Polymer Derived From Acrylic Or Methacrylic Acids, Acid Halides Or Salt Monomers Patents (Class 525/329.7)
  • Patent number: 8487048
    Abstract: Objects of the present invention are: to provide a water-absorbent resin which exhibits excellent balances between water absorption performances; and further to provide a process by which a water-absorbent resin having excellent absorption properties can be produced even if no hydrophilic organic solvent is used, or even if its amount is extremely reduced, when carrying out the surface-crosslinking treatment; and further to provide a water-absorbent resin optimum to absorbent articles such as diapers.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: July 16, 2013
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Masatoshi Nakamura, Kazuki Kimura, Kunihiko Ishizaki
  • Publication number: 20130177807
    Abstract: A binder for an electrode of a lithium battery, and a lithium battery containing the binder. The binder includes: a carbon nanotube; and a polymer chemically bonded to the carbon nanotube, and thus may form a conducting path by improving dispersion of the carbon nanotube. Accordingly, the binder may have high capacity and improve the lifetime of the lithium battery.
    Type: Application
    Filed: August 29, 2012
    Publication date: July 11, 2013
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Beom-Wook LEE, Hye-Sun JEONG, Hye-Ran LEE
  • Publication number: 20130171066
    Abstract: The present invention relates to the preparation and use of polymer complements to ?-amyloid peptides (A?) for detecting soluble or aggregated A? in fluid samples or for treating a subject having a neurodegenerative disease.
    Type: Application
    Filed: July 25, 2011
    Publication date: July 4, 2013
    Inventors: Boerje Sellergren, Carla Sofia Antunes Aureliano, Javier Urraca Ruiz, Eric Schillinger
  • Patent number: 8470510
    Abstract: A polymer for lithographic purposes has at least a repeating structural unit represented by following General Formula (I). In Formula (I), R1, R3, R4, and R6 each independently represent hydrogen atom, a halogen atom, cyano group, an alkyl group, or a haloalkyl group; R2 and R5 each independently represent hydrogen atom, cyano group, etc.; X1 and X2 each independently represent single bond, or a substituted or unsubstituted bivalent alkylene, alkenylene, or cycloalkylene group, etc.; X3 and X4 each independently represent single bond or —CO—; R7, R8, R9, and R10 each independently represent hydrogen atom, an alkyl group, or a cycloalkyl group. The polymer for lithographic purposes shows good balance between line edge roughness (LER) and etching resistance and allows very fine and uniform patterning.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: June 25, 2013
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Arimichi Okumura, Keizo Inoue, Kazuki Okamoto
  • Patent number: 8450428
    Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, which comprises thermal postcrosslinking in the presence of steam.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: May 28, 2013
    Assignee: BASF SE
    Inventors: Thomas Daniel, Marco Krüger, Karin Flore, Stefan Blei, Uwe Stueven, Norbert Herfert, Michael A. Mitchell
  • Patent number: 8420164
    Abstract: The present invention relates to a solid type rubber-based pressure-sensitive adhesive composition, which is prepared by adding a tackifier, a softener, and an isocyanate-based crosslinking agent reactable with active hydrogen into an acrylic rubber containing a monomer having an active hydrogen-containing functional group as a copolymerization component to thereby obtain a solventless and nonaqueous pressure-sensitive adhesive composition, and particularly it relates to a solid type rubber-based pressure-sensitive adhesive composition having the above-mentioned constitution, in which the above-mentioned acrylic rubber includes a copolymer containing butyl acrylate as a main component, and as the copolymerization component a monomer having a hydroxyl group or a carboxyl group as the active hydrogen-containing functional group.
    Type: Grant
    Filed: July 2, 2007
    Date of Patent: April 16, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Tomoo Yamaguchi, Yasunobu Ina, Tomoaki Uchiyama, Minoru Yagi
  • Publication number: 20130090432
    Abstract: A process for the preparation of alkoxylated polymers comprising the steps (i) preparation of a polymeric product (I) having at least one functional group by radical copolymerization in a high temperature polymerization process and (ii) contacting the polymeric product (I) having at least one functional group obtained in step (i) with at least one alkylene oxide; an alkoxylated polymer obtainable by the process of the present invention; a process for preparing polyurethanes by reaction of the alkoxylated polymer according to the present invention; polyurethane prepared by the process of the present invention; surface active reagents comprising or consisting of the alkoxylated polymer according to the present invention as well as detergent formulations comprising at least one alkoxylated polymer according to the present invention.
