With Saturated Aldehyde Or Aldehyde Derivative (including Methylol Ethers Or Condensates) Reactant Or Solid Polymer Thereof; Or With Solid Copolymer Derived From At Least One Aldehyde Or Aldehyde Derivative Reactant Wherein At Least One Of The Reactants Forming The Solid Copolymer Is Saturated; Or With Spfi Wherein At Least One Of The Necessary Ingredients Is An Aldehyde Or Aldehyde Derivative Reactant Or With A Reaction Product Thereof; Or With Sicp Containing An Aldehyde Or Aldehyde Derivative Patents (Class 525/154)
  • Patent number: 4511683
    Abstract: Compounds having a cyclopentadiene skeleton and at least one sulfonic acid group are novel, and produced by subjecting cyclopentadiene, dicyclopentadiene and/or hydroxydicyclopentadiene to sulfonation, and subjecting the same, before or after the sulfonation, to reaction with alkylbenzene, polymerization and/or condensation through an aldehyde. The aforesaid compounds are useful as dispersants for cement.By incorporating a polymer emulsion into a slurry composition comprising a powder and a dispersant having at least one sulfonic acid group the proportion of said polymer emulsion being 0.05 to 50 parts by weight per 100 parts by weight of said dispersant, the dispersing effect of said dispersant is improved, the fluidizing effect of the dispersant is further enhanced, the slump loss is made very small, and the workability becomes good.
    Type: Grant
    Filed: March 3, 1983
    Date of Patent: April 16, 1985
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hironobu Shinohara, Noboru Yamahara, Yoshinori Yoshida
  • Patent number: 4495325
    Abstract: Coating compositions containing large amounts of polymer-bound ultraviolet radiation absorbing stabilizers and cross linkers give highly ultraviolet absorbent properties.
    Type: Grant
    Filed: February 25, 1983
    Date of Patent: January 22, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Michael DeBergalis, Robert P. O'Fee
  • Patent number: 4483959
    Abstract: Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
    Type: Grant
    Filed: June 28, 1983
    Date of Patent: November 20, 1984
    Assignee: Hercules Incorporated
    Inventors: William W. Maslanka, Gavin G. Spence
  • Patent number: 4444671
    Abstract: An arc quenching composition suitable for deionizing and extinguishing a high voltage electrical arc comprising an effective proportion of hexamethylenetetramine. Depending on the application in which the arc extinguishing composition is employed, the hexamethylenetetramine may be utilized alone, admixed with a suitable binder, or used to impregnate another material.
    Type: Grant
    Filed: March 29, 1976
    Date of Patent: April 24, 1984
    Assignee: S&C Electric Company
    Inventor: Bernard M. Wiltgen, Jr.
  • Patent number: 4424307
    Abstract: An oxymethylene polymer which is modified with 1,2-polybutadiene is provided which exhibits enhanced physical properties, including tensile impact, elongation, and work to break. The oxymethylene polymer may be a homopolymer, consisting essentially of recurring oxymethylene groups, or a copolymer (as described).
    Type: Grant
    Filed: March 26, 1982
    Date of Patent: January 3, 1984
    Assignee: Celanese Corporation
    Inventors: Andrew H. DiEdwardo, Rajal M. Kusumgar
  • Patent number: 4424317
    Abstract: A Mannich condensation product of an amorphous, oil soluble olefin/carbonyl polymer, amine and formaldehyde yielding reactant wherein the carbonyl groups are provided by at least one member selected from the group consisting of carbon monoxide and vinyl alkyl ketone and lube oil compositions comprising said polymers.
    Type: Grant
    Filed: December 6, 1982
    Date of Patent: January 3, 1984
    Assignee: Standard Oil Company (Indiana)
    Inventors: Carl Serres, John G. Schaffhausen
  • Patent number: 4417022
    Abstract: Coating compositions capable of liquid application to substrates consist essentially of a curable film forming polyol-containing component and an organic reactive diluent. The reactive diluent is an organic compound containing a primary or secondary hydroxyl group and further characterized by having a retained solids value of greater than about 80 percent, a hydroxyl equivalent weight of from about 180 to about 800, and a liquid viscosity of less than about 10 poise at 60.degree. C. The coating compositions can be formulated to contain little or no volatile organic solvent and/or water.
    Type: Grant
    Filed: April 2, 1982
    Date of Patent: November 22, 1983
    Assignee: PPG Industries, Inc.
