Solid Polymer From Ethylenic Reactants Only Is Derived From Unsaturated Hydrocarbon Patents (Class 525/106)
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Patent number: 5952419Abstract: A curable organosiloxane-polyisobutylene composition comprising 20 to 87 weight percent of a polyisobutylene comprising at least 2 alkenyl groups per molecule, 0.4 to 70 weight percent of a polyorganosiloxane comprising at least 2 silicon-bonded alkenyl groups per molecule, 7 to 50 weight percent of a treated reinforcing silica filler, an amount sufficient to cure the composition of an organohydrogensiloxane crosslinker, and a platinum-group metal hydrosilation catalyst in an amount sufficient to effect curing of the composition. Cured elastomers prepared from the compositions can have improved resistance to gas and vapor permeability.Type: GrantFiled: December 10, 1998Date of Patent: September 14, 1999Assignee: Dow Corning CorporationInventors: Jon Vierling DeGroot, Jr., Carl Allen Fairbank, William James Schulz, Jr.
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Patent number: 5948865Abstract: In order to provide a crosslinking formed body having a low hardness and superior tensile characteristics and rubber properties, an ethylene-.alpha. olefin copolymer, polypropylene, and an organosilane compound are graft polymerized in the presence of a free radical generating agent to form a reaction product, the reaction product is formed into a desired shape formed body, and the formed body is crosslinked by being exposed to moisture in the presence of a silanol catalyst.Type: GrantFiled: October 8, 1997Date of Patent: September 7, 1999Assignee: Hitachi Cable, Ltd.Inventors: Yukio Shimazaki, Hideki Yagyu, Masahiro Suzuki, Norio Tanioka, Kenji Hirose
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Patent number: 5936028Abstract: An improved process for the preparation of thermoplastic elastomers by hydrosilylation crosslinking, in which a platinum containing hydrosilylation catalyst is used in combination with oil which is substantially free of materials which have the chemical behavior of a Lewis base. A crosslinked rubber component is obtained in the thermoplastic elastomer composition.Type: GrantFiled: November 1, 1996Date of Patent: August 10, 1999Assignee: Advanced Elastomer Systems, L.P.Inventors: Robert Eugene Medsker, Raman Patel, Jianqun Zhao, Gary Gilbertson
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Patent number: 5936029Abstract: The present invention provides a method of anionic synthesis of stable macrocyclic polymers that are compounded to form vulcanizable elastomeric compounds exhibiting reduced hysteresis properties. Cyclic organometallic compounds containing divalent metal atoms of Groups IIA and IIB of the Periodic System are employed as initiators of anionic polymerization of conjugated diene, vinyl aromatic and/or triene monomers. Coupling of the living ends of the resulting macrocyclic polymers or copolymers with a coupling agent or a coupling agent that is also a functionalizing agent results in stable macrocyclic polymers with improved hysteresis properties.Type: GrantFiled: September 29, 1997Date of Patent: August 10, 1999Assignee: Bridgestone CorporationInventor: James E. Hall
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Patent number: 5932649Abstract: Block copolymers are described which comprise alternating blocks of (A) a polysiloxane; and (B) a copolymer of a 1,3-conjugated diene and a monovinyl aromatic compound. The block copolymers can be prepared by reacting a polysiloxane with a dilithiated copolymer of a conjugated diene and a monovinyl aromatic compound and thereafter neutralizing the reaction product with a protonic acid or a polyfunctional alkyl silane or silicon tetrachloride. Cured elastomer compositions exhibiting surface release characteristics are obtained by curing a mixture comprising the above-described block copolymer in the presence of a curing system comprising a peroxide and sulfur. Multilayer elastomer structures useful in manufacturing articles from elastomeric materials also are described wherein at least a portion of an outer layer of the multilayer elastomer structure has release characteristics and comprises the cured block copolymers of the present invention.Type: GrantFiled: November 1, 1993Date of Patent: August 3, 1999Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Daniel F. Graves
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Patent number: 5928794Abstract: This invention relates to the preparation of an addition curable composition having self adhesion to substrates. The addition curable composition comprises an organic polymer having on average at least 1.4 alkenyl groups per molecule, a crosslinker having on average at least 1.4 hydrosilyl groups per molecule, a platinum group metal containing catalyst, an alkoxy silicon compound and a titanium compound having Ti--O--C bonds. Another embodiment of this invention is a method of adhering the addition curable composition to a substrate surface.Type: GrantFiled: December 3, 1997Date of Patent: July 27, 1999Assignees: Dow Corning GmbH, Dow Corning CorporationInventors: Robert Edward Kalinowski, Mary Kay Tomalia, Andreas Thomas Franz Wolf, Ming Hsiung Yeh
