With Nitrogen-containing Reactant, Or Wherein The Poly 1,2-epoxy Reactant Contains A Nitrogen Atom Patents (Class 525/113)
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Patent number: 4503174Abstract: A low temperature curing coating composition containing 10-80% by weight of binder and 20-90% by weight of an organic solvent in which the binder is(1) an acrylic polymer containing monomers having reactive groups such as acrylamide, methacrylamide, methacrylic acid, acrylic acid and glycidyl methacrylate,(2) an epoxy resin,(3) a polyamine curing agent,(4) phenol and(5) a bicyclic amindine;The composition is used as a primer or topcoating for metal substrates and curings at temperatures of 0.degree. C. to ambient temperatures and provides a primer that has excellent adhesion to the substrate and provides a durable, corrosion resistant finish.Type: GrantFiled: September 6, 1983Date of Patent: March 5, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventor: Joseph A. Vasta
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Patent number: 4500660Abstract: An epoxy resin composition having excellent adhesive and high mechanical strength is disclosed. The composition comprises:(A) a bisphenol A type epoxy resin present in an amount of at least 45 wt % of the total epoxy resin;(B) a novolak type epoxy resin present in an amount of at least 8 wt % of the total epoxy resin;(C) a glycidyl amine type epoxy resin (including the one used in (D)) present in an amount of at least 15 wt % of the total epoxy resin;(D) a reaction product of a butadiene-acrylonitrile copolymer having carboxyl groups on at least both ends of the molecule and a glycidyl amine type epoxy resin, said butadiene-acrylonitrile copolymer being present in an amount of 1.Type: GrantFiled: April 18, 1983Date of Patent: February 19, 1985Assignee: Toho Belson Co., Ltd.Inventors: Tsuyoshi Minamisawa, Yasuo Kogo, Yasuhisa Nagata
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Patent number: 4486571Abstract: A novel crosslinkable coating composition suitable for use in cathodic electrodeposition of coating to retard corrosion of substrates is provided, which coating composition comprises:A. crosslinkable resin, optionally at least partially neutralized, comprising the reaction product of:(a) substantially non-gelled epoxy-modified polybutadiene, comprising the reaction product of:(i) diamine functionalized polybutadiene reactant of number average molecular weight about 500 to about 5000; with(ii) monoepoxide reactant of number average molecular weight about 30 to about 500; and with(iii) diepoxide reactant of number average molecular weight about 100 to about 1000;the diamine functionalized polybutadiene reactant bearing two secondary amine functionality and being reacted with said monoepoxide reactant and diepoxide reactant in relative molar ratio of about 1:0.9-1.1:0.9-1.Type: GrantFiled: January 5, 1983Date of Patent: December 4, 1984Assignee: Ford Motor CompanyInventor: Joseph W. Holubka
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Patent number: 4485200Abstract: Conventional carboxylated neoprene latex adhesives are improved with respect to their metal adhesion, heat and water resistance and bonding range by the addition thereto of an epoxy resin, preferably an epoxy resin prepared by the reaction of para-aminophenol with epichlorohydrin.Type: GrantFiled: February 3, 1982Date of Patent: November 27, 1984Assignee: National Starch and Chemical CorporationInventors: Witold Perlinski, Irwin J. Davis, John F. Romanick
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Patent number: 4482660Abstract: A prepreg for making a composite is disclosed. The prepreg comprising reinforcing fibers impregnated with a resin composition comprising (A) an epoxy resin, (B) a reaction product of an epoxy resin and a butadiene-acrylonitrile copolymer having carboxyl groups on at least both terminals of the molecular chain of the copolymer, and (C) 4,4'-diaminodiphenylsulfone as a curing agent. A composite produced by curing this prepreg is high in both tensile elongation and heat resistance and is used with advantage as primary and secondary structural materials in aircraft.Type: GrantFiled: January 14, 1983Date of Patent: November 13, 1984Assignee: Toho Beslon Co., Ltd.Inventors: Tsuyoshi Minamisawa, Masato Andoh
