular plasticizer, (E) a reactive plasticizer or (F) a compound having one silanol group in its molecule and/or a compound capable of reacting with moisture to give a compound having one silanol group in the molecule.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: June 17, 2008
    Assignee: Kaneka Corporation
    Inventors: Masayuki Fujita, Nobuhiro Hasegawa, Yoshiki Nakagawa
  • Publication number: 20080138634
    Abstract: Stable blend compositions composed of mixtures of polysiloxane(s) and organic polymer(s) are claimed. These polymer blends are white and opaque indicating the presence of phase separation on the micron scale. Such blends can be stored for long periods of time (years) without exhibiting evidence of macroscopic phase separation. These stable blends are achieved without substantial crosslinking as evidenced by the fact that the polymer blend is readily dissolved in a suitable organic solvent for molecular weight characterization. The stable blends of the present invention have particular utility as fouling release coatings for marine applications.
    Type: Application
    Filed: July 25, 2007
    Publication date: June 12, 2008
    Inventors: Joseph P. Morris, Samuel P. Gido, Jimmy W. Mays
  • Patent number: 7375162
    Abstract: Filled propylene polymer compositions having significantly improved melt strength are provided. The compositions are blends of propylene polymer, mineral filler with an ethylene polymer component consisting of an ethylene plastomer and a silane-containing ethylene polymer.
    Type: Grant
    Filed: November 30, 2005
    Date of Patent: May 20, 2008
    Assignee: Equistar Chemicals, LP
    Inventors: Jeffrey J. Strebel, Sameer D. Mehta, Jeffrey A. Jones
  • Patent number: 7375170
    Abstract: Since the majority of conventional organic/inorganic composite materials are obtained by mechanical blending of a silsesquioxane and an organic polymer or other means, it was extremely difficult to control the structure of the composite as a molecular agglomerate. In order to solve such a problem, the invention is to provide a silicon compound represented by Formula (1). This novel silicon compound has a living radical polymerization initiating ability for addition polymerizable monomers of a wide range.
    Type: Grant
    Filed: December 27, 2005
    Date of Patent: May 20, 2008
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Hisao Oikawa, Mikio Yamahiro, Koji Ohguma, Nobumasa Ootake, Kenichi Watanabe, Kohji Ohno, Yoshinobu Tsujii, Takeshi Fukuda
  • Patent number: 7368174
    Abstract: An aqueous dispersion coating for rubber and polymer substrates comprises a blend of a polysiloxane and a curable polyurethane and various additives such as a urethane crosslinking agent, a heat resistant filler, and the like. The aqueous dispersion coating reduces the noise upon contact or movement of the coated substrate with an article and maintains the initial static coefficient of friction therewith over a period of time. A desired end use is as a coating on vehicle weatherstrips such as for doors, trunks, and other enclosing articles.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: May 6, 2008
    Assignee: Lord Corporation
    Inventor: James B. Fonda
  • Patent number: 7351768
    Abstract: This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, wherein the article has improved tensile strength and improved tear strength, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an ether moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy) silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold.
    Type: Grant
    Filed: October 13, 2006
    Date of Patent: April 1, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Michael Joseph Rachita, Vanessa Marika Guscoff, Lawson Gibson Wideman
  • Patent number: 7348371
    Abstract: Cellulosic-reinforced composites having increased resistance to water absorption are provided. The improved composites are obtained using a mixture of high density polyethylene and silane copolymer with the cellulosic filler.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: March 25, 2008
    Assignee: Equistar Chemicals, LP
    Inventors: Sameer D. Mehta, Manivakkam J. Shankernarayan
  • Patent number: 7316846
    Abstract: A hard coat composition comprising an acid functional organosiloxane polyol wherein at least some of the acid functionality has been neutralized is disclosed. The hard coat is suitable for application to a substrate, and can be used without an adhesive promoting primer.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: January 8, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Shan Cheng, Brian K. Rearick, William H. Retsch, Jr.
  • Patent number: 7271218
    Abstract: This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, wherein the article has improved tensile strength and improved tear strength, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an ether moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy)silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: September 18, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, Vanessa Marika Guscoff, Michael Joseph Rachita
  • Patent number: 7256243
    Abstract: The present invention provides a novel silicon compound represented by Formula (1) having a living radical polymerization initiating ability for addition-polymerizable monomers and a polymer obtained using the same. The above polymer can provide an organic-inorganic composite material having a distinct structure. wherein R1 is hydrogen, alkyl, aryl or arylalkyl; R2 and R3 are alkyl, phenyl or cyclohexyl; and A is a group having an ability to initiate polymerization of a monomer.
