Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
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Publication number: 20150030867Abstract: The present disclosure is directed to compositions and methods for improving the cling performance in stretch-cling films. Compositions include: (a) 80.0 to 99.5 wt. % of a propylene-based elastomer, the propylene-based elastomer comprising at least about 60.0 wt. % propylene-derived units and about 5.0 to about 25.0 wt. % ethylene-derived units, based on total weight of the propylene-based elastomer, wherein the propylene-based elastomer has a heat of fusion of less than about 80.0 J/g; and (b) 0.5 to 20.0 wt. % of a polyalphaolefin, wherein the amounts of the propylene-based elastomer, and the polyalphaolefin are based on the weight of the composition. Methods of making such compositions as well as compositions including an ethylene-based polymer and films and methods of making films are also disclosed.Type: ApplicationFiled: May 22, 2014Publication date: January 29, 2015Inventor: Paul M. German
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Patent number: 8940837Abstract: The present invention is a polyolefin composition, which comprises a thermoplastic olefin polymer and a polyethylene. The thermoplastic olefin polymer (TPO) comprises a polypropylene and an olefin copolymer and is present in an amount of about 10 weight percent to about 50 weight percent; the TPO has a density in the range of about 0.85 g/cm3 to about 0.92 g/cm3 and a flexural modulus of less than about 700 MPa as measured by ISO 178. The polyethylene is either a medium density polyethylene or a high density polyethylene and present in an amount of about 50 weight percent to about 90 weight percent. The polyolefin composition is useful for preparing articles of manufacture such as sheets, roofing membranes, geomembranes, soft skins, drawn tapes, drawn fibers, and drawn filaments.Type: GrantFiled: August 8, 2013Date of Patent: January 27, 2015Assignee: Equistar Chemicals, LPInventors: Fabio Ceccarani, Paolo Goberti
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Publication number: 20150025195Abstract: The present disclosure is related to bimodal high-density polyethylene polymer compositions with increased high melt strength and good processability comprising a base resin which has a density of about 945 kg/m3 to about 955 kg/m3, and comprises an ethylene polymer (A) having a density of at least about 968 kg/m3, in an amount ranging from 45% to 55% by weight and an ethylene polymer (B) having a density lower than the density of polymer (A) wherein said composition has a complex viscosity at a shear rate of 0.01 rad/s ranging from about 200 to about 450 kPa·s and a complex viscosity at a shear rate of 100 rad/s ranging from about 1900 to about 2500 Pa·s. The present disclosure also relates to methods of making, and using the present compositions, and to articles made from there composition, and preferably to pipes and fittings.Type: ApplicationFiled: December 21, 2012Publication date: January 22, 2015Applicant: INEOS Olefins & Polymers USA, a division of INEOS USA LLCInventors: Joshua Allen Cottle, Mark Anthony Gessner, Robert Ernest Sander, Luc Dheur
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Publication number: 20150018492Abstract: The present invention relates to a polypropylene composition comprising comonomer units derived from ethylene in an amount of from 0.5 wt % to 25 wt %, and from at least one C5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles XS of at least 20 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4 wt % to 50 wt %.Type: ApplicationFiled: February 26, 2013Publication date: January 15, 2015Inventors: Kristin Reichelt, Juha Paavilainen, Matthew Parkinson
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Publication number: 20150017867Abstract: A bi-component fiber (1), in particular for the production of spunbond fabrics (4), with a first component (2) and a second component (3), whereby the first component (2) has a first polymer as an integral part and the second component has a second polymer as an integral part. The polymer of one of the two components (2, 3) has been polymerized with a metallocene catalyst and the polymer of the other component (2, 3) has been polymerized with a Ziegler-Natta catalyst and subjected to a subsequent visbreaking treatment.Type: ApplicationFiled: July 15, 2014Publication date: January 15, 2015Inventors: Jörn Schröer, Daniel Placke
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Publication number: 20150018491Abstract: The present invention provides an ethylene polymer composition having a particularly high formability and having an excellent mechanical strength, a shaped article formed of such an ethylene polymer, and a film and multilayer film having a particularly excellent blocking resistance. An ethylene polymer composition (?) according to the present invention includes a specific ethylene polymer (?) that is a copolymer of ethylene and an ?-olefin having 4 to 10 carbon atoms and an ethylene polymer (?) that is a copolymer of ethylene and an ?-olefin having 4 to 10 carbon atoms but different from the ethylene polymer (?), and weight fraction [W?] of the ethylene polymer (?) is in the range of not less than 0.1 and not more than 0.9, and weight fraction [W?] of the ethylene polymer (?) is in the range of not less than 0.1 and not more than 0.9 (the sum of the W? and the W? is 1.0).Type: ApplicationFiled: December 26, 2012Publication date: January 15, 2015Inventors: Yasuo Satoh, Yasuyuki Harada
