Amine Contains A Hydroxyl Group Patents (Class 525/380)
  • Patent number: 5369184
    Abstract: Resins which comprise polymers which contain multiple acetal groups have been developed which are useful for crosslinking and adhesion promotion in coating and adhesive applications. The polymers which make up these resins are prepared by the addition of aminoacetals to polymers containing anhydride functionality. The polymers are modified by titration with ammonia or a primary or secondary amine which solubilizes the polymer in aqueous systems.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: November 29, 1994
    Assignee: Air Products and Chemicals, Inc.
    Inventors: William F. Burgoyne, Jr., Jeremiah P. Casey, Thomas A. Manuel
  • Patent number: 5369189
    Abstract: The present invention relates to a process for the preparation of heat resistant and transparent acrylic resin which is characterized by imidizing methacrylic resin in a solution with primary amine or the ammonia compounds generating primary amine in the presence or absence of catalyst and under a suitable temperature condition. The reaction product is the compound of formula (I) comprising more than 10% by weight of imidized structure unit. Formula (I) wherein R.sub.1, R.sub.2 and R.sub.3 independently represent a hydrogen atom, or unsubstituted and substituted C.sub.1 to C.sub.20 alkyl, cycloalkyl, aryl, aralkyl, alkaryl, or mixtures thereof.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: November 29, 1994
    Assignee: Lucky, Ltd.
    Inventors: Jin B. Kim, Young S. Hur
  • Patent number: 5362816
    Abstract: A pressure-sensitive adhesive having improved shear strength obtained by virtue of the formation of the enamine of a pendent acetoacetate is described. These materials contain acetoacetate functional monomer in a low Tg emulsion polymer. Shear strength is improved without compromise of either peel strength or tack.
    Type: Grant
    Filed: June 4, 1992
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Barry S. Snyder, Daniel A. Bors
  • Patent number: 5349023
    Abstract: A vinyl alcohol copolymer having a terminal amino group and comprising 1-90 mol % of vinyl alcohol units and 10-90 mol % vinyl monomers selected from the group consisting of olefins, acrylamides, methacrylamides, vinyl ethers, nitriles, vinyl halides, and vinylidene halides, said copolymer having at least one terminal amino group is useful for preparing resin compositions having good gas barrier properties.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: September 20, 1994
    Assignee: Kuraray Co., Ltd.
    Inventors: Kaoru Ikeda, Toshiaki Sato
  • Patent number: 5346965
    Abstract: A process for preparing a polybutene amine composition comprises the steps of reacting a chlorinated polybutene with an excess of at least one mole of at least one type of an amine compound per mole of the chlorinated polybutene at a reaction temperature of at least about 100.degree. C.; neutralizing the reaction mixture with a base selected from the group of alkali metal and alkaline earth metal alkoxides and amides with formation of one of an alcohol or ammonia, respectively; neutralizing any excess base with an acid that will produce essentially no water as a by-product; and recovering the polybutene amine composition, the process including the steps of removing the alcohol or ammonia in a timely fashion; and removing excess of the amine compound.
    Type: Grant
    Filed: August 19, 1993
    Date of Patent: September 13, 1994
    Assignee: Ferro Corporation
    Inventors: James L. Dever, Mannat C. Menon, Steven D. Phillips, Larry J. Baldwin
  • Patent number: 5342901
    Abstract: The invention provides a film-formable, chelate-forming resin having, per 1000 g of the resin, about 0.2 to about 3.5 moles of chelate-forming group represented by the formula [1], [2], [3] or [4]: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and each represents a hydrogen atom, a halogen atom, a nitro group, a nitroso group, a cyano group, a hydrocarbon group having up to 18 carbon atoms, or an alkoxyalkyl group having up to 12 carbon atoms, and a process for preparing the resin.The invention also provides a metal surface treating composition and a corrosion preventive coating composition both containing the above chelate-forming resin, and a chelate-forming resin composition comprising the resin and a crosslinking agent.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: August 30, 1994
    Assignee: Kansai Paint Company, Limited
    Inventors: Hideo Kogure, Heihachi Murase, Masafumi Kume
  • Patent number: 5328179
    Abstract: Gasketing paper is commonly made by the beater addition process. In the beater addition process a furnish composition is prepared by mixing latex into a fiber slurry which also typically contains one or more fillers. The beater addition process is currently being scrutinized because of environmental concerns. More specifically, conventional lattices used in the beater addition process contain curatives, such as amines, sulfur, and zinc compounds, which are discharged into the environment via the affluent from the process. By practicing the process of this invention gasketing paper can be manufactured by an environmentally sound technique. In one embodiment of this invention gasketing paper is made by beater addition with the latex utilized in the process being comprised of (a) at least one rubber having both pendant blocked isocyanate groups and groups containing at least one active Zerewitinoff hydrogen, (b) at least one emulsifier, and (c) water.
