With Saturated -n=c=x (x Is Chalcogen) Reactant Or Polymer Thereof; Or With Solid Copolymer Derived From At Least One -n=c=x Reactant Wherein At Least One Of The Reactants Forming The Solid Copolymer Is Saturated; Or With Spfi Wherein At Least One Of The Necessary Ingredients Contains A -n=c=x Group Or With A Reaction Product Thereof; Or With Sicp Containing A -n=c=x Group Patents (Class 525/123)
  • Patent number: 7183355
    Abstract: A curable, aqueous film-forming composition is provided, comprising: (a) a copolymer containing reactive functional groups and comprising at least 30 mol % of residues having alternating structural units: -[DM-AM]- wherein DM represents a residue from a donor monomer, and AM represents a residue from an acceptor monomer, at least 15 mol % of the copolymer comprising a donor monomer having the structure (I): wherein R1 is linear or branched C1 to C4 alkyl, R2 is selected from methyl, linear, cyclic or branched C1 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl; and (b) a curing agent having functional groups reactive with the reactive functional groups of (a). The invention is also directed to a multi-component composite coating composition including a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. At least one-coat is the film-forming composition described above.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: February 27, 2007
    Assignee: PPG Industries, Ohio, Inc.
    Inventors: Roxalana L. Martin, Edward R. Coleridge, Mark A. Tucker, Mary E. Grolemund
  • Patent number: 7183354
    Abstract: The coating for substrates or materials, preferably elastomers or elastomers bonded to metal. The coating composition comprises (a) a functionalized hydrogenated copolymer comprising at least one repeat unit derived from a conjugated diene monomer; preferably including an unsaturated nitrile monomer; and a functional group containing monomer or graft linked compound or combinations thereof; (b) a curing component comprising at least one isocyanate group, or a carbodiimide compound, or an amino resin, or combinations thereof, and (c) a solvent. The coating compounds can be applied to an substrate either before or after the substrate has been vulcanized. The coatings can be cured at ambient temperatures.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: February 27, 2007
    Assignee: Lord Corporation
    Inventors: James R. Halladay, Frank J. Krakowski, Ernest Barritt Troughton, Jr.
  • Patent number: 7179882
    Abstract: The present invention relates to low viscosity polymer polyols and to a process for the preparation of these low viscosity polymer polyols. These polymer polyols comprise the free-radical polymerization product of (A) a base polyol, (B) a pre-formed stabilizer, and (C) at least one ethylenically unsaturated monomer, in the presence of (D) at least one free-radical polymerization initiator, and (E) at least one polymer control agent. The total amount of polymer control agent present in the polymer polyols of the present invention ranges from greater than about 5.0% up to about 20% by weight, based on 100% by weight of the polymer polyol.
    Type: Grant
    Filed: August 2, 2004
    Date of Patent: February 20, 2007
    Assignee: Bayer Materialscience LLC
    Inventors: Rick L. Adkins, Scott A. Guelcher, James R. Charron, John E. Hayes
  • Patent number: 7179861
    Abstract: A carbamate or terminal urea functional vinyl polymer is prepared by reacting a compound having an hydroxyl group and a carbamate group, terminal urea group, or a group that can be converted to a carbamate or terminal urea group, with a cyclic carboxylic acid anhydride group to form an ester bond and a free acid group from the anhydride; and reacting the free acid group with a compound having an epoxide group. The cyclic carboxylic acid anhydride group may be pendant to a vinyl polymer, or one of the compound having an hydroxyl group, a compound having the cyclic carboxylic acid anhydride group, and the compound having an epoxide group may have polymerizable ethylenic unsaturation that is polymerized, optionally with one or more copolymerizable monomers to form a vinyl polymer. When the compound having an hydroxyl group has a group that can be converted to a carbamate or terminal urea group, the group is converted to the carbamate or terminal urea group after step (a).
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: February 20, 2007
    Assignee: BASF Corporation
    Inventors: Donald H. Campbell, Donald L. St. Aubin, Walter H. Ohrbom
  • Patent number: 7173089
    Abstract: This invention is directed to a processing approach for the rapid and efficient in-situ polymerization of specially prepared precursor mixtures to achieve near-net-shape production of objects/articles with exact dimensions. The process relies on the use of polymerizable compositions comprised of a mixture of a dead polymer, a reactive plasticizer and, optionally, an initiator, which compositions are semi-solid-like prior to curing and induce low shrinkage upon curing as a result of their partially polymerized nature prior to processing. The partially polymerized nature of the precursor mixtures also allows extremely impact-resistant objects/articles to be fabricated. Other desirable engineering property attributes can similarly be achieved via the judicious blending of starting ingredients in formulating the polymerizable (curable) mixtures.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: February 6, 2007
    Assignee: ZMS, LLC.
