Cyclic Anhydride Patents (Class 525/285)
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Patent number: 4954276Abstract: C.sub.5 -C.sub.9 lactone based adduct materials are made by reacting a C.sub.5 -C.sub.9 lactone with a polyamine, a polyol or an amino alcohol to form a lactone adduct intermediate, and thereafter reacting the intermediate with a hydrocarbyl substituted C.sub.4 -C.sub.10 monounsaturated dicarboxylic acid producing material, e.g., a polyisobutenyl succinimide, which, in turn, preferably was made by reacting a polymer of a C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a molecular weight of about 300 to 10,000 with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 0.7 to 2.0 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting adduct material are useful per se, as oil soluble dispersant additives, and are useful in fuel and lubricating oil compositions including concentrates containing the additives.Type: GrantFiled: August 31, 1989Date of Patent: September 4, 1990Assignee: Exxon Chemical Patents Inc.Inventors: Antonio Gutierrez, Robert D. Lundberg
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Patent number: 4939209Abstract: A polymer prepared by subjecting to conditions of radical graft polymerization a copolymer of an .alpha.-olefin and an aliphatic nonconjugated diene and a monomer that is capable of radical polymerization with said copolymer is described. This polymer has high miscibility with a dissimilar resin and has a high practical value for use as a compatibilizing agent in blending two or more resins.Type: GrantFiled: November 1, 1989Date of Patent: July 3, 1990Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Sadao Kitagawa, Masaki Saito, Shiroh Gotoh, Shin-ichi Yamauchi
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Patent number: 4929682Abstract: Grafting of maleic anhydride, possibly together with styrene, on olefinic polymers, carried out in the presence of radical starters, characterized in that one operates with the polymer maintained in suspension of either an aliphatic, cycloaliphatic or aromatic ketone, containing from 3 to 22 carbon atoms.Type: GrantFiled: May 6, 1988Date of Patent: May 29, 1990Assignee: Ausimont S.p.A.Inventors: Viviano Banzi, Roberto Fabbri
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Patent number: 4927888Abstract: Maleic anhydride can be satisfactorily grafted to polymers at low pressures by feeding the polymer through a multiple screw extruder and injecting the maleic anhydride and a free radical initiator into the extruder. The maleic anhydride and initiator can be pre-mixed in a solvent solution. The solvent and unreacted maleic anhydride can be removed by low pressure devolatilization. The graft copolymer has a yellowness index as measured by ASTM D-1925-70 less than about 10.0 and as measured by ASTM E-313-73 less than about 11.0. Further, between 0.75 and 2.0 weight percent of the graft copolymer comprises maleic anhydride. The graft copolymer can further be blended with an olefinic polymer to yield adhesive thermoplastics suitable for use as food packaging multilayer coextruded films.Type: GrantFiled: August 5, 1988Date of Patent: May 22, 1990Assignee: The Dow Chemical CompanyInventors: Chad A. Strait, Ricky L. Tabor, Gerald M. Lancaster
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Patent number: 4927889Abstract: A modified block copolymer composition comprising a thermoplastic polymer and a modified block copolymer consisting essentially of a base block copolymer of a monovinyl substituted aromatic hydrocarbon polymer block and an olefin compound polymer block having an ethylenic unsaturation degree not exceeding 20%, the base block copolymer having a molecular unit containing a carboxylic acid group and/or a group derived therefrom grafted thereto. The modified block copolymer composition of the present invention is a resinous composition excellent in impact resistance, adhesion, paint adhesion, weatherability, resistance to thermal deterioration, transparency and gloss or a rubbery or leather-like composition excellent in heat resistance, abrasion resistance, compression set resistance, adhesion, transparency, oil resistance, weatherability and resistance to heat aging.Type: GrantFiled: October 27, 1987Date of Patent: May 22, 1990Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Toshinori Shiraki, Fusakazu Hayano, Hideo Morita
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Patent number: 4927890Abstract: The present invention relates to a method of synthesizing a bigraft compolymer based on grafted type peracid polymer, which comprises graft polymerizing a first ethylenically unsaturated monomer containing a carboxyl group onto a polymer substrate having a form of a membrane, particulate or tube; oxidizing the carboxyl groups of the resulting graft polymer into peracids; and then graft polymerizing a second ethylenically unsaturated monomer onto the grafted chain of the graft polymer through the decomposition of the peracid. Surface profile and morphology of the bigraft copolymer membrane product is also investigated by scanning electron microscopy and transmission electron microscopy respectively.Type: GrantFiled: September 23, 1988Date of Patent: May 22, 1990Assignee: National Science CouncilInventors: Ging-Ho Hsiue, Wen-Kuei Huang
