Cyclic Anhydride Patents (Class 525/285)
  • Patent number: 7408007
    Abstract: A process for the manufacture of maleated polypropylenes having an acid number greater than 4.5, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process for making the maleated polypropylenes includes forming a mixture of molten polypropylene and molten maleic anhydride in a reactor, introducing a free radical initiator into the molten mixture to produce a product having maleic anhydride grafted onto the polypropylene, and recovering a high acid number, high molecular weight maleated polypropylene of low color from the reactor.
    Type: Grant
    Filed: February 4, 2005
    Date of Patent: August 5, 2008
    Assignee: Eastman Chemical Company
    Inventors: Thomas David Roberts, Stephen Wayne Coe
  • Patent number: 7396887
    Abstract: A process for producing polymers having at least one high vinyl end segment is provided. The process comprises: (a) forming a living prepolymer high vinyl initiator with a vinyl content greater than about 45% using a vinyl modifier, (b) adding a R1R2R3aluminum or R1R2R3boron compound to nullify the effect of the vinyl modifier, and (c) initiating polymerization of diene monomers using said living prepolymer high vinyl initiator so as to form a polymer product with at least one high vinyl end segment, where R1, R2, and R3 are selected from the group consisting of C1-C12 alkyl, C2-C12 alkene, C2-C12 alkyne, phenyl, and alkyl-substituted phenyl, and may all be identical or may all be separately selected but cannot be H. The polymers having at least one high vinyl end segment may be coupled to produce a polymer having a high vinyl end segment on all ends.
    Type: Grant
    Filed: December 29, 2006
    Date of Patent: July 8, 2008
    Assignee: Bridgestone Corporation
    Inventor: James E. Hall
  • Patent number: 7371713
    Abstract: A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: May 13, 2008
    Assignee: Castrol Limited
    Inventors: Irwin L. Goldblatt, Shean-Jer Chen, Manish R. Patel, Stephen T. McKenna
  • Patent number: 7368507
    Abstract: A graft copolymer having a structure in which a vinyl copolymer segment formed from a vinyl monomer having an acid is suspended in a molecular chain of a polyolefin resin segment via a ?-substituted propylene group is obtained, by reaction of polyolefin resin having ?-substituted propenyl group as a pendant and a vinyl monomer having an acid, and further a graft copolymer composition containing the same and a molded product thereof are obtained. The obtained graft copolymer, the composition containing the same and the molded product thereof are excellent in adhesive property to a polar material and scratch resistance.
    Type: Grant
    Filed: October 23, 2003
    Date of Patent: May 6, 2008
    Assignee: NOF Corporation
    Inventors: Masumi Takamura, Hitoshi Uchida, Yoshiki Yamamoto, Motoyuki Sugiura
  • Patent number: 7365123
    Abstract: Thermoplastic polymer compositions, films, continues, closures, laminates can comprise a modified vinyl polymer said modified polymer having a moiety comprising a cyclodextrin compound. The cyclodextrin compound, locked into the polymer structure, can absorb impurities, permeants, or other undesirable volatile materials. The cooperation between the cyclodextrin grafted onto the thermoplastic polymer and the polymer structure can provide barrier properties to a film, web or other polymer structure. A permeant or a contaminant can be complexed or trapped within the polymer and held within the film or Web preventing the permeant or contaminant from passing into the interior of a container or enclosure.
    Type: Grant
    Filed: April 13, 2006
    Date of Patent: April 29, 2008
    Assignee: Cellresin Technologies, LLC
    Inventors: Willard E. Wood, Neil J. Beaverson, Kasyap V. Seethamraju
  • Patent number: 7348398
    Abstract: The invention relates to a method for separating transition metals from polymers. According to the invention, a solid polymer containing transition metals is treated with an extracting agent, the duration of the treatment and the extraction temperature being selected in such a way that the transition metal content is reduced by at least 30 wt. %.
