Polymer Derived From Ethylenic Reactants Only Derived From Reactant Containing A -cooh Group Patents (Class 525/119)
  • Patent number: 6060557
    Abstract: The present invention relates to a powdery, cross-linked polymer absorbing water and aqueous liquids formed of polymerized, unsaturated, acid groups-containing monomers that are present as salts neutralized to the extent of at least 50 mol-% and which optionally comprise further monomers which are copolymerizable with the acid groups-containing monomers as well as water-soluble polymers, the polymer being formed of acidic, polymerized monomers partially neutralized to the extent of 5-30 mol-%, relative to the acid groups-containing monomer portion. The polymer has a high retention, high liquid absorption under pressure, high swelling pressure, and a low content of soluble components.
    Type: Grant
    Filed: April 23, 1998
    Date of Patent: May 9, 2000
    Assignee: Stockhausen GmbH & Co. KG
    Inventors: Kurt Dahmen, Reinmar Peppmoller
  • Patent number: 6051652
    Abstract: A composition for preparing a reactive hot melt composition comprises (a) a thermoplastic polymer which comprises a polyolefin having an epoxy group, and (b) a radiation polymerizable component containing (b-1) an aliphatic alkyl (meth)acrylate and (b-2) an acrylic compound having a functional group reactive with an epoxy group. A reactive hot melt composition is obtained by polymerizing this composition so as to polymerize the radiation polymerizable component.The reactive hot melt composition which can be easily hot melt coated, crosslinked quickly in the absence of radiation or moisture after bonding adherends, does not form moisture during crosslinking, and has high flowability during hot melting.
    Type: Grant
    Filed: April 30, 1998
    Date of Patent: April 18, 2000
    Assignee: 3M Innovative Properties Company
    Inventors: Kohichiro Kawate, Shigeyoshi Ishii
  • Patent number: 6037411
    Abstract: This invention provides an acoustic vibrational material containing various fibers as the reinforcement material and having the epoxy resin as the matrix resin, wherein the epoxy resin is modified by a polybutadiene base elastomer containing not less than 90 mole percent of 1,2-linked units. The epoxy resin modified with the above polybutadiene elastomer exhibits a maximum value of loss coefficient at the temperature region near the room temperature. Thus compatibility between large internal loss and high elastic modulus is achieved.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: March 14, 2000
    Assignees: Sony Corporation, Mitsui Petrochemical Industries
    Inventors: Kunihiko Tokura, Masaru Uryu, Seiji Matsuura
  • Patent number: 6037412
    Abstract: Powder compositions comprising about 5-15 wt % of PVdF-compatible thermoplastic resin, about 50-90 wt % of a thermosetting binder system, about 0-35 wt % of pigments and about 0-3 wt % of leveling agent are disclosed which are particularly suitable for use as primers with a later application of a pigmented PVdF-based top coating. Preferred compositions are based on an epoxy system containing about 8 wt % of PVdF or acrylic thermoplastic resin, 5-25 wt % of pigments and 0.7-1 wt % of leveling agent.
    Type: Grant
    Filed: July 14, 1999
    Date of Patent: March 14, 2000
    Assignee: Fina Research, S.A.
    Inventors: Ludwig Karl Rijkse, Willem Sietses, Michel Gillard
  • Patent number: 6025438
    Abstract: A one-component thermosetting coating composition containing of one or more chemically setting binders, at least one curing or crosslinking agent, and one or more toughening substances, the composition being semisolid and tackfree at temperatures <50.degree. C., wherein the chemically setting binders have an average molecular weight (M.sub.w) of between 500 and 250,000, a melting point of more than 50.degree. C., a glass transition temperature of more than 20.degree. C. and cure fully at temperatures in the range from 80 to 250.degree. C.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: February 15, 2000
    Assignee: A. Raymond & Cie
    Inventors: Rudolf Hinterwaldner, Hans-Jurgen Lesser, Axel Bottcher, Ullrich Grundke, Klaus-Peter Liebetanz
  • Patent number: 6013730
    Abstract: A curable composition and a method of making it comprises reacting in the presence of a catalyst epoxy resin(s) having at least 0.05% by weight of epoxy resin oligomer with a solid rubber which is swellable or soluble in the reaction mixture and possessing at least 1% by weight of reactive groups, in a rubber:epoxy resin(s) weight ratio of between 1:1 and 1:20, wherein said epoxy resin(s) comprises (a) at least one epoxy resin having an epoxy functionality of greater than three and (b) at least one second epoxy resin having a functionality of greater than one but not more than three; heating to effect the reaction, cooling to substantially ambient temperature, and adding any remaining portion of epoxy resin and curing agent(s).
