Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
  • Patent number: 8883884
    Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a polymer blend comprising a copolymer and an additional polymer, the copolymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer immiscible with the backbone; the additional polymer consisting of a polymer miscible with the polymeric sidechains.
    Type: Grant
    Filed: November 27, 2012
    Date of Patent: November 11, 2014
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Liqing Ma, Robert Fokko Roskamp, Ralf Mruk, Frank James Feher, Bruce Raymond Hahn
  • Patent number: 8883918
    Abstract: The present invention relates to a process for recycling product streams that have been separated from a hydrocarbon-containing feed stream comprising olefin monomer, olefin co-monomer, hydrocarbon diluent and components such as H2, N2, O2, CO, CO2, and formaldehyde. In accordance with the present process a hydrocarbon-containing feed stream is separated into a) a first side stream comprising hydrocarbon diluent and olefin monomer; b) a second side stream which is substantially hydrogen-free and comprises hydrocarbon diluent and olefin monomer, c) a bottom stream comprising substantially olefin-free hydrocarbon diluent, and d) an overhead vapor stream comprising olefin monomer, hydrocarbon diluent and components such as formaldehyde, H2, N2, O2, CO and CO2. The present process further includes recycling said first and said second side streams in a polymerization process for preparing bimodal polyolefin.
    Type: Grant
    Filed: September 10, 2010
    Date of Patent: November 11, 2014
    Assignee: Total Research & Technology Feluy
    Inventors: Denis Mignon, David Vandewiele, Bernard Van De Schrick, Camille Vercruysse
  • Patent number: 8877856
    Abstract: Provided is an adhesive resin composition having improved heat resistance without deteriorations in adhesive strength and flexibility. The adhesive resin composition comprises 30 to 98 wt % of an ethylene/vinyl acetate copolymer (a) and 70 to 2 wt % of a propylene resin composition (P), wherein the total of the component (a) and the component (P) is 100 wt %. The propylene resin composition (P) comprises 60 to 0 wt % of a propylene polymer (b) having a melting point of 120 to 170° C. and a melt flow rate of 0.1 to 500 g/10 min, and 40 to 100 wt % of a propylene polymer (c) having a melting point of less than 120° C. or showing no melting points and having a melt flow rate of 0.1 to 500 g/10 min, wherein the total of the component (b) and the component (c) is 100 wt %.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: November 4, 2014
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroto Yasui, Koji Matsunaga
  • Patent number: 8877305
    Abstract: High temperature performance hot melt adhesives are formulated for application at low temperature, i.e., below 300° F. Hot melt adhesive formed with metallocene polymer together with a maleated polyethylene wax show an excellent balance of high and low temperature performance and are particularly useful as packaging case and carton adhesive.
    Type: Grant
    Filed: January 30, 2012
    Date of Patent: November 4, 2014
    Assignee: Henkel US IP LLC
    Inventors: Jagruti B. Patel, Andrea Keys Eodice, Yew Guan Low
  • Patent number: 8877867
    Abstract: A process for preparing modified thermoplastic vulcanizate compositions, the process comprising the steps of introducing molten thermoplastic vulcanizate and a free-radical source, where the thermoplastic vulcanizate includes cured rubber dispersed within a thermoplastic matrix.
    Type: Grant
    Filed: October 15, 2009
    Date of Patent: November 4, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Hari P. Nadella, Jianya Cheng
  • Patent number: 8871868
    Abstract: Propylene impact copolymers (ICPs) are provided which comprise: (a) a matrix phase which comprises from 60 to 95 weight % of a polypropylene polymer containing from 0 to 6 mole % of units derived from one or more alpha-olefins other than propylene, and (b) a dispersed phase which comprises from 5 to 40 weight % of a copolymer derived from a first comonomer which can be either propylene or ethylene together with a second alpha-olefin comonomer. The ICP is further characterized by having a beta/alpha ratio less than or equal to 1.1. The ICPs of the present invention are particularly well suited for applications requiring clear, tough polymers such as thin walled injection molded articles for frozen food packaging applications.
    Type: Grant
    Filed: January 9, 2013
    Date of Patent: October 28, 2014
    Assignee: Braskem America, Inc.