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Patent number: 4927886Abstract: Polyvinyl chloride resins are treated with a low inherent viscosity-high glass transition temperature enhancing agent to impart improved processing properties thereto, especially melt flow, which are desirable in various melt type fabrication processes such as custom injection molding. The high glass transition temperature-inherent viscosity enhancing agent is made by polymerizing one or more high glass transition temperature agent forming monomers in the presence of a chain transfer agent. The agent has a high glass transition temperature as well as a low inherent viscosity. The high glass transition temperature-inherent viscosity enhancing agent is produced as an overpolymer in a mass polymerization reaction.Type: GrantFiled: August 14, 1987Date of Patent: May 22, 1990Assignee: The B. F. Goodrich CompanyInventors: Richard H. Backderf, Frank J. Donat
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Patent number: 4925897Abstract: Polyacetylene which is modified by reaction with a dienophilic compound, preparation of the said polyacetylene and its use for the production of moldings by processing by a thermoplastic method.Type: GrantFiled: January 10, 1989Date of Patent: May 15, 1990Assignee: BASF AktiengesellschaftInventors: Herbert Naarmann, Gernot Koehler
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Patent number: 4921906Abstract: The invention relates to a process for the preparation of a thermoplastic polymer on the basis of an alkenyl aromatic monomer, an unsaturated dicarboxylic anhydride, and, optionally, a rubber, characterized in that the monomers and/or solution thereof are/is reacted in at least two reaction zones that are in open connection with each other at the top and at the bottom, the reaction mixture being circulated through the reaction zones by means of a mixing device and/or a conveying device.Using the process, a homogeneous product of constant composition is obtained.Type: GrantFiled: May 27, 1988Date of Patent: May 1, 1990Assignee: Stamicarbon B.V.Inventors: Peter J. N. Meyer, Reinard J. M. Steeman
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Patent number: 4920179Abstract: A sulfone adduct which comprises the reaction product of: ##STR1## and an unsaturated hydrocarbon polymer wherein X is an alkyl group selected from the group consisting of C.sub.n H.sub.2n +1, wherein n=1 to 18; X is an aryl group selected from the group consisting of C.sub.m H.sub.m-1 wherein m=6 and C.sub.m H.sub.m-2 Z wherein m=6 and Z is selected from the group consisting of OR', R", COOR'", NO.sub.2, Cl, Br, F and I where R', R" and R'" having about 1 to about 18 carbon atoms; wherein said unsaturated hydrocarbon polymer is selected from the group consisting of ethylene propylene terpolymers, ethylene diene copolymers, propylene diene copolymers, polyisoprene, butyl rubber, polybutadiene and styrenebutadiene, and styrene-isoprene random and block copolymers, polypropylenes and polyisobutylenes.Type: GrantFiled: March 28, 1988Date of Patent: April 24, 1990Assignee: Exxon Research and Engineering CompanyInventors: Warren A. Thaler, Stanley J. Brois, Henry K. Hall
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Patent number: 4908411Abstract: A modified ethylenic random copolymer derived from 100 parts by weight of base ethylenic random copolymer composed of 25 to 75 mole % of ethylene and 75 to 25 mole % of an alpha-olefin having 3 to 20 carbon atoms and grafted thereto, (a) 0.2 to 50 parts by weight of an unsaturated carboxylic acid having 3 to 10 carbon atoms or an anhydride or ester thereof, (b) 0.2 to 200 parts by weight of a styrene-type hydrocarbon having 8 to 12 carbon atoms, or (c) 0.2 to 300 parts by weight of an unsaturated silane compound having 2 to 20 carbon atoms, said modified ethylenic random copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of 0.01 to 1.5 dl/g and a molecular weight distribution (Mw/Mn), measured by gel permeation chromatography, of not more than 4.Type: GrantFiled: May 1, 1989Date of Patent: March 13, 1990Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tatsuo Kinoshita, Syuji Minami
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Patent number: 4888394Abstract: Stabilized, stereoregular polymers of branched, higher alpha-olefins can be modified with unsaturated silanes, carboxylic acids, and/or carboxylic acid anhydrides in the presence of a free radical generator in the polymer melt. These polymers can also contain additional additives, such as glass fibers.Type: GrantFiled: June 15, 1988Date of Patent: December 19, 1989Assignee: Phillips Petroleum CompanyInventor: Edwin Boudreaux, Jr.