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Patent number: 4482673Abstract: Non-gelled compositions containing hydroxy ester copolymer having carboxyl groups and substantially free of oxirane groups and the method of making them are disclosed which are the esterification reaction product of(A) acidic addition copolymer; and(B) epoxy resin including aromatic polyether containing oxirane groups in which the epoxy resin comprises at least 40% of the total resin solids and contains insufficient oxirane groups to react with all of the carboxyl groups in the copolymer; in which esterification is conducted in the presence of higher than the normal amount of amine catalyst, i.e., 1.5% or more. The resulting composition is neutralized with amine, is self-emulsifiable in water and is useful for coatings, e.g., for cans.Type: GrantFiled: May 14, 1982Date of Patent: November 13, 1984Assignee: SCM CorporationInventors: George L. Brown, Miksa de Sorgo, Arthur T. Spencer
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Patent number: 4480084Abstract: This invention is directed to polymeric compounds which contain the polyalkylpiperidine radical and at least two primary hydroxyl groups. These compounds are useful as light stabilizers for plastics and coatings. More particularly, the polymeric stabilizers is formed by chain extending polyalkylpiperidine with an excess of epoxy resin to form a diepoxide functional polymer which is then capped with hydroxy functional monomer.Type: GrantFiled: October 13, 1983Date of Patent: October 30, 1984Assignee: Ford Motor CompanyInventors: Panagiotis I. Kordomenos, Delores J. Alexander, David M. Thomson
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Patent number: 4480058Abstract: Sanitary coatings based on self-emulsifiable epoxy ester copolymers are produced by esterifying a solvent-soluble carboxyl polymer with an epoxy resin in an organic resin and in the presence of at least about 2% amine catalyst to provide a carboxyl-functional epoxy polymer which can be reacted with a base and dispersed into water.Type: GrantFiled: January 6, 1981Date of Patent: October 30, 1984Assignee: SCM CorporationInventors: Vincent W. Ting, Richard M. Marcinko
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Patent number: 4477629Abstract: New compositions of matter are disclosed which comprise (1) a cyanate-containing polymer or mixture thereof and optionally (2) a polycyanate or mixture thereof and/or (3) an epoxy resin. These compositions are thermosettable upon heating in the presence of suitable curing agents or catalysts.Type: GrantFiled: July 27, 1983Date of Patent: October 16, 1984Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 4476285Abstract: A rubber-modified epoxy adhesive and the method of making the same is dissed for use in bonding graphite-epoxy composite structures. The adhesive comprises a two-part formulation, one part being a reaction product of a carboxyl terminated reactive liquid rubber prereacted with a bisphenol A epoxy resin so that linear epoxy-rubber chains are developed. The second part of the adhesive is an amine curing agent. One effective example of the adhesive is formulated as follows: approximately 4 parts by weight of the bisphenol A epoxy resin is mixed per part of a carboxyl terminated butadiene acrylonitrile rubber and heated to 170.degree. C. At 160.degree. C., a catalyst of approximately 0.01 parts by weight of triphenyl phosphene per part of the rubber is added and the mixture stirred for one hour at 170.degree.-175.degree. C. to provide the reaction product.Type: GrantFiled: March 2, 1983Date of Patent: October 9, 1984Assignee: The United States of America as represented by the Secretary of the NavyInventors: David J. Crabtree, Elizabeth Y. Park
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Patent number: 4468497Abstract: A novel bis-imide matrix resin system especially useful for high temperature, high performance, graphite fiber composites is disclosed. Microcracking of composites is reduced and transverse strength is increased by the addition to the resin system of 1 to 15 percent of compatible elastomers, such as polyether sulfones, bis-phenol linear homopolymeric epoxies or polyacrylic esters. The resin system comprises 50 to 95 percent by weight of ethylenically unsaturated bis-imides, preferably a low melting mixture of a major portion of maleimides of aromatic amines with a minor portion of maleimides of an aliphatic amine and 5 percent to 35 percent by weight of a diunsaturated low-temperature cross-linking agent such as divinyl benzene which gels the bis-imide at low temperatures. Room temperature tackiness, heat resistance and cross-link density are improved by the presence of 1 to 10 percent of a trifunctional curing agent.Type: GrantFiled: January 24, 1983Date of Patent: August 28, 1984Assignee: HitcoInventors: Sidney W. Street, Don A. Beckley
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Patent number: 4467071Abstract: Structural adhesive systems having improved heat resistance comprising a solution or dispersion of a polymeric material in a monomer copolymerizable therewith, an unsaturated organophosphorus partial ester and an epoxy resin are disclosed.Type: GrantFiled: September 13, 1982Date of Patent: August 21, 1984Assignee: Lord CorporationInventor: Terrance H. Dawdy