    Inventors: Peter S. Dias, Jonathan D. Kersey, Peter S. Martin, Thomas R. Cuthbert
  • Patent number: 8871825
    Abstract: There is provided a polypropylene resin composition comprising a propylene polymer (A) containing 0 to 70% by mass of a propylene homopolymer (A-1) and 30 to 100% by mass of a propylene-ethylene block copolymer (A-2) defined below, an ethylene-?-olefin copolymer (B) defined below, and an inorganic filler (C), wherein the proportion of the amount of the (A), the proportion of the amount of (B), and the proportion of the amount of (C) relative to the total amount of the (A), the (B) and the (C) are 40 to 94% by mass, 5 to 30% by mass, and 1 to 30% by mass, respectively, the propylene-ethylene block copolymer (A-2) is a mixture of a propylene homopolymer component and a propylene-ethylene random copolymer component, wherein the intrinsic viscosity, as measured in Tetralin of 135° C., of the propylene-ethylene random copolymer component is within the range of 2.0 to 8.
    Type: Grant
    Filed: October 30, 2008
    Date of Patent: October 28, 2014
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyoshi Nakajima, Yoshitaka Kobayashi, Takashi Fujimoto
  • Publication number: 20140316070
    Abstract: Propylene copolymer having a melt flow rate MFR2 (230° C.) in the range of 2.5 to 12.0 g/10 min, a xylene cold soluble content (XCS) in the range of 20.0 to 45.0 wt.-%, a comonomer content in the range of more than 7.5 to 12.0 wt.-%, wherein further the comonomer content of xylene cold soluble (XCS) fraction of the propylene copolymer is in the range of 16.0 to 28.0 wt.-%.
    Type: Application
    Filed: December 18, 2012
    Publication date: October 23, 2014
    Applicant: BOREALIS AG
    Inventors: Martina Sandholzer, Klaus Bernreitner, Katja Klimke, Markus Gahleitner
  • Publication number: 20140315035
    Abstract: A hot melt adhesive material and articles made using the hot melt adhesive to assemble structures in an article. The adhesive material typically is manufactured by blending amorphous polymer with a heterophase polymer having crystallinity into an adhesive composition.
    Type: Application
    Filed: January 31, 2014
    Publication date: October 23, 2014
    Applicant: IFS INDUSTRIES INC.
    Inventor: William L. Bunnelle
  • Publication number: 20140316069
    Abstract: A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene (co)polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process comprising: (i) a first step of polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins, to produce a propylene (co)polymer being for at least 85% by weight insoluble in xylene at 25° C.
    Type: Application
    Filed: November 7, 2012
    Publication date: October 23, 2014
    Applicant: Basell Polilefine Italia S.r.l.
    Inventors: Monica Galvan, Roberto Pantaleoni, Ofelia Fusco, Benedetta Gaddi, Andreas Neumann, Antonio Mazzucco, Gianni Collina, Marco Ciarafoni
  • Patent number: 8865838
    Abstract: Provided are methods for producing a thermoplastic vulcanizate. One method includes charging vulcanizable rubber to a reactor; charging a masterbatch of thermoplastic resin and a catalyst for a phenolic resin curative to the reactor; charging a phenolic resin curative to the reactor; and dynamically vulcanizing the rubber with the phenolic resin curative in the presence of the catalyst. Also provided are thermoplastic vulcanizates made by the methods of the invention.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: October 21, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Stephen F. Roche, Randal H. Kerstetter
  • Patent number: 8865846
    Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.
    Type: Grant
    Filed: September 25, 2012
    Date of Patent: October 21, 2014
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Errun Ding, Qing Yang, Youlu Yu, Lloyd W. Guatney, Jim B. Askew
  • Patent number: 8865824
    Abstract: A hot melt adhesive material and articles made using the hot melt adhesive to assemble structures in an article. The adhesive material typically is manufactured by blending amorphous polymer with a heterophase polymer having crystallinity into an adhesive composition.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: October 21, 2014
    Assignee: IFS Industries Inc.
    Inventor: William L. Bunnelle
  • Patent number: 8865834
    Abstract: A novel adhesive composition suitable for composing multilayered coatings onto large, industrial equipment such as pipeline tubes is devised. The composition is a blend based on a polyethylene which determines the blend's favorable properties, which polyethylene itself can be used further in coating cables and for producing moldings, especially rotomoulded articles.
    Type: Grant
    Filed: February 18, 2009
    Date of Patent: October 21, 2014
    Assignee: Basell Polyolefine GmbH
    Inventors: Heinz Vogt, Shahram Mihan, Gerd Mannebach, Gerhardus Meier, Joachim Berthold, Manfred Hecker
  • Publication number: 20140308502
    Abstract: The present invention is directed to a modified polypropylene comprising from 0.3 to 2 long-chain branches per 1,000 carbon atoms, wherein said long-chain branch has more than 1,000 carbon atoms and 0 to 6% of ethene and/or alpha-olefinic comonomer having 3 to 18 carbon atoms. The polypropylene of the present invention is a homopolymer, a random copolymer, or a heterophasic copolymer. The present invention also relates to large, deep, complex and/or thick articles which are thermoformed from said polypropylene. Furthermore, the present invention relates to the process for thermoforming said modified polypropylene into large, deep, complex and/or thick articles. The present invention also relates to the use of the polypropylene to prepare large, deep, complex and/or thick articles.