    Type: Grant
    Filed: January 24, 2004
    Date of Patent: March 25, 2008
    Assignee: Roehm GmbH & Co. KG
    Inventors: Thorsten Goldacker, Klaus Koralewski
  • Patent number: 7314902
    Abstract: The present invention provides a hot-melt adhesive composition comprising a blend of: a reactive filler comprising an aluminum compound, a magnesium compound, a calcium compound, a barium compound or a mixture thereof; and, a grafted polyolefin having a functional group for reaction with the reactive filler. Such a hot-melt adhesive is particularly useful for bonding a polyolefin-based substrate to dissimilar materials such as metals, wood, ceramics and thermoset plastics.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: January 1, 2008
    Assignee: National Research Council of Canada
    Inventors: Minh-Tan Ton-That, Johanne Denault, Marie Gundjian
  • Patent number: 7304111
    Abstract: A problem of the invention is to provide a propylene copolymer which is excellent in adhesion to crystalline propylene-based polymers and which is excellent in solubility and compatibility with polar resins, a process for producing the same, and a composition containing the subject polypropylene copolymer. The invention is concerned with a polypropylene copolymer, which is characterized by having a polymer principal chain (A) derived from a propylene-based polymer having (1) a prescribed requirement as defined by the 13C-NMR spectral measurement and having (2) a melting point [Tm] by a differential scanning calorimeter of not higher than 100° C., or a crystal melting heat of less than 5 J/g; and a side chain containing a polymer chain (B) which is different from the principal chain, with a weight ratio of (A)/(B) being in the range of from 20/1 to 1/20, a composition containing the subject copolymer, and a process for producing the subject copolymer.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: December 4, 2007
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Kazuyuki Hata
  • Patent number: 7300977
    Abstract: This method for preparing an acrylic-modified chlorinated polyolefin resin comprises graft-copolymerizing an acid-modified chlorinated polyolefin resin with a monomer mixture containing a (meth)acrylate ester monomer having one hydroxyl group and another vinyl monomer in the presence of a cyclic ether compound. Also, the cyclic ether compound may be added in an amount of 1 to 100 parts by weight based on 100 parts by weight of the acid-modified chlorinated ployolefin resin, and the cyclic ether compound may be dioxane and/or 1,3-dioxolane.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: November 27, 2007
    Assignee: Fujikura Kasei Co., Ltd.
    Inventors: Mitsuo Najima, Takashi Isogai
  • Patent number: 7300982
    Abstract: A process for producing a modified polyethylene resin, which comprises the step of melt kneading at least: (A) 100 parts by weight of a polyethylene resin, (B) from 0.1 to 20 parts by weight of at least one compound selected from the group consisting of: (B1) a compound having in its molecule (i) at least one carbon-carbon double or triple bond and (ii) at least one polar group, and (B2) a compound having in its molecule (iii) an OR group and (iv) at least two specific functional groups, and (C) from 0.01 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 50 to 115° C., at which temperature a half-life thereof is 1 minute.
    Type: Grant
    Filed: March 16, 2004
    Date of Patent: November 27, 2007
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shinichi Kondo, Takashi Sanada
  • Patent number: 7294673
    Abstract: A method of modifying a polymeric material whereby the polymeric material is modified to give a highly durable surface without decreasing its strength. Namely, a polymeric material is modified by the method comprising a combination of an impregnation step, an activation step, a step of grafting a monomer and a step of a treatment with a hydrophilic polymer. Thus, the hydrophilic nature, adhesiveness, and so forth of polymeric materials such as polyolefins can be improved without causing any decrease in the practical strength. The thus obtained polymeric materials are usable in articles with a need for high water absorptivity and high adhesiveness, for example, water-absorbing materials and water-retaining materials for medical, sanitary, cosmetic articles or supplies, agricultural materials, synthetic papers, filters and fiber products for clothes, for improving adhesiveness of composite materials and the like.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: November 13, 2007
    Assignee: FiberMark Gessner GmbH & Co.
    Inventor: Hitoshi Kanazawa
  • Patent number: 7282541
    Abstract: A process for preparing a functionalized propylene-based polymer and a functionalized polymer having a propylene-based polymer backbone is disclosed. The propylene-based polymer backbone can further comprise one or more alpha olefins.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: October 16, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jean-Roch Schauder, Abdelhadi Sahnoune, Sudhin Datta
  • Patent number: 7279528
    Abstract: Resins and oligomer materials and/or combinations thereof grafted with an unsaturated acid or anhydride, such as maleic anhydride, are disclosed herein. The grafted materials are useful in adhesive formulations, particularly in hot melt adhesive applications.
