With Phenolic Reactant Or Polymer Thereof And Is Free Of 1,2-epoxy Groups Patents (Class 525/109)
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Patent number: 8293839Abstract: Disclosed herein is a polycarbonate-polysiloxane copolymer resin composition comprising: (A) about 100 parts by weight of a thermoplastic polycarbonate resin; and (B) about 0.1 to about 30 parts by weight of an organo-siloxane polymer having an epoxy group. The polycarbonate-polysiloxane copolymer resin composition has high impact strength at low temperature and high mechanical strength.Type: GrantFiled: June 16, 2009Date of Patent: October 23, 2012Assignee: Cheil Industries Inc.Inventors: Bo Young Kim, Jong Cheol Lim, Tae Gon Kang
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Publication number: 20120264870Abstract: A composite prepared using a thermosettable epoxy resin composition having, as components: (1) an epoxy resin; (2) an epoxidized cycloaliphatic dicyclopentadiene phenolic resin; (3) an optional epoxidized bisphenol-A novolac resin; (4) an optional oligomeric butadiene; (5) an optional organic solvent; and (6) an alkylphenol novolac resin, the alkylphenol novolac resin serving as a curing agent. The composite so prepared may have good physical properties and superior a electrical properties as compared to conventional composites, such as laminates. The prepregs used to make the laminates may have a better surface appearance as well.Type: ApplicationFiled: April 9, 2012Publication date: October 18, 2012Inventor: Charles David Shirrell
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Patent number: 8273825Abstract: A method of making resin composition having excellent wear properties that includes 50 to 99 wt. % of a polycarbonate resin and from 1 to 50 wt. % of a polyolefin that has been modified with at least one functional group selected from a carboxyl, an acid anhydride, an epoxy groups or mixtures containing at least one of the foregoing functional groups, each based on the total combined weight of the resin composition, exclusive of any filler. The resin composition optionally contains an unmodified polyolefin and/or a bi-functional monomer. The resin composition can be molded into articles having improved wear characteristics. The process is a one-step process that improves the efficiency and/or yield of the resin composition as compared to prior-art two-step processes.Type: GrantFiled: March 20, 2007Date of Patent: September 25, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ye-Gang Lin, Donghai Sun, David Xiangping Zou
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Patent number: 8217115Abstract: A liquid resin composition of the present invention is a liquid resin composition for bonding a semiconductor element on a support, exhibiting a tackiness of 0.05 N or less after heating at 120° C. for 10 min and a tackiness of 1 N or more at 80° C. A semiconductor wafer having an adhesive layer of the present invention is a semiconductor wafer having an adhesive layer in which the adhesive layer is formed from the above liquid resin composition. A process for manufacturing a semiconductor element of the present invention has the application step of applying an adhesive as a liquid resin composition containing a thermosetting resin and a solvent to one side of a wafer; the evaporation step of evaporating said solvent while substantially maintaining a molecular weight of said liquid resin composition to form an adhesive layer; the bonding step of bonding a dicing sheet on one side of said wafer; and the cutting step of cutting said wafer into pieces.Type: GrantFiled: October 30, 2007Date of Patent: July 10, 2012Assignee: Sumitomo Bakelite Company, LtdInventors: Takeshi Masuda, Hikaru Okubo
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Patent number: 8202948Abstract: Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P?O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R?(Y)m?]m(X—O—R?)n??Formula (I) wherein R? is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R? is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m?, m and n are, independently, numbers equal to or greater than 1; and (C) a thermosetting or thermoplastic composition.Type: GrantFiled: November 4, 2010Date of Patent: June 19, 2012Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Patent number: 8198381Abstract: Disclosed is a phenol aralkyl epoxy resin having a structure wherein at least a phenol or a naphthol is bound by using an aralkyl group as a linking group and a structure represented by formula (1) below, while satisfying the condition 1 below. This epoxy resin is excellent in workability during production of a composition and is easy to control quality. Condition 1: The following relation (?) is satisfied with A being the hydroxyl equivalent (as measured in accordance with JIS K 0070) of a phenol-modified epoxy resin obtained by adding an equivalent molar amount of phenol relative to the epoxy equivalent of the epoxy resin, and B being the epoxy equivalent of the epoxy resin. 50?1000×(A?B)/B?250 (?).Type: GrantFiled: October 16, 2006Date of Patent: June 12, 2012Assignee: Nippon Kayaku Kabushiki KaishaInventors: Masataka Nakanishi, Katsuhiko Oshimi, Kazuyuki Ohhashi, Toru Kurihashi