    Type: Grant
    Filed: November 4, 1991
    Date of Patent: July 12, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Joel Muse, Dane K. Parker, Robert F. Roberts
  • Patent number: 5324790
    Abstract: A process for esterifying a polymer containing carboxyl(ate) groups, by maintaining the polymer at 0.degree. C. to 200.degree. C., where the counterion for the carboxylate groups is a selected ammonium or sulfoxonium ions. Such processes are useful for preparing improved films and coatings, particularly automotive coatings.
    Type: Grant
    Filed: September 29, 1992
    Date of Patent: June 28, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Lewis E. Manring
  • Patent number: 5317063
    Abstract: A water-soluble polymer sensitive to salts is a copolymer of (A) 10 to 90% of acrylic acid and/or methacrylic acid; and (B) 90 to 10% of a vinyl monomer of Formula (I): ##STR1## (wherein R represents a hydrogen atom or a methyl group; and R.sup.1 represents an aryl group or a cycloalkyl group); or the foregoing component (A); (B) 2 to 70% of a vinyl monomer of Formula (II): ##STR2## (wherein R.sup.2 represents an alkyl group, an aryl group or a cycloalkyl group); and (C) 2 to 40% of a vinyl monomer of Formula (III): ##STR3## (wherein R.sup.3 represents an aryl group), 2 to 70 mole % of the repeating units derived from the acrylic acid and/or methacrylic acid being in the form of a salt. It is soluble in tap water, but insoluble in an aqueous solution containing not less than 0.5% of an inorganic salt of a monovalent ion.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: May 31, 1994
    Assignee: Lion Corporation
    Inventors: Masanori Komatsu, Yasuo Iida
  • Patent number: 5296530
    Abstract: This invention relates to a method for light-assisted curing of coatings by providing coatings with an enamine content sufficient to enhance the cure rate of the coatings. The coatings exhibit improved weatherability and gloss retention when exposed to light.
    Type: Grant
    Filed: July 28, 1992
    Date of Patent: March 22, 1994
    Assignee: Rohm and Haas Company
    Inventors: Daniel A. Bors, William D. Emmons, Steven S. Edwards
  • Patent number: 5294681
    Abstract: There is provided water insoluble cross-linked polyhydroxy polycarboxylic acid having at least two strands each having a strand skeleton of the formula: ##STR1## wherein one carbonyl group of at least one maleoyl moiety thereof in each strand is covalently linked to a--HN.[(H).sub.p (CH).sub.z.(OH).sub.m ].NH-- moietyto provide the presence therein of at least one cross linking moiety of the formula: ##STR2## wherein R is hydrogen or lower alkylene or lower alkoxy of 1-4 carbon atoms, or phenyl, z is an integer of 1-4, p is 0 or an integer up to z-1, m is 1 or an integer up to z, wherein the ratio of cross-links to poly (alkylene carbonic acid) strands is between about 1 and about 200 to 2. There is disclosed a method of making such polyhydroxy polycarboxylic acid as well as methods of utilizing same to remove proteins from aqueous media containing same to provide a matrix.
    Type: Grant
    Filed: March 20, 1992
    Date of Patent: March 15, 1994
    Assignee: Affinity Technology, Inc.
    Inventor: John Krupey
  • Patent number: 5292813
    Abstract: This invention relates to novel compositions of matter, fullerene graft amine-containing polymers, and the process of making them. The graft is made by reacting a fullerene with a primary or secondary amine-containing polymer, preferably a hydrocarbon containing polymer in effective amounts, typically from about 10:1 to about 1:10 mole ratio of reactive amine in polymer to fullerene for a time and under conditions effective to produce the compositions. Suitable starting polymers are those containing primary or secondary amino groups, e.g., EPDM amine, PIB-amine, PIBSA-PAM, and Mannich based polymers. The preferred polymers are oil soluble, as the novel compositions of that type may be used as viscosity modifiers and lube additives. The crosslinked compositions may be used in essentially any application as the original polymer, but in which an increase in tensile strength would be desired.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: March 8, 1994
    Assignee: Exxon Research & Engineering Co.