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Publication number: 20150018474Abstract: Disclosed are a propylene resin composition (A) composed of 0.5 to 10% by weight of a specific propylene homopolymer (a1), 40 to 98% by weight of a specific propylene polymer (a2), 1 to 25% by weight of a specific propylene-ethylene random copolymer (a3), and 0.5 to 25% by weight of a specific propylene-ethylene random copolymer (a4), where the total amount of (a1), (a2), (a3) and (a4) is taken as 100% by weight, and an olefin resin composition comprising 100 parts by weight of the propylene resin composition (A), 5 to 75 parts by weight of an ethylene-?-olefin copolymer (B), and 1 to 75 parts by weight of an inorganic filler (C).Type: ApplicationFiled: July 8, 2014Publication date: January 15, 2015Inventor: Hiroyoshi NAKAJIMA
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Publication number: 20150017366Abstract: Injection molded article comprising at least 60 wt.-% of a heterophasic propylene copolymer, said polymer comprises a matrix being a polypropylene, said polypropylene comprises at least three polypropylene fractions, the three polypropylene fractions differ from each other by the melt flow rate and at least one of the three polypropylene fractions has a melt flow rate in the range of 1.0 to 20.0 g/10 min, and an elastomeric propylene copolymer dispersed in said matrix, wherein said heterophasic propylene copolymer has a melt flow rate of equal or more than 20.0 g/10 min and the amorphous phase of the xylene cold soluble fraction of the heterophasic propylene copolymer has an intrinsic viscosity of equal or higher than 2.0 dl/g.Type: ApplicationFiled: January 31, 2013Publication date: January 15, 2015Inventors: Cornelia Tranninger, Stefan Schiesser, Balakantha rao Kona, Andreas Hauer
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Patent number: 8932975Abstract: A catalyst composition comprising (a) a first metallocene complex represented by the general formula: where M1 is Ti, Zr or Hf, X1 and X2 are each independently F, Cl, Br, I, methyl, benzyl, phenyl, H, BH4, a hydrocarbyloxide group having up to 20 carbon atoms, a hydrocarbylamino group having up to 20 carbon atoms, a trihydrocarbylsilyl group having up to 20 carbon atoms, OBR?2 wherein R? may be an alkyl group having up to 12 carbon atoms or an aryl group having up to 12 carbon atoms, and SO3R? wherein R? may be an alkyl group having up to 12 carbon atoms or an aryl group having up to 12 carbon atoms, and Cp1 and Cp2 are each independently a substituted or unsubstituted cyclopentadienyl group, or a substituted or unsubstituted indenyl group, where any substituent on Cp1 and Cp2 is H, a hydrocarbyl group having up to 18 carbon atoms or a hydrocarbylsilyl group having up to 18 carbon atoms, (b) a second metallocene complex, (c) a non-group 4 metallocene transition-metal complex, (d) an activator or activatoType: GrantFiled: September 7, 2010Date of Patent: January 13, 2015Assignee: Chevron Phillips Chemical Company LPInventors: Qing Yang, Max P. McDaniel, Joel L. Martin, Errun Ding, David C. Rohlfing, Tony R. Crain
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Publication number: 20150010741Abstract: Shrinkable film layers having a blend of (i) one or more polymers with a high glass transition temperature, and (ii) one or more polymers with a low glass transition temperature are disclosed. Methods for preparing such film layers are also disclosed.Type: ApplicationFiled: July 2, 2014Publication date: January 8, 2015Inventors: Hoang T. PHAM, Anle XUE, Yatin PATIL
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Publication number: 20150011696Abstract: A method can include consecutively batch processing at least two different polyethylene grades in pellet form in a pellet handling unit. A ratio of a melt flow index (MI) of a first polyethylene in pellet form (MIf) to a MI of a later processed polyethylene in pellet form (MIl) can be smaller than 0.30. The method can include processing an intermediate polyethylene grade in pellet form. An amount of intermediate polyethylene grade processed can be at most 1/100th of a handling capacity of the pellet handling unit. The intermediate polyethylene grade can have the same MI as the later processed polyethylene in pellet form.Type: ApplicationFiled: January 24, 2012Publication date: January 8, 2015Inventors: Peter Stevens, Franky Fant, Daan Dewachter, Alain Brusselle
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Patent number: 8927108Abstract: Inelastic film structures including at least one layer incorporating a combination of a first polymeric component that is at least one polymer incorporating propylene-derived units and a second polymeric component that is a thermoplastic polymer, for example, a polymer incorporating a polyolefin, are provided. The combination of the first polymeric component and the second polymeric component incorporates from about 40 wt. % to about 98 wt. % of the at least one polymer incorporating propylene-derived units and from about 2 wt. % to about 60 wt. % of the at least one polymer incorporating a polyolefin. The film structures are found to have properties making the structures useful for inclusion in a variety of applications. In certain embodiments, the film structures may exhibit optical clarity, tack, sealability, toughness, softness, and machinability properties superior to conventional polypropylene films and other conventional polyolefin films.Type: GrantFiled: December 15, 2006Date of Patent: January 6, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventors: David Michael Fiscus, Narayanaswami Raja Dharmarajan, Michael Charles Bulawa