    Inventors: David S. Soane, Michael R. Houston, Toshiaki Hino
  • Patent number: 7169841
    Abstract: A curable aqueous polyurethane dispersion substantially comprises a) at least one compound having two free isocyanate groups, at least one allophanate group and at least one C?C double bond capable of free radical polymerization, a carbonyl group or an oxygen atom in the form of an ether function being bonded directly to the double bond, b) at least one compound having at least one group reactive toward isocyanate groups and having a C?C double bond capable of free-radical polymerization, c) if required, at least one compound having at least two groups reactive towards isocyanate groups and selected from hydroxyl, mercapto, primary and/or secondary amino groups, d) at least one compound having at least one group reactive towards isocyanate groups and having at least one acid group, e) at least one basic compound for neutralizing or partially neutralizing the acid groups of the compounds d), and a thermal initiator and is used for coating substrates.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: January 30, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhold Schwalm, Bernd Bruchmann, Frank Voellinger, Erich Beck, Wolfgang Schrof, Uwe Meisenburg
  • Patent number: 7166673
    Abstract: A water-dispersible polyisocyanate composition comprises a hydrophobic polyisocyanate (A) and a vinyl polymer (B) having a nonionic group and an isocyanate group, in which the hydrophobic polyisocyanate (A) can be dispersed in a water-based medium by the vinyl polymer (B) having a nonionic group and an isocyanate group. The water-dispersible polyisocyanate composition is produced by reacting a hydrophobic polyisocyanate with a vinyl polymer (b) having a nonionic group and an active hydrogen group-containing group capable of reacting with an isocyanate group at a molar ratio of the isocyanate group to the active hydrogen group-containing group of 3 to 350.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: January 23, 2007
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Hajime Suganuma, Masaki Watanabe, Masataka Ooka
  • Patent number: 7160975
    Abstract: This invention relates to ethylenically unsaturated macromers which contain reactive unsaturation, and to a process for preparing these ethylenicallly unsaturated macromers which contain reactive unsaturation. The process of preparing these ethylenically unsaturated macromers comprises reacting a monofunctional compound which corresponds to a specific formula with at least one alkylene oxide, in the presence of at least one alkoxylation catalyst. The ethylenically unsaturated macromers correspond to the formula set forth herein. This invention also relates to preformed stabilizers comprising ethylenically unsaturated macromers, to a process for preparing these preformed stabilizers, to polymer polyols comprising these preformed stabilizers, and to a process of preparing these polymer polyols which comprise these preformed stabilizers. Polymer polyols comprising ethylenically unsaturated macromers and a process for their preparation are also described.
    Type: Grant
    Filed: August 2, 2004
    Date of Patent: January 9, 2007
    Assignee: Bayer MaterialScience LLC
    Inventors: Rick L. Adkins, Scott A. Guelcher
  • Patent number: 7160973
    Abstract: A composition comprising a reaction product of a diisocyanate, a chain extension agent having at least difunctional reactivity with an isocyanate, and a material comprising a blend of i) a primary carbamate material having at least one functional group reactive with an isocyanate and at least one primary carbamate group or a group convertible to a primary carbamate group, and ii) a reaction product of the primary carbamate material with an extending agent, wherein at least one of i) the isocyanate groups of the diisocyanate have a different reactivity in relation to each other, and ii) at least two of the groups with reactivity with an isocyanate on the chain extension agent have a different reactivity in relation to each other.
    Type: Grant
    Filed: December 12, 2002
    Date of Patent: January 9, 2007
    Assignee: BASF Corporation
    Inventors: Walter H. Ohrbom, Craig S. Schang, Joanne Casale, Thaddeus J. Lepkowski
  • Patent number: 7153907
    Abstract: A composition for fluororesin powder coating material, with which a coating film having an excellent matte effect is obtainable without impairing features of fluororesins including excellent weather resistance, and a process for its production, are presented. The composition for fluororesin powder coating material comprises at least two curing systems each comprising a fluororesin having crosslinkable sites and a curing agent reactive to the crosslinkable sites, wherein the respective curing systems substantially independently react and crosslink, and the crosslinking reaction time of one curing system is different by at least 20 seconds from the crosslinking reaction time of other curing system(s).