    Inventors: Abhimanyu O. Patil, George W. Schriver, Robert D. Lundberg
  • Patent number: 5278248
    Abstract: Water-soluble polymers and/or copolymers possessing enhanced biodegradability, and their applications are disclosed.Acrylic and/or vinyl polymers and/or copolymers containing acid groups, in which 35% to 90% of the active acid sites are neutralized by magnesium ions, the specific viscosity is at most 25, and biodegradability is enhanced. Their decomposition after 36 days is greater than 50% as measured by the modified Sturm test.These polymers can be used in industries as varied as: paper-making, paints, plastics, petroleum, drilling fluids, water treatment, detergents, cosmetics, textiles, inks, leather, grinding and/or splitting of minerals in water.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: January 11, 1994
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Georges Ravet, Jacky Rousset
  • Patent number: 5278249
    Abstract: A curable coating composition comprises a hydroxy-functional component (A) having at least two hydroxy groups per molecule and an anhydride-functional component (B) having at least two carboxylic acid anhydride groups per molecule. At least one of the components (A) and (B) is a film-forming polymer. The coating composition contains amidine groups for accelerating the curing reaction between the hydroxy groups of component (A) and the anhydride groups of component (B). The amidine groups are present in the molecule of either of the components (A) or (B) and/or are present in the form of a separate compound containing an amidine group. The component or compound containing an amidine group generally has the formula ##STR1## in which R.sup.1 represents hydrogen, or an organic group attached through a carbon atom, or an amine group which can be substituted, or a hydroxy group or etherified hydroxy group; R.sup.2 and R.sup.
    Type: Grant
    Filed: January 10, 1992
    Date of Patent: January 11, 1994
    Assignee: Courtaulds Coatings (Holdings) Limited
    Inventor: Alastair R. Marrion
  • Patent number: 5276103
    Abstract: A uranium adsorbent is prepared by reacting a polymer containing nitrile groups with hydroxylamine, wherein the amount of imidedioxime groups formed is relatively larger than that of amidoxime groups formed in terms of the integral values of areas of peaks respectively assigned to imidedioxime groups and amidoxime groups in the .sup.13 C-NMR spectrum chart of the adsorbent. The reaction may be effected: 1) in an organic solvent containing water under substantially neutral or weakly alkaline conditions, or 2) under acidic conditions. The uranium adsorptivity of the adsorbent is improved by hydrolyzing its residual nitrile groups under alkaline conditions.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: January 4, 1994
    Assignee: Goran Lagstrom
    Inventors: Kobuke Yoshiaki, Yoshida Shigeto
  • Patent number: 5270369
    Abstract: A composition comprising a polyolefin and a hydroxylamine is disclosed as having improved clarity and viscosity. In addition, a method of reducing the viscosity and improving the clarity of a polyolefin is disclosed, wherein the process comprises visbreaking the polyolefin in the presence of a hydroxylamine.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: December 14, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Kenneth W. Willcox, Francis X. Mueller, Jr.
  • Patent number: 5264528
    Abstract: Copolymers of 4-hydroxystyrene are produced by hydrolyzing copolymers of 4-acetoxystyrene with hydroxylamine.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: November 23, 1993
    Assignee: Hoechst Celanese Corporation
    Inventors: Michael T. Sheehan, Brad L. Smith
  • Patent number: 5258468
    Abstract: Permanently antistatic polyacrylate resin articles, antistatic polyacrylate resin compositions, and process for making them are described. The antistatic articles and compositions are obtained by reacting pendant ester groups on the surface of polyacrylate resin articles or on the chains of the polyacrylate resin compositions with dialkanolamines. The dialkanolamines used are typically dialkanolamines with lower alkanol groups, i.e. groups containing 1 to 4 carbon atoms. A preferred polyacrylate resin composition is poly(methyl methacrylate). A preferred alkanolamine is diethanolamine.
