Polymer Derived From Aromatic Hydrocarbon Monomer, E.g., Styrene, Etc. Patents (Class 525/333.3)
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Patent number: 7385009Abstract: The instant invention relates to a process for the preparation of hydroxy-vinyl-aromatic polymers in particular 4-hydroxystyrene polymers or copolymers by anionic or controlled radical polymerization of the respective monomer, wherein the hydroxy functionality is blocked with a protective group which is subsequently removed by reacting it with a halosilane reagent. The resulting (co)polymers have a narrow polydispersity and are useful for manufacturing photoresists.Type: GrantFiled: November 5, 2003Date of Patent: June 10, 2008Assignee: Ciba Specialty Chemicals CorporationInventors: Kazuhiko Kunimoto, Peter Nesvadba, Andreas Kramer
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Patent number: 7365151Abstract: A solvent for polystyrene resin treatment is used for reducing the volume of a polystyrene resin by contacting it with the solvent; and a method of treating polystyrene resins. The solvent is characterized by comprising 20 to 70 wt. % of diethylene glycol dimethyl ether and 30 to 80 wt. % of C9-13 aliphatic hydrocarbon. The method employs the solvent.Type: GrantFiled: November 29, 2002Date of Patent: April 29, 2008Inventor: Shigenobu Hamano
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Patent number: 7351771Abstract: The present invention relates to a recycling process for the preparation of solid phase bonded 2-chlorotrityl chloride (2-CTC resin) useful for solid phase peptide synthesis, wherein active chloride CTC resin is regenerated by reacting the spent resin with a chlorinating agent in organic solvent.Type: GrantFiled: December 18, 2003Date of Patent: April 1, 2008Assignee: Hoffmann-La Roche Inc.Inventors: Kleomenis Barlos, Bernhard Knipp
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Patent number: 7312281Abstract: An anhydrous, liquid phase process for preparing hydroxyl containing polymers of enhanced purity comprising the steps of polymerization, purification, transesterification, purification, catalyst removal, and solvent exchange. The resultant polymer in solution can be used directly, without further processing steps, to prepare a photoresist composition.Type: GrantFiled: February 24, 2005Date of Patent: December 25, 2007Assignee: DuPont Electronic Polymers L.P.Inventors: Michael T. Sheehan, James R. Sounik
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Patent number: 7312280Abstract: There is provided a process for producing a modified ethylene-vinylcyclohexane copolymer resin, which comprises the steps of: (1) blending at least the following components (A) to (C) to produce a blend; (A) 100 parts by weight of an ethylene-vinylcyclohexane copolymer resin, (B) from 0.1 to 20 parts by weight of at least one compound selected from the group consisting of: (B1) a compound having in its molecule (i) at least one carbon-carbon double or triple bond and (ii) at least one polar group, and (B2) a compound having in its molecule (iii) an OR group and (iv) at least two same or different functional groups selected from the group consisting of a carboxylic acid group, an acid halide group, an acid anhydride group, an acid halide anhydride group, an acid ester group, an acid amide group, an imide group, an imido group, an amino group and a salt of an amino group, wherein the R is hydrogen, an alkyl group, an aryl group, an acyl group or a carbonyldioxy group, and (C) from 0.Type: GrantFiled: July 23, 2003Date of Patent: December 25, 2007Assignee: Sumitomo Chemical Company, LimitedInventors: Shinichi Kondo, Takashi Sanada
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Patent number: 7262254Abstract: The invention relates to a tire having a tread of a rubber composition with compositional limitations containing minimal, if any, of in situ formed volatile alcohol byproduct. The tread component rubber composition contains a combination or pre-hydrophobated silica reinforcement and siloxane functionalized styrene/butadiene copolymer elastomer. The pre-hydrophobated silica is prepared, prior to mixing with the elastomer(s), by reacting hydroxyl groups (e.g. silanol groups) contained on the surface of a precipitated silica with an alkoxyorganomercaptosilane or with a bis-3(triethoxysilylpropyl)polysulfide which contains an average of from 2 to 4 connecting sulfur atoms in its polysulfidic bridge to form a composite thereof which may optionally include an alkyl silane. The volatile alcohol byproduct (e.g. ethanol) therefrom is thereby removed from the pre-hydrophobated silica composite prior to its introduction into the rubber composition(s).Type: GrantFiled: August 26, 2005Date of Patent: August 28, 2007Assignee: The Goodyear Tire & Rubber CompanyInventor: David John Zanzig
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Patent number: 7250476Abstract: A multi-functional polymer defined by the formula (Q—RnZ—P2—Y where (Q—R)n is a functionality cluster, Q is a functional group, R is a multi-valent organic group, P2 is a long-chain polymer, n is an integer from about 2 to about 10, Y is a proton, a weak functional group, or a selective functional group, and Z is a branch point where the functionality clusters join the long-chain polymer.Type: GrantFiled: August 1, 2003Date of Patent: July 31, 2007Assignee: Bridgestone CorporationInventors: Georg G. A. Böhm, William L. Hergenrother, Christine M. Rademacher