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Patent number: 5929166Abstract: The present invention relates to compounds composed essentially of a linear, cyclic or branched polyorganosiloxane having, per molecule, at least 3 siloxy units, including at least one siloxy functional unit of formula: ##STR1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical, X contains an N,N'-di- and/or trisubstituted phenylenediamine functional group, bonded to the silicon via an Si-(hydrocarbon linking unit)-N and/or Si-(hydrocarbon linking unit)-C bond, and a is a number chosen from 0, 1 and 2. The present invention also relates to the use of such compounds as antiozonants for rubbers and in particular for rubber compositions for tires.Type: GrantFiled: November 26, 1997Date of Patent: July 27, 1999Assignee: Rhone-Poulenc ChimieInventors: Yves Bomal, Philippe Karrer, Jean-Manuel Mas, Gerard Mignani
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Patent number: 5905117Abstract: A low dielectric resin composition comprising the following components (a) and (b), and the dielectric constant of a coating film formed by this composition being at most 3:(a) a resin having functional groups in its molecule and being soluble in a solvent; and(b) a partially hydrolyzed condensate of alkoxysilanes of the formula R.sup.1.sub.m R.sup.2.sub.n Si(OR.sup.3).sub.4-m-n, wherein each of R.sup.1 and R.sup.2 which may be the same or different, is a non-hydrolyzable group, R.sup.3 is an alkyl group, and m and n are integers of from 0 to 3 satisfying 0.ltoreq.m+n.ltoreq.3.Type: GrantFiled: September 19, 1996Date of Patent: May 18, 1999Assignees: Asahi Glass Company Ltd., Hitachi Chemical Co., Ltd.Inventors: Shunsuke Yokotsuka, Aya Serita, Ko Aosaki, Ikuo Matsukura, Takenori Narita, Hiroyuki Morishima, Shunichiro Uchimura
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Patent number: 5905104Abstract: The invention provides a protective coating composition for use on substrates including steel, aluminum, iron and the like. This composition further provides abrasion resistance, electrical resistance, ultra-violet protection, corrosion resistance and heat resistance. It can be particularly useful for coating high temperature stacks, mufflers, manifolds, boilers, ovens, furnaces, steam lines, heat exchangers, barbecue equipment, cooking utensils and other parts that require such powder coating composition. This composition further provides good initial adhesion.This invention also provides a powder coating composition containing a hydroxyl-functional silicone resin, a glycidyl-functional acrylic resin and an optional flow control agent.Type: GrantFiled: October 29, 1997Date of Patent: May 18, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Wayne G. Eklund, Paula Torrejon Ramos, Charles J. Torborg
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Patent number: 5902854Abstract: This invention relates to compositions comprising ethylene interplymers, such as a linear or substantially linear ethylene interpolymer and polydimethylsiloxane. The compositions have good abrasion resistance without sacrificing coefficient of friction.Type: GrantFiled: September 27, 1996Date of Patent: May 11, 1999Assignee: The Dow Chemical CompanyInventors: David C. Kelley, Jose V. Saavedra, Laura B. Weaver, John O. Bieser
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Patent number: 5891979Abstract: A cross-linkable polymer composition contains a cross-linkable polymer with hydrolysable silane groups and at least one silanol condensation catalyst. The polymer composition is distinguished by the silanol condensation catalyst being a tinorganic compound of formula (I); RSn(OH).sub.k X.sub.1 OSn(OH).sub.m X.sub.n R', wherein R and R' are hydrocarbon radicals, R' being the same as or different from R, X is a halogen, h is 1 or 2, j is 1 or 2, h+j=3, k, l, m and n are 1 or 2, k+1=2, m+n=2 and at least one of 1 and n is different from 0. Preferably, the composition contains 0.0001-3% by weight of the silanol condensation catalyst.Type: GrantFiled: July 30, 1996Date of Patent: April 6, 1999Assignee: Borealis Holding A/SInventors: Ruth Dammert, Bernt-.ANG.ke Sultan
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Patent number: 5886111Abstract: A silicone gel formulation is described having a Voland hardness of from about 6 to 20 grams, a tack of from about 17 to 35 grams, and a stress relaxation greater than 50%. The material is especially suitable for sealing the back end of connectors containing a multiple fine wires with gauges between about 14 gauge and 28 gauge. It is particularly suitable to seal the back end of an automotive connector subjected to a wide variety of harsh environmental conditions.Type: GrantFiled: March 24, 1997Date of Patent: March 23, 1999Assignee: Raychem CorporationInventors: Achilles Chiotis, Janusz Wojtowicz