    Inventors: Wen-Hsuan Chang, James B. O'Dwyer, John R. Peffer
  • Patent number: 4413999
    Abstract: The invention provides amidoxime derivatives of the general formula ##STR1## wherein R.sub.1 is an alkyl group of 1 to 8 carbon atoms, phenyl, a heterocyclic ring structure of 5 to 8 atoms containing one or more nitrogen or oxygen atoms or combinations thereof or a bicyclic condensed ring system optionally containing at least one heterocyclic ring which groups may each be optionally substituted. R.sub.2 is a mono or bicyclic heterocyclic radical containing at least two nitrogen atoms which radical is also optionally substituted. R.sub.3 and R.sub.4 are independently H, or an alkyl of 1 to 4 carbon atoms or one, but not both, is ##STR2## and the other, H, wherein R.sub.5 or R.sub.6 are alkyls of 2 to 5 carbon atoms optionally substituted by R.sub.1, or a phenyl optionally substituted by R.sub.1 or R.sub.5 or R.sub.6 is combined with R.sub.1 to jointly form cyclic imidoximes or imidedioximes.
    Type: Grant
    Filed: March 5, 1982
    Date of Patent: November 8, 1983
    Assignee: Research Products Rehovot Ltd.
    Inventors: Charles Linder, Gershon Aviv
  • Patent number: 4412041
    Abstract: A process for modifying a rubber, which comprises reacting a rubber having an unsaturated carbon linkage with an organic compound having a carboxyl group and an aldehyde group in the presence of an acid catalyst.
    Type: Grant
    Filed: February 18, 1983
    Date of Patent: October 25, 1983
    Assignee: Nippon Zeon Co. Ltd.
    Inventors: Shizuo Kitahara, Yoshitsugu Hirokawa, Haruki Kawada, Toshihiro Fujii, Nagatoshi Sugi, Hiroaki Hasegawa, Akira Yoshioka
  • Patent number: 4412031
    Abstract: A modified rubber composition comprising a blend of (a) a modified rubber obtained by reaction a rubber having an unsaturated carbon linkage with an organic compound having a carboxyl group and an aldehyde group in the presence of an acid catalyst, and (b) carbon black.
    Type: Grant
    Filed: February 18, 1983
    Date of Patent: October 25, 1983
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shizuo Kitahara, Yoshitsugu Hirokawa, Haruki Kawada, Toshihiro Fujii, Nagatoshi Sugi, Hiroaki Hasegawa, Akira Yoshioka
  • Patent number: 4404310
    Abstract: Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
    Type: Grant
    Filed: October 13, 1981
    Date of Patent: September 13, 1983
    Assignee: Hercules Incorporated
    Inventors: William W. Maslanka, Gavin G. Spence
  • Patent number: 4388450
    Abstract: Aromatic polyvinylethers and active hydrogen compound reaction products thereof have been found to provide fast heat curable molding compositions when used with various heat activated curing catalysts, for example, diaryliodonium salts in combination with aromatic polyvinylether soluble copper compounds, or dialkylhydroxyarylsulfonium salts in combination with certain organic oxidants.
    Type: Grant
    Filed: March 13, 1981
    Date of Patent: June 14, 1983
    Assignee: General Electric Company
    Inventor: James V. Crivello
  • Patent number: 4374953
    Abstract: Polyacetals and polyketals are prepared by reacting emulsified carbonyl compounds with emulsified polyfunctional alcohols in aqueous media and in the presence of specified polycondensation catalysts. Coherent films of the resultant polymers can be applied to substrates from aqueous or non-aqueous media.
    Type: Grant
    Filed: April 19, 1982
    Date of Patent: February 22, 1983
    Assignee: Dow Corning Corporation
    Inventors: Yungnien J. Chou, John C. Saam
  • Patent number: 4374230
    Abstract: Polyolefin resins are rendered stable against degradation caused by exposure to heat and oxygen in the presence of copper by the incorporation of a novel polymeric stabilizer functioning dually as an antioxidant and a chelating agent.
    Type: Grant
    Filed: March 28, 1979
    Date of Patent: February 15, 1983
    Assignee: El Paso Polyolefins Company
    Inventors: John L. H. Allan, Arnold B. Finestone, John J. Roderick
  • Patent number: 4366194
    Abstract: Aqueous solutions of amide polymers, such as polyacrylamide when treated with small amounts of a water-soluble polyaldehyde and a hypohalite salt at an alkaline pH, react to form firm gels within a short time at ambient temperature. Such gels, which are stable under alkaline as well as acidic conditions, are usefully employed to plug porous subterranean formations, for grouting of leaking soil pipes or wells, and to otherwise render porous structures impermeable to the passage of liquids such as water.