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Patent number: 8192840Abstract: A spring with high durability has a coating film composed of an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of the coating film. A method of coating a spring with high durability comprises a coating step of making an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of a coating film adhere to a surface on which the coating film is formed, and a baking step of baking the epoxy resin powder coating containing softening agent adhered to the surface.Type: GrantFiled: June 21, 2010Date of Patent: June 5, 2012Assignees: Chuo Hatsujo Kabushiki Kaisha, Rock Paint Co., Ltd.Inventors: Yasuhiko Kunita, Takayuki Sakakibara, Masami Wakita, Yuichi Kondo, Norio Sawatari
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Patent number: 8173745Abstract: A composite prepared using a thermosettable epoxy resin composition having, as components: (1) an epoxy resin; (2) an epoxidized cycloaliphatic dicyclopentadiene phenolic resin; (3) an optional epoxidized bisphenol-A novolac resin; (4) an optional oligomeric butadiene; (5) an optional organic solvent; and (6) an alkylphenol novolac resin, the alkylphenol novolac resin serving as a curing agent. The composite so prepared may have good physical properties and superior a electrical properties as compared to conventional composites, such as laminates. The prepregs used to make the laminates may have a better surface appearance as well.Type: GrantFiled: December 16, 2009Date of Patent: May 8, 2012Assignee: Momentive Specialty Chemicals Inc.Inventor: Charles David Shirrell
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Patent number: 8143357Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.Type: GrantFiled: November 4, 2010Date of Patent: March 27, 2012Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Patent number: 8138266Abstract: A semiconductor-encapsulating resin composition includes a curing agent and a compound (A) having a plurality of glycidyl ether groups. When ion viscosity of the resin composition is measured under conditions of a measurement temperature of about 175° C. and a measurement frequency of about 100 Hz, minimum ion viscosity appears at about 5 seconds or later and within about 40 seconds from a measurement starting point. The minimum ion viscosity is at least about 4.0 and at most about 7.0. A maximum slope of the ion viscosity appears at about 10 seconds or later and within about 60 seconds from the measurement starting point. The maximum slope is at least about 2.0 and at most about 6.0.Type: GrantFiled: March 21, 2008Date of Patent: March 20, 2012Assignee: Sumitomo Bakelite Co., Ltd.Inventor: Hirofumi Kuroda
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ADHESIVE FILM FOR SOLAR CELL ELECTRODE AND METHOD FOR MANUFACTURING SOLAR CELL MODULE USING THE SAME
Publication number: 20120048332Abstract: There are provided an adhesive film for a solar cell electrode providing a solar cell capable of reducing adverse effects on photovoltaic cells caused by heating or pressure and having sufficient solar cell characteristics, and a method for manufacturing a solar cell module using the same. The adhesive film for a solar cell electrode is an adhesive film used for electrical connection between photovoltaic cell surface electrodes and wiring members, wherein the adhesive film contains a crystalline epoxy resin, a curing agent and a film forming material.Type: ApplicationFiled: August 25, 2011Publication date: March 1, 2012Applicant: HITACHI CHEMICAL COMPANY, LTD.Inventors: Shigenori Shimizu, Hiroyuki Izawa, Keisuke Ookubo, Shigeaki Funyu, Yutaka Okada, Keiko Funyu, Naotaka Tanaka -
Patent number: 8124716Abstract: Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P?O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R?(Y)m?]m(X—O—R?)n??Formula (I) wherein R? is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R? is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m?, m and n are, independently, numbers equal to or greater than 1. These compounds are useful for making flame retardant epoxy and polyurethane resins and ignition resistant thermoplastic resins, each of which is useful for a variety of end uses requiring flame retardancy or ignition resistance. Flame retardant epoxy resins may be used to make electrical laminates.Type: GrantFiled: November 4, 2010Date of Patent: February 28, 2012Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Patent number: 8124674Abstract: The present invention relates to a halogen-free resin composition with high frequency dielectric property, and a prepreg and a laminate made therefrom. The halogen-free resin composition with high frequency dielectric property comprises, calculating according to the parts by weight of organic solids: (A) 10-50 parts by weight of copolymer of styrene-maleic anhydride; (B) 10-50 parts by weight of at least one compound having dihydrobenzoxazine ring; (C) 10-50 parts by weight of at least one polyepoxide; (D) 5-30 parts by weight of at least one phosphorus-containing flame retardant. Prepregs and laminates made from the resin composition have low dielectric constant, low dielectric dissipation factor, high glass transition temperature, high heat resistance, low moisture adsorption, and the technological operation is simple.Type: GrantFiled: January 28, 2010Date of Patent: February 28, 2012Assignee: Guangdong Shengyi Sci. Tech Co., Ltd.Inventors: Shi Guo Su, Yue Shan He, Bi Wu Wang, Jie Li, Tao Chen