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Patent number: 4888393Abstract: The invention relates to a novel low profile additive (LPA) for uncured polyester resins and the resultant molding compositions. The low profile additive is the reaction product of an ethylene/alphaolefin copolymer with a carboxylic acid or anhydride, to thereby form a non-thermoplastic carboxyl modified polyolefin. The novel LPA is a remarkably effective dimensional stabilizer and has displayed the ability to achieve net expansion in a cured polyester resin molding composition.Type: GrantFiled: May 19, 1988Date of Patent: December 19, 1989Assignee: Uniroyal Chemical Company, Inc.Inventors: Frank C. Cesare, William P. Whelan, Jr., Henno A. Petersen, Thomas S. Coolbaugh, Robert G. Davis
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Patent number: 4886858Abstract: A thermosetting resin composition comprising a special poly(p-hydroxystyrene) derivative resin and a radical polymerization initiator, and if necessary an epoxy modified polybutadiene, can provide prepregs and laminates having a low dielectric constant, a shorter signalling delay time, good heat resistance and flame retardancy and thus being suitable for producing multilayer printed circuit boards.Type: GrantFiled: February 17, 1987Date of Patent: December 12, 1989Assignee: Hitachi, Ltd.Inventors: Junichi Katagiri, Akira Nagai, Keiko Tawara, Akio Takahashi, Motoyo Wajima, Toshikazu Narahara, Ryo Hiraga
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Patent number: 4885334Abstract: A thermoplastic resin composition is described, comprising (a) a polyphenylene ether resin, (b) a polar thermoplastic resin having a polar functional group, and (c) a modified block copolymer obtained by subjecting a hydrogenated block copolymer comprising an aromatic vinyl compound polymer block (A) and a conjugated diene compound polymer block (B) to graft polymerization in the presence of a monomer having an epoxy group. The resin composition is excellent in impact resistance, solvent resistance, and compatibility among the resinous components thereof.Type: GrantFiled: November 16, 1987Date of Patent: December 5, 1989Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Junji Mayumi, Hiroshi Omori
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Patent number: 4877685Abstract: The present invention relates to a modified polyolefine which has good adhesion to metals and to polar substances. The polyolefine is admixed with or grafted to fumaric acid. The fumaric acid may be added at about 0.01-20%, preferably 0.01-1% of the polyolefine weight, while the preferred polyolefine is an ethylene copolymer.Type: GrantFiled: May 28, 1987Date of Patent: October 31, 1989Assignee: Neste OyInventors: Christer Bergstrom, Tor H. Palmgren
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Patent number: 4876313Abstract: Improved core-shell polymers having an alkali-insoluble core and an alkali-soluble shell are prepared by emulsion polymerization of the core-shell polymers utilizing compounds which chemically graft the core and shell together. The core-shell polymers exhibit improved solvent stability, water resistance, heat resistance and rheology. The polymers are useful in application such as inks, coatings and varnishes, floor polishes, leather treatment, cement formulations, and as a seed for further emulsion polymerization.Type: GrantFiled: August 29, 1986Date of Patent: October 24, 1989Assignee: Rohm and Haas CompanyInventor: Dennis P. Lorah
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Patent number: 4869963Abstract: A multilayer composite which comprises a layer of an ethylene vinylalcohol polymer tied to a thermoplastic polymer with a hydrogenated alkadiene vinyl aromatic block copolymer which is graft modified with an unsaturated acid anhydride or unsaturated dicarboxylic acid thereof.Type: GrantFiled: July 20, 1987Date of Patent: September 26, 1989Assignee: General Electric CompanyInventors: Robert R. Gallucci, Dana C. Bookbinder
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Patent number: 4866135Abstract: Polymer C.sub.5 -C.sub.9 derivatives are made by reacting a C.sub.5 -C.sub.9 lactone with an aminoalkyl derivative, e.g., N-(3-aminopropyl) morpholine, to form an adduct having a hydroxyl group on one end thereof and a tertiary amino nitrogen-containing heterocyclic ring group on the other end thereof, and then reacting the adduct with an ethylene-C.sub.3 to C.sub.28 alpha-olefin copolymer or terpolymer which has from about 0.2 to about 5 wt. % of ethylenically unsaturated carboxylic acid units grafted thereto, e.g., maleic anhydride ethylene-propylene copolymer. The resulting polymeric C.sub.5 -C.sub.9 lactone derivatives are usful per se as multifunctional oil soluble additives for fuel and lubricating oil compositions, including concentrates containing the additives.Type: GrantFiled: October 7, 1986Date of Patent: September 12, 1989Assignee: Exxon Chemical Patents Inc.Inventors: Antonio Gutierrez, Robert D. Lundberg