    Type: Application
    Filed: September 29, 2010
    Publication date: April 11, 2013
    Applicant: BASF SE
    Inventors: Andreas Kunst, Daniel Freidank, Marco A. Villalobos
  • Patent number: 8410223
    Abstract: There is provided a production method for a water-absorbing resin for stably and continuously producing the water-absorbing resin with industrially high property, in particular, the water-absorbing resin with high liquid permeation. A method of the present invention relates to a production method for a water-absorbing resin including: a polymerization step of an aqueous solution of an unsaturated monomer; a drying step of the resultant hydrogel polymer; and a surface cross-linking step after drying; characterized by including a pneumatic transportation step for pneumatic transporting the water-absorbing resin powder substance in a pipeline with a surface roughness (Rz) of the inner surface of equal to or smaller than 800 nm, by using gas with a dew point of ?5° C. to ?100° C.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: April 2, 2013
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Koji Matsumoto, Kozo Nogi, Kunihiko Ishizaki
  • Patent number: 8410222
    Abstract: A process for producing water-absorbing polymer particles, comprising polymerization, drying, comminution, classification and recycling of the undersize obtained in the classification, wherein the recycled undersize is coated with a reducing agent and/or inorganic particles.
    Type: Grant
    Filed: July 3, 2009
    Date of Patent: April 2, 2013
    Assignee: BASF SE
    Inventors: Rüdiger Funk, Matthias Weismantel, Sylvia Bertha
  • Patent number: 8404783
    Abstract: The invention relates to novel crosslinkable copolymers which are obtainable by (a) copolymerizing at least two different hydrophilic monomers selected from the group consisting of N,N-dimethyl acrylamide (DMA), 2-hydroxyethyl acrylate (HEA), glycidyl methacrylate (GMA), N-vinylpyrrolidone (NVP), acrylic acid (AA) and a C1-C4-alkoxy polyethylene glycol (meth)acrylate having a weight average molecular weight of from 200 to 1500, and at least one crosslinker comprising two or more ethylenically unsaturated double bonds in the presence of a chain transfer agent having a functional group; and (b) reacting one or more functional groups of the resulting copolymer with an organic compound having an ethylenically unsaturated group.
    Type: Grant
    Filed: July 10, 2007
    Date of Patent: March 26, 2013
    Assignee: Novartis AG
    Inventors: Frank Chang, Norberto Arturo Medina
  • Publication number: 20130066019
    Abstract: A method of enhancing and stabilizing the physical property (for example, liquid permeability) of a water absorbent resin by means of a simple technique without requiring any alteration of the raw materials or high capital investment, is provided. Disclosed is a method for producing a water absorbent resin, which includes a polymerization step of polymerizing an aqueous solution of acrylic acid (salt) to obtain a water-containing gel-like crosslinked polymer; a drying step of drying the water-containing gel-like crosslinked polymer, to obtain a water absorbent resin powder; a classification step of classifying the water absorbent resin powder; and a surface crosslinking step of surface crosslinking the water absorbent resin powder, wherein in the classification step that is carried out before the surface crosslinking step and/or after the surface crosslinking step, a tapping material is installed below the metal sieve mesh used in the classification step, and thereby classification is carried out.
    Type: Application
    Filed: March 17, 2011
    Publication date: March 14, 2013
    Applicant: Nippon Shokubai Co., Ltd.