    Type: Grant
    Filed: May 4, 2005
    Date of Patent: August 14, 2007
    Assignee: Chisso Corporation
    Inventors: Hisao Oikawa, Mikio Yamahiro, Kazuhiro Yoshida, Nobumasa Ootake, Kenichi Watanabe, Kohji Ohno, Yoshinobu Tsujii, Takeshi Fukuda
  • Patent number: 7247385
    Abstract: Branched copolymers of polypropylene (PP) and polysilanes are prepared by procedures involving melt phase hydrosilylation. Such branched copolymers may be formed in situ during the melt phase hydrosilylation or may be prepared by subsequent processing. The branched copolymers exhibit superior properties.
    Type: Grant
    Filed: August 11, 1999
    Date of Patent: July 24, 2007
    Assignee: University of Waterloo
    Inventors: Costas Tzoganakis, Hauke Malz
  • Patent number: 7235612
    Abstract: This invention is a method for manufacturing a polymer alloy, by making at least two resins used as components miscible, and inducing the spinodal decomposition for causing phase separation, for forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 ?m or a dispersed structure with a distance between particles of 0.001 to 1 ?m. This invention is also a polymer alloy manufactured by the method. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
    Type: Grant
    Filed: January 29, 2004
    Date of Patent: June 26, 2007
    Assignee: Toray Industries, Inc.
    Inventors: Sadayuki Kobayashi, Jiro Kumaki, Akira Hirai, Toru Nishimura
  • Patent number: 7223817
    Abstract: The present invention relates to a vinyl polymer terminated in a silanol group, a hydrolyzable silyl group or an acrylic functional group, to a method of producing a vinyl polymer having a hydrolyzable silyl group at one or more termini thereof which comprises reacting a vinyl polymer having a silanol group at one or more termini thereof with a silicon compound having two or more silicon atom-bound hydrolyzable groups, and a method of producing a vinyl polymer having an acrylic functional group at one or more termini thereof which comprises reacting a vinyl polymer having a silanol group at one or more termini thereof with a silicon compound represented by the general formula (3): XSiR2—G—O—C(O)C(L)?CH2 ??(3) wherein X is a hydrolyzable group.
    Type: Grant
    Filed: May 23, 2005
    Date of Patent: May 29, 2007
    Assignee: Kaneka Corporation
    Inventors: Yoshiki Nakagawa, Kenichi Kitano, Masayuki Fujita
  • Patent number: 7208549
    Abstract: The present invention is based upon the unexpected finding that polyisoprene rubber which is clear and of high purity can be cured utilizing the curative system of this invention to attain an elongation at break of greater than 1200% without compromising the clarity or purity of the rubber. The curative system of this invention is comprised of a carbonyl inhibited platinum catalyst, and a branched crosslinking agent having at least 2 hydrosilyl groups per molecule. The curative system of this invention can be used to cure solid polyisoprene rubber that is used in a wide variety of application and is a particular value in curing polyisoprene rubber used in manufacturing sporting goods, healthcare, and medical products.
    Type: Grant
    Filed: August 26, 2005
    Date of Patent: April 24, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, Vanessa Marika Guscoff, Michael Joseph Rachita
  • Patent number: 7195720
    Abstract: The invention provides a curable composition for a heat conductive material, having an excellent durability, a satisfactory heat conductive property and a high productivity with easily controllable surface tackiness, a heat conductive material obtained from such curable composition and a method for controlling the surface tackiness of the composition after curing. The curable composition for the heat conductive material is formed by a curable composition of heat curable type based on crosslinking by a hydrosilylation reaction and including a saturated hydrocarbon polymer containing at least an alkenyl group in a molecule, a curing agent containing at least two hydrosilyl groups in a molecule and a hydrosilylation catalyst, to which a heat conductive filler is incorporated, thereby providing a flexible elastomer with a satisfactory heat conductivity and with an easily controllable surface tackiness.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: March 27, 2007
    Assignee: Kaneka Corporation
    Inventor: Masashi Sakaguchi
  • Patent number: 7186776
    Abstract: The present invention relates to a sulfur-cross-linkable elastomeric composition that is useful for the manufacture of tires. This elastomeric composition is based on at least one isoprene elastomer (in particular natural rubber), a reinforcing inorganic filler (in particular, silica), and an (inorganic filler/isoprene elastomer) coupling agent. The coupling agent is a multifunctional polyorganosiloxane (POS), which comprises functions denoted as “Y” and “X”, wherein the Y function is at least one hydroxyl or hydrolyzable function grafted to the silicon atoms of the coupling agent and the X function is a group bearing at least one activated ethylene double bond and is grafted to the silicon atoms of the coupling agent. This POS is, in particular, a POS having an imide, acid or ester function, the ethylene double bond of which is activated by at least one adjacent carbonyl group (—C?O).