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Patent number: 5883183Abstract: The present invention is directed toward anionic polymerization employing lithio amines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio amines have the general formula (A)Li(SOL)y, where SOL is a solubilizing component, A is an alkyl, dialkyl, cycloalkyl or dicycloalkyl amine radical or a cyclic amine, and y is 0 or is from about 0.5 to about 3. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.Type: GrantFiled: June 6, 1995Date of Patent: March 16, 1999Assignee: Bridgestone CorporationInventors: Takashi Kitamura, David F. Lawson, Koichi Morita, Yoichi Ozawa
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Patent number: 5880187Abstract: The present invention relates to a top coating composition having:(A) A hydroxyl-containing vinyl resin containing 40 to 90 wt. % of an aromatic hydrocarbon ring-containing vinyl monomer as a monomer component, optionally in combination with (B) a hydroxyl-containing polyester resin,(C) hexamethoxymethylmelamine and/or an etherified melamine resin obtained by substituting a part or the whole of the methoxy groups in hexamethoxymethylmelamine by an alkoxy group having at least 4 carbon atoms,(D) a particulate polymer having an average particle diameter of 0.01 to 1 .mu.m, and(E) a polysiloxane compound represented by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represent a C.sub.1-10 alkyl group, a C.sub.1-10 alkoxy group or a hydroxyl group, R.sub.5 and R.sub.6 are the same or different and each represent C.sub.1-10 alkyl group or a hydrogen atom, and n is an integer of 10 to 1,000.Type: GrantFiled: April 22, 1997Date of Patent: March 9, 1999Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kenji Kawazu, Koichi Seike, Chikara Kawamura, Hiroaki Kiyata, Hiroyuki Onoyama
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Patent number: 5861450Abstract: An additive to improve the hydrophobicity of a thermoplastic resin wherein the additive is at least 0.3 parts by weight of a thermoplastic silicone blend, said thermoplastic silicone blend having:(A) an organosilicone resin of the empirical formula(R.sub.3 Sio.sub.1/2)a (R.sub.2 SiO.sub.2/2)b (RSiO.sub.3/2)c( SiO.sub.4/2) dwherein: a and d are positive numerical values and b and c are zero or positive numerical values with the provisos that a+b+c+d=1, 0.ltoreq.(b+c).ltoreq.0.2 and the ratio of a:(b+c+d) is between about 0.3 and 1.0; and R is a monovalent radical independently selected from the group consisting of hydrogen, hydroxyl, alkyl, alkenyl, alkoxy, oximo, aryl, epoxide, carboxyl, ether, polyether, amide and alkyl amino radicals, which R groups may be the same or different, with the proviso that at least sixty mole percent of said R radicals are methyl; and(B) a predominantly linear silicone fluid having the empirical formula(R'.sub.3 SiO.sub.1/2)x (R'.sub.2 SiO.sub.2/2)y (R'SiO.sub.Type: GrantFiled: August 28, 1996Date of Patent: January 19, 1999Assignee: Dow Corning CorporationInventors: Wei Chen, Kevin Edward Lupton, David Joseph Romenesko, Randall Gene Schmidt, Hongxi Zhang
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Patent number: 5856392Abstract: The synthesis and characterization of novel higher order, multi-arm star polymers comprising polyisobutylene arms connected to condensed cyclosiloxane cores are described. The synthesis has been achieved by hydrosilating olefin-capped (e.g., allyl- or isopropenyl-terminated) polyisobutylene with hydrogencyclosiloxanes carrying a plurality of Si--H groups and simultaneously and competitively converting SiH functions, in the presence of moisture, to Si--OH groups to rapidly self-condense or react with SiH groups to form coupled cyclosiloxane cores via core-core coupling. Thus, higher order stars having many more arms than first order stars can be formed.Type: GrantFiled: May 21, 1997Date of Patent: January 5, 1999Assignee: The University of AkronInventors: Joseph P. Kennedy, Naoki Omura, Alexander Lubnin
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Patent number: 5849847Abstract: Polyalkenylaromatic-polyethylene copolymers are prepared using protected functional organolithium initiators. Polymerization of an alkenylsubstituted aromatic monomer followed by ethylene, results in a protected functional block polystyrene-co-polyethylenyllithium. Termination with a functionalizing agent followed by deprotection produces polymeric products with high functionalization at the initiating chain-end and at least partial functionalization at the terminal chain-end.Type: GrantFiled: July 29, 1996Date of Patent: December 15, 1998Assignee: FMC CorporationInventor: Roderic P. Quirk