    Type: Grant
    Filed: April 16, 1991
    Date of Patent: November 2, 1993
    Inventor: Raj Chakrabarti
  • Patent number: 5254636
    Abstract: This invention relates to a process which significantly reduces the time for hydrolyzing a crosslinked maleic anhydride/lower alkyl vinyl ether copolymer to a clear gel which comprises suspending or dispersing fine granules of the crosslinked copolymer in deionized water and agitating the resulting dispersion or suspension for a period of between about 15 and about 130 minutes at a temperature of from about 60.degree. to about 90.degree. C. and then cooling the hydrolyzed mixture before introducing a basic neutralizing agent at a temperature of from about 15.degree. to about 85.degree. C. to produce a clear, homogeneous hydrolyzed gel having a Brookfield viscosity of from 5,000 to 250,000 cps.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: October 19, 1993
    Assignee: ISP Investments Inc.
    Inventors: Yoon T. Kwak, Stephen L. Kopolow
  • Patent number: 5252628
    Abstract: A method of making pigmented hydrophilic polymers in such a manner that the resulting polymers absorb ultraviolet and visible radiation, and that no migration, separation or leaching of the pigment can take place, is disclosed. The polymer compositions comprise blends of hydrophilic polymers with melanin pigments, the latter being synthesized on the hydrophilic polymer matrix. The disclosed polymer compositions are useful in the manufacture of ocular devices, particularly intraocular lenses and aphakic contact lenses capable of absorbing ultraviolet and visible radiation, at wavelengths between 300 and 700 nanometers, to the same extent as the natural crystalline lens of the eye. The disclosed method is also useful to impart photoprotective properties to the already made said ocular devices.
    Type: Grant
    Filed: December 7, 1989
    Date of Patent: October 12, 1993
    Assignee: Lions Eye Institute of Western Australia, Inc.
    Inventors: Traian V. Chirila, Ian J. Constable, Richard L. Cooper
  • Patent number: 5247018
    Abstract: A modified thermoplastic resin or elastomer composition having excellent paint adhesion is obtained by dynamically heat-treating a peroxide-crosslinkable olefin type copolymer and/or an olefin type plastic and a monomer containing at least one amino group and/or an unsaturated carboxylic acid or a derivative thereof in the presence of an organic peroxide. This thermoplastic resin or elastoemr composition is valuable as a material for an interior automotive trim. If a layer of this thermoplastic elastomer composition is laminated with a polyurethane layer, a laminate having excellent tensile strength and heat resistance, which is especially valuable as an interior trim of a vehicle such as an automobile, is obtained.
    Type: Grant
    Filed: May 20, 1992
    Date of Patent: September 21, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshikyuki Maeda, Yasuhiko Otawa, Katsuo Okamoto
  • Patent number: 5241003
    Abstract: Succinimides, succinic esters, and succinic ester-amides are formed by (A) reacting (i) at least one substantially aliphatic polymer of at least one lower olefin, and (ii) an acidic reactant or a mixture of two or more acidic reactants represented by the general formulaR--CO--CH.dbd.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: August 31, 1993
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventors: David J. Degonia, Paul G. Griffin
  • Patent number: 5231140
    Abstract: The invention relates to a process for the preparation of (meth)acrylate polymers with side-chain, non-linear optical chromophores and molecular weights of from 5000 to 5000000, which comprises reacting polymers of (meth)acryloyl chloride in solution with D-.omega.-hydroxyalkyl chromophores of the formula (I) or the alcoholates thereof ##STR1## where D is an electron donor,A is an electron acceptor,X is CH and/or N, and m is from 2 to 11.The polymers can be used in optical components.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: July 27, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Heike Kilburg, Karl-Heinz Etzbach, Karin H. Beck, Peter Strohriegl, Harry Mueller, Oskar Nuyken
  • Patent number: 5229466
    Abstract: The present invention relates to a powdery absorbing material for aqueous liquids based on a water-swellable powdery polymer having at least 0.2 equivalents carboxyl groups per 100 parts by weight which are neutralized by 50 to 99, advantageously by at least 80 mole %. The powdery absorbing material is obtained by treating the water-swellable carboxyl-groups-containing polymer with a solution of an N-(hydroxyalkyl).beta.-(meth)-alanine ester or with the polycondensation products thereof. As a solvent for the powdery absorbing material, water is used which either contains water-miscible organic diluents which evaporate on heating, or non-evaporative water-miscible organic diluents, i.e., diluents remaining in the polymer.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: July 20, 1993
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Brehm, Richard Mertens
  • Patent number: 5223582
    Abstract: The present invention relates to polymers capable of oxidative crosslinking, characterized in that they contain 10 to 80% by weight of structural units corresponding to formula (I) and/or (Ia) ##STR1## wherein R.sub.1 is an aliphatic saturated hydrocarbon radical containing 2 to 6 carbon atoms, provided that at least 2 carbon atoms are arranged between the nitrogen atom and the oxygen atom, andR.sub.2 at least 30% of the substituents R are monoolefinically or polyolefinically unsaturated hydrocarbon radicals and the remainder, i.e. up to 70% of the substituents R.sub.2, are saturated aliphatic and/or aromatic hydrocarbon radicals which may optionally contain oxygen and/or nitrogen as hetero atoms in the form of ether, ester, keto, urethane, urea and/or amide groups, provided that substituent R.sub.2 contains at least 2.0% by weight, based on the weight of the polymer, of aliphatically unsaturated double bonds, expressed as C.dbd.C (molecular weight=24).