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: January 11, 2000
    Assignee: Fiberite, Inc.
    Inventors: Patrick T. McGrail, Stephen D. Jenkins, Jeffrey T. Carter, Peter R. Ciriscioli, Scott D. Lucas, Robin K. Maskell
  • Patent number: 6013733
    Abstract: Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer.
    Type: Grant
    Filed: March 11, 1998
    Date of Patent: January 11, 2000
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Debra L. Singer, Kurt G. Olson, Kurt A. Humbert, Karen A. Barkac, Mark E. Wozniak
  • Patent number: 6011107
    Abstract: A coating composition for producing a water washable, protective coating, comprising, by weight, 10-50% of a mixture of at least two acrylic polymers each having different molecular weights, acid numbers, and glass transition temperatures. The composition includes water and an alkali, in an amount sufficient to maintain the composition at a pH in the range of 7.5 to 9.5 and is further characterized in that the average molecular weight of the mixture of the at least two acrylic polymers is in the range of approximately 35,000 to 100,000. The average acid number of the mixture is in the range of approximately 65 to 150 and the glass transition temperature of a coating produced by the evaporation of the water from the composition is in the range of 0 to 70.degree. C.
    Type: Grant
    Filed: August 25, 1998
    Date of Patent: January 4, 2000
    Assignee: Gage Products Company
    Inventors: Jeffrey Maxwell, Xenophon G. Saquet
  • Patent number: 5977245
    Abstract: Low VOC automotive sealer compositions containing reactive urea/urethane compounds are disclosed. Sealers and tintable sealers utilyzing the reactive urea/urethane compounds have improved physical properties with a faster dry times without sacrificing other desirable properties. These compositions are found to be useful for automotive refinish according to this invention.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: November 2, 1999
    Assignee: BASF Corporation
    Inventors: Rajnikant P. Shah, Sudhakar Dantiki, Stewart Shepler
  • Patent number: 5952435
    Abstract: A composite material for a lateral rigid member of a track belt for use in a snowmobile. A glycidylamine epoxy resin that is a polyfunctional epoxy thermosetting resin and has a molecular weight of about 250 to 1000 is included in an amount of 100 parts by weight. A 2-functional epoxy resin having a molecular weight of about 100 to 600 is included in an amount of 12 to 14.5 parts by weight. An aromatic polycarbonate thermoplastic resin having a molecular weight of about 12000 to 80000, a glass transition point of 130.degree. C. or more, a melting point of 220.degree. C. to 240.degree. C. is included in an amount of 5 to 45 parts by weight. An acid anhydride curing agent is included in an amount of 90 to 130 parts by weight. The composite material also includes reinforcing fiber.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: September 14, 1999
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Fumio Chiba, Yuichi Tanaka
  • Patent number: 5932657
    Abstract: Powder compositions comprising about 5-15 wt % of PVdF-compatible thermoplastic resin, about 50-90 wt % of a thermosetting binder system, about 0-35 wt % of pigments and about 0-3 wt % of leveling agent are disclosed which are particularly suitable for use as primers with a later application of a pigmented PVdF-based top coating. Preferred compositions are based on an epoxy system containing about 8 wt % of PVdF or acrylic thermoplastic resin, 5-25 wt % of pigments and 0.7-1 wt % of leveling agent.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: August 3, 1999
    Assignee: Fina Research, S. A.