    Inventors: Sumio Okuda, Syuji Kanzaki, Kunihiko Ishizaki, Shinichi Fujino, Kozo Nogi
  • Publication number: 20130066007
    Abstract: A terminally unsaturated polyolefin satisfying the following (1) to (4): (1) the mesopentad fraction [mmmm] of propylene chain unit or butene-1 chain unit is 20 to 80 mol %; (2) the number of terminal vinylidene groups per molecule is 1.3 to 2.5; (3) the weight-average molecular weight Mw is 500 to 100,000; and (4) the molecular weight distribution Mw/Mn is 1.1 to 2.6.
    Type: Application
    Filed: May 17, 2011
    Publication date: March 14, 2013
    Applicant: IDEMITSU KOSAN CO., LTD.
    Inventors: Shuji Machida, Tomio Tatsumi, Takenori Fujimura
  • Patent number: 8394895
    Abstract: A process for continuous thermal postcrosslinking of water-absorbing polymer particles, wherein the postcrosslinker is applied to the water-absorbing polymer particles by means of suitable nozzles and the nozzles are exchanged or cleaned via the interior of a glovebox adjoining the plant section comprising the nozzle.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: March 12, 2013
    Assignee: BASF SE
    Inventors: Oskar Stephan, Karl J. Possemiers, Ann Becker, Leo Van Miert, Ronny De Kaey
  • Patent number: 8389658
    Abstract: A process for preparing postcrosslinked water-absorbing polymer beads with high absorption by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, wherein the solids content of the monomer solution is at least 35% by weight and the polymer beads have a mean diameter of at least 150 ?m.
    Type: Grant
    Filed: February 10, 2012
    Date of Patent: March 5, 2013
    Assignee: BASF SE
    Inventors: Uwe Stueven, Matthias Weismantel, Wilfried Heide, Marco Krüger, Volker Seidl, Stefan Blei, Dennis Lösch, Rüdiger Funk, Annemarie Hillebrecht
  • Patent number: 8367772
    Abstract: A crosslinked aramid polymer comprising a first aramid backbone which is crosslinked through a poly(meth)acrylic acid with a second aramid backbone. The crosslinked aramid polymer is obtained by polymerizing a monomeric aromatic diamine with a monomeric aromatic diacid, or halide or ester thereof in the presence of poly(meth)acrylic acid, followed by a curing step. The crosslinked aramid polymer is crosslinked through its amide bonds and can be made to a fiber, film or fibrid.
    Type: Grant
    Filed: April 22, 2009
    Date of Patent: February 5, 2013
    Assignee: Teijin Aramid B.V.
    Inventors: Johannes Bos, Wilhelmus Hendrikus Johannes Nijenhuis
  • Patent number: 8362154
    Abstract: A novel process for the metathetic degradation of nitrile rubbers is provided which uses specific transition metal complex catalysts showing an increased activity.
    Type: Grant
    Filed: August 13, 2008
    Date of Patent: January 29, 2013
    Assignee: LANXESS Deutschland GmbH
    Inventors: Christopher Ong, Werner Obrecht, Oskar Nuyken, Julia Maria Muller
  • Patent number: 8349621
    Abstract: A ligand molecule-immobilized polymer has a structure represented by the following general formula (1). In the general formula (1), R1 represents a ligand molecule-containing group, R2 represents a hydrophobic group, R3 represents a spacer site, R4 represents a hydrophilic group, R5 represents a group having charge, a to d specify a composition ratio and each represent an integer of 1 or more, and n and m specify chain lengths and represent integers satisfying the relationships of 1?n(a+b+c+d)?10,000 and 1?m?350.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: January 8, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventor: Kousuke Mukumoto
  • Patent number: 8349962
    Abstract: A pre-adhesive composition is described comprising an acid-functional (meth)acrylate copolymer and an acylaziridine crosslinking agent, which when crosslinked provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles.
