Solid Polymer From Ethylenic Reactants Only Is Derived From Unsaturated Hydrocarbon Patents (Class 525/106)
  • Patent number: 5952419
    Abstract: A curable organosiloxane-polyisobutylene composition comprising 20 to 87 weight percent of a polyisobutylene comprising at least 2 alkenyl groups per molecule, 0.4 to 70 weight percent of a polyorganosiloxane comprising at least 2 silicon-bonded alkenyl groups per molecule, 7 to 50 weight percent of a treated reinforcing silica filler, an amount sufficient to cure the composition of an organohydrogensiloxane crosslinker, and a platinum-group metal hydrosilation catalyst in an amount sufficient to effect curing of the composition. Cured elastomers prepared from the compositions can have improved resistance to gas and vapor permeability.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: September 14, 1999
    Assignee: Dow Corning Corporation
    Inventors: Jon Vierling DeGroot, Jr., Carl Allen Fairbank, William James Schulz, Jr.
  • Patent number: 5948865
    Abstract: In order to provide a crosslinking formed body having a low hardness and superior tensile characteristics and rubber properties, an ethylene-.alpha. olefin copolymer, polypropylene, and an organosilane compound are graft polymerized in the presence of a free radical generating agent to form a reaction product, the reaction product is formed into a desired shape formed body, and the formed body is crosslinked by being exposed to moisture in the presence of a silanol catalyst.
    Type: Grant
    Filed: October 8, 1997
    Date of Patent: September 7, 1999
    Assignee: Hitachi Cable, Ltd.
    Inventors: Yukio Shimazaki, Hideki Yagyu, Masahiro Suzuki, Norio Tanioka, Kenji Hirose
  • Patent number: 5936028
    Abstract: An improved process for the preparation of thermoplastic elastomers by hydrosilylation crosslinking, in which a platinum containing hydrosilylation catalyst is used in combination with oil which is substantially free of materials which have the chemical behavior of a Lewis base. A crosslinked rubber component is obtained in the thermoplastic elastomer composition.
    Type: Grant
    Filed: November 1, 1996
    Date of Patent: August 10, 1999
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Robert Eugene Medsker, Raman Patel, Jianqun Zhao, Gary Gilbertson
  • Patent number: 5936029
    Abstract: The present invention provides a method of anionic synthesis of stable macrocyclic polymers that are compounded to form vulcanizable elastomeric compounds exhibiting reduced hysteresis properties. Cyclic organometallic compounds containing divalent metal atoms of Groups IIA and IIB of the Periodic System are employed as initiators of anionic polymerization of conjugated diene, vinyl aromatic and/or triene monomers. Coupling of the living ends of the resulting macrocyclic polymers or copolymers with a coupling agent or a coupling agent that is also a functionalizing agent results in stable macrocyclic polymers with improved hysteresis properties.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: August 10, 1999
    Assignee: Bridgestone Corporation
    Inventor: James E. Hall
  • Patent number: 5932649
    Abstract: Block copolymers are described which comprise alternating blocks of (A) a polysiloxane; and (B) a copolymer of a 1,3-conjugated diene and a monovinyl aromatic compound. The block copolymers can be prepared by reacting a polysiloxane with a dilithiated copolymer of a conjugated diene and a monovinyl aromatic compound and thereafter neutralizing the reaction product with a protonic acid or a polyfunctional alkyl silane or silicon tetrachloride. Cured elastomer compositions exhibiting surface release characteristics are obtained by curing a mixture comprising the above-described block copolymer in the presence of a curing system comprising a peroxide and sulfur. Multilayer elastomer structures useful in manufacturing articles from elastomeric materials also are described wherein at least a portion of an outer layer of the multilayer elastomer structure has release characteristics and comprises the cured block copolymers of the present invention.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: August 3, 1999
    Assignee: Bridgestone Corporation
    Inventors: William L. Hergenrother, Daniel F. Graves
  • Patent number: 5928794
    Abstract: This invention relates to the preparation of an addition curable composition having self adhesion to substrates. The addition curable composition comprises an organic polymer having on average at least 1.4 alkenyl groups per molecule, a crosslinker having on average at least 1.4 hydrosilyl groups per molecule, a platinum group metal containing catalyst, an alkoxy silicon compound and a titanium compound having Ti--O--C bonds. Another embodiment of this invention is a method of adhering the addition curable composition to a substrate surface.