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: March 6, 2007
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Jean-Claude Tardivat, Salvatore Pagano, Christel Thonier, Nathalie Guennouni
  • Patent number: 7132170
    Abstract: An adhesive coating composition for fabric substrates, such as automotive airbags. The coating is formed from a blend including a silicone polymer and a second polymer which is thermodynamically compatible with silicone. In particular, the second polymer has a cohesion parameter (?/MPa1/2) that is similar to that of silicone so that any thermodynamic barrier to the second polymer dissolving in silicone is removed.
    Type: Grant
    Filed: July 29, 2003
    Date of Patent: November 7, 2006
    Assignee: Milliken & Company
    Inventor: Richard Henry Parker
  • Patent number: 7129294
    Abstract: A vinyl polymer which has at least one terminal functional group per molecule and has a ratio of weight average molecular weight to number average molecular weight of less than 1.8 as determined by gel permeation chromatography, said terminal functional group being a crosslinking silyl group, an alkenyl group, or a hydroxyl group.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: October 31, 2006
    Assignee: Kaneka Corporation
    Inventors: Yoshiki Nakagawa, Kenichi Kitano, Masato Kusakabe
  • Patent number: 7122599
    Abstract: The invention relates to coating compositions having anti-adhesion and dirt repellency properties, these compositions being admixed as additive with from 0.1 to 10% by weight, based on the solids content of the coating composition, of a branched polymer which possesses a weight-average molecular weight of from 2000 to 200,000 and comprises a polymeric base molecule and also polydiorganosiloxane side chains which are bonded covalently to the base molecule via Si—C bonds, have a weight-average molecular weight of between 1000 and 30,000, and whose fraction of the total weight of the branched polymer is from 5 to 25% by weight. The present invention further relates to polymeric moulding compounds having anti-adhesion and dirt repellency properties, to which this branched polymer is added as additive in an amount of from 0.1 to 10% by weight, based on the total weight of the polymeric moulding compounds.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: October 17, 2006
    Assignee: BYK-Chemie GmbH
    Inventors: Karlheinz Haubennestel, Alfred Bubat, Albert Frank, Axel Woocker, Udo Krappe
  • Patent number: 7105233
    Abstract: The invention provides for the use of organomodified polysiloxanes of the general formula (I) in which R1 independently at each occurrence is an aliphatic or aromatic C1-20 hydrocarbon radical, R2, R2* independently of one another are R1 or are aliphatic, saturated or unsaturated C1-60 hydrocarbon radicals, optionally containing functional groups, a=1 to 500, preferably <100, in particular 5 to 50, b=0 to 50, preferably <20, in particular <10, c=0 to 50, preferably 0 to 10, in particular 0 as additives for surface enhancement in polyolefins.
    Type: Grant
    Filed: August 3, 2004
    Date of Patent: September 12, 2006
    Assignee: Goldschmidt GmbH
    Inventors: Nina Bechthold, Manfred Scheiba, Stefan Stadtmüller, Markus Weimann
  • Patent number: 7081494
    Abstract: The present invention has for its object to provide a curable composition which, despite its low viscosity, gives a cured product with a high gel fraction, low residual tack, low modulus, high elongation, and good flexibility. The present invention relates to a curable composition comprising the following two components: (A) a vinyl polymer having at least one crosslinking silyl group on the average per molecule: and (B) a photocurable substance, (C) an air oxidation-curable substance, (D) a high molecular plasticizer, (E) a reactive plasticizer or (F) a compound having one silanol group in its molecule and/or a compound capable of reacting with moisture to give a compound having one silanol group in the molecule.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: July 25, 2006
    Assignee: Kaneka Corporation
    Inventors: Masayuki Fujita, Nobuhiro Hasegawa, Yoshiki Nakagawa
  • Patent number: 7067605
    Abstract: An organic polymer is provided which has an end structure expressed by general formula (1): In the formula, R1 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, or a triorganosiloxy group expressed by (R?)3SiO—. R2 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, an alkoxy group having a carbon number in the range of 1 to 20, or a triorganosiloxy group expressed by (R?)3SiO—. X represents a monovalent organic group having an epoxy group and/or an oxetanyl group. m represents an integer in the range of 0 to 20. n represents an integer of 1, 2, or 3.