    Type: Grant
    Filed: September 19, 2002
    Date of Patent: October 9, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Anne Vera Macedo, Kenneth Lewias, John Richard Shutt
  • Patent number: 7276557
    Abstract: Resins and oligomer materials and/or combinations thereof grafted with an unsaturated acid or anhydride, such as maleic anhydride, are disclosed herein. The grafted materials are useful in adhesive formulations, particularly in hot melt adhesive applications.
    Type: Grant
    Filed: September 19, 2002
    Date of Patent: October 2, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Anne Vera Macedo, Kenneth Lewtas, John Richard Shutt
  • Patent number: 7256236
    Abstract: Disclosed are methods for advantageously producing maleated polypropylenes having a relatively high percentage of bound maleic anhydride, based on the total amount of maleic anhydride moieties present in the grafting reaction product, and the maleated polypropylenes produced therefrom. The methods produce maleated polypropylenes wherein at least about 60% of the maleic anhydride moieties in the grafting reaction product are bound to the polypropylene.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: August 14, 2007
    Assignee: Honeywell International Inc.
    Inventor: Scott M. Hacker
  • Patent number: 7253231
    Abstract: A novel highly grafted, multi-functional olefin copolymer is provided comprising an additive reaction product of a method comprising reacting acylating agent with an olefin copolymer having a number average molecular weight greater than about 1,000 in the presence of a free radical initiator and essentially free of hydrocarbon solvent in an extruder to provide an olefin copolymer intermediate comprising an acylated olefin copolymer having a degree of grafting (DOG) of at least 0.5 wt. %, which copolymer intermediate's molecular weight is reduced, vacuum stripped of unreacted components, pelletized, dissolved in a neutral oil (preferably with inert gas sparging), and further reacted with a polyamine to provide a grafted multi-functional olefin copolymer viscosity modifier, and lubricating oil concentrates and compositions containing the same and uses thereof.
    Type: Grant
    Filed: January 31, 2005
    Date of Patent: August 7, 2007
    Assignee: Afton Chemical Corporation
    Inventors: Cathy C. Devlin, Charles A. Passut, Joe S. Bradley, Michael A. Danylo, Yoon Song, Sanjay Srinivasan, Zhaoyao Joe Qiu, Errol Joseph Olivier, Patric Meessen, Gerhard Van Vliet, Gerardus Arnoldus Rademakers, Johannes Hendrik Geesink
  • Patent number: 7238405
    Abstract: An insulating material comprising a cycloolefin polymer, specifically, an interlayer insulating material for a high-density assembly board having interlayer-connecting via holes at most 200 ?m in diameter, comprising a cycloolefin polymer containing at least 50 mol % of a repeating unit derived from a cycloolefin monomer; a dry film formed from a curable resin composition comprising a polymer having a number average molecular weight within a range of 1,000 to 1,000,000 as measured by gel permeation chromatography, and a hardener; and a resin-attached metal foil obtained by forming a film of a cycloolefin polymer on one side of a metal foil. Laminates, multi-layer laminates and build-up multi-layer laminates making use of these materials, and production processes thereof.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: July 3, 2007
    Assignee: Nippon Zeon Company, Ltd.
    Inventors: Yasuo Tsunogae, Yasuhiro Wakizaka, Junji Kodemura, Tohru Hosaka
  • Patent number: 7235610
    Abstract: The purpose of the invention is to provide a novel aqueous dispersion that allows high solidification and that has good adherence and gasohol resistance to polyolefin substrates even on low-temperature baking. An aqueous dispersion characterized by dispersedly containing carboxyl group-containing chlorinated propylenic random copolymer with chlorine content of 5 to 40% by weight, grafting level of ?,?-unsaturated carboxylic acid or its anhydride of 0.1 to 20% by weight and weight average molecular weight of 10,000 to 300,000, and stabilizer, a method for the production and the uses thereof.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: June 26, 2007
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Kenichi Fujino, Hidetoshi Yoshioka
  • Patent number: 7208552
    Abstract: The invention provides a novel binder resin composition with good adherence onto prime materials of polyolefin, poly (vinyl chloride), polycarbonate, PET, ABS and nylon, and also with excellent solvent solubility. A binder resin composition characterized by being chlorinated propylenic random copolymer with weight average molecular weight of 3000 to 250000, wherein propylenic random copolymer with melting point (Tm) measured by differential scanning calorimeter (DSC) of 115 to 165° C.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: April 24, 2007
    Assignee: Nippon Paper Industries, Co., Ltd.
