Specified Blending Process Patents (Class 525/197)
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Patent number: 5270115Abstract: Reversible polymer gels comprising:(a) 55-98% by weight based on the total polymers contained in the gel, of an elastomeric copolymer of vinylidene fluoride comprising, in moles, 55-85% of vinylidene fluoride, 15-45% of hexafluoropropene and 0.30% of tetrafluoroethylene;(b) 2-45% based on the total polymers contained in the gel, of a non-elastomeric polymer selected from non-elastomeric VDF. based polymers, or polyvinylfluoride, or acrylic resins, for example polyalkylmethacrylates and copolymers of alkylmethacrylates with alkylacrylates, having T.sub.g >50.degree. C.Type: GrantFiled: April 2, 1993Date of Patent: December 14, 1993Assignee: Ausimont S.p.A.Inventors: Liberato Mascia, Giovanni Moggi
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Patent number: 5248729Abstract: A thermoplastic resin composition is prepared by heat-treating a mixture of a thermoplastic resin substantially containing no olefinic unsaturated carbon-carbon bond and an elastomer having an olefinic unsaturated carbon-carbon bond, dynamically in the presence of a crosslinking agent, characterized in that as said elastomer there is used at least one member selected from the group consisting of styrene-butadiene-styrene block copolymer (SBS), styrene-isoprene-styrene block copolymer (SIS), 1,2-polybutadiene rubber and ethylene-propylene-diene random copolymer (EPDM), and that as said crosslinking agent there is used a dihydroaromatic compound or a polymer thereof.Type: GrantFiled: August 21, 1992Date of Patent: September 28, 1993Assignee: Nippon Petrochemicals Company LimitedInventors: Toshio Inoue, Shiyuji Kashiwase, Masaaki Miyazaki, Toshitsune Yoshikawa, Masaaki Kobayashi
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Patent number: 5244942Abstract: The invention concerns a homogenous, in particular multicolored plastic sheet or panel, based on ethylene vinyl acetate copolymer (EVA) as binder with a filler content of 30 to 80 wt. % and a process for producing it. In other embodiments the binder contains, in addition to the 70 to 85 wt. % of EVA, polypropylenes to improve the processability (tendency to adhere), EPDM to improve the flexibility, and polyethylenes to reduce the tendency to soiling. In the process described, several additives, each consisting of a binder containing at least some ethylene vinyl acetate copolymer, up to 80 wt. % of fillers and up to 5 wt. % of pigments, are mixed, plasticized and granulated or comminuted to form granules or chips of assorted colours which are mixed and, possibly after other processing operations, pressed to form the plastic web or plates.Type: GrantFiled: August 31, 1992Date of Patent: September 14, 1993Assignee: Huels Troisdorf AGInventors: Alexander Hover, Manfred Simon, Herbert Schulte, Josef Becker, Richard Weiss, Hans-Joachim Kaseler
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Patent number: 5239000Abstract: Thermoplastic elastomers in which low molecular weight ethylene/propylene/nonconjugated diene rubber ("liquid" EPDM rubber) replaces part of the high molecular weight EPDM rubber used in conventional blends exhibit better tension set properties than conventional blends in which liquid EPDM rubber is not used. A masterbatch containing liquid EPDM rubber and phenolic curing resin which is added to a mixture of polyolefin, high molecular weight EPDM rubber, and other ingredients during mixing results in a thermoplastic elastomer having better mechanical properties as well as better tension set properties than blends of conventional materials.Type: GrantFiled: June 21, 1991Date of Patent: August 24, 1993Assignee: Yukong LimitedInventors: Myung H. Kim, Byung H. Lee
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Patent number: 5229460Abstract: A solventless process for preparing a fluoropolymer based coating which involves mixing and heating a fluoropolymer with a thermoplastic acrylic resin to obtain a molten mixture, slowly cooling the molten mixture to obtain a solid mass having a degree of crystallinity of at least 85% and grinding the solid mass at a temperature higher than -50.degree. C.Type: GrantFiled: December 6, 1991Date of Patent: July 20, 1993Assignee: Evodex Powder CoatingsInventors: Mohammed K. Yousuf, Peter J. Stephenson, Nicholas J. Welton, Adrian J. Shortland
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Patent number: 5218046Abstract: The compositions contain a) less than 90% and at least 2% by weight of at least one ethylene polymer (A), and optionally, at least one .alpha.-olefin having from 3 to 12 carbon atoms, said polymer containing at least 70% in moles of patterns derived from ethylene, and b) more than 10% and up to 98% by weight of at least one polymer (B) containing at least 85% in moles of patterns derived from at least one .alpha.-olefin having from 3 to 12 carbon atoms and at the most 15% in moles of patterns derived from ethylene, and are characterized in that the polymer (A) is a modified polymer of which the measured limit viscosity is comprised between 1.3 and 100 times its limit viscosity calculated from the distribution of molecular masses. The compositions are obtained by a process consisting in providing a polymer of ethylene and, optionally, of at least one .alpha.Type: GrantFiled: December 7, 1989Date of Patent: June 8, 1993Assignee: NorsolorInventors: Joel Audureau, Vincent Crenna