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Patent number: 5849832Abstract: This invention relates generally to sealants for insulating glass units. More specifically, this invention is a one-component, hot applied, chemically curing sealant for edge sealing insulating glass units. The sealant contains a thermoplastic hot melt resin blended with an atmospheric curing resin. The hot melt resin functions as the meltable component during the initial application, and supplies strength immediately upon cooling. The polymer phase then begins to cure by reaction with atmospheric oxygen and/or moisture to form a cross-linked thermoset elastomer which is temperature resistant. At this point, the hot melt resin functions as an inert plasticizer within the cured polymer phase. The sealant of the present invention may additionally include plasticizers, fillers, pigments, catalysts and the like.Type: GrantFiled: October 25, 1995Date of Patent: December 15, 1998Assignee: Courtaulds AerospaceInventors: Bruce Virnelson, Pat Niega
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Patent number: 5849823Abstract: This application relates to flexible gaskets formed from blends of linear or substantially linear homogeneously branched ethylene/.alpha.-olefin interpolymers and that possess improved processability as well as low temperature resistance and resistance to staining and attack by microbes. Such gaskets do not require formulation other than the addition of color, to produce a functional product. The gaskets of the present invention do not impact negatively on the environment and are also relatively inexpensive to produce.Type: GrantFiled: September 4, 1996Date of Patent: December 15, 1998Assignee: The Dow Chemical CompanyInventors: Lawrence T. Kale, Robert R. Turley, Pradeep Jain, Lonnie G. Hazlitt
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Patent number: 5844031Abstract: A method of dispersing silicone compositions in organic thermoplastic materials is disclosed. The novel compositions produced by the method of the invention have a fine and relatively uniform dispersion or organosilicone in an organic thermoplastic. An organosilicone resin (A) and a predominantly linear silicone fluid (B) are first blended to substantial homogeneity to form an organosilicone alloy therefrom. The organosilicone alloy exhibits thermoplastic behavior and has a temperature-dependent complex viscosity .eta.*.sub.Si (T) associated therewith. Likewise the organic thermoplastic materials have a temperature-dependent complex viscosity, .eta.*.sub.OTP (T), associated therewith. The organic thermoplastic and the organosilicone alloy are thereafter mixed at a predetermined mixing temperature, T.sub.m, and a predetermined shear strain rate. The organic thermoplastic material and the organosilicone alloy are both in a flowable state at T.sub.m. The value of T.sub.m is selected to be about .+-.30.degree. C.Type: GrantFiled: August 28, 1996Date of Patent: December 1, 1998Assignee: Dow Corning CorporationInventors: Wei Chen, Hongxi Zhang, Kevin Edward Lupton, David Joseph Romenesko, Randall Gene Schmidt
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Patent number: 5840805Abstract: A highly storage-stable room-temperature-curable organopolysiloxane composition that cures to yield a product whose surface resists staining and that does not cause staining of the neighboring regions of the substrate in contact with said cured product. The organopolysiloxane composition is made from a polydiorganosiloxane, an imidazolinyl-functional organosiloxane, a filler, and a crosslinking compound which is a Si-bonded hydrolyzable group-containing organosilane or organosiloxane oligomer.Type: GrantFiled: October 25, 1995Date of Patent: November 24, 1998Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Hisataka Nakashima, Shigeki Sugiyama
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Patent number: 5840800Abstract: A crosslinked polymer dispersion comprising a preformed polymer, selected from the group consisting of silicon modified organic polymers, mixtures of silicon modified organic polymers, mixtures of silicon modified organic polymer(s) with regular organic polymers, mixtures of silicon modified organic polymer(s) with siloxane polymers, mixtures of above polymers, and mixtures of above polymer(s) with organic plasticizers or solvents.Type: GrantFiled: November 2, 1995Date of Patent: November 24, 1998Assignee: Dow Corning CorporationInventors: Eric Jude Joffre, Arthur James Tselepis, Andreas Thomas Franz Wolf
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Patent number: 5840806Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).Type: GrantFiled: January 7, 1997Date of Patent: November 24, 1998Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka
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Patent number: 5840814Abstract: The synthesis of star polymers having well-defined arms emanating from well-defined and readily controllable calix?n!arene (n=4 to 16) cores are described. The synthesis is particularly suitable for polyisobutylene and/or polysiloxane star polymers. The synthesis has been achieved using carbocationic and/or anionic ring-opening polymerization techniques to form polymer arms of desired molecular weights, then separately preparing the calixarene derivative core, and finally, linking the arms to the core by transesterification or hydrosilation.Type: GrantFiled: August 7, 1996Date of Patent: November 24, 1998Assignee: The University of AkronInventors: Istvan J. Majoros, Timea M. Marsalko, Joseph P. Kennedy