    Inventors: Ludwig Karl Rijkse, Willem Sietses, Michel Gillard
  • Patent number: 5908877
    Abstract: A water dispersible powder composition is provided. The powder composition contains at least one film-forming polymer having at least one functional group and at least one reactive component that reacts to form a non-ionic bond with the polymer functional group following dispersion of the powder composition in water. The reaction between the polymer particles in the admixture and the reactive component renders the resulting coating water-resistant. The powder composition of this invention is useful for producing water-resistant coatings.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: June 1, 1999
    Inventors: Xiaohong Ci, David RIchard Amick, Richard Foster Merritt
  • Patent number: 5886071
    Abstract: An adhesive composition comprising: a) a metal-chelate cross-linker; b) a polyurethane or diepoxy cross-linker; c) an acrylate base polymer; d) a stabilizer for the metal-chelate cross-linker; and e) a non-reactive organic solvent is provided. The adhesive composition is stable and high-performance. The stable adhesive composition is stored as a one-part system.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: March 23, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Deepak Hariharan
  • Patent number: 5869568
    Abstract: A one-part cold crosslinking emulsion composition containing, in an aqueous medium, a double-structure fine grain comprising the following Component (A) 1 and the following Component (B) 2 covering the same, wherein the following Component (C) is contained in Component (B) 2:(A) a copolymer comprising an epoxy group-containing monomer and an ethylenic unsaturated monomer;(B) a copolymer comprising an unsaturated carboxylic acid and an ethylenic unsaturated monomer; and(C) a low molecular weight monofunctional epoxy compound.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: February 9, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Norihisa Maeda
  • Patent number: 5840384
    Abstract: An aqueous coating composition for exterior surface of a can, in which the resin component comprises a water-soluble or water-dispersible resin product prepared by reacting a resin having carboxyl functionality (a), an epoxy resin (b) and a tertiary amine (c), at least 50 mole % of the epoxy groups of said epoxy resin (b) being quaternary ammonium salt, provides a coating with a smooth and glossy surface, excellent processability, excellent adhesion properties, excellent retorting resistant properties and the like. Furthermore, the coating composition minimizes a generation of fume in an oven during curing.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: November 24, 1998
    Assignee: Kansai Paint Company, Ltd
    Inventors: Sumio Noda, Seiji Takami, Keiichi Shimizu, Kaoru Morita
  • Patent number: 5837353
    Abstract: A coating composition based on low molecular weight anhydrides having pendant, non-cyclic anhydride moieties, hydroxy-functional epoxy resin, and active catalyst wherein the coating composition cures at ambient conditions.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: November 17, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert J. Barsotti, Lee R. Harper
  • Patent number: 5792814
    Abstract: There are herein disclosed a method for preparing a modified resin which comprises thermal/reaction by the use of a norbornenyl group-containing compound typified by norbornenecarboguanamine or its derivative, a method for preparing an epoxy-modified resin which comprises the step of reacting the above-mentioned modified resin and an epoxide, a flame-retarding method, a thermal stabilization method, a compatibilizing method and a surface modification method which comprise utilizing the modified resin, as well as a coating resin composition and an adhesive resin composition containing the modified resin.According to the preparation methods of the present invention, the deterioration of a material scarcely occurs, and a functional group which is excellent in flame retardancy, thermal stability, compatibility and the like can be introduced to the resins.
    Type: Grant
    Filed: August 5, 1997
    Date of Patent: August 11, 1998
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tetsuya Oishi, Kazuo Sugazaki, Jin Suzuki
  • Patent number: 5789493
    Abstract: The invention relates to a process for preparing a composition contains a polymer and a crosslinking agent which comprises mixing a polymer that is solid at room temperature with a crosslinking agent, the polymer and the crosslinker having complementary reactive groups, at a temperature at which the viscosity of the polymer (measured according to Emila) is less than 5000 dpas, in a means for achieving a homogeneous composition in such a short time that less than 20% of the reactive groups of one of either the polymer or crosslinking agent has reacted, and subsequently cooling and comminuting the composition.The mixing is preferably effected in a static mixer at a temperature higher than 140.degree. C.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: August 4, 1998
    Assignee: DSM N.V.
    Inventors: Josephus M. Van Aaken, Guillaume F. M. Hoedemakers, Johannes S. Van Der Bas, Adrianus J. Van De Werff
  • Patent number: 5783631
    Abstract: A thermoplastic elastomer composition has a plastic phase or matrix of an engineering thermoplastic such as an ester polymer and a crosslinked phase of self-cured acrylic rubber particles. The rubber particles are the reaction product of at least one functionalized acrylic rubber self-cured by a different functionalized acrylic rubber wherein the functional groups are generally a carboxyl, an epoxy, or hydroxyl, and the like. The composition can be dynamically vulcanized in the presence of an accelerator and desirably has a single low temperature brittle point.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: July 21, 1998
    Assignee: Advanced Elastomer System, L.P.