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Patent number: 5210139Abstract: A thermoplastic olefin comprising an alloy of an olefin copolymer elastomer and a propylene/comonomer random copolymer is provided. The comonomer is selected from one or more of ethylene and C.sub.4 to C.sub.10 alpha-olefins. Polypropylene is an optional component of the alloy. The alloy may be produced by melt blending, reactor blending or a combination thereof, of the various components.Type: GrantFiled: February 6, 1991Date of Patent: May 11, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Terrence Huff, James J. McAlpin
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Patent number: 5198471Abstract: A method for separating polymers from a physically commingled solid mixture containing a plurality of polymers comprises dissolving a first one of the polymers in a solvent at a first lower temperature to form a first preferably single phase solution and a remaining solid component. The solid component contains additional polymers which are not soluable to the solvent at the first temperature but which may be soluble at higher temperatures. The method includes subsequently heating the solvent to dissolve additional polymer from the solid component to form subsequent solutions. The polymers are then separated from their respective solution either using flash evaporation techniques when more than one polymer has been dissolved at a single temperature, or conventional techniques for extracting a polymer from a solvent in a solution.Type: GrantFiled: September 11, 1989Date of Patent: March 30, 1993Assignee: Rensselaer Polytechnic InstituteInventors: E. Bruce Nauman, Jerry C. Lynch
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Patent number: 5187231Abstract: Plastics suitable for use as thermoplastic moulding compositions obtained fromA) a thermoplastic vinyl polymer andB) a mixture ofB1) a copolymer of 35 to 49% by weight of maleic acid anhydride and 65 to 51% by weight of styrene andB2) a copolymer of styrene, .alpha.-methylstyrene or mixtures thereof on the one hand and acrylonitrile on the other having an acrylonitrile content of 35 to 60% by weight [based on B2)]and a process for their preparation.Type: GrantFiled: August 30, 1991Date of Patent: February 16, 1993Assignee: Bayer AktiengesellschaftInventors: Christian Lindner, Herbert Eichenauer, Holger Lutjens, Hans-Eberhard Braese
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Patent number: 5180783Abstract: Compositions containing at least 60% by weight of at least one copolymer (A) of ethylene and at least one alpha-olefin with 3 to 10 carbon atoms, and no more than 40% by weight of at least one copolymer (B) based on ethylene and at least one anhydride of an unsaturated dicarboxylic acid, characterized in that:(i) copolymer (A) has a density between 0.850 and 0.890,(ii) copolymer (B) contains at least 80 mol-% of units derived from ethylene and at least 0.1 mol-% of units derived from the anhydride of an unsaturated dicarboxylic acid, and(iii) at least one of copolymers (A) and (B) is modified by means of an effective amount either of a free-radical initiator if the modification involves copolymer (A), or of at least one compound capable of reacting with the anhydride functions of copolymer (B).Type: GrantFiled: December 21, 1990Date of Patent: January 19, 1993Assignee: AtochemInventors: Brigitte Seguela, Patrick Kaifasz
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Patent number: 5157081Abstract: A dynamically vulcanized alloy composition having improved tensile strength including a first butyl or halogenated butyl rubber-based elastomer and a second EPM and/or EPDM elastomer in a matrix of a crystalline polyolefinic resin, and processes for producing the improved composition.Type: GrantFiled: June 10, 1991Date of Patent: October 20, 1992Assignee: Advanced Elastomer Systems, L.P.Inventors: Robert C. Puydak, Donald R. Hazelton, Trazollah Ouhadi
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Patent number: 5128446Abstract: Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the prsence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.Type: GrantFiled: September 6, 1989Date of Patent: July 7, 1992Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Hayashi, Shunyo Uesugi, Hiroo Wamura
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Patent number: 5106906Abstract: 37 Highly dispersed mixtures of at least two polymers which are not completely miscible in the melt under customary conditions are produced by melting the polymers used in the presence of supercritical gases or mixtures of gases, intensively thoroughly mixing the molten polymers for long enough until the viscosity of the melt has diminished by at least 10%, subsequently cooling the polymer melt with further thorough mixing, until the viscosity of the melt has at least reached the original value again and then depressurizing the polymer melt. The highly dispersed mixtures produced in this way can be processed in the customary manner into mouldings.Type: GrantFiled: September 22, 1989Date of Patent: April 21, 1992Assignee: Bayer AktiengesellschaftInventors: Erich Meier, Hanns-Ingolf Paul, Rudiger Plaetschke, Gunther Weymanns