    Type: Grant
    Filed: October 6, 2011
    Date of Patent: January 8, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: Belma Erdogan, Timothy D. Filiatrault, Maureen A. Kavanagh, Larry R. Krepski, Babu N. Gaddam
  • Patent number: 8344085
    Abstract: The present invention provides a novel polymer, and a mixture and a cement admixture thereof. The cement admixture has higher dispersibility compared to the previous ones. The novel polymer of the present invention has a different structure from the conventional copolymers used for cement admixtures, using an unsaturated carboxylic acid monomer and an unsaturated polyalkylene glycol monomer as the monomer components. The novel polymer of the present invention basically contains a polyalkylene glycol chain and a polymer segment bonded to the chain. Another type of the novel polymer of the present invention contains two polyalkylene glycol chains and a polymer segment connecting the chains. In these polymers, at least one of unsaturated monomers constituting the polymer segment is an unsaturated carboxylic acid monomer or an unsaturated polyalkylene glycol monomer. The cement admixture of the present invention comprises a polymer, made from these monomers, or a mixture thereof.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: January 1, 2013
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Tsutomu Yuasa, Noboru Sakamoto, Yuko Matsuda
  • Publication number: 20120329953
    Abstract: The present invention is to provide a drying method by which both cost reduction and superior physical properties can be attained in a step which comprises subjecting a water-containing gel-like crosslinked polymer obtained by polymerizing an aqueous monomer solution to fine granulation during or after the polymerization, and drying the resultant particulate water-containing gel-like crosslinked polymer with a through-circulation band dryer. The method has a feature in that the drying conditions over a period from a time of introducing the particulate water-containing gel-like crosslinked polymer into a drying zone of the through-circulation band dryer to a time of reaching a solid content concentration thereof to 80% by weight, satisfy that (1) a difference of temperature between a temperature of hot air blown to a particulate hydrogel layer and a temperature measured after the hot air passes through the particulate hydrogel layer is 20 to 70° C.
    Type: Application
    Filed: March 7, 2011
    Publication date: December 27, 2012
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventor: Yoshio Irie
  • Patent number: 8318865
    Abstract: The present invention is a method of manufacturing an eye lens material having a process in which a phosphorylcholine group-containing chemical compound represented by the following formula (1) is reacted and covalently bonded to the surface of an eye lens material having hydroxyl groups wherein the chemical compound represented by the following formula (2) is reacted and covalently bonded through ester-bonding to the eye lens material in an organic solvent. The object of the present invention is to provide an eye lens material that prevents protein adsorption and a method of manufacturing thereof.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: November 27, 2012
    Assignees: Shiseido Company, Ltd., Kazuhiko Ishihara
    Inventors: Yukimitsu Suda, Kazuyuki Miyazawa, Kazuhiko Ishihara
  • Patent number: 8318895
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: August 2, 2012
    Date of Patent: November 27, 2012
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 8314186
    Abstract: An adhesive composition for use in bonding of a polarizing plate is prepared from acrylic-based polymer graft-polymerized and modified by a reactive silane coupling agent with a specific grafting position and an ordinary cross-linking agent. Compared with unmodified acrylic-based copolymers, the adhesive composition thus synthesized demonstrates high adhesion property, cohesion property, elasticity property and high durability and, when used in bonding of the polarizing plate, flexibly follows dimensional changes of the polarizing plate in a high-temperature high-humidity atmosphere, alleviates the phenomenon where the polarizing plate demonstrates uneven distribution of residual stress due to dimensional changes of the polarizing plate, and prevents light leakage and uneven color which might otherwise occur to the polarizing plate due to the aging, cracking, or peeling of a conventional adhesive.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: November 20, 2012
    Assignee: Nan Ya Plastics Corporation
    Inventors: Dein-Run Fung, Sen-Huang Hsu, Hung-Hsun Wu, Huei-Jiun Juang
  • Patent number: 8309682
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: November 13, 2012
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Publication number: 20120283379
    Abstract: What is provided includes a nanoparticle of porous silica, incorporating at least one molecule of interest, the silica network inside said nanoparticle being functionalized by at least one group capable of setting up an ionic and/or hydrogen non-covalent bond with the molecule of interest, whereby the molecule(s) of interest is(are) linked to the silica network solely by non-covalent bonds. In addition, a method for preparing said silica particle and uses thereof is provided.