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: July 27, 1999
    Assignees: Dow Corning GmbH, Dow Corning Corporation
    Inventors: Robert Edward Kalinowski, Mary Kay Tomalia, Andreas Thomas Franz Wolf, Ming Hsiung Yeh
  • Patent number: 5929166
    Abstract: The present invention relates to compounds composed essentially of a linear, cyclic or branched polyorganosiloxane having, per molecule, at least 3 siloxy units, including at least one siloxy functional unit of formula: ##STR1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical, X contains an N,N'-di- and/or trisubstituted phenylenediamine functional group, bonded to the silicon via an Si-(hydrocarbon linking unit)-N and/or Si-(hydrocarbon linking unit)-C bond, and a is a number chosen from 0, 1 and 2. The present invention also relates to the use of such compounds as antiozonants for rubbers and in particular for rubber compositions for tires.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: July 27, 1999
    Assignee: Rhone-Poulenc Chimie
    Inventors: Yves Bomal, Philippe Karrer, Jean-Manuel Mas, Gerard Mignani
  • Patent number: 5905117
    Abstract: A low dielectric resin composition comprising the following components (a) and (b), and the dielectric constant of a coating film formed by this composition being at most 3:(a) a resin having functional groups in its molecule and being soluble in a solvent; and(b) a partially hydrolyzed condensate of alkoxysilanes of the formula R.sup.1.sub.m R.sup.2.sub.n Si(OR.sup.3).sub.4-m-n, wherein each of R.sup.1 and R.sup.2 which may be the same or different, is a non-hydrolyzable group, R.sup.3 is an alkyl group, and m and n are integers of from 0 to 3 satisfying 0.ltoreq.m+n.ltoreq.3.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: May 18, 1999
    Assignees: Asahi Glass Company Ltd., Hitachi Chemical Co., Ltd.
    Inventors: Shunsuke Yokotsuka, Aya Serita, Ko Aosaki, Ikuo Matsukura, Takenori Narita, Hiroyuki Morishima, Shunichiro Uchimura
  • Patent number: 5905104
    Abstract: The invention provides a protective coating composition for use on substrates including steel, aluminum, iron and the like. This composition further provides abrasion resistance, electrical resistance, ultra-violet protection, corrosion resistance and heat resistance. It can be particularly useful for coating high temperature stacks, mufflers, manifolds, boilers, ovens, furnaces, steam lines, heat exchangers, barbecue equipment, cooking utensils and other parts that require such powder coating composition. This composition further provides good initial adhesion.This invention also provides a powder coating composition containing a hydroxyl-functional silicone resin, a glycidyl-functional acrylic resin and an optional flow control agent.
    Type: Grant
    Filed: October 29, 1997
    Date of Patent: May 18, 1999
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Wayne G. Eklund, Paula Torrejon Ramos, Charles J. Torborg
  • Patent number: 5902854
    Abstract: This invention relates to compositions comprising ethylene interplymers, such as a linear or substantially linear ethylene interpolymer and polydimethylsiloxane. The compositions have good abrasion resistance without sacrificing coefficient of friction.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 11, 1999
    Assignee: The Dow Chemical Company
    Inventors: David C. Kelley, Jose V. Saavedra, Laura B. Weaver, John O. Bieser
  • Patent number: 5891979
    Abstract: A cross-linkable polymer composition contains a cross-linkable polymer with hydrolysable silane groups and at least one silanol condensation catalyst. The polymer composition is distinguished by the silanol condensation catalyst being a tinorganic compound of formula (I); RSn(OH).sub.k X.sub.1 OSn(OH).sub.m X.sub.n R', wherein R and R' are hydrocarbon radicals, R' being the same as or different from R, X is a halogen, h is 1 or 2, j is 1 or 2, h+j=3, k, l, m and n are 1 or 2, k+1=2, m+n=2 and at least one of 1 and n is different from 0. Preferably, the composition contains 0.0001-3% by weight of the silanol condensation catalyst.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: April 6, 1999
    Assignee: Borealis Holding A/S
    Inventors: Ruth Dammert, Bernt-.ANG.ke Sultan
  • Patent number: 5886111
    Abstract: A silicone gel formulation is described having a Voland hardness of from about 6 to 20 grams, a tack of from about 17 to 35 grams, and a stress relaxation greater than 50%. The material is especially suitable for sealing the back end of connectors containing a multiple fine wires with gauges between about 14 gauge and 28 gauge. It is particularly suitable to seal the back end of an automotive connector subjected to a wide variety of harsh environmental conditions.