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Patent number: 5100947Abstract: A dynamically vulcanized composition comprising a polyolefin resin and an elastomer is provided in which a major portion of fillers or specified additives are present in the polyolefin resin. A process for producing the dynamically vulcanized composition is also provided including the addition of the fillers and/or specified additives after the dynamic vulcanization step. The compositions have improved stiffness to impact balance.Type: GrantFiled: March 19, 1990Date of Patent: March 31, 1992Assignee: Advanced Elastomer Systems, L. P.Inventors: Robert C. Puydak, Donald R. Hazelton, Blair A. Graham, Narayanaswami R. Dharmarajan
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Patent number: 5086121Abstract: Thermoplastic compositions of matter useful as gasketing materials as well as flexible boots and seals which are soft, have low compression set and high tensile. The compositions comprise a polyolefin resin and at least two different rubbers, one of which is vulcanized to a fully cured state by a cure systems which leaves the other rubber(s) unvulcanized. The preferred embodiment comprises a blend of polypropylene and ethylene vinylacetate as the polyolefin resin component, EPDM as the uncured rubber component and a ZnO cured halogenated butyl rubber. In another embodiment of the invention, the resin is excluded and the uncured rubber is a high crystallinity EPDM.Type: GrantFiled: July 20, 1990Date of Patent: February 4, 1992Assignee: Advanced Elastomer Systems, L. P.Inventors: Donald R. Hazelton, Robert C. Puydak, D. A. Booth
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Patent number: 5075355Abstract: An improved stabilizer concentrate for use in stabilizing polymeric blend compositions which comprise a thermally sensitive interpolymer. The stabilizer concentrate comprises a carrier resin, and a stabilizing agent capable of stabilizing a thermally sensitive interpolymr. The improvement comprises employing a carrier resin having a viscosity such that the stabilizer concentrate has a viscosity of less than 60 percent of the viscosity of the polymeric blend composition.Type: GrantFiled: September 14, 1989Date of Patent: December 24, 1991Assignee: The Dow Chemical CompanyInventors: Mark J. Hall, Joseph R. Powers
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Patent number: 5073597Abstract: A dynamically vulcanized alloy composition having improved tensile strength including a first butyl or halogenated butyl rubber-base elastomer and a second EPM and/or EPDM elastomer in a matrix of a crystalline polyolefinic resin, and processes for producing the improved composition.Type: GrantFiled: May 26, 1989Date of Patent: December 17, 1991Assignee: Advanced Elastomer Systems, L. P.Inventors: Robert C. Puydak, Donald R. Hazelton, Trazollah Ouhadi
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Patent number: 5073598Abstract: A method for improving the processing characteristics of a polyethylene blend comprised of at least two polyethylene components having at least one dissimilar rheological property. The method comprises the steps of (a) establishing a functional relationship between free radical generator dosage and a rheological property for at least one polyethylene component of the polyethylene blend; (b) determining a free radical generator dosage from said relationship for use with at least one polyethylene component, said dosage level sufficient to enable the polyethylene component so treated to exhibit a rheological property substantially similar to that of all components present in the blend; (c) treating at least one polyethylene component at the dosage of free radical generator determined in step (b); and (d) blending the polyethylene components in melt form. A process for the extrusion of films from blends of polyethylenes is also provided.Type: GrantFiled: June 21, 1989Date of Patent: December 17, 1991Assignee: Mobil Oil CorporationInventor: David J. Anzini
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Patent number: 5057575Abstract: Polymer blend composition having improved processibility and comprising:(a) a major portion of a difficultly melt-procesible polymer, and(b) a minor portion of:1 at least an effective amount, to improve processibility, of a fluorocarbon copolymer which at the melt-processing temperature of (a) is either in a melted form if crystalline, or is above its glass transition temperature if amorphous, and(2) at least an effective amount, to improve processibility, of at least one tetrafluoroethylene homopolymer or copolymer of tetrafluoroethylene and at least one monomer copolymerizable therewith, wherein the mole ratio of fluorine to hydrogen is at least 1:1, and which is solid at the melt-processing temperature of (a);masterbatches comprised of the processing aid; and processes utilizing the processing aid.Type: GrantFiled: February 1, 1991Date of Patent: October 15, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventors: George R. Chapman, Jr., Donnan E. Priester, Charles W. Stewart