    Inventor: Krishna Venkataswamy
  • Patent number: 5777029
    Abstract: A thermoplastic elastomer composition has a plastic phase or matrix of an engineering thermoplastic such as an ester polymer and a crosslinked phase of cured acrylic rubbers. The rubbers are cured by a curing agent and contain at least two functionalized acrylic rubbers wherein the functional group such as a carboxyl, an epoxy, or a hydroxyl can be the same or different. The composition can be dynamically vulcanized and desirably when one of the functionalized acrylic rubbers is a terpolymer of ethylene-alkyl acrylate-unsaturated carboxylic acid, the composition has a single low temperature brittle point.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: July 7, 1998
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Jacques Horrion, Raman Patel, Sabet Abdou-Sabet, Krishna Venkataswamy
  • Patent number: 5767175
    Abstract: An aqueous coating composition comprising an acrylic resin-modified epoxy resin (D), which is obtained by the reaction between a mixture of a bisphenol F based epoxy resin (A) and a bisphenol F based phenoxy resin (B) and an acrylic resin having carboxyl functionality (C), said acrylic resin-modified epoxy resin (D) being dispersed into water, preferably by using ammonia or amine, provides a composition with low viscosity, excellent storage stability and excellent application workability. In addition, the coating of the present invention can be applied to an interior surface and the resulting film has a smooth surface, excellent processability, excellent retorting resistant properties, excellent adhesion properties, and excellent corrosion resistant properties.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: June 16, 1998
    Assignee: Kansai Paint Company, Ltd.
    Inventors: Yasuo Kamekura, Tomokuni Ihara, Kaoru Morita
  • Patent number: 5728779
    Abstract: A binder composition for thermosetting powder paints comprising (i) a polymer that is capable of reacting with epoxy groups and (ii) a crosslinker that contains epoxy groups, wherein the crosslinker comprises at least one C.sub.5 to C.sub.26 linear or branched aliphatic chain with the proviso that epoxy groups are carried on at least one aliphatic chain. In order to function as a crosslinker the amount of oxirane-oxygen originating from the crosslinker in the binder composition is higher than 0.1 meq/gram. The crosslinker is, for example, an epoxydized oil, a modified epoxydized oil or an epoxydized alkyd resin. A powder paint comprising the binder composition can contain a suitable catalyst and, optionally, an additional curing agent.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: March 17, 1998
    Assignee: DSM N.V.
    Inventors: Adrianus J. van de Werff, Leendert J. Molhoek, Marten Houweling, Robert van den Berg Jeths, Dirk A. W. Stanssens, Robert van der Linde, Tosko A. Misev
  • Patent number: 5707729
    Abstract: An adhesive composition and foils coated with the adhesive, wherein the adhesive consisting essentially of: (I) a fist amount of a non-modified epoxy resin and a second amount of a rubber-modified epoxy resin in a total amount of 60-100 parts by weight, wherein the amount of rubber-modified epoxy resin is 0.5 to 20 parts by weight; (II) 5-30 parts by weight of a polyvinyl acetal resin; and optionally contains (III) at least one resin selected rom the group consisting of blocked isocyanate resins, polyester resins, polyester resins, melamine resins and urethane resins. The adhesive coating can optionally contain inorganic fillers, fire retardants, and curing agents.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: January 13, 1998
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventor: Tetsuro Satoh
  • Patent number: 5708059
    Abstract: A stable, aqueous epoxy resin dispersion including: (A) an epoxy resin prepared by condensation of at least one epoxide compound having on average at least two epoxide groups per molecule, with an aralkylated polyhydroxy aromatic compound obtained by reaction of a polyhydroxy aromatic compound with an aromatic compound which carries an alkenyl group; (B) a dispersant; and water, is useful, for example, in a coating or adhesive.