    Type: Grant
    Filed: March 24, 1997
    Date of Patent: March 23, 1999
    Assignee: Raychem Corporation
    Inventors: Achilles Chiotis, Janusz Wojtowicz
  • Patent number: 5883183
    Abstract: The present invention is directed toward anionic polymerization employing lithio amines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio amines have the general formula (A)Li(SOL)y, where SOL is a solubilizing component, A is an alkyl, dialkyl, cycloalkyl or dicycloalkyl amine radical or a cyclic amine, and y is 0 or is from about 0.5 to about 3. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 16, 1999
    Assignee: Bridgestone Corporation
    Inventors: Takashi Kitamura, David F. Lawson, Koichi Morita, Yoichi Ozawa
  • Patent number: 5880187
    Abstract: The present invention relates to a top coating composition having:(A) A hydroxyl-containing vinyl resin containing 40 to 90 wt. % of an aromatic hydrocarbon ring-containing vinyl monomer as a monomer component, optionally in combination with (B) a hydroxyl-containing polyester resin,(C) hexamethoxymethylmelamine and/or an etherified melamine resin obtained by substituting a part or the whole of the methoxy groups in hexamethoxymethylmelamine by an alkoxy group having at least 4 carbon atoms,(D) a particulate polymer having an average particle diameter of 0.01 to 1 .mu.m, and(E) a polysiloxane compound represented by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represent a C.sub.1-10 alkyl group, a C.sub.1-10 alkoxy group or a hydroxyl group, R.sub.5 and R.sub.6 are the same or different and each represent C.sub.1-10 alkyl group or a hydrogen atom, and n is an integer of 10 to 1,000.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: March 9, 1999
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Kenji Kawazu, Koichi Seike, Chikara Kawamura, Hiroaki Kiyata, Hiroyuki Onoyama
  • Patent number: 5861450
    Abstract: An additive to improve the hydrophobicity of a thermoplastic resin wherein the additive is at least 0.3 parts by weight of a thermoplastic silicone blend, said thermoplastic silicone blend having:(A) an organosilicone resin of the empirical formula(R.sub.3 Sio.sub.1/2)a (R.sub.2 SiO.sub.2/2)b (RSiO.sub.3/2)c( SiO.sub.4/2) dwherein: a and d are positive numerical values and b and c are zero or positive numerical values with the provisos that a+b+c+d=1, 0.ltoreq.(b+c).ltoreq.0.2 and the ratio of a:(b+c+d) is between about 0.3 and 1.0; and R is a monovalent radical independently selected from the group consisting of hydrogen, hydroxyl, alkyl, alkenyl, alkoxy, oximo, aryl, epoxide, carboxyl, ether, polyether, amide and alkyl amino radicals, which R groups may be the same or different, with the proviso that at least sixty mole percent of said R radicals are methyl; and(B) a predominantly linear silicone fluid having the empirical formula(R'.sub.3 SiO.sub.1/2)x (R'.sub.2 SiO.sub.2/2)y (R'SiO.sub.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: January 19, 1999
    Assignee: Dow Corning Corporation
    Inventors: Wei Chen, Kevin Edward Lupton, David Joseph Romenesko, Randall Gene Schmidt, Hongxi Zhang
  • Patent number: 5856392
    Abstract: The synthesis and characterization of novel higher order, multi-arm star polymers comprising polyisobutylene arms connected to condensed cyclosiloxane cores are described. The synthesis has been achieved by hydrosilating olefin-capped (e.g., allyl- or isopropenyl-terminated) polyisobutylene with hydrogencyclosiloxanes carrying a plurality of Si--H groups and simultaneously and competitively converting SiH functions, in the presence of moisture, to Si--OH groups to rapidly self-condense or react with SiH groups to form coupled cyclosiloxane cores via core-core coupling. Thus, higher order stars having many more arms than first order stars can be formed.
