Amine Contains A Hydroxyl Group Patents (Class 525/380)
  • Patent number: 7160957
    Abstract: A method for residual monomer diminution by which a residual monomer is speedily removed from an N-vinyl compound polymer or the like without posing a problem such as an increase in ash content; and a process for producing an N-vinyl compound polymer solution or powder which has a regulated pH and is free from a decrease in pH with time. The method comprises adding an organic acid having a boiling point of 140° C. or higher at ordinary pressure to anaqueous solution of an N-vinyl compound polymer. The process comprises adding an organic base to an aqueous N-vinyl compound polymer solution having a pH lower than 7.0 to thereby neutralize the solution and regulate the pH thereof. Those operations are conducted in a reaction vessel in which a gaseous phase is regulated so as to have an oxygen concentration of 5.0% by volume or lower.
    Type: Grant
    Filed: July 8, 2003
    Date of Patent: January 9, 2007
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Toshiaki Kuriyama, Yasuko Inui
  • Patent number: 7148292
    Abstract: The invention concerns a method for hydrogenation of unsaturated polymers in dispersed medium based on an oxidation-reduction system containing hydrazine, an oxidant such as a peroxide and optionally a carboxylic acid. The hydrogenation rate can reach 100% in certain conditions.
    Type: Grant
    Filed: April 11, 2002
    Date of Patent: December 12, 2006
    Assignee: Arkema
    Inventors: Jean-Laurent Pradel, Pierre Nogues, Christophe Loret
  • Patent number: 7132477
    Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material, and a monocarboxylic acid. Multi-component composite coatings, coated substrates, and related methods are also provided.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: November 7, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Kurt A. Humbert, Karen S. Rechenberg, Edward R. Coleridge, Charles M. Kania, Paul H. Lamers
  • Patent number: 7132476
    Abstract: A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: November 7, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 7125931
    Abstract: A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: October 24, 2006
    Assignee: PPG industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 7122605
    Abstract: The invention relates to a method of making an acrylic graft polymer, especially a urethanized acrylic graft polymer. The method of the invention requires an ethylenically unsaturated monomer mixture (a) comprising a monomer (ai) of a particular structure having at least one cyclic carbonate group and the polymerization of the monomer mixture (a) under free radical polymerization conditions to make an acrylic backbone polymer (b) comprising one or more cyclic carbonate functional groups (bi). At least one grafting moiety (c) is then provided, said grafting moiety (c) comprising at least one amine group (ci) selected from primary amines, secondary amines, and mixtures of both primary and secondary amines. The grafting moiety (c) is then grafted onto acrylic backbone polymer (b) via reaction between the at least one amine group (ci) and cyclic carbonate functional groups (bi) so as to make an urethanized acrylic graft polymer.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: October 17, 2006
    Assignee: BASF Corporation
    Inventors: Walter H. Ohrbom, Patricia A. Herrel, John W. Rehfuss
  • Patent number: 7122600
    Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material. The crosslinking agent includes a copolymer having at least 30 mol % of alternating structural units of a residue from a donor monomer and a residue from one or more acrylic acceptor monomers. The thermosetting composition may coat a substrate by coalescing the composition to form a continuous film and curing the composition. The thermosetting composition may be included as part of a multi-component composite coating composition that includes an optional primer coat, a base coat deposited from a pigmented film-forming composition, and a transparent top coat applied over the base coat, where either the base coat, the transparent top coat, or both, are deposited from the thermosetting composition.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: October 17, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Karen S. Rechenberg, Simion Coca, Karen A. Barkac, James B. O'Dwyer, Linda J. Bowser
  • Patent number: 7098272
    Abstract: The present invention provides a method for producing hydroxyl group-containing polymer particles including causing cross-linked polymer particles containing a (meth)acrylate polymer to react in the presence of a metal-containing ester-exchange reaction catalyst with at least one compound selected from the group consisting of a compound including at least two hydroxyl groups and a compound including at least one primary amino group and at least one hydroxyl group, the cross-linked polymer particles comprising the (meth)acrylate polymer represented by the following formula (I): wherein R1 represents a hydrogen atom or a methyl group; R2 to R4 may be the same or different from each other, and each independently represents a substituted or non-substituted alkyl group or a substituted or non-substituted aryl group, any one of which has 1 to 12 carbon atoms; and n represents an integer of 1 or more.