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Patent number: 8119737Abstract: Disclosed is an adhesive composition which includes (a) an epoxy resin, (b) a curing agent and (c) a polymer compound incompatible with said epoxy resin, and further optionally includes (d) a filler and/or (e) a curing accelerator. Also disclosed are a process for producing an adhesive composition, including mixing (a) the epoxy resin and (b) the curing agent with (d) the filler, followed by mixing the resultant mixture with (c) the polymer compound incompatible with the epoxy resin; an adhesive film including the above-mentioned adhesive composition formed into a film; a substrate for mounting a semiconductor including a wiring board and the above-mentioned adhesive film disposed thereon on its side where chips are to be mounted; and a semiconductor device which includes the above-mentioned adhesive film or the substrate for mounting a semiconductor.Type: GrantFiled: April 12, 2011Date of Patent: February 21, 2012Assignee: Hitachi Chemical Company, Ltd.Inventors: Teiichi Inada, Keiji Sumiya, Takeo Tomiyama, Tetsurou Iwakura, Hiroyuki Kawakami, Masao Suzuki, Takayuki Matsuzaki, Youichi Hosokawa, Keiichi Hatakeyama, Yasushi Shimada, Yuuko Tanaka, Hiroyuki Kuriya
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Publication number: 20120028050Abstract: The present invention relates to a film for flip chip type semiconductor back surface to be formed on a back surface of a semiconductor element flip chip-connected onto an adherend, the film for flip chip type semiconductor back surface having a ratio of A/B falling within a range of 1 to 8×103 (%/GPa), in which A is an elongation ratio (%) of the film for flip chip type semiconductor back surface at 23° C. before thermal curing and B is a tensile storage modulus (GPa) of the film for flip chip type semiconductor back surface at 23° C. before thermal curing.Type: ApplicationFiled: July 27, 2011Publication date: February 2, 2012Applicant: NITTO DENKO CORPORATIONInventors: Goji SHIGA, Naohide TAKAMOTO, Fumiteru ASAI
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Publication number: 20120016057Abstract: It is an object of the present invention to provide an adhesive for electronic components that prevents warpage of electronic components and reflow cracks even in the case of bonding thin electronic components. The present invention relates to an adhesive for electronic components, comprising: an epoxy compound having an aliphatic polyether backbone and a glycidyl ether group; an epoxy group-containing acrylic polymer; an episulfide compound; and a curing agent, wherein the amount of the episulfide compound is 1 parts by weight or more, and less than 30 parts by weight relative to 100 parts by weight of the epoxy compound having an aliphatic polyether backbone and a glycidyl ether group.Type: ApplicationFiled: January 29, 2010Publication date: January 19, 2012Inventors: Akinobu Hayakawa, Hideaki Ishizawa, Kohei Takeda, Ryohei Masui
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Publication number: 20120010330Abstract: A curable composition including (a) at least one cyclic diamine, (b) at least one non-heterocyclic amine that has a pKa value of approximately 9.5 to about 12 at 25° C. for the most basic amine group in the non-heterocyclic amine molecule, (c) at least one epoxy resin, and (d) at least one alkylated phenol; (i) wherein the equivalents of the amine hydrogens from the cyclic diamine compared to the total amine hydrogens from both the cyclic diamine and the non-heterocyclic amine in the composition are greater than about 5%; (ii) wherein the ratio of the equivalents of the total amine hydrogens in the composition to the equivalents of the total epoxies in the composition is greater than or equal to about 1; and (iii) wherein the alkylated phenol is in an amount greater than about 10 wt % of the curable composition.Type: ApplicationFiled: February 16, 2010Publication date: January 12, 2012Inventors: Marvin L. Dettloff, James R. Lowrey, Hemant A. Naik, Maurice J. Marks
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Patent number: 8092876Abstract: A coating composition for a food or beverage can that includes an emulsion polymerized latex polymer formed by combining an ethylenically unsaturated monomer component with an aqueous dispersion of a water-dispersible polymer.Type: GrantFiled: July 17, 2009Date of Patent: January 10, 2012Assignee: Valspar Sourcing, Inc.Inventors: Robert M. O'Brien, Daniel E. Rardon, Rachael Ann Spynda, George K. Bartley, III, Richard H. Evans, T. Howard Killilea, Carl Cavallin
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Patent number: 8053533Abstract: A solvent-free polyimide silicone resin composition, and a cured product thereof, includes (A) a polyimide silicone resin having recurring units having a specific type of structure and having a weight average molecular weight of 5,000 to 150,000, (B) an epoxy resin, and (C) an epoxy resin curing agent wherein the resin composition having a fluidity at 25° C. and is free of a solvent.Type: GrantFiled: August 26, 2009Date of Patent: November 8, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshinori Yoneda, Michihiro Sugo