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Patent number: 4861841Abstract: A powder coating composition comprises a component (A) containing carboxylic acid or anhydride functionality and a component (B) containing hydroxy functionality. The components (A) and (B) are both solids at temperatures up to 50.degree. C. and at least one of them is a synthetic resin having a glass transition temperature in the range 0.degree. to 120.degree. C. The carboxylic acid or anhydride-functional component (A) is a compound or polymer containing at least two cyclic carboxylic anhydride groups per molecule or is a compound containing a moiety of the formula: ##STR1## where X is a hydrogen atom or an alkyl group, or a cyclic anhydride thereof. The hydroxy-functional component (B) contains at least two hydroxy groups per molecule and contains at least one amine group in its molecule to catalyze the reaction of the carboxylic acid or anhydride groups of component (A) with the hydroxy groups of component (B).Type: GrantFiled: July 14, 1986Date of Patent: August 29, 1989Assignee: International Paint public limited companyInventor: Alastair R. Marrion
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Patent number: 4857563Abstract: The invention provides an encapsulant composition capable of use with signal transmission devices, such as electrical or optical cable. The composition is the extended reaction product of an admixture of an anhydride functionalized composition and a crosslinking agent.Type: GrantFiled: March 9, 1987Date of Patent: August 15, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Thomas S. Croft, Hartwick A. Haugen
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Patent number: 4857600Abstract: A process for grafting an anhydride of an unsaturated aliphatic diacid onto a polyolefin comprising:(a) passing molten polyolefin through at least two injection zones connected in series;(b) injecting, under grafting conditions, a portion of a solution comprising the anhydride, an organic peroxide catalyst, and an inert organic solvent into the molten polyolefin as it passes through each injection zone, and mixing same in each injection zone until the portion is at least partially grafted onto the polyolefin; and(c) passing the grafted polyolefin, in the molten state, into a devolatilization zone, and mixing same in said zone, under devolatilization conditions, until the grafted polyolefin is essentially devolatilized.Type: GrantFiled: May 23, 1988Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Laurence H. Gross, Thorne M. Bartlett
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Patent number: 4855215Abstract: A photosetting polymer composition comprises:a base polymer comprising a denatured copolymer which is produced by reacting a copolymer of maleic anhydride and an unsaturated hydrocarbon compound with a specific aminocarboxylic acid, an alcohol or a cellosolve derivative, and a glycidyl (meth)acrylate compound under specific conditions;5-500 weight parts of a photopolymerizable monomer per 100 weight parts of the base polymer; and1-50 weight parts of a photopolymerization initiator per 100 weight parts of the base polymer.Type: GrantFiled: October 15, 1987Date of Patent: August 8, 1989Assignee: Ube Industries, Ltd.Inventors: Tsunetomo Nakano, Toshikazu Hayashi, Toshinori Tsukada
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Patent number: 4851278Abstract: An improved hot melt pressure sensitive adhesive composition comprises copolymerized monomeric acrylate or methacrylate ester of a non teritary alcohol, polar monomer such as acrylic acid, 2-polystyrylethyl methacrylate macromolecular monomer and sufficient zinc carboxylate to endow the composition with improved melt flow properties and cohesive strength. The invention also provides adhesive coated sheet materials comprising the adhesive composition coated onto a flexible sheet.Type: GrantFiled: February 25, 1988Date of Patent: July 25, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventor: Rudyard M. Enanoza
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Patent number: 4845155Abstract: A composition of matter which comprises an elastomer grafted at a level of from about 40 to about 60 weight percent with a polymer matrix comprising recurring units of at least one free radical polymerizable monomer and its method of preparation are disclosed.Type: GrantFiled: April 30, 1987Date of Patent: July 4, 1989Assignee: Arco Chemical Technology, Inc.Inventor: Barry D. Dean
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Patent number: 4839437Abstract: A composition comprising a blend of a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon and an at least partially crystalline polyamide polymer having a number average molecular weight of at least 5,000, a process for making the blend, and articles prepared thereof.Type: GrantFiled: April 29, 1988Date of Patent: June 13, 1989Assignee: Shell Oil CompanyInventors: William P. Gergen, Robert G. Lutz