    Type: Grant
    Filed: February 24, 2004
    Date of Patent: August 29, 2006
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yoshihiro Inaba, Takako Kobayashi, Chisato Urano
  • Patent number: 7060752
    Abstract: Nitrophenol resins based upon various support materials. The nitrophenol resins are prepared by amide bond formation between a hydroxyl nitro benzoic acid and an aminoalkyl polymer support.
    Type: Grant
    Filed: October 28, 2003
    Date of Patent: June 13, 2006
    Assignee: New York University
    Inventors: Young-Tae Chang, Jaw Wook Lee
  • Patent number: 7012118
    Abstract: The present invention relates to a photopolymerizable composition, which comprises: (a) a block copolymer component comprising an unhydrogenated styrene diene block copolymer and a hydrogenated controlled distribution styrene diene block copolymer (b) one or more photopolymerizable ethylenically unsaturated low molecular weight compounds, (c) one or more polymerization initiators, and optionally (d) from 0 to 40% by weight, based on the total photopolymerizable compositions, of one or more auxiliaries. The invention also includes flexographic printing plates derived from said photopolymerizable compositions, and flexographic printing relief forms prepared from said plates.
    Type: Grant
    Filed: October 8, 2003
    Date of Patent: March 14, 2006
    Assignee: KRATON Polymers U.S. LLC
    Inventors: David Romme Hansen, David John St. Clair, Donn Anthony Dubois, Dale Lee Handlin, Jr., Carl Lesley Willis
  • Patent number: 6992137
    Abstract: A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: January 31, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 6881761
    Abstract: Disclosed are (1) a porous polymer particle comprising a polymer substrate having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, (2) an alkali-resistant, high-strength porous polymer particle having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, a part of the ester bonds being saponified and converted to a hydroxyl group(s), (3) a porous polymer particle comprising a polymer substrate having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, the porous polymer particles being treated with an alkaline solution to generate a hydroxyl and/or a carboxyl group on a surface of the substrate, (4) an anion exchanger comprising any one of the particles (1) to (3) above, (5) a packing material for anion chromatography comprising the anion exchanger (4) above, (6) a column for anion chromatography using the anion exchanger (4) above, and (7) a method for meas
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: April 19, 2005
    Assignee: Showa Denko K.K.
    Inventors: Takashi Kotsuka, Kuniaki Shimbo, Hiroshi Suzuki, Hisako Sakuma, Toshio Tokuda
  • Patent number: 6803107
    Abstract: Surface-treated superabsorbent polymer particles obtained by mixing 100 parts by weight of superabsorbent polymer particles with 0.001 to 10 parts by weight of a hydroxyalkylamide, and heating the surface-treated superabsorbent polymer particles to crosslink molecular chains existing at least in the vicinity of the surfaces of the superabsorbent polymer particles is disclosed. Surface crosslinking the superabsorbent polymer particles with a hydroxyalkylamide substantially increases both the rate of liquid absorption and the quantity of liquid absorbed and retained by the superabsorbent particles.
    Type: Grant
    Filed: May 16, 2003
    Date of Patent: October 12, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael A. Mitchell, David Eckert, Thomas W. Beihoffer
  • Publication number: 20040171705
    Abstract: A high-molecular flocculant rendered water-soluble by conversion of cyano groups contained in a high-molecular material, a method for producing the flocculant, and a method for efficiently processing water using the flocculant. A high-molecular material containing acrylonitrile as a monomer is processed safely to impart hydrophilicity to the material and the resulting product is used for water processing to contribute to environmental conservation. An amino compound is added to a cyano group containing high-molecular material to convert at least a portion of the cyano group (—C≡N) into a molecular structure portion having an imidamino structure and, if necessary, to convert at, least the portion into one of an acid salt, a quaternary ammonium salt or a hydrolyzate structure portion to give a high-molecular flocculant.
    Type: Application
    Filed: March 10, 2004
    Publication date: September 2, 2004
    Inventors: Yasuhito Inagaki, Haruo Watanabe, Tsutomu Noguchi
  • Patent number: 6784248
    Abstract: A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: August 31, 2004
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 6774193
    Abstract: Stabilized pre-promoted unsaturated polymer resin systems that include a tertiary aromatic amine cure promoter. The stabilized curable resins systems can include a vinyl ester resin.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: August 10, 2004
    Assignees: Albemarle Corporation, The University of Southern Mississippi
    Inventors: John Gabriel Santobianco, Robson F. Storey, Rajamani Nagarajan
  • Publication number: 20040127652
    Abstract: The invention relates to a rubber composition which contains an aminoalcohol as a tack retention additive. The invention also relates to a tire having a component of such rubber composition. The invention is further directed to a method of preparing a tire having tire tread ends or other rubber components joined together without an adhesive.