    Inventors: Naosuke Komoto, Hidetoshi Yoshioka
  • Patent number: 7205341
    Abstract: The present invention relates to an aqueous pigment dispersion that shows excellent dispersibility and storage stability, an inkjet ink that shows excellent jetability, water resistance, and adhesion, and a process for producing an aqueous pigment dispersion that shows excellent dispersibility and storage stability, as well as superior jetability, water resistance and adhesion. An aqueous pigment dispersion of the present invention comprises a dispersion formed by dispersing a monoalkyl maleate graft polymer of a maleic anhydride/?-olefin copolymer in water in the presence of a base, a pigment, and an aqueous medium.
    Type: Grant
    Filed: August 25, 2003
    Date of Patent: April 17, 2007
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventor: Seiji Aida
  • Patent number: 7196141
    Abstract: The present invention provides a vinyl polymer with an epoxy group terminally introduced therein and an epoxy resin composition comprising (A) an epoxy resin and (B) a vinyl polymer which has a main chain produced by living-radical polymerization and has a reactive functional group at a main chain terminus. A flexible epoxy resin composition can be obtained using these compounds. The invention further provides an epoxy resin composition-having an epoxy group at a main chain terminus thereof.
    Type: Grant
    Filed: September 7, 2006
    Date of Patent: March 27, 2007
    Assignee: Kaneka Corporation
    Inventors: Kenichi Kitano, Yoshiki Nakagawa, Masayuki Fujita
  • Patent number: 7183359
    Abstract: Polypropylene having high maleic anhydride content, between about 5 and about 45 wt %, may be prepared by first reacting a metallocene-prepared polypropylene having terminal unsaturation with one mole equivalent of maleic anhydride to give polypropylene having a single unsaturation and a terminal succinic anhydride moiety. This product is then reacted with additional maleic anhydride in the presence of a free radical initiator (such as a peroxide or UV radiation) to give a polypropylene with maleic anhydride moieties along the backbone. The polypropylene product does not suffer scission or crosslinking with subsequently undesirable increases in molecular weight or viscosity. The maleic anhydride moieties provide reactivity to the polypropylene and thus expand its uses and applications.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: February 27, 2007
    Assignee: Baker Hughes Incorporated
    Inventors: Paul K. Hanna, David D. Truong
  • Patent number: 7179863
    Abstract: The present invention relates to the use of films, formed from an adhesive layer and a layer (A), for coating articles made of a thermoset, the adhesive layer comprising, by weiqht: 0 to 60 parts of PVDE, 10 to 100 parts of functionalized PMMA, 0 to 50 parts of an acrylic elastomer and 0 to 4 parts of a UV absorber, the total making up 100 parts, the layer (A) comprising, as main constituents, 0 to 100 parts of PVDF per 100 to 0 parts of PMMA, respectively. This film may be manufactured by coextrusion and is then fixed to the thermoset, for example by hot pressing. The invention also relates to an SMC (Sheet Moulding Compound) multilayer structure comprising, in this order: a backing film, a crosslinkable composition (the precursor of the thermoset), the above adhesive layer and the above layer (A).