    Type: Application
    Filed: October 11, 2011
    Publication date: October 16, 2014
    Applicant: BRASKEM S.A.
    Inventors: Marcelo Farah, Fernando Cruz, Alessandro Cauduro Lima, Alexandre di Pintor da Luz, Etienne Marcos de Almeida Rocha, Ana Paula de Azeredo, Claudio Jose Autran Neves, Fabio Lamon Sofri
  • Publication number: 20140308466
    Abstract: The invention provides a resin composition for a sealant capable of improving non-adsorption properties and heat sealing properties with respect to an organic component in an article contained, a laminated film and a packaging bag. The resin composition for a sealant of the invention is made of a resin obtained by blending a cycloolefin polymer (COP), a cycloolefin copolymer (COC) and polyethylene (PE), and the blending ratio is 42 weight % to 98 weight % of the cycloolefin polymer (COP), 1 weight % to 49 weight % of the cycloolefin copolymer (COC) and 1 weight % to 19 weight % of the polyethylene (PE).
    Type: Application
    Filed: December 11, 2012
    Publication date: October 16, 2014
    Inventors: Kousuke Kashima, Hajime Okamoto, Masakazu Inada, Mihoko Yoshida
  • Patent number: 8859066
    Abstract: A coating composition, a process for producing it and substrate coated therewith are described. The composition comprises a multimodal ethylene polymer, which contains from 80 to 99.8% by weight of ethylene repeating units and from 0.2 to 20% by weight of C3-C20 ?-olefin repeating units, and is a blend of at least a first and a second ethylene polymer prepared by polymerization in the presence of a single site catalyst system. The blend has a density of 0.915-0.955 g/cm3, a melt flow rate, MFR2, of 0.028-1.5 g/10 min., a molecular weight distribution, Mw/Mn, of 3-10, and a CTL 5.0 MPa-value according to ISO 6259 of at least 500 hrs.
    Type: Grant
    Filed: January 28, 2004
    Date of Patent: October 14, 2014
    Assignee: Borealis Technology Oy
    Inventors: Solveig Johansson, Christer Lind, Cecilia Rydin
  • Publication number: 20140299188
    Abstract: A solar cell panel end-sealing composition contains a butyl rubber, a polyolefin resin having a silyl group, and a catalyst. The catalyst is at least one of a metal oxide, a metal hydroxide, and a metal complex of a transition element and the solar cell panel end-sealing composition has a flow viscosity at 140° C. of 500 Pa·s or more and 8000 Pa·s or less.
    Type: Application
    Filed: April 2, 2014
    Publication date: October 9, 2014
    Applicant: NITTO DENKO CORPORATION
    Inventors: Youhei HAYASHI, Akihiro KIRIYAMA, Kazumasa ASANO, Shinichiro KOSE, Masato SHIRAI, Toru ISEKI
  • Publication number: 20140303309
    Abstract: A high pressure polymerization process to form an ethylene-based polymer comprises the steps of: A. Injecting a first feed comprising ethylene and optionally a chain transfer agent system (CTA system) into a first autoclave reactor zone operating at polymerization conditions to produce a first zone reaction product, the CTA system of the first reactor zone having a transfer activity Z1; and B. (1) Transferring at least part of the first zone reaction product to a second reactor zone selected from a second autoclave reactor zone or a tubular reactor zone and operating at polymerization conditions, and, optionally, (2) freshly injecting a second feed into the second reactor zone to produce a second zone reaction product, with the proviso that the second reactor zone contains a CTA system having a transfer activity Z2; and with the proviso that the ratio of Z1/Z2 is less than 1.
    Type: Application
    Filed: April 28, 2014
    Publication date: October 9, 2014
    Applicant: Dow Global Technologies LLC
    Inventors: Otto J. Berbee, Cornelis Den Doelder, Egbert Nijhof, Mehmet Demirors, Sjoerd A. De Vries
  • Publication number: 20140303325
    Abstract: Composition comprising a polypropylene matrix (M-PP), at least one elastomeric copolymer (EP), a high density polyethylene (HDPE) being bimodal or multimodal, and a filler (F).