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Publication number: 20150000510Abstract: A rigid ballistic-resistant composite includes large denier per filament (dpf) yarns. The yarns are held in place by a resin to form a rigid composite panel with improved ballistic performance. The large dpf yarns may be selected from aromatic heterocyclic co-polyamide fibers, polyester-polyarylate fibers, high modulus polypropylene (HMPP) fibers, ultra high molecular weight polyethylene (UHMWPE) fibers, poly(p-phenylene-2,6-benzobisoxazole) (PBO) fibers, poly-diimidazo pyridinylene (dihydroxy)phenylene (PIPD) fibers, carbon fibers, and polyolefin fibers.Type: ApplicationFiled: September 17, 2014Publication date: January 1, 2015Inventor: Jason Aaron van Heerden
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Publication number: 20150005438Abstract: Propylene polymer compositions comprising: A) from 70 wt % to 95 wt %, of a random copolymer of propylene with ethylene, containing from 1.5 wt % to 4.5 wt %, of ethylene derived units, having a content of fraction insoluble in xylene at 25° C. of not less than 93%; B) from 5 wt % to 35 wt %, of a copolymer of propylene with ethylene, containing from 7.0 wt % to 17.0 wt % of ethylene derived units; the sum A+B being 100; wherein the melt flow rate ,MFR. (Melt Flow Rate according to ASTM 1238, condition L, i.e. 230° C. and 2.16 kg load) ranges from 40 g/10 min and 130 g /10 min; and wherein the relation (I) is fulfilled: 10<XS*C2A-MFR/C2B<30 ??(I) wherein XS is the wt % of xylene soluble content at 25° C.Type: ApplicationFiled: October 5, 2012Publication date: January 1, 2015Applicant: Basell Poliolefine Italia S.r.I.Inventors: Gisella Biondini, Marco Ciarafoni, Paola Massari, Roberto Pantaleoni
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Patent number: 8921488Abstract: The present invention provides a resin composition for extrusion coating, the composition including (1) at least one of a copolymer of ethylene and ?,?-unsaturated carboxylic acid or an ionomer thereof and (2) a homopolypropylene, wherein a content of the component (2) is 3 to 12% by mass based on the total mass of the component (1) and the component (2) and has a melt flow rate (at a load of 2160 g and 190° C., JIS K7210) of 4.0 g/10 min. or more.Type: GrantFiled: December 14, 2011Date of Patent: December 30, 2014Assignee: Du Pont-Mitsui Polychemicals Co., Ltd.Inventors: Shigenori Nakano, Kaoru Suzuki
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Patent number: 8920891Abstract: A polymer composition comprises a low-molecular-weight (LMW) ethylene polymer component and a high-molecular-weight (HMW) ethylene polymer component coupled with a polysulfonyl azide. Preferably, the LMW polyethylene component and the HMW polyethylene component co-crystallize in the composition such that it exhibits a single or substantially single peak in a lamella thickness distribution (LTD) curve. The ethylene polymer for the LMW and the HMW polyethylene components can be either homopolymer or ethylene copolymer. Preferably, both components are an ethylene copolymer of the same, or different, composition (that is, with the same or different comonomers). A method of making a pipe that includes selecting a polymer composition having a substantially single peak in the LTD curve is described. Compositions comprising a chromium-catalyzed ethylene polymer, coupled with a polysulfonyl azide are also described herein.Type: GrantFiled: December 9, 2005Date of Patent: December 30, 2014Assignee: Dow Global Technologies LLCInventors: William J. Michie, Jr., Dane Chang, Anthony C. Neubauer, Mridula Kapur, Todd A. Hogan, Felipe B. Martinez, Stephane Costeux
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Patent number: 8921484Abstract: Disclosed herein is a polymeric composition. The polymeric composition includes: (A) a propylene-based polymer; (B) an ethylene/a-olefin polymer; (C) a block composite comprising: i) a propylene-based crystalline polymer; ii) an ethylene/a-olefin polymer; and iii) a block copolymer comprising a propylene-based crystalline block and an ethylene/a-olefin block. The polymeric composition provides improved heat seals when formed into film, film layer, or flexible containers such as retort pouch.Type: GrantFiled: September 29, 2011Date of Patent: December 30, 2014Assignee: Dow Global Technologies LLCInventors: Wenbin Liang, Kim L. Walton, Gary R. Marchand