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Patent number: 4465542Abstract: An adhesive composition containing: (a) a nitrogen atom-free epoxy compound, (b) a poly N-glycidyl type epoxy resin, (c) a nitrile rubber having a carboxyl group, and optionally (d) a finely divided silica, a clay substance treated with an onium compound, or a mixture thereof. The compounding ratio by weight of the components (a), (b), (c) and (d) is as follows:0.05.ltoreq.(b)/(a).ltoreq.190.05.ltoreq.[(a)+(b)]/(c).ltoreq.1.750.0125.ltoreq.(d)/(c).ltoreq.0.75This adhesive composition has excellent adhesion strength, soldering heat resistance, flexibility, and chemical resistance, and has a small resin flow property.Type: GrantFiled: February 17, 1983Date of Patent: August 14, 1984Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Toshikazu Furihata
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Patent number: 4463110Abstract: The metal adhesion and heat and water resistance of conventional neoprene latex adhesives are improved by the addition thereto of a polyfunctional amine and an epoxy resin wherein for every 100 parts by weight of dry neoprene, the epoxy is added in an amount of 10-40 parts and the amine is added in an amount sufficient to provide 50-150% of the stoichiometric amount required to cure the epoxy.Type: GrantFiled: February 18, 1982Date of Patent: July 31, 1984Assignee: National Starch and Chemical CorporationInventors: Witold Perlinski, Irwin J. Davis, John F. Romanick
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Patent number: 4463134Abstract: Modified epoxy resin compositions having excellent flexibility and excellent compatibility with conventional epoxy resins as well as exhibiting the original properties of the epoxy resin before being modified such as mechanical strength, adhesion, heat resistance are disclosed and chemical resistance, which are obtained by treating an epoxy resin with at least one modified adduct [D] of a conjugated diene polymer or copolymer which has an imido bond and/or amido bond and a semi-ester structure and has an acid value owing to a free carboxyl group of 5 to 100. The modified adduct is obtained by reacting an adduct [A] of a polymer of a conjugated diene having a number average molecular weight of 300 to 20,000 or a copolymer of the conjugated diene and a vinyl monomer with an .alpha.,.beta.-unsaturated dicarboxylic acid or its anhydride, with a compound [B] containing one primary amino group in the molecule and a compound [C] containing a hydroxy group in the molecule.Type: GrantFiled: December 22, 1981Date of Patent: July 31, 1984Assignees: Sumitomo Chemical Company, Limited, Tohto Kasei Co., Ltd.Inventors: Minoru Hino, Takao Oshima, Akihiro Tachibana
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Patent number: 4454283Abstract: A novel bis-imide matrix resin system comprising 50 to 95 percent by weight of ethylenically unsaturated bis-imides, preferably a low melting mixture of a major portion of maleimides of aromatic amines such as toluene diamine and methylene dianiline with a minor portion of maleimide of an aliphatic amine such as trimethyl hexamethylene diamine and 5 percent to 35 percent by weight of a diunsaturated low-temperature cross-linking agent such as divinyl benzene which gels the bis-imide at low temperatures. This reduces stress between the matrix resin and the surface of the reinforcing fiber, thus reducing the tendency to form microcracks. Room temperature stability is improved by the presence of 0.5 to 5 percent of an oxidation inhibitor such as hydroquinone. The resin is useful as a matrix resin for high performance, graphite fiber reinforced composites.CROSS REFERENCE TO RELATED APPLICATIONThis application is a continuation of Ser. No. 248,978, filed Mar. 30, 1981, now U.S. Pat. No.Type: GrantFiled: January 24, 1983Date of Patent: June 12, 1984Assignee: HITCOInventors: Sidney W. Street, Don A. Beckely
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Patent number: 4447579Abstract: The present invention relates to a room temperature curable epoxy resin adhesive composition having excellent T-peel strength, comprising an epoxy resin containing more than one epoxy group in a molecule on an average, and a hardener in the form of a polyamide-amine, which is obtained from reaction of polyamine with diene rubber having carboxyl terminal groups and other compound having carboxyl groups.Type: GrantFiled: April 20, 1982Date of Patent: May 8, 1984Assignees: Cemedine Co., Ltd., Tohto Kasei Co., Ltd.Inventors: Yasuo Takagi, Michiharu Horibe