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Patent number: 4835220Abstract: Block polymers of vinylaromatic compounds and conjugated dienes which possess acidic terminal groups, are present in the form of lithium salts and form an aluminum complex. A process for the preparation of such complexes and the use of these block polymer complexes as molding materials and for modifying thermoplastic materials.Type: GrantFiled: October 24, 1986Date of Patent: May 30, 1989Assignee: BASF AktiengesellschaftInventors: Klaus Bronstert, Karl Gerberding, Helmut Jenne
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Patent number: 4833208Abstract: Composite acrylic resin particles prepared by effecting an emulsion polymerization of a monomer mixture of(A) at least one crosslinking monomer having in its molecule two or more radically polymerizable mono- or 1,1-di-substituted ethylenic unsaturation bonds, or a combination of at least two monomers each having a mutually reactive functional group and one or more radically polymerizable mono- or 1,1-di-substituted ethylenic unsaturation bonds,(B) at least one mono-functional polymerizable monomer other than an aromatic compound, and(C) at least one monomer having in its molecule one or more radically polymerizable mono- or 1,1-di-substituted ethylenic unsaturation bonds and one or more radically polymerizable 1,2-di-, 1,1,2-tri- or 1,1,2,2-tetra-substituted ethylenic unsaturation bonds, and graft-polymerizing thus obtained particles with a polymerizable aromatic compound and other optional mono-functional monomers.Type: GrantFiled: April 20, 1987Date of Patent: May 23, 1989Assignee: Nippon Paint Co., Ltd.Inventors: Tadafumi Miyazono, Akio Kashihara, Shinichi Ishikura
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Patent number: 4822688Abstract: Adhesive composition consisting essentially of polypropylene modified by grafting with an acid anhydride to further reacted with a compound bearing at least two groups capable of reacting with the anhydride preferrably a polyol or a polyamine.Type: GrantFiled: June 19, 1987Date of Patent: April 18, 1989Inventor: Pierre Nogues
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Patent number: 4820773Abstract: Improved water-absorbing, crosslinked acrylate resins are prepared by aqueous polymerization of (A) acrylic acid neutralized 70 to 100 mole percent for example with ammonia and/or caustic alkali and/or an amine; with (B) acrylamide in a mole ratio of 70 to 100 mole percent (A) to 30:0 mole percent (B); and (C) a water miscible or a water soluble polyvinyl monomer in the presence of (D) a styrene-maleic anhydride copolymer, neutralized 70 to 100 mole percent for example with ammonia, and/or caustic alkali and/or an amine, in an amount of 1% to 25% based on the weight of acrylic acid or acrylate, such that the amount of (C) is 0.001 to 0.6 weight percent based on the total weight of (A), (B), (C) and (D). In addition, surface treating the water-absorbing crosslinked acrylate resins with a polyquaternary amine substantially further increases both the rate of water absorption and the quantity of water absorbed and retained by the resin.Type: GrantFiled: June 25, 1987Date of Patent: April 11, 1989Assignee: American Colloid CompanyInventors: William Alexander, Mark Anderson, Barbara R. Regan
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Patent number: 4816515Abstract: Compositions with enhanced impact strength, solvent and thermal aging resistance are prepared by interpolymerizing polyphenylene ether resins functionalized with acids or anhydrides, e.g., fumaric acid, and rubbers, e.g., EPDM rubbers, grafted with glycidyl acrylates or methacrylates.Type: GrantFiled: April 13, 1987Date of Patent: March 28, 1989Assignee: General Electric CompanyInventor: Kurt A. Weiss
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Patent number: 4816520Abstract: The terminally functionalized polymers are prepared from living polymers obtained by anionic polymerization of olefinically unsaturated monomers by reacting the living polymers first with capping reagents comprising nitrogen compounds of the general formulae I to VII: ##STR1## where R.sup.1 and R.sup.4 are each H, alkyl cycloalkyl or aryl, R.sup.2, R.sup.3 and R.sup.5 are each alkyl, cycloalkyl or aryl and A is a substituted or unsubstituted bridge which, in addition to the C members, can also contain N or O members and ##STR2## where R.sup.6 and R.sup.7 are each alkyl or aryl, A is a single-membered substituted or unsubstituted carbon bridge and B is a 2- to 12-membered bridge of which at least those members adjacent to the nitrogen atom comprise --C(R.sup.8, R.sup.9) radicals, where R.sup.8 and R.sup.9 can be identical or different and are H, alkyl, cycloalkyl or aryl, and the nonadjacent members can be not only --C(R.sup.8, R.sup.Type: GrantFiled: November 12, 1987Date of Patent: March 28, 1989Assignee: Basf AktiengesellschaftInventor: Klaus Bronstert