    Type: Application
    Filed: June 18, 2014
    Publication date: October 9, 2014
    Inventors: Klaus Bernreitner, Claudia Kniesel, Robert Gubo, Klaus Maureder
  • Publication number: 20140303308
    Abstract: The present invention relates to a polyolefin composition comprising a heterophasic propylene copolymer having a MFR2 of at least 5 g/10 min and a polyethylene (PE) having a density of at least 935 kg/m3 and a melt flow rate MFR5 (190° C.) of less than 1.5 g/10 min.
    Type: Application
    Filed: August 14, 2012
    Publication date: October 9, 2014
    Inventors: Georg Grestenberger, Christelle Grein, Cornelia Kock
  • Patent number: 8853326
    Abstract: An RF-weldable thermoplastic elastomer composition, including a thermoplastic elastomer of non-RF-weldable or poorly RF-weldable character, e.g., a styrenic copolymer/olefinic polymer blend thermoplastic elastomer, and polyol in an amount that is less than 1% by weight, based on weight of the thermoplastic elastomer, and is effective to enhance RF-weldability of the thermoplastic elastomer. The composition may also contain an antistatic ionomer, in an amount that is less than 15% by weight, based on weight of the thermoplastic elastomer. Films of such composition are usefully employed to form RF-welded film articles, such as blood bags, IV fluid bags, glucose bags, urine bags, stool bags, biological sample bags, pouches, covers, and liners.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: October 7, 2014
    Assignee: Polyzen Inc.
    Inventors: Tilak M. Shah, Kimberly Ogburn, Christopher D. Strom
  • Patent number: 8853329
    Abstract: The present invention relates to an adhesive, comprising at least one polymer system obtained by a process for reducing the melt viscosity of at least one polymer blend starting material, wherein the process comprises the step of treating at least one polymer blend with at least one radical donor under shear stress at a temperature above the softening point of said polymer blend.
    Type: Grant
    Filed: September 26, 2011
    Date of Patent: October 7, 2014
    Assignees: Henkel AG & Co. KGAA, Henkel US IP LLC
    Inventors: Dirk Kasper, Thomas Möller, Gunter Hoffmann, Knut Hoffmann, Andy Swain, Claudia Yaacoub, Maria Cristina Barbosa Dejesus
  • Patent number: 8852748
    Abstract: A polymeric resin having a density of greater than about 0.960 g/cc, a melt index of from about 1.3 g/10 min. to about 2.8 g/10 min., a zero shear viscosity of from about 1×104 Pa*s to about 1×105 Pa*s, a recoverable shear parameter of from about 220 to about 370, and a CY-a parameter of from about 0.155 to about 0.200. A polymeric resin having an initial tension defined by the equation IT??1.67*(MI)+b where b is 5.17 and a percent decrease in the extrusion pressure of the resin of about 30% when compared to polymer resin of similar melt index prepared with a catalyst that has not undergone an activation comprising an oxidation, reduction, oxidation sequence wherein the resin when formed into a film has a moisture vapor transmission rate of from about 0.21 g.mil/100 in2/day to about 0.33 g.mil/100 in2/day.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: October 7, 2014
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Ashish M. Sukhadia, Max P. McDaniel, Ted Cymbaluk, Rajendra K. Krishnaswamy, Lawrence Szmutko
  • Patent number: 8846815
    Abstract: A thermoplastic vulcanizate comprising a dynamically cured rubber, where the rubber is peroxide cured, and a thermoplastic phase, where at least 10% by weight of the thermoplastic phase includes an ultrahigh molecular weight plastic, where the ultrahigh molecular weight plastic is characterized by a Mw that is greater than 0.8×106 g/mole.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: September 30, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria Dolores Ellul, Eugene Ronald Uhl, Patrick Brant, Jeffrey Lawrence Brinen, Zerong Lin
  • Patent number: 8846814
    Abstract: The present invention relates to the use of polyolefins having isotactic structural elements in floor coverings, in particular in carpets or artificial lawns.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: September 30, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Hinnerk Gordon Becker, Marlies Vey, Lutz Mindach
  • Patent number: 8846774
    Abstract: The present invention relates to a resin composition for a polyolefin resin foam, including: a polyolefin (A) having a melt flow rate (MFR) at a temperature of 230° C. of 0.2 to 0.7 g/10 min and a melt tension at break measured at a temperature of 190° C. of 30 cN or more; and a polyolefin (B) having a melt flow rate (MFR) at a temperature of 230° C. of 1.5 to 10 g/10 min and a melt tension at break measured at a temperature of 190° C. of 10 cN or more, in which the polyolefin (B) is contained in an amount of from 15 to 75 parts by weight based on 100 parts by weight of the polyolefin (A).