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: December 26, 2006
    Assignee: Asahi Glass Company, Limited
    Inventors: Akihiko Asakawa, Masaru Yamauchi, Sho Masuda, Masao Unoki
  • Patent number: 7151130
    Abstract: Polyurethane-modified addition copolymers preparable by free-radically (co)polymerizing an olefinically unsaturated monomer (a) in an aqueous or nonaqueous medium comprising at least one reaction product (A/B) of (A) at least one addition copolymer containing on average per molecule at least 0.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: December 19, 2006
    Assignee: BASF Coatings AG
    Inventors: Wolfgang Bremser, Thomas Krüger, Wilma Löcken, Stephan Schwarte, Heinz-Peter Rink
  • Patent number: 7148310
    Abstract: The present invention is directed to a multiple component coating composition comprising (a) a film forming binder component having isocyanate reactive groups; (b) a stable polyisocyanate solution comprising organic liquid and up to 30% by weight, based on the weight of the polyisocyanate solution, of a polyisocyanate having reactive isocyanate groups selected from an aromatic polyisocyanate having tertiary isocyanate groups or a (meth)acrylic polymer containing reactive isocyanate groups; and (c) optionally, a tinting composition comprising pigment, a dispersing agent and an organic liquid carrier; whereby components (a), (b) and (c) are blended together before application to a substrate and after application to a substrate the composition is cured to form a finish. The present invention is also directed to a method of producing a finish on a substrate and to the resulting coated substrate.
    Type: Grant
    Filed: August 13, 2004
    Date of Patent: December 12, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert John Barsotti, Christopher Scopazzi, Douglas Matt Lamb
  • Patent number: 7144954
    Abstract: The present invention relates to mixtures containing A) compounds of the formula (I) and (II) where R1 is independently at each instance hydrogen or a methyl radical, R2 is independently at each instance a linear or branched, aliphatic or cycloaliphatic radical or a substituted or unsubstituted aromatic or heteroaromatic radical and m and n are each independently an integer of not less than 0 subject to the proviso that m+n>0, and B) at least one ethylenically unsaturated monomer (A) which is different from the compounds of the formula (I) and (II). The present invention further relates to processes for polymerizing these mixtures, the highly transparent polymers thus obtainable and to their use.
    Type: Grant
    Filed: September 13, 2003
    Date of Patent: December 5, 2006
    Assignee: Röhm GmbH & Co. KG
    Inventors: Bardo Schmitt, Wolfgang Klesse, Volker Kerscher, Patrik Hartmann
  • Patent number: 7144605
    Abstract: A curable coating composition comprises (a) a component having an active methylene group and/or an active methane group, (b) a component having a methacrylate group and/or an acrylate group, (c) a Michael reaction catalyst, and (d) a photo-polymerization initiator.
    Type: Grant
    Filed: May 28, 2004
    Date of Patent: December 5, 2006
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Akihiro Kanakura, Takashi Irie, Hiroto Yoneda, Hisaki Tanabe
  • Patent number: 7144956
    Abstract: The present invention relates to adhesive and sealant compositions in non-flowable form. More particularly, the present invention relates to non-flowable adhesive and sealant compositions which are particularly useful in the threadlocking and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: December 5, 2006
    Assignee: Henkel Corporation
    Inventors: Shabbir Attarwala, Zhu Qinyan, Matthew P. Burdzy
  • Patent number: 7144955
    Abstract: Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: December 5, 2006
    Assignees: Bayer MaterialScience LLC, Bayer MaterialScience AG
    Inventors: Scott A. Grace, Michael J. Dvorchak, Richard R. Roesler, Dinesh Pethiyagoda, Michael K. Jeffries, Jan Weikard
  • Patent number: 7141616
    Abstract: The invention relates to urethane prepolymers, obtainable by reaction of: (A) 15 to 85 wt.-% of one or more ?,?-terminated poly(meth)acrylate diols, (B) 0 to 30 wt.-% of one or more radically curable, polyhydroxy-functional compounds, (C) 14 to 60 wt.-% of one or more polyisocyanates, (D) 1 to 40 wt.-% of a monofunctional compound, reactive vis-à-vis isocyanate groups, which also contains one or more radically curable grouping, as well as their use.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: November 28, 2006
    Assignee: 3M ESPE AG
    Inventors: Reinhold Hecht, Günther Lechner, Thomas Lehmann, Gunther Eckhardt, Bernd Gangnus
  • Patent number: 7141628