    Type: Grant
    Filed: October 10, 1991
    Date of Patent: June 29, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Lothar Fleiter
  • Patent number: 5216086
    Abstract: Polymers tagged with pendant fluorescent groups are prepared by the (trans)amidation derivatization of pre-existing polymers having carbonyl-type pendant groups. Polymers having pendant amide groups wherein the amide nitrogen is substituted with fluorescent moieties, prepared by (trans)amidation derivatization, are provided. Polymers having pendant (sulfonated) napthalene moieties substituted to amide nitrogen are provided.
    Type: Grant
    Filed: April 29, 1992
    Date of Patent: June 1, 1993
    Assignee: Nalco Chemical Company
    Inventors: Dodd W. Fong, John E. Hoots
  • Patent number: 5206279
    Abstract: Aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers (e.g., random ethylene/acrylic acid interpolymers) are formed using a mixture of bases at a concentration of at least about 0.2 equivalents of base per mole of .alpha.,.beta.-unsaturated carboxylic acid. The dispersions have at least about 10 weight percent dispersed solids and not more than about 1 weight percent of the initial polymer in non-dispersed form. Preferred bases for use in forming the dispersions are ammonium hydroxide and/or alkali metal hydroxides. A mixture of ammonium hydroxide and potassium hydroxide is especially preferred for forming the dispersions with ethylene/acrylic acid interpolymers at an ammonium hydroxide:acrylic acid molar ratio of about 1:1 and a potassium hydroxide:acrylic acid molar ratio in the range of about 0.6-0.8:1. The dispersions are particularly useful in forming thin coatings of adhesive on substrates, such as paper and metal foil, using conventional techniques.
    Type: Grant
    Filed: January 25, 1991
    Date of Patent: April 27, 1993
    Assignee: The Dow Chemical Company
    Inventors: Michael E. Rowland, Kenneth E. Springs
  • Patent number: 5200473
    Abstract: For the preparation of hydrophilic polymer resins with functional groups on ligands, one reacts a resin which consists of units of formula I, in which R.sub.1 is hydrogen or an aliphatic residue, with a ligand in the presence of a coupling agent. The reaction is conducted in the presence of a competitive agent which is capable of reacting with the coupling agent at approximately the same rate as the amido group, to achieve a statistical limitation of the reaction of the coupling agent with the polymer. The competitive agent must not react with the resin.The resin is used for the recovery of metal ions from effluents or natural or industrial residual waters.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: April 6, 1993
    Inventor: Gilbert Jeanneret-Gris
  • Patent number: 5189111
    Abstract: Water-dilutable side-chain-containing vinylic copolymers comprising groups (.gamma.) of the formula--X--Alk--Y-- (I),whereinAlk signifies alkylene with 2-6 carbon atoms or hydroxysubstituted alkylene with 3-6 carbon atoms or alkylene with 4-6 carbon atoms, interrupted by --O--,X signifies a basic amino group or an ammonium group andY signifies a basic --NH-group or an acid adduct thereof,one of X and Y being further bound to an optionally substituted aliphatic or heteroaromatic hydrocarbon radical and the other to hydrogen or an optionally substituted aliphatic hydrocarbon radical, as a constituent of a least some of the side-chains and at least one mole % of the comonomer units constituting the copolymer bearing such (.gamma.)-containing side-chains - which are obtainable by copolymerization of corresponding comonomers or by amino-alkylation of corresponding starting polymers - are particularly suitable as precipitating and/or flocculating agents, e.g.
    Type: Grant
    Filed: January 4, 1989
    Date of Patent: February 23, 1993
    Assignee: Sandoz Ltd.