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Patent number: 5824760Abstract: A thermal transfer image-receiving sheet having a dye-receiving layer, which is excellent in reaction rate of a release agent, coating strength of a release layer and releasability from a thermal transfer sheet. The thermal transfer image-receiving sheet comprises a substrate sheet and a dye-receiving layer provided on at least one surface of the substrate sheet, wherein the dye-receiving layer contains a release agent mixture comprising an addition-polymerizable silicone and a hydrogen-modified silicone or wherein the dye-receiving layer has on its surface a release layer comprising an addition-polymerizable silicone and a hydrogen-modified silicone. The present invention relates also to a process for producing the above thermal transfer image-receiving sheets.Type: GrantFiled: June 19, 1996Date of Patent: October 20, 1998Assignee: Dai Nippon Printing Co., Ltd.Inventors: Yoshihiko Tamura, Mitsuru Tsuchiya
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Patent number: 5811193Abstract: Novel loop polymers having a polymeric backbone and a plurality of olefinic groups which have been converted to closed loops by reaction with difunctional organic compounds reactive with said olefinic groups, said olefinic groups from which the loops are formed may either be present within the backbone and/or pendent from the polymeric backbone. The loop polymers may also have hydroxy or carboxy groups which can be capped with diisocyanates or epoxies, respectively.Type: GrantFiled: May 27, 1997Date of Patent: September 22, 1998Assignee: Fluorochem, Inc.Inventor: Kurt Baum
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Patent number: 5792812Abstract: A thermoplastic resin composition comprising 100 parts by weight of a thermoplastic resin and 2 to 12 parts by weight of a thermoplastic resin oligomer containing 0.1 to 35% by weight of an aliphatic unsaturated group is molded with silicone rubber to form an integrally molded part. The thermoplastic resin composition maintains the inherent properties of the thermoplastic resin and firmly bonds with silicone rubber.Type: GrantFiled: December 26, 1995Date of Patent: August 11, 1998Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hironao Fujiki, Shigeki Shudo
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Patent number: 5792813Abstract: A fluorescent polymer having the moiety ##STR1## is disclosed. R.sub.1 and R.sub.2 are H.sub.1 alkyl, or aromatic. R.sub.3, R.sub.4, and R.sub.5 are aromatic. A preferred fluorescent composition may be formed by combining the fluorescent polymer with a second polymer, such as polystyrene or polysilystyrene.Type: GrantFiled: March 14, 1997Date of Patent: August 11, 1998Assignee: Wisconsin Alumni Research FoundationInventors: Chien-Hua Yuan, Robert C. West
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Patent number: 5773512Abstract: This invention relates to libraries of non-peptide compounds each comprised of a core structure and methods for making such libraries. This invention also relates to novel silicon-based polymer resins and silane linkers, methods for their preparation and their use in the synthesis of libraries of compounds to be screened as pharmaceutical agents.Type: GrantFiled: June 12, 1996Date of Patent: June 30, 1998Assignee: SmithKline Beecham Corp.Inventors: Balan Chenera, John Elliott, Michael Moore, Joseph Weinstock
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Patent number: 5756562Abstract: A novel silicone system comprising a methoxy terminated silane or polysiloxane, an adhesion promoter and water, useful as a filler alone or in combination with other fillers is disclosed.Type: GrantFiled: August 21, 1996Date of Patent: May 26, 1998Assignee: General Electric CompanyInventors: Michael Anthony Lucarelli, William John Raleigh
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Patent number: 5744548Abstract: A melt-extrudable thermoplastic polypropylene composition having a melt flow rate in a range of from about 18 to about 30 g/10 minutes at a temperature of 190.degree. C. and a load of 2.16 kg, a polydispersity less than 4, and a Z-average molecular weight greater than 300,000 as determined by differential refractometry. The composition may include a first thermoplastic polypropylene having a melt flow rate lower than 18 g/10 minutes at a temperature of 190.degree. C. and a load of 2.16 kg and a second thermoplastic polypropylene having a melt flow rate higher than 18 g/10 minutes at a temperature of 190.degree. C. and a load of 2.16 kg. The weight ratio of the first polypropylene to the second polypropylene is in a range of from about 90:10 to about 10:90. The composition may include from about 0.1 to about 1 percent by weight, based on the weight of the first and second thermoplastic polypropylenes, of a defined alkyl-substituted polysiloxane.Type: GrantFiled: October 30, 1996Date of Patent: April 28, 1998Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Ronald Sinclair Nohr, John Gavin MacDonald, Peter Michelovich Kobylivker