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Patent number: 8026310Abstract: A low temperature curable coating powder comprising an epoxy functional resin is cured with styrene maleimide in combination with at least one other curing agent such as dicyandiamide, imidazole, or an imidazole adduct. The combination of three curing agents such styrene maleimide, dicyandiamide, and an imidazole or imidazole adduct is useful for achieving gloss control. The coating powder may be curable at temperatures of 300° F. or lower. The coating of heat-sensitive and non-conductive substrates is facilitated with use of such coating powder, although other substrates, such as metal may be coated in accordance with the invention.Type: GrantFiled: June 23, 2008Date of Patent: September 27, 2011Assignee: Alpha Coating Technologies, IncInventor: Jeno Muthiah
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Patent number: 7981963Abstract: In a semiconductor device, the topmost wiring layer of the package board is formed from an insulation material in which the elongation at break is 20% or higher and Young's modulus is 1 GPa or less when the temperature is 10 to 30° C. This insulation material contains a reactive elastomer that reacts with epoxy resin or an epoxy resin curing agent; an epoxy resin; an epoxy resin curing agent; and a crosslinked styrene-butadiene rubber having a double bond and a hydroxyl group, a carboxylic group, or another polar group. It is therefore possible to provide a semiconductor device that has a wiring board in which the connection reliability in relation to temperature cycles is high and the adhesiveness between the insulation layer and the electroless copper plating layer is also high.Type: GrantFiled: April 10, 2007Date of Patent: July 19, 2011Assignee: NEC CorporationInventors: Yukihiro Kiuchi, Masahiro Ishibashi, Yoshitaka Kyogoku, Masatoshi Iji
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Patent number: 7977412Abstract: An epoxy resin composition for encapsulating semiconductors which comprises as essential components (A) an epoxy resin, (B) a phenol resin, (C) a curing accelerator, (D) an inorganic filler and (E) a component comprising (e1) a butadiene-acrylonitrile copolymer having carboxyl group and/or (e2) a reaction product of (e1) a butadiene-acrylonitrile copolymer having carboxyl group with an epoxy resin, wherein the content of component (e1) in the entire epoxy resin composition is 0.01 to 1% by weight. The composition exhibits excellent releasing property in molding, continuous molding property and resistance to solder reflow.Type: GrantFiled: September 25, 2009Date of Patent: July 12, 2011Assignee: Sumitomo Bakelite Company, Ltd.Inventor: Yasuhiro Mizuno
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Publication number: 20110120761Abstract: Epoxy resin compositions which comprise an epoxy resin (A), an active ester compound (B), and a triazine-containing cresol novolac resin (C), when cured and roughened, exhibit a roughed surface which has a high adhesion strength to a metal plated conductor, even though the roughness of the roughed surface is small, and provide an insulating layer which has a low coefficient of linear expansion and a low dielectric loss tangent.Type: ApplicationFiled: November 22, 2010Publication date: May 26, 2011Applicant: AJINOMOTO CO. INC.Inventor: Kenji KAWAI
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Patent number: 7947779Abstract: Disclosed is an adhesive composition which includes (a) an epoxy resin, (b) a curing agent and (c) a polymer compound incompatible with said epoxy resin, and further optionally includes (d) a filler and/or (e) a curing accelerator. Also disclosed are a process for producing an adhesive composition, including mixing (a) the epoxy resin and (b) the curing agent with (d) the filler, followed by mixing the resultant mixture with (c) the polymer compound incompatible with the epoxy resin; an adhesive film including the above-mentioned adhesive composition formed into a film; a substrate for mounting a semiconductor including a wiring board and the above-mentioned adhesive film disposed thereon on its side where chips are to be mounted; and a semiconductor device which includes the above-mentioned adhesive film or the substrate for mounting a semiconductor.Type: GrantFiled: October 7, 2010Date of Patent: May 24, 2011Assignee: Hitachi Chemical Company, Ltd.Inventors: Teiichi Inada, Keiji Sumiya, Takeo Tomiyama, Tetsurou Iwakura, Hiroyuki Kawakami, Masao Suzuki, Takayuki Matsuzaki, Youichi Hosokawa, Keiichi Hatakeyama, Yasushi Shimada, Yuuko Tanaka, Hiroyuki Kuriya
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Patent number: 7897258Abstract: A composition useful as an impregnant for the making of laminates for printed wiring boards comprises a FR4 epoxy resin which is a bisphenol A epoxy resin advanced with tetrabromobisphenol A, a crosslinking agent of a strene-maleic anhydride copolymer and a co-crosslinking agent is an optionally brominated bisphenol A and/or an optionally brominated bisphenol A diglycidyl ether.Type: GrantFiled: June 16, 2008Date of Patent: March 1, 2011Assignee: Isola USA Corp.Inventors: Franz Tikart, Karl-Heinz Leis, Karl Walter Kopp