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: February 20, 2007
    Assignee: Arkema France
    Inventors: Anthony Bonnet, Philippe Bussi, David Silagy
  • Patent number: 7160950
    Abstract: A modified olefin-based copolymer produced by graft-polymerizing an alkenyl aromatic hydrocarbon and/or an unsaturated carboxylic acid or derivative thereof to an olefin-based copolymer containing repeating units derived from a linear ?-olefin and/or ethylene copolymer of ethylene and repeating units derived from a vinyl compound (I) or (II) described below, and an adhesive containing the product as an effective ingredient, in which an adhesiveness to an adherend such as olefin resins (e.g. polyethylene, polypropylene) is further improved, are provided. Vinyl compound (I): a vinyl compound represented by the general formula CH2?CH—R, wherein steric parameters Es and B1 of the substituent R are respectively ?1.64 or less and 1.53 or more. Vinyl compound (II): a vinyl compound represented by the general formula CH2?CH—R?, wherein a substituent R? is a secondary or tertiary alkyl group.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: January 9, 2007
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toshiki Mori, Nobuo Oi
  • Patent number: 7153498
    Abstract: A composition, comprising, in a physiologically acceptable medium, an aqueous phase dispersed in an oily phase by means of an emulsifier of at least one oligomer or one polymer derived from a polyolefin, comprising a polyolefinic apolar component comprising at least 40 carbon atoms and at least one polar component.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: December 26, 2006
    Assignee: L'Oreal
    Inventors: Odile Aubrun-Sonneville, Jean-Thierry Simonnet
  • Patent number: 7144951
    Abstract: A process is disclosed that comprises solution grafting a hydrocarbon polymer prepared from at least C2 to C28 polymerizable hydrocarbon, said polymer having a number average molecular weight in the range of from about 5,000 to about 500,000, with an ethylenically unsaturated C3 to C10 carboxylic acid material, using a free radical initiator, in the presence of an aromatic ester oil of the formula (I) wherein R1, R2, R3, R4, R5, and R6 are independently selected from the group consisting of hydrogen, —COOR7, —COOR8, —COOR9, —COOR10, —COOR11, and —COOR12, provided that no more than 5 of R1, R2, R3, R4, R5 and R6 are hydrogen, and R7, R8, R9, R10, R11, and R12 are independently selected from the group consisting of alkyl and alkylesters
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: December 5, 2006
    Assignee: Crompton Corporation
    Inventors: Karl Duyck, Theodore E. Nalesnik, Uyen Thanh Tran
  • Patent number: 7122604
    Abstract: This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: October 17, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Teruaki Ashihara, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Akio Tanna
  • Patent number: 7112632
    Abstract: A process for the preparation of low branch content polybutadiene comprising: (a) a first butadiene polymerisation stage; (b) treatment of the polymer solution obtained upon completion of stage (a) with a coupling agent selected from: (i) polyunsaturated natural oils; (ii) butadiene and/or isoprene oligomers; (iii) butadiene and/or isoprene co-polymers with vinylarene monomers; the unsaturations present in compounds (i)–(iii) being at least partially substituted with groups selected from epoxides, anhydrides and esters; (c) recovery of the low branch content polybutadiene obtained upon completion of stage (b).
    Type: Grant
    Filed: October 17, 2005
    Date of Patent: September 26, 2006
    Assignee: Polimeri Europa S.p.A.
    Inventors: Gian Tommaso Viola, Fabio Bacchelli, Silvia Valenti
  • Patent number: 7098271
    Abstract: Melt-fabricable thermoplastic fluoropolymer having pendant functional groups is thermally cross-linked in the presence of polyfunctional nucleophile.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: August 29, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Paul Douglas Brothers, Patrick Edward Lindner, Peter Dwight Spohn
  • Patent number: 7091306
    Abstract: The present invention relates to an improved process for preparing polyalkenylsuccinimides having a sediment level less than 0.1 vol % comprising the steps of: (a) preparing a polyalkenyl derivative of an unsaturated acidic reagent by (i) reacting a polyalkylene with an unsaturated acidic reagent in the absence of a strong acid until at least 25% of the polyalkylene is converted to a polyalkenyl derivative of an unsaturated acidic reagent; (ii) continuing the reaction with an excess of the unsaturated acidic reagent in the presence of a strong acid to convert at least some of the unreacted polyalkylene to additional polyalkenyl derivative of an unsaturated acidic reagent; and (iii) removing the unreacted unsaturated acidic reagent; (b) reacting the unfiltered product of step (a) with a polyamine having at least one basic nitrogen atom; (c) diluting the product of step (b); and (d) subsequently filtering the polyalkenylsuccinimide product.
    Type: Grant
    Filed: May 9, 2003
    Date of Patent: August 15, 2006
    Assignees: Chevron Oronite Company LLC, Chevron Oronite S. A.