    Abstract: The object of the present invention is to provide a golf ball having an improved impact resistance without lowering the productivity, and a golf ball paint which is used therefor. The present invention is characterized in the use of two component curing type urethane paint comprising an aqueous polyol having hydroxyl value of from 50 mgKOH/g below 100 mgKOH/g and a weight average molecular weight of 4,000 to 20,000, and a polyisocyanate.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: November 28, 2006
    Assignee: SRI Sports Limited
    Inventors: Kazuhiko Isogawa, Koichi Fujisawa
  • Patent number: 7138437
    Abstract: A composition comprising at least a part A and a part B is disclosed. The part A comprises at least one polyol and the part B comprises at least one isocyanate. At least one part further comprises at least one of the following: a strength enhancer having a softening point of from about 120° F. to about 400° F.; a non-reactive hydrophobic enhancer; and/or an impact absorption enhancer. These enhancers provide, among optional other benefits, enhanced pull strength. Additionally, a mass can be prepared by a method of combining part A with part B and applying the mixture to a void. The compositions may also be used in the repair of surface defects or for the reinforcement of structural members such as spike holes left after spike removal from railroad ties during road bed maintenance or repair.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: November 21, 2006
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: Albert A. Giorgini, Charles J. Torborg
  • Patent number: 7135522
    Abstract: An aqueous dispersion, contains: a) an amorphous urethanized, unsaturated polyester resin, b) a nonvolatile content of from 20% to 60% by weight, c) from 0 to 60% by weight of a solvent, d) a pH of between 5.0 and 9.5, and e) a viscosity at 20° C. of from 20 to 500 mPas. The polyester resin is obtained from I. an alcohol component, II. i) from 20 to 100 mol % of an ?,?-unsaturated carboxylic acid component, and ii) from 0 to 80 mol % of a further carboxylic acid component, and III. at least one isocyanate component. The alcohol component contains a dicidol mixture of the isomeric compounds 3,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane, 4,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane and 5,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane. Each isomer is present in a fraction of from 20 to 40% in the dicidol mixture. The sum of the three isomers in the dicidol mixture is from 90 to 100%. The dicidol mixture is present from 10 to 100 mol % in the alcohol component of the polyester.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: November 14, 2006
    Assignee: Degussa AG
    Inventors: Patrick Gloeckner, Lutz Mindach, Martina Ortelt
  • Patent number: 7132476
    Abstract: A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: November 7, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 7132477
    Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material, and a monocarboxylic acid. Multi-component composite coatings, coated substrates, and related methods are also provided.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: November 7, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Kurt A. Humbert, Karen S. Rechenberg, Edward R. Coleridge, Charles M. Kania, Paul H. Lamers
  • Patent number: 7129288
    Abstract: Novel polyurethanes containing sulfide groups which comprise at least one group of the general formula I in the polymer main chain and/or at least one group of the general formula II incorporated at the chain end: —X—A—S—B—Y—??(I) —X—A—S—B—YH??(II) in which the variables have the following definitions: S is the sulfur atom; X and Y independently of one another are oxygen atoms, sulfur atoms or groups —NZ where Z is the hydrogen atom or an alkyl radical of 1 to 10 carbon atoms; and A and B independently of one another are divalent organic radicals; novel polymer mixtures based thereon, and the use of the novel polyurethanes and polymer mixtures and dispersions thereof for the preparation of coating materials, adhesives and sealing compounds.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: October 31, 2006
    Assignee: BASF Coatings AG
    Inventors: Wilma Löcken, Heinz-Peter Rink, Thomas Krüger, Stefan Schwarte, Hans-Ulrich Moritz, Hartmut Kagerer
  • Patent number: 7129295
    Abstract: A golf ball excellent in abrasion resistance and rebound characteristics. The golf ball according to the present invention is characterized in that the golf ball comprises a base resin constituting the cover containing a polyurethane having a polyisocyanate and a polyol as the constituents thereof and the polyol further comprises a hydroxyl group-containing diene polymer and/or a hydrogenated derivative of the hydroxyl group-containing diene polymer.