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: January 5, 1999
    Assignee: The University of Akron
    Inventors: Joseph P. Kennedy, Naoki Omura, Alexander Lubnin
  • Patent number: 5849847
    Abstract: Polyalkenylaromatic-polyethylene copolymers are prepared using protected functional organolithium initiators. Polymerization of an alkenylsubstituted aromatic monomer followed by ethylene, results in a protected functional block polystyrene-co-polyethylenyllithium. Termination with a functionalizing agent followed by deprotection produces polymeric products with high functionalization at the initiating chain-end and at least partial functionalization at the terminal chain-end.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: December 15, 1998
    Assignee: FMC Corporation
    Inventor: Roderic P. Quirk
  • Patent number: 5849832
    Abstract: This invention relates generally to sealants for insulating glass units. More specifically, this invention is a one-component, hot applied, chemically curing sealant for edge sealing insulating glass units. The sealant contains a thermoplastic hot melt resin blended with an atmospheric curing resin. The hot melt resin functions as the meltable component during the initial application, and supplies strength immediately upon cooling. The polymer phase then begins to cure by reaction with atmospheric oxygen and/or moisture to form a cross-linked thermoset elastomer which is temperature resistant. At this point, the hot melt resin functions as an inert plasticizer within the cured polymer phase. The sealant of the present invention may additionally include plasticizers, fillers, pigments, catalysts and the like.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: December 15, 1998
    Assignee: Courtaulds Aerospace
    Inventors: Bruce Virnelson, Pat Niega
  • Patent number: 5849823
    Abstract: This application relates to flexible gaskets formed from blends of linear or substantially linear homogeneously branched ethylene/.alpha.-olefin interpolymers and that possess improved processability as well as low temperature resistance and resistance to staining and attack by microbes. Such gaskets do not require formulation other than the addition of color, to produce a functional product. The gaskets of the present invention do not impact negatively on the environment and are also relatively inexpensive to produce.
    Type: Grant
    Filed: September 4, 1996
    Date of Patent: December 15, 1998
    Assignee: The Dow Chemical Company
    Inventors: Lawrence T. Kale, Robert R. Turley, Pradeep Jain, Lonnie G. Hazlitt
  • Patent number: 5844031
    Abstract: A method of dispersing silicone compositions in organic thermoplastic materials is disclosed. The novel compositions produced by the method of the invention have a fine and relatively uniform dispersion or organosilicone in an organic thermoplastic. An organosilicone resin (A) and a predominantly linear silicone fluid (B) are first blended to substantial homogeneity to form an organosilicone alloy therefrom. The organosilicone alloy exhibits thermoplastic behavior and has a temperature-dependent complex viscosity .eta.*.sub.Si (T) associated therewith. Likewise the organic thermoplastic materials have a temperature-dependent complex viscosity, .eta.*.sub.OTP (T), associated therewith. The organic thermoplastic and the organosilicone alloy are thereafter mixed at a predetermined mixing temperature, T.sub.m, and a predetermined shear strain rate. The organic thermoplastic material and the organosilicone alloy are both in a flowable state at T.sub.m. The value of T.sub.m is selected to be about .+-.30.degree. C.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: December 1, 1998
    Assignee: Dow Corning Corporation
    Inventors: Wei Chen, Hongxi Zhang, Kevin Edward Lupton, David Joseph Romenesko, Randall Gene Schmidt
  • Patent number: 5840805
    Abstract: A highly storage-stable room-temperature-curable organopolysiloxane composition that cures to yield a product whose surface resists staining and that does not cause staining of the neighboring regions of the substrate in contact with said cured product. The organopolysiloxane composition is made from a polydiorganosiloxane, an imidazolinyl-functional organosiloxane, a filler, and a crosslinking compound which is a Si-bonded hydrolyzable group-containing organosilane or organosiloxane oligomer.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: November 24, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hisataka Nakashima, Shigeki Sugiyama
  • Patent number: 5840800
    Abstract: A crosslinked polymer dispersion comprising a preformed polymer, selected from the group consisting of silicon modified organic polymers, mixtures of silicon modified organic polymers, mixtures of silicon modified organic polymer(s) with regular organic polymers, mixtures of silicon modified organic polymer(s) with siloxane polymers, mixtures of above polymers, and mixtures of above polymer(s) with organic plasticizers or solvents.