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Publication number: 20140378602Abstract: The invention provides a composition comprising a first composition comprising the following: A) a first ethylene/?-olefin interpolymer that has a weight average molecular weight (Mw) greater than 90,000 g/mole and a MWD less than, or equal to 3, each as determined by conventional GPC; B) a second ethylene/?-olefin interpolymer; and wherein the first composition has a number average molecular weight (Mn) less than 10,000 g/mole, as determined by conventional GPC; and wherein the ?-olefin of first interpolymer is the same as the ?-olefin of the second interpolymer.Type: ApplicationFiled: December 27, 2012Publication date: December 25, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Brian W. Walther, Timothy E. Clayfield, Curvel Hypolite
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Publication number: 20140377577Abstract: Disclosed herein are blended polymer compositions having a polyethylene first resin and a mLLDPE resin. The polyethylene first resin have a density of at least 0.926 g/cm3; and the mLLDPE resin has a density of between about 0.910 to about 0.925 g/cm3 and a melt index ranging from about 0.05 to about 5. The amount of the mLLDPE is less than about 20 weight percent based on the weight of the polyethylene first resin and mLLDPE resin; and the mLLDPE resin has a narrower molecular weight distribution than the polyethylene first resin.Type: ApplicationFiled: October 24, 2013Publication date: December 25, 2014Applicant: Equistar Chemicals, LPInventors: Chun D. Lee, Harilaos Mavridis, Mick C. Hundley
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Patent number: 8916648Abstract: A polymer filament comprising a polyolefin composition which comprises (percentages by weight): A) 5%-95% of a propylene homopolymer; and B) 5-95% of a butene-1 homopolymer or copolymer having a flexural modulus of 80 MPa or higher.Type: GrantFiled: October 11, 2011Date of Patent: December 23, 2014Assignee: Basell Poliolefine Italia S.r.l.Inventors: Roberto Vanzini, Roberto De Palo
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Patent number: 8916647Abstract: The invention provides cross-linked polymeric films, laminates, membranes or other polymeric articles, which show rubber like heat resistance (hot set) and dimensional stability above the polymer melting point, while maintaining heat sealing properties. For example, the invention provides a film comprising at least one layer formed from a composition comprising the following components: A) at least one polymer selected from the group consisting of the following: i) an ethylene-based polymer, ii) an ethylene/?-olefin/diene interpolymer, and ii) a C4-C10 olefin-based polymer; B) at least one polymer selected from the group consisting of a propylene/ethylene interpolymer and a propylene/&alpha,- -olefin interpolymer; and wherein the film is crosslinked using radiation and/or chemicals.Type: GrantFiled: July 13, 2009Date of Patent: December 23, 2014Assignee: Dow Global Technologies LLCInventors: Karl Zuercher, Stefan Ultsch
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Patent number: 8916644Abstract: [Object] To provide a polypropylene resin composition for use in the formation of a microporous membrane having excellent heat resistance and strength. [Solution] A polypropylene resin composition for use in the formation of a microporous membrane according to the present invention comprises as an essential component an ultra-high-molecular-weight propylene homopolymer (A) that satisfies the following requirements (1) to (4): (1) the intrinsic viscosity [?] is 7 dl/g or more and less than 25 dl/g; (2) the mesopentad fraction ranges from 90.0% to 99.5%; (3) the melting point ranges from 153° C. to 167° C.; and (4) in an elution temperature-elution volume curve measured by temperature-rising elution fractionation (TREF), the maximum peak has a peak top temperature in the range of 116° C. to 125° C. and a half-width of 7.0° C. or less.Type: GrantFiled: January 7, 2010Date of Patent: December 23, 2014Assignees: Toray Battery Separator Film Co., Ltd, Prime Polymer Co., Ltd.Inventors: Satoshi Tamura, Ryoichi Tsunori
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Patent number: 8916649Abstract: The present invention relates to a process of producing an ethylene polymer composition in multiple stages, of which the first stage is preferably a slurry polymerization stage, in the presence of a catalyst system, comprising: a) a solid catalyst precursor, comprising a transition metal selected from titanium and vanadium; magnesium; a halide, optionally an electron donor; and a solid particulate material comprising an inorganic oxide, and wherein the median particle diameter, D50, of the solid catalyst precursor, based upon the total volume of solid catalyst precursor, is from 1 to 13 micrometers; and b) an organoaluminium compound.Type: GrantFiled: May 3, 2012Date of Patent: December 23, 2014Assignee: Dow Global Technologies LLCInventors: Patrick J. C. Schouterden, Ruddy A. J. Nicasy, Sarat Munjal, Robert J. Jorgesen, Burkhard E. Wagner
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Publication number: 20140371397Abstract: A high-density polyethylene (HDPE) can be adapted for the manufacture of caps and closures. The caps and closures can be used as screw-on caps for carbonated or still drinks. The high-density polyethylene can have a density of at least 940 kg/m3 and of at most 970 kg/m3, and a high load melt index HLMI of at least 35 dg/min and of at most 180 dg/min. The high-density polyethylene can include a first polyethylene fraction and a second polyethylene fraction. The first polyethylene fraction can have a density of at least 920 kg/m3 and of at most 945 kg/m3, and a melt index HL275 of at least 3 dg/min and of at most 12 dg/min. The second polyethylene fraction can have a density of at least 960 kg/m3 and of at most 980 kg/m3.Type: ApplicationFiled: September 28, 2012Publication date: December 18, 2014Inventors: David Ribour, Alain Standaert, Daniel Siraux, Ludovic Horion, Olivier Lhost