    Type: Application
    Filed: December 27, 2002
    Publication date: July 1, 2004
    Inventors: Ramendra Nath Majumdar, Lewis Timothy Lukich, Bruce Raymond Hahn, David W. Killian
  • Patent number: 6713580
    Abstract: The present invention relates to novel templates useful for generating novel compounds and to compounds produced utilizing the templates. The templates comprise quaternary amino acids that may be linked to solid supports. These templates make possible the production of novel classes of chemical compounds through a plurality of chemical reactions. The templates are advantageous for use in drug discovery regimes.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: March 30, 2004
    Assignee: Pharmacore, Inc.
    Inventors: Michael Johnson, Keqiang Li, Elso DiFranco, Daljit S. Dhanoa
  • Publication number: 20030176589
    Abstract: The present invention provides: a water-absorbing agent which has excellent urine resistance; a water-absorbing agent which has not only excellent urine resistance, but also excellent absorption properties that are stable to any composition of urine and show little change with time; and production processes and uses for these water-absorbing agents. The present invention water-absorbing agent exhibits a specific or larger value of absorption capacity under a load in a process in which the absorption capacity under a load is measured in a new manner using a specific liquid to be absorbed, and the present invention provides an absorbent matter and an absorbent article which display a specific or larger value of new absorption index as is, for example, led from the absorption capacity under a load or from the resin concentration using the above water-absorbing agent. The present invention further provides a production process for a water-absorbing agent having the above specific parameter.
    Type: Application
    Filed: March 3, 2003
    Publication date: September 18, 2003
    Applicant: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Hiroko Ueda, Naoko Takahashi, Kinya Nagasuna, Koji Miyake, Yasuhiro Fujita, Takumi Hatsuda
  • Patent number: 6599987
    Abstract: The present invention provides cured, compositions of matter that are non-swellable in water after curing. In general, the compositions comprise a water soluble copolymers comprising vinylpyrrolidone and glycidyl acrylate and a water soluble secondary aromatic amine or aliphatic ring diamine. The present invention further provides a cured composition of matter that is non-swellable in water after curing, comprising a water soluble copolymer comprising acrylamide and glycidyl methacrylate; and a water soluble secondary aromatic amine. The present invention also provides methods of preparation of the compositions and uses thereof.
    Type: Grant
    Filed: September 26, 2000
    Date of Patent: July 29, 2003
    Assignee: The University of Akron
    Inventors: Vassilios Galiatsatos, Yong-Chang Zheng
  • Patent number: 6599989
    Abstract: Water-absorbing agents containing polycarboxylic amine chelating agents. The water-absorbing agents are obtained by a process including the step of adding to a water-absorbent resin at least one chelating agent selected from the group consisting of polycarboxylic amines and maleic hydrophilic polymers. The polycarboxylic amine may be selected from a class that includes N-carboxymethyl-aspartic acid as one of its members or selected from a class that includes N,N′-bis(1,2-dicarboxyethyl)-ethylenediamine as one of its members. The water-absorbing agents have not only excellent urine resistance, but also excellent absorption properties that are stable to any composition of urine and show little change with time.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: July 29, 2003
    Assignee: Nippon Skokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Hiroko Ueda, Naoko Takahashi, Kinya Nagasuna, Koji Miyake, Yasuhiro Fujita, Takumi Hatsuda
  • Publication number: 20030119994
    Abstract: Copolymer prepared by polymerizing a branched neo vinyl ester component, an acidic component, and a component capable of providing a Tg of about −20° C. to 100° C. The copolymer can optimally be prepared in the presence of at least one surfactant. An amine neutralizing agent can be added to the copolymer.