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Patent number: 7244791Abstract: A method for preparing sulfonated polystyrene, whereby a styrene monomer having a sulfonyl chloride is prepared by reacting p-styrene sulfonic acid salt with a chloride, a styrene-based polymer having the sulfonyl chloride is synthesized by the polymerization of a p-styrene sulfonyl chloride monomer and optionally at least one monomer of a styrene and an acrylic monomer, the styrene-based polymer having the sulfonyl chloride is treated with an inorganic base aqueous solution to change the sulfonyl chloride into a SO3M group where M is an alkali metal, and treated with an acidic aqueous solution to prepare a styrene-based polymer having a sulfonic acid group. The styrene-based polymer having the sulfonic acid group prepared according to the process of the present invention has high proton conductivity and good mechanical properties.Type: GrantFiled: October 27, 2004Date of Patent: July 17, 2007Assignee: Samsung SDI Co., Ltd.Inventors: Hyoung-Juhn Kim, Ho-Jin Kweon, Yeong-Chan Eun, Sung-Yong Cho
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Patent number: 7241830Abstract: Provided is a film-forming composition substantially free of organic solvent which includes an aqueous dispersion of polymeric microparticles prepared by emulsion polymerization of a monomeric composition containing (1) at least 10 percent by weight of one or more vinyl aromatic compounds; (2) 0.1 to 10 percent by weight of one or more carboxylic acid functional polymerizable, ethylenically unsaturated monomers; (3) 0 to 10 percent by weight of one or more polymerizable monomers having one or more functional groups capable of reacting to form crosslinks; and (4) one or more polymerizable ethylenically unsaturated monomers. Each of (1), (2), (3) and (4) are different one from the other and at least one of (3) and (4) is present in the monomeric composition. Multi-layer composite coatings and coated substrates also are provided.Type: GrantFiled: May 7, 2004Date of Patent: July 10, 2007Assignee: PPG Industries Ohio, Inc.Inventors: Charles M. Kania, Roxalana L. Martin, Carolyn A. K. Novak, Thomas R. Hockswender, Mark A. Tucker, Mary Beth Grolemund, Deirdre Ragan, Alicia Williams
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Patent number: 7232864Abstract: The present invention is a coupled radial anionic polymer comprising a polyhedral oligosilsesquioxane [POSS] of the formula [R—SiO3/2]n. POSS compounds having R=vinyl, glycidyldimethyl silyl, and isobutyl have been found effective in coupling anionic living polymers to yield radial polymers having 2 to 10 arms. Radial polymers of the present invention have been formed using POSS octamers and mixtures of POSS octamers, decamers and dodecamers. The present invention also relates to a process for coupling living anionic polymers with POSS compounds.Type: GrantFiled: October 14, 2004Date of Patent: June 19, 2007Inventor: Robert C. Bening
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Patent number: 7211537Abstract: A modified aluminum oxy compound (A) obtained by reacting an aluminum oxy compound (a), water (b) and a compound having a hydroxyl group (c); a polymerization catalyst component comprising the modified aluminum oxy compound; a polymerization catalyst obtained by contacting said modified aluminum oxy compound (A), a transition metal compound (B) and optionally an organoaluminum compound (C) and a specified boron compound; and a process for producing an olefin polymer or an alkenyl aromatic hydrocarbon polymer with the polymerization catalyst.Type: GrantFiled: April 26, 2005Date of Patent: May 1, 2007Assignee: Sumitomo Chemical Company LimitedInventors: Masayuki Fujita, Tatsuya Miyatake, Yoshinori Seki, Nobuo Oi
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Patent number: 7208539Abstract: The present invention relates to a thermosetting resin composition comprising: (1) a metal salt of a disubstituted phosphinic acid, and (2) a resin having a dielectric constant of 2.9 or less at a frequency of 1 GHz or more, and a prepreg and a laminated board using the same.Type: GrantFiled: April 16, 2003Date of Patent: April 24, 2007Assignee: Hitachi Chemical Co., Ltd.Inventors: Shinji Tsuchikawa, Michitoshi Arata, Kenichi Tomioka, Kazuhito Kobayashi
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Patent number: 7199175Abstract: A tire tread comprising a rubber composition based on (phr: parts by weight per hundred parts of elastomer): (i) a diene elastomer; (ii) more than 50 phr of an inorganic filler as reinforcing filler; (iii) between 2 and 15 phr of an (inorganic filler/diene elastomer) coupling agent; (iv) between 1 and 10 phr of a methylene acceptor, and (v) between 0.5 and 5 phr of a methylene donor. This tread has, after mechanical running-in of the tire for which it is intended (“auto-accommodation”), a rigidity gradient which increases radially from the surface towards the inside of the tread. Use of such a tread for the manufacturing or recapping of tires. Tires comprising a tread according to the invention, in particular of the snow or ice type (“winter” tires).Type: GrantFiled: January 28, 2003Date of Patent: April 3, 2007Assignee: Michelin Recherche et Technique S.A.Inventor: Didier Vasseur