    Inventor: Bernard Danner
  • Patent number: 5189084
    Abstract: o-Hydroxyohenyl-s-triazines containing suitable functional groups are incorporated in polymers by copolymerisation, copolycondensation, copolyaddition or by polymer-analogous reaction. The modified polymers so obtained have excellent stability to degradation induced by light, oxygen and heat. They can also be used as stabilisers.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: February 23, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Luc Birbaum, Jean Rody, Mario Slongo, Andreas Valet
  • Patent number: 5171789
    Abstract: The present invention relates to poly(oxydiphenylamines) of the formula: ##STR1## wherein n is an integer ranging from about 1 to 100. The poly(oxydiphenylamines) are useful as a rubber additive and have shown improvement in the tear strength of the rubber as measured by increased peel adhesion.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: December 15, 1992
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson G. Wideman, George F. Balogh, Denise J. Keith
  • Patent number: 5145914
    Abstract: Polyacrylate esters with ammonium salt groups obtained by the transesterification of alkyl polyacrylates produced by free radical polymerization are disclosed, wherein the alkyl groups of the acrylate esters have 1 to 8 carbon atoms, up to 50% of the acrylate esters can be replaced by the corresponding methacrylate esters and the transesterification is carried out witha) compounds of the formula ##STR1## b) saturated or unsaturated aliphatic alcohols having 8 to 22 carbon atoms or alkoxylated alkylphenols having 9 to 27 carbon atoms in the alkylphenol group,wherein the molar ratio of component a) to component b) is 1:9 to 9:1, in such amount that 5 to 70% of the ester groups are transesterified and subsequently, the transesterification product is transformed into a salt.
    Type: Grant
    Filed: March 7, 1991
    Date of Patent: September 8, 1992
    Assignee: TH. Goldschmidt AG
    Inventors: Eberhard Esselborn, Jurgen Fock, Helmut Lammerting
  • Patent number: 5137980
    Abstract: Succinimides, succinic esters, and succinic ester-amides are formed by(A) reacting (i) at least one substantially aliphatic polymer of at least one lower olefin, and (ii) an acidic reactant or a mixture of two or more acidic reactants represented by the general formulaR--CO--CH.dbd.
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: August 11, 1992
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventors: David J. DeGonia, Paul G. Griffin
  • Patent number: 5135987
    Abstract: Binders for moisture-hardening coating or sealing compositions contain modified copolymers having a weight average molecular weight of from 1,500 to 75,000 determined by gel permeation chromatography of olefinically unsaturated compounds containing chemically incorporated moieties which are addition-reactive to amino wherein the modified copolymers contain both(i) intramolecular carboxylic anhydride moieties and(ii) olefinically unsaturated (meth)acrylate moieties in chemically bound form as the moieties which are addition-reactive to amino, with the anhydride equivalent weight being in the range from 392 to 9,800 and the (meth)acrylate equivalent weight in the range from 284 to 7,100.
    Type: Grant
    Filed: February 22, 1991
    Date of Patent: August 4, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Harald Blum, Josef Pedain, Peter Hohlein
  • Patent number: 5130378
    Abstract: The present invention relates to copolymers prepared from olefinically unsaturated compounds, having a molecular weight (M.sub.n) of 600 to 20,000 and containing 0.1 to 6.0% by weight of secondary amino groups, --NH--, in the form of structural units corresponding to formula I ##STR1## wherein R.sub.1 is a saturated aliphatic hydrocarbon radical containing 2 to 6 carbon atoms, provided that at least two carbon atoms are arranged between the two nitrogen atoms, andR.sub.2 is a methyl, ethyl or 2-hydroxyethyl group.The present invention also relates to a process for the production of these copolymers.
    Type: Grant
    Filed: August 28, 1990
    Date of Patent: July 14, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Josef Pedain, Christian Wamprecht
  • Patent number: 5128419
    Abstract: Polymers tagged with pendant fluorescent groups are prepared by the (trans)amidation derivatization of pre-existing polymers having carbonyl-type pendant groups. Polymers having pendant amide groups wherein the amide nitrogen is substituted with fluorescent moieties, prepared by (trans)amidation drrivatization, are provided. Polymers having pendant (sulfonated) napthalene moieties substituted to amide nitrogen are provided.