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Publication number: 20140370312Abstract: The invention relates to a method for producing a biaxially oriented polypropylene film including at least one layer, which is constructed from propylene polymer B and a propylene polymer that has been recycled once. The film is used in capacitors.Type: ApplicationFiled: September 4, 2014Publication date: December 18, 2014Inventors: Detlef BUSCH, Harald EIDEN, Christian PETERS, Josef SCHAAN
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Patent number: 8912263Abstract: The invention relates to propylene polymer compositions comprising 50-70 wt % of a propylene homo- or copolymer, 5-20 wt % of a first elastomeric ethylene-propylene copolymer, 5-25 wt % of a second elastomeric ethylene-propylene copolymer and 5-30 wt % of an ethylene polymer. The propylene polymer compositions are suitable for molding and they have low haze and a good impact strength/stiffness balance with good impact strengths at low temperatures.Type: GrantFiled: March 2, 2011Date of Patent: December 16, 2014Assignee: Borealis Technology OyInventors: Johannes Wolfschwenger, Christelle Grein, Klaus Bernreitner, Markus Gahleitner, Thor Kamfjord
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Patent number: 8912285Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.Type: GrantFiled: December 6, 2012Date of Patent: December 16, 2014Assignee: Chevron Phillips Chemical Company LPInventors: Qing Yang, Max P. McDaniel, Tony R. Crain, Youlu Yu, Yongwoo Inn
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Patent number: 8912282Abstract: Polymer blends comprise at least one ethylene/?-olefin interpolymer and one or more oil. The oil can be an aromatic oil, napththenic oil, paraffinic oil or a combination thereof. The ethylene/?-olefin interpolymers are random block copolymers comprising at least a hard block and at least a soft block. The resulting blends can be used to make flexible molded articles.Type: GrantFiled: July 21, 2010Date of Patent: December 16, 2014Assignee: Dow Global Technologies LLCInventors: Mahalia Soediono, Patricia Ansems Bancroft, Caroline Woelfle, Stephen M. Hoenig, Yunwa W. Cheung
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Patent number: 8912284Abstract: The present invention relates to a crosslinkable polymer composition, comprising (i) an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of more than 0.37, and (ii) a polar copolymer.Type: GrantFiled: June 1, 2006Date of Patent: December 16, 2014Assignee: Borealis Technology OyInventors: Jan-Ove Boström, Annika Smedberg
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Patent number: 8911872Abstract: The invention relates to A process for the polymerization of ethylene to produce a polyethylene resin in at least two slurry loop reactors connected to each other in series, the resin having a bimodal molecular weight distribution, a molecular weight distribution MWD of at least 7.0, an HLMI of from 1 to 100 g/10 min, and a density of from 0.935 to 0.960 g/cm3, wherein in one reactor 30 to 47 wt % based on the total weight of the polyethylene resin of a high molecular weight (HMW) polyethylene fraction is produced having an HL275 of from 0.05 to 1.8 g/10 min (the equivalent of HLMI of from 0.01 to 1.56 g/10 min), a density of from 0.925 to 0.942 g/cm3 and an MWD of at least 5.0, and in the other reactor a low molecular weight (LMW) polyethylene fraction is produced having an HLMI of from 10 to 1500 g/10 min and a density of from 0.960 to 0.975 g/cm3, in the presence of a Ziegler-Natta catalyst system.Type: GrantFiled: June 9, 2014Date of Patent: December 16, 2014Assignee: Total Research & Technology FeluyInventors: Aurélien Vantomme, Daniel Siraux, Alain Van Sinoy, Jean-Léon Gielens
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Publication number: 20140363105Abstract: A bag includes a body and a floor coupled to a bottom end of the body to define an interior region therebetween. A mouth is formed in a top end of the body and is arranged to open into the interior region. The body and floor of the bag are made from plastics materials.Type: ApplicationFiled: June 7, 2013Publication date: December 11, 2014Inventors: Gary M. Pelletier, Frank P. Watson, Donnel Gray, JR., Douglas E. McDonald
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Patent number: 8907019Abstract: A propylene polymer composition comprising (percent by weight referring to the sum of A+B): A) 60%-90% of a crystalline propylene copolymer containing from 1.0% to 5.0% of ethylene derived units; B) 10%-40% of a copolymer of propylene with from 18% to 32% of ethylene derived units, said propylene polymer composition having a melt flow rate value according to ISO 1133 (230° C., 2.16 kg) of from 1.0 to 2.0 g/10 min.Type: GrantFiled: December 19, 2011Date of Patent: December 9, 2014Assignee: Basell Polyolefine GmbHInventors: Alexander Woerz, Mike Freudenstein, Gerald Lutz