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Patent number: 7182086Abstract: A mouth guard which is excellent in impact absorbability and durability, is thin and has good fittability, and is able to easily chew thereupon, and does not give vomiting feel; and a sheet for mouth guard which is suitable for producing the mouth guard.Type: GrantFiled: May 29, 2002Date of Patent: February 27, 2007Assignee: Kuraray Co., Ltd.Inventors: Yukihiro Fujieda, Kazuaki Takada, Koichi Wada, Miyuki Kaneyama, Koji Inai
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Patent number: 7163992Abstract: A process for producing a copolymer which comprises reacting a vinyl monomer with a macromonomer composition containing a macromonomer. The macromonomer composition is obtained by polymerizing at a temperature of 160 to 350° C. a monomer mixture comprising 10 to 80 wt. % first vinyl monomer having an alkyl group in the ?-position, 0 to 30 wt. % styrene as an optional ingredient, and 0 to 90 wt. % one or more other vinyl monomers based on the total amount of all monomers.Type: GrantFiled: February 26, 2002Date of Patent: January 16, 2007Assignee: Toagosei Co., Ltd.Inventor: Michihiro Kaai
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Patent number: 7160950Abstract: A modified olefin-based copolymer produced by graft-polymerizing an alkenyl aromatic hydrocarbon and/or an unsaturated carboxylic acid or derivative thereof to an olefin-based copolymer containing repeating units derived from a linear ?-olefin and/or ethylene copolymer of ethylene and repeating units derived from a vinyl compound (I) or (II) described below, and an adhesive containing the product as an effective ingredient, in which an adhesiveness to an adherend such as olefin resins (e.g. polyethylene, polypropylene) is further improved, are provided. Vinyl compound (I): a vinyl compound represented by the general formula CH2?CH—R, wherein steric parameters Es and B1 of the substituent R are respectively ?1.64 or less and 1.53 or more. Vinyl compound (II): a vinyl compound represented by the general formula CH2?CH—R?, wherein a substituent R? is a secondary or tertiary alkyl group.Type: GrantFiled: August 6, 2002Date of Patent: January 9, 2007Assignee: Sumitomo Chemical Company, LimitedInventors: Toshiki Mori, Nobuo Oi
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Patent number: 7148288Abstract: A process is disclosed for formation of a preformed stabilizer for use in formation of graft polyols. The preformed stabilizer has a reduced level of transesterification products and results in less reactor fouling. The preformed stabilizer is prepared in the presence of phosphorous compounds, which reduces the unwanted transesterification products.Type: GrantFiled: June 27, 2003Date of Patent: December 12, 2006Assignee: BASF CorporationInventors: Joseph P. Borst, Mao-Yao Huang, David D. Peters
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Patent number: 7144947Abstract: The invention concerns copolymers of the poly(styrene)-poly(ethylene-butylene)-poly(styrene) type wherein the central poly(ethylene-butylene) sequence has been modified by chemical grafting of hydrophilic groups to make them amphiphilic. The invention also concerns a method for preparing said novel amphiphilic copolymers and their use in particular emulsifying agent or absorbent.Type: GrantFiled: October 18, 2001Date of Patent: December 5, 2006Assignee: Laboratories d'Hygiene et de DietetiqueInventors: Elise Camus, Claire Brachais, Stéphane Auguste
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Patent number: 7119164Abstract: A sulfonated organic porous material in which at least 0.5 mg-equivalent/g (on a dry basis) of sulfonic acid groups has been introduced can be obtained by causing a gaseous substance containing sulfuric anhydride to come in contact with an organic porous material having mesopores existing on the walls of interconnected macropores and having a median radius of 0.01–100 ?m and a total pore volume of 1–50 ml/g. This preparation method can ensure the introduction of a large amount of sulfonic acid groups into an organic porous material in a short period of time.Type: GrantFiled: September 2, 2003Date of Patent: October 10, 2006Assignee: Organo CorporationInventors: Hiroshi Inoue, Koji Yamanaka, Akiko Yoshida, Yusaku Suenaga
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Patent number: 7087558Abstract: A process for reacting relatively small hydrophilic carboxylic molecules with relatively large, hydrophobic hydrocarbon based molecules, said process comprising conducting the reacting in the presence of a sulfonic acid catalyst having solubilizing properties. In a preferred embodiment the large hydrophobic molecule comprises at least one member of the group consisting of (1) olefinically unsaturated hydrocarbons containing at least about 10 carbon atoms and (2) aliphatic hydrocarbyl group substituted hydroxy aromatic compounds wherein the aliphatic hydrocarbyl group contains at least 12 carbon atoms and the small hydrophilic molecule comprises a carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5 wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof.Type: GrantFiled: May 17, 2001Date of Patent: August 8, 2006Assignee: The Lubrizol CorporationInventors: Marvin B. DeTar, John C. Smoggie, Richard M. Lange