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Patent number: 4435383Abstract: This invention relates to a one-phase, solid controlled release pesticidal composition consisting essentially of a pesticide in homogeneous combination with a cross-linked copolymer prepared from hydrophobic monomers, selected from styrene and .alpha.-methyl styrene, and carboxylic acid-containing monomers.Type: GrantFiled: July 22, 1981Date of Patent: March 6, 1984Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert D. Wysong
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Patent number: 4427802Abstract: A curable composition, and composites comprising (A) an epoxy resin and (B) a heterocyclic compound prepared by reacting at least one aromatic or aliphatic polyamine compound having at least two amine groups, which are separated by no more than one carbon atom, with at least one carbonyl-containing compound selected from the group consisting of aldehydes and ketones.Type: GrantFiled: July 27, 1981Date of Patent: January 24, 1984Assignee: Hexcel CorporationInventors: Richard J. Moulton, John D. Neuner
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Patent number: 4423172Abstract: A self-curable coating composition for cathode-precipitating electrodeposition is disclosed which essentially comprises a water-dispersible resin having a carbon-carbon double bond and a tertiary amino group and an epoxy resin having a teritary amino group and an unsaturated group of the formula ##STR1## The two resins are neutralized by an acid to render the composition water-soluble or water-dispersible.Type: GrantFiled: March 30, 1982Date of Patent: December 27, 1983Assignee: Nippon Oil Co., Ltd.Inventors: Yutaka Otsuki, Yoshihiko Araki, Hiroyoshi Omika, Hajime Hara, Kazuho Aoyama
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Patent number: 4421897Abstract: One-component systems which are stable on storage and can be converted to crosslinked epoxide resins on heating and which contain a crystalline epoxide resin with, on average, more than one epoxide group per molecule and a melting point between 40.degree. and 150.degree. C., and, homogeneous distribution, a curing catalyst.Type: GrantFiled: December 7, 1981Date of Patent: December 20, 1983Assignee: Ciba-Geigy CorporationInventors: Ferdinand Gutekunst, Hans Lehmann, Rolf Schmid
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Patent number: 4421878Abstract: The invention herein disclosed provides a method for preparing improved fluoroelastomer film compositions including the steps of dissolving a fluoroelastomer gum selected from the group consisting of copolymers of vinylidene fluoride and hexafluoropropylene, and terpolymers of vinylidene fluoride, hexafluoropropylene and tetrafluoroethylene in a solvent, adding an amine-derived curative to the gum solution and curing the fluoroelastomer gum with the curative in the absence of metallic oxides. A method is also provided for adhering fluoroelastomer film compositions, devoid of metallic oxides, to substrates which includes the steps of dissolving the fluoroelastomer gum in a solvent, adding an amine-derived curative to the gum solution, coating the substrate with the fluoroelastomer gum-curative solution and evaporating the solvent leaving a film firmly adhered to the substrate.Type: GrantFiled: November 25, 1981Date of Patent: December 20, 1983Assignee: David Hudson, Inc.Inventor: Donald Close
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Patent number: 4420574Abstract: Ungelled resins, aqueous dispersions of cationic resins, coating compositions, and electrodeposition using the resinous coating compositions are disclosed. The resins are formed from reacting polyepoxides with polyoxyalkylenepolyamines. The aqueous dispersions are prepared by at least partially neutralizing the resins to provide cationic groups and dispersing the cationic resins in aqueous medium. When added to cationic electrode-positable coating compositions, such as high throwpower compositions, the ungelled cationic resins provide better appearing, more flexible and water-resistant electrodeposited coatings.Type: GrantFiled: September 20, 1982Date of Patent: December 13, 1983Assignee: PPG Industries, Inc.Inventors: Thomas C. Moriarity, William J. Geiger
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Patent number: 4419495Abstract: The gloss of epoxy resin powder coatings is reduced by employing as the curing agent therefor or as a portion of the curing agent therefor, a polymer of two or more polymerizable ethylenically unsaturated monomers, at least one of which contains a group which is reactive with a vicinal epoxy group.Type: GrantFiled: August 23, 1982Date of Patent: December 6, 1983Assignee: The Dow Chemical CompanyInventor: Rhetta Q. Davis