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: September 30, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Naomi Jintoku, Itsuhiro Hatanaka, Tetsurou Kobayashi
  • Publication number: 20140288228
    Abstract: The present invention relates to polypropylene compositions with a balance of high strength, good clarity, excellent stress whitening resistance, and excellent impact properties—especially at low temperatures—for use in demanding plastics applications. Blends consist of both homopolymer and random copolymer polypropylene fractions, as well as propylene-ethylene elastomers and styrenic based elastomers. The invention also covers molded articles made from these blends.
    Type: Application
    Filed: March 18, 2014
    Publication date: September 25, 2014
    Applicant: Asahi Kasei Plastics North America, Inc.
    Inventors: Sameer G. MEHTA, Michael James BALOW, Vaibhav Vishnu APTE, Laura Therese Shereda
  • Patent number: 8841390
    Abstract: Method for the preparation of a sticky high impact heterophasic polypropylene (HECO) in a reactor facility comprising in series (i) a first reaction system, (ii) a first conveying line connecting the first reactor system with a second reactor system comprising an outlet, (iii) a second conveying line connecting the outlet with a purge bin comprising a feeder, and (iv) a conveying system being connected with the feeder, and the preparation of said heterophasic polypropylene (HECO) comprises the steps in the order of (a) producing in said first reactor system the polypropylene matrix (M), (b) transferring at least a part of said polypropylene to said second reactor system via the first conveying line, (c) producing in said second reactor system the elastomeric copolymer obtaining the heterophasic polypropylene (HECO), (d) discharging said heterophasic polypropylene (HECO) from said second reactor system via the outlet, (e) transferring said discharged heterophasic polypropylene (HECO) via the second conveying l
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: September 23, 2014
    Assignee: Borealis AG
    Inventors: Pauli Leskinen, Olli Tuominen, Veli-Matti Keinänen
  • Patent number: 8841383
    Abstract: Disclosed is an ethylene-propylene-diene terpolymer having isotactic polypropylene crystallinity compounded with a blend rubber wherein the terpolymer can be present in an amount effective to improve tack, aged tensile strength retention, fatigue resistance, ozone cracking resistance, and reversion resistance. Also disclosed is an elastomer composition wherein the terpolymer can have at least 60 wt % propylene-derived units, at least 6 wt % ethylene-derived units and from 0.3 to 10 wt % diene-derived units, and a tire sidewall composition comprising from 10 to 30 phr terpolymer, from 20 to 60 phr natural rubber, from 20 to 60 phr polybutadiene rubber, and an optional secondary blend rubber. Also disclosed is a vulcanizate of the elastomer composition, and articles, tire sidewalls, tires, retreaded tires, bias truck tires, off-road tires, and passenger automobile tires made with the vulcanizate. Further disclosed are processes for making molded articles and tires, and for retreading tires.
    Type: Grant
    Filed: November 2, 2007
    Date of Patent: September 23, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Michael B. Rodgers, Sunny Jacob, Michael C. Bulawa, Bharat B. Sharma, Nitin K. Tambe
  • Publication number: 20140275427
    Abstract: The present invention relates to a low density polyethylene having a molecular weight distribution Mw/Mn which is greater than 15, a storage modulus G? (5 kPa) which is above 3000 and a vinylidene content which is at least 15/100k C, compositions, a process for production of the low density polyethylene, a continuous ethylene polymerization method for introducing vinylidene in a low density polyethylene, a method for an extrusion coating process, an article, e.g. an extrusion article, and use in extrusion coating.
    Type: Application
    Filed: December 7, 2012
    Publication date: September 18, 2014
    Applicant: BOREALIS AG
    Inventors: Auli Nummila-Pakarinen, Bernt-Ake Sultan, Bjorn Voigt, Martin Anker, Mattias Bergqvist, Thomas Gkourmpis, Thomas Hjertberg
  • Publication number: 20140275426
    Abstract: A polymer suitable for use in a thin film hinge (living hinge) comprising from about 0.1 to about 5 weight % of a C4-8 comonomer and the balance ethylene, said composition having a density as determined according to ASTM D 792 from about 0.945 to about 0.965 g/cm3; a melt index as determined according to ASTM D1238 (2.16 kg/190° C.) from about 10 to about 20 g/10 min; a weight average molecular weight (Mw) from about 45,000 to about 55,000 g/mol; a polydispersity from about 2.5 to about 3.1 and when molded into a strip having a length of about 13 cm and gross thickness from about 50 to about 70 mil (about 1 to about 2 mm) and completely bent over end to end four times to create a thinned region or crease having a thickness from about 15 to about 30 mil (about 0.3 to about 0.7 mm) tested by bending and releasing the deformed thinned region of the strip through a radius of curvature from about 180 to about 190° about a rounded plate goes through not less than 500 cycles without breaking.