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Patent number: 7858173Abstract: A novel flame-retardant thermoplastic polyhydroxy polyether resin obtained by reacting at least one epoxy resin (A) selected from glycidyl esters of divalent aliphatic carboxylic acids having 15 to 64 carbon atoms or glycidyl ethers of divalent aliphatic alcohols having 15 to 64 carbon atoms with a phosphorus atom-containing divalent phenol compound (B) as essential components, wherein the component (A) accounts for 2 to 52 mol % with respect to the whole resin, the weight average molecular weight thereof is 10,000 to 200,000, and the phosphorus content thereof is 1 to 5 wt %.Type: GrantFiled: March 24, 2008Date of Patent: December 28, 2010Assignee: Nippon Steel Chemicals Co., Ltd.Inventors: Masao Gunji, Chiaki Asano
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Patent number: 7816069Abstract: An antireflective coating that contains at least two polymer components and comprises chromophore moieties and transparent moieties is provided. The antireflective coating is useful for providing a single-layer composite graded antireflective coating formed beneath a photoresist layer.Type: GrantFiled: June 23, 2006Date of Patent: October 19, 2010Assignee: International Business Machines CorporationInventors: Colin J. Brodsky, Sean D. Burns, Dario L. Goldfarb, Michael Lercel, David R. Medeiros, Dirk Pfeiffer, Daniel P. Sanders, Steven A. Scheer, Libor Vyklicky
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Patent number: 7776440Abstract: A spring with high durability has a coating film composed of an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of the coating film. A method of coating a spring with high durability comprises a coating step of making an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of a coating film adhere to a surface on which the coating film is formed, and a baking step of baking the epoxy resin powder coating containing softening agent adhered to the surface.Type: GrantFiled: January 26, 2007Date of Patent: August 17, 2010Assignees: Chuo Hatsujo Kabushiki Kaisha, Rock Paint Co., Ltd.Inventors: Yasuhiko Kunita, Takayuki Sakakibara, Masami Wakita, Yuichi Kondo, Norio Sawatari
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Patent number: 7772334Abstract: A crosslinker for polymerizing a film-forming material including an alkyl or aromatic compound comprising at least two functional groups reactive with a film-forming resin and at least one pendent group having a nonionic metal coordinating structure. Coating compositions can include a film-forming material and the crosslinker. The coating compositions can be used to coat a substrate, such as a metal substrate. Applied coating layers on substrates can be cured to form coating films.Type: GrantFiled: October 26, 2006Date of Patent: August 10, 2010Assignee: BASF Coatings GmbHInventors: Timothy S. December, Sergio Gonzalez, Günther Ott, Karl-Heinz Grosse-Brinkhaus
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Publication number: 20100129045Abstract: The present invention provides an adhesive composition for an optical waveguide which comprises (a) an epoxy resin, (b) a curing agent and (c) a high molecular compound, in which a total light transmittance and a light transmittance in a wavelength of 700 to 1600 nm in a cured matter of the adhesive composition are 80% or more and in which a transparency is consistent with a heat resistance, an adhesive film for an optical waveguide prepared by forming the above adhesive composition into a film form, an adhesive sheet for an optical waveguide comprising the above adhesive composition and a supporting base material and an optical device produced by using them.Type: ApplicationFiled: March 13, 2008Publication date: May 27, 2010Inventors: Tomoaki Shibata, Atsushi Takahashi, Keisuke Ookubo, Tetsurou Iwakura
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Patent number: 7674859Abstract: An adhesive sheet which can actualize a high package reliability wherein there is no separation at the adhesive interface and no package cracking, in a package in which a semiconductor chip being reduced in thickness is mounted under severe reflow conditions after exposure to a hot and humid environment. The adhesive sheet includes a base material and, formed thereon, an adhesive layer having an adhesive composition including an acrylic copolymer (A) containing 20 to 95% by weight of a structural unit derived from a benzyl (meth)acrylate, an epoxy thermosetting resin (B), and a thermosetting agent (C).Type: GrantFiled: June 24, 2008Date of Patent: March 9, 2010Assignee: Lintec CorporationInventors: Naoya Saiki, Isao Ichikawa, Hironori Shizuhata
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Publication number: 20100055842Abstract: The thermosetting die-bonding film of the present invention is used in manufacturing a semiconductor device, has at least an epoxy resin, a phenol resin, and an acrylic copolymer, and the ratio X/Y is 0.7 to 5 when X represents a total weight of the epoxy resin and the phenol resin and Y represents a weight of the acrylic copolymer.Type: ApplicationFiled: August 28, 2009Publication date: March 4, 2010Inventors: Yuki Sugo, Sedahito Misumi, Takeshi Matsumura