    Type: Application
    Filed: November 10, 2010
    Publication date: November 8, 2012
    Applicant: Commissariat a l'energie atomique et aux energies alternatives
    Inventors: Aurélien Auger, Olivier Raccurt, Olivier Jean Christian Poncelet, Jorice Samuel, Sylvie Sauvaigo, Chloé Schubert
  • Patent number: 8293845
    Abstract: A method for increasing the efficacy of hydrophobically modified (meth)acrylic based polymers to increase the critical micelle concentration of a surfactant composition by attenuating the degree of neutralization (DN) of the polymer is disclosed.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: October 23, 2012
    Inventors: Krishnan Tamareselvy, William F. Masler, III, Deborah S. Filla, Gary Gray
  • Patent number: 8273836
    Abstract: A process for producing water-absorbing polymer particles, wherein a product stream comprising water-absorbing polymer particles is tested for nonferritic metallic impurities by means of an eddy current detector.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: September 25, 2012
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Rüdiger Funk, Dominicus van Esbroeck
  • Publication number: 20120238705
    Abstract: Provided are resin particles having an inorganic dispersing agent adhering to their surfaces and having a volume mean particle diameter of 1 to 1000 ?m. The amount of the inorganic dispersing agent adhering to the resin particle surfaces is in the range of 0.0001 to 0.02 g/m2, said amount being determined by the following equation (I): Amount of inorganic dispersing agent adhering to resin particle surfaces=(amount of inorganic dispersing agent (part(s) by weight)/amount of polymerizable monomer (part(s) by weight))/resin particle specific surface area as measured by Mastersizer 2000 manufactured by Malvern Instruments Ltd. (I) (wherein the amount of the inorganic dispersing agent and the amount of the polymerizable monomer in the right-hand member of the equation (I) are each an amount introduced in the production of resin particles, and the amount of the polymerizable monomer is 100 parts by weight).
    Type: Application
    Filed: November 17, 2010
    Publication date: September 20, 2012
    Applicant: Soken Chemical & Engineering Co., Ltd.
    Inventor: Toshio Sekiya
  • Patent number: 8263711
    Abstract: Described is a pre-adhesive, curable composition comprising an acid-functional (meth)acrylate copolymer and a novel (meth)acryloyl-aziridine crosslinking agent, which when crosslinked provides a pressure-sensitive adhesive composition.
    Type: Grant
    Filed: August 4, 2010
    Date of Patent: September 11, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Larry R. Krepski, Peiwang Zhu, Belma Erdogan-Haug, Wen Jie Zhang, Dang Xie, Maureen A. Kavanagh, Marie Aloshyna ep Lesuffleur, Babu Gaddam, Qing Wu
  • Patent number: 8258223
    Abstract: The invention concerns a process for producing water-absorbing polymer, which comprises a base polymer A being mixed with a first aqueous solution B of at least one surface postcrosslinker and a second aqueous solution C of at least one polyvalent cation and thermally treated, wherein said base polymer A is based on at least 50% neutralized acid-functional monomer and said solutions B and C are metered wholly or partly concurrently through separate nozzles whereby a water-absorbing polymer having a high saline flow conductivity value is obtained.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: September 4, 2012
    Assignee: BASF SE
    Inventors: Ulrich Riegel, Thomas Daniel, Matthias Weismantel, Mark Elliott, Dieter Hermeling
  • Patent number: 8252848
    Abstract: A method for re-mobilizing superabsorbent polymer particles which have previously been immobilized by a solidified thermoplastic composition comprising at least 30 weight-% of a thermoplastic polymer. The superabsorbent polymer particles are separated from the solidified thermoplastic composition by using a supercritical fluid comprising carbon dioxide, propane, or mixtures thereof. Separation may be further improved by the use of one or more co-solvents.
    Type: Grant
    Filed: February 25, 2011
    Date of Patent: August 28, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Carsten Luckert, Marion Michnacs, Carsten Zetzl
  • Patent number: 8252715
    Abstract: To provide a water absorbing agent which is excellent in balance between absorbency and liquid permeability against pressure and is excellent in flowability at the time of moisture absorption. The water absorbing agent comprises water absorbent resin particles and an organic surface additive, wherein: the organic surface additive having (i) a reactive group for a functional group of a surface of each water absorbent resin particle and (ii) a hydrophobic group exists on the surface of the water absorbent resin particle, and the hydrophobic group has a hydrocarbon group whose carbon number is 8 or more, and a ratio of an oxyalkylene group in a molecular mass of the organic surface additive is 0 or more and 25 mass % or less.