    Type: Application
    Filed: March 12, 2014
    Publication date: September 18, 2014
    Applicant: NOVA Chemicals (International) S.A.
    Inventors: Jason Michael Rycroft, Gilbert Alexander Arnould, Matthew Zaki Botros, Mark Rejman
  • Patent number: 8835568
    Abstract: A propylene polymer composition comprising (percent by weight): A) 65%-85% of a propylene copolymer containing from 2.0% to 5.0% of ethylene derived units having MFR L (Melt Flow Rate according to ASTM 1238, condition L, i.e. 230° C. and 2.16 kg load) from 0.5 to 50 g/10 min and a melting temperature Tm ranging from 146° C. to 155° C.; B) 15%-35%, of a copolymer of ethylene and propylene with from 74% to 87%, of ethylene derived units; the composition having the intrinsic viscosity of the fraction soluble in xylene ranging from 0.8 to 1.2 dl/g preferably from 0.9 to 1.1 dl/g.
    Type: Grant
    Filed: April 6, 2011
    Date of Patent: September 16, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Marco Ciarafoni, Paola Massari, Claudio Cavalieri, Tiziana Caputo
  • Patent number: 8835567
    Abstract: The instant invention is a sealant composition, method of producing the same, articles made therefrom, and method for forming such articles. The sealant composition according to the present invention comprises: (a) from 70 to 99.5 percent by weight of an ethylene/?-olefin interpolymer composition, based on the total weight of the sealant composition, wherein said ethylene/?-olefin interpolymer composition comprises an ethylene/?-olefin interpolymer, wherein ethylene/?-olefin interpolymer has a Comonomer Distribution Constant (CDC) in the range of from 15 to 250, and a density in the range of from 0.875 to 0.963 g/cm3, a melt index (I2) in a range of from 0.2 to 20 g/10 minutes, and long chain branching frequency in the range of from 0.02 to 3 long chain branches (LCB) per 1000 C; (b) from 0.
    Type: Grant
    Filed: October 26, 2011
    Date of Patent: September 16, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Mehmet Demirors, Rongjuan Cong, Cristina Serrat, Gagan Saini, Michael Rutkowske
  • Patent number: 8834977
    Abstract: A bag in box packaging comprising an outer carton having a plurality of sides, thereby defining a cavity, and an inner bag having a wall structure comprising a plurality of layers of a co-extrusion. The inner bag being formed from at least one film having a plurality of seals to define a fluid tight configuration, the inner bag co-extrusion having a plurality of layers with a tie layer having at least 0.5% maleic anhydride-grafted polyethylene. Films made through an orientation process for bag in box packaging is likewise disclosed, as are manufacturing processes.
    Type: Grant
    Filed: October 22, 2012
    Date of Patent: September 16, 2014
    Assignee: Scholle Corporation
    Inventors: David Bellmore, Karen Berger, Gail Becke
  • Patent number: 8835569
    Abstract: A reactor blend polyethylene composition comprising: from 35 to 70 percent by weight of a first polyethylene component; and a second polyethylene component; wherein the polyethylene resin has a melt index I2 of less than 1 dg/min and greater than or equal to 0.25 dg/min and exhibits a V0.1/V100 of greater than or equal to 9; and wherein the first and second polyethylene components are produced in continuous dual solution polymerization reactors, wherein the second polyethylene component is produced in the presence of the first polyethylene component and wherein a Ziegler-Natta catalyst is present in each of the first and second polymerization reactors is provided. Also provided are methods for producing the polyethylene resin and films made therefrom.
    Type: Grant
    Filed: June 8, 2012
    Date of Patent: September 16, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Lawrence J. Effler, Cornelis F. J. den Doelder, Mehmet Demirors, Jian Wang
  • Publication number: 20140256883
    Abstract: The instant invention is a high-density polyethylene composition, method of producing the same, articles made therefrom, and method of making such articles. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21.6) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g? of 1.
    Type: Application
    Filed: March 12, 2014
    Publication date: September 11, 2014
    Applicant: Dow Global Technologies LLC
    Inventors: William J. Michie, JR., Thomas W. Kay, Stephanie M. Whited, Dale M. Elley-Bristow, David T. Gillespie, Lonnie G. Hazlitt
  • Patent number: 8829106
    Abstract: Thermoplastic compositions including component C, an ethylene/?-olefin interpolymer wherein the interpolymer has a Mooney Viscosity (ML 1+4, 125° C.) greater than, or equal to 55 and a ?Hf greater than, or equal to 36 J/g; and component D, a high density polyethylene (HDPE) are provided. In particular, the thermoplastic compositions are characterized by the ethylene/?-olefin interpolymer which is an ethylene/a-olefin/diene interpolymer having a rheology ratio (V0.1/V 100) at 190° C. greater than, or equal to 25. Also are provided the articles comprising the thermoplastic compositions.