    Type: Grant
    Filed: June 8, 2004
    Date of Patent: October 31, 2006
    Assignee: SRI Sports Limited
    Inventors: Kazuhiko Isogawa, Koichi Fujisawa
  • Patent number: 7125927
    Abstract: Paint or varnish composition comprising, as solids: from 10 to 50 parts by weight of at least one polyurethane in aqueous emulsion form; from 10 to 30 parts by weight of at least two acrylic polymers or copolymers in aqueous emulsion form; from 10 to 70 parts by weight of mineral or organic fillers; from 5 to 20 parts by weight of processing aids; and from 0 to 10 parts by weight of crosslinking agent; said composition furthermore comprising from 40 to 150 parts by weight of water, the parts being given by weight of active material in the composition.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: October 24, 2006
    Assignee: Hutchinson
    Inventors: Nathalie Thenault, Celine Desaindes
  • Patent number: 7125931
    Abstract: A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: October 24, 2006
    Assignee: PPG industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 7125932
    Abstract: The present invention provides (i) a novel composition which is the polyol reaction product polyol made by mixing together a polyhydroxyl-tertiary amine, at least two of the hydroxyl groups of said amine being indirectly bonded to a nitrogen atom of said amine through a chain containing at least two carbon atoms, with an organic polyisocyanate, essentially all the isocyanate groups of said polyisocyanate being reacted with hydroxyl groups of said amine, and (ii) a coating composition containing a film forming binder and a volatile organic liquid carrier, said binder containing (I) hydroxyl-containing acrylic polymer and (II) the novel composition (i).
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: October 24, 2006
    Assignee: E. I. du Pont Nemours and Company
    Inventor: Gia Huynh-Ba
  • Patent number: 7122600
    Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material. The crosslinking agent includes a copolymer having at least 30 mol % of alternating structural units of a residue from a donor monomer and a residue from one or more acrylic acceptor monomers. The thermosetting composition may coat a substrate by coalescing the composition to form a continuous film and curing the composition. The thermosetting composition may be included as part of a multi-component composite coating composition that includes an optional primer coat, a base coat deposited from a pigmented film-forming composition, and a transparent top coat applied over the base coat, where either the base coat, the transparent top coat, or both, are deposited from the thermosetting composition.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: October 17, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Karen S. Rechenberg, Simion Coca, Karen A. Barkac, James B. O'Dwyer, Linda J. Bowser
  • Patent number: 7122596
    Abstract: Provided are a leather-like sheet fabricated by infiltrating an aqueous resin dispersion (A) into a fibrous substrate, which satisfies a requirement (I) that the aqueous resin dispersion, (A) comprises essentially a main resin (a) stabilized with a surfactant, a polymer (b) having a polyoxyethylene group in its side chains, and a surfactant (c), a requirement (II) that the main resin (a) comprises an urethane resin (a1) and/or an urethane-acrylic composite resin (a2), and the resin skeleton contains from 1 to 10 mmols of a carboxyl group per 100 g of the resin, a requirement (III) that the polymer (b) is obtained through polymerization of a polyoxyethylene group-having ethylenic unsaturated monomer (b1) and any other ethylenic unsaturated monomer (b2) in a ratio by mass (b1)/(b2)=60/40 to 100/0, and a requirement (IV) that the percentage, % by mass (?) of the polyoxyethylene group in the polymer (b) and the number of mols (?) of the amino group per gram of the polymer (b) satisfy 35??+?×20000?60; and an indus
    Type: Grant
    Filed: August 5, 2003
    Date of Patent: October 17, 2006
    Assignee: Kuraray Co., Ltd.
    Inventors: Mitsuru Kato, Kimio Nakayama, Nobuo Takaoka
  • Patent number: 7119160
    Abstract: There are provided a polyalkenyl ether type polyurethane, which is excellent in flexibility, aor the like, and which has in the molecule, a structural unit represented by formula (XXX): (wherein n represents an integer of 2 to 1000, R1 represents substituted or unsubstituted lower alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted aryl, or substituted or unsubstituted aralkyl, and R2, R3 and R4, which are the same or different, each represent a hydrogen atom, substituted or unsubstituted lower alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted aryl or substituted or unsubstituted aralkyl, and R1s, R2s, R3s, and R4s, when they are each present two or more in number, may be respectively the same or different), and the like.
    Type: Grant
    Filed: April 3, 2003
    Date of Patent: October 10, 2006
    Assignee: Kyowa Hakko Chemical Co., Ltd.