    Type: Application
    Filed: August 6, 2002
    Publication date: June 26, 2003
    Inventors: Henry W. Yang, James R. Hester
  • Publication number: 20030100687
    Abstract: The invention relates to a method of making an acrylic graft polymer, especially a urethanized acrylic graft polymer. The method of the invention requires an ethylenically unsaturated monomer mixture (a) comprising a monomer (ai) of a particular structure having at least one cyclic carbonate group and the polymerization of the monomer mixture (a) under free radical polymerization conditions to make an acrylic backbone polymer (b) comprising one or more cyclic carbonate functional groups (bi). At least one grafting moiety (c) is then provided, said grafting moiety (c) comprising at least one amine group (ci) selected from primary amines, secondary amines, and mixtures of both primary and secondary amines. The grafting moiety (c) is then grafted onto acrylic backbone polymer (b) via reaction between the at least one amine group (ci) and cyclic carbonate functional groups (bi) so as to make an urethanized acrylic graft polymer.
    Type: Application
    Filed: November 29, 2001
    Publication date: May 29, 2003
    Inventors: Walter H. Ohrbom, Patricia A. Herrel, John W. Rehfuss
  • Patent number: 6541572
    Abstract: Disclosed is a two-step method of making soft, high refractive index, acrylic ophthalmic device materials. In the first step, a copolymer containing pendant oxirane groups is formed by copolymerizing one or more aryl acrylic hydrophobic monomers with one or more compounds of the formula wherein X is H or CH3; and n is 1-4. In the second step, the copolymer containing pendant oxirane groups formed in the first step is reacted with a compound of the formula W—T—H wherein W is H, CH3(CH2)a, or Z(OCH2CH2)b; a is 0-3; b is 1-5; Z is H, or CH3(CH2)p; p is 0-3; and T is O, NH, S; provided that if T≠O, then W≠H.
    Type: Grant
    Filed: September 17, 2001
    Date of Patent: April 1, 2003
    Assignee: Alcon Manufacturing, Ltd.
    Inventor: Albert R. LeBoeuf
  • Publication number: 20030027935
    Abstract: An acrylic rubber composition comprising 100 parts by weight of (a) an acrylic rubber having carboxyl groups, 0.3 to 8 parts by weight of (b) an aromatic secondary amine compound, and 0.3 to 8 parts by weight of (c) nickel dialkyldithiocarbamate. A crosslinkable acrylic rubber composition further comprising 0.1 to 10 parts by weight of a crosslinking agent in addition the ingredients (a), (b) and (c). By crosslinking the crosslinkable acrylic rubber composition, a crosslinked article having high heat resistance and exhibiting especially a reduced variation in elongation by heat load can be obtained.
    Type: Application
    Filed: July 29, 2002
    Publication date: February 6, 2003
    Inventors: Isao Kubota, Daisuke Tsugawa, Koichi Nishimura
  • Publication number: 20030018092
    Abstract: A high-molecular flocculant rendered water-soluble by conversion of cyano groups contained in a high-molecular material, a method for producing the flocculant, and a method for efficiently processing water using the flocculant. A high-molecular material containing acrylonitrile as a monomer is processed safely to impart hydrophilicity to the material and the resulting product is used for water processing to contribute to environmental conservation. An amino compound is added to a cyano group containing high-molecular material to convert at least a portion of the cyano group (—C≡N) into a molecular structure portion having an imidamino structure and, if necessary, to convert at, least the portion into one of an acid salt, a quaternary ammonium salt or a hydrolyzate structure portion to give a high-molecular flocculant.
    Type: Application
    Filed: August 23, 2001
    Publication date: January 23, 2003
    Inventors: Yasuhito Inagaki, Haruo Watanabe, Tsutomu Noguchi
  • Publication number: 20020120074
    Abstract: The present invention provides: a water-absorbing agent which has excellent urine resistance; a water-absorbing agent which has not only excellent urine resistance, but also excellent absorption properties that are stable to any composition of urine and show little change with time; and production processes and uses for these water-absorbing agents. The present invention water-absorbing agent exhibits a specific or larger value of absorption capacity under a load in a process in which the absorption capacity under a load is measured in a new manner using a specific liquid to be absorbed, and the present invention provides an absorbent matter and an absorbent article which display a specific or larger value of new absorption index as is, for example, led from the absorption capacity under a load or from the resin concentration using the above water-absorbing agent. The present invention further provides a production process for a water-absorbing agent having the above specific parameter.