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Patent number: 4401499Abstract: A crosslinked resin excellent in heat resistance, toughness, moisture resistance and adhesiveness can be obtained by the use of an epoxy compound having both alcoholic hydroxyl groups and epoxy groups in its molecule and an isocyanate compound having isocyanate groups in its molecule by first reacting the alcoholic hydroxyl groups of said epoxy compound and the isocyanate groups of said isocyanate compound to produce an epoxy prepolymer having urethane linkages stable at room temperature, followed by dissociating the urethane linkages of the prepolymer to regenerate the isocyanate groups and reacting said isocyanate groups with the epoxy groups of said epoxy compound.Type: GrantFiled: December 1, 1981Date of Patent: August 30, 1983Assignee: Sumitomo Bakelite Company LimitedInventors: Shoroku Kaneko, Sigenori Yamaoka, Masuo Mizuno, Yukihiro Okabe
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Patent number: 4388451Abstract: A copolymer formed by reacting maleic anhydride or a maleimide or a mixture of these with an allylphenol, a methallylphenol, or substituted allyl or methallylphenol. The anhydride polymers are characterized as having a 1:1 molar ratio of maleic anhydride to phenol or substituted phenol. The maleic anhydride copolymers are water soluble materials, useful as epoxy resin modifiers and curatives, as ion exchange resins or membranes, laminates, and detergent additives and builders. The maleimide containing copolymers are also useful as epoxy resin modifiers and useful in the production of laminates, composites and coatings.Type: GrantFiled: September 28, 1981Date of Patent: June 14, 1983Assignee: Ashland Oil, Inc.Inventors: Billy M. Culbertson, Larry K. Post, Ann E. Aulabaugh
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Patent number: 4384093Abstract: Copolymers and terpolymers formed by reacting either 4,7-dihydro-1,3-dioxepins or 6,7-dihydro-1,3-dioxepins with maleic anhydride and/or a maleimide. The copolymers are characterized as linear, low molecular weight, water soluble alternating copolymers. These copolymers are useful as a water soluble polymer, as epoxy resin modifies and curing agents. The copolymers formed from 4,7-dihydro-1,3-dioxepins and maleic anhydride can be rearranged to form a poly (.gamma.Type: GrantFiled: April 15, 1981Date of Patent: May 17, 1983Assignee: Ashland Oil, Inc.Inventors: Billy M. Culbertson, Ann E. Aulabaugh
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Patent number: 4379728Abstract: This invention is directed to latent thermal curing agents for epoxy resins comprising cyanourea compounds of the formula: ##STR1## wherein R is the organic moiety of a mono- or poly-isocyanate remaining after reaction of the isocyanate group or groups to form cyanourea groups and n is 1 or more, preferably 1 to 2. The epoxy-curing agent system is stable at room temperature and cures at temperatures above 100.degree. C. to form a crosslinked, solid material suitable as an adhesive, sealant or coating. The polymeric form polymerized from dicyanourea compound can be dissolved in a solvent and admixed with an epoxy resin to form a thermoset adhesive, sealant or coating on heating above 100.degree. C. The polymeric form from the combination of cyanourea and dicyanourea or dicyanourea per se dissolving in epoxy resin also forms a thermosetting adhesive, sealant or coating on heating above 100.degree. C.Type: GrantFiled: February 4, 1982Date of Patent: April 12, 1983Assignee: W. R. Grace & Co.Inventor: Shiow C. Lin
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Patent number: 4379872Abstract: Amphoteric amino sulfonate derivatives of epoxy resins having at least one terminal group of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen or methyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.20 alkyl or substituted alkyl, and R.sub.4 is C.sub.1 -C.sub.6 alkylene or substituted alkylene, which are reaction products of an epoxy resin having a plurality of terminal groups of the formula: ##STR2## wherein R.sub.1 and R.sub.2 are as defined, with an amino sulfonate of the formula:R.sub.3 --NH--R.sub.4 --SO.sub.3 Mwherein R.sub.3 and R.sub.4 are as defined, and M is a cation.Type: GrantFiled: August 17, 1981Date of Patent: April 12, 1983Assignee: Nippon Paint Co., Ltd.Inventors: Shin-Ichi Ishikura, Kazunori Kanda, Ryuzo Mizuguchi