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Patent number: 4814387Abstract: Various fabrication properties of polyvinyl chloride are improved such as melt flow by treating the polyvinyl chloride resin with a low inherent viscosity-high glass transition temperature enhancing agent. The treatment occurs as a suspension overpolymerization on the polyvinyl chloride resin by reacting at least one high glass transition temperature enhancing agent with at least one substantially water insoluble chain transfer agent. The formed high glass transition temperature-low inherent viscosity agent imparts a high glass transition temperature to the polyvinyl chloride resin and also reduces the inherent viscosity to a level below the inherent viscosity formed by the combined effect of the polyvinyl chloride resin and the glass transition temperature agent.Type: GrantFiled: August 14, 1987Date of Patent: March 21, 1989Assignee: The B. F. Goodrich CompanyInventor: Frank J. Donat
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Patent number: 4810755Abstract: An adhesive resin composition useful for bonding a resin having gas barrier properties and a hydrophobic thermoplastic resin which comprises an ethylene-acrylate or methacrylate copolymer grafted with an ethylenic unsaturated carboxylic acid or its acid anhydride; and 0.02 to 0.6 equivalent to the ethylenic unsaturated carboxylic acid or its acid anhydride of a periodic table group Ia or IIa metal hydroxide, or said metal hydroxide and an ethylene-acrylate or methacrylate copolymer. A laminated material of a resin having gas barrier properties and a hydrophobic thermoplastic resin laminated with the adhesive resin composition and a resin composition comprising the adhesive resin composition, a resin having gas barrier properties and a hydrophobic thermoplastic resin are also disclosed.Type: GrantFiled: February 12, 1987Date of Patent: March 7, 1989Assignees: Kuraray Co., Ltd., Nippon Petrochemical Co., Ltd.Inventors: Toshiyuki Akazawa, Takuji Okaya, Takashi Inoue, Toshitaka Kobayashi
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Patent number: 4806581Abstract: Graft polymers are prepared by reacting an ethylenically unsaturated polymerizable monomer with a polymer of an olefin of 2 to about 8 carbon atoms in a process wherein the olefin polymer is substantially insoluble in the monomer but is capable of absorbing the monomer. In a preferred aspect, a vinyl halide polyolefin graft polymer is produced by reacting a solid polyolefin particle with a vinyl halide monomer in which the polyolefin is substantially insoluble, but is capable of absorbing the monomer. The solid particles can be contacted with the monomer in one step or in stages. When the stage-wise reaction is continued until the proportion of polyolefin in the polymer product is about 2 to about 20 weight percent, the resulting product can be formed to a transparent or translucent article.Type: GrantFiled: March 10, 1987Date of Patent: February 21, 1989Assignee: Occidental Chemical CorporationInventor: Leigh E. Walker
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Patent number: 4806381Abstract: Oligomeric or prepolymeric organic compounds that contain both polymerizable unsaturated groups and acid radicals, their salts, or their reactive-derivative radicals. The compounds exhibit outstanding adhesion properties, especially to biological substrates, and are appropriate for application as bonding agents, adhesive filling materials, or adhesive cements in the fields of dentistry and medicine.Type: GrantFiled: October 8, 1986Date of Patent: February 21, 1989Assignee: Ernst Muhlbauer KGInventors: Jurgen Engelbrecht, Helmut von Wallis, Michael Gunther
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Patent number: 4800216Abstract: The invention relates to ABS molding compositions having a markedly reduced residual butadiene content, even at high processing temperatures.Type: GrantFiled: November 2, 1987Date of Patent: January 24, 1989Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Alfred Pischtschan
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Patent number: 4795785Abstract: A coating resin composition comprising a chlorinated polyolefin-containing polymer obtained by polymerizing a monomer blend containing 0.01 to 5% by weight of an unsaturated organic silane compound in the presence of a chlorinated polyolefin resin having a chlorine content of 50% by weight or less can yield molded articles or coatings excellent in adhesiveness, gloss, resistance to gasoline, resistance to alcohol, or the like.Type: GrantFiled: December 3, 1986Date of Patent: January 3, 1989Assignee: Hitachi Chemical Company, Ltd.Inventors: Toshihiko Ito, Masayuki Mogami, Kengo Kobayashi