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Patent number: 5051477Abstract: A dynamically vulcanized thermoplastic composition is provided which comprises a polymer blend of a polyolefin resin, a halogenated elastomeric copolymer, such as a halogenated butyl rubber, or a halogenated copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene, and a halogenated polyethylene. The composition has improved flame retarding properties. Additional flame retarding additives may be incorporated in the composition. The dynamically vulcanized thermoplastic composition is suitable for use in roofing sheets.Type: GrantFiled: May 4, 1990Date of Patent: September 24, 1991Assignee: Advanced Elastomer Systems, L. P.Inventors: Thomas C. Yu, Robert C. Puydak, Charles W. Degener
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Patent number: 5051478Abstract: A dynamically vulcanized composition is provided which comprises a polyolefin resin, an elastomer, and an ethylene copolymer resin such as a copolymer of ethylene and vinyl acetate or an alkyl acrylate. A process for producing the dynamically vulcanized composition is also provided, which process includes the addition of the ethylene copolymer resin after the dynamic vulcanization step. The resulting composition comprises the ethylene copolymer resin predominantly in the polyolefin resin phase. The compositions have improved surface appearance and softness.Type: GrantFiled: July 26, 1990Date of Patent: September 24, 1991Assignee: Advanced Elastomer Systems, L. P.Inventors: Robert C. Puydak, Donald R. Hazelton
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Patent number: 5051479Abstract: A melt-processable thermoplastic composition consisting essentially of a blend of a melt processable thermoplastic fluorocarbon polymer and about 0.05 to about 0.5 percent by weight of an elastomeric copolymer of tetrafluoroethylene and a perfluoro(alkyl vinyl ether) exhibits improved processing properties.Type: GrantFiled: April 3, 1989Date of Patent: September 24, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventors: Anestis L. Logothetis, Charles W. Stewart
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Patent number: 5041500Abstract: A heterogeneous meltable fluorine-containing polymer blend composition which comprises a tetrafluoroethylene/hexafluoropropylene copolymer and a copolymer of tetrafluoroethylene and at least one fluorovinyl ether of the formula:CF.sub.2 .dbd.CF--O--R.sub.f (I)wherein R.sub.f is a fluoroalkyl group having 1 to 10 carbon atoms, which is easily molded and provides an article having good mechanical properties.Type: GrantFiled: September 25, 1989Date of Patent: August 20, 1991Assignee: Daikin Industries, Ltd.Inventors: Kazuo Ishiwari, Tsuyoshi Noguchi
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Patent number: 5039747Abstract: A process for the production of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) a thermoplastic resin, andb) a rubber-rich graft polymerin which aqueous emulsions of a) and b) having polymer contents of 15 to 50% by weight are mixed continuously or semicontinuously in separate product streams, but at the same time, with a coagulation solution at a temperature of 50.degree. to 100.degree. C. with coagulation of polymers a) and b), the product streams are combined and the polymer mixture is separated off.Type: GrantFiled: April 10, 1989Date of Patent: August 13, 1991Assignee: Bayer AktiengesellschaftInventors: Karl-Erwin Piejko, Christian Lindner, Otto Koch
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Patent number: 5028663Abstract: This invention involves polyethylene blends prepared by a particular method to achieve a unique solid state processability. More specifically, the polyethylene blends of this invention are high density polyethylenes (HDPE) blended in solution with a minor fraction of branched low density polyethylene, linear low density polyethylene or other polyethylene copolymers with a melting point significantly lower than that of HDPE. The HDPE blends described herein possess a unique large scale deformation characteristics below the melting pointing of the major HDPE component, such that the HDPE blends are suitable for solid state processing such as stamping or forging, etc.Type: GrantFiled: February 22, 1990Date of Patent: July 2, 1991Inventor: Chan I. Chung
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Patent number: 5023300Abstract: A thermoplastic olefin comprising an alloy of an olefin copolymer elastomer and a propylene/comonomer random copolymer is provided. The comonomer is selected from one or more of ethylene and C.sub.4 to C.sub.10 alpha-olefins. Polypropylene is an optional component of the alloy. The alloy may be produced by melt blending, reactor blending or a combination thereof, of the various components.Type: GrantFiled: May 23, 1989Date of Patent: June 11, 1991Assignee: Exxon Chemical Patents Inc.Inventors: Terrence Huff, James J. McAlpin