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Patent number: 4371665Abstract: Modified epoxy resin composition having excellent flexibility and excellent compatibility with conventional epoxy resins as well as the original properties of the epoxy resin before modified such as mechanical strength, adhesion, heat resistance and chemical resistance, which is obtained by treating an epoxy resin with at least one modified adduct [D] of a conjugated diene polymer or copolymer which has an imido bond and/or amido bond and a semi-ester structure and has an acid value owing to a free carboxyl group of 5 to 100, said modified adduct being obtained by reacting an adduct [A] of a polymer of a conjugated diene having a number average molecular weight of 300 to 20,000 or a copolymer of the conjugated diene and a vinyl monomer with an .alpha.,.beta.-unsaturated dicarboxylic acid or its anhydride, with a compound [B] of the formula: ##STR1## and a compound [C] of the formula:R.sub.3 --CH.sub.2).sub.m OH [II].Type: GrantFiled: December 22, 1981Date of Patent: February 1, 1983Assignees: Sumitomo Chemical Company, Limited, Tohto Kasei Co., Ltd.Inventors: Minoru Hino, Takao Oshima
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Patent number: 4365043Abstract: A process for preparing resinous particles for a coating composition, which comprises the steps of (1) subjecting an aqueous resin composition having an ionic group and no material solubility or dispersibility in water is dissolved or dispersed in an aqueous medium by at least partly neutralizing the ionic group to treatment with a powdering agent while applying thereto an operation for pulverization to deposit the resin in a particulate form and (2) recovering the deposited resinous particles from the aqueous medium.Type: GrantFiled: March 14, 1977Date of Patent: December 21, 1982Assignee: Nippon Paint Co., Ltd.Inventors: Sakuichi Konishi, Yukio Omori, Hiroyoshi Kataoka
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Patent number: 4351932Abstract: A novel bis-imide matrix resin system comprising 50 to 95 percent by weight of ethylenically unsaturated bis-imides, preferably a low melting mixture of a major portion of maleimides of aromatic amines with a minor portion of maleimide of an aliphatic amine and 5 percent to 35 percent by weight of a diunsaturated low-temperature cross-linking agent such as divinyl benzene which gels the bis-imide at low temperatures. This reduces stress between the matrix resin and the surface of the reinforcing fiber, thus reducing the tendency to form microcracks. Microcracking is further reduced and transverse strength is increased by the addition of 0 to 15% of compatible elastomers to the resin and cross-linking agent. Room temperature tackiness, heat resistance and cross-link density are improved by the presence of 0 to 10% of a trifunctional curing agent.Type: GrantFiled: March 27, 1980Date of Patent: September 28, 1982Assignee: HitcoInventors: Sidney W. Street, Don A. Beckley
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Patent number: 4349645Abstract: Protective coating powder comprising a polyglycidyl ether of bisphenol A and trimellitic anhydride has improved shelf stability when it contains a hindered nitrogen-containing compound such as N,N-diethylaniline.Type: GrantFiled: August 5, 1981Date of Patent: September 14, 1982Assignee: Minnesota Mining and Manufacturing CompanyInventor: Allen L. Griggs
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Patent number: 4344875Abstract: An antifouling coating composition includes an antifouling compound formed f the esterification product of tributyltin oxide combined with the copolymer of styrene and maleic anhydride. The antifouling compound is combined with a blend of selected Bisphenol A epoxy and polyacrylate resins, solvent, fillers, pigment, and amine based curing agent to provide a durable marine coating which exhibits controlled leaching of antifoulant.Type: GrantFiled: June 26, 1981Date of Patent: August 17, 1982Assignee: The United States of America as represented by the Secretary of the NavyInventor: Albert R. Parks
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Patent number: 4342843Abstract: The metal adhesion and heat and water resistance of conventional neoprene latex adhesives are improved by the addition thereto of a polyamine and an epoxy resin wherein for every 100 parts by weight of dry neoprene, the epoxy is added in an amount of 10-40 parts and the amine is added in an amount sufficient to provide 50-150% of the stoichiometric amount required to cure the epoxy.Type: GrantFiled: February 24, 1981Date of Patent: August 3, 1982Assignee: National Starch and Chemical Corp.Inventors: Witold Perlinski, Irwin J. Davis, John F. Romanick