    Inventors: Sai Kodama, Shigeru Murata, Toshihiro Inayama, Tatsuo Niimi
  • Patent number: 7109285
    Abstract: The present invention relates to novel polyurethane prepolymers (PU prepolymers) of low viscosity containing NCO groups blocked with compounds containing phenol groups and to their use for producing polyurethane polymers. The PU prepolymers are prepared by reacting one or more diisocyanates or polyisocyanates with at least one isocyanate-reactive compound with a functionality of at least 1.5 to form an NCO-functional polyurethane prepolymer and subsequently blocking the free NCO groups with at least one hydrocarbon resin containing phenolic OH groups and/or one optionally substituted phenol in the presence of a catalyst which comprises at least one triorganoamine.
    Type: Grant
    Filed: April 5, 2004
    Date of Patent: September 19, 2006
    Assignee: Bayer MaterialScience AG
    Inventors: Michael Mager, Thomas Stingl
  • Patent number: 7101956
    Abstract: Compounds that include diorgano groups having quaternary carbons and optionally urethane groups, urea groups, or combinations thereof (i.e., polyurethanes, polyureas, or polyurethane-ureas), as well as materials and methods for making such compounds.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: September 5, 2006
    Assignee: Medtronic, Inc.
    Inventors: Michael Eric Benz, Edward DiDomenico, Christopher M. Hobot, Randall V. Sparer, Kenneth B. Wagener, John E. Schwendeman
  • Patent number: 7101934
    Abstract: An object of the present invention is to provide a coating composition used for a golf ball, which is superior in not only abrasion resistance and impact resistance but also weather resistance to a conventional coating used for a golf ball. According to the present invention, there is provided a coating composition used for a golf ball, which comprises (A) a polyester- and/or polyether-containing acrylic polyol having a hydroxyl value of from 30 to 180 mg KOH/g(solid) and (B) a polyisocyanate, wherein the component (A) is composed of a main chain comprising an acrylic polymer and a side chain comprising a polyester and/or a polyether, and a molar ratio of an isocyanate group in the component (B) to a hydroxyl group in the component (A), [NCO]/[OH], is from 0.5 to 1.5.
    Type: Grant
    Filed: February 25, 2003
    Date of Patent: September 5, 2006
    Assignees: Asia Industry Co., Ltd., Bridgestone Sports Co., Ltd.
    Inventors: Noriyuki Shimura, Kazuya Sugimoto, Yutaka Miyata, Takashi Ohira
  • Patent number: 7090799
    Abstract: The invention provides a golf ball comprising a core and a cover of one or more layers, characterized in that at least one layer which constitutes the cover is formed primarily of a mixture of (A) a thermoplastic resin composition selected from among a thermoplastic block copolymer, polyester base elastomer, polyamide base elastomer and polyolefin, which are modified with functional groups having reactivity with isocyanate, and (B) an isocyanate compound or an isocyanate mixture having at least two isocyanate groups as functional groups in a molecule, and a method for preparing the same. The golf ball has excellent flight performance, feel on impact, and scuff resistance.
    Type: Grant
    Filed: March 9, 2004
    Date of Patent: August 15, 2006
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Rinya Takesue, Hiroyuki Nagasawa, Toshihiko Manami, Eiji Takehana
  • Patent number: 7091286
    Abstract: Low-cure powder coating compositions are disclosed, comprising at least one epoxy-containing resin and/or at least one siloxane-containing resin, and at least one material having the structure wherein R1 is an organic radical having 6 to 25 carbon atoms; each R2 is independently a multivalent hydrocarbon group having 1 to 20 carbon atoms; Y is each R3 and R4 are independently alkyl or aryl groups having 1 to 8 carbon atoms; each Z is independently oxygen or nitrogen; R5 is absent when Z is oxygen and R5 is hydrogen, an alkyl or aryl group having 1 to 20 carbon atoms, or (Y)a —R2— when Z is nitrogen; a and b are integers; a is at least 1; b is 1 to 3; and (b) at least one epoxy-containing resin and/or at least one siloxane-containing resin. The material can optionally be reacted with an acidic hydrogen-containing compound. Some compositions are curable without using crosslinking agents or accelerators.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: August 15, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Shawn P. Duffy, Anthony M. Chasser, Ronald R. Ambrose
  • Patent number: 7084211