    Type: Grant
    Filed: November 2, 1995
    Date of Patent: November 24, 1998
    Assignee: Dow Corning Corporation
    Inventors: Eric Jude Joffre, Arthur James Tselepis, Andreas Thomas Franz Wolf
  • Patent number: 5840806
    Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: November 24, 1998
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka
  • Patent number: 5840814
    Abstract: The synthesis of star polymers having well-defined arms emanating from well-defined and readily controllable calix?n!arene (n=4 to 16) cores are described. The synthesis is particularly suitable for polyisobutylene and/or polysiloxane star polymers. The synthesis has been achieved using carbocationic and/or anionic ring-opening polymerization techniques to form polymer arms of desired molecular weights, then separately preparing the calixarene derivative core, and finally, linking the arms to the core by transesterification or hydrosilation.
    Type: Grant
    Filed: August 7, 1996
    Date of Patent: November 24, 1998
    Assignee: The University of Akron
    Inventors: Istvan J. Majoros, Timea M. Marsalko, Joseph P. Kennedy
  • Patent number: 5824760
    Abstract: A thermal transfer image-receiving sheet having a dye-receiving layer, which is excellent in reaction rate of a release agent, coating strength of a release layer and releasability from a thermal transfer sheet. The thermal transfer image-receiving sheet comprises a substrate sheet and a dye-receiving layer provided on at least one surface of the substrate sheet, wherein the dye-receiving layer contains a release agent mixture comprising an addition-polymerizable silicone and a hydrogen-modified silicone or wherein the dye-receiving layer has on its surface a release layer comprising an addition-polymerizable silicone and a hydrogen-modified silicone. The present invention relates also to a process for producing the above thermal transfer image-receiving sheets.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: October 20, 1998
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Yoshihiko Tamura, Mitsuru Tsuchiya
  • Patent number: 5811193
    Abstract: Novel loop polymers having a polymeric backbone and a plurality of olefinic groups which have been converted to closed loops by reaction with difunctional organic compounds reactive with said olefinic groups, said olefinic groups from which the loops are formed may either be present within the backbone and/or pendent from the polymeric backbone. The loop polymers may also have hydroxy or carboxy groups which can be capped with diisocyanates or epoxies, respectively.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: September 22, 1998
    Assignee: Fluorochem, Inc.
    Inventor: Kurt Baum
  • Patent number: 5792812
    Abstract: A thermoplastic resin composition comprising 100 parts by weight of a thermoplastic resin and 2 to 12 parts by weight of a thermoplastic resin oligomer containing 0.1 to 35% by weight of an aliphatic unsaturated group is molded with silicone rubber to form an integrally molded part. The thermoplastic resin composition maintains the inherent properties of the thermoplastic resin and firmly bonds with silicone rubber.
    Type: Grant
    Filed: December 26, 1995
    Date of Patent: August 11, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Shigeki Shudo
  • Patent number: 5792813
    Abstract: A fluorescent polymer having the moiety ##STR1## is disclosed. R.sub.1 and R.sub.2 are H.sub.1 alkyl, or aromatic. R.sub.3, R.sub.4, and R.sub.5 are aromatic. A preferred fluorescent composition may be formed by combining the fluorescent polymer with a second polymer, such as polystyrene or polysilystyrene.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: August 11, 1998
    Assignee: Wisconsin Alumni Research Foundation
    Inventors: Chien-Hua Yuan, Robert C. West
  • Patent number: 5773512
    Abstract: This invention relates to libraries of non-peptide compounds each comprised of a core structure and methods for making such libraries. This invention also relates to novel silicon-based polymer resins and silane linkers, methods for their preparation and their use in the synthesis of libraries of compounds to be screened as pharmaceutical agents.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: June 30, 1998
    Assignee: SmithKline Beecham Corp.
    Inventors: Balan Chenera, John Elliott, Michael Moore, Joseph Weinstock
  • Patent number: 5756562
    Abstract: A novel silicone system comprising a methoxy terminated silane or polysiloxane, an adhesion promoter and water, useful as a filler alone or in combination with other fillers is disclosed.