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Patent number: 5741859Abstract: The present invention relates to a method for preparing a polyisobutylene-siloxane block copolymer, said method comprising:(I) lithiating(A) a polyisobutylene having one or two terminal silanol groups with(B) an organolithium compound;(II) reacting the silanolate-functional polyisobutylene obtained in step (I) with(C) a hexaorganocyclotrisiloxane; and(III) capping the siloxanotate-functional block copolymer obtained in step (II) with a compound selected from(D) a silane having at least one hydrolyzable group or(E) an acid.Type: GrantFiled: February 3, 1997Date of Patent: April 21, 1998Assignee: Dow Corning CorporationInventors: Anil Kumar Saxena, Toshio Suzuki
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Patent number: 5733998Abstract: The dispersion polymerization of isobutylene includes a dispersing agent. The dispersing agent is a compound having a CO.sub.2 -phobic moiety and at least one CO.sub.2 -philic moiety. The CO.sub.2 -phobic moiety is polysibutylene-philic. Novel polymerization initiators are organometallic.Type: GrantFiled: March 26, 1996Date of Patent: March 31, 1998Assignee: The University of AkronInventors: Joseph P. Kennedy, Tibor Pernecker
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Patent number: 5733538Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.Type: GrantFiled: June 7, 1995Date of Patent: March 31, 1998Assignee: Thoratec Laboratories, Inc.Inventor: Judy S. Riffle
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Patent number: 5728768Abstract: This invention relates to the preparation of an addition curable composition which when cured has increased resistance to degradation by ultraviolet light. The addition curable composition comprises an organic polymer having on average at least 1.4 alkenyl groups per molecule, a crosslinker having on average at least 2 hydrosilyl groups per molecule, a platinum group metal-containing catalyst and a benzotriazole derivative stabilizer.Type: GrantFiled: December 24, 1996Date of Patent: March 17, 1998Assignee: Dow Corning CorporationInventors: Anil Kumar Saxena, Toshio Suzuki
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Patent number: 5728469Abstract: Release surfaces comprising extruded polymer-siloxane block copolymer mixtures are provided. At least one block of the copolymer is a polymer compatible with the bulk polymeric material, while a second block is polysiloxane. Coextruded release surfaces comprising two or more polymeric layers, including one layer of a polymer-siloxane block copolymer mixture, are provided. The release surfaces serve as release liners for pressure sensitive adhesive labels and tapes.Type: GrantFiled: June 6, 1995Date of Patent: March 17, 1998Assignee: Avery Dennison CorporationInventors: Roger H. Mann, Edward I. Sun, Sebastian S. Plamthottam, Charles W. Newing
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Patent number: 5717009Abstract: An adhesive composition which comprises:(A) 100 parts by weight of a polyorganosiloxane represented by the formula (I): ##STR1## (wherein R.sup.1 s may be the same or different from each other and each represent a monovalent hydrocarbon group or a halogen-substituted hydrocarbon group; and n is a positive integer);(B) 0.5 to 10 parts by weight of a tetraalkoxysilane represented by the following formula:R.sup.2.sub.a Si(OR.sup.3).sub.4-a (II)(wherein R.sup.2 represents an alkyl group having 1 to 3 carbon atoms, a phenyl group or a vinyl group; R.sup.3 represents an alkyl group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group having 3 to 6 carbon atoms; and a is 0 or 1),or a partially hydrolyzed condensate thereof; and(C) 0.1 to 15 parts by weight of a trialkoxysilane represented by the formula (III):R.sup.4 (R.sup.5).sub.b Si(OR.sup.6).sub.3-b (III)(wherein R.sup.4 represents a substituted or unsubstituted aminoalkyl group; R.sup.Type: GrantFiled: July 17, 1996Date of Patent: February 10, 1998Assignee: Toshiba Silicone Co., Ltd.Inventors: Shigeki Matsushita, Fumihiko Kobayashi
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Patent number: 5708085Abstract: There is disclosed a polyolefin composition which can be extruded at relatively high rates to provide extrudate having improved hydrophobicity, said composition comprising(A) 100 parts by weight of a polythylene resin; and(B) 1 to 5 parts by weight of an interactive diorganopolysiloxane process aid, said diorganopolysiloxane having a number average molecular weight of at least 10,000. In particularly preferred embodiments, an interactive diorganopolysiloxane in combination with a low density polyethylene is used as a process aid for linear low density polyethylene.Type: GrantFiled: August 28, 1996Date of Patent: January 13, 1998Assignee: Dow Corning CorporationInventors: Dale Earl Hauenstein, Caibao Qian, David Joseph Romenesko