    Type: Application
    Filed: February 22, 1999
    Publication date: August 29, 2002
    Inventors: KATSUYUKI WADA, HIROKO UEDA, NAOKO TAKAHASHI, KINYA NAGASUNA, KOJI MIYAKE, YASUHIRO FUJITA, TAKUMI HATSUDA
  • Patent number: 6335398
    Abstract: A super absorbent polymer composition comprising a chelating compound (A) which has a site capable of forming a chelate with a copper ion and whose copper salt has a solubility in physiological saline at 25° C. of 0.01% by weight or less and a super absorbent polymer (B), wherein the chelating compound (A) is present in an amount of from 0.0001 to 30 parts by weight per 100 parts by weight of said super absorbent polymer (B).
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: January 1, 2002
    Assignee: Kao Corporation
    Inventors: Takayuki Amiya, Seiichi Miyanaga, Yoko Hanada
  • Publication number: 20010053826
    Abstract: A superabsorbent resin composition comprising the following components
    Type: Application
    Filed: July 3, 2001
    Publication date: December 20, 2001
    Applicant: Kao Corporation
    Inventors: Yasunori Hosokawa, Tadashi Igarashi, Isao Tsuru, Yoko Hanada
  • Patent number: 6316507
    Abstract: A high-molecular flocculant rendered water-soluble by conversion of cyano groups contained in a high-molecular material, a method for producing the flocculant, and a method for efficiently processing water using the flocculant. A high-molecular material containing acrylonitrile as a monomer is processed safely to impart hydrophilicity to the material and the resulting product is used for water processing to contribute to environmental conservation. An amino compound is added to a cyano group containing high-molecular material to convert at least a portion of the cyano group (—C≡N) into a molecular structure portion having an imidamino structure and, if necessary, to convert at least the portion into one of an acid salt, a quaternary ammonium salt or a hydrolyzate structure portion to give a high-molecular flocculant.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: November 13, 2001
    Assignee: Sony Corporation
    Inventors: Yasuhito Inagaki, Harou Watanabe, Tsutomu Noguchi
  • Patent number: 6303703
    Abstract: The present invention provides a new and improved method of producing halogen-free oligomeric olefin monoamines which avoids the use of costly high-pressure and high-temperature equipment. In one embodiment the method comprises epoxidizing a specific class of oligomeric olefins to provide an epoxidized oligomeric olefin, converting the epoxidized oligomeric olefin to an aldehyde, converting the aldehyde to an oxime and then converting the oxime to an amine. Alternatively, the aldehyde may be formed directly from the oligomeric olefin. In an alternative embodiment, the method comprises converting the aldehyde to a formamide intermediate, and then using hydrolysis to convert the formamide to the oligomeric olefin monoamine. In another preferred embodiment the method includes converting an oligomeric olefin directly to an aldehyde, converting the aldehyde to an oxime and then reducing the oxime to provide the oligomeric olefin monoamine.
    Type: Grant
    Filed: October 13, 1999
    Date of Patent: October 16, 2001
    Assignee: Ferro Corporation
    Inventors: James D. Kinder, Larry J. Baldwin, James L. Dever, Kevin M. Sonby, Daniel P. Taylor
  • Patent number: 6300411
    Abstract: The present invention discloses an aqueous resin composition containing (A) a copolymer of (a) a monomer having one or more aldehyde groups or ketone groups, and a radical polymerizable unsaturated bond, in a molecule, with (b) a monomer having a radical polymerizable unsaturated bond copolymerizable with the monomer (a); (B) a hydrazine compound of the following formula (1) where R1, R2, R3 and R4 independently represent a hydrogen atom, or a hydroxyl group, p denotes an integer of 0 to 3, and q denotes an integer of 2 to 8, provided that the relationships p+q≦8 and p<q are satisfied; and an aqueous medium. When the aqueous resin composition of the present invention is applied and then dried, a film excellent in film intactness, transparency, whitening after water immersion, and adhesion after water immersion can be formed.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: October 9, 2001
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toshiya Seko, Kazuhide Hayama, Yasuo Kitani, Kazumasa Kinugasa
  • Publication number: 20010020070
    Abstract: Water-soluble homo- and/or copolymers containing alkali metal and/or alkaline earth metal carboxylate groups and based on acrylic or methacrylic derivatives, and corresponding water-soluble homo- and/or copolymers containing carboxyl groups and homo- and/or copolymers containing ammonium carboxylate groups are provided, which homo- and/or copolymers possess excellent suitability for increasing the viscosity of aqueous systems, in particular of print pastes for textile treatment.