    Inventors: Mohammed Heddadj, William R. Ruhe, Jr., Gilles P. Sinquin
  • Patent number: 7091285
    Abstract: A reaction product comprising an adduct of a mid-range vinylidene content PIB polymer composition and maleic anhydride, a phenolic compound or a compound having a reactive site for subsequent amination. The PIB composition comprises a relatively low molecular weight, mid-range vinylidene content PIB polymer product wherein at least about 90% of the PIB molecules present in the product comprise alpha or beta position isomers. The vinylidene (alpha) isomer content of the product may range from 20% to 70% thereof and the content of tetra-substituted internal double bonds is very low, preferably less than about 5% and ideally less than about 1–2%. The mid-range vinylidene content PIB polymer products may be prepared employing a liquid phase polymerization process conducted in a loop reactor at a temperature of at least 60° F. using a BF3/methanol catalyst complex and a contact time of no more than 4 minutes.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: August 15, 2006
    Assignee: Texas Petrochemicals LP
    Inventors: C. Edward Baxter, Jr., Christopher Lobue, Gilbert Valdez, Daniel Herndon, Timothy Lowry
  • Patent number: 6930153
    Abstract: A method for producing maleic anhydride modified butyl rubber comprising reacting a halogenated butyl rubber with maleic anhydride in the presence of (i) an acid acceptor and (ii) a monofunctional hindered amine and/or monofunctional hindered phenol; which is useful for further, modifying by a nitrogen-containing heterocyclic compound to form the modified butyl rubber having the improved processability.
    Type: Grant
    Filed: June 19, 2003
    Date of Patent: August 16, 2005
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventor: Makoto Ashiura
  • Patent number: 6921792
    Abstract: Disclosed are a chemically modified polyolefin elastomer composition that is highly compatible with thermoplastics and useful in improving the low temperature impact strength of thermoplastics, and a method for preparing the chemically modified polyolefin elastomer composition. The elastomer composition includes a polyolefin resin and a chemically modified ethylene-?-olefin elastomer mixed with the polyolefin resin. The chemically modified ethylene-?-olefin elastomer includes an ethylene-?-olefin elastomer backbone and grafted branches from the backbone. The branches includes polymers of one or more monomers comprising an unsaturated organic compound containing at least one carbonyl group. The method of producing the composition includes mixing an ethylene-?-olefin elastomer and a polyolefin resin to provide a mixture thereof, to which added is one or more monomers having an unsaturated organic compound containing at least one carbonyl group.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: July 26, 2005
    Assignee: Kumho Polychem Co., Ltd.
    Inventors: Sang Bae Kim, Sung Su Na, Yeon Won Jeyong
  • Patent number: 6919410
    Abstract: There is provided a process for producing a modified polypropylene resin, which comprises the steps of mixing the following components (A) to (D), and reacting them with one another: (A) 100 parts by weight of a polypropylene resin, (B) 0.1 to 30 parts by weight of a compound having a bond or a functional group selected from the group consisting of a non-aromatic carbon-carbon multiple bond, an oxirane group and a derived carboxyl group, (C) 0.001 to 30 parts by weight of a compound having at least two functional groups reactive to a carboxyl group, and (D) 0.01 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 50 to 120° C., at which temperature a half-life of the organic peroxide is 1 minute.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: July 19, 2005
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Katsuhisa Kitano, Takashi Sanada
  • Patent number: 6894121
    Abstract: Cement dispersants made of graft copolymers of a specified type and/or their salts are produced by using as an intermediate product allyletherester monomers prepared by an esterification reaction of ?-allyl-?-hydroxy-polyoxyalkylene refined so as to have peroxide value less than 5.0 meq/kg and aliphatic monocaboxylic acid under a specified condition in the absence of solvent and in the presence of an antioxidant.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: May 17, 2005
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Mitsuo Kinoshita, Shinji Tamaki
  • Patent number: 6887943
    Abstract: This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: May 3, 2005
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Teruaki Ashihara, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Akio Tanna
  • Patent number: 6884851
    Abstract: Process for producing polyolefins, comprising the following steps: a) grafting of acid groups onto polyolefins by means of a graftable monomer bearing at least one functional group chosen from a carbonyl and an acid anhydride, optionally in the presence of another graftable monomer bearing a vinyl unsaturated group and, optionally, one or more aromatic rings; b) purification, consisting in removing at least some of the graftable monomer bearing at least one functional group chosen from a carbonyl and an acid anhydride that has not reacted with the polyolefins; c) neutralization of the acid groups by at least one neutralizing agent. Polyolefin obtained.