    Type: Grant
    Filed: April 21, 1980
    Date of Patent: December 28, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Richard J. Pilny, Thomas W. Regulski
  • Patent number: 4351916
    Abstract: A polyoxymethylene molding composition comprising an admixture which contains a small amount of poly(ethylene glycol) and a small amount of a dispersion of polyamide in a carrier resin.
    Type: Grant
    Filed: May 7, 1981
    Date of Patent: September 28, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Melvin I. Kohan
  • Patent number: 4343925
    Abstract: Coating compositions capable of liquid application to substrates consist essentially of a curable film forming polyol-containing component and an organic reactive diluent. The reactive diluent is an organic compound containing a primary or secondary hydroxyl group and further characterized by having a retained solids value of greater than about 80 percent, a hydroxyl equivalent weight of from about 180 to about 800, and a liquid viscosity of less than about 10 poise at 60.degree. C. The coating compositions can be formulated to contain little or no volatile organic solvent and/or water.
    Type: Grant
    Filed: December 7, 1979
    Date of Patent: August 10, 1982
    Assignee: PPG Industries, Inc.
    Inventors: Wen-Hsuan Chang, James B. O'Dwyer, John R. Peffer
  • Patent number: 4328133
    Abstract: Organic micro-fiber reinforced rubber compositions having high elastic modulus, excellent crack growth resistance, impact cut resistance and rebound resilience and a small swell value are prepared by incorporating 10-100 parts by weight of carbon black, 3-30 parts by weight of organic micro-fibers based on 100 parts by weight of at least one rubber selected from a group consisting of natural rubber, synthetic polyisoprene rubber, butyl rubber, halogenated butyl rubber, polybutadiene rubber, styrene-butadiene copolymeric rubber, ethylene-propylene-diene ternary copolymeric rubber and acrylonitrile-butadiene copolymeric rubber, said micro-organic staple fibers being lower than 30.degree. C. or higher than 120.degree. C. in glass transition temperature of amorphous portion and higher than 160.degree. C. in melting point of crystal portion, and having an average length of the micro-fibers of 0.8-30 .mu.m, an average diameter of the micro-fibers of 0.02-0.8 .mu.
    Type: Grant
    Filed: June 23, 1981
    Date of Patent: May 4, 1982
    Assignee: Bridgestone Tire Company Limited
    Inventors: Masaki Ogawa, Yasushi Hirata, Mikihiko Ikegami
  • Patent number: 4297448
    Abstract: A thermosetting coating composition which may have nonvolatile solids content as high as 60% or greater and which may be employed as an automotive topcoat. The composition, exclusive of pigments, solvent, reactive and non-reactive diluents and other non-reactive components, consists essentially of:(A) A binder composition consisting essentially of:(1) Between about 30 and about 75 weight percent of one or more low viscosity resins selected from hydroxy functional acrylic polymers, hydroxy functional polyethers and hydroxy functional polyesters, each of which (i) is substantially soluble in the solvent of the composition and (ii) has a number average molecular weight of between about 1000 and about 2500; and(2) Between about 70 and about 25 weight percent of one or more crosslinked dispersion polymers each of which is substantially insoluble in the solvent of the composition; and(B) An aminoplast crosslinking agent in an amount of between about 5 and about 40 parts per 100 parts of said binder composition.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: October 27, 1981
    Assignee: Ford Motor Company
    Inventors: Yun-Feng Chang, Henk V. Oene, Elaine C. Beckwith
  • Patent number: 4279809
    Abstract: Polyolefin resins are rendered stable against degradation caused by exposure to heat and oxygen in the presence of copper by the incorporation of a novel polymeric stabilizer functioning dually as an antioxidant and a chelating agent.
    Type: Grant
    Filed: July 14, 1976
    Date of Patent: July 21, 1981
    Assignee: El Paso Polyolefins Company
    Inventors: John L. H. Allan, Arnold B. Finestone, John J. Roderick
  • Patent number: 4277577
    Abstract: The invention provides a molding composition of a mixture of an oxymethylene polymer, an elastomer having a softening temperature of below the crystallite melting point of the oxymethylene polymer and a second order transition temperature of from -120.degree. to +30.degree. C., and a segmented thermoplastic copolyester.The molding composition of the invention is distinguished by improved mechanical properties, especially with respect to the impact strength.