    Type: Grant
    Filed: August 21, 1996
    Date of Patent: May 26, 1998
    Assignee: General Electric Company
    Inventors: Michael Anthony Lucarelli, William John Raleigh
  • Patent number: 5744548
    Abstract: A melt-extrudable thermoplastic polypropylene composition having a melt flow rate in a range of from about 18 to about 30 g/10 minutes at a temperature of 190.degree. C. and a load of 2.16 kg, a polydispersity less than 4, and a Z-average molecular weight greater than 300,000 as determined by differential refractometry. The composition may include a first thermoplastic polypropylene having a melt flow rate lower than 18 g/10 minutes at a temperature of 190.degree. C. and a load of 2.16 kg and a second thermoplastic polypropylene having a melt flow rate higher than 18 g/10 minutes at a temperature of 190.degree. C. and a load of 2.16 kg. The weight ratio of the first polypropylene to the second polypropylene is in a range of from about 90:10 to about 10:90. The composition may include from about 0.1 to about 1 percent by weight, based on the weight of the first and second thermoplastic polypropylenes, of a defined alkyl-substituted polysiloxane.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: April 28, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald, Peter Michelovich Kobylivker
  • Patent number: 5741859
    Abstract: The present invention relates to a method for preparing a polyisobutylene-siloxane block copolymer, said method comprising:(I) lithiating(A) a polyisobutylene having one or two terminal silanol groups with(B) an organolithium compound;(II) reacting the silanolate-functional polyisobutylene obtained in step (I) with(C) a hexaorganocyclotrisiloxane; and(III) capping the siloxanotate-functional block copolymer obtained in step (II) with a compound selected from(D) a silane having at least one hydrolyzable group or(E) an acid.
    Type: Grant
    Filed: February 3, 1997
    Date of Patent: April 21, 1998
    Assignee: Dow Corning Corporation
    Inventors: Anil Kumar Saxena, Toshio Suzuki
  • Patent number: 5733998
    Abstract: The dispersion polymerization of isobutylene includes a dispersing agent. The dispersing agent is a compound having a CO.sub.2 -phobic moiety and at least one CO.sub.2 -philic moiety. The CO.sub.2 -phobic moiety is polysibutylene-philic. Novel polymerization initiators are organometallic.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: March 31, 1998
    Assignee: The University of Akron
    Inventors: Joseph P. Kennedy, Tibor Pernecker
  • Patent number: 5733538
    Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 31, 1998
    Assignee: Thoratec Laboratories, Inc.
    Inventor: Judy S. Riffle
  • Patent number: 5728768
    Abstract: This invention relates to the preparation of an addition curable composition which when cured has increased resistance to degradation by ultraviolet light. The addition curable composition comprises an organic polymer having on average at least 1.4 alkenyl groups per molecule, a crosslinker having on average at least 2 hydrosilyl groups per molecule, a platinum group metal-containing catalyst and a benzotriazole derivative stabilizer.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: March 17, 1998
    Assignee: Dow Corning Corporation
    Inventors: Anil Kumar Saxena, Toshio Suzuki
  • Patent number: 5728469
    Abstract: Release surfaces comprising extruded polymer-siloxane block copolymer mixtures are provided. At least one block of the copolymer is a polymer compatible with the bulk polymeric material, while a second block is polysiloxane. Coextruded release surfaces comprising two or more polymeric layers, including one layer of a polymer-siloxane block copolymer mixture, are provided. The release surfaces serve as release liners for pressure sensitive adhesive labels and tapes.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 17, 1998
    Assignee: Avery Dennison Corporation
    Inventors: Roger H. Mann, Edward I. Sun, Sebastian S. Plamthottam, Charles W. Newing
  • Patent number: 5717009
    Abstract: An adhesive composition which comprises:(A) 100 parts by weight of a polyorganosiloxane represented by the formula (I): ##STR1## (wherein R.sup.1 s may be the same or different from each other and each represent a monovalent hydrocarbon group or a halogen-substituted hydrocarbon group; and n is a positive integer);(B) 0.5 to 10 parts by weight of a tetraalkoxysilane represented by the following formula:R.sup.2.sub.a Si(OR.sup.3).sub.4-a (II)(wherein R.sup.2 represents an alkyl group having 1 to 3 carbon atoms, a phenyl group or a vinyl group; R.sup.3 represents an alkyl group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group having 3 to 6 carbon atoms; and a is 0 or 1),or a partially hydrolyzed condensate thereof; and(C) 0.1 to 15 parts by weight of a trialkoxysilane represented by the formula (III):R.sup.4 (R.sup.5).sub.b Si(OR.sup.6).sub.3-b (III)(wherein R.sup.4 represents a substituted or unsubstituted aminoalkyl group; R.sup.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: February 10, 1998
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Shigeki Matsushita, Fumihiko Kobayashi
  • Patent number: 5708085
    Abstract: There is disclosed a polyolefin composition which can be extruded at relatively high rates to provide extrudate having improved hydrophobicity, said composition comprising(A) 100 parts by weight of a polythylene resin; and(B) 1 to 5 parts by weight of an interactive diorganopolysiloxane process aid, said diorganopolysiloxane having a number average molecular weight of at least 10,000. In particularly preferred embodiments, an interactive diorganopolysiloxane in combination with a low density polyethylene is used as a process aid for linear low density polyethylene.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: January 13, 1998
    Assignee: Dow Corning Corporation
    Inventors: Dale Earl Hauenstein, Caibao Qian, David Joseph Romenesko
  • Patent number: 5703163
    Abstract: Novel loop polymers having a polymeric backbone and a plurality of olefinic groups which have been converted to closed loops by reaction with difunctional organic compounds reactive with said olefinic groups, said olefinic groups from which the loops are formed may either be present within the backbone and/or pendent from the polymeric backbone. The loop polymers may also have hydroxy or carboxy groups which can be capped with diisocyanates or epoxies, respectively.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: December 30, 1997
    Assignee: Fluorochem, Inc.