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Patent number: 4338236Abstract: An acrylic polyamine copolymer with amine and hydroxy functionality. The copolymer can be formulated with auxiliary resins and optional crosslinkers to make a nearly-neutral pH cathodic dispersion and the formulations can be used in cathodic electrodeposition, giving good cure response at 150.degree.-175.degree. C.Type: GrantFiled: December 29, 1980Date of Patent: July 6, 1982Assignee: E. I. Du Pont de Nemours and CompanyInventor: Isidor Hazan
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Patent number: 4337187Abstract: A cationic electrocoating composition containing a polyhydroxyamine and polyesters or alkyds and optionally a crosslinker resin.Type: GrantFiled: December 29, 1980Date of Patent: June 29, 1982Assignee: E. I. DuPont de Nemours and CompanyInventor: Isidor Hazan
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Patent number: 4335031Abstract: A cationic electrocoating composition containing a polyhydroxyamine and polybutadiene and optionally a crosslinker resin.Type: GrantFiled: December 29, 1980Date of Patent: June 15, 1982Assignee: E. I. Du Pont de Nemours and CompanyInventor: Isidor Hazan
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Patent number: 4333869Abstract: This invention relates to self-extinguishing polymeric compositions, comprising a thermoplastic polymer, preferably a polyolefin, and an anti-flame additive consisting of:(1) 10-25% by weight, on the total composition, of an ammonium or amine phosphate; and(2) 10-25% by weight, on the total composition, of a product obtained by reacting in bulk, at a temperature comprised between 80.degree. C. and 230.degree. C.,(a) at least one organic compound selected from the group consisting of(i) linear or cyclic nitrogen containing compounds having at least one >C.dbd.O or >C.dbd.S group and at least one --NH--group being part of the linear chain or of the ring, and(ii) amino-triazine compounds; with(b) an epoxyalkyl ester of isocyanuric acid of the formula: ##STR1## wherein n is an integer from 1 to 3; the reaction being carried out according to a molar ratio (a):(b) comprised between 3:1 and 0.1:1.Type: GrantFiled: September 15, 1980Date of Patent: June 8, 1982Assignee: Montedison S.p.A.Inventors: Franco Marciandi, Pasquale Relvini
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Patent number: 4332713Abstract: A liquid or pasty thermosetting adhesive which can be pre-gelled, which is suitable for the bonding of moulded parts or for the sealing of folded seams, and which contains (a) a liquid epoxide resin having on average more than one epoxide group in the molecule, and (b) a latent epoxide curing agent insoluble in the epoxide resin, the adhesive being characterized in that it also contains (c) in an amount of 5 to 50 percent by weight relative to the epoxide resin, at least one halogen-free thermoplast in powder form, which is insoluble in the epoxide resin at room temperature, and which has a softening point of between 60.degree. and 160.degree. C., such as a polyethylene, a polypropylene or an ethylene/acrylic acid/acrylate terpolymer.Type: GrantFiled: October 29, 1980Date of Patent: June 1, 1982Assignee: Ciba-Geigy CorporationInventor: Hans Lehmann
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Patent number: 4324713Abstract: A two-package solventless rust preventive material comprises (A) a sprayable component essentially containing a liquid epoxy resin and a liquid polycarboxylic acid anhydride and (B) a sprayable component essentially containing a liquid primary or secondary amino compound and a curing accelerator, at least one of said components (A) and (B) essentially comprising a non-reactive epoxy resin diluent having a molecular weight of 300 to 4,000 and an electrically conductive powder.Type: GrantFiled: February 4, 1980Date of Patent: April 13, 1982Assignees: Nippon Zeon Co. Ltd., Nisson Motor Co. Ltd.Inventors: Ryuji Kita, Hisataka Komai, Makoto Wakabayashi, Haruyoshi Takagishi
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Patent number: 4322508Abstract: A high solids, thermosetting coating composition which, exclusive of pigments, solvents and other nonreactive components consists essentially of:(A) A hydroxy functional component consisting of:(1) between about 1 and about 90 weight percent of an oligoester (i) having a number average molecular weight (M.sub.n) of between about 150 and about 3000 (ii) bearing at least about 2 hydroxyl groups and (iii) being formed by an esterification reaction between a carboxylic acid and an epoxide; and(2) between about 99 and about 10 weight percent of a hydroxy functional copolymer having a number average molecular weight (M.sub.Type: GrantFiled: June 9, 1980Date of Patent: March 30, 1982Assignee: Ford Motor CompanyInventors: Stephen C. Peng, David M. Thomson