    Type: Grant
    Filed: April 23, 1979
    Date of Patent: July 7, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karlheinz Burg, Werner Schmieder, Ernst Wolters
  • Patent number: 4265835
    Abstract: In a process for preparing a N-substituted derivative of a carboxamide, the conversion of carboxamide to the derivative is determined by carbon-13 nuclear magnetic resonance analysis (CMR) wherein the intensities of the carbonyl carbon peaks attributable to the carboxamide and the derivative are measured under conditions of magnetic resonance and the mole ratio of carboxamide to derivative is determined by comparing the intensities of said carbonyl carbon peaks.For example, in the reaction of polyacrylamide with a secondary amine such as dimethylamine and formaldehyde, the conversion of the polyacrylamide to its N-(dimethylaminomethyl) derivative is determined by subjecting the sample to CMR analysis and comparing the intensities of the carbonyl carbon peaks of the polyacrylamide and the N-(dimethylaminomethyl) derivative.
    Type: Grant
    Filed: September 10, 1979
    Date of Patent: May 5, 1981
    Assignee: The Dow Chemical Company
    Inventors: Charles J. McDonald, Robert H. Beaver
  • Patent number: 4259459
    Abstract: An improved polymerization emulsifier for use in the manufacture of synthetic rubber is prepared wherein a mixture of tall oil fatty acids and resin acids as found in crude or distilled tall oil is disproportionated to reduce the amount of abietic type acids and linoleic type acids and treated with acid catalyzed formaldehyde or paraformaldehyde. The disproportionation and aldehyde treatment can occur in sequence or simultaneously. Emulsifiers prepared by the invention process minimize prefloc in latex production and improve rubber physicals.
    Type: Grant
    Filed: May 21, 1980
    Date of Patent: March 31, 1981
    Assignee: Westvaco Corporation
    Inventor: Carlton G. Force
  • Patent number: 4258162
    Abstract: Alicyclic organomonolithium compounds having delocalized conjugated unsaturation are effective initiators in the preparation of polymers of conjugated dienes. Polymers of conjugated dienes, prepared with or without the alicyclic organomonolithium compounds, are terminated with alicyclic compounds having conjugated unsaturation. Either or both approaches can be used to provide polymers containing alicylic conjugated unsaturated functional groups. Alternatively, polymers prepared from the alicyclic organomonolithium compounds can be coupled to produce linear or branched polymers. Polymers prepared from multichelic lithium compounds also can be terminated with alicyclic conjugated unsaturated compounds.
    Type: Grant
    Filed: July 10, 1979
    Date of Patent: March 24, 1981
    Assignee: Phillips Petroleum Company
    Inventors: Carl A. Uraneck, John E. Burleigh
  • Patent number: 4250661
    Abstract: A covering multilayer film or sheet structure for agricultural application, which consists essentially of:(1) a film or sheet of a resin composition comprising (A) 100 parts by weight of a thermoplastic resin selected from the group consisting of olefinic resins and vinyl chloride resins and (B) about 1 to about 40 parts by weight of an acetal resin, and(2) a layer of the thermoplastic resin (A) laminated to at least one surface of the film or sheet (1); and a method for maintaining an agricultural locus at temperatures suitable for the growth of plants, using aforesaid covering multilayer film or sheet.
    Type: Grant
    Filed: August 23, 1979
    Date of Patent: February 17, 1981
    Assignee: Sekisui Kagaku Kogyo K.K.
    Inventors: Yoshiaki Kodera, Kiyoyuki Watanabe, Tetsuo Kadoya, Tadashi Taguchi
  • Patent number: 4237243
    Abstract: Use of cross-linked polymers for increasing the viscosity in cosmetic, pharmaceutical and technical compositions, wherein the polymer chains have the following composition:k - p molar % of groups of the formula ##STR1## p molar % of groups of the formula ##STR2## from 0 to 45 molar % of groups of the formula ##STR3## and from 0.1 to 20 molar % of a cross-linking agent, whereinR.sup.1 represents as a statistical mean value from 0 to 100 molar % of hydrogen and from 100 to 0 molar %, each calculated on the proportion of (k-p) molar %, of CH.sub.2 OH groups,R.sup.2 and R.sup.3 are hydrogen, or one of the radicals R.sup.2 and R.sup.
    Type: Grant
    Filed: February 9, 1979
    Date of Patent: December 2, 1980
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jochen M. Quack, Alwin Reng, Juliane Balzer, Friedrich Engelhardt, Joachim Ribka
  • Patent number: 4237249
    Abstract: A crosslinked copolymer useful in textile printing is prepared by(a) polymerizing in the presence of a radical initiator in a water-miscible alkanol k mole percent acrylamide with 0 to 45 mole percent of a compound of the formula ##STR1## and 0.1 to 20 mole percent of a crosslinked agent wherein k is 99.9 to 50, R.sup.2 and R.sup.3 are hydrogen or methyl with the proviso that only one of R.sup.2 and R.sup.