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Patent number: 5013793Abstract: A dynamically vulcanized thermoplastic composition is provided which comprises a polymer blend of a thermoplastic olefinic resin, and an elastomeric halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a paraalkylstyrene. A process for preparing the dynamically vulcanized composition is also provided.Type: GrantFiled: July 26, 1990Date of Patent: May 7, 1991Assignee: Exxon Chemical Patents Inc.Inventors: Hsien C. Wang, Kenneth W. Powers, Robert C. Puydak, Narayanaswami R. Dharmarajan
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Patent number: 5013801Abstract: Polymer having a polymodal MWD ethylene copolymer are prepared by conducting the polymerization in a substantially mix free reactor using an essentially transfer agent free reaction mixture, the reaction being carried out in a manner such that the propagation of essentially all copolymer chains is initiated simultaneously. In carrying out the process of this invention, the catalyst components are premixed and aged prior to introduction into the reactor. The process is preferably carried out in a tubular reactor using VCl.sub.4 and aluminum sesquichloride as the catalyst system.Type: GrantFiled: August 2, 1988Date of Patent: May 7, 1991Inventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
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Patent number: 5006594Abstract: New blends of fluorinated thermoplastic elastomers are disclosed that contain a two-phase composition including a continuous phase of a melt processible crystalline thermoplastic fluorocarbon resin and a dispersed phase of an amorphous crosslinked fluoroelastomer, and a dispersion-process-produced, non-fibrillating, non-melt-processible polytetrafluoroethylene (PTFE) powder. The PTFE copolymer is made up of recurring units of hexafluoropropylene, perfluoro(alkyl vinyl ether) wherein the alkyl group has 1-4 carbon atoms, and mixtures thereof. The PTFE compounds uniformly with the two-phase composition without forming visible agglomerates. Poly(phenylene sulfide) powder can be added to the blend to increase melt flow characteristics. Additionally, an uncured fluoroelastomer can be incorporated into the blend to enhance its mechanical properties.Type: GrantFiled: December 6, 1989Date of Patent: April 9, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventor: Richard W. Rees
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Patent number: 5001194Abstract: A functionalized polymeric composition, said polymeric composition comprising a first phase and a second phase. The first phase comprises a first copolymer of a monovinylidene monomer and a comonomer selected to have at least one reactive epoxide functionality. The second phase is dispersed with the first phase. The second phase comprises a copolymer of an olefin monomer and one or more ethylenically unsaturated monomers copolymerizable with the olefin monomer wherein at least one of the ethylenically unsaturated monomers copolymerizable with the olefin monomer comprises a reactive functionality capable of reacting with one or more of the reactive epoxide functionalities of the first copolymer.Type: GrantFiled: July 7, 1989Date of Patent: March 19, 1991Assignee: The Dow Chemical CompanyInventor: David E. Henton
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Patent number: 4978716Abstract: Thermoplastic vulcanizates are prepared by curing, at least partially by dynamic vulcanization, blends of chlorinated polyethylene and crystalline thermoplastic polymers such as polypropylene. Inclusion of a plasticizing material or extender oil, e.g. trioctyl trimellitate, enhances softness and oil resistance of the blends. Vulcanizing materials include a basic material, normally added with the chlorinated polyethylene, and (1) a derivative of 2,5-dimercapto-1,3,4-thiadiazole or (2) a combination of 2,5-dimercapto-1,3,4-thiadizaole and an activator material such as an amine having a boiling point of 110.degree. C. or higher and a pk value less than 4.5.Type: GrantFiled: December 11, 1989Date of Patent: December 18, 1990Assignee: The Dow Chemical CompanyInventors: James H. Flynn, Oliver C. Ainsworth, Robert R. Blanchard
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Patent number: 4978703Abstract: A chlorinated polyethylene dispersed in a polyolefin, vulcanized and then the vulcanizate dispersed into a thermoplastic chlorinated polyethylene forming a partially crosslinked thermoplastic chlorinated polyethylene vulcanizate having good interply adhesion, hot weld strength, processable on commercially available equipment, and cracking resistance.Type: GrantFiled: January 4, 1990Date of Patent: December 18, 1990Assignee: The Dow Chemical CompanyInventors: Oliver C. Ainsworth, Ronald L. Glomski