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Patent number: 4316967Abstract: Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s).Type: GrantFiled: March 5, 1979Date of Patent: February 23, 1982Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
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Patent number: 4316979Abstract: Compositions of matter comprising a liquid thiol terminated polysulfide polymer, a liquid epoxy resin and a liquid amine terminated polymer containing from about 1.7 to about 4 amine groups per molecule of the general formula ##STR1## wherein Y is a univalent radical derived by removal of an amine hydrogen from an aliphatic, alicyclic, heterocyclic or aromatic amine containing from 2 to about 20 carbon atoms and at least 2 amino groups and B is a polymeric backbone comprising carbon-carbon linkages are disclosed. Insulated window units fabricated therefrom possess superior mechanical and dewpoint retention properties.Type: GrantFiled: August 11, 1980Date of Patent: February 23, 1982Assignee: Thiokol CorporationInventor: Henry N. Paul, 3rd
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Patent number: 4316002Abstract: Novel thermosetting compositions, including a polyimide/N-vinylpyrrolidone prepolymer, optionally comprising an unsaturated polyester, and an epoxy resin, are well adapted for the molding of a variety of useful shaped articles.Type: GrantFiled: October 23, 1979Date of Patent: February 16, 1982Assignee: Rhone-Poulenc IndustriesInventors: Robert Cassat, Gerard Guillot
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Patent number: 4299747Abstract: Coating compositions which may be applied by conventional techniques as well as by electrodeposition are provided by reacting a polyglycidyl ether of a polyphenol with an amino acid containing at least one amine group and one carboxyl group, wherein the amine group of the acid is preferentially reactive with the epoxy groups of the polyglycidyl ether. The resultant product can then be solubilized by neutralizing at least a portion of the acid functionality thereof with an amine or other base. Especially useful amino acids are the aminobenzoic acids.Type: GrantFiled: March 8, 1977Date of Patent: November 10, 1981Assignee: PPG Industries, Inc.Inventor: William J. Birkmeyer
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Patent number: 4299926Abstract: Condensation polymers or addition polymers which contain sterically hindered polyalkylpiperidine groups are proposed as light stabilizers for plastics. The polymers concerned are relatively low-molecular polymers and a difunctional derivatives of a polyalkylpiperidine is additionally used for the manufacture of these. The piperidine radical can be present in the main chain or as a side group of the polymeric stabilizer. Polymeric stabilizers of this type do not tend to migrate out of the plastic or to be removed by extraction; they are therefore very permanent in use.Type: GrantFiled: August 5, 1980Date of Patent: November 10, 1981Assignee: Ciba-Geigy CorporationInventors: Jean Rody, Michael Rasberger
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Patent number: 4298656Abstract: A sprayable, solventless bracing composition is made from the admixture of 100 parts of bisphenol A epoxy resin, up to about 8 parts of a coloring pigment, about 0.5 to about 4 parts of a thixotropic agent, about 100 to about 200 parts of butadiene/acrylonitrile polymer, and about 20 to about 40 parts of an amine terminated curing agent.Type: GrantFiled: March 28, 1980Date of Patent: November 3, 1981Assignee: Westinghouse Electric Corp.Inventor: Morris A. Mendelsohn
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Patent number: 4294944Abstract: Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.Type: GrantFiled: November 13, 1979Date of Patent: October 13, 1981Assignee: BASF Wyandotte CorporationInventors: David D. Newkirk, Robert B. Login, Basil Thir
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Patent number: 4288569Abstract: A powder lacquer binder composition which comprises a homogeneous crosslinkable mixture comprising: (A) a polymer containing more than one carboxyl group and having a melting and softening point of from 20.degree. to 150.degree. C. (as determined by differential thermoanalysis) and an acid number of from 10 to 150 mg of KOH/g; and (B) a 1,2-polyepoxide which is N,N',N"-triglycidyl triazolidine-3,5-dione having an epoxide value of from 0.6 to 1.13; the mixture containing from 0.5 to 1.5 1,2-epoxide group per carboxyl group; and a process for the preparation thereof.Type: GrantFiled: August 29, 1980Date of Patent: September 8, 1981Assignee: Bayer AktiengesellschaftInventors: Ludwig Rottmaier, Rudolf Merten, Rolf Dhein, Hans J. Kreuder