    Abstract: A cold setting coating composition comprises an urethane-modified vinyl resin (A) produced by reacting a reaction product with an isocyanate group-possessing compound (c). The reaction product is produced by reacting an epoxy group-containing vinyl copolymer (a) with a fatty acid component (b) containing an unsaturated fatty acid. The vinyl copolymer (a) is a copolymer of a first polymerizable unsaturated monomer containing an epoxy group and a second polymerizable unsaturated monomer. The composition also comprises a polymer dispersion (B) obtained by polymerizing two or more of vinyl monomers in the presence of a dispersion stabilizer (d) in an organic liquid in which vinyl monomers are soluble and a polymer formed from the monomers is insoluble. The dispersion stabilizer (d) is soluble in the organic liquid. The coating composition improved weathering resistance and water resistance of the resulting coated film.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: August 1, 2006
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Tadahiro Nakao, Chicara Kawamura, Toshihiro Hamamura, Hiroyuki Tsukadaira, Masami Sugishima
  • Patent number: 7078454
    Abstract: This invention provides compositions for treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising a 1) fluorochemical urethane formed by reacting a tri- or higher order isocyanate with a fluorochemical monofunctional compound and optionally a non-fluorinated aliphatic monofunctional compound; and 2) a fluorochemical polymeric surfactant.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: July 18, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Malcolm B. Burleigh, David P. Cheatham, John C. Clark, A. Dale Otteson
  • Patent number: 7064165
    Abstract: Coating materials curable thermally and with actinic radiation, comprising (A) at least one binder containing isocyanate-reactive functional groups and (B) a crosslinking component comprising (i) free and/or blocked isocyanate groups, (ii) reactive functional groups containing at least one bond which can be activated with actinic radiation, (iii) flexibilizing segments which as part of three-dimensional networks lower their glass transition temperature Tg, and (iv) hardening segments which as part of three-dimensional networks raise their glass transition temperature Tg; with the proviso that the crosslinking component (B) comprises or consists of at least one constituent which has the features (i) and (ii); processes for their preparation, and their use.
    Type: Grant
    Filed: June 18, 2002
    Date of Patent: June 20, 2006
    Assignee: BASF Coatings AG
    Inventors: Hubert Baumgart, Uwe Meisenburg
  • Patent number: 7064151
    Abstract: The invention provides in one aspect a process for preparing a microgel by RAFT polymerizing in the presence of a RAFT chain transfer agent, one or more solvophobic monomers and one or more solvophilic monomers to form one or more block copolymers comprising one or more solvophobic blocks and one or more solvophilic blocks wherein the solvophobic block is insoluble in a dispersing medium and the solvophilic block is soluble in the dispersing medium. The block copolymer is dispersed in the dispersing medium to form micelles, which is then stabilized to form the microgel. The dispersing medium can be aqueous or lipophilic. The method of the present invention also permits one to encapsulate a wide variety of materials, such as pigments, dye molecules, and aluminum flakes used in metallized paints.
    Type: Grant
    Filed: April 6, 2001
    Date of Patent: June 20, 2006
    Assignees: E. I. du Pont de Nemours and Company, Commonwealth Scientific and Industrial Research Organisation
    Inventors: Charles T. Berge, John Chiefari, Jeffery W. Johnson, Albert Mau, Roshan Mayadunne, Catherine Louise Moad, Graeme Moad, Ezio Rizzardo, Gerry Swiegers, San Thang, Gerry Wilson
  • Patent number: 7064168
    Abstract: AnB block copolymers, wherein n is at least two, that include A blocks with poly(vinyl pyrrolidone) units and B blocks with urethane groups, urea groups, imide groups, amide groups, ether groups, ester groups, or combinations thereof, as well as medical devices and methods.
    Type: Grant
    Filed: May 10, 2004
    Date of Patent: June 20, 2006
    Assignee: Medtronic, Inc.
    Inventors: Michael Eric Benz, Julie A Alkatout, SuPing Lyu
  • Patent number: 7060357
    Abstract: A coating composition contains solid particulates of a mixture of an aminoplast crosslinking agent, a solid polymer having functionality reactive with the aminoplast crosslinking agent, and a crystalline, carbamate-functional additive. The crystalline, carbamate-functional additive has a melting point of at least about 30° C. and is up to about 15% by weight of the powder coating composition.
    Type: Grant
    Filed: October 4, 2002
    Date of Patent: June 13, 2006
    Assignee: BASF Corporation
    Inventors: Walter H. Ohrbom, David J. Law, Robert D. Weise, James A. Laugal
  • Patent number: 7041725
    Abstract: Modified polyurethanes based on polyurethane reactive systems composed of at least one organic polyisocyanate and a polyol formulation, which additionally contains at least one polymer modifier and at least one filler are prepared. These modified polyurethanes are useful in the production of electroplated/metallized molded articles.