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Patent number: 4795792Abstract: A copolymer of an olefin and maleic anhydride is produced in the form of particles by co-polymerizing an olefin having 2 to 8 carbon atoms with maleic anhydride in a solvent capable of dissolving both co-monomers, but incapable of dissolving the copolymer in the presence of a dispersant of an oil-soluble, cationic copolymer comprising (a) ethylenically unsaturated monomer units having cationic groups of a quaternary ammonium salt and (b) lipophilic, ethylenically unsaturated monomer units.Type: GrantFiled: April 28, 1988Date of Patent: January 3, 1989Assignee: Kao CorporationInventors: Shoji Ohtani, Yoshiyuki Muroi, Rikio Tsushima
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Patent number: 4789568Abstract: An organic solvent-type coating composition comprising as a main film-forming component a modified polyolefin composed of an adduct of a monoepoxy compound with an polyolefin having maleic acid or its anhydride grafted thereto, and a method of coating a plastic material using the coating composition.Type: GrantFiled: April 13, 1987Date of Patent: December 6, 1988Assignee: Kansai Paint Co., Ltd., a Japanese Corp.Inventors: Takao Matoba, Osamu Iwase, Tuguo Nezu, Shinji Sugiura
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Patent number: 4788264Abstract: A method of preparing a modified polyethylene which comprises melt kneading 100 parts by weight of (A) a high density polyethylene having a branching degree of not more than 5 per 1,000 carbon atoms of principal chain, from 0.2 to 3 parts by weight of (B) an unsaturated carboxylic acid or a derivative thereof, and from 0.01 to 0.5 part by weight of (C) an organic peroxide, the weight ratio of (C) to (B), (C)/(B), being from 0.01 to 0.5.The modified polyethylenes obtained by the use of the method of the present invention not only have excellent heat resistance, moldability, and so forth, but also are extremely improved in their adhesion property, especially in the property of adhering to a saponified ethylene-vinyl acetate copolymer, a polyamide resin, and a polyester resin, and therefore the modified polyethylenes can be advantageously used with these materials for the production of laminated boards.Type: GrantFiled: January 22, 1988Date of Patent: November 29, 1988Assignee: Idemitsu Petrochemical Co., Ltd.Inventor: Mamoru Ukita
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Patent number: 4780509Abstract: Impact-resistant thermoplastic molding materials based on a resin A containing one or more vinylaromatic monomers are prepared by reacting the resin A (component A) with one or more monomers from the group consisting of the .alpha.,.beta.-unsaturated dicarbonyl compounds (component B) by a process in which the reaction is carried out in a melt of A in the presence of B and in the absence of initiators, and the resin A used is one which contains from 3 to 50% by weight, based on A, of one or more elastomers a.sub.1 (rubber) and has been prepared in a conventional manner by polymerizing one or more vinylaromatic monomers of 8 to 12 carbon atoms in the presence of the elastomer a.sub.1 are used for the production of moldings.Type: GrantFiled: April 28, 1987Date of Patent: October 25, 1988Assignee: BASF AktiegesellschaftInventors: Christof Taubitz, Erhard Seiler, Lothar Schlemmer
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Patent number: 4762890Abstract: Maleic anhydride can be satisfactorily grafted to polymers at low pressures by feeding the polymer through a co-rotating, twin-screw extruder and injecting the maleic anhydride and a free radical initiator into the extruder. The maleic anhydride and initiator can be pre-mixed in a solvent solution. The solvent and unreacted maleic anhydride can be removed by low pressure devolatilization.Type: GrantFiled: September 5, 1986Date of Patent: August 9, 1988Assignee: The Dow Chemical CompanyInventors: Chad A. Strait, Gerald M. Lancaster, Ricky L. Tabor
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Patent number: 4762882Abstract: A modified polyolefin resin and a composition containing therein such modified polyolefin, having excellent adhesive property and heat-sealing property at the time of high speed forming operations, the modified polyolefin resin consisting essentially of: a copolymer of ethylene and .alpha.-olefin having 4 or more carbon atoms, the copolymer having a density in a range of from 0.890 to 0.910 g/cm.sup.3, a ratio of a weight-average molecular weight (Mw) to a number-average molecular weight (Mn) of Mw/Mn=2 to 15, and a product of a melt tension (g) and a melt-index (g/10 min.) of a molten resin measured at 160.degree. C. of 4 or below; and unsaturated carboxylic acid or derivatives thereof grafted on the ethylene type copolymer at a ratio of from 0.01 to 3% by weight.Type: GrantFiled: June 26, 1986Date of Patent: August 9, 1988Assignee: Mitsubishi Chemical Industries LimitedInventors: Shigeaki Okano, Katsuhiko Hayashi, Yoshiteru Sakurazawa, Yoshinori Suga