    Type: Application
    Filed: February 1, 2001
    Publication date: September 6, 2001
    Inventors: Thomas Gross, Siegfried Korte, Rolf-Volker Meyer, Hans-Jorg Seiler
  • Patent number: 6281296
    Abstract: Perfluoroelastomer compositions comprising perfluoroelastomers having copolymerized units of tetrafluoroethylene, a perfluoro(vinyl ether), and a nitrile-containing cure site monomer are cured with compounds that are capable of generating ammonia at temperatures of 40° C.-330° C. to produce cured compositions having excellent thermal stability. The ammonia-generating compounds also act as cure accelerators in perfluoroelastomer compositions that incorporate other curing agents.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: August 28, 2001
    Assignee: DuPont Dow Elastomers L.L.C.
    Inventors: James Daniel MacLachlan, Peter Arnold Morken, Walter Werner Schmiegel, Kohtaro Takahashi
  • Patent number: 6262183
    Abstract: Hydroxamic acid polymers which are comprised of hydroxamic groups and carboxylic acid groups wherein the carboxylic acid groups constitute less than about 3% of the functional groups. The polymers hereof are also especially useful in biomedical applications because, for example, the low concentration of carboxylic acid groups decreases the incidence of bioincompatibility. Additionally, the polymers exhibit anticoagulant activity, urease inhibition activity, metal chelating activity and ion exchange activity.
    Type: Grant
    Filed: March 28, 1994
    Date of Patent: July 17, 2001
    Assignee: Cytec Technology Corp.
    Inventors: Abraham J. Domb, Robert S. Langer, Ernest G. Cravalho, Gershon Golomb, Edith Mathiowitz, Cato T. Laurencin
  • Patent number: 6228950
    Abstract: A novel high-purity polymer dispersant and sludge conditioner added to the feedwater entering the secondary side of a nuclear steam generator for minimizing the accumulation of metal-oxide deposits within the nuclear steam generator during the continuing operation of the generator is disclosed. The high-purity polymer is selected from a group consisting of acrylic acid polymer, methacrylic acid polymer, acrylate polymer, methacrylate polymer, copolymers, and terpolymers, acrylate/acrylamide copolymer, acrylate/methacrylate copolymer, terpolymers, and mixtures thereof. Methods of making and applying the polymer dispersant and sludge conditioner are described. Means for removing the metal oxides and polymer from the blowdown stream are disclosed.
    Type: Grant
    Filed: December 8, 1998
    Date of Patent: May 8, 2001
    Assignees: Commonwealth Edison Company, Betz Dearborn Inc.
    Inventors: Phillip M. Egerbrecht, Joseph D. Bates, John A. Kelly, James D. Haff, Ralph Minnis
  • Patent number: 6221970
    Abstract: Curable perfluoroelastomer compositions are disclosed that comprise ammonia and uncured perfluorinated elastomers having copolymerized units of nitrile-containing cure site monomers. Such compositions are curable at low temperatures. In addition, curable perfluoroelastomer compositions are disclosed wherein ammonia functions as a cure rate accelerator in the presence of other curing agents.
    Type: Grant
    Filed: August 6, 1999
    Date of Patent: April 24, 2001
    Assignees: E.I. DuPont de Nemours and Company, DuPont Dow Elastomers, L.L.C.
    Inventors: Peter Arnold Morken, Walter Werner Schmiegel
  • Patent number: 6180724
    Abstract: An absorbing agent has a diffusing absorbency under pressure of not less than 25 g/g when 60 minutes elapsed after absorption is started, and a water-soluble content is above 0 percent by weight and not more than 7 percent by weight. The absorbing agent is prepared by surface-crosslinking a precursor of the absorbing agent obtained by performing an aqueous solution polymerization of a hydrophilic unsaturated monomer having not less than 50 mole percent neutralized acrylic acid as a main component using a specific crosslinking agent having a main component composed of an ester compound of a specific polyhydroxy alcohol and an unsatuated carboxylic acid, and a high-boiling component having at least two alcohol structures in a molecule as a specific ratio.