    Type: Grant
    Filed: April 16, 2003
    Date of Patent: May 9, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Detlef Arntz, Eduard Mayer, Helmut Meyer
  • Patent number: 7041379
    Abstract: Elastomer coating composition are disclosed which cure at room temperature, and form highly flex-resistant, durable, and flexible protective layer on elastomers and provides excellent adhesion to elastomeric and metal substrates. The coating is a solvent solution of (A) a carboxylated hydrogenated acrylonitrile-butadiene copolymer, and (B) a room temperature isocyanate curing component. Coated bonded elastomer-metal composites are obtained without an additional application of heat to cure the coating.
    Type: Grant
    Filed: September 4, 2003
    Date of Patent: May 9, 2006
    Assignee: Lord Corporation
    Inventors: James R. Halladay, Frank J. Krakowski
  • Patent number: 7040797
    Abstract: Provided is a method of producing a composition comprising a thermoplastic resin and a rubber, wherein a solid rubber is molten by a rubber kneading machine and fed into an extruder, and the molten rubber is melt-kneaded with the thermoplastic resin in the extruder. The composition has a uniform component ratio and excellent moldability, and can be used widely as raw materials of molded articles, sheets, films and containers.
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: May 9, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takanari Yamaguchi, Motonobu Furuta
  • Patent number: 7030201
    Abstract: The present invention relates to bottom antireflective coating compositions and polymers useful in making such compositions.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: April 18, 2006
    Assignee: AZ Electronic Materials USA Corp.
    Inventors: Huirong Yao, Shuji Ding-Lee, Hengpeng Wu, Zhong Xiang
  • Patent number: 7025853
    Abstract: A moisture-reactive hot-melt composition, useful as an adhesive, is provided that has improved balance of open time and green strength. In particular, the composition is made from a polyol, a polyisocyante, and an acrylic polymer. Also provided are a method for making such compositions and a method for using such compositions for bonding substrates.
    Type: Grant
    Filed: June 12, 2003
    Date of Patent: April 11, 2006
    Assignee: Rohm and Haas Company
    Inventor: Mark Alan Kesselmayer
  • Patent number: 7022257
    Abstract: A floor coating composition containing one or more unsaturated urethane compounds, which is(are) obtained from an isocyanate compound(s) and a hydroxyl compound(s) as starting materials, wherein at least one of the isocyanate compound(s) and the hydroxyl compound(s) has an unsaturated bond(s), wherein the poly(alkyleneoxy) group content (as defined in the specification) is 2–16 wt % and the proportion of the number of the unsaturated bonds (as defined in the specification) is not less than 6, can form a coating film superior in staining resistance against extremely powerful staining substances and gloss retentivity against extremely great load from walking, and which permits easy polishing away of damages and color stain, as well as use of water as a solvent. When a coating object is covered with a film made from the composition, a coated material can be obtained, wherein warpage of a coating object (floor, floor material, plastic film and the like) and cracks in the film are suppressed.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: April 4, 2006
    Assignees: Shin-Nakamura Chemical Co., Ltd., GEN Maintenance Technology Inc.
    Inventors: Masaji Ohkido, Yoji Tominaga, Ryo Imami
  • Patent number: 7022767
    Abstract: The present invention provides a composition of matter having the structure: where Q is a multi-valent organic moiety containing isocyanurate functionality; X is H, —CH2OH, or —CH2OR?; R? is an alkyl or aryl group having from 1 to 12 carbon atoms; and y is at least 2. Also provided is a curable composition containing the composition of matter.
    Type: Grant
    Filed: February 5, 2004
    Date of Patent: April 4, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Michael A. Mayo, Steven V. Barancyk, Jane N. Valenta, Sherry M. Gaggini, William A. Humphrey
  • Patent number: 7012115
    Abstract: The present invention provides an aqueous urethane polyol comprising a hydroxyl group, a urethane group and a hydrophilic groups in a molecule, wherein: an average number of hydroxyl group is 3 to 20; a hydroxyl value is 10 to 200 (mg KOH/g); an equivalent ratio of (urethane group)/(hydroxyl group+hydrophilic group) is 1 to 2; and a number average molecular weight is 1,000 to 20,000.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: March 14, 2006
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Yoshiyuki Asahina, Hironori Katagawa
  • Patent number: 7005470
    Abstract: The invention relates to aqueous two-component polyurethane systems comprising vinyl polymer polyol dispersions modified with reactive diluents, to a process for preparing them and to use as coating materials.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: February 28, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Probst, Martin Melchiors, Gerhard Ruttmann, Thomas Stingl, Hartmut Ottensmann