    Type: Grant
    Filed: August 20, 1990
    Date of Patent: July 7, 1992
    Assignee: Nalco Chemical Company
    Inventors: Dodd W. Fong, John E. Hoots
  • Patent number: 5116912
    Abstract: A metal treatment solution comprising an effective amount of a soluble or dispersible compound which is a derivative of a polyphenol. A composition for treatment and after treatment of metal with polyphenol compounds is provided. The present invention includes novel derivatives of polyphenol compounds which are useful in surface treatment solutions or dispersions. A method for using these solutions or dispersions is also provided. The molecular weight of the polyphenols used to form the derivatives of the present invention are in the range of from about 360 to 30,000 or greater. The resulting derivatives of the present invention typically have molecular weight of up to about 2,000,000 with molecular weights within the range of about 700 to about 70,000 being preferred.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: May 26, 1992
    Assignee: Henkel Corporation
    Inventors: Andreas Lindert, John R. Pierce, David R. McCormic, William D. Zimmermann
  • Patent number: 5115039
    Abstract: Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with a mixture of dialkylaminoalkanols and saturated or unsaturated aliphatic alcohols with 8 to 22 carbon atoms, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.
    Type: Grant
    Filed: June 5, 1991
    Date of Patent: May 19, 1992
    Assignee: Th. Goldschmidt AG
    Inventors: Jurgen Fock, Dietmar Schaefer, Eberhard Esselborn
  • Patent number: 5115040
    Abstract: Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with dialkylaminoalkanols, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: May 19, 1992
    Assignee: Th. Goldschmidt AG
    Inventors: Jurgen Fock, Dietmar Schaefer, Eberhard Esselborn
  • Patent number: 5110875
    Abstract: Polymers bearing a quaternary ammonium group are disclosed as being useful in lowering serum cholesterol levels in man. A compound of the invention is N-(2-N,N-dimethylamino)ethyl)-N,N-dimethylammoniomethyl-substituted polystyrene, chloride salt.
    Type: Grant
    Filed: June 12, 1990
    Date of Patent: May 5, 1992
    Assignee: Smith Kline & Franch Laboratories Limited
    Inventors: Albert A. Jaxa-Chamiec, Deirdre M. B. Hickey
  • Patent number: 5102958
    Abstract: A partially crosslinked, unsaturated elastomeric polymer of a C.sub.4 to C.sub.7 isomonoolefin and a C.sub.4 to C.sub.14 conjugated multiolefin is provided which has a low crosslink density. The partially crosslinked polymer is produced by curing an uncrosslinked unsaturated polymer having a low level of chemically bound halogen with a curing agent which reacts only with the halogen. Processes for preparing these partially crosslinked unsaturated polymers are also provided.
    Type: Grant
    Filed: May 30, 1991
    Date of Patent: April 7, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Pierre Hous, Olivier H. Lacoste, James V. Fusco, Irwin J. Gardner, William M. Davis, Lawrence W. Flatley
  • Patent number: 5100969
    Abstract: A pigment dispersing agent for paints is a combination of particular amine compound and particular acrylic copolymer or a combination of particular amine compound, particular acrylic copolymer and particular polyester resin. This pigment dispersing agent is applicable to both acrylic resin series paints and polyester resin series paints.
    Type: Grant
    Filed: August 18, 1989
    Date of Patent: March 31, 1992
    Assignee: Nippon Oil and Fats Company Limited
    Inventors: Toshio Yamamoto, Yoshiaki Matsukura, Osamu Ohe, Hisao Ogawa, Masahiro Ishidoya, Yoshiro Matsubara
  • Patent number: 5096977
    Abstract: Ultraviolet light stabilizers are chemically bound to anhydride containing polymers or copolymers. Polymeric stabilizers are prepared by the reaction of primary amino or hydrazido-substituted UV absorbers with some or all of the anhydride groups of the polymer or copolymer to form pendant stabilizer substituted imide or amic acid groups. The polymer bound stabilizers are not lost from the polymer system by volatilization, migration, or extraction, even at high temperature. The polymeric stabilizers of this invention may be used as they are or as concentrates to stabilize other polymer systems.
    Type: Grant
    Filed: September 24, 1990
    Date of Patent: March 17, 1992
    Assignee: Atochem North America, Inc.