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Patent number: 7629398Abstract: An epoxy resin composition for encapsulating semiconductors which comprises as essential components (A) an epoxy resin, (B) a phenol resin, (C) a curing accelerator, (D) an inorganic filler and (E) a component comprising (e1) a butadiene-acrylonitrile copolymer having carboxyl group and/or (e2) a reaction product of (e1) a butadiene-acrylonitrile copolymer having carboxyl group with an epoxy resin, wherein the content of component (e1) in the entire epoxy resin composition is 0.01 to 1% by weight. The composition exhibits excellent releasing property in molding, continuous molding property and resistance to solder reflow.Type: GrantFiled: March 15, 2006Date of Patent: December 8, 2009Assignee: Sumitomo Bakelite Company LimitedInventor: Yasuhiro Mizuno
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Patent number: 7615595Abstract: The present invention relates to an epoxy adhesive composition comprising a) a first epoxy resin, b) a second epoxy resin modified with a copolymer based on a 1,3-diene and a polar, ethylenically unsaturated comonomer, c) a toughener and d) a polymer comprising a polyester segment, said polymer being at least partially crystalline at room temperature and having a softening temperature in the range of 40° to 125° C. The invention further relates to the use of such an epoxy adhesive composition for bonding parts of a vehicle without prehardening of the epoxy adhesive composition and to a vehicle, parts of which are bonded by the epoxy adhesive composition.Type: GrantFiled: May 27, 2005Date of Patent: November 10, 2009Assignee: Dow Global Technologies, Inc.Inventors: Andreas Lutz, Jeannine Flueckiger, Karsten Frick
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Publication number: 20090186955Abstract: The present invention provides an adhesive composition which comprises (a) an epoxy resin, (b) a curing agent and (c) a polymer compound incompatible with said epoxy resin, and further optionally comprises (d) a filler and/or (e) a curing accelerator; a process for producing an adhesive composition, comprising: mixing (a) the epoxy resin and (b) the curing agent with (d) the fillers followed by mixing the resultant mixture with (c) the polymer compound incompatible with the epoxy resin; an adhesive film comprising the above-mentioned adhesive composition formed into a film; a substrate for mounting semiconductor comprising a wiring board and the above-mentioned adhesive film disposed thereon on its side where chips are to be mounted; and a semiconductor device which comprises the above-mentioned adhesive film or the substrate for mounting semiconductor.Type: ApplicationFiled: March 30, 2009Publication date: July 23, 2009Inventors: Teiichi INADA, Keiji Sumiya, Takeo Tomiyama, Tetsurou Iwakura, Hiroyuki Kawakami, Masao Suzuki, Takayuki Matsuzaki, Youichi Hosokawa, Keiichi Hatakeyama, Yasushi Shimada, Yuuko Tanaka, Hiroyuki Kuriya
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Publication number: 20090088497Abstract: The purposes of the present invention are to provide a paving material which is easy to be handled, has less restriction on the conditions of execution of work, decomposes fast, and is superior in durability, and a method for construction of paved body using the paving material. The purposes are attained by providing a paving material and a method for construction of paved body using the same, said paving material comprises at least binder emulsion for pavement, non-water soluble epoxy resin, and amine compound(s) a hardener thereof, and is prepared by mixing these three ingredients at the time of the execution of work, at the scene of the execution of work. The purposes are also attained by providing binder emulsion for pavement comprising an amine compound(s) that is a hardener of epoxy resin and the amine compound comprises at least polyaminoamido.Type: ApplicationFiled: August 23, 2006Publication date: April 2, 2009Applicants: PETRO CHEMICALS CO., LTD., NICHIREKI CO. LTD.Inventors: Yoshihito Sasada, Akito Hagiwara, Masahiko Fujii, Kazuma Takeuchi, Sadaharu Ueno, Takashi Kanazawa, Tada-aki Ikeda
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Patent number: 7498383Abstract: A thermoplastic composition comprises a polycarbonate, a polysiloxane-polycarbonate, and a gel-type low gloss additive, wherein the 60° gloss is measured to be less than or equal to 90 GU according to ASTM D2457. The thermoplastic composition has excellent impact strength and color capability. A method of making the thermoplastic composition, and an article comprising the thermoplastic composition are also disclosed.Type: GrantFiled: July 8, 2005Date of Patent: March 3, 2009Assignee: SABIC Innovative Plastics IP B.V.Inventors: Jing Chen, Theo Hoeks, Xinmin Yang