    Type: Grant
    Filed: May 1, 2003
    Date of Patent: April 26, 2005
    Assignee: Solvay (Societe Anonyme)
    Inventor: Fernand Gauthy
  • Patent number: 6884850
    Abstract: Propylene ethylene copolymers with an ethylene content between 8 and 32 mole % have been grafted with maleic anhydride and a peroxide. The functionality level is higher than what is reported with polypropylene.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: April 26, 2005
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jean-Roch H. Schauder, Sudhin Datta
  • Patent number: 6875804
    Abstract: The syndiotactic polystirene resin composition according to the present invention is superior in compatibility between a syndiotactic polystyrene and a rubber component and mechanical properties such as impact strength, in which a syndiotactic polystyrene-maleic anhydride (sPS-MA) and a hydrogenated styrene/butadiene/styrene-maleic anhydride (SEBS-MA) are employed as compatibilizers and a diamine compound is added as a coupling agent. The compatibilizers and coupling agents improve polarity of both the syndiotactic polystyrene and the rubber component and impact strength of the syndiotactic polystyrene composition.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: April 5, 2005
    Assignee: Samsung Atofina Co., Inc.
    Inventors: Xuequan Zhang, Jae Gon Lim
  • Patent number: 6875823
    Abstract: There is provided a process for producing a modified polyolefin resin, which comprises the steps of: (1) blending at least the following components (A) to (D) to produce a blend: (A) 100 parts by weight of a polyolefin resin, (B) from 0.1 to 20 parts by weight of a compound having an epoxy group and an unsaturated bond, (C) from 0.01 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 50 to 115° C., at which temperature a half-life thereof is 1 minute, and (D) from 0 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 150 to 200° C., at which temperature a half-life thereof is 1 minute, and (2) melt-kneading said blend to produce a modified polyolefin resin.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: April 5, 2005
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shinichi Kondo, Takashi Sanada
  • Patent number: 6870003
    Abstract: A process for producing modified thermoplastic resin by subjecting a thermoplastic resin to a modifying reaction in a molten state, comprising performing the modifying reaction using carbon dioxide as the reaction medium, wherein carbon dioxide is used in a proportion of 2-200 parts by weight per 100 parts by weight of the thermoplastic resin, whereby the efficiency and the uniformity of the reaction can be increased to a high extent while attaining considerable decrease in the remaining amount of the unreacted components in the resulting modified thermoplastic resin without having recourse to the use of an organic reaction solvent, so that the production can be realized easily at a low cost in an efficient manner.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: March 22, 2005
    Assignee: Mitsui Chemical, Inc.
    Inventors: Shigeo Nishikawa, Haruo Inoue, Naohiro Yamada
  • Patent number: 6861471
    Abstract: The present invention provides a coating composition for polyolefin resins, comprising a resin obtained by graft-copolymerizing at least one member selected from the group consisting of an ?,?-unsaturated carboxylic acid and an acid anhydride thereof with at least one member selected from the group consisting of polypropylene and a propylene-?-olefin copolymer, chlorinating the graft copolymer to give an acid-modified chlorinated polyolefin, linking a (meth)acrylic ester having one hydroxyl group to the polyolefin via an ester linkage, and then graft-copolymerizing (meth)acrylic acid monomers with the polyolefin; and a process for producing the composition.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: March 1, 2005
    Assignee: Toyo Kasei Kogyo Company Limited
    Inventors: Takafumi Masuda, Shoji Maekawa, Shigeru Sugiyama, Shin-ichi Akiyama
  • Patent number: 6855771
    Abstract: A process for manufacturing block polymer or copolymer from isotactic polypropylene. Polyolefins are introduced into an extruder. Free radical generator is mixed with the polyolefins to form a mixture at room temperature for free radical formation. The mixture is brought up to a temperature of between 175° C. to 220° C. Chain degradation of the polyolefins is induced by the free radical formation to form degraded polymer. Alkenically unsaturated monomers or polymer segments are mixed with the degraded polymer to form a second mixture. The temperature of the second mixture may be lowered to a temperature of between 90° C. to 150° C. The temperature of the second mixture is then adjusted to a temperature between 100° C. to 250° C. to form a novel block polymer or copolymer.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: February 15, 2005
    Inventors: Grant Doney, Keith Salsman
  • Publication number: 20040260029
    Abstract: Graft polymers are disclosed. These are obtainable by polymerization of a mixture containing A) from 40 to 99 wt. % vinyl monomers and B) from 1 to 60 wt. % of a double-bond-containing polyalkylene oxide rubber having a glass transition temperature below −50° C. and a number-average molecular weight of from 25,000 to 10,000,000. The inventive graft polymers are characterized by their very good low-temperature strength and weathering resistance.