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Patent number: 4978717Abstract: Thermoplastic compositions are prepared by blending an ethylene-hexene and/or an ethylene-butene copolymer resin, with a rubber and dynamically vulcanizing the rubber to form a heat-shrinkable dynamically vulcanized alloy of exceptionally low hardness, and great flexibility and elasticity. The preferred rubber is halogenated butyl rubber. Uncured rubber can be included in the composition.Type: GrantFiled: April 19, 1989Date of Patent: December 18, 1990Assignee: Exxon Chemical Patents Inc.Inventors: Donald R. Hazelton, Robert C. Puydak
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Patent number: 4973437Abstract: A method for inspecting the quality of modifiers for vinyl chloride type resins which includes kneading, with rolls, a soft vinyl chloride resin composition which is free of modifiers and is composed of a stabilizer, a plasticizer and a light shielding pigment to melt the composition and completely remove fish eyes present in the composition; adding a modifier for vinyl chloride type resins to the melted soft vinyl chloride resin composition; again kneading the mixture and then forming the mixture into a sheet to detect and count the number of fish eyes present in the sheet. This method makes it possible to simply and correctly determine the number of fish eyes of modifiers utilizing a widely used apparatus to thereby perform quality inspection of the modifiers. Moreover, when modifiers for vinyl chloride type resins are used in extrusion molding, the method is particularly effective for inspecting the quality of such modifiers.Type: GrantFiled: June 27, 1989Date of Patent: November 27, 1990Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Takezi Yanagisawa
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Patent number: 4946888Abstract: A high-hardness rubber composition which is obtained by vulcanizing an unvulcanized rubber composition comprisingan unvulcanized ethylene..alpha.-olefin rubber composition (A) comprising 100 parts by weight of an ethylene..alpha.-olefin copolymer rubber, 60-150 parts by weight of a reinforcing agent and 0-70 parts by weight of a softener;5-40 parts by weight of a solid diene rubber (B) based on 100 parts by weight of said ethylene..alpha.-olefin copolymer rubber; and4-15 parts by weight of sulfur (C) based on 100 parts by weight of said ethylene..alpha.-olefin copolymer rubber,wherein said unvulcanized rubber composition is obtained by adding said solid diene rubber (B) and said sulfur (C) to said unvulcanized ethylene..alpha.-olefin rubber composition (A).Type: GrantFiled: November 17, 1989Date of Patent: August 7, 1990Assignee: Sumitomo Chemical Company LimitedInventors: Keisaku Yamamoto, Yoshio Tanimoto, Isao Takano
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Patent number: 4945127Abstract: A heat-resistant formed product produced from a polymer composition comprising 40-70 weight % of a thermoplastic elastomer containing a repeating unit derived from ethylene and a repeating unit derived from propylene and 60-30 weight % of an ethylene-vinyl acetate copolymer containing 7.5 weight % or more of a vinyl acetate repeating unit, by blending the polymer composition at a temperature of 160.degree. C. or less, molding it at a temperature of 180.degree. C. or less, and then cross-linking the resulting molded product by irradiating electron beam or heating. The formed product also has good shape memory characteristics.Type: GrantFiled: December 23, 1988Date of Patent: July 31, 1990Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Seiji Kagawa, Hideaki Toda, Shinichiro Nomura
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Patent number: 4935164Abstract: Substantially monomer-free, electrically conductive organic polymers and/or organic conductors are dissolved or dispersed in a melt or solution of a thermoplastic matrix polymer or polymer mixture partially compatible therewith and having a solubility parameter >8.6 (cal/cm.sup.3).sup.1/2, in order to obtain mouldable polymer blends. The latter are suitable for producing moulded articles, particularly for electrical conductors, semiconductors or photoconductors. A suitable apparatus for producing the polymer blends comprises an extruder or kneader, through whose barrel one or more sonotrodes project into the transformation zone.Type: GrantFiled: June 13, 1985Date of Patent: June 19, 1990Assignee: Zipperling Kessler & Co. (GmbH & Co.)Inventors: Bernhard M. Wessling, Harald K. Volk
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Patent number: 4921625Abstract: A process for incorporating carboxy and/or carboxyl derivative functionality into a hydrocarbon polymer which is substantially free of ethylenic unsaturation. The functionalization is accomplished by contacting the functionalizing agent or agents with the polymer in the presence of a free radical initiator in a blending apparatus capable of imparting high mechanical energy into the reaction medium. The blending apparatus is preferably an extruder and most preferably a non-intermeshing twin screw extruder. The amount of degradation resulting from the presence of a free radical initiator and the high mechanical shear at the elevated temperatures employed during the contacting is reduced by effecting the contacting in a suitable diluent. Similarly, the amount of polymer crosslinking and/or coupling is reduced through the use of a suitable diluent. The polymer is maintained in the molten phase during the reaction.Type: GrantFiled: June 27, 1988Date of Patent: May 1, 1990Assignee: Shell Oil CompanyInventors: John E. Gorman, John A. Morris