    Type: Grant
    Filed: June 11, 1999
    Date of Patent: January 30, 2001
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Kinya Nagasuna, Shin-ichi Fujino, Yoshihiko Masuda
  • Patent number: 6114452
    Abstract: Perfluoroelastomer compositions are provided which have excellent high temperature properties. The perfluoroelastomer component of the compositions are copolymers having a plurality of carbonyl-containing functional groups and copolymerized monomer units comprising a perfluoroolefin, a perfluoro(vinyl) ether and a nitrile-containing cure site monomer. The curative component is other than an organotin compound and includes peroxides, ammonium salts, aromatic amino compounds, bisamidrazones, and bisamidoximes.
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: September 5, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Walter Werner Schmiegel
  • Patent number: 6114470
    Abstract: Methods of promoting the cure of unsaturated polymer resins with a peroxide initiator by including as a promotor N-alkyl-N-(2-hydroxyalkyl)-p-toluidines. The use of the tertiary aromatic amines as a promotor provides a fast cure at a wide range of temperatures. Polymerizable compositions and methods of applying the same to a surface are also described.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: September 5, 2000
    Assignee: First Chemical Corporation
    Inventors: John Gabriel Santobianco, Cary Cecil Geiger, Joseph Stanton Bowers, Jr.
  • Patent number: 6111027
    Abstract: This invention relates to an adhesive composition comprising a copolymer comprising units derived from one or more macromonomers and an unsaturated acid or an unsaturated anhydride wherein the weight average molecular weight of the copolymer is at least twice the weight average molecular weight of the macromonomer, the melt index of the copolymer is 1 dg/min or more, and wherein the macromonomer:(1) has a weight average molecular weight between 500 and 100,000;(2) has at least 30% terminal unsaturation; and(3) comprises a copolymer of ethylene and at least one .alpha.-olefin, and/or a copolymer of propylene and ethylene or an .alpha.-olefin.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: August 29, 2000
    Assignee: Exxon Chemical Patents, Inc
    Inventors: Pamela J. Wright, Dennis George Peiffer, Kenneth Lewtas, Quoc Luvinh, Joseph Jacques Ripet, Anne Vera Macedo
  • Patent number: 6100224
    Abstract: A copolymer comprising units of an unsaturated dicarboxylic monomer and an ethylene .alpha.-olefin macromer is disclosed. The macromer is an unsaturated ethylene .alpha.-olefin polymer comprising units of from ethylene and at least one .alpha.-olefin represented by the formula CH.sub.2 .dbd.CHR.sup.a, wherein R.sup.a is a C.sub.1 to C.sub.18 linear alkyl group or a C.sub.3 to C.sub.18 branched alkyl group; the ethylene .alpha.-olefin polymer has a number average molecular weight of from about 500 to about 100,000; and at least about 30% of the unsaturation in the ethylene .alpha.-olefin polymer is terminal vinylidene. The copolymer has a carbon-carbon backbone and contains succinic groups and hydrocarbyl groups. The copolymer can be derivatized by reaction with nucleophilic reactants including monoamines, polyamines, monoalcohols, polyols, amino alcohols, reactant metal compounds and mixtures thereof. The derivatized copolymers can be post-treated (e.g., borated) with one or more post-treating agents (e.g.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: August 8, 2000
    Assignee: Exxon Chemical Patents Inc
    Inventors: Dennis G. Peiffer, Kenneth Lewtas, Robert D. Lundberg, Pamela J. Wright, Antonio G. Lazarus, Jacob Emert
  • Patent number: 6077903
    Abstract: There is a need for polymers which are utilized in automotive interiors which offer increased heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance. This invention discloses a continuous process for preparing a rubbery polymer which can be blended with polyvinyl chloride to make leathery compositions having good heat and ultraviolet light resistance. This technique involves utilizing a multiple continuous reactor system wherein a first phase monomer solution containing butyl acrylate, an acrylic monomer, acrylonitrile and a crosslinking agent is continuously charged into at least three initial reactors. To attain a small particle size, it is necessary to limit the solids content in each of these initial reactors.