    Type: Grant
    Filed: November 9, 2010
    Date of Patent: September 9, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Laura B. Weaver, Ashish Batra, Kim L. Walton
  • Patent number: 8829115
    Abstract: An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions are useful for making many articles, especially including films. The polymers are made using a metal complex of a polyvalent aryloxyether.
    Type: Grant
    Filed: March 2, 2011
    Date of Patent: September 9, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Theresa J. Hermel-Davidock, Mehmet Demirors, Sarah M. Hayne, Rongjuan Cong, Lori L. Kardos, Teresa P. Karjala
  • Patent number: 8829113
    Abstract: Automotive interior element comprising a polypropylene composition comprising (percent by weight): A) from 60% to 90% of a propylene homopolymer having: i) a polydispersity Index (P.I.) value of from 3.5 to 10.0; ii) a fraction insoluble in xylene at 25° C., higher than 90%; and iii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 50 to 200 g/10 min; B) from 10% to 40%; of a copolymer of propylene with from 30% to 60% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.5 and 4.0 dl/g; a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 15 to 100 g/10 min and all the three values of carbon emission measured according to VDA 227 (C-emission) are lower than 30.0 ?gC/g; wherein the values of carbon emission are measured in the ex reactor propylene composition.
    Type: Grant
    Filed: October 12, 2011
    Date of Patent: September 9, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Benedetta Gaddi, Marco Ciarafoni, Mara Destro, Ofelia Fusco, Paola Massari, Ines Mingozzi
  • Publication number: 20140248488
    Abstract: [Object] To provide a resin composition with excellent mold releasability and blocking resistance. [Solution] A resin composition containing a 4-methyl-1-pentene polymer includes 0.01 to 10 parts by mass of a 4-methyl-1-pentene polymer (B) per 100 parts by mass of at least one resin (A) selected from the group consisting of thermoplastic resins and thermosetting resins, wherein the 4-methyl-1-pentene polymer (B) has (B1) an intrinsic viscosity [?] of 0.01 or more but less than 0.50 dl/g measured at 135° C. in a decalin solvent.
    Type: Application
    Filed: May 9, 2014
    Publication date: September 4, 2014
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Kuniaki KAWABE, Masayoshi Sutou, Toshiyuki Itou, Mai Kurihara, Akinori Etoh, Shinichirou Asao, Kenji Sugimura, Hiroshi Hoya, Koji Matsunaga, Yoji Hayakawa, Kunihiko Mizumoto
  • Publication number: 20140249264
    Abstract: Heterophasic propylene copolymers can include a matrix phase and a dispersed phase. The heterophasic propylene copolymers can be characterized by good processability and good mechanical properties, particularly an improved rigidity. The heterophasic propylene copolymers can be well-suited for injection molding applications, particularly for injection molding of thin-walled articles.
    Type: Application
    Filed: October 2, 2012
    Publication date: September 4, 2014
    Inventors: Isabelle Ydens, Geoffroy Terlinden, Alain Standaert, David Ribour
  • Patent number: 8822601
    Abstract: The invention provides an ethylene-based polymer comprising the following properties: A) a MWDconv from 7 to 10; and B) a “normalized LSF” greater than, or equal to, 9.5.
    Type: Grant
    Filed: December 2, 2011
    Date of Patent: September 2, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Teresa P. Karjala, Lori L. Kardos, Wallace W. Yau, Jose Ortega
  • Patent number: 8821995
    Abstract: Fibers, tapes, monofilaments including copolymers of ethylene and ?-olefins which exhibit improved tensile properties expressed as a balance between tenacity and elongation at break. The copolymers may be prepared by use of metallocene catalyst systems in particular by use of monocyclopenadienyl catalyst systems. The fibers, tapes, monofilaments of the invention are particularly suitable for end-use applications including artificial grass, woven and nonwoven fabrics, cordages, ropes, netting and flexible intermediate bulk containers.