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Patent number: 8907018Abstract: Resins suitable for rotomolded articles comprise a bimodal polyethylene copolymer comprising from 0.1 to 5 weight % of one or more C6-8 alpha olefins and the balance ethylene, comprising from 20 to 50 weight % of a higher molecular weight polymer component having an Mw greater than 120,000 and correspondingly from 80 to 50 weight % of a lower molecular weight polymer component having an Mw less than 100,000 having a density greater than 0.942 g/cc [but less than 0.965 g/cc] and a bent strip ESCR as determined by ASTM D 1693 in 100% Igepal® CO-630 (ethoxylated nonylphenols) for conditions A and B of greater than 1000 hours. The resulting articles have a very good balance of properties and significant ESCR.Type: GrantFiled: May 9, 2013Date of Patent: December 9, 2014Assignee: NOVA Chemicals (International) S.A.Inventors: Celine Bellehumeur, Yves Lacombe, Mark Hoidas
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Publication number: 20140357799Abstract: The invention provides a composition comprising at least the following: A) an ethylene/?-olefin interpolymer; B) an olefin-based polymer; and C) a crosslinking agent; and wherein the ethylene/?-olefin interpolymer of component A) has the following properties: i) has a density greater than, or equal to, 0.850 g/cc; ii) a molar ratio of “vinyl to total unsaturation” greater than, or equal to, 1/10; iii) an 110/12 ratio from 6.2 to 40.Type: ApplicationFiled: September 11, 2012Publication date: December 4, 2014Applicant: Dow Global Technologies LLCInventors: Xiaosong Wu, Kim L. Walton, Jeffrey C. Munro
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Patent number: 8901240Abstract: [Object] To provide a polypropylene resin composition for use in the formation of a microporous membrane having excellent heat resistance and low thermal shrinkage ratio. [Solution] A polypropylene resin composition for use in the formation of a microporous membrane according to the present invention comprises as an essential component a propylene homopolymer (A) that satisfies the following requirements (1) to (4) and (7): (1) the intrinsic viscosity [?] is 1 dl/g or more and less than 7 dl/g; (2) the mesopentad fraction ranges from 94.0% to 99.5%; (3) the integral elution volume during heating to 100° C. is 10% or less; (4) the melting point ranges from 153° C. to 167° C.; and (7) in an elution temperature-elution volume curve, the maximum peak has a peak top temperature in the range of 105° C. to 130° C. and a half-width of 7.0° C. or less.Type: GrantFiled: January 6, 2010Date of Patent: December 2, 2014Assignees: Mitsui Chemicals Inc., Prime Polymer Co., Ltd.Inventors: Satoshi Tamura, Keita Itakura, Ryoichi Tsunori, Satoshi Hashizume
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Patent number: 8901260Abstract: An interpolymer of ethylene and at least one alpha-olefin is claimed, wherein the ethylene interpolymer is characterized as having an average Mv and a valley temperature between the interpolymer and high crystalline fraction, Thc, such that the average Mv for a fraction above Thc from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mp) is less then about 1.95 and wherein the interpolymer has a CDBI of less than 60%. The interpolymer of ethylene and at least one alpha-olefin can also be characterized as having a high density (HD) fraction and an overall density such that % HD fraction<?2733.3+2988.7x+144111.5 (x?0.92325)2 where x is the density in grams/cubic centimeter. Fabricated articles comprising the novel interpolymers are also disclosed.Type: GrantFiled: March 30, 2010Date of Patent: December 2, 2014Assignee: Dow Global Technologies LLCInventors: Ayush A. Bafna, Mehmet Demirors, Sylvie Desjardins, Douglas S. Ginger, Colleen M. Tice, Terry A. Pearce
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Patent number: 8901249Abstract: Polymer composition comprising—a heterophasic propylene copolymer comprising a polypropylene matrix and an elastomeric propylene copolymer comprising at least one comonomer selected from the group consisting of ethylene and C4 to C20 ?-olefin, and—a styrenic based elastomer(s) (B), wherein the styrene content in each styrenic based elastomer (B) is equal or below 15 wt.-%, and the total amount of the styrenic based elastomer(s) (B) based on the total amount of polymers present in the polymer composition is of 16.0 to 46.0 wt.-%.Type: GrantFiled: July 27, 2009Date of Patent: December 2, 2014Assignee: Borealis AGInventors: Tonja Schedenig, Christelle Grein, Dietrich Gloger
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Publication number: 20140349051Abstract: A polyolefin composition comprising: A) from 85.0 wt % to 99.5 wt %; A terpolymer containing propylene, ethylene and 1-hexene wherein: (i) the content of 1-hexene derived units ranges from 1.0 wt % to 5.0%; (ii) the content of ethylene derived units is comprised between 0.5 wt % and 10.0 wt % (iii) the melting temperature ranges from 130° C. to 145° C.; B) from 0.5 wt % to 10.0 wt %; of a propylene, ethylene copolymer composition comprising: b1) from 12 wt % to 52 wt %; of a propylene homopolymer or a propylene/ethylene copolymer having a content of ethylene derived units ranging from 0.1 wt % to 4.5 wt %; and having a xylene soluble content measured at 25° C. lower than 10 wt %; b2) from 48 wt % to 88 wt % of a propylene ethylene copolymer having a content of ethylene derived units ranging from 15.0 wt % to wt % to 42.0 wt %; wherein the resulting polyolefin composition has an melt flow rate (230° C./5 kg. ISO 1133) ranging from 0.2 g/10 min to 4.0 g/10 min; the sum A+B being 100 and the sum b1+b2 being 100.Type: ApplicationFiled: December 5, 2012Publication date: November 27, 2014Inventors: Monica Galvan, Giampaolo Pellegatti, Herbert Terwyen, Claudio Cavalieri