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Patent number: 7078464Abstract: Compositions comprising acid salts of amine-functionalized styrene-maleic anhydride resins are disclosed. The salts can be dissolved in organic solvents, UV/EB polymerizable monomers and/or oligomers, and/or water and act as a polymeric surfactants to disperse pigments or fillers, emulsifying agents, or hard resin additives in a variety of formulations. The compositions react under UV/EB cure conditions, and provide enhanced properties such as cure speed, hardness and adhesion to polymer compositions.Type: GrantFiled: June 16, 2003Date of Patent: July 18, 2006Assignee: Sartomer Technology, Inc.Inventors: John Schmidhauser, James Goodrich, Bruce McEuen, William R. Dougherty
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Patent number: 7041733Abstract: It has been discovered that certain compounds serve as particle size regulators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers in the presence of diene polymers. Suitable compounds that can control particle size include, but are not necessarily limited to, cobalt naphthenate, zinc naphthenate, iron octoate, calcium octoate, zinc octoate, zinc neodecanoate, potassium octoate, copper naphthenate, calcium versalate, and the like. Use of these metal carboxylates when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in reduced polybutadiene particles. Grafting and morphology characteristics may also be improved.Type: GrantFiled: October 23, 2003Date of Patent: May 9, 2006Assignee: Fina Technology, Inc.Inventors: Cyril Chevillard, Jose M. Sosa
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Patent number: 7026409Abstract: The present invention provides a solid acid catalyst that is excellent from the point of toxicity, environment and others, wherein reaction can be progressed effectively with Bronsted acid or Lewis acid catalyst. For example, the benzoylation reaction of alcohol can also be progressed easily, and further, the catalyst can be recovered and recycled easily. The para position of arylbis(perfluoroalkylsulfonyl)methane represented by the general formula [1] (wherein R1 shows a substituted or unsubstituted aryl group, Rf1 and Rf2 are independent to each other and show a perfluoroalkyl group), a pentafluorophenylbis(perfluoroalkylsulfonyl)methane, for example, is supported on a polystyrene resin, and a polystyrene-supported arylbis(perfluoroalkylsulfonyl)methane represented by the general formula [3] (wherein R3 shows a substituted or unsubstituted arylene group, Rf1 and Rf2 are the same as described above) is obtained.Type: GrantFiled: March 12, 2002Date of Patent: April 11, 2006Assignee: Japan Science and Technology AgencyInventors: Kazuaki Ishihara, Hisashi Yamamoto
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Patent number: 7022775Abstract: The present invention relates to resins based on functionalized polystyrene, to the method for the production thereof, to the use thereof for producing columns for purifying anti-factor VIII antibodies, and also to a method for purifying anti-factor VIII antibodies ex vivo.Type: GrantFiled: November 6, 2001Date of Patent: April 4, 2006Assignee: BioracsInventors: Rosa Siali, Hamid Lakhiari, Catherine Boisson-Vidal, Jacqueline Jozefonvicz
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Patent number: 7019084Abstract: The present invention relates to the preparation of rubber compositions for tire tread and tire sidewall component applications. A tire is provided having tread of such composition designed for relatively heavy loads such as, for example, truck tires. A tire having a sidewall of such composition is also provided. Such tire component rubber compositions are of rubber compositions reinforced with precipitated silica and selected carbon black in specified amounts and prepared with a prescribed order of addition to the rubber composition and composed of elastomers as a specific combination of high trans styrene-butadiene rubber with natural or synthetic cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber.Type: GrantFiled: December 11, 2002Date of Patent: March 28, 2006Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul Harry Sandstrom
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Patent number: 7019093Abstract: The invention is a photoswitchable benzocyclobutene-based polymer that while remaining aqueous developable, avoids the problem of significant moisture uptake. The oligomer or polymer comprises a polymeric backbone, benzocyclobutene reactive groups, and photoswitchable pendant groups. The pendant groups are bonded to the polymeric backbone and are characterized by the presence of a moiety that converts to carboxylic acid upon exposure to activating wavelengths of radiation a carboxylic acid. When the oligomer or polymer is subsequently heated to cause cure of the oligomer or polymer, carbon dioxide is emitted and the group forms a substantially non-polar moiety. The invention is also a method of making such a polymer and a method of forming a patterned film using such a polymer.Type: GrantFiled: October 18, 2002Date of Patent: March 28, 2006Assignee: Dow Global Technologies Inc.Inventors: Ying Hung So, Keith J. Watson, Scott J. Bis
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Patent number: 7009007Abstract: A novel resin is provided, which is renewable with less energy. A process for renewing the resin is also provided. The present invention includes a polymer having the repeating unit represented by Structural Formula (1) [—P1—R—]n (1). In the formula, P1 indicates an addition polymer moiety having a continuous hydrocarbon chain as the skeleton containing no condensation system, and is a polymer or oligomer prepared by addition polymerization of one or more monomers having a double bond; R indicates a linking group constituted of a condensation system for linking the polymer moieties P; and n is a number of repeating units and is an integer of 2 or more.Type: GrantFiled: May 22, 2003Date of Patent: March 7, 2006Assignee: Canon Kabushiki KaishaInventors: Hiroshi Maehara, Chieko Mihara, Yoshihiko Kikuchi