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Patent number: 4921909Abstract: Emulsion polymerization type thermoplastic resin of high performance can be produced by the following methods: namely, a method which comprises removing an aqueous phase from a two-phase mixture comprising a latex of polymer (1) produced by emulsion polymerization, a water soluble agent (2) in an amount of 10% by weight or less of said polymer (1) which is capable of coagulating the latex of polymer (1) and an organic agent (3) in an amount of 0.1 to 6 times the weight of said polymer (1) which is capable of dissolving both an uncrosslinked polymer contained in said polymer (1) and thermoplastic polymer (4) mentioned hereinbelow and has a solubility in water of 5% by weight or less at 25.degree. C.Type: GrantFiled: December 24, 1986Date of Patent: May 1, 1990Assignee: Mitsubishi Rayon Company, Ltd.Inventors: Teruhiko Sugimori, Noriyuki Tajiri, Yutaro Fukuda
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Patent number: 4912148Abstract: Thermoplastic elastomer having excellent processability and physical properties is provided by the composition:(A) monoolefin copolymer rubber: 20 to 90 parts by weight(B) crystalline poly-alpha olefin resin: 5 to 70 parts by weight(C) mineral oil-type oil: 5 to 100 parts by weight with respect to (A) plus (B)(D) polyolefin-type wax: 5 to 60 parts by weight with respect to (A) plus (B)(E) butyl rubber: 0.1 to 10 parts by weight with respect to (A) plus (B)in the extruder and then are dynamically partial cross-linked together with a certain amount of organic peroxide, cross-linking aids and coupling agents in the extruder.Type: GrantFiled: July 15, 1988Date of Patent: March 27, 1990Assignee: Tong Yang Nylon Co., Ltd.Inventors: Jae K. Kim, Sung M. Lee, Young D. Kim
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Patent number: 4895906Abstract: The invention relates to a polychloroprene rubber which shows advantages over the prior art in the sum total of its performance properties, namely vulcanization rate, tensile strength, elongation at break, modulus, tear propagation resistance and thermal stability of the vulcanizate.Type: GrantFiled: July 19, 1988Date of Patent: January 23, 1990Assignee: Bayer AktiengesellschaftInventors: Peter Wendling, Werner Obrecht, Wilhelm Gobel, Rudiger Musch, Rudolf Casper, Eberhard Muller
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Patent number: 4894408Abstract: Heat shrinkable thermoplastic compositions are prepared by blending an ethylene copolymer resin with an EPDM rubber and dynamically vulcanizing the rubber. The ethylene copolymer resin is a copolymer of ethylene with an alkyl ester of an alpha, beta monoethylenically unsaturated monocarboxylic acid as well as copolymers of ethylene with the acid per se. The preferred copolymer is ethylene-vinylacetate copolymer. Uncured rubber can be included in the composition.Type: GrantFiled: August 23, 1988Date of Patent: January 16, 1990Assignee: Exxon Chemical Patents Inc.Inventors: Donald R. Hazelton, Robert C. Puydak
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Patent number: 4892911Abstract: This invention teaches using blends of polyisobutylene and polypropylene copolymer in the formation of single layer films and multiple layer sheet materials. The films and sheet materials are useful as flexible packaging materials. The multiple layer sheet materials may be entirely polymeric or may include layers having non-polymeric components, such as metal. The blends of polyisobutylene and polypropylene copolymer unexpectedly have the capability of being extruded through a slot die to form a film having a functionally useful mixture of its components. Thus the invention further includes methods of forming film-like layers of the blends of polyisobutylene and polypropylene copolymer.Type: GrantFiled: January 11, 1988Date of Patent: January 9, 1990Assignee: American National Can CompanyInventor: Roger P. Genske
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Patent number: 4886689Abstract: A novel adhesive is described, consisting of a matrix-matrix polyblend of polymer components useful in an adhesive tie layer to bond incompatible polymer layers. The adhesives are a blend of the components making up the incompatible polymer layers themselves, or polymers substantially similar to these, and are melt processed to produce a matrix-matrix morphology with mechanical interlocking of the polymer components that is maintained upon cooling. Additives may be provided in one or both adhesive components to improve the cohesive strength of the adhesive formed by the mechanical interlocking.Type: GrantFiled: May 19, 1988Date of Patent: December 12, 1989Assignee: Ausimont, U.S.A., Inc.Inventors: Abraham M. Kotliar, William Sacks, John P. Sibilia, Rakesh Kumar