    Type: Grant
    Filed: March 3, 2008
    Date of Patent: August 28, 2012
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kazushi Torii, Yoshifumi Adachi, Taishi Kobayashi, Yusuke Watanabe, Hiroyuki Ikeuchi, Toshimasa Kitayama
  • Patent number: 8247499
    Abstract: A water-absorbing polymer structure is disclosed, whose surface has been brought into contact with a combination of a metal salt and an oxide of a metal. The invention also relates to a process for treating the surface of water-absorbing polymer structures whereby the surface of water-absorbing polymer structures is brought into contact with a combination of a metal salt and an oxide of a metal at a temperature of from about 50 to about 300° C. The present invention further relates to the water-absorbing polymer structures obtainable by this process, a composite comprising a water-absorbing polymer structure and a substrate, chemical products such as foams and fibers comprising water-absorbing polymer structures or a composite, and the use of a combination of an oxide of a metal and of a metal salt for treatment of the surface of super-absorbing polymer structures.
    Type: Grant
    Filed: April 21, 2006
    Date of Patent: August 21, 2012
    Assignee: Evonik Stockhausen GmbH
    Inventors: Mirko Walden, Franck Furno, Harald Schmidt
  • Patent number: 8236903
    Abstract: An acid-functional polymer is reacted with a transition metal compound having an average particle size small enough to react with the polymer at a temperature below the glass transition temperature of the polymer, e.g., at room temperature, to produce cross-linked polymer. The process produces a liquid polymer product that dries to a cross-linked film without the required presence of volatile ligands. Improved coatings such as floor polishes that can be formed from these cross-linked polymers are also disclosed.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: August 7, 2012
    Inventors: Jay M. Shaffer, Tracy L. Eifolla
  • Publication number: 20120183769
    Abstract: An adhesive composition of the present invention is characterized by including: an acrylic copolymer (A) containing 30 to 77% by weight of a structural unit (a1) derived from an alkyl acrylate monomer in which an alkyl group has 5 to 20 carbon atoms; 20 to 60% by weight of a structural unit (a2) derived from an alicyclic group-containing (meth)acrylate monomer; 0.01 to 5% by weight of a structural unit (a3) derived from a tertiary amino group-containing monomer that is derived from (meth)acrylic acid; and 0.
    Type: Application
    Filed: September 29, 2010
    Publication date: July 19, 2012
    Applicant: LINTEC Corporation
    Inventors: Kenji Nasu, Yuki Hongo
  • Patent number: 8221866
    Abstract: A carpet cushion has attached thereto or thereon a layer of polymer composition comprising, consisting essentially of, consisting of, or produced from a fatty acid-modified ionomer and optionally blended or coextruded with an ethylene-containing polymer wherein the ionomer comprises, consists essentially of, consists of, or is produced from an ethylene copolymer and a fatty acid.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: July 17, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Donna Lynn Visioli, Gregory E. Hindman
  • Publication number: 20120178621
    Abstract: A superabsorbent produced by polymerizing a monomer mixture which comprises at least one ethylenically unsaturated monomer bearing at least one acid group, at least 0.1% by weight and at most 20% by weight, based on the total amount of ethylenically unsaturated monomers bearing at least one acid group (calculated as the free acid), of at least one alkaline earth metal salt (calculated without water of crystallization) selected from the salts of calcium, strontium or barium having been added before or during the polymerization and/or, if the polymerization is followed by a separate drying step, to the polymer before the drying, exhibits improved stability to discoloration in the course of storage under elevated temperatures and/or elevated air humidity.
    Type: Application
    Filed: September 14, 2010
    Publication date: July 12, 2012
    Applicant: BASF SE
    Inventors: Mark Elliott, Thomas Daniel, Norbert Herfert
  • Publication number: 20120172536
    Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production on a huge scale (for example, 1 t/hr or more), the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.