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Patent number: 5703163Abstract: Novel loop polymers having a polymeric backbone and a plurality of olefinic groups which have been converted to closed loops by reaction with difunctional organic compounds reactive with said olefinic groups, said olefinic groups from which the loops are formed may either be present within the backbone and/or pendent from the polymeric backbone. The loop polymers may also have hydroxy or carboxy groups which can be capped with diisocyanates or epoxies, respectively.Type: GrantFiled: May 31, 1995Date of Patent: December 30, 1997Assignee: Fluorochem, Inc.Inventor: Kurt Baum
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Patent number: 5691399Abstract: Disclosed are sealant compositions having excellent slump and spew resistant, even at relatively high operating temperatures for electrical connectors. The sealants, which are flowable at such elevated temperatures, comprise two essential components: elastomeric thermoplastic polymer, preferably an organic polymer composite comprising diblock and triblock copolymers, and extender for the polymer. The extender may comprise a primary and a secondary extender, such as polybutene oil and mineral oil, respectively.Type: GrantFiled: May 31, 1995Date of Patent: November 25, 1997Assignee: The Whitaker CorporationInventors: Francis Frederick Koblitz, Thomas John Lynch, Ricky Charles Mellinger
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Patent number: 5681895Abstract: A high yield of three armed radial anionic polymers is produced by the process of coupling metal terminated anionic polymers with a trialkoxysilane having a silicon-hydrogen bond, preferably trimethoxysilane. The metal terminated anionic polymer is preferably produced by initiating polymerization with a protected functional initiator which is readily converted to terminal hydroxyl groups or derivatives thereof for use in adhesives, sealants, and coatings.Type: GrantFiled: August 29, 1996Date of Patent: October 28, 1997Assignee: Shell Oil CompanyInventors: Robert Charles Bening, Ronald James Hoxmeier
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Patent number: 5679414Abstract: A liquid crystal-polymer composite film comprising (1) a high-molecular weight compound containing at least one kind of monomer units providing a side chain having a liquid crystal nature and at least one kind of monomer units providing a side chain having no liquid crystal nature and (2) a low-molecular weight liquid crystal, the high-molecular weight compound (1) and the low-molecular weight liquid crystal (2) being in separate phases, and the monomer units providing a side chain having no liquid crystal nature being crosslinked; and an electro-optical element comprising a pair of substrates each having an electrode having interposed therebetween a liquid crystal-polymer composite film comprising (2) a low-molecular weight liquid crystal and (1) a high-molecular weight compound in separate phases, the substrates each having a surface comprising a material having a reactive group on the side in contact with the composite film, the reactive group being chemically bonded to the high-molecular weight compound (Type: GrantFiled: December 15, 1995Date of Patent: October 21, 1997Assignee: Fuji Xerox Co., Ltd.Inventors: Ryojiro Akashi, Masanobu Ninomiya
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Patent number: 5677066Abstract: A sealing part for connector waterproofing is disclosed, which comprises a vulcanized molding obtained from a composition comprising 100 parts by weight of a polyorganosiloxane (1), from 5 to 100 parts by weight of a reinforcing silica powder filler (2), from 0.01 to 10 parts by weight of a hydrogensiloxane polymer (3) having two or more Si-H bonds per molecule, and from 0.01 to 5 parts by weight of t-butyl peroxy-3,5,5-trimethylhexanoate (4). The sealing part for connector waterproofing of the present invention is satisfactory in heat resistance, low-temperature resistance, and oil resistance and can be produced at low cost in a reduced molding time.Type: GrantFiled: July 20, 1995Date of Patent: October 14, 1997Assignee: Yazaki CorporationInventors: Kiyotaka Okazaki, Masahiro Kanda
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Patent number: 5672660Abstract: An improved process for the preparation of thermoplastic elastomers by hydrosilylation crosslinking, in which a platinum containing hydrosilylation catalyst is used in combination with specific diene-containing rubbers. A fully crosslinked rubber component is obtained in the thermoplastic elastomer composition.Type: GrantFiled: December 1, 1995Date of Patent: September 30, 1997Assignee: Advanced Elastomer Systems, L.P.Inventors: Robert Eugene Medsker, Raman Patel