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Patent number: 6969737Abstract: A rubber composition including a natural or synthetic rubber, and an adhesive resin capable of unexpected adhesion to metal, polymer and glass substrates, particularly cords in radical tires, hoses, conveyor belts, transmission belts, and the like by the addition of long chain esters, including mono, di- and tri-esters.Type: GrantFiled: May 9, 2003Date of Patent: November 29, 2005Assignee: The C.P. Hall CompanyInventors: Gary Wentworth, Stephen O'Rourke, Kimberly L. Stefanisin, John English
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Patent number: 6964996Abstract: The present invention relates to a ternary copolymer represented by the following formula (1) of the penta-block structure, wherein the molecular weight is 50, 000 to 400,000, pB is more than 70% of 1,4 structure, the content of pS is in range of 5% to 50%, and pB and pI are in a weight ratio of pB/pI?1. pS-pI-pB-pI-pS??(1) Wherein, pS is vinyl aromatic polymer, pB is polybutadiene and pI is polyisoprene. The block copolymer in the present invention with the structure, in which polyisoprene block is inserted between vinyl aromatic polymer block and polybutadiene block, has high mechanical properties such as tensile strength. The manufacturing method of the ternary block copolymer with penta-block structure is also provided.Type: GrantFiled: July 22, 2003Date of Patent: November 15, 2005Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Kwanyoung Lee, Young Jin Kim, Jong Kim
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Patent number: 6943219Abstract: The present invention provides a vinyl polymer with an epoxy group terminally introduced therein and an epoxy resin composition comprising (A) an epoxy resin and (B) a vinyl polymer which has a main chain produced by living radical polymerization and has a reactive functional group at a main chain terminus. A flexible epoxy resin composition can be obtained using these compounds. The invention further provides an epoxy resin composition having an epoxy group at a main chain terminus thereof.Type: GrantFiled: February 24, 2003Date of Patent: September 13, 2005Assignee: Kaneka CorporationInventors: Kenichi Kitano, Yoshiki Nakagawa, Masayuki Fujita
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Patent number: 6939923Abstract: A method for functionalizing a crosslinked polymer bead. The method comprises the steps of: (a) swelling the bead in a first solvent or solvent mixture to a volume from 200% to 310% of its volume when dry; and (b) contacting the bead with a functionalizing reagent in a second solvent or solvent mixture capable of swelling the bead to a volume from 200% to 310% of its volume when dry.Type: GrantFiled: August 7, 2003Date of Patent: September 6, 2005Assignee: Rohm and Haas CompanyInventors: James Charles Bohling, Marlin Kenneth Kinzey, John Joseph Maikner, William Joseph Zabrodski
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Patent number: 6919382Abstract: The invention provides novel solid supports comprising dihydroxyalkyl aminoalkyl and dihydroxyalkylaminobenzyl groups, and methods for making and using them. The supports are particularly useful for immobilizing and derivatizing functionalized boronic acids for use in solid phase synthesis, such as those used in combinatorial chemistries. The compositions and methods of the invention are also useful as scavenger solid supports, e.g., in solution-phase parallel synthesis of small molecule libraries, and for use in resin-to-resin transfer reactions via phase transfer of solid supported boronic acids under both aqueous and anhydrous conditions. The methods of the invention provide convergent solid-phase synthesis of symmetrically or unsymmetrically functionalized compounds, such as biphenyl compounds. Also provided are synthesizer devices, e.g., semiautomated parallel synthesizers.Type: GrantFiled: August 31, 2001Date of Patent: July 19, 2005Assignee: The Governors of the University of AlbertaInventor: Dennis G. Hall
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Patent number: 6900274Abstract: A process for preparing a surfactant, useful for dispersing tackifier resins in aqueous media, comprises reacting an ??-unsaturated carboxylic acid or anhydride, or an ester thereof, with a terpene- or hydrocarbon-based resin to form an adduct, then reacting the adduct with a polyalkylene polyol to yield the surfactant. In a related embodiment, the surfactant is subsequently functionalized. Also disclosed are surfactants prepared using a disclosed process; compositions comprising a disclosed surfactant and a tackifier resin; aqueous dispersions comprising a disclosed surfactant; tackifier resin and water; adhesive compositions comprising a disclosed aqueous dispersion and a polymer latex; and pressure sensitive adhesive overlays prepared using a disclosed adhesive composition.Type: GrantFiled: February 6, 2003Date of Patent: May 31, 2005Assignee: Arizona Chemical CompanyInventors: Erwin R. Ruckel, Kerry L. Thompson, George L. Gergely, Jr.