    Type: Grant
    Filed: February 12, 2009
    Date of Patent: September 2, 2014
    Assignee: INEOS Manufacturing Belgium NV
    Inventors: Choon Chai, Dominique Jan, Stefan Spitzmesser
  • Patent number: 8822602
    Abstract: Heterophasic propylene copolymer (HECO) comprising: (a) a polypropylene matrix comprising: (a1) a first propylene homopolymer fraction (PPH1) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >200 to 500 g/10 min, (a2-1) a second propylene homopolymer fraction (PPH2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >30 to ?200 g/10 min or, (a2-2) a second propylene homopolymer fraction (PPH2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >5 to ?30 g/10 min and, (a3-1) a third propylene homopolymer fraction (PPH3) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 0.03 to ?5 g/10 min, if the second propylene homopolymer fraction is fraction (a2-1) or, (a3-2) a third propylene homopolymer fraction (PPH3) with a melt flow rate MFR2 (230° C.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: September 2, 2014
    Assignee: Borealis AG
    Inventors: Pauli Leskinen, Petar Doshev, Cornelia Kock
  • Patent number: 8815357
    Abstract: A metallocene-catalyzed polymer comprising (i) a higher molecular weight component and (ii) a lower molecular weight component wherein the polymer has a polydispersity index of from about 10 to about 26; a zero shear viscosity of from about 5×105 Pa·s to about 2×1014 Pa·s and a smooth-to-matte transition critical stress of from about 20 kPa to about 85 kPa at a shear rate of from about 1.5 s?1 to about 17 s?1. A dual metallocene catalyzed polyethylene comprising (i) a higher molecular weight component and (ii) a lower molecular weight component wherein the polymer has a polydispersity index of from about 10 to about 26; a zero shear viscosity of from about 5×105 Pa·s to about 2×1014 Pa·s and a smooth-to-matte transition stress of from about 20 kPa to about 85 kPa at a shear rate of from about 1.5 s?1 to about 17 s?1.
    Type: Grant
    Filed: February 27, 2013
    Date of Patent: August 26, 2014
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Yongwoo Inn, Qing Yang
  • Patent number: 8816010
    Abstract: Composition having a melt flow rate MFR2 (230° C.) in the range of 10 to 50 g/10 min. said composition comprises two heterophasic polypropylenes comprising a propylene homopolymer matrix and an elastomeric copolymer, a plastomer and a mineral filler, wherein—said two heterophasic polypropylenes have different melt flow rates, —the first heterophasic polypropylene has a melt flow rate MFR2 (230° C.) in the range of 3.0 to 30.0 g/10 min and—the second heterophasic polypropylene has a xylene cold soluble (XCS) content in the range of 7.0 to 20.0 wt.-%.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: August 26, 2014
    Assignee: Borealis AG
    Inventor: Michael Tranninger
  • Patent number: 8809461
    Abstract: Disclosed is a multimodal propylene impact copolymer composition with improved stiffness while maintaining good impact strength. The continuous phase has a broad PI and provides the multimodal propylene impact copolymer composition with excellent processability. Thermoformed articles made from the multimodal propylene impact copolymer exhibit improved rigidity and good impact strength.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: August 19, 2014
    Assignee: Braskem America, Inc.
    Inventors: Alechia Crown, Debra R. Wilson, John Kaarto
  • Patent number: 8809462
    Abstract: An ethylene-?-olefin copolymer comprising monomer units derived from ethylene and monomer units derived from an ?-olefin having 3 to 20 carbon atoms, having a density (d) of 860 to 950 kg/m3, having a melt flow rate (MFR) of 0.01 to 100 g/10 min, having a bimodal molecular weight distribution, and having a single melting peak measured by a differential scanning calorimeter (DSC).
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: August 19, 2014
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshinobu Nozue, Naoko Ochi
  • Patent number: 8802781
    Abstract: A polypropylene composition comprising: A) from 30% to 90% by weight of a propylene polymer composition comprising: a1) from 20% to 90% of a propylene homopolymer, or a copolymer of propylene containing 3% or less of derived units of ethylene or C4-C10 ?-olefin(s) or of combinations thereof, said homopolymer or copolymer having a content of isotactic pentads (mmmm), measured by 13C NMR on the fraction insoluble in xylene at 25° C., higher than 96; a2) from 10% to 80%, of a copolymer of ethylene containing from 40% to 70% of derived units of propylene or C4-C10 ?-olefin(s) or of combinations thereof; B) from 10% to 70% by weight of a multimodal ethylene copolymer wherein the comonomer is selected from the derived units of alpha olefins of formula CH2?CHT wherein T is a C3-C10 alkyl group; having the following properties: i) density (with ISO 1183) comprised in the range from 0.850 to 0.
    Type: Grant
    Filed: January 4, 2010
    Date of Patent: August 12, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Giampaolo Pellegatti, Davide Micheletti, Shahram Mihan, Fabiana Fantinel, Gerd Mannebach