    Type: Grant
    Filed: February 11, 1997
    Date of Patent: January 13, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Armin Pfeil, Michael Hoenel, Uwe Neumann
  • Patent number: 5705558
    Abstract: Water-reducible coating formulations suitable for use in thermal reflow coating protocols are described. The water-based coating formulations comprise an aqueous dispersion of a resin solids composition. The resin solids comprise about 70 to about 99% by weight of an acrylic resin having a glass transition temperature less than 150.degree. F. and an effective amount of a reflow modifier selected from a thermoplastic resin having a glass transition temperature greater than 150.degree. F. or less than 80% of the stoichiometric amount of a cross-linking agent for the acrylic resin. The improved water-based formulations in accordance with the invention provide high gloss, thermally reflowable coatings without the high organic volatiles content of art-recognized thermal reflow coating systems.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: January 6, 1998
    Assignee: C.P., Inc.
    Inventor: James N. Krouse
  • Patent number: 5691419
    Abstract: A coating agent comprises a binding agentcontaining at least one acrylate copolymer (A) with carboxyl groups and/or at least one acrylate copolymer (B) with epoxide groups, the acrylate copolymers (A) and (B) being obtained by solution polymerization using less than 5% by weight based on the total weight of monomers of one or more polysiloxane macromonomers a.sub.1 having a number-average molecular weight of 1000 to 40,000 and on average 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; and one or more epoxy resins.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: November 25, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Stephan Engelke, Michael Brunnemann, Olaf Rotter, Andreas Holst
  • Patent number: 5686531
    Abstract: A coating agent comprises a binding agent containing at least one acrylate copolymer (A) with carboxyl groups and/or at least one acrylate copolymer (B) with epoxide groups, the acrylate copolymers (A) and (B) being obtained by solution polymerization using less than 5% by weight based on the total weight of monomers of one or more polysiloxane macromonomers a.sub.1 having a number-average molecular weight of 1000 to 40,000 and on average 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; one or more addition and/or condensation resins with carboxyl groups; and one or more epoxy resins.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: November 11, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Stephan Engelke, Michael Brunnemann, Olaf Rotter, Andreas Holst
  • Patent number: 5686511
    Abstract: A method of preparing a water-dispersible epoxy resin coating composition comprises:(a) Reacting an epoxy polymer with a carboxyl bearing polymer in the presence of an esterification catalyst;(b) Quenching with an excess of tertiary amine before the esterification reaction is completed; and(c) adding water to form an aqueous dispersion.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: November 11, 1997
    Assignee: The Valspar Corporation
    Inventor: William S. Bobo
  • Patent number: 5654081
    Abstract: In a method of producing an integrated circuit assembly, an IC device is metallurgically bonded to a supporting substrate. The mounting of the IC device to the substrate also includes a polymeric underfill body adhesively bonding the IC device to the substrate. The polymeric underfill body is formed of a curable underfill composition comprising epoxy resin, anhydride curing agent for the epoxy resin, amine catalyst and a minor amount of an additional component selected from alkyl-substituted imidazole and phenyl-substituted imidazole. Such additional component may act as a catalyst, as used with an amine catalyst known catalyst for the polymerization reaction of the epoxy resin with the anhydride curing agent, may act as a co-catalyst. The polymeric underfill body has improved glass transition temperature values and improved coefficient of thermal expansion values to provide good thermal stress cycling life for the integrated circuit assembly.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: August 5, 1997
    Assignee: Ford Motor Company
    Inventor: Michael G. Todd
  • Patent number: 5635549
    Abstract: Vehicles for one-component aqueous emulsion/dispersion acrylic paints having improved washability and wash-fastness include (a) from 96% to 99.9% by weight, relative to the solids content thereof, of an aqueous dispersion of acrylic latex, and (b) from 0.1% to 4% by weight, also relative to the solids content thereof, of an aqueous emulsion of an aromatic epoxy resin which comprises a nonionic surface-active agent.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: June 3, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Francois D'Allest, Yves Decloitre, Philippe Larraillet
  • Patent number: 5618884
    Abstract: Anhydride-functional polymerizable monomers having the structure: ##STR1## and polymers and reactive compositions prepared from these monomers are disclosed. The reactive compositions are especially useful in primer and clearcoat/basecoat applications.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: April 8, 1997