    Type: Application
    Filed: August 27, 2010
    Publication date: July 5, 2012
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kozo Nogi, Kunihiko Ishizaki, Katsuyuki Wada
  • Publication number: 20120157635
    Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production on a huge scale (for example, 1 t/hr or more), the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.
    Type: Application
    Filed: August 27, 2010
    Publication date: June 21, 2012
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kozo Nogi, Kunihiko Ishizaki, Syuji Kanzaki
  • Patent number: 8202957
    Abstract: A process for preparing postcrosslinked water-absorbing polymer beads with high absorption by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, wherein the solids content of the monomer solution is at least 35% by weight and the polymer beads have a mean diameter of at least 150 ?m.
    Type: Grant
    Filed: July 9, 2007
    Date of Patent: June 19, 2012
    Assignee: BASF SE
    Inventors: Uwe Stueven, Matthias Weismantel, Wilfried Heide, Marco Krüger, Volker Seidl, Stefan Blei, Dennis Loesch, Rüdiger Funk, Annemarie Hillebrecht
  • Patent number: 8188193
    Abstract: A process for thermally surface postcrosslinking water-absorbing polymer particles in a fluidized bed generated by means of a carrier gas, wherein the surface postcrosslinker is supplied to the fluidized bed in gaseous form.
    Type: Grant
    Filed: July 3, 2009
    Date of Patent: May 29, 2012
    Assignee: BASF SE
    Inventors: Stefan Blei, Marco Krüger, Wilfried Heide, Matthias Weismantel, Uwe Stueven
  • Patent number: 8182916
    Abstract: An object of the present invention is to provide a water absorbing agent having a low amount of residual monomer, small variance of the amount of residual monomer among ranges of particle size distribution and favorable absorption properties, and being sanitary; an absorbing article; and a method for the production of a water absorbing agent. The water absorbing agent of the present invention has the amount of residual monomer of not higher than 500 ppm, and a residual monomer index of not greater than 0.30.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: May 22, 2012
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kazuki Kimura, Shin-ichi Fujino, Katsuyuki Wada, Kunihiko Ishizaki
  • Publication number: 20120071609
    Abstract: A method for harnessing rain and dew water with superabsorbent polymers. Highly absorbent superabsorbent polymers which are stimuli-responsive are used to absorb rain/dew water to augment water supply and solve water crisis. The polymers may be recycled and rehydrated number of times. They may be an additional source for drinking water. The polymers are used for storage of water in warehouses and the invention may obviate the need to construct controversial huge dams and canals or drill wells. The stored water in superabsorbent polymers is released at the point of use by any stimulus which may be mechanical, light-induced, electrical, thermal treatment or chemical treatment. Superabsorbent polymers with absorbing power of at least 1000 times their own weight are preferred. With 2000 g/g of swelling capacity, we can have 99.95% pure water in solid/gel form. In solid form, water can be transported anywhere without leakage.
    Type: Application
    Filed: September 13, 2011
    Publication date: March 22, 2012
    Inventor: Manilal J. Savla
  • Publication number: 20120027814
    Abstract: A method for bonding a polymeric fiber to tissue is provided which includes providing a polymeric fiber having a plurality of tissue reactive members linked to a surface of the fiber via a specific binding pair, and contacting the polymeric fiber to biological tissue, to covalently bond the fiber to the tissue.
    Type: Application
    Filed: July 27, 2011
    Publication date: February 2, 2012
    Inventor: Sébastien Ladet
  • Publication number: 20120021156
    Abstract: The present application relates to a process for the manufacture of copolymers of ethylene and of at least one vinyl ester, comprising the following steps: a) fermentation of renewable starting materials so as to produce at least one alcohol comprising ethanol; b) dehydration of the alcohol obtained so as to produce at least one alkene comprising ethylene and, optionally, purification of the alkene so as to obtain ethylene, c) copolymerization of the ethylene with at least one vinyl ester, d) isolation of the copolymer obtained. The application also relates to the copolymers of ethylene and of at least one vinyl ester in which the ethylene is at least partly obtained from renewable starting materials, and to uses thereof.