    Type: Grant
    Filed: December 1, 1978
    Date of Patent: December 2, 1980
    Assignee: Cassella Aktiengesellschaft
    Inventors: Juliane Balzer, Friedrich Engelhardt, Joachim Ribka, Wolfram Schidlo
  • Patent number: 4228218
    Abstract: A polymer composite material which comprises a first rigid polymeric material composed substantially of rigid molecular chains having an average chain length of 50 A or more, and a second polymeric material composed substantially of flexible molecular chains, wherein said first rigid polymeric material is present in an amount of 20% or less based on the total weight of polymeric material in said composite and said first material is uniformly dispersed in said second polymeric material in a microscopic region of 1 .mu.m or less.
    Type: Grant
    Filed: November 6, 1978
    Date of Patent: October 14, 1980
    Assignees: Motowo Takayanagi, Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Motowo Takayanagi, Tisato Kajiyama
  • Patent number: 4221700
    Abstract: A stabilized synthetic polymer composition comprising(1) 100 parts by weight of a synthetic polymer,(2) 0.001 to 5 parts by weight of a poly(alkylated alkenylphenol) composed substantially of monomeric units represented by the following formula (I) ##STR1## wherein R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R.sub.1 represents an alkyl group having 1 to 18 carbon atoms; and R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 18 carbon atoms; and(3) 0.001 to 5 parts by weight of an auxiliary stabilizer selected from the group consisting of polyhydric alcohol esters of alkylthioalkanoic acids, polyesters of thiodipropionic acid and organic phosphite compounds.
    Type: Grant
    Filed: July 5, 1978
    Date of Patent: September 9, 1980
    Assignee: Maruzen Oil Co., Ltd.
    Inventors: Motomobu Minagawa, Mitsuo Akutsu, Hiroshi Fujiwara, Masayuki Kashiki
  • Patent number: 4220736
    Abstract: A resin composition in the form of a covering film or sheet comprising (A) 100 parts by weight of a thermoplastic olefinic resin and (B) about 1 to about 20 parts by weight of an acetal resin; and a method for maintaining an agricultural locus at temperatures suitable for the growth of plants, using above covering film or sheet.
    Type: Grant
    Filed: June 1, 1978
    Date of Patent: September 2, 1980
    Assignee: Sekisui Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshiaki Kodera, Kiyoyuki Watanabe, Takayuki Kusu
  • Patent number: 4214034
    Abstract: A covering multilayer film or sheet structure for agricultural application, which consists essentially of:(1) a film or sheet of a resin composition comprising (A) 100 parts by weight of a thermoplastic resin selected from the group consisting of olefinic resins and vinyl chloride resins and (B) about 1 to about 40 parts by weight of an acetal resin,and(2) a layer of the thermoplastic resin (A) laminated to at least one surface of the film or sheet (1); and a method for maintaining an agricultural locus at temperatures suitable for the growth of plants, using aforesaid covering multilayer film or sheet.
    Type: Grant
    Filed: June 1, 1978
    Date of Patent: July 22, 1980
    Assignee: Sekisui Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshiaki Kodera, Kiyoyuki Watanabe, Tetsuo Kadoya, Tadashi Taguchi
  • Patent number: 4193906
    Abstract: A composition for a solid writing material and a writing implement, the composition comprising: (i) at least one of dibenzylidene sorbitol and derivatives thereof and tribenzylidene sorbitol and derivatives thereof, (ii) at least one of (a) esters of a mono-saturated fatty acid having 10 to 20 carbon atoms and a mono-saturated aliphatic alcohol having 1 to 8 carbon atoms and (b) a mixture of the ester or esters and at least one liquid paraffin, (iii) a resin component, (iv) a coloring agent, and (v) an organic solvent.
    Type: Grant
    Filed: February 14, 1978
    Date of Patent: March 18, 1980
    Assignee: Sakura Color Products Corporation
    Inventor: Akio Hatanaka
  • Patent number: 4163764
    Abstract: A monovinyl arene, such as styrene, is polymerized with a monofunctional lithium initiator, followed by addition of a conjugated diene, such as butadiene, with additional monofunctional lithium initiator. The resultant block copolymers are coupled to give linear coupled block copolymers or radial coupled block copolymers with a random distribution of homopolymer and copolymer branches. The polymers exhibit increased tack and improved creep resistance in adhesive compositions. The amount of initiator added as the second increment with the second monomer must be greater than the amount added as the first increment with the first monomer.
    Type: Grant
    Filed: June 23, 1977
    Date of Patent: August 7, 1979
    Assignee: Phillips Petroleum Company
    Inventor: Larry L. Nash