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Patent number: 6890524Abstract: This invention provides a method of preparing a polymeric delivery system for active ingredients. The delivery system is formed either by attaching the active ingredient to a linker through a hydrolyzable covalent bond, then forming a covalent bond between the linker and a portion of the subunits of a cross-linked polymer, or by attaching a linker to a portion of the subunits of a cross-linked polymer, then attaching the active ingredient to the polymer-linker combination through a hydrolyzable covalent bond. The invention also provides a delivery system comprising an active ingredient covalently bonded through a hydrolyzale covalent bond to a linker, which is in turn covalently bonded to a portion of subunits of a cross-linked polymer.Type: GrantFiled: March 30, 1998Date of Patent: May 10, 2005Assignee: Monsanto CompanyInventor: Samuel J. Tremont
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Patent number: 6890981Abstract: Rubber mixtures which contain an organosilane of the general structure 1R2R3Si—R4—Z (I), wherein R1, R2 and R3 independently of one another are H, (C1-C4)alkyl, (C1-C4)alkoxy or halogen and the number of alkyl groups is ?1; R4 is a linear or branched (C1-C18)alkylidene group; and Z=H, halogen, SCN, SH or Sx—R4—SiR1R2R3, where x is 2 to 10. The rubber mixtures are useful in molding compositions particularly for tires and tire treads.Type: GrantFiled: March 31, 2000Date of Patent: May 10, 2005Assignee: Degussa AGInventor: Hans-Detlef Luginsland
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Patent number: 6884832Abstract: A rubber composition including a natural or synthetic rubber, and an adhesive resin capable of unexpected adhesion to metal, polymer and glass substrates, particularly cords in radical tires, hoses, conveyor belts, transmission belts, and the like by the addition of long chain esters, including mono, di- and tri-esters.Type: GrantFiled: May 10, 2002Date of Patent: April 26, 2005Assignee: The C.P. Hall CompanyInventors: Gary Wentworth, Stephen O'Rourke, Kimberly Stefanisin, John English
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Patent number: 6881453Abstract: A film which is a single polymer film and has a smaller phase difference as the wavelength becomes shorter. This film is made from an olefin-based polymer which has an alicyclic group in the side chain, such as hydrogenated polystyrene, the amount of the alicyclic group in the side chain being 60 to 90 wt % based on the whole polymer, and satisfies the following expression: R(450)/R(550)<1 wherein R(450) and R(550) are phase differences on the film plane at a wavelength of 450 nm and a wavelength of 550 nm, respectively.Type: GrantFiled: April 23, 2001Date of Patent: April 19, 2005Assignees: Teijin Limited, Bayer AGInventors: Nobuaki Kido, Shunichi Matsumura, Kaoru Iwata, Takashi Kushida, Akihiko Uchiyama, Michio Yamaura, Takeshi Sasaki, Kiyonari Hashidzume
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Patent number: 6875804Abstract: The syndiotactic polystirene resin composition according to the present invention is superior in compatibility between a syndiotactic polystyrene and a rubber component and mechanical properties such as impact strength, in which a syndiotactic polystyrene-maleic anhydride (sPS-MA) and a hydrogenated styrene/butadiene/styrene-maleic anhydride (SEBS-MA) are employed as compatibilizers and a diamine compound is added as a coupling agent. The compatibilizers and coupling agents improve polarity of both the syndiotactic polystyrene and the rubber component and impact strength of the syndiotactic polystyrene composition.Type: GrantFiled: December 18, 2000Date of Patent: April 5, 2005Assignee: Samsung Atofina Co., Inc.Inventors: Xuequan Zhang, Jae Gon Lim
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Patent number: 6864324Abstract: An anhydrous, liquid phase process for preparing hydroxyl containing polymers of enhanced purity comprising the steps of polymerization, purification, transesterification, purification, catalyst removal, and solvent exchange. The resultant polymer in solution can be used directly, without further processing steps, to prepare a photoresist composition.Type: GrantFiled: April 19, 2002Date of Patent: March 8, 2005Assignee: Chem First Electronic Materials L.P.Inventors: Michael T. Sheehan, James R. Sounik