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Patent number: 4877839Abstract: Composition, optionally curable, comprising a fluorocopolymer admixed with an acrylic polymer, where the fluoropolymer comprises units of a fluorolefine (e.g. TFE) and fluoroallylether (e.g. tetrafluororallylether).Type: GrantFiled: June 8, 1988Date of Patent: October 31, 1989Assignee: Imperial Chemical Industries PLCInventors: John N. Conti-Ramsden, Richard L. Powell, Brian D. Young, Jeffrey Farrar, Debra K. Brown
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Patent number: 4877821Abstract: An improved stabilizer concentrate for use in stabilizing polymeric blend compositions which comprise a thermally sensitive interpolymer. The stabilizer concentrate comprises a carrier resin, and a stabilizing agent capable of stabilizing a thermally sensitive interpolymer. The improvement comprises employing a carrier resin having a viscosity such that the stabilizer concentrate has a viscosity of less than 60 percent of the viscosity of the polymeric blend composition.Type: GrantFiled: February 11, 1988Date of Patent: October 31, 1989Assignee: The Dow Chemical CompanyInventors: Mark J. Hall, Joseph R. Powers, William A. Wood
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Patent number: 4874820Abstract: The present invention relates to polymeric composition of a first copolymer which includes at least one copolymer having at least one of Mw/Mn less than 2 and Mz/Mw less than 1.8; and a second copolymer having Mw/Mn greater than or equal to 2. The composition can be produced by preparing the first and second copolymers in different reactors and blending them. The blend can also be produced in a single reactor by initiating the reaction to prepare one copolymer, and adding additional reactants, or recycling the reaction mixture, during the reaction to produce the other copolymer.Type: GrantFiled: December 27, 1985Date of Patent: October 17, 1989Assignee: Exxon Research and Engineering CompanyInventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
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Patent number: 4873288Abstract: A two-step process for production of thermoplastic elastomer, which comprises dynamically vulcanizing polypropylene and olefinic rubber in the presence of peroxide (1st step), and dynamically vulcanizing the vulcanized mixture, polypropylene and halogenated butyl rubber in the presence of zinc oxide (2nd step). In another method (a) polyolefin and olefin rubber are dynamically cross-linked in the presence of an organic peroxide and (b) in a separate second operation a dynamically vulcanized blend comprising polyolefin and halogenated butyl rubber is prepared and mixed with (a) to disperse (a) and (b) in one another. The thermoplastic elastomer composition is useful in materials for parts of automobiles.In an example, pp 9 wt. % parts, EPDM 21 wt. % parts, peroxide 0.3 wt. % part and divinylbenzene 0.5 wt. % part were blended and supplied to the first hopper (1) of biaxial extruder as shown in a figure. In the first blending zone (2), temperature and residence time are 200.degree. C.Type: GrantFiled: October 4, 1988Date of Patent: October 10, 1989Assignee: Toa Nenryo Kogyo K.K.Inventors: Masato Komatsu, Isao Baba, Takashi Mikami, Kiyotada Narukawa, Tsuyoshi Kanai
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Patent number: 4861834Abstract: The compositions contain:(a) from 90 to 99.8% by weight of at least one modified polymer of ethylene and, where appropriate, at least one .alpha.-olefin having from 3 to 12 carbon atoms, the said polymer containing at least 80 mol % of units derived from ethylene, and(b) from 0.2 to 10% by weight of at least one polymer phase (B) comprising at least one polymer containing at least 90 mol % of units derived from at least one .alpha.-olefin having from 3 to 12 carbon atoms, and at most 10 mol % of units derived from ethylene,the said compositions having a measured limiting viscosity of between 1.5 and 100 times their limiting viscosity calculated from the distribution of the molecular masses.The process for preparing them consists in modifying a polymer (A) containing at least 80 mol % of units derived from ethylene and at most 20 mol % of units derived from at least one .alpha.Type: GrantFiled: October 6, 1987Date of Patent: August 29, 1989Assignee: Societe Chimique des Charbonnages S.A.Inventors: Joel Audureau, Edouard Piecuch
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Patent number: H1077Abstract: The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 1,000 cps; forming an interpolymer complex of neutralized sulfonated polymer (water insoluble) and copolymer of styrene/vinylpyridine in the solvent system to form a solution, a concentration of the water insoluble interpolymer complex polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and interpolymer complex transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken).Type: GrantFiled: May 21, 1990Date of Patent: July 7, 1992Inventors: Dennis G. Peiffer, Robert D. Lundberg, Ilan Duvdevani