    Type: Grant
    Filed: May 12, 1998
    Date of Patent: June 20, 2000
    Assignee: The Goodyear Tire Rubber Company
    Inventor: Hung Dang Ngoc
  • Patent number: 6054541
    Abstract: An absorbing agent has a diffusing absorbency under pressure of not less than 25 g/g when 60 minutes elapsed after absorption is started, and a water-soluble content is above 0 percent by weight and not more than 7 percent by weight. The absorbing agent is prepared by surface-crosslinking a precursor of the absorbing agent obtained by performing an aqueous solution polymerization of a hydrophilic unsaturated monomer having not less than 50 mole percent neutralized acrylic acid as a main component using a specific crosslinking agent having a main component composed of an ester compound of a specific polyhydroxy alcohol and an unsatuated carboxylic acid, and a high-boiling component having at least two alcohol structures in a molecule as a specific ratio.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: April 25, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Kinya Nagasuna, Shin-ichi Fujino, Yoshihiko Masuda
  • Patent number: 5976382
    Abstract: There is provided water insoluble cross-linked polycarboxylic acid having at least two strands in a strand skeleton of the formula: ##STR1## wherein one carbonyl group of at least one maleoyl moiety thereof in each strand is covalently linked to a--HN.[(H).sub.p (CH).sub.2.(OH).sub.m ].NH-- moietyto provide the presence therein of at least one cross linked moiety of the formula: ##STR2## wherein R is hydrogen or lower alkylene or lower alkoxy of 1-4 carbon atoms, or phenyl, x and y are integers, z is an integer of 1-6, p is 0 or an integer up to z-1, m is 0 or an integer up to z, and w is an integer from 2-12. There is disclosed a method of making such polycarboxylic acid as well as methods of utilizing same to remove proteins from aqueous media containing same to provide a matrix. Methods are disclosed for recovering proteins from said matrix without denaturing them and methods for recovering the polycarboxylic acid from said matrix.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: November 2, 1999
    Assignee: LigoChem, Inc.
    Inventor: John Krupey
  • Patent number: 5973080
    Abstract: The process includes the reaction of a chloro-formamidinium chloride with a polystyrene-divinylbenzene resin functionalized with primary amine groups. The resins which can be obtained according to this process may in particular have a spacer arm of general formula (IV): ##STR1## with X representing oxygen or sulphur and m being equal to 1 or 2. This spacer arm bears at its end, on the right, a primary amine group or a guanidine group.
    Type: Grant
    Filed: January 27, 1998
    Date of Patent: October 26, 1999
    Assignee: Elf Aquitaine Production
    Inventors: Pierre Le Perchec, Marie Abiuso, Emmanuel Arretz
  • Patent number: 5952438
    Abstract: Polymeric polyamines obtainable by reacting linear, alternating carbon monoxide/1-alkene copolymers with ammonia or amines of the formula (I)R--NH.sub.2 (I)where R is --NH.sub.2, --OH, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.20 -aryl, C.sub.7 -C.sub.20 -arylalkyl, C.sub.7 -C.sub.20 -alkylaryl or an organosilicon radical having 3 to 30 carbon atoms,or with a reagent which releases ammonia or the amine (I), and subsequent hydrogenation.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: September 14, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Detlef Kratz, Ferdinand Lippert, Peter Schwab, Dieter Boeckh, Johannes Perner
  • Patent number: 5932665
    Abstract: By carefully adjusting the molecular weight and amounts of methacrylic acid and maleic acid and/or maleic anhydride comonomers in polyacrylic acid-based fiberglass binders, binder-treated fiberglass cured and B-staged product throughput may be maintained at production rates designed for phenol/formaldehyde binders due to the lower thermal requirements for cure as compared to homopolyacrylic acid-based binder systems.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: August 3, 1999
    Assignee: Johns Manville International, Inc.
    Inventors: Craig Donald DePorter, Thomas John Taylor
  • Patent number: 5891956
    Abstract: Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: April 6, 1999
    Assignee: The Regents of the University of California, Office of Technology Transfer
    Inventors: Barbara F. Smith, Thomas W. Robison, Joel W. Gohdes
  • Patent number: RE38444
    Abstract: An absorbing agent has a diffusing absorbency under pressure of not less than 25 g/g when 60 minutes elapsed after absorption is started, and a water-soluble content is above 0 percent by weight and not more than 7 percent by weight. The absorbing agent is prepared by surface-crosslinking a precursor of the absorbing agent obtained by performing an aqueous solution polymerization of a hydrophilic unsaturated monomer having not less than 50 mole percent neutralized acrylic acid as a main component using a specific crosslinking agent having a main component composed of an ester compound of a specific polyhydroxy alcohol and an unsaturated carboxylic acid, and a high-boiling component having at least two alcohol structures in a molecule as a specific ratio.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: February 24, 2004
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Kinya Nagasuna, Shin-ichi Fujino, Yoshihiko Masuda