    Inventor: Kurt Baum
  • Patent number: 5691399
    Abstract: Disclosed are sealant compositions having excellent slump and spew resistant, even at relatively high operating temperatures for electrical connectors. The sealants, which are flowable at such elevated temperatures, comprise two essential components: elastomeric thermoplastic polymer, preferably an organic polymer composite comprising diblock and triblock copolymers, and extender for the polymer. The extender may comprise a primary and a secondary extender, such as polybutene oil and mineral oil, respectively.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: November 25, 1997
    Assignee: The Whitaker Corporation
    Inventors: Francis Frederick Koblitz, Thomas John Lynch, Ricky Charles Mellinger
  • Patent number: 5681895
    Abstract: A high yield of three armed radial anionic polymers is produced by the process of coupling metal terminated anionic polymers with a trialkoxysilane having a silicon-hydrogen bond, preferably trimethoxysilane. The metal terminated anionic polymer is preferably produced by initiating polymerization with a protected functional initiator which is readily converted to terminal hydroxyl groups or derivatives thereof for use in adhesives, sealants, and coatings.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: October 28, 1997
    Assignee: Shell Oil Company
    Inventors: Robert Charles Bening, Ronald James Hoxmeier
  • Patent number: 5679414
    Abstract: A liquid crystal-polymer composite film comprising (1) a high-molecular weight compound containing at least one kind of monomer units providing a side chain having a liquid crystal nature and at least one kind of monomer units providing a side chain having no liquid crystal nature and (2) a low-molecular weight liquid crystal, the high-molecular weight compound (1) and the low-molecular weight liquid crystal (2) being in separate phases, and the monomer units providing a side chain having no liquid crystal nature being crosslinked; and an electro-optical element comprising a pair of substrates each having an electrode having interposed therebetween a liquid crystal-polymer composite film comprising (2) a low-molecular weight liquid crystal and (1) a high-molecular weight compound in separate phases, the substrates each having a surface comprising a material having a reactive group on the side in contact with the composite film, the reactive group being chemically bonded to the high-molecular weight compound (
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: October 21, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Ryojiro Akashi, Masanobu Ninomiya
  • Patent number: 5677066
    Abstract: A sealing part for connector waterproofing is disclosed, which comprises a vulcanized molding obtained from a composition comprising 100 parts by weight of a polyorganosiloxane (1), from 5 to 100 parts by weight of a reinforcing silica powder filler (2), from 0.01 to 10 parts by weight of a hydrogensiloxane polymer (3) having two or more Si-H bonds per molecule, and from 0.01 to 5 parts by weight of t-butyl peroxy-3,5,5-trimethylhexanoate (4). The sealing part for connector waterproofing of the present invention is satisfactory in heat resistance, low-temperature resistance, and oil resistance and can be produced at low cost in a reduced molding time.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: October 14, 1997
    Assignee: Yazaki Corporation
    Inventors: Kiyotaka Okazaki, Masahiro Kanda
  • Patent number: 5672660
    Abstract: An improved process for the preparation of thermoplastic elastomers by hydrosilylation crosslinking, in which a platinum containing hydrosilylation catalyst is used in combination with specific diene-containing rubbers. A fully crosslinked rubber component is obtained in the thermoplastic elastomer composition.