    Assignee: The Sherwin-Williams Company
    Inventors: Rubing Cai, Thomas W. Yokoyama
  • Patent number: 5593730
    Abstract: Powder coating composition which comprises a hybrid polymer system in granular form of a polymer A formable from monomer(s) by aqueous suspension polymerisation and a polymer B, different to A, which polymer system has been obtained using a process which comprises dissolving polymer B in monomeric material to be used in the formation of polymer A, polymerising the monomer(s) to form polymer A using an aqueous suspension polymerisation process, and removing the aqueous phase to form a hybrid of the polymers A and B in granular form, and wherein polymer A and polymer B bear functional groups for imparting curability to the hybrid polymer system, and wherein further the hybrid polymer system has a number average molecular weight within the range of from 1500 to 15,000.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: January 14, 1997
    Assignee: Zeneca Limited
    Inventors: Rajasingham Satgurunathan, David C. Hinde, John C. Padget, Stephen G. Yeates
  • Patent number: 5578677
    Abstract: A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: November 26, 1996
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5576361
    Abstract: Protective coating compositions free of volatile organic solvents and particularly useful as can coatings are produced based on an aqueous dispersed microgel polymeric binder comprising between about 1% and 70% low molecular weight polyester diluent, between about 1% and 70% epoxy resin, between about 10% and 80% addition copolymer, and between about 1% and 40% low molecular weight diepoxide crosslinking resin. The aqueous dispersed solvent free microgel polymer is produced by mixing the polyester diluent with high molecular weight epoxy to produce a fluid resin mixture, copolymerizing in-situ ethylenically unsature monomers including carboxyl monomers in the presence of the fluid resin mixture and dispersing the resulting polymeric mixture into water. Low molecular weight diepoxide resin is added and crosslinked with carboxyl functionality to produce the microgel polymers.
    Type: Grant
    Filed: April 20, 1995
    Date of Patent: November 19, 1996
    Assignee: The Glidden Company
    Inventor: Gary P. Craun
  • Patent number: 5576389
    Abstract: A powder coating comprising a thermosetting resinous composition comprising a base resin having 2 or more oxirane groups in its molecule and a hardener for epoxy resin, which is characterized by further containing 0.5 to 10% by weight based on the base resin weight of a vinyl resin containing 1 to 10% by weight of at least one aliphatic dicarboxylic acid selected from thiomalic acid, maleic acid, fumaric acid and itaconic acid and having a number average molecular weight of 1000 to 8000 and a glass transition temperature of -40.degree. to 100.degree. C. The coating obtained is excellent in smoothness, gloss and image clarity.
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: November 19, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Tasaburo Ueno, Akimitsu Uenaka, Harunori Gohji, Yuji Toyoda, Kouichi Tsutsui
  • Patent number: 5554671
    Abstract: An aqueous dispersed, very low VOC (less than about 0.4 pounds per gallon), protective surface coating composition comprises crosslinked microgel particles of less than 1 micron and produced by dispersing low molecular weight carboxyl functional addition copolymer into water, stably dispersing diepoxide epoxy resin in the aqueous dispersion, and coreacting the diepoxide resin with the carboxyl functional copolymer to provide epoxy-ester crosslinked microgel polymer particles stably dispersed into water. The microgel particles are useful as a polymeric binder for aqueous dispersed coatings particularly useful for coating interior surfaces of beer and beverage cans.
    Type: Grant
    Filed: March 21, 1995
    Date of Patent: September 10, 1996
    Assignee: The Glidden Company
    Inventors: Gary P. Craun, Victor V. Kaminski
  • Patent number: 5539064
    Abstract: A resist ink composition developable with a diluted, alkaline solution, which exhibits high dispersion stability itself, can form a pattern with excellent resolution, even in the case of a low exposure amount, and can produce a cured resist film excellent in solvent resistance for high-performance printed circuits and which comprises an ultraviolet-curable resin obtained by copolymerizing (a) from 5 to 50% by weight of an ethylenically unsaturated monomer of a general formula: ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group; R.sub.2 represents a hydrogen atom or an alkyl group; n represent an integer of from 1 to 4, and/or glycerol mono(meth)acrylate, (b) from 10 to 90% by weight or glycidyl (meth)acrylate and (c) from 0 to 80% by weight of other ethylenically unsaturated monomers capable of copolymerizing with these (a) and (b), followed by reacting the resulting copolymer with from 0.7 to 1.