    Inventors: Ronald E. MacLeay, Terry N. Myers
  • Patent number: 5096974
    Abstract: Polymer bound stabilizer compounds are provided in which two or more different classes of stabilizers are chemically bound to anhydride containing polymers or copolymers. Polymeric stabilizers are prepared by the reaction of primary amino or hydrazido substituted stabilizers (i.e., antioxidants, light stabilizers, etc.) with some or all of the anhydride groups of the polymer or copolymer to form pendant stabilizer substituted imide or amic acid groups. The polymer bound stabilizers are not lost from the polymer system by volatilization, migration or extraction, even at high temperatures. The polymer bound stabilizer compounds may be used as concentrates to stabilize other polymer systems.
    Type: Grant
    Filed: September 24, 1990
    Date of Patent: March 17, 1992
    Assignee: Atochem North America, Inc.
    Inventors: Ronald E. MacLeay, Terry N. Myers
  • Patent number: 5086089
    Abstract: A process for use with a polymer which is crosslinkable by reaction with an amino resin, which comprises the steps of determining a period of time within which full gelation of the polymer is to be achieved; preparing a gel-forming aqueous-based mixture comprising the polymer, a rapid amino resin crosslinking agent and a delayed amino resin crosslinking agent, the gel-forming aqueous-based mixture capable of complete gelation within the period of time so determined; partially gelling the aqueous-based mixture by reacting the polymer with the rapid amino resin crosslinking agent which is effective to complete the partial gelation by crosslinking the polymer within four hours; and fully gelling the aqueous-based mixture by reacting the polymer with the delayed amino resin crosslinking agent which is effective to complete the full gelation by crosslinking the polymer within the period of time so determined. A method of enhancing the recovery of oil from a subterranean oil-bearing formation is also provided.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: February 4, 1992
    Assignee: Mobil Oil Corporation
    Inventor: Paul Shu
  • Patent number: 5084520
    Abstract: The preparation of polymers which contain pendant hydrophobic groups or a mixture of both pendant hydrophobic and alkoxylated groups is accomplished by reacting a preexisting polymer having pendant acid amide and/or carboxylic groups with a primary or secondary amine in a substantially homogenous reaction mixture, the amine reactant including the desired hydrophobic and alkoxylated radicals. A unique polymer, having both pendant hydrophobic and alkoxylated groups, is provided.
    Type: Grant
    Filed: July 22, 1991
    Date of Patent: January 28, 1992
    Assignee: Nalco Chemical Company
    Inventor: Dodd W. Fong
  • Patent number: 5079306
    Abstract: Aqueous, uncured but curable, polymer compositions which are stable at room temperature and possess excellent shelf life in uncured form are disclosed. The uncured polymer compositions can be made into fibers using conventional fiber forming processes and cured to produce absorbent fibers capable of absorbing at least 60 times their weight of brine.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: January 7, 1992
    Assignee: Arco Chemical Technology, Inc.
    Inventor: Bi Le-Khac
  • Patent number: 5075390
    Abstract: The preparation of polymers which contain pendant hydrophobic groups or a mixture of both pendant hydrophobic and alkoxylated groups is accomplished by reacting a preexisting polymer having pendant acid amide and/or carboxylic groups with a primary or secondary amine in a substantially homogenous reaction mixture, the amine reactant including the desired hydrophobic and alkoxylated radicals. A unique polymer, having both pendant hydrophobic and alkoxylated groups, is provided.
    Type: Grant
    Filed: July 6, 1990
    Date of Patent: December 24, 1991
    Assignee: Nalco Chemical Company
    Inventor: Dodd W. Fong
  • Patent number: 5075387
    Abstract: A partially crosslinked, unsaturated elastomeric polymer of a C.sub.4 to C.sub.7 isomonoolefin and a C.sub.4 to C.sub.14 conjugated multiolefin is provided which has a low crosslink density. The partially crosslinked polymer is produced by curing an uncrosslinked unsaturated polymer having a low level of chemically bound halogen with a curing agent which reacts only with the halogen. Processes for preparing these partially crosslinked unsaturated polymers are also provided.
    Type: Grant
    Filed: December 22, 1989
    Date of Patent: December 24, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Pierre Hous, Olivier H. Lacoste, James V. Fusco, Irwin J. Gardner, William M. Davis, Lawrence W. Flatley
  • Patent number: 5057579
    Abstract: Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with dialkylaminoalkanols, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.
    Type: Grant
    Filed: December 8, 1989
    Date of Patent: October 15, 1991
    Assignee: Th. Goldschmidt AG
    Inventors: Jurgen Fock, Dietmar Schaefer, Eberhard Esselborn