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Publication number: 20090011166Abstract: The present invention pertains to an adhesive tape composition for electronic components used for bonding electronic components used in semiconductor devices, e.g., leads, PRH, semiconductor chips, die pads, etc. In particular, the present invention concerns an adhesive tape composition excellent in electric reliability, adhesive strength and taping workability. The adhesive tape composition according to the present invention is characterized in that it contains acrylonitrile butadiene rubber (NBR) containing the carboxyl functional group at the end thereof, epoxy resin, phenol resin and one or more sorts of hardener selected from amine and acid anhydride hardeners.Type: ApplicationFiled: August 12, 2008Publication date: January 8, 2009Applicant: TORAY SAEHAN, INC.Inventors: Sang-Pil KIM, Hae-Sang Jun, Woo-Seok Kim, Se-Young Cha
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Patent number: 7432335Abstract: There are provided a composition for functioning as an effective additive for epoxy resin that is solid at room temperature and has high storage stability, and a method thereof. The composition of the present invention is a basic silane coupling agent organic carboxylate composition obtained by first synthesizing an organic carboxylate of a basic silane coupling agent by reacting a basic silane coupling agent and an organic carboxylic acid, and subsequently heating and mixing the organic carboxylate of the basic silane coupling agent with a compound exhibiting good affinity for the basic silane coupling agent or organic carboxylic acid and having a softening point or melting point of 40° C. or greater.Type: GrantFiled: June 1, 2006Date of Patent: October 7, 2008Assignee: Nikko Materials Co., Ltd.Inventors: Masashi Kumagai, Takashi Ouchi, Katsuyuki Tsuchida
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Patent number: 7423096Abstract: An underfill composition includes a thermosetting resin and a thermally cleavable component that releases sulfonic acid upon thermal activation. The underfill composition is applied to flip-chip technology during no-flow underfill mounting of the flip-chip to a mounting substrate. The mounting substrate can be further mounted on a board. A process includes formation of the underfill composition. A method includes assembly of the underfill composition with the flip-chip, and further can include assembly of the mounting substrate to a board. A computing system is also included that uses the underfill composition.Type: GrantFiled: September 29, 2004Date of Patent: September 9, 2008Assignee: Intel CorporationInventor: Saikumar Jayaraman
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Patent number: 7393895Abstract: A method of forming a poly(arylene ether)-containing solid concentrate is described. The method includes blending a poly(arylene ether), a thermosetting resin, and a compatibilizing agent in the presence of a solvent to form a homogeneous solution, and removing the solvent to yield the solid concentrate. The solid concentrate is useful for preparing curable conditions.Type: GrantFiled: August 23, 2007Date of Patent: July 1, 2008Assignee: Sabic Innovative Plastics IP B.V.Inventors: Michael John Davis, James Estel Tracy
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Patent number: 7348057Abstract: An adhesive sheet made of an acrylic adhesive composition comprising (A) an acrylic polymer containing carboxyl groups and having a Tg of 5-30° C., (B) a resol phenolic resin, (C) an epoxy resin, and (D) a curing accelerator has improved heat resistance, processing and handling as well as good adhesion, and is suited for use in the manufacture of FPC.Type: GrantFiled: November 9, 2004Date of Patent: March 25, 2008Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazunori Kondo, Shigehiro Hoshida, Michio Aizawa, Tadashi Amano
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Patent number: 7323521Abstract: Comb polymers prepared by reacting an epoxy resin and a lactone are disclosed. These comb polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described comb polymers are also disclosed.Type: GrantFiled: March 19, 2004Date of Patent: January 29, 2008Assignee: PP6 Industries Ohio, Inc.Inventors: Michael J. Ziegler, Anthony M. Chasser, Jackie L. Kulfan
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Patent number: 7323242Abstract: A heat-curable binder based on an aqueous polymer dispersion comprising an emulsion polymer (EP), a polymer composed of at least 5% by weight of an ethylenically unsaturated monocarboxylic acid, dicarboxylic acid or dicarboxylic anhydride (acid polymer SP for short), and monofunctional or polyfunctional epoxide compounds as curatives. The monofunctional or polyfunctional epoxide compound is stirred, preferably in the liquid state, into the aqueous polymer dispersion. Besides the epoxide compound, the heat-curable binder may further comprise a polyol or an alkanolamine as hardener.Type: GrantFiled: October 18, 2002Date of Patent: January 29, 2008Assignee: BASF AktiengesellschaftInventors: Matthias Gerst, Matthias Laubender, Bernd Reck