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Patent number: 8895668Abstract: A cycloolefin resin composition which controls the flexibility of a cycloolefin resin and may be molded in an environment having a temperature exceeding about 140° C. is provided. A cycloolefin resin film, a cycloolefin resin preform and the like are provided utilizing the cycloolefin resin composition including two or more cycloolefin copolymer resins having Tg values different from each other by about 10° C. or more, and the storage modulus of about 120° C. (E?120) relative to the storage modulus of about 50° C. (E?50), namely E?120/E?50 is set within the range of about 0.15 to about 0.65.Type: GrantFiled: August 5, 2008Date of Patent: November 25, 2014Assignee: Polyplastics Co., Ltd.Inventors: Toshio Nakane, Daisaku Ikeda
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Publication number: 20140343230Abstract: The invention relates to a process for preparing polypropylene films, a polypropylene film obtained by such a process, use of said polypropylene film as packaging material, an article comprising said polypropylene film as well as to the use of a polypropylene composition to improve the processability of a film production process.Type: ApplicationFiled: November 28, 2012Publication date: November 20, 2014Applicant: Borealis AGInventors: Nina Ackermans, Bert Broeders
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Patent number: 8889794Abstract: A composition of matter suitable for use in extrusion coating applications is disclosed. The composition comprises a blend of particular LLDPE with particular LDPE. The LLDPE has the following characteristics: a density in the range of from 0.89 g/cc to 0.97 g/cc; an MWD less than 2.8; a melt index (I2) in the range of 4.0 to 25 g/10 min; a Comonomer Distribution Constant in the range of from greater than from 45 to 400; and a vinyl unsaturation of less than 0.12 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition. The LDPE has a melt index (I2) in the range of 0.1 to 15 g/10 min, and has a melt strength which satisfies the inequality: Log Melt strength (cN)>1.14?0.6×Log I2(g/10 min,190° C.Type: GrantFiled: December 27, 2011Date of Patent: November 18, 2014Assignee: Dow Global Technologies LLCInventor: Jian Wang
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Patent number: 8889793Abstract: The invention relates to a multimodal polyethylene copolymer resin composition comprising (a) a lower molecular weight (LMW) ethylene polymer fraction and (b) a higher molecular weight (HMW) ethylene copolymer fraction, wherein the higher molecular weight (HMW) ethylene copolymer fraction comprises (b1) a higher molecular weight (HMW) ethylene copolymer subfraction having a weight average molecular weight at least 2 times the weight average molecular weight (Mw) of said multimodal polyethylene copolymer resin composition, which (b1) higher molecular weight (HMW) ethylene copolymer subfraction amounts from about 1-30 wt % of the total amount of the multimodal polyethylene copolymer resin composition and comprises comonomers in amount of at least about 1 wt % of the total amount of comonomer present in said multimodal polyethylene copolymer resin composition, a process for its preparation and its use.Type: GrantFiled: July 3, 2008Date of Patent: November 18, 2014Assignee: Borealis Technology OYInventors: Michiel Friso Bergstra, Erik Johan Gunnar Eriksson
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Patent number: 8889792Abstract: Propylene copolymer composition (P) comprising (a) a propylene copolymer (A) having a comonomer content of at least 1.0 wt.-%, the comomers are C5 to C12 a-olefins, and (b) a propylene copolymer (B) having a comonomer content of 4.0 to 20.0 wt.-%, the comomers are C5 to C12 a-olefins, wherein further (i) the comonomer content in the propylene copolymer (A) is lower compared to the comonomer content in the propylene copolymer (B), (ii) the propylene copolymer composition (P) has a comonomer content of 2.0 to 10.0 wt.-%, the comomers are C5 to C12 a-olefins, (iii) the weight ratio of the propylene copolymer (A) to the propylene copolymer (B) is the range of 30/70 to 80/20.Type: GrantFiled: April 18, 2011Date of Patent: November 18, 2014Assignee: Borealis AGInventors: Juha Paavilainen, Petar Doshev, Kristin Reichelt