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Patent number: 6858683Abstract: Process for the production of statistic elastomeric conjugated diene-vinyl arene copolymers having a branched structure which comprises: (1) anionic copolymerization in solution of the conjugated diene and vinyl arene monomers, in the presence of randomizing agents and an initiator selected from the group of Lithium alkyls, the copolymerization being carried out until the almost total disappearance of the monomers; (2) addition to the solution of step (1) of a quantity of Lithium alkyl from 1 to 4 times the molar quantity of the Lithium alkyl of step (1); (3) addition to the polymeric solution of step (2) of a compound having the general formula R—Br, the molar ratio between R—Br and the total Lithium alkyl ranging from 0.6/1 to 1/1, preferably from 0.7/1 to 0.9/1, thus obtaining an elastomeric branched copolymer.Type: GrantFiled: April 5, 2001Date of Patent: February 22, 2005Assignee: Polimeri Europa S.p.A.Inventors: Gian Tommaso Viola, Luca Soddu, Sabrina Isidori, Attilio Taccioli, Francesco Masi
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Patent number: 6858301Abstract: Polymer particles are provided having (1) a core with a glass transition temperature within a range of ?50° to +110° C. and (2) a shell surrounding the core. The core comprises at least one layer, with the layer(s) comprising at least one polymerized hydrophobic monomer and, optionally, a first cross-linker. The shell comprises a copolymerized mixture of least one hydrophobic monomer and at least one hydrophilic monomer and a second cross-linker for increasing thermal shear stability by forming cross-linkages. Use of these polymer particles in aqueous-based ink-jet inks provide laser print quality without any secondary treatment.Type: GrantFiled: January 2, 2003Date of Patent: February 22, 2005Assignee: Hewlett-Packard Development Company, L.P.Inventor: Sivapackia Ganapathiappan
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Patent number: 6852786Abstract: A rubber compound is described containing as a reinforcing filler a layered silicate which is obtained by excessive leaching of a smectitic layered silicate with mineral acids. The rubber compound further contains at least one diene polymer or copolymer and a coupler containing groups reactive with the filler. There is also described a method for production of the rubber compound and molded articles produced from the rubber compound.Type: GrantFiled: March 8, 2001Date of Patent: February 8, 2005Assignee: Sud-Chemie AGInventors: Rainer Brandsch, Stefan Dick, Klaus Schurz, Nikolaus Rennar, Andreas Siedler
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Patent number: 6852802Abstract: An object of the present invention is to provide a heavy metal ion scavenger having more excellent scavenging performance than previously. In order to attain this object, organic polymer materials of the present invention are characterized in that they have a polymer side chain derived from a haloalkyl-substituted styrene on the backbone of an organic polymer base and a functional group capable of forming a complex with a heavy metal ion has been introduced onto said polymer side chain. These organic polymer materials have excellent heavy metal ion scavenging performance so that they can be suitably used as heavy metal ion scavengers.Type: GrantFiled: October 20, 2000Date of Patent: February 8, 2005Assignee: Ebara CorporationInventors: Makoto Komatsu, Kazuyoshi Takeda, Kunio Fujiwara, Takeshi Takai
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Patent number: 6849695Abstract: A resin composite covered piping material is provided having high heat resistance and excellent flame retardation property, anti-corrosion property, chemical resistance, insulation property and sufficiently high adhesion property with steel material and moreover, is highly economical. The piping material having a covering layer of a resin composite wherein said resin composite comprises: (A) 10 to 80 weight percent of polyphenylene ether resin, (B) 10 to 80 weight percent of polystyrene polymer possessing syndiotactic structure, and (C) 10 to 80 weight percent of polystyrene resin other than component (B) wherein the total of (A), (B) and (C) is 100 weight percent. The resin composite described above may further contain an impact resistance improving agent (D) in a quantity of 1 to 50 parts by weight, with respect to the total of 100 parts by weight of components (A), (B) and (C).Type: GrantFiled: December 13, 2002Date of Patent: February 1, 2005Assignee: General Electric CompanyInventor: Sho Sato