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Patent number: 5665823Abstract: The present invention relates to a method for preparing an acrylic-functional polyisobutylene polymer or copolymer, said method comprising reacting a polyisobutylene polymer or copolymer which contains at least one carbon-bonded silanol group in its molecule with a silane having both an acrylic-containing group and a silicon-bonded hydrolyzable group in its molecule.Type: GrantFiled: August 30, 1996Date of Patent: September 9, 1997Assignee: Dow Corning CorporationInventors: Anil Kumar Saxena, Toshio Suzuki
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Patent number: 5663245Abstract: The synthesis and characterization of novel multi-arm star polymers comprising polyisobutylene arms connected to a well-defined, siloxane core are described. The synthesis has been achieved by hydrosilating olefin-capped (e.g., allyl- or isopropenyl-terminated) polyisobutylene with siloxanes carrying a plurality of Si--H groups.Type: GrantFiled: March 22, 1996Date of Patent: September 2, 1997Assignee: The University of AkronInventors: Joseph P. Kennedy, Naoki Omura, Alexander Lubnin
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Patent number: 5654368Abstract: The invention is to provide elastomer-like or rubber-like, recyclable cross-linked polymers capable of being liquefied and re-molded repeatedly without detracting from the physical properties of the polymers. The polymer comprises meltable cross-linked oligomer units and linkage units via which the oligomer units are linked to construct the main chains of the polymer. Each linkage unit in the polymer comprises a chemical bond that can be cleaved and re-formed repeatedly by predetermined treatment by which the bond between monomers in the oligomer units are not cleaved. The method for producing the polymer comprises a step of forming oligomer units by polymerizing monomers, a step of forming linkage units by linking the oligomer units via linkage units and a step of forming cross-linked units between the oligomer units.Type: GrantFiled: March 1, 1996Date of Patent: August 5, 1997Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Mitsuru Nakano, Makoto Mouri, Arimitsu Usuki, Akane Okada
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Patent number: 5652307Abstract: Graft copolymers obtained by(A) polymerizing 10 to 89 wt % of a mixture consisting essentially of either(a1) from 70 to 99.89 wt % of a C.sub.1 -C.sub.18 -alkyl ester of acrylic acid,(a2) from 0.1 to 10 wt % of a polyfunctional monomer,(a3) from 0 to 29.89 wt % of an ethylenically unsaturated monomer which differs from (a1) and (a2), is copolymerizable therewith and carries no acid group and(a4) from 0.01 to 10 wt % of a copolymerizable monomer containing at least one acid groupor(a5) from 49.99 to 99.99 wt % of at least one diene,(a6) from 0 to 50 wt % of a monomer which is copolymerizable therewith and carries no acid group and(a7) from 0.01 to 10 wt % of a copolymerizable monomer containing at least one acid groupin the presence of from 1 to 80 wt % of a cross-linked silicone rubber to form a copolymer A,and(B) polymerizing 10 to 89 wt % of a mixture consisting essentially of(b1) from 50 to 99.99 wt % of a styrene compound of the formula (I) ##STR1## where R.sup.1 and R.sup.Type: GrantFiled: October 17, 1996Date of Patent: July 29, 1997Assignee: BASF AktiengesellschaftInventors: Norbert Niessner, Wolfgang Fischer
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Patent number: 5648066Abstract: Disclosed are solid silicone compositions comprising low molecular weight polyethylene solidifying agents and one or more non-volatile silicone fluids, along with a method for their preparation. The compositions are suitable for topical application to skin or hair, and are particularly useful in the preparation of novel skin treatment, hair treatment, lipstick and makeup products.Type: GrantFiled: October 3, 1995Date of Patent: July 15, 1997Assignee: Estee Lauder CompaniesInventor: George J. Stepniewski
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Patent number: 5648426Abstract: A method and composition for improving the impact resistance of thermoplastics is disclosed. An impact resistant thermoplastic is formed by forming a silicone containing thermosetting component, compounding it with a thermoplastic to form a silicone-thermoplastic mixture, disposing a catalyst on the mixture, and activating the catalyst while compounding the mixture with a thermoplastic. The silicone containing thermosetting component includes a first silicone compound containing hydride groups and a second silicone compound containing unsaturated groups. Activating the catalyst, preferably a platinum complex, causes the thermosetting component to cure, creating a silicone-thermoplastic semi-interpenetrating polymer network having higher impact resistance than the unmodified thermoplastic.Type: GrantFiled: May 5, 1995Date of Patent: July 15, 1997Assignee: Huls America Inc.Inventor: Mikhail Zolotnitsky