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Patent number: 7262261Abstract: Condensation products of dihydroxyaromatics A, alone or in mixture with mono- or polyhydroxyaromatics C, with diepoxides or polyepoxides B which have been alkylolated by reaction with aldehydes D and whose alkylol groups may have been etherified with alcohols, a process for preparing them, and a method of use thereof in particular as compositions for coating the inside of foodstuff and beverage packaging forms made from metals.Type: GrantFiled: November 6, 2003Date of Patent: August 28, 2007Assignee: Surface Specialities Germany GmbH & Co. KGInventors: Gerhard Brindöpke, Oliver Etz, Paul Oberressl, Bodo Wixmerten
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Patent number: 7193016Abstract: In accordance with the present invention, there are provided toughening agents which are useful for improving the performance properties of epoxy-based adhesive formulations. For example, epoxidized polybutylacrylates have been found to be useful toughening agents of component level underfill adhesive compositions. Invention materials are generally liquid rubbers which provided improved fracture toughness while maintaining satisfactory capillary flow properties. Invention materials can be synthesized in neat (solventless) reactions from readily available low-cost raw materials and isolated in high yields. They have a branched telechelic structure with terminal epoxide functional groups. The polyacrylate is typically obtained as a mixture of epoxidized polymer, chain extended polyoligomer and unreacted monomer. Invention materials are compatible with common epoxy formulations and may be used without purification.Type: GrantFiled: October 27, 2003Date of Patent: March 20, 2007Assignee: Henkel CorporationInventors: John G. Woods, Mark M. Konarski, Kyra M. Kozak, Yuhshi Luh
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Patent number: 7101933Abstract: A process for producing high speed transmitting dielectric materials comprises essentially mixing and reacting a proportion of polyphenylene ether (PPE) with a proportion of an epoxy resin of the type of low bromine content in a non-polar solvent in the presence of a catalyst in a reactor at a temperature of 90° C. to 220° C., characterized in that, in the course of the reaction, PPE needs not to be cleaved into small molecules and in stead, can mix and react directly with the epoxy resin to thereby produce a high speed transmitting dielectric material. The process of the invention can reduce greatly the synthetic reaction time, and is applicable in the production of the material useful in printed circuit board for wireless communication, base station and the like.Type: GrantFiled: December 10, 2003Date of Patent: September 5, 2006Assignee: Uniplus Electronics Co., Ltd.Inventors: Chen-Yu Hsieh, Ming-Cheng Hsiao, Tai-Wen Chien
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Patent number: 7094845Abstract: There is provided a composition for functioning as an effective additive for an epoxy resin that is a solid at room temperature and has a high storage stability, and a method thereof. The composition of the present invention is a basic silane coupling agent organic carboxylate composition obtained by first synthesizing an organic carboxylate of a basic silane coupling agent by reacting a basic silane coupling agent and an organic carboxylic acid, and subsequently heating and mixing the organic carboxylate of the basic silane coupling agent with a compound exhibiting a good affinity for the basic silane coupling agent or organic carboxylic acid and having a softening point or melting point of 40° C. or greater.Type: GrantFiled: August 27, 2002Date of Patent: August 22, 2006Assignee: Nikko Materials Co., Ltd.Inventors: Masashi Kumagai, Takashi Ouchi, Katsuyuki Tsuchida
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Patent number: 7087664Abstract: A resin film comprising (A) an epoxy resin having two or more glycidyl groups in a molecule, (B) an epoxy resin curing agent, (C) a thermoplastic resin, and (D) a filler, wherein the filler content in at least either one of the surface regions on the cross-section of the film is less than the filler concentration in the central region. The resin film has not only toughness but also fire retardancy, high interlayer adhesion strength and good processability of metal plating.Type: GrantFiled: January 23, 2004Date of Patent: August 8, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Toshiaki Hayashi, Katsuhiro Furuta
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Patent number: RE39615Abstract: The invention relates to an adhesive composition, comprising: (A) at least one phenolic resole resin; and (B) the product made by reacting (B-1) at least one difunctional epoxy resin, with (B-2) at least one compound represented by the formula wherein in Formulae (I) and (II): G, T and Q are each independently functional groups selected from the group consisting of COOH, OH, SH, NH2, NHR1, (NHC(?NH))mNH2, R2COOH, NR12, C(O)NHR1, R2NR12, R2OH, R2SH, R2NH2 and R2NHR1, wherein R1 is a hydrocarbon group, R2 is an alkylene or alkylidene group and m is a number in the range of 1 to about 4; T can also be R1, OR1 or SO2C6H4—NH2; and Q can also be H. The invention also relates to copper foils having the foregoing adhesive composition adhered to at least one side thereof to enhance the adhesion between said foils and dielectric substrates.Type: GrantFiled: October 17, 2002Date of Patent: May 8, 2007Assignee: Nikko Materials USA, Inc.Inventor: Charles A. Poutasse