    Type: Application
    Filed: July 12, 2004
    Publication date: December 23, 2004
    Inventors: Evgueni Avtomonov, Burkhard Kohler, Pierre Vanhoorne, Rolf-Volker Meyer
  • Patent number: 6833045
    Abstract: Disclosed is a resin dispersion comprising solid particles of a graft modified ethylene/1-olefin random copolymer dispersed in an organic solvent, which has (a) a specific content of an &agr;-olefin component, (b) a specific intrinsic viscosity (&eegr;) and (h) a specific content of a polar monomer component. The resin dispersion of the invention exhibits excellent adhesion properties as an adhesive between polyolefins or metal and polyolefin or as a heat-sealing material, so that the dispersion is effectively used particularly as an adhesive for packaging, an adhesive for lamination, a coating material or a primer.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: December 21, 2004
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Suguru Tokita, Tadao Saito
  • Patent number: 6812296
    Abstract: The present invention provides compositions and methods for removing water from a sealant composition. This includes the addition of a particularly selected anhydride to a sealant composition and further addition of an acrylic acid, in order to remove water from a sealant composition.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: November 2, 2004
    Inventors: Frederick F. Newberth, III, Peter J. Chupas
  • Patent number: 6800688
    Abstract: A resin which has excellent adhesion to nonpolar substrates, is nontacky, and has satisfactory solubility in aromatic or nonaromatic solvents and satisfactory compatibility with other resins. The resin is a modified polyolefin resin having a weight-average molecular weight of 15,000 to 150,000 obtained by modifying a polyolefin resin by grafting thereto (A) an unsaturated polycarboxylic acid or a derivative thereof and (B) a (meth)acrylic ester represented by a specific general formula, the contents of (A) and (B) in the modified polyolefin resin being 0.1 to 20 wt. % and 0.1 to 30 wt. %, respectively.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: October 5, 2004
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Kazuhiro Usui, Kenichi Fujino, Terumasa Fujitaka, Tadashi Matsui, Hidetoshi Yoshioka, Shunji Sekiguchi
  • Patent number: 6784251
    Abstract: An emulsible polyolefin wax having sufficient functionality to be emulsible in an aqueous medium, a melt viscosity of less than 1,000 cps at 190° C., and an emulsion light transmittance of at least 10% at 525 nm with a 20 mm light pathlength.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: August 31, 2004
    Assignee: Honeywell International Inc.
    Inventors: Charles Lences, Peter F. Romeo, Manfred Seven
  • Patent number: 6780963
    Abstract: The polyamide resin composition of the invention is characterized by having a solder reflow heat-resistant temperature of not lower than 250° C. Since the polyamdie resin composition has low water absorption and is excellent in moldability, heat resistance, shape stability and mechanical strength, it can be suitably used for, for example, automobile parts and electric or electronic parts.
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: August 24, 2004
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiro Sawada, Kunihiro Ohuchi
  • Patent number: 6774208
    Abstract: A two step method for solid state polymerization of dry crystalline thermoplastic polymers to form polymers with superior mechanical properties, first by mechanically fluidizing dry crystalline thermoplastic polymer particles in the absence of oxygen by means of blades moving through the fluidized polymer particles at velocities sufficient to heat the particles to an incipient melt temperature and maintain the temperature until solid state polymerization provides the desired molecular weight and before chemical degradation of the polymer occurs; and second by immediately quenching by application of liquefied cryogenic gases directly to the surfaces of the polymer particles in amounts sufficient to cool the particles to temperatures lower than the glass transition temperature of the polymer before crystals in the polymer aggregate into large spherulites.
    Type: Grant
    Filed: June 30, 2003
    Date of Patent: August 10, 2004
    Assignee: Agri-Nutrients Technology Group, Inc.
    Inventor: William P. Moore