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Publication number: 20140336334Abstract: A polyolefin compositions comprising: A) From 77 wt % to 90 wt %, of a propylene homopolymer having the fraction soluble in xylene at 25° C. lower than 2 wt %; B) from 10 wt % to 23 wt % of a copolymer of ethylene with one C4-C10 alpha-olefin containing from 20 wt % to 30 wt %, of said C4-C10 alpha-olefin derived units; said composition having the value of melt flow rate (MFR) at 230° C., 2.16 kg of from 0.5 to 4.5 g/10 min; the total content of ethylene of from 10 wt % to 18 wt %; the value of the intrinsic viscosity of the total fraction soluble in Xylene at 25° C. (AMXSIVtot) is less than 1.5 dl/g.Type: ApplicationFiled: October 19, 2012Publication date: November 13, 2014Applicant: Basell Poliolefine Italia S.r.l.Inventors: Roberta Marzolla, Monica Galvan, Angelo Ferraro
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Patent number: 8883884Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a polymer blend comprising a copolymer and an additional polymer, the copolymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer immiscible with the backbone; the additional polymer consisting of a polymer miscible with the polymeric sidechains.Type: GrantFiled: November 27, 2012Date of Patent: November 11, 2014Assignee: The Goodyear Tire & Rubber CompanyInventors: Liqing Ma, Robert Fokko Roskamp, Ralf Mruk, Frank James Feher, Bruce Raymond Hahn
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Patent number: 8883918Abstract: The present invention relates to a process for recycling product streams that have been separated from a hydrocarbon-containing feed stream comprising olefin monomer, olefin co-monomer, hydrocarbon diluent and components such as H2, N2, O2, CO, CO2, and formaldehyde. In accordance with the present process a hydrocarbon-containing feed stream is separated into a) a first side stream comprising hydrocarbon diluent and olefin monomer; b) a second side stream which is substantially hydrogen-free and comprises hydrocarbon diluent and olefin monomer, c) a bottom stream comprising substantially olefin-free hydrocarbon diluent, and d) an overhead vapor stream comprising olefin monomer, hydrocarbon diluent and components such as formaldehyde, H2, N2, O2, CO and CO2. The present process further includes recycling said first and said second side streams in a polymerization process for preparing bimodal polyolefin.Type: GrantFiled: September 10, 2010Date of Patent: November 11, 2014Assignee: Total Research & Technology FeluyInventors: Denis Mignon, David Vandewiele, Bernard Van De Schrick, Camille Vercruysse
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Patent number: 8877856Abstract: Provided is an adhesive resin composition having improved heat resistance without deteriorations in adhesive strength and flexibility. The adhesive resin composition comprises 30 to 98 wt % of an ethylene/vinyl acetate copolymer (a) and 70 to 2 wt % of a propylene resin composition (P), wherein the total of the component (a) and the component (P) is 100 wt %. The propylene resin composition (P) comprises 60 to 0 wt % of a propylene polymer (b) having a melting point of 120 to 170° C. and a melt flow rate of 0.1 to 500 g/10 min, and 40 to 100 wt % of a propylene polymer (c) having a melting point of less than 120° C. or showing no melting points and having a melt flow rate of 0.1 to 500 g/10 min, wherein the total of the component (b) and the component (c) is 100 wt %.Type: GrantFiled: January 17, 2012Date of Patent: November 4, 2014Assignee: Mitsui Chemicals, Inc.Inventors: Hiroto Yasui, Koji Matsunaga
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Patent number: 8877305Abstract: High temperature performance hot melt adhesives are formulated for application at low temperature, i.e., below 300° F. Hot melt adhesive formed with metallocene polymer together with a maleated polyethylene wax show an excellent balance of high and low temperature performance and are particularly useful as packaging case and carton adhesive.Type: GrantFiled: January 30, 2012Date of Patent: November 4, 2014Assignee: Henkel US IP LLCInventors: Jagruti B. Patel, Andrea Keys Eodice, Yew Guan Low
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Patent number: 8877867Abstract: A process for preparing modified thermoplastic vulcanizate compositions, the process comprising the steps of introducing molten thermoplastic vulcanizate and a free-radical source, where the thermoplastic vulcanizate includes cured rubber dispersed within a thermoplastic matrix.Type: GrantFiled: October 15, 2009Date of Patent: November 4, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Hari P. Nadella, Jianya Cheng
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Patent number: 8871868Abstract: Propylene impact copolymers (ICPs) are provided which comprise: (a) a matrix phase which comprises from 60 to 95 weight % of a polypropylene polymer containing from 0 to 6 mole % of units derived from one or more alpha-olefins other than propylene, and (b) a dispersed phase which comprises from 5 to 40 weight % of a copolymer derived from a first comonomer which can be either propylene or ethylene together with a second alpha-olefin comonomer. The ICP is further characterized by having a beta/alpha ratio less than or equal to 1.1. The ICPs of the present invention are particularly well suited for applications requiring clear, tough polymers such as thin walled injection molded articles for frozen food packaging applications.Type: GrantFiled: January 9, 2013Date of Patent: October 28, 2014Assignee: Braskem America, Inc.Inventors: Peter S. Dias, Jonathan D. Kersey, Peter S. Martin, Thomas R. Cuthbert