    Type: Grant
    Filed: December 1, 1995
    Date of Patent: September 30, 1997
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Robert Eugene Medsker, Raman Patel
  • Patent number: 5665823
    Abstract: The present invention relates to a method for preparing an acrylic-functional polyisobutylene polymer or copolymer, said method comprising reacting a polyisobutylene polymer or copolymer which contains at least one carbon-bonded silanol group in its molecule with a silane having both an acrylic-containing group and a silicon-bonded hydrolyzable group in its molecule.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: September 9, 1997
    Assignee: Dow Corning Corporation
    Inventors: Anil Kumar Saxena, Toshio Suzuki
  • Patent number: 5663245
    Abstract: The synthesis and characterization of novel multi-arm star polymers comprising polyisobutylene arms connected to a well-defined, siloxane core are described. The synthesis has been achieved by hydrosilating olefin-capped (e.g., allyl- or isopropenyl-terminated) polyisobutylene with siloxanes carrying a plurality of Si--H groups.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: September 2, 1997
    Assignee: The University of Akron
    Inventors: Joseph P. Kennedy, Naoki Omura, Alexander Lubnin
  • Patent number: 5654368
    Abstract: The invention is to provide elastomer-like or rubber-like, recyclable cross-linked polymers capable of being liquefied and re-molded repeatedly without detracting from the physical properties of the polymers. The polymer comprises meltable cross-linked oligomer units and linkage units via which the oligomer units are linked to construct the main chains of the polymer. Each linkage unit in the polymer comprises a chemical bond that can be cleaved and re-formed repeatedly by predetermined treatment by which the bond between monomers in the oligomer units are not cleaved. The method for producing the polymer comprises a step of forming oligomer units by polymerizing monomers, a step of forming linkage units by linking the oligomer units via linkage units and a step of forming cross-linked units between the oligomer units.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: August 5, 1997
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Mitsuru Nakano, Makoto Mouri, Arimitsu Usuki, Akane Okada
  • Patent number: 5652307
    Abstract: Graft copolymers obtained by(A) polymerizing 10 to 89 wt % of a mixture consisting essentially of either(a1) from 70 to 99.89 wt % of a C.sub.1 -C.sub.18 -alkyl ester of acrylic acid,(a2) from 0.1 to 10 wt % of a polyfunctional monomer,(a3) from 0 to 29.89 wt % of an ethylenically unsaturated monomer which differs from (a1) and (a2), is copolymerizable therewith and carries no acid group and(a4) from 0.01 to 10 wt % of a copolymerizable monomer containing at least one acid groupor(a5) from 49.99 to 99.99 wt % of at least one diene,(a6) from 0 to 50 wt % of a monomer which is copolymerizable therewith and carries no acid group and(a7) from 0.01 to 10 wt % of a copolymerizable monomer containing at least one acid groupin the presence of from 1 to 80 wt % of a cross-linked silicone rubber to form a copolymer A,and(B) polymerizing 10 to 89 wt % of a mixture consisting essentially of(b1) from 50 to 99.99 wt % of a styrene compound of the formula (I) ##STR1## where R.sup.1 and R.sup.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: July 29, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Niessner, Wolfgang Fischer
  • Patent number: 5648066
    Abstract: Disclosed are solid silicone compositions comprising low molecular weight polyethylene solidifying agents and one or more non-volatile silicone fluids, along with a method for their preparation. The compositions are suitable for topical application to skin or hair, and are particularly useful in the preparation of novel skin treatment, hair treatment, lipstick and makeup products.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: July 15, 1997
    Assignee: Estee Lauder Companies
    Inventor: George J. Stepniewski
  • Patent number: 5648426
    Abstract: A method and composition for improving the impact resistance of thermoplastics is disclosed. An impact resistant thermoplastic is formed by forming a silicone containing thermosetting component, compounding it with a thermoplastic to form a silicone-thermoplastic mixture, disposing a catalyst on the mixture, and activating the catalyst while compounding the mixture with a thermoplastic. The silicone containing thermosetting component includes a first silicone compound containing hydride groups and a second silicone compound containing unsaturated groups. Activating the catalyst, preferably a platinum complex, causes the thermosetting component to cure, creating a silicone-thermoplastic semi-interpenetrating polymer network having higher impact resistance than the unmodified thermoplastic.
    Type: Grant
    Filed: May 5, 1995
    Date of Patent: July 15, 1997
    Assignee: Huls America Inc.
    Inventor: Mikhail Zolotnitsky