    Type: Grant
    Filed: April 8, 2003
    Date of Patent: June 27, 2006
    Assignee: Kaneka Corporation
    Inventors: Yoshiyuki Kohno, Hidetoshi Odaka, Hiroshi Ando
  • Patent number: 7056987
    Abstract: The present invention refers to a process for preparing cross-linked polyolefins, comprising the steps of adding a diazido compound of the formula (I) N?N?N—X—R—X—N?N=N wherein R represents an aryl, alkyl or aralkyl group having 3 to 20 carbon atoms and X stands for —CO—, —O—CO— —SO2—, —PO2—, —PO3—, or —Si (?O)—, and a peroxide compound of the general formula (II) R1—X1—OO—X2—R2 wherein R1 and R2 are the same or different and represent hydrogen, an aryl, alkyl or aralkyl group having 3 to 20 carbon atoms and optionally comprising further peroxide groups, wherein one of R1 and R2 can form a ring, and X1 and X2 are the same or different and stand for a direct bond, —CO2— or —CO— to a polyolefin in powder or pellet form; mixing the product to obtain a mixture; extruding the mixture in an extruder at a temperature above the decomposition temperature of the diazido compound of formula (I) and of the peroxide compound of formula (II).
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: June 6, 2006
    Assignee: Borealis Technology OY
    Inventors: Kjetil Borve, Keith Redford, Aage Stori
  • Patent number: 7045572
    Abstract: An organosilicon compound represented by the following general formula (1): wherein R1 is a hydrogen atom, a phenyl group or a halogenated phenyl group; R2 is a hydrogen atom or a methyl group; R3's are each a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms; X is a hydrolyzable group; Z1 is —R4—, —R4O— or —R4(CH3)2SiO—, where R4 is a substituted or unsubstituted divalent hydrocarbon group having 1 to 10 carbon atoms; Z2 is an oxygen atom or a substituted or unsubstituted divalent hydrocarbon group having 1 to 10 carbon atoms; and m is 0, 1 or 2 and n is 0, 1 or 2. When incorporated in silicone compositions, the organosilicon compound acts as a cross-linking agent having well-balanced photopolymerizability and condensation curability.
    Type: Grant
    Filed: December 20, 2004
    Date of Patent: May 16, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshiyuki Ozai, Hiroyasu Hara, Yoshifumi Inoue, Tomoyuki Goto
  • Patent number: 7026399
    Abstract: A composition including a non-silicone material, a silicone material, and a crosslinking agent. The composition forms a structure selected from the group consisting of an interpenetrating network structure and a thermoplastic vulcanizate structure.
    Type: Grant
    Filed: September 15, 2003
    Date of Patent: April 11, 2006
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun Jin Kim, Hong Guk Jeon
  • Patent number: 7001966
    Abstract: The present invention relates to a process for preparing an isobutene polymer using a cyclopentene derivative as initiator and to the isobutene polymer obtainable by means of the process and to particular functionalization products thereof.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: February 21, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Gabriele Lang, Arno Lange, Hans Peter Rath, Helmut Mach
  • Patent number: 6998438
    Abstract: The present invention provides plastics with high toughness and the preparation thereof. The plastics with high toughness, which have the balance of stiffness and toughness, stable properties and good processability, are obtained by blending the rubber particles having an average particle size of 20 to 200 nm with the pseudoductile plastics, wherein the weight ratio of the rubber particles to the plastics is from 0.5:99.5 to 70:30. The present invention also provides plastics with both high stiffness and high toughness and the preparation thereof. The plastics with both high stiffness and high toughness, which have also an improved heat resistance and good processability, are prepared by blending the rubber particles having an average particle size of 20 to 500 nm and the crystalline plastics, wherein the amount of the rubber particles added in the plastics matrix is from 0.3 to 5 weight parts.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: February 14, 2006
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry
    Inventors: Jinliang Qiao, Shijun Zhang, Xiaohong Zhang, Yiqun Liu, Jianming Gao, Wei Zhang, Genshuan Wei, Jingbo Shao, Hua Yin, Renli Zhai, Zhihai Song, Fan Huang, Jiuqiang Li