    Type: Application
    Filed: November 10, 2009
    Publication date: January 26, 2012
    Inventors: Samuel Devisme, Fabrice R. Chopinez, Christian Laurichesse, Thomas Roussel, Jean-Luc Dubois
  • Publication number: 20120010372
    Abstract: The physical properties of a water-absorbing resin with low residual monomer content are improved or stabilized, without sacrifices in productivity, production cost, stability, etc. Provided is a water-absorbing resin with low residual monomer content and excellent whiteness, wherein a water-absorbing resin consumed in large quantities in disposable diapers, etc., is preferably a sustainable and renewable water-absorbing resin that does not require excessive purification of the acrylic acid, particularly acrylic acids derived from non-fossil sources, that is the starting material of the water-absorbing resin. Disclosed is a method of manufacturing a hydrophilic polyacrylic acid (salt) resin, which is a method of manufacturing a water-absorbing polyacrylic acid resin that comprises a step in which a monomer is prepared from acrylic acid, a step in which said monomer is polymerized, and a step in which the resulting hydrous gel is dried.
    Type: Application
    Filed: February 8, 2010
    Publication date: January 12, 2012
    Inventors: Shinichi Fujino, Satoshi Matsumoto, Kunihiko Ishizaki
  • Publication number: 20110319518
    Abstract: The present invention is a method for producing a water absorbent resin which method is a method for producing surface cross-linked water absorbent resin particles, the method including the successive steps of: (a) adding a surface cross-linking agent and water to a particulate water absorbent resin in a mixer; and (b) reacting the resulting water absorbent resin mixture taken out from the mixer with the surface cross-linking agent in a reactor by heating or active energy ray irradiation, water vapor being used as part or all of the water added in the mixer. This makes it possible to provide a method for producing a water absorbent resin in which method a surface cross-linked water absorbent resin that has excellent properties can be obtained efficiently at low cost with high productivity.
    Type: Application
    Filed: March 4, 2010
    Publication date: December 29, 2011
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kenji Kadonaga, Kenji Tada, Masazumi Sasabe, Seiji Kato
  • Patent number: 8084542
    Abstract: An acrylic rubber comprised of a copolymer comprising 0.1 to 20% by weight of (A) units of a butenedioic acid monoester monomer having an alicyclic structure and 50 to 99.9% by weight of (B) units of at least one kind of monomer selected from acrylic acid ester monomers and methacrylic acid ester monomers. A crosslinkable acrylic rubber composition comprising the acrylic rubber and a crosslinking agent, especially a polyamine crosslinking agent, has good process-stability and good shapability and gives a shaped article having high heat resistance and exhibiting reduced permanent set.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: December 27, 2011
    Assignee: Zeon Corporation
    Inventors: Hirofumi Masuda, Yoshiaki Aimura, Kiyonori Umetsu
  • Patent number: 8071974
    Abstract: An organic thin film transistor includes a gate electrode having a first thickness on a substrate; an organic insulating layer on the gate electrode and the substrate, a portion of the organic insulating layer on the substrate having a second thickness, and a portion of the organic insulating layer on the gate electrode having a third thickness of about 2000 ? to 5000 ?; a semiconductor layer on the organic insulating layer; and source and drain electrodes on the organic insulating layer and contacting both side portions of the semiconductor layer.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: December 6, 2011
    Assignee: LG Display Co. Ltd.
    Inventors: Hyun-Sik Seo, Nack-Bong Choi
  • Patent number: 8067504
    Abstract: A pre-adhesive composition is described comprising an acid-functional (meth)acrylate copolymer and an acylaziridine crosslinking agent, which when crosslinked provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles.
    Type: Grant
    Filed: August 25, 2009
    Date of Patent: November 29, 2011
    Assignee: 3M Innovative Properties Company
    Inventors: Belma Erdogan, Timothy D. Filiatrault, Maureen A. Kavanagh, Larry R. Krepski, Babu N. Gaddam