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Patent number: 4755553Abstract: A primer composition composed of 1 to 100 parts by weight of a chlorinated carboxyl group-containing .alpha.-olefin polymer and 100 parts by weight of an organic solvent therefor, the improvement wherein(i) said chlorinated carboxyl group-containing .alpha.-olefin polymer is a post-chlorination product [C] of a graft-modified propylene polymer [B] having a chlorine content of 10 to 35% by weight, said graft-modified propylene polymer [B] having an acid value of 6 to 187 mg-KOH/g-polymer and obtained by grafting an unsaturated dicarboxylic acid anhydride to a propylene polymer [A] having an intrinsic viscosity [.eta.], determined at 135.degree. C. in decalin, of 0.6 to 10 dl/g and comprising 70 to 100 mole % of propylene and 0 to 30 mole % of an .alpha.-olefin other than propylene, and(ii) said solvent is an organic solvent boiling at about 60.degree. to about 200.degree. C.Type: GrantFiled: October 23, 1986Date of Patent: July 5, 1988Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kotaro Kishimura, Riichiro Nagano
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Patent number: 4753997Abstract: A method of grafting maleic anhydride or maleic anhydride/styrene onto a polyolefin, in particular polypropylene comprising mixing maleic anhydride or maleic anhydride-styrene/styrene homologue with the polyolefin in the presence of a catalyst having the formula: ##STR1## wherein X=S, O or N;R.sub.1 and R.sub.2 =an alkyl group, for example C.sub.1 -C.sub.14 or higher;R=H or ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 equal H, an alkyl group, (CH.sub.2).sub.n COOH, or mixtures thereof; andn=1 to about 6.Type: GrantFiled: November 27, 1985Date of Patent: June 28, 1988Assignee: The Standard Oil CompanyInventors: Wen B. Shyu, David A. Woodhead
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Patent number: 4753998Abstract: Unique Diels-Alder adducts of an activated olefin and an alloocimene polymer containing pendant conjugated double bonds were prepared. These adducts are useful as binders in adhesive, printing ink and coating formulations.Type: GrantFiled: June 30, 1986Date of Patent: June 28, 1988Assignee: Union Camp CorporationInventors: Kathryn S. Hayes, Charles R. Frihart, Richard L. Veazey
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Patent number: 4751270Abstract: A maleic acid-modified polyolefin prepared by graft polymerization of maleic anhydride to polyolefin in the presence of a compound having the formula (I): ##STR1## in which each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently an alkyl group having 1-6 carbon atoms; and each of X and Y is independently any one of the hydrogen atom, an alkyl group having 1-6 carbon atoms and a halogen atom. A process for the preparation of said maleic acid-modified polyolefin is also disclosed.Type: GrantFiled: May 30, 1986Date of Patent: June 14, 1988Assignee: Ube Industries, Ltd.Inventors: Shotaro Urawa, Keiichi Nagata, Noboru Yamaguchi
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Patent number: 4749747Abstract: A process for the production of a nonaqueous stable emulsion feedstock comprising a rubber, a block copolymer having at least one component miscible with the rubber and at least one component miscible with the monomer, and at least two unsaturated organic monomers capable of free radical polymerization is disclosed. At least one of the monomers must be miscible with the rubber and the mixture of the monomers is substantially a nonsolvent for the rubber. The block copolymer maintains the rubber or rubber-rich particles in emulsified form within the mixture of monomers. In general, the process comprises (1) mixing the rubber, block copolymer and at least a portion of the rubber miscible monomers to form a first nonaqueous solution, (2) mixing the remaining monomers and the remaining portion of the rubber miscible monomers to form a second solution, and (3) combining the two solutions to form the nonaqueous stable emulsion feedstock.Type: GrantFiled: August 28, 1987Date of Patent: June 7, 1988Assignee: The Standard Oil CompanyInventors: Wen B. Shyu, David A. Woodhead, Vincent P. Quigley
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Patent number: 4749505Abstract: Olefin polymers are degraded in molecular weight in the presence of a free radical initiator under an inert blanket. The degradation preferably is carried out under high shearing stress and/or a high temperature in order to increase the degradation. The degradation may be separate from, overlap, or occur simultaneously with further derivatization of the polymer.Type: GrantFiled: July 8, 1985Date of Patent: June 7, 1988Assignee: Exxon Chemical Patents Inc.Inventors: David Y. Chung, John E. Johnston