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Patent number: 6841626Abstract: A process for hydrogenating aromatic polymers is disclosed. The process entails using a supported catalyst wherein support contains alumina and where the catalyst comprise at least one metal of subgroup VIII of the Periodic Table. The catalyst is characterized in that the pore volume of the pores having diameters of 1000 to 10,000 Angstrom is 15 to 100% relative to the total pore volume, as determined by mercury porosimetry.Type: GrantFiled: January 26, 2000Date of Patent: January 11, 2005Assignees: Bayer Aktiengesellschaft, Teijin LimitedInventors: Volker Wege, Konstadinos Douzinas, Johann Rechner
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Patent number: 6838527Abstract: As an ?-iminoester derivative that is stable under normal conditions and a method of producing various ?-aminoester derivatives using them, a polymer-immobilized ?-iminoester derivative represented by the following general formula (1): wherein R1 represents an alkyl chain of 1 or more carbons, and R2 represents a hydrogen atom, halogen atom, or an alkyl group, aryl group or alkoxy group that may contain substituents, and a method of producing an ?-iminoester derivative using them are provided.Type: GrantFiled: March 13, 2001Date of Patent: January 4, 2005Assignee: Japan Science and Technology CorporationInventor: Shu Kobayashi
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Patent number: 6835804Abstract: A polymer comprising recurring units of formula (2) is prepared by effecting deblocking reaction on a polymer comprising recurring units of formula (1) in the presence of an acid catalyst. In the formulae, R1 and R4 are H or methyl, R2 and R3 are C1-C10 alkyl, or R2 and R3 may form a ring, R5 is H, hydroxyl, alkyl, alkoxy or halogen, R6 and R7 are H, methyl, alkoxycarbonyl, cyano or halogen, R8 is C4-C20 tertiary alkyl, n is an integer of 0 to 4, p is a positive number, q and r each are 0 or a positive number, exclusive of q=r=0, p1 is a positive number, p2 is 0 or a positive number, and p1+p2=p. The polymer thus produced has a narrower molecular weight distribution than polymers produced by the prior art methods. A resist composition comprising the polymer as a base resin has advantages including a dissolution contrast of resist film, high resolution, exposure latitude, process flexibility, good pattern profile after exposure, and minimized line edge roughness.Type: GrantFiled: December 6, 2001Date of Patent: December 28, 2004Assignee: Shin-Etsu Chemical Co., LTD.Inventors: Takanobu Takeda, Osamu Watanabe
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Publication number: 20040249085Abstract: The present invention includes an isobutylene based terpolymer suitable for air barriers such as innerliners where adhesion to tire carcass materials (e.g., SBR) and flexibility are desirable, as well as low air permeability. The terpolymer in one embodiment is a halogenated terpolymer of C4 to C8 isoolefin derived units, C4 to C14 multiolefin derived units, and p-alkylstyrene derived units. The present invention also includes a method of producing an elastomeric terpolymer composition comprising combining in a polar diluent C4 to C8 isoolefin monomers, C4 to C14 multiolefin monomers, and p-alkylstyrene monomers in the presence of a Lewis acid and at least one initiator to produce the terpolymer.Type: ApplicationFiled: May 10, 2004Publication date: December 9, 2004Inventors: Walter Harvey Waddell, David Yen-Lung Chung
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Patent number: 6828389Abstract: A method for producing polymer-bound 2-chlorotrityl chloride of the formula (I): wherein is a polymer support, preferably cross-linked polystyrene, by reacting a corresponding carboxylic acid with hydrogen chloride. The method enables the support resin from the solid-phase peptide synthesis produced after the splitting off of the peptide to be reused.Type: GrantFiled: November 12, 2002Date of Patent: December 7, 2004Assignee: Lonza AGInventor: Carsten Meininghaus
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Patent number: RE39746Abstract: The invention relates to phosphoric esters of the general formula I where X is 1 or 2; n is from 2 to 18; m and o are each from 2 to 100; k is from 2 to 4; R? is H or a linear or branched alkyl radical; and R? is an alkyl, alkaryl, alkenyl, or sulfopropyl radical, and to there use as dispersants for pigments and fillers in aqueous or organic media.Type: GrantFiled: May 25, 2004Date of Patent: July 31, 2007Assignee: Goldschmidt GmbHInventors: Tammo Boinowitz, Eberhard Esselborn, Arno Knebelkamp, Christian Psiorz, Stefan Silber, Stefan Stadtmüller, Ellen Wallhorn