    Type: Grant
    Filed: September 12, 1995
    Date of Patent: July 23, 1996
    Assignee: Goo Chemical Industries Co., Ltd.
    Inventors: Soichi Hashimoto, Satoshi Miyayama, Toshiaki Nishimura, Toshikazu Oda
  • Patent number: 5527840
    Abstract: An aqueous coating composition and a method of coating a metal substrate are provided. The composition and method are particularly suitable for use in coating can bodies and can ends or for can side seam coatings. The coating composition includes a solvent component and a film forming component. The solvent component includes water and an organic solvent. The film forming component includes a curing agent and the product of the reaction of a carboxy addition polymer and an epoxy resin in the presence of a tertiary amine catalyst.
    Type: Grant
    Filed: October 4, 1994
    Date of Patent: June 18, 1996
    Assignee: The Valspar Corporation
    Inventors: Mary Jo Chutko, Phillip C. Martino
  • Patent number: 5527857
    Abstract: An adhesive primer composed of a cross-linkable polymer exhibiting electrostatic induction proof properties, and a laminated film having such a primer layer. The laminated film represents a material capable of maintaining a high electrification preventative performance despite the fact that the base film itself constitutes the outer film surface.
    Type: Grant
    Filed: February 7, 1995
    Date of Patent: June 18, 1996
    Assignee: Altech Co., Ltd.
    Inventor: Kanji Hayashi
  • Patent number: 5516846
    Abstract: Coating compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhydride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; wherein at least one of the compounds (i), (ii), or (iii) comprises a film forming polymer.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: May 14, 1996
    Assignee: The Sherwin-Williams Company
    Inventors: Mohamad D. Shalati, James A. Marquart, John L. Petty, Rodney M. Harris
  • Patent number: 5508381
    Abstract: The present invention provides an improved process for preparing a highly water absorbent resin having a superior suction power and excellent gel strength, which consists essentially of:(1) neutralizing acrylic acid to a neutralization degree ranging from 50 to 100% based on the total number of moles of the acid employed and polymerizing it by a reverse phase suspension polymerization to provide a neutralized polymer;(2) dehydrating the polymer until its water content reaches 25% by weight or less based on the weight of the polymer through an azeotropic distillation thereof in the presence of a lipophilic solvent;(3) crosslinking the dehydrated polymer in the presence of a hydrophilic crosslinking agent containing at least two epoxy groups in an amount ranging from 0.05 to 5.0% by weight and water added in an amount ranging from 7.0 to 25.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: April 16, 1996
    Assignee: Lucky Limited
    Inventors: Tae-Hwan Jang, Su-Beom Choi, Hyung-Mann Lee, Myung-Joong Kim
  • Patent number: 5504151
    Abstract: This invention is the polycapped oligomer adduct of a long chain fatty acid with a multi hydroxy functional or multi epoxy functional compound. This polycapped oligomer is useful in resin compositions to enhance the performance of thermoplastic low profile additives which improve the surface quality of molded composites such as automotive body panels.
    Type: Grant
    Filed: November 8, 1994
    Date of Patent: April 2, 1996
    Assignee: Ashland Inc.
    Inventors: Dennis H. Fisher, Timothy A. Tufts, C. Timothy Moss
  • Patent number: 5500246
    Abstract: A water-based coating composition that does not use an organic solvent is formed by dispersing a resin composition into an aqueous medium. The water-based coating composition has excellent stability over time. The coating film obtained from the composition has excellent retort resistance, adhesion to metals, processability and chemical resistance; and it can be cured at relatively low temperatures.
    Type: Grant
    Filed: August 18, 1994
    Date of Patent: March 19, 1996
    Inventors: Kenichi Morizono, Taira Harada
  • Patent number: 5498783
    Abstract: A thermosetting powder coating composition resistant to overspray incompatibility defects that comprises solid particulates of a uniform mixture of (a) a polyester resin having an average of two or more carboxyl groups, (b) a first crosslinker that is reactive toward the carboxyl groups of the polyester resin, (c) from 1% to 20% of a reactive acrylic copolymer having a weight average molecular weight of from 10,000 to 40,000, and (d) a second crosslinker that is reactive toward the reactive functionality of the acrylic copolymer is described.
    Type: Grant
    Filed: August 22, 1994
    Date of Patent: March 12, 1996
    Assignee: BASF Corporation
    Inventors: Richard J. Foukes, Cynthia A. Stants
  • Patent number: 5486569
    Abstract: A method of enhancing the water or aqueous fluid absorption of and/or increasing the particle size of fine water-absorbent polyacrylic SAP polymer particles includes surface-contacting the SAP polymer particles with a solution containing a cross-linking agent for the polyacrylic SAP polymer, and then subjecting the particles to conditions sufficient to further cross-link the surfaces of the SAP polymer particles. The surface cross-linked particles are then impregnated with water in a weight ratio of SAP polymer, dry basis, to water in the range of about 1:1 to about 1:10 to form a paste, and the paste is subjected to conditions, such as increased temperature, e.g., 50.degree. C.-150.degree. C. to dry the polymer particles to form an acrylic SAP polymer having enhanced fluid absorption under load and, upon pulverizing, increased particle size.
    Type: Grant
    Filed: September 28, 1994
    Date of Patent: January 23, 1996
    Assignee: American Colloid Company
    Inventors: John A. Henderson, Anthony S. Tomlin, David M. Lucas
  • Patent number: 5478870
    Abstract: An aqueous resin dispersion which comprises as the chief component acrylic-modified epoxy-polyamine resin composed of a bisphenolic epoxy resin containing at least two epoxy groups per molecule; and, as bound to at least a part of said epoxy groups, an acrylic resin having on the average at least one functional group which is capable of reacting with said epoxy group, per molecule, the molecular weight distribution of said acrylic resin as expressed by its weight average molecular weight (Mw)/number average molecular weight (Mn) being within a range of 1 to 1.2, and an active hydrogen-containing amino compound. Said aqueous resin dispersion may further optionally contain non-ionic, film-forming resin. Such dispersions are useful for cationic electrodeposition paint which can form a coating excelling in weatherability and corrosion resistance.
    Type: Grant
    Filed: August 25, 1994
    Date of Patent: December 26, 1995
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Masanobu Kudoh, Hidehiko Haneishi
  • Patent number: 5472999
    Abstract: An aqueous resin dispersion which comprises as the chief component acrylic-modified epoxy-polyamine resin composed of a bisphenolic epoxy resin containing at least two epoxy groups per molecule; and, as bound to at least a part of said epoxy groups, an acrylic resin having on the average at least one functional group which is capable of reacting with said epoxy group, per molecule, the molecular weight distribution of said acrylic resin as expressed by its weight average molecular weight (Mw)/number average molecular weight (Mn) being within a range of 1 to 1.2, and an active hydrogen-containing amino compound. Said aqueous resin dispersion may further optionally contain non-ionic, film-forming resin. Such dispersions are useful for cationic electrodeposition paint which can form a coating excelling in weatherability and corrosion resistance.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: December 5, 1995
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Masanobu Kudoh, Hidehiko Haneishi
  • Patent number: 5464885
    Abstract: An aqueous dispersed acrylic grafted epoxy-ester polymer useful as a polymeric binder for protective coatings is produced by first forming a carboxyl functional epoxy-ester by esterifying a low molecular weight epoxy resin with a low molecular weight, unsaturated, carboxyl terminated polyester, followed by in-situ copolymerizing ethylenic monomers in the presence of water-dispersed epoxy-ester.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: November 7, 1995
    Assignee: The Glidden Company
    Inventor: Gary P. Craun
  • Patent number: 5464902
    Abstract: Relatively brittle epoxy resin systems which may be employed as structural film adhesives and matrix resins for fiber-reinforced prepregs are toughened against impact-induced damage by the addition of minor quantities of functionalized elastomer particles having a glass transition temperature of less than 10.degree. C.
    Type: Grant
    Filed: February 4, 1994
    Date of Patent: November 7, 1995
    Assignee: Cytec Technology Corp.
    Inventor: Hans G. Recker
  • Patent number: 5453323
    Abstract: Super-absorbent polymers having superior dryness properties when incorporated into absorbent articles are made from acrylic acid and crosslinking agent polymerized under controlled conditions.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: September 26, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Douglas R. Chambers, Hubert H. Fowler, Jr., Yoji Fujiura, Fusayoshi Masuda